CN109160808A - Arc furnace ventral triangle area prefabricated component dedicated pouring material - Google Patents

Arc furnace ventral triangle area prefabricated component dedicated pouring material Download PDF

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CN109160808A
CN109160808A CN201811137923.6A CN201811137923A CN109160808A CN 109160808 A CN109160808 A CN 109160808A CN 201811137923 A CN201811137923 A CN 201811137923A CN 109160808 A CN109160808 A CN 109160808A
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parts
prefabricated component
arc furnace
fine powder
powder
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丁丰收
晁尚奎
李理想
丁家浩
李旭柯
许人杰
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REWELL REFRACTORY (ZHENGZHOU) CO Ltd
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REWELL REFRACTORY (ZHENGZHOU) CO Ltd
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    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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Abstract

The invention discloses a kind of arc furnace ventral triangle area prefabricated component dedicated pouring materials, it is by 20 ~ 35 parts, 10 ~ 25 parts of plate diamond spar, 15 ~ 32 parts of pink fused alumina of the high-purity bauxite of raw material, 3 ~ 5 parts of spinelle fine powder, 1.5 ~ 2.5 parts of kyanite, 5 ~ 9 parts of Reactive alumina, 1 ~ 3 part of chrome oxide green fine powder, 2 ~ 4 parts of silicon powder, 3.11 ~ 5.25 parts of bonding agent, 0.03 ~ 0.06 part of organic fiber, 0.5 ~ 1 part of stainless steel fibre is formulated.The present invention uses the grain size distribution of science to body particles material, ensure that triangle zone prefab has good elevated temperature strength and heat shaken stability;High-intensitive low-temperature setting combination liner body can be formed after the materials such as Spinel micropowder, pure calcium aluminate cement, activated alumina and the chrome oxide green of compound addition, moulding by casting and drying, ensure that the compactness and volume stability of prefabricated component;Pink fused alumina (Al in raw material2O3+ Cr2O3It >=95%) is the clinker for smelting electrofusion metal chromium, the use of the raw material can reduce product cost and reduce the discharge of industrial waste, effectively realize recycling for industrial waste.

Description

Arc furnace ventral triangle area prefabricated component dedicated pouring material
Technical field
The present invention relates to electric arc furnaces refractory materials, more particularly, to a kind of arc furnace ventral triangle area prefabricated component Special pouring Material feeding.
Background technique
Electric arc furnaces is one of important equipment used in smelting iron and steel.With the fast development of China's steel and iron industry, smelter Skill is also being constantly brought forth new ideas, and electric arc furnaces is also to enlargement and ultra high powerization development, and the requirement to the resistance to material of electric arc furnaces is also increasingly It is high.Arc furnace cover (also referred to as furnace roof) is a component of the utmost importance of electric arc furnaces, and service life height seriously affects the work of electric arc furnaces Industry rate, and large effect is generated to steel quality and safety in production.The structure of arc furnace cover is as shown in Figure 1, which is provided with Electrode hole and charging aperture, during its work, bell center (being commonly called as furnace roof trigonum) since structure bring is unfavorable, and Hyperthermia radiation and slag corrosion and hot and cold alternation vulnerable to electric arc recycle, and cause central area to be very easy to damage, in turn Cause entire bell overall structure unstable, damage is fast, reduces the service life of bell.Especially high-power and super high power Electric-arc furnace steelmaking increasingly increases so that arc furnace cover service life reduction is larger, so tradition adopt it is pre- by High-Alumina, magnalium matter etc. The bell trigonum that brickmaking is built into is no longer satisfied the requirement of electric-arc furnace steelmaking.
Summary of the invention
It is an object of the invention to for the short bad phenomenon of existing bell service life, provide a kind of consistency and intensity Height, good thermal shock stability, slag-resistant erosion performance is good, arc furnace ventral triangle with long service life area prefabricated component dedicated pouring Material.
To achieve the above object, the present invention can take following technical proposals:
Arc furnace ventral triangle of the present invention area prefabricated component dedicated pouring material, be by the high-purity bauxite of raw material, plate diamond spar, Pink fused alumina, spinelle fine powder, kyanite, Reactive alumina, chrome oxide green fine powder, silicon powder and bonding agent, organic fiber, Stainless steel fibre is formulated;Wherein
20 ~ 35 parts of high-purity bauxite, 10 ~ 25 parts of plate diamond spar, 15 ~ 32 parts of pink fused alumina, 3 ~ 5 parts of spinelle fine powder, kyanite 1.5 ~ 2.5 parts, 5 ~ 9 parts of Reactive alumina, 1 ~ 3 part of chrome oxide green fine powder, 2 ~ 4 parts of silicon powder, 3.11 ~ 5.25 parts of bonding agent, have 0.03 ~ 0.06 part of machine fiber, 0.5 ~ 1 part of stainless steel fibre.
The granularity of the rafifinal vanadine is 3 ~ 15mm;The granularity of plate diamond spar is 0.1 ~ 5mm;In the pink fused alumina, grain Spend the pink fused alumina particulate material 10 ~ 20 of 0.1 ~ 3mm, 5 ~ 12 parts of the pink fused alumina powder of 180 ~ 220 mesh of granularity.
The bonding agent by 3 ~ 5 parts of pure calcium aluminate cement, 0.06 ~ 0.15 part of sodium tripolyphosphate, calgon 0.05 ~ 0.1 part is formulated, wherein Al in pure calcium aluminate cement2O3≥69wt%。
To reduce cost, effective use industrial waste, the clinker for smelting electrofusion metal chromium is can be used in the pink fused alumina, wherein Al2O3>=85wt%, Cr2O3≥10%。
To guarantee that the quality of finished product prefabricated component meets requirement, in the raw materials used in the present invention, in high-purity bauxite Al2O3Content is 88 ~ 90wt%;Al in plate diamond spar2O3≥99wt%;The spinelle fine powder is 325 mesh, wherein Al2O3≥ 70wt%, MgO >=27wt%;The chrome oxide green fine powder is 325 mesh, wherein Cr2O3≥99wt%;The granularity of the kyanite fine powder For 80 mesh, wherein Al2O3≥55wt%;SiO in the silicon powder2≥95wt%。
304# stainless steel heat-resistant steel fibre can be used in the stainless steel fibre, and the organic fiber is that water-soluble low melting point has Machine fiber, JT-60 type water-soluble 60 DEG C of -70 DEG C of explosion-proof fibers, the Taian Shandongs produced such as Liaoyang Jin Tai chemical fibre Co., Ltd Water-soluble 80 DEG C of -90 DEG C of explosion-proof fibers of the JT-80 type of Ling Zhong composite material Co., Ltd production etc..
After above-mentioned each raw material are weighed by component, fine powder component is uniformly mixed spare;Strength is added in grain fraction Blender stirs 2 ~ 3min, adds mixing fine powders and stirs 5 ~ 6min, adds water 4 ~ 5% by raw material gross weight, continues after mixing evenly, It is cast into fetal membrane and is formed, vibrated in casting, casting process must be carried out continuously, to guarantee the densification of pour mass Property and globality.It spontaneously dries 24 hours and demoulds after casting complete, then 24 ~ 48h of natural curing, pour mass is finally packed into electricity and is added 20 DEG C ~ 350 DEG C baking 96h of hot baking room, obtain the pre- triangle zone prefab of arc furnace.
The pre- triangle zone prefab periphery faying face inclined surface with a narrow upper and lower width of molding furnace is prepared, it is directly embedded (edge of reserved location is in matched inclined surface) combines it naturally at furnace roof reserved location.
After tested, the technical indicator of the arc furnace ventral triangle area prefabricated component formed by a firing is as shown in table 1 below
The advantage of the invention is that using the grain size distribution of science to body particles material, it ensure that triangle zone prefab has very Good elevated temperature strength and heat shaken stability;Spinel micropowder, pure calcium aluminate cement, activated alumina and the chromium oxide of compound addition Green equal materials, can form high-intensitive low-temperature setting combination liner body after moulding by casting and drying, ensure that the densification of prefabricated component Property and volume stability;Pink fused alumina (Al in raw material2O3+ Cr2O3 It >=95%) is the clinker for smelting electrofusion metal chromium, the raw material Use can reduce product cost and reduce the discharge of industrial waste, effectively realize that industrial waste recycles.Its advantage It is embodied in following several points:
1, prefabricated component good integrity of the present invention, easy for installation, service life can achieve 300 ~ 1000 times, instead of traditional electric furnace The brickwork construction that ventral triangle area service life is 80 ~ 200 times avoids the defect that construction is slow, brickwork joint is more, globality is bad;
2, for the heated baking temperature that castable of the present invention uses for 150 DEG C ~ 350 DEG C, energy-saving effect is significant;And traditional electric furnace top Brick needs 1450 DEG C ~ 1600 DEG C high temperature firings, and energy consumption is high;
3, present invention science uses pink fused alumina (Al2O3+ Cr2O3 It >=95%) is raw material, and pink fused alumina is to smelt electrofusion metal The use of the clinker of chromium, the raw material can reduce product cost and reduce the discharge of industrial waste, effectively realize industrial waste It recycles;
4, the present invention is the entirety of one-time cast-forming, and convenient field replacement operation can effectively improve electric furnace steel making operation effect Rate reduces labor intensity;
5, long service life of the present invention can be such that raw material resources make full use of, and effectively reduce the discharge of industrial waste, product Using safe and environment-friendly.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of arc furnace cover.
Specific embodiment
More detailed explanation is done to the present invention below by specific embodiment, in order to the reason of those skilled in the art Solution.
Embodiment 1 fires 30 tons of arc furnace cover triangle zone prefabs (portion A in Fig. 1)
Its parts by weight of raw materials proportion are as follows:
35 parts of the high-purity aluminum-vanadium soil particle material of 3 ~ 15mm of granularity, 15 parts of the plate diamond spar particulate material of 0.1 ~ 5mm of granularity, granularity 20 parts of the pink fused alumina particulate material of 0.1 ~ 3mm, 180 ~ 220 11 parts of mesh pink fused alumina powders, 3 parts of spinelle fine powder, chrome oxide green fine powder 1 Part, 80 1.5 parts of mesh aquamaine mountain flours, 2 μm 5 parts of activated alumina powder, 0.7 μm 3.5 parts of silicon powder, 5 parts of pure calcium aluminate cement, three 0.15 part of polyphosphate sodium, 0.05 part of calgon, 1 part of 304# stainless steel fibre, 0.06 part of JT-80 organic fiber.
It fires: by above-mentioned raw material according to parts by weight precise, first by pink fused alumina powder, spinelle fine powder, chrome oxide green Fine powder, aquamaine mountain flour, activated alumina powder, silicon powder, pure calcium aluminate cement, sodium tripolyphosphate, calgon and organic Fiber is sufficiently mixed spare.Then surplus stock is entered to mix in machine,massing 2min, then pour into the fine powder material mixed and stir Mix 5min, the drinking water that material gross weight 4.6% is added after mixing continues to stir, it is to be mixed uniformly after pour into mold, side vibration Side batch turning, until surface is smooth, casting is can be completed in no pitted skin.Then natural curing demoulds afterwards for 24 hours, spontaneously dries after demoulding For 24 hours, it enters back into electric heating baking room to be toasted, is set as 20 DEG C ~ 350 DEG C according to heating curve baking temperature, toasts 96h, Obtain the pre- triangle zone prefab finished product of arc furnace.
After measured, the technical parameter of finished product prefabricated component is as follows:
Embodiment 2 fires 60 tons of arc furnace cover triangle zone prefabs
Its parts by weight of raw materials proportion are as follows:
30 parts of the high-purity aluminum-vanadium soil particle material of 3 ~ 15mm of granularity, 20 parts of the plate diamond spar particulate material of 0.1 ~ 5mm of granularity, granularity 20 parts of the pink fused alumina particulate material of 0.1 ~ 3mm, 180 ~ 220 8 parts of mesh pink fused alumina powders, 4 parts of spinelle fine powder, chrome oxide green fine powder 2 Part, 80 2 parts of mesh aquamaine mountain flours, 2 μm 7 parts of activated alumina powder, 0.7 μm 3 parts of silicon powder, 4 parts of pure calcium aluminate cement, trimerization phosphorus 0.15 part of sour sodium, 0.05 part of calgon, 1 part of 304# stainless steel fibre, 0.06 part of JT-80 organic fiber.
It fires: by above-mentioned raw material according to parts by weight precise, first by pink fused alumina powder, spinelle fine powder, chrome oxide green Fine powder, aquamaine mountain flour, activated alumina powder, silicon powder, pure calcium aluminate cement, sodium tripolyphosphate, calgon and organic Fiber is sufficiently mixed spare.Then surplus stock is entered to mix in machine,massing 2min, then pour into the fine powder material mixed and stir Mix 5min, the drinking water that material gross weight 4.2% is added after mixing continues to stir, it is to be mixed uniformly after pour into mold, side vibration Side batch turning, until surface is smooth, casting is can be completed in no pitted skin.Then natural curing demoulds afterwards for 24 hours, spontaneously dries after demoulding 36h enters back into electric heating baking room and is toasted, and is set as 20 DEG C ~ 350 DEG C according to heating curve baking temperature, toasts 96h, Obtain the pre- triangle zone prefab finished product of arc furnace.
After measured, the technical parameter of finished product prefabricated component is as follows:
Embodiment 3 fires 100 tons of arc furnace cover triangle zone prefabs
Its parts by weight of raw materials proportion are as follows:
20 parts of the high-purity aluminum-vanadium soil particle material of 3 ~ 15mm of granularity, 25 parts of the plate diamond spar particulate material of 0.1 ~ 5mm of granularity, granularity 25 parts of the pink fused alumina particulate material of 0.1 ~ 3mm, 180 ~ 220 5.5 parts of mesh pink fused alumina powders, 5 parts of spinelle fine powder, chrome oxide green fine powder 3 parts, 80 2.5 parts of mesh aquamaine mountain flours, 2 μm 9 parts of activated alumina powder, 0.7 μm 2 parts of silicon powder, 3 parts of pure calcium aluminate cement, three 0.15 part of polyphosphate sodium, 0.05 part of calgon, 1 part of 304# stainless steel fibre, 0.06 part of JT-80 organic fiber.
It fires: by above-mentioned raw material according to parts by weight precise, first by pink fused alumina powder, spinelle fine powder, chrome oxide green Fine powder, aquamaine mountain flour, activated alumina powder, silicon powder, pure calcium aluminate cement, sodium tripolyphosphate, calgon and organic Fiber is sufficiently mixed spare.Then surplus stock is entered to mix in machine,massing 2min, then pour into the fine powder material mixed and stir Mix 5min, the drinking water that material gross weight 4.4% is added after mixing continues to stir, it is to be mixed uniformly after pour into mold, side vibration Side batch turning, until surface is smooth, casting is can be completed in no pitted skin.Then natural curing demoulds afterwards for 24 hours, spontaneously dries after demoulding 48h enters back into electric heating baking room and is toasted, and is set as 20 DEG C ~ 350 DEG C according to heating curve baking temperature, toasts 96h, Obtain the pre- triangle zone prefab finished product of arc furnace.
After measured, the technical parameter of finished product prefabricated component is as follows:
Test proves that prefabricated component good integrity of the present invention, easy for installation, service life can achieve 300 ~ 1000 times, can be complete Meet the requirement of electric-arc furnace steelmaking.

Claims (6)

1. a kind of arc furnace ventral triangle area prefabricated component dedicated pouring material, it is characterised in that: be by the high-purity bauxite of raw material, plate It is corundum, pink fused alumina, spinelle fine powder, kyanite, Reactive alumina, chrome oxide green fine powder, silicon powder and bonding agent, organic Fiber, stainless steel fibre are formulated;Wherein
20 ~ 35 parts of high-purity bauxite, 10 ~ 25 parts of plate diamond spar, 15 ~ 32 parts of pink fused alumina, 3 ~ 5 parts of spinelle fine powder, kyanite 1.5 ~ 2.5 parts, 5 ~ 9 parts of Reactive alumina, 1 ~ 3 part of chrome oxide green fine powder, 2 ~ 4 parts of silicon powder, 3.11 ~ 5.25 parts of bonding agent, have 0.03 ~ 0.06 part of machine fiber, 0.5 ~ 1 part of stainless steel fibre.
2. arc furnace ventral triangle according to claim 1 area prefabricated component dedicated pouring material, it is characterised in that: described high-purity The granularity of aluminium vanadine is 3 ~ 15mm;The granularity of plate diamond spar is 0.1 ~ 5mm;In the pink fused alumina, the pink fused alumina of 0.1 ~ 3mm of granularity 10 ~ 20 parts of particulate material, 5 ~ 12 parts of the pink fused alumina powder of 180 ~ 220 mesh of granularity.
3. arc furnace ventral triangle according to claim 1 area prefabricated component dedicated pouring material, it is characterised in that: the combination By 3 ~ 5 parts of pure calcium aluminate cement, 0.06 ~ 0.15 part of sodium tripolyphosphate, 0.05 ~ 0.1 part of calgon is formulated for agent, wherein Al in pure calcium aluminate cement2O3≥69wt%。
4. arc furnace ventral triangle according to claim 1 area prefabricated component dedicated pouring material, it is characterised in that: the chromium is rigid Jade is the clinker for smelting electrofusion metal chromium, wherein Al2O3>=85wt%, Cr2O3 ≥10%。
5. arc furnace ventral triangle according to claim 1 area prefabricated component dedicated pouring material, it is characterised in that: described high-purity Al in bauxite2O3Content is 88 ~ 90wt%;Al in plate diamond spar2O3≥99wt%;The spinelle fine powder is 325 mesh, wherein Al2O3>=70wt%, MgO >=27wt%;The chrome oxide green fine powder is 325 mesh, wherein Cr2O3≥99wt%;The kyanite is thin The granularity of powder is 80 mesh, wherein Al2O3≥55wt%;SiO in the silicon powder2≥95wt%。
6. arc furnace ventral triangle according to claim 1 area prefabricated component dedicated pouring material, it is characterised in that: described stainless Steel fibre is 304# stainless steel heat-resistant steel fibre, and the organic fiber is water-soluble low melting point organic fiber.
CN201811137923.6A 2018-09-28 2018-09-28 Arc furnace ventral triangle area prefabricated component dedicated pouring material Pending CN109160808A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111592367A (en) * 2020-06-05 2020-08-28 郑州市瑞沃耐火材料有限公司 Anhydrous stemming for blast furnace taphole
CN111848187A (en) * 2020-07-08 2020-10-30 甘肃酒钢集团宏兴钢铁股份有限公司 Method for preparing iron ladle castable by using high-carbon ferrochrome slag
RU210483U1 (en) * 2021-10-26 2022-04-18 Общество с ограниченной ответственностью "Кералит" THE CENTRAL PART OF THE COVER OF THE ARC STEEL-MELTING FURNACE

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CN104591757A (en) * 2015-02-04 2015-05-06 郑州市瑞沃耐火材料有限公司 Low-temperature curing abrasion-resistant pouring material
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CN106995310A (en) * 2017-03-17 2017-08-01 周九喜 A kind of wear-resisting high-strength degree aluminum electric furnace cover and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN104591757A (en) * 2015-02-04 2015-05-06 郑州市瑞沃耐火材料有限公司 Low-temperature curing abrasion-resistant pouring material
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Application publication date: 20190108