CN109206088A - A kind of preparation method of decorative panel - Google Patents
A kind of preparation method of decorative panel Download PDFInfo
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- CN109206088A CN109206088A CN201710516088.6A CN201710516088A CN109206088A CN 109206088 A CN109206088 A CN 109206088A CN 201710516088 A CN201710516088 A CN 201710516088A CN 109206088 A CN109206088 A CN 109206088A
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- China
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- parts
- middle bed
- decorative panel
- alkali
- alkaline residue
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Finishing Walls (AREA)
Abstract
The present invention provides a kind of preparation methods of decorative panel.The decorative panel is pressed by architectural surface and the middle bed of material, and the outer surface spraying and decorating surface layer material of architectural surface, the middle bed of material takes molding middle bed of material material to be made by copying.The architectural surface material is made of the component of following weight parts meter: 100 parts of alkaline residue, 0-50 parts of cement, 1-20 parts of alkali-activator, 20-60 parts of water, 5-30 parts of paper pulp fiber, 1-30 parts of pigment and 0.5-1 parts of polypropylene fibre.The middle bed of material material is made of following weight parts component: 100 parts of alkaline residue, 0-30 parts of cement, 1-15 parts of alkali-activator, 10-40 parts of water, 5-50 parts of paper pulp fiber and 0.5-2 parts of polypropylene fibre.Technical solution provided by the invention takes full advantage of the latent hydraulicity of alkaline residue, generates in higher hydration rate and reaches the high-strength products of decorative plate of outer wall performance indexes, and ensure that plate at base quality, it can be achieved that batch production.
Description
Technical field
The present invention relates to a kind of decorative panel, in particular to a kind of preparation method of decorative panel.
Background technique
There are commonly building coating, exterior wall tile, glass curtain wall, ceramics for the building exposed wall decoration material researched and developed in recent years
Hanging plate, aluminium sheet, aluminium-plastic panel etc..Exterior coating is safe, it is rich in color, be easy to update, but to such as crack resistance of wall, weather-proof resistance to
Long property protective value is poor, and easily dirty, fugitive color；And reflective, ceramic hanging board the high density and exterior wall tile itself of glass curtain wall
From great, potential danger is brought in exterior wall skyscraper use, and usually high temperature is fired, and is belonged to high pollution high energy consumption class and is produced
Product, security risk and environmentally friendly hidden danger are simultaneously deposited.Aluminium sheet, the metals class external wall decorative material such as aluminium-plastic panel is since its cost is high, installation
It is required that complicated, it is difficult to universal.Therefore, people put forth effort to research and develop it is cheap, environmentally friendly, be readily produced, and light weight, intensity are high, tough
Property high, durability is good, shrinking percentage is low outer wall decoration board.
Alkali-activated carbonatite cementitious material is a kind of cementitious material generated by potential cement components and alkali-activator reaction,
With abundant raw materials (using trade waste), preparation is simple and low power consumption and other advantages, and has both good corrosion resistant, resistance to
The performances such as high temperature.Wherein, potential gel rubber material component is mainly metakaolin, granulated blast-furnace slag, granulation phosphorus slag and flyash
Deng.Alkali-activator is mainly caustic alkali, soluble silicate or non-silicate.Alkali-activated carbonatite cementitious material and Conventional Portland water
Mud is compared, and has many advantages, such as that requirement is small, the heat of hydration is low, intensity is high and durability is good.And the ingredient of the type of alkali-activator, slag
The Nomenclature Composition and Structure of Complexes of hydrated product can be all set to generate larger difference with the difference of structure.(application study of alkali-activated carbonatite cementitious material,
Zhang Bo (173) 53, the 3rd phase of volume 23 " Chinese gelling agent " in March, the 2014th)
Experiment discovery of the present inventor by long-term and arduous exploration and repeatedly produces exterior wall using alkali-activated carbonatite cementitious material
Decorative panel needs solve the problems, such as following many numerous and jumbled: how potential gel rubber material component are selected out from countless possible schemes
Compounding to improve early hydration speed and generate high-intensitive product, reach anticorrosive decorative plate of outer wall, shock resistance, resist it is tired
The performance indexess such as labor, toughness are high, durability is good, shrinking percentage is low etc.；How appropriate alkali-activator is prepared in aquation mistake
To the potential gel rubber material activity excitation of compounding in journey, its latent hydraulicity is made to be not fully exerted；How thin pulp thin material is improved
At base quality and how to realize that pipelining reaches batch production.A series of this linksystem problem becomes alkali-activated carbonatite gelling material
Expect the difficult point of industrialization production decorative plate of outer wall.
Summary of the invention
In view of this, in order to overcome above-mentioned difficult point, the present invention provide a kind of decorative panel compound scheme and corresponding production
Technique, the technical solution have given full play to the latent hydraulicity of alkaline residue, generated in higher hydration rate high-intensitive product with
Reach decorative plate of outer wall performance indexes, and ensure that plate at base quality, it can be achieved that batch production pipelining.
A kind of preparation method of decorative panel provided by the invention, the preparation method of above-mentioned decorative panel include the following steps:
1) by the architectural surface material and middle bed of material material respectively according to solution, powder and paper pulp fiber sequence successively
It is added in blender and stirs 5-10min；
2) architectural surface material is injected in be coated with release agent in textured template；
3) middle bed of material material is discharged into copy to take to copy in machine and takes molding, in 20-35 DEG C, 0.1-1MPa and 10-20m/min speed
Under copy and take dehydration forming；
4) texture formwork with architectural surface material is compressed on to copy and is taken on the molding middle bed of material；
5) molding wet panel is cut into corresponding size；
6) plate is put into 20-50 DEG C, conserved 1-3 days in the environment of relative humidity 70-90%；
7) blank flat is cut into specification.
Further, the decorative panel includes the architectural surface and the middle bed of material of pressing,
Further, the architectural surface outer surface is coated with architectural surface material, and the architectural surface material is by by weight
Following components of amount part meter are made:
100 parts of alkaline residue, 0-50 parts of cement, 1-20 parts of alkali-activator, 20-60 parts of water, 5-30 parts of paper pulp fiber, pigment 1-
30 parts and polypropylene fibre 0.5-1 parts；
Further, the middle bed of material takes molding middle bed of material material to be made by copying, and the middle bed of material material is by by weight
Following components of meter are made:
100 parts of alkaline residue, 0-30 parts of cement, 1-15 parts of alkali-activator, 10-40 parts of water, 5-50 parts of paper pulp fiber and poly- third
0.5-2 parts of alkene fiber.
Further, the alkali-activator is caustic soda, lime and dihydrate gypsum is compound is formulated.
Further, the architectural surface material is made of following components by weight:
100 parts of alkaline residue, 25 parts of cement, 10 parts of alkali-activator, 40 parts of water, 20 parts of paper pulp fiber, 5 parts of pigment and polypropylene
0.5 part of fiber.
Further, the architectural surface material is made of following components by weight:
100 parts of alkaline residue, 50 parts of cement, 12 parts of alkali-activator, 50 parts of water, 30 parts of paper pulp fiber and 1 part of polypropylene fibre.
Further, the middle bed of material material is made of following components by weight:
100 parts of alkaline residue, 20 parts of cement, 8 parts of alkali-activator, 25 parts of water, 25 parts of paper pulp fiber and 1 part of polypropylene fibre.
Further, the middle bed of material material is made of following components by weight:
100 parts of alkaline residue, 30 parts of cement, 10 parts of alkali-activator, 30 parts of water, 35 parts of paper pulp fiber and polypropylene fibre 1.5
Part.
Further, the ingredient of the alkaline residue are as follows: mass percent CaSO345.6%, CaCl210.5%, Al2O33.0%,
SiO27.8%, CaCO43.9%, CaO 10.3%, Fe2O30.7%, Mg (OH)29.0%, NaCl 2.7%, H2O 5.3%.
Further, the alkali-activator is by caustic soda, lime and dihydrate gypsum is compound is formulated, and weight ratio is 4:
3:1.5.
Further, the alkali-activator is by caustic soda, lime and dihydrate gypsum is compound is formulated, and weight ratio is 8:
5:3.
Further, the alkaline residue is that alkaline residue original slag is made after grinding, and specific surface area is 300-600m2/kg；The water
Mud is portland cement, and more than 32.5 grades.
The reagent for preparing alkali-activator is technical grade, high-class product, content >=99.0%.
Alkaline residue refers to the alkaline scrap material that alkaline and alkali process are discharged in the process in industrial production, includes ammonia-soda process alkali producing process
The alkaline scrap material of the waste residue of middle discharge and other industrial processes discharge.Alkaline residue composition mainly includes calcium carbonate, calcium sulfate, chlorine
Change the waste residue that the calcium salts such as calcium are main component, also containing compositions such as a small amount of sulfur dioxide, since it contains a large amount of chloride
As reluctant solid waste, the serious pollution environment of alkaline residue stockpiling restricts the development of basic industry.
Alkali-activator and a small amount of cement are mixed in alkaline residue powder can prepare alkali-activated carbonatite alkaline residue cementitious material, have basicity
The high, plurality of advantages such as the heat of hydration is low, it is less in application aspect research at present, especially in board product on still in sky
It is white.Therefore, further seek needed for alkaline residue decorative plate of outer wall more preferably for building becomes a reality.
Compared with the latest prior art, technical solution provided by the invention has following excellent effect:
1, the present invention chooses alkali-activated carbonatite alkaline residue and generates cementitious material, and simple production process, alkaline residue is cheap, can become useless
For treasured；
2, alkali-activator can be released effectively the alkaline components of alkaline residue, increase basicity, improve the aquation speed of cementitious material
Degree and early strength；
3, the decorative plate of outer wall prepared, excellent durability, toughness are high, excellent in cushion effect, anti-fatigue performance is good；
4, the production efficiency is high, at low cost, it is easy to form pipelining and batch production；
5, the thin material of thin pulp can be improved into base quality in the technique.
Specific embodiment
Further clear and complete explanation is done to technical solution provided by the invention below by the mode of specific embodiment,
But they are not construed as limiting the invention.
Embodiment 1
Prepare a kind of decorative plate of outer wall
1, raw material preparation:
1) alkali-activator is prepared:
By weight, caustic soda: lime: dihydrate gypsum 4:3:1.5.
2) architectural surface material is prepared:
By weight, 100 parts of alkaline residue, 25 parts of cement, 10 parts of alkali-activator, 40 parts of water, 20 parts of paper pulp fiber, pigment
5 parts, 0.5 part of polypropylene fibre.
3) bed of material material in preparing:
By weight, 100 parts of alkaline residue, 20 parts of cement, 8 parts of alkali-activator, 25 parts of water, 25 parts of paper pulp fiber, poly- third
1 part of alkene fiber.
The ingredient of alkaline residue in said components are as follows: mass percent CaSO345.6%, CaCl210.5%, Al2O33.0%,
SiO27.8%, CaCO43.9%, CaO 10.3%, Fe2O30.7%, Mg (OH)29.0%, NaCl 2.7%, H2O 5.3%.
2, decorative plate of outer wall step is prepared:
1) architectural surface material and middle bed of material material are sequentially added according to the sequence of solution, powder and paper pulp fiber respectively
8min is stirred in blender；
2) architectural surface material is injected in the template with special texture for being coated with release agent；
3) middle bed of material material is discharged into copy to take to copy in machine and takes molding, copied and take in dewatering pressure molding, temperature is 25 DEG C, pressure
For 0.1MPa, speed 15m/min；
4) texture formwork with architectural surface material is compressed on to copy and takes middle bed of material material after molding；
5) molding wet panel is cut into corresponding size；
6) plate is put into 30 DEG C of temperature, conserves 2 days in 75% environment of relative humidity；
7) blank flat is cut into specification.
Embodiment 2
Prepare a kind of decorative plate of outer wall
1, raw material preparation:
1) alkali-activator is prepared:
By weight, caustic soda: lime: dihydrate gypsum 8:5:3.
2) architectural surface material is prepared:
By weight, 100 parts of alkaline residue, 50 parts of cement, 12 parts of alkali-activator, 50 parts of water, 30 parts of paper pulp fiber, pigment
5 parts, 1 part of polypropylene fibre.
3) bed of material material in preparing:
By weight, 100 parts of alkaline residue, 30 parts of cement, 10 parts of alkali-activator, 30 parts of water, 35 parts of paper pulp fiber, poly- third
1.5 parts of alkene fiber.
2, decorative plate of outer wall step is prepared:
1) architectural surface material and middle bed of material material are sequentially added according to the sequence of solution, powder and paper pulp fiber respectively
10min is stirred in blender；
2) architectural surface material is injected in the template with special texture for being coated with release agent；
3) middle bed of material material is discharged into copy to take to copy in machine and takes molding, copied and take in dewatering pressure molding, temperature is 30 DEG C, pressure
For 0.5MPa, speed 20m/min；
4) texture formwork with architectural surface material is compressed on to copy and takes middle bed of material material after molding；
5) molding wet panel is cut into corresponding size；
6) plate is put into 35 DEG C of temperature, conserves 1 day in 85% environment of relative humidity；
7) blank flat is cut into specification.
Embodiment 3-14 is as follows: (with embodiment 1, preparation process is with embodiment 2 for the preparation of alkali-activator)
Surface layer material is prepared such as table 1:(by weight)
Table 1
| Embodiment number | Alkaline residue | Cement | Alkali-activator | Water | Paper pulp fiber | Pigment | Polypropylene fibre |
| Embodiment 3 | 100 | 40 | 11 | 24 | 28 | 15 | 0.5 |
| Embodiment 4 | 100 | 3 | 20 | 46 | 14 | 21 | 0.9 |
| Embodiment 5 | 100 | 34 | 7 | 20 | 9 | 30 | 0.7 |
| Embodiment 6 | 100 | 27 | 1 | 32 | 5 | 2 | 1.0 |
| Embodiment 7 | 100 | 0 | 9 | 50 | 13 | 10 | 0.6 |
| Embodiment 8 | 100 | 16 | 4 | 40 | 21 | 1 | 0.8 |
| Embodiment 9 | 100 | 50 | 19 | 28 | 19 | 26 | 0.7 |
| Embodiment 10 | 100 | 9 | 14 | 25 | 7 | 15 | 1.0 |
| Embodiment 11 | 100 | 46 | 18 | 60 | 30 | 28 | 0.5 |
| Embodiment 12 | 100 | 38 | 16 | 48 | 28 | 20 | 0.6 |
| Embodiment 13 | 100 | 46 | 12 | 52 | 24 | 22 | 0.8 |
| Embodiment 14 | 100 | 44 | 15 | 44 | 25 | 23 | 0.9 |
Middle bed of material material is prepared such as table 2:(by weight)
Table 2
The performance of the decorative plate of outer wall prepared in above-described embodiment is as follows:
Table 3
The above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof, although referring to above-described embodiment pair
The present invention is described in detail, those of ordinary skill in the art still can to a specific embodiment of the invention into
Row modifies perhaps equivalent replacement and these exist without departing from any modification of spirit and scope of the invention or equivalent replacement
Apply within pending claims of the invention.
Claims (10)
1. a kind of preparation method of decorative panel, which is characterized in that the decorative panel includes the architectural surface and the middle bed of material of pressing, institute
It states architectural surface outer surface and is coated with architectural surface material, the middle bed of material takes molding middle bed of material material to be made by copying, including
Following steps:
1) the architectural surface material and middle bed of material material are separately added into blender and stir 5-10min；
2) architectural surface material is injected in be coated with release agent in textured template；
3) middle bed of material material is discharged into copy to take to copy in machine and takes molding, copied under 20-35 DEG C, 0.1-1MPa and 10-20m/min speed
Take dehydration forming；
4) texture formwork with architectural surface material is compressed on to copy and is taken on the molding middle bed of material；
5) molding wet panel is cut into corresponding size；
6) plate is put into 20-50 DEG C, conserved 1-3 days in the environment of relative humidity 70-90%；
7) blank flat is cut into specification.
2. a kind of preparation method of decorative panel as described in claim 1, which is characterized in that the architectural surface material is by by weight
Following components of part meter are made:
100 parts of alkaline residue, 0-50 parts of cement, 1-20 parts of alkali-activator, 20-60 parts of water, 5-30 parts of paper pulp fiber, 1-30 parts of pigment
With 0.5-1 parts of polypropylene fibre.
3. a kind of preparation method of decorative panel as described in claim 1, which is characterized in that the middle bed of material by copy take it is molding
Middle bed of material material is made, and the middle bed of material material is made of following components by weight:
100 parts of alkaline residue, 0-30 parts of cement, 1-15 parts of alkali-activator, 10-40 parts of water, 5-50 parts of paper pulp fiber and polypropylene are fine
0.5-2 parts of dimension.
4. according to a kind of preparation method of decorative panel described in claim 2 or 3, which is characterized in that the alkali-activator is
Caustic soda, lime and dihydrate gypsum is compound is formulated.
5. a kind of preparation method of decorative panel as claimed in claim 2, which is characterized in that the architectural surface material is by pressing
Following components of parts by weight meter are made:
100 parts of alkaline residue, 25 parts of cement, 10 parts of alkali-activator, 40 parts of water, 20 parts of paper pulp fiber, 5 parts of pigment and polypropylene fibre
0.5 part.
6. a kind of preparation method of decorative panel as claimed in claim 2, which is characterized in that the architectural surface material is by pressing
Following components of parts by weight meter are made:
100 parts of alkaline residue, 50 parts of cement, 12 parts of alkali-activator, 50 parts of water, 30 parts of paper pulp fiber and 1 part of polypropylene fibre.
7. a kind of preparation method of decorative panel as claimed in claim 3, which is characterized in that the middle bed of material material is by by weight
Following components of part meter are made:
100 parts of alkaline residue, 20 parts of cement, 8 parts of alkali-activator, 25 parts of water, 25 parts of paper pulp fiber and 1 part of polypropylene fibre.
8. a kind of preparation method of decorative panel as claimed in claim 3, which is characterized in that the middle bed of material material is by by weight
Following components of part meter are made:
100 parts of alkaline residue, 30 parts of cement, 10 parts of alkali-activator, 30 parts of water, 35 parts of paper pulp fiber and 1.5 parts of polypropylene fibre.
9. a kind of preparation method of decorative panel as claimed in claim 2 or claim 3, which is characterized in that the ingredient of the alkaline residue are as follows: matter
Measure percentage CaSO345.6%, CaCl210.5%, Al2O33.0%, SiO27.8%, CaCO43.9%, CaO 10.3%,
Fe2O30.7%, Mg (OH)29.0%, NaCl 2.7%, H2O 5.3%.
10. a kind of preparation method of decorative panel as described in claim 1, which is characterized in that the alkaline residue is alkaline residue original slag warp
It is made after grinding, and specific surface area is 300-600m2/kg；The cement is portland cement, and more than 32.5 grades.
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| CN201710516088.6A CN109206088A (en) | 2017-06-29 | 2017-06-29 | A kind of preparation method of decorative panel |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109761568A (en) * | 2019-03-14 | 2019-05-17 | 徐州帝威伦新型建材有限公司 | A kind of light-weight water-proof decorative plate of outer wall and preparation method thereof |
| CN112110708A (en) * | 2020-09-18 | 2020-12-22 | 唐山中陶纪元工程设计有限公司 | Waterproof isolation plate and preparation method thereof |
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- 2017-06-29 CN CN201710516088.6A patent/CN109206088A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20120260594A1 (en) * | 2009-07-06 | 2012-10-18 | Blackstock Jonh Mcilvenna | Geopolymeric structural building units and methods of manufacture thereof |
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|---|
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109761568A (en) * | 2019-03-14 | 2019-05-17 | 徐州帝威伦新型建材有限公司 | A kind of light-weight water-proof decorative plate of outer wall and preparation method thereof |
| CN112110708A (en) * | 2020-09-18 | 2020-12-22 | 唐山中陶纪元工程设计有限公司 | Waterproof isolation plate and preparation method thereof |
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