CN109181589A - A kind of environmental protection mythimna separata offset plate and preparation method thereof - Google Patents
A kind of environmental protection mythimna separata offset plate and preparation method thereof Download PDFInfo
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- CN109181589A CN109181589A CN201811014969.9A CN201811014969A CN109181589A CN 109181589 A CN109181589 A CN 109181589A CN 201811014969 A CN201811014969 A CN 201811014969A CN 109181589 A CN109181589 A CN 109181589A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J135/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J135/02—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to a kind of environmentally friendly mythimna separata offset plates and preparation method thereof, belong to pest control technical field.The present invention is added Isooctyl acrylate monomer, butyl acrylate, hydroxy-ethyl acrylate etc. and is stirred, become pre-emulsion, have outstanding cementability, filming performance and anti-aging property using nonylphenol polyoxyethylene ether sulfonic acid ammonium salt as emulsifier；Using dibutyl itaconate, isoprene as matrix, 4-vinylpridine is added and has synthesized the functionalized biological species rubber thickening activating agent of pyridine as modified monomer, while introducing is biodegradable tackifier, substance in system is environment-friendly type additive, will not generate penetrating odor；Phenylmethyl acetate, cinnamic acid, caryophyllus oil, honey etc. is added, improves and lures efficiency, to make insect close to stickum, be adhered on mythimna separata offset plate.The present invention solves the problems, such as poor, the irritant smell of current mythimna separata offset plate viscosity.
Description
Technical field
The present invention relates to a kind of environmentally friendly mythimna separata offset plates and preparation method thereof, belong to pest control technical field.
Background technique
With the development of society, enhancing of the people to environmental consciousness, people gradually have found can be to environment using chemical pesticide
Destructive influences are generated with the ecosystem.So-called non-environmental pollution control method refers to control measure to people, animal, fowl, fish, honeybee
And beneficial insect (i.e. the natural enemy of pest) safe fanout free region, while to the ecological balance without destruction, agricultural product meet nuisanceless
Agricultural requires.So now for the prevention and treatment for the pest that agriculture and forestry produce is influenced also by relying on chemical method to turn to without public affairs merely
Harmful control method.Therefore, it is particularly important in the prevention and control of plant diseases, pest control of agriculture and forestry using non-harmful control method.It utilizes
Many pests have the habit of context tree, smear the prevention and treatment that nuisanceless insect sticker carries out pest in trunk, can receive half function of thing
Effect again.Therefore, non-environmental pollution control measure is studied and applied, environmental pollution caused by control of insect is reduced, has become people
Know together and Future Development direction.Using insect sticker prevention and treatment forest disease and pest as one of non-environmental pollution control method, increasingly
It is valued by people.But the mythimna separata plastic sheet product having been commercialized now, all different degrees of presence are not easy to construct, are irritating
Property smell, easily trickling, viscosity it is poor, validity period is short and use temperature range is narrow the disadvantages of, therefore, urgent need develop one kind it is at low cost,
Nuisanceless, blowing-resistant solarization, drenches with rain, the mythimna separata offset plate that viscosity is strong and lasting.
Summary of the invention
The technical problems to be solved by the invention: it aiming at the problem that poor current mythimna separata offset plate viscosity, irritant smell, mentions
For a kind of environmentally friendly mythimna separata offset plate and preparation method thereof.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of environmental protection mythimna separata offset plate, including viscose glue lotion matrix, thickening activating agent, insect trapping agent；
The preparation method of the viscose glue lotion matrix, includes the following steps:
It takes nonylphenol polyoxyethylene ether sulfonic acid ammonium salt 1 ~ 3:20 in mass ratio ~ 25 that distilled water is added to be stirred, obtains emulsifier, press
Mass fraction meter takes 3 ~ 7 parts of Isooctyl acrylate monomers, 1 ~ 3 part of butyl acrylate, 2 ~ 5 parts of hydroxy-ethyl acrylates, 5 ~ 8 parts of methyl-props
E pioic acid methyl ester, 8 ~ 10 parts of methacrylic acids are stirred, and are obtained stirring mixture, are added and be stirred amount of substance 0.5 ~ 1.5%
Hexadecanol obtains mixture, and mixture 3 ~ 5:50 ~ 70 in mass ratio is taken to be added dropwise in emulsifier, controls 40 ~ 60min of time for adding,
It is stirred 30 ~ 50min, obtains viscose glue lotion matrix.
The stirring mixture is stirred condition are as follows: is warming up to 30 ~ 40 DEG C and is stirred 30 ~ 50min.
The preparation method of the thickening activating agent, includes the following steps:
(1) dibutyl itaconate, isoprene, 4-vinylpridine 70 ~ 80:15 in mass ratio ~ 20:2 ~ 5 is taken to mix, in
400rpm is stirred, and obtains mixture, according to the mass fraction, takes the oleic acid aqueous solutions of potassium, 1 ~ 3 part of disproportionation that mass fraction is 10%
Potassium rosinate, 0.2 ~ 0.5 part of potassium phosphate, 0.5 ~ 0.8 part of potassium chloride, 0.04 ~ 0.08 portion of EDTA Fe salt, 0.3 ~ 0.5 part of formaldehyde
Sodium bisulphite, 200 ~ 300 parts of deionized waters, 80 ~ 100 parts of mixtures, are passed through nitrogen protection, are stirred, must be stirred
Object a；
(2) take stirring mixture a 100 ~ 200:0.2 in mass ratio ~ 0.5 that tert-butyl hydroperoxide is added, it is mixed in 250rpm stirring
Close, add stirring mixture a mass 0.4 ~ 0.8% azanol, stand, obtain standing liquid, take stand liquid 2 ~ 5:8 in mass ratio ~
10 are added dehydrated alcohol to get thickening activating agent.
Stirring mixture a's is stirred condition in the step (1) are as follows: is stirred 1 ~ 3h in 15 ~ 20 DEG C.
The insect trapping agent: according to the mass fraction, 2 ~ 4 parts of phenylmethyl acetates, 1 ~ 3 portion of cinnamic acid, 1 ~ 3 portion of cloves are taken
Oil, the mixing of 5 ~ 10 parts of honey to get.
A kind of preparation method of environmental protection mythimna separata offset plate includes the following steps:
S1. according to the mass fraction, 6 ~ 10 parts of viscose glue lotion matrixes, 80 ~ 100 parts of distilled water, 0.1 ~ 0.3 part of sodium bicarbonate are taken, is stirred
20 ~ 30min of mixing is mixed, mixture is obtained, is warming up to 75 ~ 80 DEG C, the ammonium persulfate of mixture quality 1 ~ 3% is added, it is warming up to 80 ~
The thickening of 85 DEG C of 30 ~ 40min of heat preservation, the viscose glue lotion matrix and mixture quality 30 ~ 40% that instill mixture quality 10 ~ 20% are living
Property agent, control 1 ~ 3h of time for adding and in 80 ~ 85 DEG C of 2 ~ 4h of heat preservation be cooled to 70 ~ 75 DEG C, obtain cooled material；
S2. it takes cooled material 100 ~ 150:1 in mass ratio ~ 3 that tert-butyl hydroperoxide is added, is stirred 50 ~ 60min, is cooled to
Room temperature adjusts pH to 7 ~ 7.2 with ammonium hydroxide, obtains mythimna separata rubber base, takes mythimna separata rubber base 50 ~ 80:4 in mass ratio ~ 9 that insect is added
Trapping bait mixing, obtains environmentally friendly insect sticker, environmentally friendly insect sticker is taken to be applied on yellow plate to get environmentally friendly mythimna separata offset plate.
The applying amount of environmentally friendly insect sticker in the step S2 are as follows: 2 ~ 5g/cm2。
The present invention is compared with other methods, and advantageous effects are:
(1) present invention using nonylphenol polyoxyethylene ether sulfonic acid ammonium salt as emulsifier, be added Isooctyl acrylate monomer, butyl acrylate,
Hydroxy-ethyl acrylate etc. is stirred, and becomes pre-emulsion, forms the viscose glue lotion matrix of acrylic acid esters co-polymer, has
Outstanding cementability, filming performance and anti-aging property；
(2) 4-vinylpridine is added as modified monomer, synthesis using dibutyl itaconate, isoprene as matrix in the present invention
The functionalized biological species rubber of pyridine viscosifies activating agent, and 4-vinylpridine gradually increases loaded rubber network, therefore multiple
The non-deformability of condensation material is gradually increased, and mixes viscose glue lotion matrix as modifying agent, hydrolyzes the carboxyl object generated
Hydroxyl, carboxyl in matter and viscose glue lotion matrix strand etc. form hydrogen bond, and intermolecular and intramolecular generates hydrogen bond crosslinks, increase
Cross-linked network density between polymer, and in reaction process, due to introducing ammonium persulfate initiator, draw under heating conditions
It has sent out the double bond of thickening activating agent and Acrylate copolymerical emulsion generates crosslinking copolymerization and reacts, so that linear polymer molecules
Chain is cross-linked to form reticular structure, so that the consistency of viscose glue is improved, viscosity is improved, and will not generate showing of easily trickling
As, while introducing is biodegradable tackifier, the substance in system is environment-friendly type additive, will not generate irritation gas
Taste；
(3) present invention is added phenylmethyl acetate, cinnamic acid, caryophyllus oil, honey etc. and is added what insect was liked in terms of smell, the sense of taste
Sweet taste and fragrance etc., while insect trapping agent surface layer is formed by adhesivity substance and is protected, it is not easy volatilization and is lost, to make to draw
It lures the time limit to be extended, improves and lure efficiency, to make insect close to stickum, be adhered on mythimna separata offset plate.
Specific embodiment
Viscose glue lotion matrix: it takes nonylphenol polyoxyethylene ether sulfonic acid ammonium salt 1 ~ 3:20 in mass ratio ~ 25 that distilled water is added, stirs
20 ~ 30min of mixing is mixed, emulsifier is obtained, according to the mass fraction, takes 3 ~ 7 parts of Isooctyl acrylate monomers, 1 ~ 3 part of butyl acrylate, 2 ~ 5
Part hydroxy-ethyl acrylate, 5 ~ 8 parts of methyl methacrylates, 8 ~ 10 parts of methacrylic acids, be warming up to 30 ~ 40 DEG C be stirred 30 ~
50min obtains stirring mixture, adds the hexadecanol for being stirred amount of substance 0.5 ~ 1.5%, obtains mixture, takes mixture by matter
Amount is added dropwise in emulsifier than 3 ~ 5:50 ~ 70, is controlled 40 ~ 60min of time for adding, is stirred 30 ~ 50min, obtains viscose glue lotion
Matrix.
Viscosify activating agent:
(1) dibutyl itaconate, isoprene, 4-vinylpridine 70 ~ 80:15 in mass ratio ~ 20:2 ~ 5 is taken to mix, in
400rpm is stirred 30 ~ 40min, obtains mixture, according to the mass fraction, take mass fraction be 10% oleic acid aqueous solutions of potassium, 1 ~
3 parts of disproportionated rosin acid potassium, 0.2 ~ 0.5 part of potassium phosphate, 0.5 ~ 0.8 part of potassium chloride, 0.04 ~ 0.08 part of EDTA Fe salt, 0.3 ~ 0.5
Part rongalite, 200 ~ 300 parts of deionized waters, 80 ~ 100 parts of mixtures, are passed through nitrogen protection, stir in 15 ~ 20 DEG C
1 ~ 3h is mixed, mixture a must be stirred；
(2) take stirring mixture a 100 ~ 200:0.2 in mass ratio ~ 0.5 that tert-butyl hydroperoxide is added, it is mixed in 250rpm stirring
Conjunction 18 ~ for 24 hours, 0.4 ~ 0.8% azanol of stirring mixture a mass is added, 3 ~ 5h is stood, obtains standing liquid, takes and stands liquid by matter
Dehydrated alcohol is added than 2 ~ 5:8 ~ 10 to get thickening activating agent in amount.
Insect trapping agent: according to the mass fraction, take 2 ~ 4 parts of phenylmethyl acetates, 1 ~ 3 portion of cinnamic acid, 1 ~ 3 portion of caryophyllus oil, 5 ~
The mixing of 10 parts of honey to get.
A kind of preparation method of environmental protection mythimna separata offset plate, includes the following steps:
S1. according to the mass fraction, 6 ~ 10 parts of viscose glue lotion matrixes, 80 ~ 100 parts of distilled water, 0.1 ~ 0.3 part of sodium bicarbonate are taken, is stirred
20 ~ 30min of mixing is mixed, mixture is obtained, is warming up to 75 ~ 80 DEG C, the ammonium persulfate of mixture quality 1 ~ 3% is added, it is warming up to 80 ~
The thickening of 85 DEG C of 30 ~ 40min of heat preservation, the viscose glue lotion matrix and mixture quality 30 ~ 40% that instill mixture quality 10 ~ 20% are living
Property agent, control 1 ~ 3h of time for adding and in 80 ~ 85 DEG C of 2 ~ 4h of heat preservation be cooled to 70 ~ 75 DEG C, obtain cooled material；
S2. it takes cooled material 100 ~ 150:1 in mass ratio ~ 3 that tert-butyl hydroperoxide is added, is stirred 50 ~ 60min, is cooled to
Room temperature adjusts pH to 7 ~ 7.2 with ammonium hydroxide, obtains mythimna separata rubber base, takes mythimna separata rubber base 50 ~ 80:4 in mass ratio ~ 9 that insect is added
Trapping bait mixing, obtains environmentally friendly insect sticker, takes environmentally friendly insect sticker by 2 ~ 5g/cm2Applying amount be applied on yellow plate it is viscous to get environmental protection
Shellac base.
Viscose glue lotion matrix: taking nonylphenol polyoxyethylene ether sulfonic acid ammonium salt 1:20 in mass ratio that distilled water is added, and stirring is mixed
20min is closed, emulsifier is obtained, according to the mass fraction, takes 3 parts of Isooctyl acrylate monomers, 1 part of butyl acrylate, 2 parts of acrylic acid hydroxyl second
Ester, 5 parts of methyl methacrylates, 8 parts of methacrylic acids, are warming up to 30 DEG C and are stirred 30min, obtain stirring mixture, then plus
The hexadecanol for entering to be stirred amount of substance 0.5%, obtains mixture, and mixture 3:50 in mass ratio is taken to be added dropwise in emulsifier, control
Time for adding 40min, is stirred 30min, obtains viscose glue lotion matrix.
Viscosify activating agent:
(1) dibutyl itaconate, isoprene, 4-vinylpridine 70:15:2 in mass ratio is taken to mix, it is mixed in 400rpm stirring
Close 30min, obtain mixture, according to the mass fraction, take mass fraction be 10% oleic acid aqueous solutions of potassium, 1 part of disproportionated rosin acid potassium,
0.2 part of potassium phosphate, 0.5 part of potassium chloride, 0.04 portion of EDTA Fe salt, 0.3 part of rongalite, 200 parts of deionized waters, 80
Part mixture, is passed through nitrogen protection, is stirred 1h in 15 DEG C, must stir mixture a；
(2) it takes stirring mixture a 100:0.2 in mass ratio that tert-butyl hydroperoxide is added, is stirred 18h in 250rpm, then
0.4% azanol of stirring mixture a mass is added, stands 3h, obtains standing liquid, takes and stands the anhydrous second of liquid 2:8 in mass ratio addition
Alcohol is to get thickening activating agent.
Insect trapping agent: according to the mass fraction, take 2 parts of phenylmethyl acetates, 1 portion of cinnamic acid, 1 portion of caryophyllus oil, 5 parts of honey mixed
Close to get.
A kind of preparation method of environmental protection mythimna separata offset plate, includes the following steps:
S1. according to the mass fraction, 6 parts of viscose glue lotion matrixes, 80 parts of distilled water, 0.1 part of sodium bicarbonate are taken, is stirred
20min obtains mixture, is warming up to 75 DEG C, and the ammonium persulfate of mixture quality 1% is added, is warming up to 80 DEG C of heat preservation 30min, instills
The viscose glue lotion matrix of mixture quality 10% and the thickening activating agent of mixture quality 30% control time for adding 1h, in 80 DEG C
2h is kept the temperature, 70 DEG C is cooled to, obtains cooled material；
S2. it takes cooled material 100:1 in mass ratio that tert-butyl hydroperoxide is added, is stirred 50min, is cooled to room temperature, use ammonia
Water adjusts pH to 7, obtains mythimna separata rubber base, takes mythimna separata rubber base 50:4 in mass ratio that insect trapping agent mixing is added, and obtains environmentally friendly viscous
Shellac takes environmentally friendly insect sticker by 2g/cm2Applying amount be applied on yellow plate to get environmentally friendly mythimna separata offset plate.
Viscose glue lotion matrix: taking nonylphenol polyoxyethylene ether sulfonic acid ammonium salt 3:25 in mass ratio that distilled water is added, and stirring is mixed
30min is closed, emulsifier is obtained, according to the mass fraction, takes 7 parts of Isooctyl acrylate monomers, 3 parts of butyl acrylates, 5 parts of acrylic acid hydroxyl second
Ester, 8 parts of methyl methacrylates, 10 parts of methacrylic acids, are warming up to 40 DEG C and are stirred 50min, obtain stirring mixture, then plus
The hexadecanol for entering to be stirred amount of substance 1.5%, obtains mixture, and mixture 5:70 in mass ratio is taken to be added dropwise in emulsifier, control
Time for adding 60min, is stirred 50min, obtains viscose glue lotion matrix.
Viscosify activating agent:
(1) dibutyl itaconate, isoprene, 4-vinylpridine 80:20:5 in mass ratio is taken to mix, it is mixed in 400rpm stirring
Close 40min, obtain mixture, according to the mass fraction, take mass fraction be 10% oleic acid aqueous solutions of potassium, 3 parts of disproportionated rosin acid potassium,
0.5 part of potassium phosphate, 0.8 part of potassium chloride, 0.08 portion of EDTA Fe salt, 0.5 part of rongalite, 300 parts of deionized waters,
100 parts of mixtures, are passed through nitrogen protection, are stirred 3h in 20 DEG C, must stir mixture a；
(2) it takes stirring mixture a 200:0.5 in mass ratio that tert-butyl hydroperoxide is added, is stirred for 24 hours in 250rpm, then
0.8% azanol of stirring mixture a mass is added, stands 5h, obtains standing liquid, takes standing liquid 5:10 to be in mass ratio added anhydrous
Ethyl alcohol is to get thickening activating agent.
Insect trapping agent: according to the mass fraction, 4 parts of phenylmethyl acetates, 3 portions of cinnamic acids, 3 portions of caryophyllus oils, 10 parts of honey are taken
Mixing to get.
A kind of preparation method of environmental protection mythimna separata offset plate, includes the following steps:
S1. according to the mass fraction, 10 parts of viscose glue lotion matrixes, 100 parts of distilled water, 0.3 part of sodium bicarbonate are taken, is stirred
30min obtains mixture, is warming up to 80 DEG C, and the ammonium persulfate of mixture quality 3% is added, is warming up to 85 DEG C of heat preservation 40min, instills
The viscose glue lotion matrix of mixture quality 20% and the thickening activating agent of mixture quality 40% control time for adding 3h, in 85 DEG C
4h is kept the temperature, 75 DEG C is cooled to, obtains cooled material；
S2. it takes cooled material 150:3 in mass ratio that tert-butyl hydroperoxide is added, is stirred 60min, is cooled to room temperature, use ammonia
Water adjusts pH to 7.2, obtains mythimna separata rubber base, takes mythimna separata rubber base 80:9 in mass ratio that insect trapping agent mixing is added, obtains environmentally friendly
Insect sticker takes environmentally friendly insect sticker by 5g/cm2Applying amount be applied on yellow plate to get environmentally friendly mythimna separata offset plate.
Viscose glue lotion matrix: taking nonylphenol polyoxyethylene ether sulfonic acid ammonium salt 2:23 in mass ratio that distilled water is added, and stirring is mixed
25min is closed, emulsifier is obtained, according to the mass fraction, takes 5 parts of Isooctyl acrylate monomers, 2 parts of butyl acrylates, 3 parts of acrylic acid hydroxyl second
Ester, 7 parts of methyl methacrylates, 9 parts of methacrylic acids, are warming up to 35 DEG C and are stirred 40min, obtain stirring mixture, then plus
The hexadecanol for entering to be stirred amount of substance 1%, obtains mixture, and mixture 4:55 in mass ratio is taken to be added dropwise in emulsifier, control drop
45min between added-time, is stirred 35min, obtains viscose glue lotion matrix.
Viscosify activating agent:
(1) dibutyl itaconate, isoprene, 4-vinylpridine 75:17:3 in mass ratio is taken to mix, it is mixed in 400rpm stirring
Close 35min, obtain mixture, according to the mass fraction, take mass fraction be 10% oleic acid aqueous solutions of potassium, 2 parts of disproportionated rosin acid potassium,
0.3 part of potassium phosphate, 0.7 part of potassium chloride, 0.06 portion of EDTA Fe salt, 0.4 part of rongalite, 250 parts of deionized waters, 90
Part mixture, is passed through nitrogen protection, is stirred 2h in 18 DEG C, must stir mixture a；
(2) it takes stirring mixture a 150:0.3 in mass ratio that tert-butyl hydroperoxide is added, is stirred 20h in 250rpm, then
0.6% azanol of stirring mixture a mass is added, stands 4h, obtains standing liquid, takes and stands the anhydrous second of liquid 3:9 in mass ratio addition
Alcohol is to get thickening activating agent.
Insect trapping agent: according to the mass fraction, take 3 parts of phenylmethyl acetates, 2 portions of cinnamic acids, 2 portions of caryophyllus oils, 7 parts of honey mixed
Close to get.
A kind of preparation method of environmental protection mythimna separata offset plate, includes the following steps:
S1. according to the mass fraction, 8 parts of viscose glue lotion matrixes, 90 parts of distilled water, 0.2 part of sodium bicarbonate are taken, is stirred
25min obtains mixture, is warming up to 77 DEG C, and the ammonium persulfate of mixture quality 2% is added, is warming up to 82 DEG C of heat preservation 35min, instills
The viscose glue lotion matrix of mixture quality 15% and the thickening activating agent of mixture quality 35% control time for adding 2h, in 83 DEG C
3h is kept the temperature, 72 DEG C is cooled to, obtains cooled material；
S2. it takes cooled material 130:2 in mass ratio that tert-butyl hydroperoxide is added, is stirred 55min, is cooled to room temperature, use ammonia
Water adjusts pH to 7.1, obtains mythimna separata rubber base, takes mythimna separata rubber base 55:6 in mass ratio that insect trapping agent mixing is added, obtains environmentally friendly
Insect sticker takes environmentally friendly insect sticker by 3g/cm2Applying amount be applied on yellow plate to get environmentally friendly mythimna separata offset plate.
Comparative example 1: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking viscose glue lotion matrix.
Comparative example 2: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking thickening activating agent.
Comparative example 3: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking insect trapping agent.
Comparative example 4: the environmentally friendly mythimna separata offset plate of Huai'an company production.
Above-described embodiment and the environmentally friendly mythimna separata offset plate that comparative example produces are detected, tack: according to GB/T 4852-
2002 rolling ball methods are tested using CZY-G type tack tester.It holds viscosity: insect sticker being melted at 120 DEG C, roller coating is in yellow
On plastic plate, 2 mm of coating layer thickness is put into 35 DEG C of non-yellowing test machines, imitates the irradiation of sunlight UV lamp with 200 W, test is viscous
The property retention time.Obtain that the results are shown in Table 1.
Table 1:
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 |
| Tack (mPas) | 80756 | 81898 | 79842 | 65354 | 66553 | 67895 | 65213 |
| Hold sticky (day) | 6 | 8 | 7 | 3 | 4 | 5 | 2 |
| Smell | It has no irritating odor | It has no irritating odor | It has no irritating odor | It has no irritating odor | It has no irritating odor | It has no irritating odor | Irritant smell |
In summary, environmentally friendly mythimna separata offset plate effect of the invention is more preferable, is worth of widely use.
Claims (7)
1. a kind of environmental protection mythimna separata offset plate, which is characterized in that including viscose glue lotion matrix, thickening activating agent, insect trapping agent；
The preparation method of the viscose glue lotion matrix, includes the following steps:
It takes nonylphenol polyoxyethylene ether sulfonic acid ammonium salt 1 ~ 3:20 in mass ratio ~ 25 that distilled water is added to be stirred, obtains emulsifier, press
Mass fraction meter takes 3 ~ 7 parts of Isooctyl acrylate monomers, 1 ~ 3 part of butyl acrylate, 2 ~ 5 parts of hydroxy-ethyl acrylates, 5 ~ 8 parts of methyl-props
E pioic acid methyl ester, 8 ~ 10 parts of methacrylic acids are stirred, and are obtained stirring mixture, are added and be stirred amount of substance 0.5 ~ 1.5%
Hexadecanol obtains mixture, and mixture 3 ~ 5:50 ~ 70 in mass ratio is taken to be added dropwise in emulsifier, controls 40 ~ 60min of time for adding,
It is stirred 30 ~ 50min, obtains viscose glue lotion matrix.
2. environmental protection mythimna separata offset plate according to claim 1, which is characterized in that the stirring mixture is stirred condition
Are as follows: it is warming up to 30 ~ 40 DEG C and is stirred 30 ~ 50min.
3. environmental protection mythimna separata offset plate according to claim 1, which is characterized in that the preparation method of the thickening activating agent, packet
Include following steps:
(1) dibutyl itaconate, isoprene, 4-vinylpridine 70 ~ 80:15 in mass ratio ~ 20:2 ~ 5 is taken to mix, in
400rpm is stirred, and obtains mixture, according to the mass fraction, takes the oleic acid aqueous solutions of potassium, 1 ~ 3 part of disproportionation that mass fraction is 10%
Potassium rosinate, 0.2 ~ 0.5 part of potassium phosphate, 0.5 ~ 0.8 part of potassium chloride, 0.04 ~ 0.08 portion of EDTA Fe salt, 0.3 ~ 0.5 part of formaldehyde
Sodium bisulphite, 200 ~ 300 parts of deionized waters, 80 ~ 100 parts of mixtures, are passed through nitrogen protection, are stirred, must be stirred
Object a；
(2) take stirring mixture a 100 ~ 200:0.2 in mass ratio ~ 0.5 that tert-butyl hydroperoxide is added, it is mixed in 250rpm stirring
Close, add stirring mixture a mass 0.4 ~ 0.8% azanol, stand, obtain standing liquid, take stand liquid 2 ~ 5:8 in mass ratio ~
10 are added dehydrated alcohol to get thickening activating agent.
4. environmental protection mythimna separata offset plate according to claim 3, which is characterized in that stirring mixture a's stirs in the step (1)
Mix mixing condition are as follows: be stirred 1 ~ 3h in 15 ~ 20 DEG C.
5. environmental protection mythimna separata offset plate according to claim 1, which is characterized in that the insect trapping agent: according to the mass fraction,
Take 2 ~ 4 parts of phenylmethyl acetates, 1 ~ 3 portion of cinnamic acid, 1 ~ 3 portion of caryophyllus oil, the mixing of 5 ~ 10 parts of honey to get.
6. a kind of preparation method of the environmentally friendly mythimna separata offset plate as described in claim 1 ~ 5 any one, which is characterized in that the preparation
Method includes the following steps:
S1. according to the mass fraction, 6 ~ 10 parts of viscose glue lotion matrixes, 80 ~ 100 parts of distilled water, 0.1 ~ 0.3 part of sodium bicarbonate are taken, is stirred
20 ~ 30min of mixing is mixed, mixture is obtained, is warming up to 75 ~ 80 DEG C, the ammonium persulfate of mixture quality 1 ~ 3% is added, it is warming up to 80 ~
The thickening of 85 DEG C of 30 ~ 40min of heat preservation, the viscose glue lotion matrix and mixture quality 30 ~ 40% that instill mixture quality 10 ~ 20% are living
Property agent, control 1 ~ 3h of time for adding and in 80 ~ 85 DEG C of 2 ~ 4h of heat preservation be cooled to 70 ~ 75 DEG C, obtain cooled material；
S2. it takes cooled material 100 ~ 150:1 in mass ratio ~ 3 that tert-butyl hydroperoxide is added, is stirred 50 ~ 60min, is cooled to
Room temperature adjusts pH to 7 ~ 7.2 with ammonium hydroxide, obtains mythimna separata rubber base, takes mythimna separata rubber base 50 ~ 80:4 in mass ratio ~ 9 that insect is added
Trapping bait mixing, obtains environmentally friendly insect sticker, environmentally friendly insect sticker is taken to be applied on yellow plate to get environmentally friendly mythimna separata offset plate.
7. the preparation method of environmental protection mythimna separata offset plate according to claim 6, which is characterized in that environmental protection is viscous in the step S2
The applying amount of shellac are as follows: 2 ~ 5g/cm2。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101044850A (en) * | 2007-04-30 | 2007-10-03 | 厦门大学 | Insects adherbing glue used specially for tea-tree garden, and its preparing method |
| CN102712835B (en) * | 2010-11-29 | 2014-10-15 | 中国医学科学院药用植物研究所 | Biomimetic adhesive and preparation method and application thereof |
| CN104497201A (en) * | 2014-12-02 | 2015-04-08 | 华南理工大学 | Rosin derivative/polyacrylate composite miniemulsion pressure-sensitive adhesive and preparation method thereof |
| CN106359337A (en) * | 2016-10-17 | 2017-02-01 | 广州瑞丰生物科技有限公司 | Novel paper insect sticking plate |
-
2018
- 2018-08-31 CN CN201811014969.9A patent/CN109181589A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101044850A (en) * | 2007-04-30 | 2007-10-03 | 厦门大学 | Insects adherbing glue used specially for tea-tree garden, and its preparing method |
| CN102712835B (en) * | 2010-11-29 | 2014-10-15 | 中国医学科学院药用植物研究所 | Biomimetic adhesive and preparation method and application thereof |
| CN104497201A (en) * | 2014-12-02 | 2015-04-08 | 华南理工大学 | Rosin derivative/polyacrylate composite miniemulsion pressure-sensitive adhesive and preparation method thereof |
| CN106359337A (en) * | 2016-10-17 | 2017-02-01 | 广州瑞丰生物科技有限公司 | Novel paper insect sticking plate |
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