CN106359337A - Novel paper insect sticking plate - Google Patents
Novel paper insect sticking plate Download PDFInfo
- Publication number
- CN106359337A CN106359337A CN201610899229.2A CN201610899229A CN106359337A CN 106359337 A CN106359337 A CN 106359337A CN 201610899229 A CN201610899229 A CN 201610899229A CN 106359337 A CN106359337 A CN 106359337A
- Authority
- CN
- China
- Prior art keywords
- insect
- percent
- agent
- paper
- sticking plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/14—Catching by adhesive surfaces
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Insects & Arthropods (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a novel paper insect sticking plate which comprises degradable and environment-friendly copper paper, and insect sticking glue and insect sex pheromone which are adhered to the copper paper. The novel paper insect sticking plate is characterized in that the insect sticking glue comprises the following components in percentage by weight: 3 to 4 percent of an acrylic acid monomer, 30 to 52 percent of an acrylic acid soft monomer, 2 percent of aids, 2 percent of a modifier, 0.2 to 0.4 percent of a non-ionic emulsifier, 0.2 to 1 percent of an anionic emulsifier, 0.1 to 0.5 percent of an initiator, 0.2 to 0.4 percent of a preservative, 0.05 to 0.08 percent of a defoaming agent and 37.62 to 57.25 percent of deionized water. The novel paper insect sticking plate has the beneficial effects that the degradable copper paper is provided, so that secondary environmental pollution is avoided; the novel insect sticking glue has the characteristics of no toxin, and high and durable stickiness; meanwhile, the insect sticking glue is combined with the insect sex pheromone, so that the novel paper insect sticking plate also can be used for preventing and controlling various pests.
Description
Technical field
The invention belongs to the technical field of chemical industry, specifically, it is to be related to a kind of novel paper insect-sticking plate.
Background technology
The Harmful Biohazard is one of natural hazard the most serious, each state all seek new green mode control worm way
Footpath, wherein physics trapping be one of green prevention and control important means, according to and using the phototaxis of insect, the color that becomes, chemotaxiss etc.
Habit principle, forms and includes the trapping disinsection methods such as light trap, colour table trapping, sound wave trapping.Ministry of Agriculture's proposition in 2006 is green
Color plant protection theory, and using colour table insect-killing trapping one of as main promotion means, propulsion green prevention and control action in 2008,2010
Environment protective plant protecting project spread is implemented.Traditional insect-sticking plate is all made using pp polypropylene, is not belonging to degradable thing
Matter, moreover, these insect stickers there is typically further that antioxidant capacity is weak, easily aging, dry and cracked, permanent tack power is poor, effect is bad etc. lacks
Point.
Content of the invention
The problem existing for above-mentioned prior art, present invention aim at provide a kind of novel paper insect-sticking plate.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of novel paper insect-sticking plate, including the copper paper of Degradable environment protection, is bonded at insect sticker and insects information above copper paper
Element it is characterised in that: described insect sticker includes acrylic monomerss: 3%-4%, acrylic acid soft monomer: 30%- by weight percentage
52%, auxiliary agent: 2%, dressing agent: 2%, nonionic emulsifier: 0.2%-0.4%, anion emulsifier 0.2%-1%, initiator: 0.1%-
0.5%, preservative: 0.2%-0.4%, defoamer: 0.05%-0.08%, deionized water 37.62%-57.25%.
Further, described auxiliary agent is sodium bicarbonate；Dressing agent is n- dodecyl mereaptan；Preservative is triethylamine；Defoamer
For emulsified silicone oil；Initiator is azo-bis-iso-dimethyl.
The raw material of insect sticker of the present invention and the selection of proportioning, be all by repeatedly, the screening experiment of science determines.By
The insect sticker that it is made is nontoxic, and antioxygenic property is strong, and polypide contact bonding is good, and cohesive force is strong, can cling before the deadline
All creep through the insect of coating.As being combined with insect sex pheromone, it may also be used for the preventing and treating to many insects.
Insect sticker of the present invention is made of according to following steps:
(1) it is individually added into nonionic emulsifier and anion emulsifier is uniformly mixed to prepare compound emulsifying agent, standby；
(2) it is individually added into acrylic monomerss and acrylic acid soft monomer is uniformly mixed to prepare mix monomer agent, standby；
(3) it is individually added into initiator and a certain amount of deionized water is uniformly mixed to prepare initiator solution, standby
(4) deionized water is added in the beaker with agitator, add compound emulsifying agent, then stir, until abundant
Dissolving；
(5) add mix monomer agent, stir 30 minutes, until filling dissolving, be not significantly layered and there is no foam, be obtained single
Body pre-emulsion, standby；
(6) in four mouthfuls of reaction flasks equipped with thermometer, agitator, reflux condenser and feeder, treat that temperature rises to 75 DEG C
Afterwards, sequentially add about 1/10 ~ 1/8 monomer pre-emulsion, 1/4 initiator solution, auxiliary agent and dressing agent, react 30 points
Zhong Hou, when capacity of returns reduces, then carries out being added dropwise to remaining monomer pre-emulsion and initiator solution, controls temperature to exist simultaneously
80～82 DEG C, it is incubated 2 hours after dripping off, is then cooled to 50 DEG C；
(7) add preservative adjust ph value be 7～8, last filtering and discharging insect sticker.
The invention has the beneficial effects as follows: the present invention is with low cost, environmental protection, has the copper paper of degradable, does not result in
Secondary environmental pollution；New insect sticker has nontoxic, non-stimulated abnormal smells from the patient, non-corrosiveness, aging resistance, the viscosity spy such as lasting by force
Point；Insect sticker is combined with insect sex pheromone simultaneously, it may also be used for the preventing and treating to many insects, and this invention is practical, is suitable for
It is widely popularized use.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited in
This.
Embodiment 1
Insect sticker is by weight percentage: acrylic monomerss: 3%, acrylic acid soft monomer: and 35%, sodium bicarbonate: 2%, positive 12 sulfur
Alcohol: 2%, nonionic emulsifier: 0.2%, anion emulsifier 0.2%, azo-bis-iso-dimethyl: 0.2%, triethylamine: 0.3%,
Emulsified silicone oil: 0.05%, deionized water 41.05%.
This insect sticker is made of according to following steps:
(1) it is individually added into nonionic emulsifier and anion emulsifier is uniformly mixed to prepare compound emulsifying agent, standby；
(2) it is individually added into acrylic monomerss and acrylic acid soft monomer is uniformly mixed to prepare mix monomer agent, standby；
(3) it is individually added into initiator and a certain amount of deionized water is uniformly mixed to prepare initiator solution, standby
(4) deionized water is added in the beaker with agitator, add compound emulsifying agent, then stir, until abundant
Dissolving；
(5) add mix monomer agent, stir 30 minutes, until filling dissolving, be not significantly layered and there is no foam, be obtained single
Body pre-emulsion, standby；
(6) in four mouthfuls of reaction flasks equipped with thermometer, agitator, reflux condenser and feeder, treat that temperature rises to 75 DEG C
Afterwards, about 1/8 monomer pre-emulsion, 1/4 initiator solution, auxiliary agent and dressing agent are sequentially added, after reacting 30 minutes,
When capacity of returns reduces, then carry out being added dropwise to remaining monomer pre-emulsion and initiator solution, control temperature at 82 DEG C simultaneously,
It is incubated 2 hours after dripping off, be then cooled to 50 DEG C；
(7) add preservative adjust ph value be 7, last filtering and discharging insect sticker.
Embodiment 2
Insect sticker is by weight percentage: acrylic monomerss: 3.5%, acrylic acid soft monomer: and 47.8%, sodium bicarbonate: 2%, positive ten
Two mercaptan: 2%, nonionic emulsifier: 0.4%, anion emulsifier 0.5%, azo-bis-iso-dimethyl: 0.42%, triethylamine:
0.32%, emulsified silicone oil: 0.06%, deionized water 50%.
This insect sticker is made of according to following steps:
(1) it is individually added into nonionic emulsifier and anion emulsifier is uniformly mixed to prepare compound emulsifying agent, standby；
(2) it is individually added into acrylic monomerss and acrylic acid soft monomer is uniformly mixed to prepare mix monomer agent, standby；
(3) it is individually added into initiator and a certain amount of deionized water is uniformly mixed to prepare initiator solution, standby
(4) deionized water is added in the beaker with agitator, add compound emulsifying agent, then stir, until abundant
Dissolving；
(5) add mix monomer agent, stir 30 minutes, until filling dissolving, be not significantly layered and there is no foam, be obtained single
Body pre-emulsion, standby；
(6) in four mouthfuls of reaction flasks equipped with thermometer, agitator, reflux condenser and feeder, treat that temperature rises to 75 DEG C
Afterwards, sequentially add about 1/10 monomer pre-emulsion, 1/4 initiator solution, auxiliary agent and dressing agent, react 30 minutes
Afterwards, when capacity of returns reduces, then carry out being added dropwise to remaining monomer pre-emulsion and initiator solution, control temperature 80 simultaneously
DEG C, it is incubated 2 hours after dripping off, be then cooled to 50 DEG C；
(7) add preservative adjust ph value be 8, last filtering and discharging insect sticker.
Make during this invention insect-sticking plate it is necessary first to first make art paper, the primary raw material of art paper be art base paper and
Coating, the coating for being coated with is that (also referred to as hargil, containing Kaolin, Pulvis Talci, Calcium Carbonate, titanium dioxide by the Chinese white of high-quality
Titanium etc.), adhesive (polyvinyl alcohol, casein, modified starch, synthetic latex etc.), and other adjuvants are (as polishing material, hardening
Agent, plasticiser, dispersant, wetting agent, opalizer, fluorescent whitening agent, toner etc.) form, uniform and thin by coating machine
Coating application on body paper, is then dried process, is rolled into drum on reel machine, be then sent through on supercalender by ground
Carry out press polish ornamenting, finally cut, select paper, packing, you can complete the making of art paper.After the completion of two-sided art paper covered
Film, smears insect sticker and insect sex pheromone after overlay film on art paper, then 2 art paper coated face bondings are become a piece of paper
Matter mythimna separata board finished product (can pull open during use and be used as 2 insect-sticking plates).
The present invention is with low cost, environmental protection, has the copper paper of degradable, does not result in secondary environmental pollution；New
Insect sticker have nontoxic, non-stimulated abnormal smells from the patient, non-corrosiveness, aging resistance, viscosity strong and persistently the features such as；Insect sticker and insecticide simultaneously
Sex pheromone combines, it may also be used for the preventing and treating to many insects, this invention is practical, is suitable for being widely popularized use.
It is best mode for carrying out the invention above, the simple change of those ordinary skill in the art and replacement are all these
Within the protection domain of invention.
Claims (3)
1. a kind of novel paper insect-sticking plate, including the copper paper of Degradable environment protection, is bonded at insect sticker and insects letter above copper paper
Breath element it is characterised in that: described insect sticker includes acrylic monomerss: 3%-4% by weight percentage, acrylic acid soft monomer:
30%-52%, auxiliary agent: 2%, dressing agent: 2%, nonionic emulsifier: 0.2%-0.4%, anion emulsifier 0.2%-1%, initiator:
0.1%-0.5%, preservative: 0.2%-0.4%, defoamer: 0.05%-0.08%, deionized water 37.62%-57.25%.
2. a kind of novel paper insect-sticking plate according to claim 1 is it is characterised in that described auxiliary agent is sodium bicarbonate；Repair
Decorations agent is n- dodecyl mereaptan；Preservative is triethylamine；Defoamer is emulsified silicone oil；Initiator is azo-bis-iso-dimethyl.
3. a kind of novel paper insect-sticking plate according to claim 1 is it is characterised in that described insect sticker is according to following step
Suddenly make:
(1) it is individually added into nonionic emulsifier and anion emulsifier is uniformly mixed to prepare compound emulsifying agent, standby；
(2) it is individually added into acrylic monomerss and acrylic acid soft monomer is uniformly mixed to prepare mix monomer agent, standby；
(3) it is individually added into initiator and a certain amount of deionized water is uniformly mixed to prepare initiator solution, standby
(4) deionized water is added in the beaker with agitator, add compound emulsifying agent, then stir, until abundant
Dissolving；
(5) add mix monomer agent, stir 30 minutes, until filling dissolving, be not significantly layered and there is no foam, prepared monomer
Pre-emulsion, standby；
(6) in four mouthfuls of reaction flasks equipped with thermometer, agitator, reflux condenser and feeder, treat that temperature rises to 75 DEG C
Afterwards, sequentially add about 1/10 ~ 1/8 monomer pre-emulsion, 1/4 initiator solution, auxiliary agent and dressing agent, react 30 points
Zhong Hou, when capacity of returns reduces, then carries out being added dropwise to remaining monomer pre-emulsion and initiator solution, controls temperature to exist simultaneously
80～82 DEG C, it is incubated 2 hours after dripping off, is then cooled to 50 DEG C；
(7) add preservative adjust ph value be 7～8, last filtering and discharging insect sticker.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610899229.2A CN106359337A (en) | 2016-10-17 | 2016-10-17 | Novel paper insect sticking plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610899229.2A CN106359337A (en) | 2016-10-17 | 2016-10-17 | Novel paper insect sticking plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106359337A true CN106359337A (en) | 2017-02-01 |
Family
ID=57896232
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610899229.2A Pending CN106359337A (en) | 2016-10-17 | 2016-10-17 | Novel paper insect sticking plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106359337A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181589A (en) * | 2018-08-31 | 2019-01-11 | 黄旭东 | A kind of environmental protection mythimna separata offset plate and preparation method thereof |
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| CN1718661A (en) * | 2005-08-04 | 2006-01-11 | 上海应用技术学院 | Modified urea formaldehyde binding agent and its preparation method |
| CN1736218A (en) * | 2005-05-13 | 2006-02-22 | 河北科技大学 | Application of high molecular polymer emulsion film in protection film for fruit growth |
| CN102070961A (en) * | 2010-11-29 | 2011-05-25 | 中国医学科学院药用植物研究所 | Method for reducing surface viscosity of bionic glue by using curing agents |
| CN102125052A (en) * | 2010-11-29 | 2011-07-20 | 中国医学科学院药用植物研究所 | Method for controlling plant diseases and insect pests by utilizing defoliant and bionic glue |
| US20140186286A1 (en) * | 2010-11-29 | 2014-07-03 | Foshan Sanshui Xianghai Adhesive Co., Ltd. | Biomimetic Adhesive and Preparation Method and Application Thereof |
| CN104961867A (en) * | 2015-06-25 | 2015-10-07 | 合肥聚合辐化技术有限公司 | Anti-stick mucilage resin and preparation method thereof |
| CN105255298A (en) * | 2015-10-17 | 2016-01-20 | 佛山市顺德区巴德富实业有限公司 | VAc/St/BA (vinyl acetate-styrene-butyl acrylate) stone paint emulsion and preparation method |
-
2016
- 2016-10-17 CN CN201610899229.2A patent/CN106359337A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1736218A (en) * | 2005-05-13 | 2006-02-22 | 河北科技大学 | Application of high molecular polymer emulsion film in protection film for fruit growth |
| CN1718661A (en) * | 2005-08-04 | 2006-01-11 | 上海应用技术学院 | Modified urea formaldehyde binding agent and its preparation method |
| CN102070961A (en) * | 2010-11-29 | 2011-05-25 | 中国医学科学院药用植物研究所 | Method for reducing surface viscosity of bionic glue by using curing agents |
| CN102125052A (en) * | 2010-11-29 | 2011-07-20 | 中国医学科学院药用植物研究所 | Method for controlling plant diseases and insect pests by utilizing defoliant and bionic glue |
| US20140186286A1 (en) * | 2010-11-29 | 2014-07-03 | Foshan Sanshui Xianghai Adhesive Co., Ltd. | Biomimetic Adhesive and Preparation Method and Application Thereof |
| CN104961867A (en) * | 2015-06-25 | 2015-10-07 | 合肥聚合辐化技术有限公司 | Anti-stick mucilage resin and preparation method thereof |
| CN105255298A (en) * | 2015-10-17 | 2016-01-20 | 佛山市顺德区巴德富实业有限公司 | VAc/St/BA (vinyl acetate-styrene-butyl acrylate) stone paint emulsion and preparation method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181589A (en) * | 2018-08-31 | 2019-01-11 | 黄旭东 | A kind of environmental protection mythimna separata offset plate and preparation method thereof |
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Application publication date: 20170201 |