CN107268181A - A kind of preparation method of dress materials - Google Patents
A kind of preparation method of dress materials Download PDFInfo
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- CN107268181A CN107268181A CN201710441286.0A CN201710441286A CN107268181A CN 107268181 A CN107268181 A CN 107268181A CN 201710441286 A CN201710441286 A CN 201710441286A CN 107268181 A CN107268181 A CN 107268181A
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- leaf
- preparation
- alkali process
- dress materials
- fiber
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01B—MECHANICAL TREATMENT OF NATURAL FIBROUS OR FILAMENTARY MATERIAL TO OBTAIN FIBRES OF FILAMENTS, e.g. FOR SPINNING
- D01B1/00—Mechanical separation of fibres from plant material, e.g. seeds, leaves, stalks
- D01B1/10—Separating vegetable fibres from stalks or leaves
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
- D01C1/00—Treatment of vegetable material
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/558—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in combination with mechanical or physical treatments other than embossing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
A kind of preparation method of dress materials, comprises the following steps:First, it is mechanically decoupled:By leaf emchanically centrifugal separation, to improve accessibility of the alkali process to leaf;2nd, alkali process:Leaf is subjected to alkali process in sodium hydroxide solution;3rd, leaf is washed through the laggard water-filling of alkali process, is adjusted pH using acid solution after washing, is washed again after regulation;4th, dry:Fiber in obtaining leaf after drying at a temperature of 80 120 DEG C;5th, using the fiber in leaf as enhancing phase, composite is obtained through hot pressing using nano-calcium carbonate and processing aid as matrix;6th, hot press pressure is kept, after the composite cooling that step 5 is obtained.The product of the present invention have good luster, brightness it is high, it is environment friendly and pollution-free the characteristics of, the fiberoptic fiber cellulose content in the leaf that extracts of the present invention is high, and fineness is thin, and composite materials property is good, internal simultaneously to have many and small spaces, with good heat-insulated and sound insulation value.
Description
Technical field
The invention belongs to clothing making technology field, and in particular to a kind of preparation method of dress materials.
Background technology
Rationally, efficiently using plant resources, turn waste into wealth, production environment friendly materials turn into the world hot subject.
China is a forestry big country, at present, and these plant leaves rich in cellulose mainly have following processing mode, but is all existed not
Foot:1. the waste treatment such as landfill, burning, not only without efficent use of resources, and can discharge substantial amounts of two in combustion
Carbonoxide, pollutes environment;2. appropriate crush makes medium-density plate, due to shorter, the humidification as the leaf length of reinforcement
It is limited, in addition, most of is to use environmentally harmful adhesive;3. preparing fuel ethanol, conversion ratio is low, and cost is high;4. burn
Generate electricity, added value is low.Therefore, the efficient utilization problem of leaf also needs to widely studied.
Fiber extracts and prepared the patent of material:Patent of invention(Grant number ZL200710052830.9)It is related to a kind of spinning
With the extracting method of stalk fibre, it is characterised in that comprise the following steps:(1)Steam explosion is pre-processed;(2)By pretreated stalk
It is put into progress steam explosion processing in steam blasting tank;(3)Feed nutrient glucose and urea;(4)Strain degumming;(5)Hardening with radiation:
Stalk fibre after bleaching is used into gamma-ray irradiation, irradiation is 2-10kgy, obtains hardening with radiation stalk fibre;(6)Oil supply;
(7)Drying;(8)Stalk fibre after drying is disperseed, rice-wheat straw fibre for spinning is obtained.Its preparation method is too multiple
It is miscellaneous, it is too high and expensive to the instrument requirements of preparation.
In summary, accordingly, it would be desirable to which a kind of more preferable fiber extracting method, carrys out efficent use of resources, the life of people is improved
Bioplasm amount, advances in living standard.
The content of the invention
It is an object of the invention to provide a kind of preparation method of dress materials, product of the invention has good luster, brightness
Fiberoptic fiber cellulose content in high, environment friendly and pollution-free the characteristics of, the leaf that the present invention is extracted is high, and fineness is thin, Compound Material Engineering
Performance is good, and inside simultaneously has many and small spaces, with good heat-insulated and sound insulation value.
The invention provides following technical scheme:
A kind of preparation method of dress materials, comprises the following steps:
First, it is mechanically decoupled:By leaf emchanically centrifugal separation, to improve accessibility of the alkali process to leaf;
2nd, alkali process:Leaf is subjected to alkali process in mass percentage concentration is 10-14% sodium hydroxide solution, alkali process
Temperature is 70-90 DEG C, and the alkali process time is 2-4h;
3rd, leaf is washed through the laggard water-filling of alkali process, is adjusted pH using acid solution after washing, is washed again after regulation;
4th, dry:Fiber in obtaining leaf after drying 40-60min at a temperature of 80-120 DEG C;
5th, using the fiber in leaf as enhancing phase, it is combined using nano-calcium carbonate and processing aid as matrix through hot pressing
Material;
6th, hot press pressure is kept, the composite that step 5 is obtained is i.e. available after natural cooling or water cooling at normal temperatures
Ready-made clothes material.
It is preferred that, the dress materials include the raw material of following parts by weight:50-80 parts of leaf, sodium hydroxide solution 20-30
10-20 parts of part, 15-35 parts of nano-calcium carbonate and processing aid.
It is preferred that, the step 3 acid solution is hydrochloric acid weak solution or acetic acid, and the acid solution acidity is low, it is easy to adjust pH
Value, and it is with low cost.
It is preferred that, under the concentration of the hydrochloric acid weak solution is 10-20%, the concentration, the speed of regulation can be accelerated, reduced
The amount of solution of regulation, and its danger to operating personnel is not also high.
It is preferred that, the step 3 adjusts pH to 7-7.5.
It is preferred that, the processing aid of the step 5 is 18 triglyceride or glycerine.
It is preferred that, the preparation of the step 5 composite:First the fiber in leaf is helped with nano-calcium carbonate and processing
Agent carries out laying and is well mixed, and hot pressing is carried out on hot press and obtains composite, hot pressing temperature is 200-220 DEG C, and pressure is
5-8MPa, hot pressing time is 10-20min.
It is preferred that, the finished product of the step 6 stands 2-4 days at normal temperatures, and standing can cause the quality of material to precipitate,
Be conducive to the performance of reinforcing material.
The beneficial effects of the invention are as follows:
The product of the present invention have good luster, brightness it is high, it is environment friendly and pollution-free the characteristics of, the fiber in the leaf that extracts of the present invention is fine
Tie up cellulose content high, fineness is thin, and composite materials property is good, it is internal that simultaneously there is many and small spaces, with heat-insulated well and
Sound insulation value.
The present invention uses renewable, the degradable environment-friendly material of resource;Because matrix is thermal plasticity high polymer, it is combined
Material can reuse;Compared with stalk, content of cellulose after extraction is high, and fineness is thin, and cohering for basal body interface, in hot pressing
Cheng Zhongke is just plastic using less pressure;Material mechanical performance is good, and inside simultaneously has many and small spaces, with good
Heat-insulated and sound insulation value.
Embodiment
Embodiment 1
A kind of preparation method of dress materials, comprises the following steps:
First, it is mechanically decoupled:By leaf emchanically centrifugal separation, to improve accessibility of the alkali process to leaf;
2nd, alkali process:Leaf is subjected to alkali process, the temperature of alkali process in mass percentage concentration is 11% sodium hydroxide solution
Spend for 90 DEG C, the alkali process time is 4h;
3rd, leaf is washed through the laggard water-filling of alkali process, is adjusted pH using acid solution after washing, is washed again after regulation;
4th, dry:Fiber in obtaining leaf after drying 46min at a temperature of 80 DEG C;
5th, using the fiber in leaf as enhancing phase, it is combined using nano-calcium carbonate and processing aid as matrix through hot pressing
Material;
6th, hot press pressure is kept, the composite that step 5 is obtained can obtain finished product after natural cooling and takes at normal temperatures
Package material.
Dress materials include the raw material of following parts by weight:80 parts of leaf, 20 parts of sodium hydroxide solution, 35 parts of nano-calcium carbonate
With 20 parts of processing aid.
Step 3 acid solution is hydrochloric acid weak solution, and the acid solution acidity is low, it is easy to adjust pH value, and with low cost.
The concentration of hydrochloric acid weak solution is 10%, under the concentration, can accelerate the speed of regulation, reduces the amount of solution of regulation, and
And its danger to operating personnel is not also high.
Step 3 adjusts pH to 7.
The processing aid of step 5 is glycerine.
The preparation of step 5 composite:The fiber in leaf first is carried out into laying with nano-calcium carbonate and processing aid to mix
Close uniform, hot pressing is carried out on hot press and obtains composite, hot pressing temperature is 200 DEG C, and pressure is 5MPa, and hot pressing time is
10min。
The finished product of step 6 stands 2 days at normal temperatures, and standing can cause the quality of material to precipitate, and be conducive to reinforcing material
Performance.
Embodiment 2
A kind of preparation method of dress materials, comprises the following steps:
First, it is mechanically decoupled:By leaf emchanically centrifugal separation, to improve accessibility of the alkali process to leaf;
2nd, alkali process:Leaf is subjected to alkali process, the temperature of alkali process in mass percentage concentration is 14% sodium hydroxide solution
Spend for 90 DEG C, the alkali process time is 2h;
3rd, leaf is washed through the laggard water-filling of alkali process, is adjusted pH using acid solution after washing, is washed again after regulation;
4th, dry:Fiber in obtaining leaf after drying 60min at a temperature of 120 DEG C;
5th, using the fiber in leaf as enhancing phase, it is combined using nano-calcium carbonate and processing aid as matrix through hot pressing
Material;
6th, hot press pressure is kept, the composite that step 5 is obtained can obtain ready-made clothes material after water cooling at normal temperatures
Material.
Dress materials include the raw material of following parts by weight:80 parts of leaf, 30 parts of sodium hydroxide solution, 15 parts of nano-calcium carbonate
With 10 parts of processing aid.
Step 3 acid solution is hydrochloric acid weak solution, and the acid solution acidity is low, it is easy to adjust pH value, and with low cost.
The concentration of hydrochloric acid weak solution is 10%, under the concentration, can accelerate the speed of regulation, reduces the amount of solution of regulation, and
And its danger to operating personnel is not also high.
Step 3 adjusts pH to 7.5.
The processing aid of step 5 is 18 triglyceride.
The preparation of step 5 composite:The fiber in leaf first is carried out into laying with nano-calcium carbonate and processing aid to mix
Close uniform, hot pressing is carried out on hot press and obtains composite, hot pressing temperature is 220 DEG C, and pressure is 5MPa, and hot pressing time is
10min。
The finished product of step 6 stands 2 days at normal temperatures, and standing can cause the quality of material to precipitate, and be conducive to reinforcing material
Performance.
Embodiment 3
A kind of preparation method of dress materials, comprises the following steps:
First, it is mechanically decoupled:By leaf emchanically centrifugal separation, to improve accessibility of the alkali process to leaf;
2nd, alkali process:Leaf is subjected to alkali process, the temperature of alkali process in mass percentage concentration is 14% sodium hydroxide solution
Spend for 70 DEG C, the alkali process time is 2h;
3rd, leaf is washed through the laggard water-filling of alkali process, is adjusted pH using acid solution after washing, is washed again after regulation;
4th, dry:Fiber in obtaining leaf after drying 60min at a temperature of 80 DEG C;
5th, using the fiber in leaf as enhancing phase, it is combined using nano-calcium carbonate and processing aid as matrix through hot pressing
Material;
6th, hot press pressure is kept, the composite that step 5 is obtained can obtain finished product after natural cooling and takes at normal temperatures
Package material.
Dress materials include the raw material of following parts by weight:50 parts of leaf, 20 parts of sodium hydroxide solution, 15 parts of nano-calcium carbonate
With 20 parts of processing aid.
Step 3 acid solution is acetic acid, and the acid solution acidity is low, it is easy to adjust pH value, and with low cost.
Step 3 adjusts pH to 7.
The processing aid of step 5 is 18 triglyceride.
The preparation of step 5 composite:The fiber in leaf first is carried out into laying with nano-calcium carbonate and processing aid to mix
Close uniform, hot pressing is carried out on hot press and obtains composite, hot pressing temperature is 200 DEG C, and pressure is 8MPa, and hot pressing time is
10min。
The finished product of step 6 stands 4 days at normal temperatures, and standing can cause the quality of material to precipitate, and be conducive to reinforcing material
Performance.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. a kind of preparation method of dress materials, it is characterised in that comprise the following steps:
First, it is mechanically decoupled:By leaf emchanically centrifugal separation, to improve accessibility of the alkali process to leaf;
2nd, alkali process:Leaf is subjected to alkali process in mass percentage concentration is 10-14% sodium hydroxide solution, alkali process
Temperature is 70-90 DEG C, and the alkali process time is 2-4h;
3rd, leaf is washed through the laggard water-filling of alkali process, is adjusted pH using acid solution after washing, is washed again after regulation;
4th, dry:Fiber in obtaining leaf after drying 40-60min at a temperature of 80-120 DEG C;
5th, using the fiber in leaf as enhancing phase, it is combined using nano-calcium carbonate and processing aid as matrix through hot pressing
Material;
6th, hot press pressure is kept, the composite that step 5 is obtained is i.e. available after natural cooling or water cooling at normal temperatures
Ready-made clothes material.
2. a kind of preparation method of dress materials according to claim 1, it is characterised in that the dress materials include with
The raw material of lower parts by weight:50-80 parts of leaf, 20-30 parts of sodium hydroxide solution, 15-35 parts of nano-calcium carbonate and processing aid 10-
20 parts.
3. a kind of preparation method of dress materials according to claim 1, it is characterised in that the step 3 acid solution is
Hydrochloric acid weak solution or acetic acid.
4. a kind of preparation method of dress materials according to claim 3, it is characterised in that the hydrochloric acid weak solution it is dense
Spend for 10-20%.
5. a kind of preparation method of dress materials according to claim 1, it is characterised in that the step 3 adjust pH to
7-7.5。
6. the preparation method of a kind of dress materials according to claim 1, it is characterised in that the processing of the step 5 is helped
Agent is 18 triglyceride or glycerine.
7. a kind of preparation method of dress materials according to claim 1, it is characterised in that the step 5 composite
Preparation:The fiber in leaf first is carried out into laying with nano-calcium carbonate and processing aid to be well mixed, carried out on hot press
Hot pressing obtains composite, and hot pressing temperature is 200-220 DEG C, and pressure is 5-8MPa, and hot pressing time is 10-20min.
8. the preparation method of a kind of dress materials according to claim 1, it is characterised in that the finished product of the step 6 exists
2-4 days are stood under normal temperature.
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CN201710441286.0A CN107268181A (en) | 2017-06-13 | 2017-06-13 | A kind of preparation method of dress materials |
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CN201710441286.0A CN107268181A (en) | 2017-06-13 | 2017-06-13 | A kind of preparation method of dress materials |
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CN107268181A true CN107268181A (en) | 2017-10-20 |
Family
ID=60066621
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107383433A (en) * | 2017-07-29 | 2017-11-24 | 合肥梵清电子商务有限公司 | A kind of preparation method of dress materials |
CN109161216A (en) * | 2018-08-16 | 2019-01-08 | 宁波元元之傲针织织造有限公司 | A kind of environment-friendly type dress materials and its processing method |
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CN1563180A (en) * | 2004-04-09 | 2005-01-12 | 陆校会 | Nano modified polyvinyl alcohol as packing material in use for clothes, and fabricating method |
CN102085680A (en) * | 2010-11-26 | 2011-06-08 | 江南大学 | Preparation method of crop straw fiber ecological composite material |
US20120009387A1 (en) * | 2009-05-15 | 2012-01-12 | Wang James H | Flexible thermoplastic films and articles |
CN106084301A (en) * | 2016-07-04 | 2016-11-09 | 铜陵方正塑业科技有限公司 | A kind of chitin modified γ polyglutamic acid grafting arghan packaging film and preparation method thereof |
CN106084526A (en) * | 2016-07-06 | 2016-11-09 | 淄博职业学院 | A kind of fruit and vegerable insulation material being applied to modern Cold Chain Logistics and preparation method thereof |
CN106366352A (en) * | 2016-08-30 | 2017-02-01 | 安徽锦鸿环保科技有限公司 | Caprolactone-starch degradable thin film with enhanced calcium carbonate and preparing method thereof |
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2017
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1563180A (en) * | 2004-04-09 | 2005-01-12 | 陆校会 | Nano modified polyvinyl alcohol as packing material in use for clothes, and fabricating method |
US20120009387A1 (en) * | 2009-05-15 | 2012-01-12 | Wang James H | Flexible thermoplastic films and articles |
CN102085680A (en) * | 2010-11-26 | 2011-06-08 | 江南大学 | Preparation method of crop straw fiber ecological composite material |
CN106084301A (en) * | 2016-07-04 | 2016-11-09 | 铜陵方正塑业科技有限公司 | A kind of chitin modified γ polyglutamic acid grafting arghan packaging film and preparation method thereof |
CN106084526A (en) * | 2016-07-06 | 2016-11-09 | 淄博职业学院 | A kind of fruit and vegerable insulation material being applied to modern Cold Chain Logistics and preparation method thereof |
CN106366352A (en) * | 2016-08-30 | 2017-02-01 | 安徽锦鸿环保科技有限公司 | Caprolactone-starch degradable thin film with enhanced calcium carbonate and preparing method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107383433A (en) * | 2017-07-29 | 2017-11-24 | 合肥梵清电子商务有限公司 | A kind of preparation method of dress materials |
CN109161216A (en) * | 2018-08-16 | 2019-01-08 | 宁波元元之傲针织织造有限公司 | A kind of environment-friendly type dress materials and its processing method |
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Application publication date: 20171020 |