CN109181332A - A kind of wear-resisting wood plastics composite new material and its processing method - Google Patents

A kind of wear-resisting wood plastics composite new material and its processing method Download PDF

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Publication number
CN109181332A
CN109181332A CN201810770138.8A CN201810770138A CN109181332A CN 109181332 A CN109181332 A CN 109181332A CN 201810770138 A CN201810770138 A CN 201810770138A CN 109181332 A CN109181332 A CN 109181332A
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Prior art keywords
parts
powder
wear
plastics composite
new material
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CN201810770138.8A
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Chinese (zh)
Inventor
汪漭
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Anhui Yu Jin Ecological Wood Materials Co Ltd
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Anhui Yu Jin Ecological Wood Materials Co Ltd
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Priority to CN201810770138.8A priority Critical patent/CN109181332A/en
Publication of CN109181332A publication Critical patent/CN109181332A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of wear-resisting wood plastics composite new materials, raw material including following parts by weight: 11 parts of waste and old polypropylene material, 11 parts of waste polyethylene material, 32 parts of mulberry tree wood powder, 12 parts of grapevine powder, 4 parts of chaff shell, 4 parts of steel-making slag powder, 14 parts of ceramic fibre, 12 parts of carboxymethyl cellulose, 12 parts of natural rubber, 11 parts of polyvinyl chloride resin, 2 parts of Lauxite, 5 parts of ethylene acrylic acid co polymer, 1.5 parts of Kiselgel A, 2.5 parts of antimony oxide, 3.5 parts of chitosan, 2 parts of talcum powder, 2 parts of bentonite, 2 parts of silver carbonate, 3.5 parts of calcium stearate, 1.5 parts of titanate coupling agent, 1.5 parts of sodium phosphite, 5 parts of polyethylene wax, 4 parts of phthalocyanine blue.Composite material reasonable utilization of the invention natural resources enhances wear-resisting property by the way that the raw materials such as steel-making slag powder, ceramic fibre, carboxymethyl cellulose, talcum powder, bentonite are added.

Description

A kind of wear-resisting wood plastics composite new material and its processing method
Technical field
The present invention relates to Wood-plastic material fields, and in particular to a kind of wear-resisting wood plastics composite new material and its processing method.
Background technique
Wood plastic composite (WPC) be by thermoplastic with wood-fibred or plant fiber are compound is prepared, the material The double grading of timber and plastics is had both, thermal expansion, water imbibition are smaller than timber, good stability of the dimension, and wear-resisting property is good, produce Product can be recycled.In order to further increase the market value of wood plastic composite, it is multiple how to provide a kind of wear-resisting wood moulding It closes new material and its processing method is an important research direction of wood moulding industry.
Summary of the invention
It is an object of the invention to: a kind of wear-resisting wood plastics composite new material and its processing method are provided.
To achieve the goals above, the invention provides the following technical scheme:
A kind of wear-resisting wood plastics composite new material, the raw material including following parts by weight:
10-15 parts of waste and old polypropylene material, 10-15 parts of waste polyethylene material, 30-40 parts of mulberry tree wood powder, grapevine powder 10-20 Part, 3-6 parts of chaff shell, 3-6 parts of steel-making slag powder, 12-18 parts of ceramic fibre, 10-16 parts of carboxymethyl cellulose, 10-15 parts of natural rubber, 10-15 parts of polyvinyl chloride resin, 1-3 parts of Lauxite, 4-7 parts of ethylene acrylic acid co polymer, 1-2 parts of Kiselgel A, antimony oxide 2- 3 parts, 3-4 parts of chitosan, 1-3 parts of talcum powder, 1-3 parts of bentonite, 1-3 parts of silver carbonate, 3-4 parts of calcium stearate, titanate esters coupling 1-2 parts of agent, 1-2 parts of sodium phosphite, 4-8 parts of polyethylene wax, 3-6 parts of phthalocyanine blue.
Preferably, a kind of wear-resisting wood plastics composite new material, the raw material including following parts by weight:
11 parts of waste and old polypropylene material, 11 parts of waste polyethylene material, 32 parts of mulberry tree wood powder, 12 parts of grapevine powder, 4 parts of chaff shell, 4 parts of steel-making slag powder, 14 parts of ceramic fibre, 12 parts of carboxymethyl cellulose, 12 parts of natural rubber, 11 parts of polyvinyl chloride resin, 2 parts of Lauxite, 5 parts of ethylene acrylic acid co polymer, 1.5 parts of Kiselgel A, 2.5 parts of antimony oxide, 3.5 parts of chitosan, 2 parts of talcum powder, swelling Native 2 parts, 2 parts of silver carbonate, 3.5 parts of calcium stearate, 1.5 parts of titanate coupling agent, 1.5 parts of sodium phosphite, 5 parts of polyethylene wax, phthalein Cyanines are 4 parts blue.
Preferably, a kind of wear-resisting wood plastics composite new material, the raw material including following parts by weight:
14 parts of waste and old polypropylene material, 14 parts of waste polyethylene material, 38 parts of mulberry tree wood powder, 18 parts of grapevine powder, 5 parts of chaff shell, 5 parts of steel-making slag powder, 17 parts of ceramic fibre, 15 parts of carboxymethyl cellulose, 14 parts of natural rubber, 14 parts of polyvinyl chloride resin, Lauxite 1.6 Part, 6 parts of ethylene acrylic acid co polymer, 1.8 parts of Kiselgel A, 2.8 parts of antimony oxide, 3.8 parts of chitosan, 1.8 parts of talcum powder, 1.5 parts of bentonite, 1.5 parts of silver carbonate, 3.5 parts of calcium stearate, 1.5 parts of titanate coupling agent, 1.5 parts of sodium phosphite, polyethylene 7 parts of wax, 5 parts of phthalocyanine blue.
Preferably, a kind of processing method of wear-resisting wood plastics composite new material, the specific steps are as follows:
(1) raw material is put into mixing machine by weight, under 90-110 DEG C, 120-180rpm revolving speed, 30-40 points of mixing Clock;
(2) mixture obtained by step (1) is added in extruder, extrusion temperature is 170-200 DEG C, screw speed 30- 50rpm is squeezed out, is granulated;
(3) particle obtained by step (2) is formed through mold pressing mold, temperature is 180-200 DEG C, pressure 10-15-MPa, cold But up to wear-resisting wood plastics composite new material.
The beneficial effects of the present invention are:
Composite material reasonable utilization of the invention natural resources, reduces economic cost, meanwhile, the material being process Expect that mechanical performance and processing performance are all relatively good, meanwhile, by the way that steel-making slag powder, ceramic fibre, carboxymethyl cellulose, talcum is added The raw materials such as powder, bentonite enhance the wear-resisting property of wood plastic composite.
Specific embodiment
Embodiment 1
A kind of wear-resisting wood plastics composite new material, the raw material including following parts by weight:
10 parts of waste and old polypropylene material, 10 parts of waste polyethylene material, 30 parts of mulberry tree wood powder, 10 parts of grapevine powder, 3 parts of chaff shell, 3 parts of steel-making slag powder, 12 parts of ceramic fibre, 10 parts of carboxymethyl cellulose, 10 parts of natural rubber, 10 parts of polyvinyl chloride resin, 1 part of Lauxite, 4 parts of ethylene acrylic acid co polymer, 1 part of Kiselgel A, 2 parts of antimony oxide, 3 parts of chitosan, 1 part of talcum powder, 1 part of bentonite, 1 part of silver carbonate, 3 parts of calcium stearate, 1 part of titanate coupling agent, 1 part of sodium phosphite, 4 parts of polyethylene wax, 3 parts of phthalocyanine blue.
The processing method of above-mentioned wear-resisting wood plastics composite new material, the specific steps are as follows:
(1) raw material is put into mixing machine by weight, under 90-110 DEG C, 120-180rpm revolving speed, 30-40 points of mixing Clock;
(2) mixture obtained by step (1) is added in extruder, extrusion temperature is 170-200 DEG C, screw speed 30- 50rpm is squeezed out, is granulated;
(3) particle obtained by step (2) is formed through mold pressing mold, temperature is 180-200 DEG C, pressure 10-15-MPa, cold But up to wear-resisting wood plastics composite new material.
Embodiment 2
A kind of wear-resisting wood plastics composite new material, the raw material including following parts by weight:
11 parts of waste and old polypropylene material, 11 parts of waste polyethylene material, 32 parts of mulberry tree wood powder, 12 parts of grapevine powder, 4 parts of chaff shell, 4 parts of steel-making slag powder, 14 parts of ceramic fibre, 12 parts of carboxymethyl cellulose, 12 parts of natural rubber, 11 parts of polyvinyl chloride resin, 2 parts of Lauxite, 5 parts of ethylene acrylic acid co polymer, 1.5 parts of Kiselgel A, 2.5 parts of antimony oxide, 3.5 parts of chitosan, 2 parts of talcum powder, swelling Native 2 parts, 2 parts of silver carbonate, 3.5 parts of calcium stearate, 1.5 parts of titanate coupling agent, 1.5 parts of sodium phosphite, 5 parts of polyethylene wax, phthalein Cyanines are 4 parts blue.
The processing method of above-mentioned wear-resisting wood plastics composite new material, the specific steps are as follows:
(1) raw material is put into mixing machine by weight, under 90-110 DEG C, 120-180rpm revolving speed, 30-40 points of mixing Clock;
(2) mixture obtained by step (1) is added in extruder, extrusion temperature is 170-200 DEG C, screw speed 30- 50rpm is squeezed out, is granulated;
(3) particle obtained by step (2) is formed through mold pressing mold, temperature is 180-200 DEG C, pressure 10-15-MPa, cold But up to wear-resisting wood plastics composite new material.
Embodiment 3
A kind of wear-resisting wood plastics composite new material, the raw material including following parts by weight:
14 parts of waste and old polypropylene material, 14 parts of waste polyethylene material, 38 parts of mulberry tree wood powder, 18 parts of grapevine powder, 5 parts of chaff shell, 5 parts of steel-making slag powder, 17 parts of ceramic fibre, 15 parts of carboxymethyl cellulose, 14 parts of natural rubber, 14 parts of polyvinyl chloride resin, Lauxite 1.6 Part, 6 parts of ethylene acrylic acid co polymer, 1.8 parts of Kiselgel A, 2.8 parts of antimony oxide, 3.8 parts of chitosan, 1.8 parts of talcum powder, 1.5 parts of bentonite, 1.5 parts of silver carbonate, 3.5 parts of calcium stearate, 1.5 parts of titanate coupling agent, 1.5 parts of sodium phosphite, polyethylene 7 parts of wax, 5 parts of phthalocyanine blue.
The processing method of above-mentioned wear-resisting wood plastics composite new material, the specific steps are as follows:
(1) raw material is put into mixing machine by weight, under 90-110 DEG C, 120-180rpm revolving speed, 30-40 points of mixing Clock;
(2) mixture obtained by step (1) is added in extruder, extrusion temperature is 170-200 DEG C, screw speed 30- 50rpm is squeezed out, is granulated;
(3) particle obtained by step (2) is formed through mold pressing mold, temperature is 180-200 DEG C, pressure 10-15-MPa, cold But up to wear-resisting wood plastics composite new material.
Embodiment 4
A kind of wear-resisting wood plastics composite new material, the raw material including following parts by weight:
15 parts of waste and old polypropylene material, 15 parts of waste polyethylene material, 40 parts of mulberry tree wood powder, 20 parts of grapevine powder, 6 parts of chaff shell, 6 parts of steel-making slag powder, 18 parts of ceramic fibre, 16 parts of carboxymethyl cellulose, 15 parts of natural rubber, 15 parts of polyvinyl chloride resin, 3 parts of Lauxite, 7 parts of ethylene acrylic acid co polymer, 2 parts of Kiselgel A, 3 parts of antimony oxide, 4 parts of chitosan, 3 parts of talcum powder, 3 parts of bentonite, 3 parts of silver carbonate, 4 parts of calcium stearate, 2 parts of titanate coupling agent, 2 parts of sodium phosphite, 8 parts of polyethylene wax, 6 parts of phthalocyanine blue.
The processing method of above-mentioned wear-resisting wood plastics composite new material, the specific steps are as follows:
(1) raw material is put into mixing machine by weight, under 90-110 DEG C, 120-180rpm revolving speed, 30-40 points of mixing Clock;
(2) mixture obtained by step (1) is added in extruder, extrusion temperature is 170-200 DEG C, screw speed 30- 50rpm is squeezed out, is granulated;
(3) particle obtained by step (2) is formed through mold pressing mold, temperature is 180-200 DEG C, pressure 10-15-MPa, cold But up to wear-resisting wood plastics composite new material.

Claims (8)

1. a kind of wear-resisting wood plastics composite new material, it is characterised in that: the raw material including following parts by weight:
10-15 parts of waste and old polypropylene material, 10-15 parts of waste polyethylene material, 30-40 parts of mulberry tree wood powder, 10-20 parts of grapevine powder, 3-6 parts of chaff shell, 3-6 parts of steel-making slag powder, 12-18 parts of ceramic fibre, 10-16 parts of carboxymethyl cellulose, 10-15 parts of natural rubber, PVC 10-15 parts of resin, 1-3 parts of Lauxite, 4-7 parts of ethylene acrylic acid co polymer, 1-2 parts of Kiselgel A, antimony oxide 2-3 Part, 3-4 parts of chitosan, 1-3 parts of talcum powder, 1-3 parts of bentonite, 1-3 parts of silver carbonate, 3-4 parts of calcium stearate, titanate coupling agent 1-2 parts, 1-2 parts of sodium phosphite, 4-8 parts of polyethylene wax.
2. a kind of wear-resisting wood plastics composite new material according to claim 1, it is characterised in that: further include 3-6 parts of phthalocyanine blue.
3. a kind of wear-resisting wood plastics composite new material according to claim 2, it is characterised in that: the original including following parts by weight Material:
11 parts of waste and old polypropylene material, 11 parts of waste polyethylene material, 32 parts of mulberry tree wood powder, 12 parts of grapevine powder, 4 parts of chaff shell, steel slag 4 parts of powder, 14 parts of ceramic fibre, 12 parts of carboxymethyl cellulose, 12 parts of natural rubber, 11 parts of polyvinyl chloride resin, 2 parts of Lauxite, ethylene 5 parts of acrylic copolymer, 1.5 parts of Kiselgel A, 2.5 parts of antimony oxide, 3.5 parts of chitosan, 2 parts of talcum powder, bentonite 2 Part, 2 parts of silver carbonate, 3.5 parts of calcium stearate, 1.5 parts of titanate coupling agent, 1.5 parts of sodium phosphite, 5 parts of polyethylene wax, phthalocyanine blue 4 parts.
4. a kind of wear-resisting wood plastics composite new material according to claim 2, it is characterised in that: the original including following parts by weight Material:
14 parts of waste and old polypropylene material, 14 parts of waste polyethylene material, 38 parts of mulberry tree wood powder, 18 parts of grapevine powder, 5 parts of chaff shell, steel slag 5 parts of powder, 17 parts of ceramic fibre, 15 parts of carboxymethyl cellulose, 14 parts of natural rubber, 14 parts of polyvinyl chloride resin, 1.6 parts of Lauxite, second 6 parts of alkene acrylic copolymer, 1.8 parts of Kiselgel A, 2.8 parts of antimony oxide, 3.8 parts of chitosan, 1.8 parts of talcum powder, swelling Native 1.5 parts, 1.5 parts of silver carbonate, 3.5 parts of calcium stearate, 1.5 parts of titanate coupling agent, 1.5 parts of sodium phosphite, polyethylene wax 7 Part, 5 parts of phthalocyanine blue.
5. a kind of processing method of wear-resisting wood plastics composite new material, it is characterised in that: specific step is as follows:
(1) raw material is put into mixing machine by weight, under 90-110 DEG C, 120-180rpm revolving speed, is mixed 30-40 minutes;
(2) mixture obtained by step (1) is added in extruder, extrusion temperature is 170-200 DEG C, screw speed 30- 50rpm is squeezed out, is granulated;
(3) particle obtained by step (2) is formed through mold pressing mold, temperature is 180-200 DEG C, pressure 10-15MPa, and cooling is Obtain wear-resisting wood plastics composite new material.
6. a kind of processing method of wear-resisting wood plastics composite new material according to claim 5, it is characterised in that: step (1) Detailed process is as follows:
Raw material is put into mixing machine by weight, under 100 DEG C, 150rpm revolving speed, is mixed 35 minutes.
7. a kind of processing method of wear-resisting wood plastics composite new material according to claim 5, it is characterised in that: step (2) Detailed process is as follows:
Mixture obtained by step (1) is added in extruder, extrusion temperature is 190 DEG C, and screw speed 40rpm is squeezed out, made Grain.
8. a kind of processing method of wear-resisting wood plastics composite new material according to claim 5, it is characterised in that: step (3) Detailed process is as follows:
Particle obtained by step (2) is formed through mold pressing mold, temperature is 190 DEG C, pressure 12MPa, cooling up to wear-resisting wood moulding Composite material.
CN201810770138.8A 2018-07-13 2018-07-13 A kind of wear-resisting wood plastics composite new material and its processing method Pending CN109181332A (en)

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CN201810770138.8A CN109181332A (en) 2018-07-13 2018-07-13 A kind of wear-resisting wood plastics composite new material and its processing method

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Application Number Priority Date Filing Date Title
CN201810770138.8A CN109181332A (en) 2018-07-13 2018-07-13 A kind of wear-resisting wood plastics composite new material and its processing method

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CN109181332A true CN109181332A (en) 2019-01-11

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157207A (en) * 2019-05-14 2019-08-23 浙江合塑控股有限公司 A kind of wear-resistant macromolecule composite wood-plastic material against corrosion and its manufacturing method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876064A (en) * 2012-09-20 2013-01-16 吴江市天源塑胶有限公司 Preparation method of wear-resistant wood/plastic material
CN105906908A (en) * 2016-05-06 2016-08-31 王泽陆 Degradable flame-retardant wood-plastic composite material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876064A (en) * 2012-09-20 2013-01-16 吴江市天源塑胶有限公司 Preparation method of wear-resistant wood/plastic material
CN105906908A (en) * 2016-05-06 2016-08-31 王泽陆 Degradable flame-retardant wood-plastic composite material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157207A (en) * 2019-05-14 2019-08-23 浙江合塑控股有限公司 A kind of wear-resistant macromolecule composite wood-plastic material against corrosion and its manufacturing method

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Application publication date: 20190111