CN109177541A - Heat transfer printing color ribbon capable of being used secondarily and preparation method thereof - Google Patents
Heat transfer printing color ribbon capable of being used secondarily and preparation method thereof Download PDFInfo
- Publication number
- CN109177541A CN109177541A CN201811267981.0A CN201811267981A CN109177541A CN 109177541 A CN109177541 A CN 109177541A CN 201811267981 A CN201811267981 A CN 201811267981A CN 109177541 A CN109177541 A CN 109177541A
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- Prior art keywords
- heat transfer
- parts
- colour ribbon
- transfer colour
- temperature
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
- B41J31/05—Ink ribbons having coatings other than impression-material coatings
- B41J31/06—Ink ribbons having coatings other than impression-material coatings the coatings being directly on the base material, i.e. below impression transfer material; Ink ribbons having base material impregnated with material other than impression material
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- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention relates to a heat transfer printing color ribbon capable of being used secondarily, which consists of a ribbon base, a high-temperature color layer and a low-temperature color layer, wherein the high-temperature color layer and the low-temperature color layer are sequentially coated on the ribbon base; the high-temperature color layer is prepared from the following raw materials in parts by weight: 20-25 parts of phenolic resin, 0.5-1.0 part of phthalate and 68-78 parts of solid powder; the low-temperature color layer is prepared from the following raw materials in parts by weight: 20-30 parts of hydrogenated rosin resin, 40-60 parts of paraffin and 20-30 parts of carbon black. The heat transfer printing color ribbon capable of being used secondarily adopts the high-temperature and low-temperature color layers for secondary coating, the formed product is subjected to secondary transfer printing of the high-temperature and low-temperature color layers at different printing temperatures, a roll of color ribbon can realize the effect of secondary use, the use cost is reduced, the waste generation amount is reduced, and the limitation that the traditional method can be used only once is overcome.
Description
Technical field
The invention belongs to technical field of hot stamping materials, and in particular to the heat transfer colour ribbon and its preparation that one kind secondary can use
Method.
Background technique
Thermal transfer is as a kind of picture-text printing method, compared with printing liquid ink method, because having energy conservation and environmental protection, side
Just the advantages that quick, and be used widely in multiple fields such as food, medicine, electronics, dress ornaments.However, institute currently on the market
The colour band of offer is disposable product, causes use cost higher although print temperature is divided into height；Together
When, the scratch tape after use is the dangerous solid waste for needing high temperature incineration to dispose.Therefore, the requirement of environmental protection and energy saving is advocated based on country,
The heat transfer colour ribbon that secondary can be used urgently is studied, to reduce use cost, dangerous waste yield is reduced, biggish economy is provided
Benefit and environmental benefit.
Summary of the invention
Present invention aims to overcome that prior art defect, provide that a kind of use cost is low, more environmentally friendly secondary can make
Heat transfer colour ribbon.
The present invention also provides the preparation methods of the above-mentioned heat transfer colour ribbon that secondary can be used.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of heat transfer colour ribbon that secondary can be used, high temperature chromatograph, the low temperature chromatograph by tape base and being successively coated on tape base
It constitutes；The high temperature chromatograph is made of the raw material of following portions by weight: 20-25 parts of phenolic resin, phthalic acid ester 0.5-
1.0 parts and 68-78 parts of solid powder；The low temperature chromatograph is made of the raw material of following portions by weight: hydrogenated rosin resin 20-
30 parts, 40-60 parts of paraffin and 20-30 parts of carbon black.
When the heat transfer colour ribbon product that user secondary can be used using the present invention, first pass sets printer word grain temperature
It is scheduled on 50-80 DEG C；The scratch tape for completing first pass printing is installed again, secondary use under the conditions of 150-180 DEG C of print temperature.
Specifically, the above-mentioned heat transfer colour ribbon that secondary can be used, the solid powder by following weight percentage raw material
Composition: carbon black 12%, polyethylene wax 2%, surplus are calcium sulfate.
Specifically, the above-mentioned heat transfer colour ribbon that secondary can be used, the particle size carbon black is at 2 μm hereinafter, oil factor is 25
ML/100g or less；The polyethylene wax partial size is in 1 μm or less, fusing point at 150 DEG C or more；The calcium sulfate partial size 2 μm with
Under.
Specifically, the above-mentioned heat transfer colour ribbon that secondary can be used, the tape base is that 12 μm of thickness of biaxial stretching polyester is thin
Film, high-temperature color layer is with a thickness of 7 μm, and low temperature chromatograph is with a thickness of 4 μm；I.e. heat transfer colour ribbon overall thickness is 23 μm.
The present invention provides the preparation methods of the above-mentioned heat transfer colour ribbon that secondary can be used, specifically includes the following steps:
A) each raw material is taken in proportion, obtains resin liquid with solvent dissolution phenolic resin, and by resin liquid and phthalic acid ester, solid
It is added in sand mill after the mixing of body powder until being ground to partial size≤5 μm, obtains ink one；By ground ink one high speed
Coating machine is coated on band primary surface, and drying forms high temperature chromatograph, controls 7 μm of coating thickness, enters subsequent processing；
B) hydrogenated rosin resin and paraffin are melted, the carbon black of corresponding amount is then added under agitation, high-speed stirred 20 is divided
Clock is rolled with three-roller to fineness≤5 μm to mix acquisition mixture, by mixture, obtains ink two；Simultaneously by the heating of ink two
It is coated on high-temperature color layer surface, is cooled into low temperature chromatograph, 4 μm of control coating thickness secondary can make to get 23 μm of overall thickness
Heat transfer colour ribbon.
Specifically, the solvent is mixed with butanone by the toluene that volume ratio is 1:1 and is formed, and solvent usage is in step a)
7 times of phenolic resin weight.
Compared to the prior art, the beneficial effect comprise that:
1) heat transfer colour ribbon that the present invention secondary can use is using high temperature, the secondary coating of low temperature chromatograph, and the product of formation is in difference
Print temperature under, high temperature, low temperature chromatograph transfer twice, and a roll of colour band can realize the effect used twice, reduce use at
This, reduces waste yield, overcomes tradition and be only capable of expendable limitation；
2) traditional heat transfer colour ribbon product, in thermoprint transfer printing image-text be it is disposable, the scratch tape after using gives up as dangerous
Object needs high temperature incineration to dispose.Heat transfer colour ribbon of the present invention is due to being coated with high temperature, low temperature two layers of coatings, it is possible to use
Twice, using effect is 2 times of traditional colour band, while the hazardous waste generated is the half of traditional colour band, be can produce biggish
Economic benefit and environmental benefit.
Specific embodiment
Technical solution of the present invention is further discussed in detail with reference to embodiments, but protection scope of the present invention
It is not limited thereto.
In following each embodiments, tape base selects 12 μm of thickness of biaxially oriented polyester film, high-temperature color layer with a thickness of 7 μm,
Low temperature chromatograph is with a thickness of 4 μm.The softening point of phenolic resin used is between 100-120 DEG C；Hydrogenated rosin softening point is in 90-
Between 105 DEG C；Paraffin melting point range is 55-65 DEG C.Calcium sulfate partial size used is at 2 μm or less；Particle size carbon black at 2 μm hereinafter,
Oil factor is in 25mL/100g or less；Polyethylene wax partial size is at 1 μm hereinafter, 150 DEG C of fusing point or more.Selected original in embodiment
Material is ordinary commercial products, can directly be bought.
In following each embodiments, solid powder used is composed of the following weight percentages of raw materials: carbon black 12%, poly- second
Alkene wax 2%, surplus are calcium sulfate.
Embodiment 1
A kind of heat transfer colour ribbon that secondary can be used, high temperature chromatograph, the low temperature chromatograph structure by tape base and being successively coated on tape base
At.
The high temperature chromatograph and the raw materials used type and parts by weight of low temperature chromatograph see the table below.Wherein, the hydrogenation of selection
Rosin resin softening point is 90 DEG C, and paraffin melting point is 60 DEG C, and phenolic resin softening point is 110 DEG C.
The preparation method of the above-mentioned heat transfer colour ribbon that secondary can be used, comprising the following steps:
A) each raw material is taken in proportion, dissolves phenolic resin (mixed solvent with the mixed solvent being made of volume 1:1 toluene and butanone
Dosage is 7 times of phenolic resin weight) resin liquid is obtained, and add after resin liquid is mixed with phthalic acid ester, solid powder
Enter until being ground to partial size≤5 μm in sand mill, obtains ink one；Ground ink one is coated on band with high speed coating machine
Primary surface, drying form high temperature chromatograph, control 7 μm of coating thickness, enter subsequent processing；
B) hydrogenated rosin resin and paraffin are melted under the conditions of 120 DEG C, the carbon black of corresponding amount are then added under agitation,
Mixture is obtained to mix within high-speed stirred 20 minutes, mixture is rolled with three-roller to fineness≤5 μm, ink two is obtained；It will
Ink two is heated to 120 DEG C and is coated on high-temperature color layer surface, is cooled into low temperature chromatograph, controls 4 μm of coating thickness to get total
23 μm of thickness of the heat transfer colour ribbon that secondary can be used.
Embodiment 2
A kind of heat transfer colour ribbon that secondary can be used, high temperature chromatograph, the low temperature chromatograph structure by tape base and being successively coated on tape base
At.
The high temperature chromatograph and the raw materials used type and parts by weight of low temperature chromatograph see the table below.Wherein, the hydrogenation of selection
Rosin resin softening point is 105 DEG C, and paraffin melting point is 55 DEG C, and phenolic resin softening point is 120 DEG C.
The preparation method of the above-mentioned heat transfer colour ribbon that secondary can be used, comprising the following steps:
A) each raw material is taken in proportion, dissolves phenolic resin (mixed solvent with the mixed solvent being made of volume 1:1 toluene and butanone
Dosage is 7 times of phenolic resin weight) resin liquid is obtained, and add after resin liquid is mixed with phthalic acid ester, solid powder
Enter until being ground to partial size≤5 μm in sand mill, obtains ink one；Ground ink one is coated on band with high speed coating machine
Primary surface, drying form high temperature chromatograph, control 7 μm of coating thickness, enter subsequent processing；
B) hydrogenated rosin resin and paraffin are melted under the conditions of 120 DEG C, the carbon black of corresponding amount are then added under agitation,
Mixture is obtained to mix within high-speed stirred 20 minutes, mixture is rolled with three-roller to fineness≤5 μm, ink two is obtained；It will
Ink two is heated to 120 DEG C and is coated on high-temperature color layer surface, is cooled into low temperature chromatograph, controls 4 μm of coating thickness to get total
23 μm of thickness of the heat transfer colour ribbon that secondary can be used.
Embodiment 3
A kind of heat transfer colour ribbon that secondary can be used, high temperature chromatograph, the low temperature chromatograph structure by tape base and being successively coated on tape base
At.
The high temperature chromatograph and the raw materials used type and parts by weight of low temperature chromatograph see the table below.Wherein, the hydrogenation of selection
Rosin resin softening point is 90 DEG C, and paraffin melting point is 65 DEG C, and phenolic resin softening point is 100 DEG C.
The preparation method of the above-mentioned heat transfer colour ribbon that secondary can be used, comprising the following steps:
A) each raw material is taken in proportion, dissolves phenolic resin (mixed solvent with the mixed solvent being made of volume 1:1 toluene and butanone
Dosage is 7 times of phenolic resin weight) resin liquid is obtained, and add after resin liquid is mixed with phthalic acid ester, solid powder
Enter until being ground to partial size≤5 μm in sand mill, obtains ink one；Ground ink one is coated on band with high speed coating machine
Primary surface, drying form high temperature chromatograph, control 7 μm of coating thickness, enter subsequent processing；
B) hydrogenated rosin resin and paraffin are melted under the conditions of 120 DEG C, the carbon black of corresponding amount are then added under agitation,
Mixture is obtained to mix within high-speed stirred 20 minutes, mixture is rolled with three-roller to fineness≤5 μm, ink two is obtained；It will
Ink two is heated to 120 DEG C and is coated on high-temperature color layer surface, is cooled into low temperature chromatograph, controls 4 μm of coating thickness to get total
23 μm of thickness of the heat transfer colour ribbon that secondary can be used.
Embodiment 4
A kind of heat transfer colour ribbon that secondary can be used, high temperature chromatograph, the low temperature chromatograph structure by tape base and being successively coated on tape base
At.
The high temperature chromatograph and the raw materials used type and parts by weight of low temperature chromatograph see the table below.Wherein, the hydrogenation of selection
Rosin resin softening point is 90 DEG C, and paraffin melting point is 65 DEG C, and phenolic resin softening point is 100 DEG C.
The preparation method of the above-mentioned heat transfer colour ribbon that secondary can be used, comprising the following steps:
A) each raw material is taken in proportion, dissolves phenolic resin (mixed solvent with the mixed solvent being made of volume 1:1 toluene and butanone
Dosage is 7 times of phenolic resin weight) resin liquid is obtained, and add after resin liquid is mixed with phthalic acid ester, solid powder
Enter until being ground to partial size≤5 μm in sand mill, obtains ink one；Ground ink one is coated on band with high speed coating machine
Primary surface, drying form high temperature chromatograph, control 7 μm of coating thickness, enter subsequent processing；
B) hydrogenated rosin resin and paraffin are melted under the conditions of 120 DEG C, the carbon black of corresponding amount are then added under agitation,
Mixture is obtained to mix within high-speed stirred 20 minutes, mixture is rolled with three-roller to fineness≤5 μm, ink two is obtained；It will
Ink two is heated to 120 DEG C and is coated on high-temperature color layer surface, is cooled into low temperature chromatograph, controls 4 μm of coating thickness to get total
23 μm of thickness of the heat transfer colour ribbon that secondary can be used.
In colour band development process of the present invention, it is preferred that emphasis is under the premise of not influencing secondary use function, improve cryosphere print
Mark adhesive force and heat zone printing material applicability.Guarantee necessary temperature difference first, heat zone mentions when preventing from using for the first time
Preceding removing；Secondly selection physical and chemical parameter suitable material and product structure (referring mainly to ink layer thickness) guarantee that cryosphere is necessary
Adhesive force and heat zone transferring effect appropriate.Through multifactor, multilevel orthogonal experiment, above-mentioned experiment parameter is determined.
When the heat transfer colour ribbon product that user secondary can be used using the present invention, first pass sets printer word grain temperature
It is scheduled on 50-80 DEG C；The scratch tape for completing first pass printing is installed again, secondary use under the conditions of 150-180 DEG C of print temperature.
In use process, it is noted that following details:
Transfer the selection of material: this product low-temperature transfer printing layer is wider to the scope of application of printing material, plastic film, paper, leather,
But high temperature transfer layer ink is plastic table printing ink, is only applicable to composite plastic film, including overlay film paper.
Claims (6)
1. the heat transfer colour ribbon that one kind secondary can use, which is characterized in that the high-temperature color by tape base and being successively coated on tape base
Layer, low temperature chromatograph are constituted；The high temperature chromatograph is made of the raw material of following portions by weight: 20-25 parts of phenolic resin, adjacent benzene two
0.5-1.0 part and 68-78 parts of solid powder of formic acid esters；The low temperature chromatograph is made of the raw material of following portions by weight: hydrogenation
20-30 parts of rosin resin, 40-60 parts of paraffin and 20-30 parts of carbon black.
2. the heat transfer colour ribbon that secondary can be used as described in claim 1, which is characterized in that the solid powder is by following heavy
Measure the raw material composition of percentage: carbon black 12%, polyethylene wax 2%, surplus are calcium sulfate.
3. the heat transfer colour ribbon that secondary can be used as claimed in claim 2, which is characterized in that the particle size carbon black 2 μm with
Under, oil factor is in 25 mL/100g or less；The polyethylene wax partial size is in 1 μm or less, fusing point at 150 DEG C or more；The sulfuric acid
Calcium grain diameter is at 2 μm or less.
4. the heat transfer colour ribbon that secondary can be used as described in claim 1, which is characterized in that the tape base is 12 μm of thickness
Biaxially oriented polyester film, high-temperature color layer is with a thickness of 7 μm, and low temperature chromatograph is with a thickness of 4 μm.
5. the preparation method of any heat transfer colour ribbon that secondary can be used of Claims 1-4, which is characterized in that including with
Lower step:
A) each raw material is taken in proportion, obtains resin liquid with solvent dissolution phenolic resin, and by resin liquid and phthalic acid ester, solid
Partial size≤5 μm are ground to after the mixing of body powder, obtain ink one；Ink one is coated on band primary surface, drying forms high-temperature color
Layer, enters subsequent processing；
B) hydrogenated rosin resin and paraffin are melted, the carbon black of corresponding amount is then added under agitation, stirs evenly acquisition
Mixture is rolled to fineness≤5 μm, obtains ink by mixture；Ink two is heated to and is coated on high-temperature color layer surface, it is cooling
Low temperature chromatograph is formed to get the heat transfer colour ribbon that secondary can be used.
6. the preparation method for the heat transfer colour ribbon that secondary can be used as claimed in claim 5, which is characterized in that in step a), institute
It states solvent to be mixed and formed with butanone by the toluene that volume ratio is 1:1, solvent usage is 7 times of phenolic resin weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811267981.0A CN109177541B (en) | 2018-10-29 | 2018-10-29 | Heat transfer printing color ribbon capable of being used secondarily and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811267981.0A CN109177541B (en) | 2018-10-29 | 2018-10-29 | Heat transfer printing color ribbon capable of being used secondarily and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109177541A true CN109177541A (en) | 2019-01-11 |
| CN109177541B CN109177541B (en) | 2021-02-09 |
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110776835A (en) * | 2019-11-08 | 2020-02-11 | 焦作卓立膜材料有限责任公司 | Marking film for hard smooth substrate surface |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110776835A (en) * | 2019-11-08 | 2020-02-11 | 焦作卓立膜材料有限责任公司 | Marking film for hard smooth substrate surface |
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| CN109177541B (en) | 2021-02-09 |
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Effective date of registration: 20220128 Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee after: Jiaozuo Zhuoli membrane materials Co.,Ltd. Address before: No.2758, Shenzhou Road, high tech Zone, Jiaozuo City, Henan Province Patentee before: ZHUOLI IMAGING TECHNOLOGY Co.,Ltd. |
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Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee after: Jiaozuo Zhuoli film material Co.,Ltd. Address before: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee before: Jiaozuo Zhuoli membrane materials Co.,Ltd. |