CN109161216A - A kind of environment-friendly type dress materials and its processing method - Google Patents
A kind of environment-friendly type dress materials and its processing method Download PDFInfo
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- CN109161216A CN109161216A CN201810935168.XA CN201810935168A CN109161216A CN 109161216 A CN109161216 A CN 109161216A CN 201810935168 A CN201810935168 A CN 201810935168A CN 109161216 A CN109161216 A CN 109161216A
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- Prior art keywords
- leaf
- environment
- dress materials
- friendly type
- polyether ester
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of environment-friendly type dress materials, its raw material includes: leaf 40%-45% by weight, chemical agent 15%-20%, sodium hydroxide solution 10%-15%, nanometer calcium carbonate 8%-10%, glue 10%-15%, polyether ester 6%-8% and polyamide 2%-3%, the polyether ester is by para Toluic Acid's dimethyl ester, butanediol and polyethylene oxide glycol and the propylene oxide dihydric alcohol PA polybutyleneterephthalate's-polyethylene oxide-polypropylene oxide thermoplastic elastomer (TPE) of the block copolymer as obtained from melt co-polycondensation, it is related to dress materials technical field.The environment-friendly type dress materials and its processing method; very environmentally friendly raw material are utilized; greatly improve its environment-friendly function; existing resource is effectively utilized; improve people's lives quality; and the processing cost of the producer is reduced, and improve whole heat resistance to a certain extent, increase whole quality.
Description
Technical field
The present invention relates to dress materials technical field, specially a kind of environment-friendly type dress materials and its processing method.
Background technique
It is reinforced phase that dress materials, which are fiber in a variety of manners, yarn, fabric, with resin, rubber, metal, cement, pottery
The materials such as porcelain are the composite material of matrix phase.The adhesion strength of the properity of garment material, textile material and basal body interface with
And the factors such as performance of matrix determine the performance of composite material, it is real or potential to solve that environmental protection generally refers to the mankind
Environmental problem coordinates the relationship of the mankind and environment, protects the living environment of the mankind, ensures the sustainable development of economic society and adopt
The general name of the various action taken makes environment be more suitable for the needs of human work and labour, this relate to the clothing of people, food, shelter,
Row, the every aspect played will meet science, health, health, requirement this level of green and belong to microcosmic, existing clothes
Package material is usually to be combined by multiple material, and the production of at high cost and raw material is complicated, does not have the good feature of environmental protection, and existing
Dress materials its heat resistances be not very well, to affect the use of user.
Traditional dress materials and its processing method can not utilize very environmentally friendly raw material, it greatly reduces
Environment-friendly function cannot effectively utilize existing resource, reduce people's lives quality, and increase being processed into for the producer
This, reduces people's lives level, and reduce whole heat resistance to a certain extent, reduces whole quality.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, it the present invention provides a kind of environment-friendly type dress materials and its processing method, solves
The problem of existing environment-friendly type dress materials can not utilize very environmentally friendly raw material and reduce whole heat resistance.
(2) technical solution
A kind of environment-friendly type dress materials proposed by the present invention, raw material include: leaf 40%-45%, chemistry by weight
Medicament 15%-20%, sodium hydroxide solution 10%-15%, nanometer calcium carbonate 8%-10%, glue 10%-15%, polyether ester
6%-8% and polyamide 2%-3%.
Preferably, the polyether ester is by para Toluic Acid's dimethyl ester, butanediol and polyethylene oxide glycol and epoxy
Propane dihydric alcohol block copolymer as obtained from melt co-polycondensation PA polybutyleneterephthalate-polyethylene oxide-polycyclic
Ethylene Oxide thermoplastic elastomer (TPE), wherein polyethylene oxide and polypropylene oxide relative molecular mass are 600 to 2800, quality percentage
Than for 20%-50%.
The invention also provides a kind of processing methods of environment-friendly type dress materials, specifically includes the following steps:
S1, by leaf emchanically centrifugal separation, add chemical agent and be centrifugated together, to improve the accessibility to leaf,
Then leaf is subjected to alkali process in the sodium hydroxide solution that mass percentage concentration is 10%-14%, the temperature of alkali process is
50-55 DEG C, the alkali process time is 15-25min；
S2, the leaf in S1 is washed after alkali process, after washing using acid solution adjust pH, after adjusting again into
Row washing, at this moment 68-96 DEG C at a temperature of drying 20-30min after obtain the fiber in leaf；
S3, using the fiber in leaf obtained in S2 as reinforced phase, using nanometer calcium carbonate and glue as matrix through heat
Pressure obtains composite material, keeps hot press pressure, by obtained composite material natural cooling or water cooling at normal temperature；
S4, by after polyamide dispersion mixing, by double screw extruder melting, mixing, extrusion, cooling, pelletizing, it is dry after
Moisture-inhibiting polyamide is obtained, then by double screw extruder melting, will be kneaded, crowded after polyether ester, moisture-inhibiting polyamide dispersion mixing
Out, modified polyether ester is obtained after cooling, pelletizing, drying, each zone temperature of double-screw extruding machine barrel used is 200 to 240 DEG C；
S5, the modified polyether ester in the composite material and S4 in S3 is subjected to Hybrid Heating, is obtained into after cooling or water cooling
Product
Preferably, the chemical agent in the S1 is by vinylacetate, phthalic acid, vinyl acetate, titanium dioxide, floating
Stone, zinc oxide, SODIUM SILICATE, aqueous Petimin aluminium, powdery fluorocarbon resin, furane resins and charcoal end in five kinds or five kinds or more at
Divide and is made.
(3) beneficial effect
The present invention provides a kind of environment-friendly type dress materials and its processing methods.Have following the utility model has the advantages that the environment-friendly type
Dress materials and its processing method, by its raw material include: by weight leaf 40%-45%, chemical agent 15%-20%,
Sodium hydroxide solution 10%-15%, nanometer calcium carbonate 8%-10%, glue 10%-15%, polyether ester 6%-8% and polyamide
2%-3%, polyether ester are led to by para Toluic Acid's dimethyl ester, butanediol and polyethylene oxide glycol and propylene oxide dihydric alcohol
Cross the PA polybutyleneterephthalate's-polyethylene oxide-polypropylene oxide thermoplasticity of block copolymer obtained from melt co-polycondensation
Elastomer, wherein polyethylene oxide and polypropylene oxide relative molecular mass are 600 to 2800, mass percent 20%-
50%, very environmentally friendly raw material are utilized, greatly improve its environment-friendly function, existing resource is effectively utilized, improve
People's lives quality, and the processing cost of the producer is reduced, people's lives level is improved, and to a certain extent mention
High whole heat resistance, increases whole quality.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The embodiment of the present invention provides a kind of technical solution: a kind of environment-friendly type dress materials, and raw material includes: tree by weight
Leaf 40%-45%, chemical agent 15%-20%, sodium hydroxide solution 10%-15%, nanometer calcium carbonate 8%-10%, glue
10%-15%, polyether ester 6%-8% and polyamide 2%-3%.
In the present invention, polyether ester is by para Toluic Acid's dimethyl ester, butanediol and polyethylene oxide glycol and epoxy third
The alkane dihydric alcohol PA polybutyleneterephthalate's-polyethylene oxide-polycyclic oxygen of the block copolymer as obtained from melt co-polycondensation
Propane thermoplastic elastomer (TPE), wherein polyethylene oxide and polypropylene oxide relative molecular mass are 600 to 2800, mass percent
For 20%-50%.
In the present invention, chemical agent in S1 is by vinylacetate, phthalic acid, vinyl acetate, titanium dioxide, floating
Stone, zinc oxide, SODIUM SILICATE, aqueous Petimin aluminium, powdery fluorocarbon resin, furane resins and charcoal end in five kinds or five kinds or more at
Divide and is made.
It is next combined with specific embodiments below that the present invention will be further described.
Embodiment 1
The invention also discloses a kind of processing methods of environment-friendly type dress materials, specifically includes the following steps:
S1, by leaf emchanically centrifugal separation, add chemical agent and be centrifugated together, to improve the accessibility to leaf,
Then leaf is subjected to alkali process in the sodium hydroxide solution that mass percentage concentration is 15%-20%, the temperature of alkali process is
50-55 DEG C, the alkali process time is 15-25min；
S2, the leaf in S1 is washed after alkali process, after washing using acid solution adjust pH, after adjusting again into
Row washing, at this moment 80-96 DEG C at a temperature of drying 25-30min after obtain the fiber in leaf；
S3, using the fiber in leaf obtained in S2 as reinforced phase, using nanometer calcium carbonate and glue as matrix through heat
Pressure obtains composite material, keeps hot press pressure, by obtained composite material natural cooling or water cooling at normal temperature；
S4, by after polyamide dispersion mixing, by double screw extruder melting, mixing, extrusion, cooling, pelletizing, it is dry after
Moisture-inhibiting polyamide is obtained, then by double screw extruder melting, will be kneaded, crowded after polyether ester, moisture-inhibiting polyamide dispersion mixing
Out, modified polyether ester is obtained after cooling, pelletizing, drying, each zone temperature of double-screw extruding machine barrel used is 200 to 240 DEG C；
S5, the modified polyether ester in the composite material and S4 in S3 is subjected to Hybrid Heating, is obtained into after cooling or water cooling
Product.
Embodiment 2
The invention also discloses a kind of processing methods of environment-friendly type dress materials, specifically includes the following steps:
S1, by leaf emchanically centrifugal separation, add chemical agent and be centrifugated together, to improve the accessibility to leaf,
Then leaf is subjected to alkali process in the sodium hydroxide solution that mass percentage concentration is 25%-30%, the temperature of alkali process is
60-70 DEG C, the alkali process time is 20-25min；
S2, the leaf in S1 is washed after alkali process, after washing using acid solution adjust pH, after adjusting again into
Row washing, at this moment 70-96 DEG C at a temperature of drying 20-30min after obtain the fiber in leaf；
S3, using the fiber in leaf obtained in S2 as reinforced phase, using nanometer calcium carbonate and glue as matrix through heat
Pressure obtains composite material, keeps hot press pressure, by obtained composite material natural cooling or water cooling at normal temperature；
S4, by after polyamide dispersion mixing, by double screw extruder melting, mixing, extrusion, cooling, pelletizing, it is dry after
Moisture-inhibiting polyamide is obtained, then by double screw extruder melting, will be kneaded, crowded after polyether ester, moisture-inhibiting polyamide dispersion mixing
Out, modified polyether ester is obtained after cooling, pelletizing, drying, each zone temperature of double-screw extruding machine barrel used is 200 to 240 DEG C；
S5, the modified polyether ester in the composite material and S4 in S3 is subjected to Hybrid Heating, is obtained into after cooling or water cooling
Product.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (4)
1. a kind of environment-friendly type dress materials, which is characterized in that its raw material parts by weights includes: leaf 40%-45%, chemical agent
15%-20%, sodium hydroxide solution 10%-15%, nanometer calcium carbonate 8%-10%, glue 10%-15%, polyether ester 6%-
8% and polyamide 2%-3%.
2. a kind of environment-friendly type dress materials according to claim 1, it is characterised in that: the polyether ester is by para Toluic Acid
Dimethyl ester, butanediol and polyethylene oxide glycol and propylene oxide dihydric alcohol block as obtained from melt co-polycondensation are total
Polymers PA polybutyleneterephthalate's-polyethylene oxide-polypropylene oxide thermoplastic elastomer (TPE), wherein polyethylene oxide and polycyclic
Ethylene Oxide relative molecular mass is 600 to 2800, mass percent 20%-50%.
3. a kind of processing method of environment-friendly type dress materials according to claim 1, it is characterised in that: specifically include following
Step:
S1, by leaf emchanically centrifugal separation, add chemical agent and be centrifugated together, to improve the accessibility to leaf, then
Leaf is subjected to alkali process in the sodium hydroxide solution that mass percentage concentration is 10%-14%, the temperature of alkali process is 50-55
DEG C, the alkali process time is 15-25min；
S2, the leaf in S1 is washed after alkali process, adjusts pH using acid solution after washing, carries out water after adjusting again
Wash, at this moment 68-96 DEG C at a temperature of drying 20-30min after obtain the fiber in leaf；
S3, using the fiber in leaf obtained in S2 as reinforced phase, obtained using nanometer calcium carbonate and glue as matrix through hot pressing
To composite material, hot press pressure is kept, by obtained composite material natural cooling or water cooling at normal temperature；
S4, by after polyamide dispersion mixing, by double screw extruder melting, mixing, extrusion, cooling, pelletizing, it is dry after thoroughly
Wet polyamide by double screw extruder melting, mixing, squeezes out, cold then by after polyether ester, moisture-inhibiting polyamide dispersion mixing
But, modified polyether ester is obtained after pelletizing, drying, each zone temperature of double-screw extruding machine barrel used is 200 to 240 DEG C；
S5, the modified polyether ester in the composite material and S4 in S3 is subjected to Hybrid Heating, obtains finished product after cooling or water cooling.
4. a kind of environment-friendly type dress materials according to claim 3 and its processing method, it is characterised in that: in the S1
Chemical agent is by vinylacetate, phthalic acid, vinyl acetate, titanium dioxide, float stone, zinc oxide, SODIUM SILICATE, aqueous silicon acid
Five kinds or five kinds or more ingredients in magnalium, powdery fluorocarbon resin, furane resins and charcoal end are made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810935168.XA CN109161216A (en) | 2018-08-16 | 2018-08-16 | A kind of environment-friendly type dress materials and its processing method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810935168.XA CN109161216A (en) | 2018-08-16 | 2018-08-16 | A kind of environment-friendly type dress materials and its processing method |
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| Publication Number | Publication Date |
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| CN109161216A true CN109161216A (en) | 2019-01-08 |
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| CN201810935168.XA Pending CN109161216A (en) | 2018-08-16 | 2018-08-16 | A kind of environment-friendly type dress materials and its processing method |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101358020A (en) * | 2008-09-28 | 2009-02-04 | 华南理工大学 | Nonporous moisture permeable and water-repellent modified polyether ester functional film material and preparation method thereof |
| CN105713353A (en) * | 2016-04-20 | 2016-06-29 | 吴江市泽旺纺织有限公司 | Novel composite aging-resistant textile material and preparing method thereof |
| CN107268181A (en) * | 2017-06-13 | 2017-10-20 | 合肥远科服装设计有限公司 | A kind of preparation method of dress materials |
| CN107312202A (en) * | 2017-07-05 | 2017-11-03 | 合肥片美环保科技有限公司 | Preparation method of energy-saving and environment-friendly clothing material |
| CN107383433A (en) * | 2017-07-29 | 2017-11-24 | 合肥梵清电子商务有限公司 | A kind of preparation method of dress materials |
-
2018
- 2018-08-16 CN CN201810935168.XA patent/CN109161216A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101358020A (en) * | 2008-09-28 | 2009-02-04 | 华南理工大学 | Nonporous moisture permeable and water-repellent modified polyether ester functional film material and preparation method thereof |
| CN105713353A (en) * | 2016-04-20 | 2016-06-29 | 吴江市泽旺纺织有限公司 | Novel composite aging-resistant textile material and preparing method thereof |
| CN107268181A (en) * | 2017-06-13 | 2017-10-20 | 合肥远科服装设计有限公司 | A kind of preparation method of dress materials |
| CN107312202A (en) * | 2017-07-05 | 2017-11-03 | 合肥片美环保科技有限公司 | Preparation method of energy-saving and environment-friendly clothing material |
| CN107383433A (en) * | 2017-07-29 | 2017-11-24 | 合肥梵清电子商务有限公司 | A kind of preparation method of dress materials |
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Application publication date: 20190108 |