CN109215705B - Method for controlling multi-domain structure of ferromagnetic single-layer film to realize ten-state data storage - Google Patents

Method for controlling multi-domain structure of ferromagnetic single-layer film to realize ten-state data storage Download PDF

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CN109215705B
CN109215705B CN201811060814.9A CN201811060814A CN109215705B CN 109215705 B CN109215705 B CN 109215705B CN 201811060814 A CN201811060814 A CN 201811060814A CN 109215705 B CN109215705 B CN 109215705B
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颜世申
田玉峰
陈延学
柏利慧
康仕寿
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    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
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Abstract

The invention relates to a method for controlling a multi-domain structure of a ferromagnetic single-layer film to realize ten-state data storage, which comprises the following steps: (1) applying a sufficiently large negative saturation magnetic field to the multi-domain magnetic film to enable the multi-domain magnetic film to be in a single-domain state; (2) applying a forward writing magnetic field to the multi-domain magnetic film operated in the step (1), and writing the magnetic film into different multi-domain states by changing the strength of the writing magnetic field, wherein each multi-domain state is used as an independent storage unit; the invention can directly store ten values of 0,1,2,3,4,5,6,7,8 and 9 in one physical storage unit, so as to be different from the traditional technology that only 0 and 1 can be stored in one physical storage unit at present, has wide application prospect in the aspect of high-density and low-power consumption magnetic electronic storage devices, and is also beneficial to developing a computer directly utilizing decimal operation. The invention has the advantages of strong universality, easy operation and room-temperature working.

Description

Method for controlling multi-domain structure of ferromagnetic single-layer film to realize ten-state data storage
Technical Field
The invention relates to a method for controlling a multi-domain structure of a ferromagnetic single-layer film to realize ten-state data storage, belonging to the field of data storage of information technology.
Background
The development of magnetic materials and science and technology are closely linked, and the magnetic materials do not make contributions from ancient compasses, modern hard disks and hard disk reading heads and novel magnetic random access memory devices. For example: the magnetic storage function in hard disks is to record "0" and "1" based on two significantly different magnetic states of the magnetic material; in a magnetic tunnel junction, "0" and "1" are represented by parallel and antiparallel alignments of the magnetic moments of the free and pinned layers, resulting in a tunnel junction having two resistance states, high and low. Also because of the ease of realisation of two different magnetic or resistive states, computers today are based on binary. However, with the rapid development of information technology, the demand for high storage density and low power consumption of devices is more and more urgent. This requires that we not only take full advantage of existing materials or devices, but also find new properties in existing material or device structures. If a stable ten-fold magnetic and resistive state can be given experimentally, a decimal-based computer can be developed, which not only can greatly improve the storage density, but also can promote the rapid development of artificial intelligence and brain-like computation.
However, magnetic thin films have been used for binary storage only, or as an integral part of functional devices to assist multi-state storage, and have not been used directly as carriers of multi-state magnetic and resistance states themselves.
Chinese patent document CN103824588A discloses a method for regulating magnetic multi-domain state, which is to apply a magnetic field intensity of 0 to 4 x 10 while passing current through a magnetic film5The magnetization state of the magnetic film is regulated and controlled by an A/m external magnetic field, wherein current is used for pushing a magnetic domain in a magnetic multi-domain state of the magnetic film to move, and the external magnetic field is used for regulating and controlling the generation of a new magnetic domain in the magnetic film and the state of an existing magnetic domain in the moving process, so that the magnetic film is in a stable magnetic multi-domain state. However, this patent suffers from the following drawbacks or deficiencies: firstly, the magnetic domain can be effectively regulated by simultaneously applying current and external magnetic field, and when the current density is less than 1 × 104A/cm2The regulation and control of time-external magnetic field and current has certain hysteresis effect; second, external magnetic fields are achieved by growing ferromagnetic layers or placing permanent magnets near magnetic films, or by means of current-generated Oersted fields and moving heads in conventional hard disks, usually only weaker magnetic fields (S) ((S))<1 tesla); third, the detection of the magnetic domain state utilizes only the hall effect.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a method for controlling a multi-domain structure of a ferromagnetic single-layer film to realize ten-state data storage;
the invention is expected to have wide application prospect in the aspect of high-density and low-power consumption magnetoelectronic memory devices.
Interpretation of terms:
1. the multi-domain magnetic thin film means that the magnetic thin film includes a large number of small magnetized regions having different directions, each of the small magnetized regions includes a large number of atoms, and magnetic moments of all the atoms are arranged in parallel in a certain direction, and the small magnetized regions are called magnetic domains. The atomic magnetic moments between adjacent magnetic domains are arranged in different directions.
2. A single domain (single domain) state is a magnetic state in which when the dimension of a magnetic material is smaller than a critical value, the original magnetic domain structure disappears and all magnetic moments are arranged in parallel only along a certain direction.
3. Ten states, which are ten remanent magnetic states or resistance states;
4. no overshot mode, the applied magnetic field does not exceed the applied field mode of the target magnetic field at any time until the target magnetic field is reached.
The technical scheme of the invention is as follows:
a method of controlling a multi-domain structure of a ferromagnetic single layer film to achieve ten-state data storage, comprising:
(1) applying a magnetic field (the applicable magnetic field range is +/-7 Tesla) which is larger than the saturation magnetic field of the multi-domain magnetic film in the direction of the negative magnetic field to make the multi-domain magnetic film in a single-domain state; a uniform initial state is provided for data storage.
Further preferably, in the step (1), a magnetic field larger than the saturation magnetic field of the multi-domain magnetic thin film is applied in the negative magnetic field direction by using a superconducting quantum interferometer magnetometer.
(2) Applying a positive magnetic field to the multi-domain magnetic film operated in the step (1), and increasing an external magnetic field to a target magnetic field (writing magnetic field) at an increasing rate of 0-200 oersteds/second through a No overshot mode to obtain a certain multi-domain state;
(3) changing the size of the target magnetic field, and executing the steps (1) to (2) to obtain another multi-magnetic-domain state; repeating the step (3) until ten multi-magnetic domain states are obtained;
the magnetic thin film is "written" to different multi-domain states by controlling the magnitude of the target magnetic field, affecting the number, size and direction of the magnetic domains. As the target magnetic field increases, more and more magnetic moments are aligned along the target magnetic field direction, resulting in an increase in the number of domains or regions aligned in the same direction as the target magnetic field, and a decrease in the number of domains or alignment in a direction opposite to the alignment of the magnetic moments of the target magnetic field toward the target magnetic field direction. Each multi-domain state acts as an independent memory cell; different multi-magnetic domain states can be read out through magnetism measurement such as residual magnetization, magneto-optical Kerr effect and the like, and can also be read out through electric transport characteristics such as abnormal Hall effect, magnetoresistance and the like.
(4) And (4) reading the ten multi-magnetic-domain states obtained in the step (3).
In the multi-domain magnetic film, the invention changes the quantity, the size and the direction of magnetic domains through an external magnetic field, thereby obtaining ten stable residual magnetic states or resistance states in the magnetic film, and realizing the direct storage of ten values of 0,1,2,3,4,5,6,7,8 and 9 in one physical storage unit, so as to be different from the traditional technology that only two values of 0 and 1 can be stored in one physical storage unit at present.
Preferably, according to the present invention, the step (4) includes: different multi-domain states are read out by residual magnetization or magneto-optical kerr effect magnetic measurement, or by abnormal hall effect or magneto-resistive electric transport property measurement.
According to a preferred embodiment of the invention, the desired multi-domain magnetic films are produced by magnetron sputtering, pulsed laser deposition, molecular beam epitaxy or electron beam evaporation.
According to the invention, the material of the multi-domain magnetic film is a ferromagnetic metal film, a ferromagnetic semiconductor film or a rare earth metal ferromagnetic film; the ferromagnetic metal film is made of Fe, Co, Ni, CoPt, CoPd, NiFe, CoFe, CoFeB, FeSi, FeSiAl or FeAl; the ferromagnetic semiconductor film is made of GaMnAs, InMnAs or CoZnO; the material of the rare earth metal ferromagnetic film is LaSrMnO or LaCaMnO.
The invention has the beneficial effects that:
1. the invention provides a method for obtaining ten stable remanent magnetic states or resistance states in a magnetic film, which can directly store ten values of 0,1,2,3,4,5,6,7,8 and 9 in one physical storage unit so as to be different from the traditional technology that only 0 and 1 values can be stored in one physical storage unit at present, has wide application prospect in the aspect of high-density and low-power-consumption magnetoelectronic storage devices, and is favorable for developing a computer directly utilizing decimal operation.
2. The invention has the advantages of strong universality, easy operation and room-temperature working.
3. The invention can realize up to 10 stable magnetic and resistance states only by controlling an applied external magnetic field (+ -7 Tesla) through the superconducting magnet without the assistance of current, and different magnetic and resistance states can be measured by an abnormal Hall effect and can also be read out through magnetic measurement and magneto-optical performance measurement.
Drawings
FIG. 1 is [ Co/Pt ]]5The magnetic film gradually increases the hysteresis loop of the write field.
FIG. 2 is [ Co/Pt ]]5The magnetic film shows the curve of the abnormal Hall effect when the writing magnetic field is gradually increased.
FIG. 3(a) shows [ Co/Pt ]]15The magnetic thin film gradually increases the magnetic domain image in the first remanence state after the magnetic field is written.
FIG. 3(b) is [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the second remanent state after the magnetic field is written.
FIG. 3(c) shows [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the third remanent state after the magnetic field is written.
FIG. 3(d) is [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the fourth remanence state after the magnetic field is written.
FIG. 3(e) is [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the fifth remanence state after the magnetic field is written.
FIG. 3(f) is [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the sixth remanence state after the magnetic field is written.
FIG. 3(g) is [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the seventh remanence state after the magnetic field is written.
FIG. 3(h) shows [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the eighth remanence state after the magnetic field is written.
FIG. 3(i) is [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the ninth remanence state after the magnetic field is written.
FIG. 3(j) is [ Co/Pt ]]15The magnetic film gradually increases the magnetic domain image in the tenth remanent state after the magnetic field is written.
Detailed Description
The invention is further defined in the following, but not limited to, the figures and examples in the description.
Examples
A method for controlling a multi-domain structure of a ferromagnetic single-layer film to realize ten-state data storage comprises the following steps:
(1) sputtering Ta (1nm)/Pt (6nm)/[ Pt0.3nm/Co0.5nm in this order on a (001) -oriented Si substrate with a magnetron sputtering apparatus]na/Ta (3nm) in which the growth rates of Pt and Co are each per second
Figure BDA0001797051110000041
And
Figure BDA0001797051110000042
and (3) preparing a Hall effect test structure with the width of 10 micrometers and the length of 70 micrometers by combining photoetching and ion etching for measuring the abnormal Hall effect.
(2)[Co/Pt]5In the thin film, the magnetic domain state is regulated and controlled through an external magnetic field, the thin film is written into ten different magnetic states, and the method comprises the following steps:
A. applying a magnetic field of-1500 oersted in the direction of the negative magnetic field by using a magnetometer of the superconducting quantum interferometer, and arranging all magnetic moments in the direction of the negative magnetic field; at this time, [ Co/Pt ] as a whole]5The film is in a monodomain state.
B. For the [ Co/Pt after the operation of the step (1)]5The film is applied with a forward magnetic field, and the write magnetic field is changed between 615 oersted and 670 oersted at an increasing rate of 0-200 oersted/second by a No overshot mode, thereby obtaining a hysteresis loop of 0-9 shown in FIG. 2. Is straightVisual detection of the magnetic domain state, for [ Co/Pt ]]15The film was subjected to the magnetic writing process of steps a-B and the magnetic domain images in the remanent state after different "writing" processes were measured. The initial negative saturation field during this process is-1000 oersted and the write field range is 676 oersted to 850 oersted. The specific situation is as follows: increasing the external magnetic field to 676 oersteds (write field) to obtain a first magnetic state; the corresponding magnetic domain image is shown in fig. 3 (a);
C. changing the write magnetic field to 701 oersted, and executing the steps A-B to obtain a second magnetic state; the corresponding magnetic domain image is shown in fig. 3 (b);
changing the write magnetic field to 703 oersted, and executing the steps A-B to obtain a third magnetic state; its corresponding magnetic domain image is shown in fig. 3 (c);
changing the write magnetic field to 704 oersted, and executing the steps A-B to obtain a fourth magnetic state; the corresponding magnetic domain image is shown in fig. 3 (d);
changing the write magnetic field to 707 oersted, and executing the steps A-B to obtain a fifth magnetic state; the corresponding magnetic domain image is shown in fig. 3 (e);
changing the write magnetic field to 720 oersted, and executing the steps A-B to obtain a sixth magnetic state; the corresponding magnetic domain image is shown in fig. 3 (f);
changing the write magnetic field to 726 oersted, and executing the steps A-B to obtain a seventh magnetic state; the corresponding magnetic domain image is shown in fig. 3 (g);
changing the writing magnetic field to 750 oersted, and executing the steps A-B to obtain an eighth magnetic state; the corresponding magnetic domain image is shown in fig. 3 (h);
changing the write magnetic field to 775 oersted, and executing the steps A-B to obtain a ninth magnetic state; the corresponding magnetic domain image is shown in fig. 3 (i);
changing the magnetic field to 850 Oersted, and executing the steps A-B to obtain the tenth magnetic state; its corresponding magnetic domain image is shown in fig. 3 (j);
gradually increasing the write field to change the number, size and direction of magnetic domains and induce the magnetic film to different valuesA multi-magnetic domain state; and a hysteresis loop between the negative saturation field and the "write" field is measured with a superconducting quantum interferometer. [ Co/Pt ]]5The hysteresis loops when the magnetic film gradually increases the write field are shown in fig. 1, and experiments show that when the write field is between 615 oersted and 670 oersted, the film hysteresis loops are obviously different, and decimal 0-9 can be obtained by using the residual magnetization as the record carrier of information.
The abnormal Hall effect, the magnetoresistance and the magnetization intensity in the magnetic material are closely related, so that the different magnetic states of the sample can be detected by using simpler electric transport measurement. FIG. 2 shows [ Co/Pt ]]5Anomalous hall effect measurements of the films during different "magnetic writing" processes. It can be seen that the hall voltage is also significantly different at different remanence states, and the remanence is proportional to the hall voltage. Therefore, different remanence states can be well read by using the Hall voltage, and ten values can be directly stored in one physical storage unit by using the Hall voltage as an information recording carrier.
The magneto-optical kerr effect measurements of fig. 3(a) -3 (j) show the distribution of the magnetic domains in the remanent state in the magnetic film and their evolution with the external field after different "magnetic writing" processes. To improve the signal-to-noise ratio, the measurement used [ Co/Pt ] repeated for 15 cycles]15A film. In the test process, the initial saturation field is-1000 oersted, and then the magnetic domain distribution in the remanence state is measured after the writing magnetic field is increased monotonously. The gray (black) areas in the figure represent the magnetic moments in the negative (positive) direction of the magnetic field. As can be seen from fig. 3(a) -3 (j), the magnetic domain distribution can be well controlled by the external magnetic field, the magnetic film can be "written" to different remanence states, and the remanence state can also be "read" intuitively by the magneto-optical effect. The area ratio of domains with different orientations can be used as information recording carrier to realize that one physical storage unit directly stores ten values.

Claims (5)

1. A method for controlling a multi-domain structure of a ferromagnetic single layer film to achieve ten-state data storage, comprising:
(1) applying a magnetic field larger than the saturation magnetic field of the multi-domain magnetic film in the direction of the negative magnetic field to make the multi-domain magnetic film in a single-domain state;
(2) applying a positive direction magnetic field to the multi-domain magnetic film operated in the step (1), and increasing an external magnetic field to a target magnetic field at an increasing rate of 0-200 oersted/second through a No overshot mode to obtain a certain multi-domain state;
(3) changing the size of the target magnetic field, and executing the steps (1) to (2) to obtain another multi-magnetic-domain state; namely: obtaining a stable magnetic domain state by changing the magnitude of the applied writing magnetic field, thereby establishing the one-to-one correspondence relationship between different magnetic domain states and different writing fields to perform magnetic writing and magnetic reading;
(4) and (4) reading the ten multi-magnetic-domain states obtained in the step (3).
2. The method for controlling the multi-domain structure of the ferromagnetic single-layer film to realize ten-state data storage according to claim 1, wherein in the step (1), a magnetic field larger than the saturation magnetic field of the multi-domain magnetic thin film is applied in the negative magnetic field direction by using a superconducting quantum interferometer magnetometer.
3. The method for controlling the multi-domain structure of the ferromagnetic single-layer film to realize ten-state data storage according to claim 1, wherein the step (4) comprises: different multi-domain states are read out by residual magnetization or magneto-optical kerr effect magnetic measurement, or by abnormal hall effect or magneto-resistive electric transport property measurement.
4. The method for controlling the multi-domain structure of the ferromagnetic single-layer film to realize ten-state data storage according to claim 1, wherein the desired multi-domain magnetic thin film is prepared by magnetron sputtering, pulsed laser deposition, molecular beam epitaxy or electron beam evaporation.
5. The method for controlling the multi-domain structure of the ferromagnetic single-layer film to realize ten-state data storage according to any one of claims 1 to 4, wherein the material of the multi-domain magnetic film is a ferromagnetic metal film, a ferromagnetic semiconductor film or a rare earth metal ferromagnetic film; the ferromagnetic metal film is made of Fe, Co, Ni, CoPt, CoPd, NiFe, CoFe, CoFeB, FeSi, FeSiAl or FeAl; the ferromagnetic semiconductor film is made of GaMnAs, InMnAs or CoZnO; the material of the rare earth metal ferromagnetic film is LaSrMnO or LaCaMnO.
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