CN109154132A - Functional fiber and its manufacturing method - Google Patents
Functional fiber and its manufacturing method Download PDFInfo
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- CN109154132A CN109154132A CN201680085873.4A CN201680085873A CN109154132A CN 109154132 A CN109154132 A CN 109154132A CN 201680085873 A CN201680085873 A CN 201680085873A CN 109154132 A CN109154132 A CN 109154132A
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- fibrous material
- functional fiber
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
Abstract
There is provided can maintain excellent heat insulating ability and deodorizing antibiotic without the functional fiber and its manufacturing method that reduce absorb-discharge humid and can effectively obtain for a long time.Functional fiber has the function of to impart the fibrous material of infrared emission and deodorizing antibiotic function.At least part surface of fibrous material is bonded to for the film of the elastomer silicone of 1~10 μm of aluminium oxide particles containing average grain diameter.The film of elastomer silicone as principal component and has siloxane backbone using the polyoxyethylene alkyl ether of carbon number 12~15.
Description
Technical field
The present invention relates to the functional fibers and its manufacturing method that impart infrared emission function and deodorizing antibiotic function.
Background technique
Method as the heat insulating ability for improving fibrous material, it is known to utilize adsorption moisture and the hygroscopic heating fibers of fever
(for example, referring to Japanese Unexamined Patent Publication 2014-9408 bulletin) makes fibrous material fluff or be inserted into plumage between fibrous material
Hairs etc. are to form the thermal insulation layer containing air (for example, referring to Japanese Unexamined Patent Publication 2013-177721 bulletin).
Summary of the invention
But even if using hygroscopic heating fibers, it, will not be into one if the moisture absorption based on the fiber becomes saturation state
Step fever, therefore the duration to generate heat is low.In addition, for example, being adsorbed in this in the case that hygroscopic heating fibers are used for clothes
The moisture not moisture releasing on the surface of fiber and become bored, to bring the worry of sticky feeling to wearer.In turn, it is adsorbed in fiber
The worry freezed of moisture.Therefore it is unsuitable for the use in extremely cold place.
In the case where forming thermal insulation layer by fluffing, which is easy to fall off from fibrous material by washing etc., therefore
It is difficult to improve heat insulating ability for a long time.In addition, thering is fibrous material volume to become larger if forming thermal insulation layer by feather etc., in the family
The problem of washing becomes difficult.
In addition, in recent years, it is expected that being improved the heat insulating ability of fibrous material and imparting the function of deodorizing antibiotic function
Property fiber separately carry out assigning deodorization anti-but in this case, need on the basis of above-mentioned such method for improving heat insulating ability
The processing of bacterium function.Therefore, the miscellaneous worry of the manufacturing process of functional property fiber.
The present invention allows for such problems and makes, it is intended that excellent guarantor can be maintained for a long time by providing
Warm nature and deodorizing antibiotic are without the functional fiber and its manufacturing method that reduce absorb-discharge humid and can effectively obtain.
In order to achieve the above objectives, the present invention is a kind of functional fiber, which is characterized in that it, which has, imparts infrared ray
The fibrous material of radiation function and deodorizing antibiotic function, at least part surface of the fibrous material are fixed with containing average grain
The film of the elastomer silicone for the aluminium oxide particles that diameter is 1~10 μm, the film of the elastomer silicone is with carbon number 12~15
Polyoxyethylene alkyl ether is principal component and has siloxane backbone.
Aluminium oxide particles particularly good absorb 8~14 μm in the infrared ray (3~50 μm) by human body radiation of range simultaneously
It releases again.That is, effectively utilizing by the infrared ray (heat of human body, the radiation of other heat sources) and generate heat infrared emission
Function.In addition, aluminium oxide particles have deodorization to ammonia, isovaleric acid, the nonenyl aldehyde (one Le of ノ ネ Na) etc. the reason of becoming stench
Function, and to staphylococcus aureus (Staphylococcus aureus), Morakot this Salmonella (Moraxella), green pus
Bacillus (Pseudomonas aeruginosa) etc. has antibacterial functions.Therefore, functional fiber of the invention is by having oxygen
Change aluminum particulate, so as to assign infrared emission function and can assign deodorizing antibiotic function, there is no need to difference one by one
These functions are assigned, can effectively be obtained.
In addition, by the way that the average grain diameter of aluminium oxide particles is set as above-mentioned range, to even if aluminium oxide particles be made to consolidate
In fibrous material, also can be avoided the flexibility of the fibrous material, feel reduces.In addition, even if utilizing above-mentioned organosilicon
The film of elastomer makes such aluminium oxide particles be bonded to the surface of fibrous material, the volume of the fibrous material will not increase,
Absorb-discharge humid will not reduce.
In turn, the film of above-mentioned elastomer silicone can follow the deformation of fibrous material and stretch comfortablely, therefore can
Maintain the state for being bonded to the surface of the fibrous material securely.Therefore, even washing when in water, in medicament to fiber
In the case that material applies frictional force etc., it is also able to suppress sur-face peeling of the elastomer silicone from the fibrous material.Pass through this
Sample makes the film for the elastomer silicone for being bonded to fibrous material securely contain aluminium oxide particles, thus attached by the aluminium oxide particles
For the above-mentioned function of adding there is a situation where reducing to be suppressed due tos washing of functional fiber etc., duration is also excellent.
According to the above, which has sufficient absorb-discharge humid, and can maintain excellent guarantor for a long time
Warm nature and deodorizing antibiotic, and can effectively obtain.
In addition, the present invention is a kind of manufacturing method of functional fiber, which is characterized in that the functional fiber, which has, to be assigned
The fibrous material of infrared emission function and deodorizing antibiotic function is given, the manufacturing method, which includes, soaks the fibrous material
Stain in the process of aqueous liquid dispersion, the aqueous liquid dispersion be make with the polyoxyethylene alkyl ether principal component of carbon number 12~15,
And the aluminium oxide particles that the particle and average grain diameter of the elastomer silicone with siloxane backbone are 1~10 μm disperse
's；And make by heat be crosslinked between the particle to the elastomer silicone made of it is membranaceous and include
The process that the elastomer silicone of the aluminium oxide particles is bonded at least part surface of the fibrous material.
By passing through above-mentioned process, it can effectively obtain having both effectively utilizing and be radiated by human body, other heat sources
Infrared ray and excellent heat insulating ability and to the deodorization of ammonia, isovaleric acid, nonenyl aldehyde etc. and to golden yellow Portugal obtained from generating heat
The functional fiber of the antibiotic property of grape coccus, Morakot this Salmonella, Pseudomonas aeruginosa etc..
In addition, even if making the oxidation aluminum shot that average grain diameter is set as to above range using the film of above-mentioned elastomer silicone
Son is bonded to fibrous material, is also able to suppress the flexibility of the fibrous material, feel reduces, the volume of fibrous material is inhibited to increase
Greatly and absorb-discharge humid is inhibited to reduce.In turn, due to make to be bonded to securely fibrous material elastomer silicone film containing aerobic
Change aluminum particulate, therefore excellent by the duration of the additional above-mentioned function of the aluminium oxide particles.
In accordance with the invention it is possible to effectively obtain having sufficient absorb-discharge humid and excellent heat preservation can be maintained for a long time
The functional fiber of property and deodorizing antibiotic.
Detailed description of the invention
Fig. 1 is the schematic structural diagram for carrying out the measurement device of infrared emission function test.
Specific embodiment
Hereinafter, being directed to functional fiber of the invention, embodiment appropriate is enumerated about the manufacturing method for manufacturing it, in detail
Carefully it is illustrated.
Functional fiber of the invention has the function of to impart as described later infrared emission and deodorizing antibiotic function
Fibrous material.The type of the fibrous material is not particularly limited, and can only be made of natural series fiber or only by synthetic fibers structure
At also may include both above-mentioned.
Natural series fiber can be only cellulose fibre or only animal origin, also may include both above-mentioned.As
Representative cellulose fibre can enumerate the cotton (kapok) as natural plant fibre, or ramie, linen
(linen), the fiber crops such as hemp (hemp), jute, abaca, sisal hemp.In addition, cellulose fibre may be by natural fiber
Element is configured to so-called regenerated fiber obtained from threadiness after being dissolved with defined solvent.As the specific of this regenerated fiber
Example, can enumerate artificial silk, polynosic (Polynosic), copper ammonia fiber, Tencel (Austrian measurement company
The registered trademark of (Ranging Inc.)).
As the typical example of animal origin, wire vent, wool or animal fiber can be enumerated.It is fine as specific animal wool
Dimension can exemplify alpaca fibre, mohair yarn (mohair), Angola hair (angola), cashmere (cashmere), camel's hair
(camel), lamb camel's hair (vicuna) etc..
As an example of synthetic fibers, can enumerate polyester, acrylic, polyurethane, fatty polyamide series fiber (including
6- nylon, 6,6- nylon), aromatic polyamide series fiber etc..
The shape of fibrous material is not particularly limited, such as can enumerate cotton, rescutched tow (tow), long filament, sliver
(sliver), silk, non-woven fabrics, fabric, braided fabric, towel, paper etc..
The ratio of cellulose fibre, animal origin, synthetic fibers in fibrous material is also not particularly limited, Ke Yishe
It is set to desired ratio.
It is fixed for the film of the elastomer silicone of 1~10 μm of aluminium oxide particles containing average grain diameter in functional fiber
In at least part surface of fibrous material.It should be noted that average grain diameter can pass through commercially available particle size analyzing device etc.
It is measured, for example, at can be using accumulated value 50% (D50) in the size distribution found out by laser diffraction/scattering method
Partial size.
Aluminium oxide particles particularly good absorb 8~14 μm in the infrared ray (3~50 μm) by human body radiation of range simultaneously
It releases again.That is, having the function of to effectively utilize by the infrared emission of human body, the infrared ray of other heat sources radiation and fever.Separately
Outside, aluminium oxide particles have deodorization functions to ammonia, isovaleric acid, the nonenyl aldehyde etc. the reason of becoming stench, and to golden yellow Portugal
Grape coccus, Morakot this Salmonella, Pseudomonas aeruginosa etc. have antibacterial functions.
The film of elastomer silicone as principal component and has siloxanes bone using the polyoxyethylene alkyl ether of carbon number 12~15
Frame.Specifically, the film of elastomer silicone is the porosity with multiple micropores (microporous), has scale shape
Surface.The film of the elastomer silicone mainly passes through the surface that the mechanisms such as anchoring effect are bonded to fibrous material.
Then, about the manufacturing method of present embodiment, to the functional fiber for obtaining substantially constituting as described above
Process be illustrated.
Firstly, making with the polyoxyethylene alkyl ether principal component of carbon number 12~15 and there is the organic of siloxane backbone
The particle and average grain diameter of silicone elastomer are that 1~10 μm of aluminium oxide particles are scattered in the aqueous dispersion mediums such as water, prepare water
Property dispersion liquid.As this aqueous liquid dispersion, (can be believed by the way that the trade name " X-51-1318 " of suitable concentration will be adjusted to
The more silicon emulsion of chemical industry Co. Ltd. system) etc. commercially available products and trade name " KB-ASN " (oxygen of Li Tian Chemical Co., Ltd
Change 20% dispersion of aluminum particulate) etc. commercially available products mixing to obtain.
After fibrous material to be impregnated in the aqueous liquid dispersion prepared as described above, carry out liquid discharge (compared with liquid).Thereafter,
The fibrous material being dried is heated, the particle of elastomer silicone is made to be cross-linked to each other.Thereby, it is possible to
The film of the elastomer silicone containing aluminium oxide particles is formed, and the film mainly passes through anchoring effect and is bonded to fiber securely
The surface of material.
The existing heating equipment such as heat setter can be used to carry out, preferably by using water in the heat treatment
The gas of steam steams setting to carry out.In this case, for example, making the grain of elastomer silicone using 100 DEG C of saturated vapors below
Son crosslinking, therefore can obtain further improving the functional fiber of flexibility.In addition, for the saturated vapor, such as even if
Also be able to enter for the mutual gap of fibrous material of overlap condition, thus can the entirety to fibrous material have with not laying particular stress on
Effect ground supply heat.
Therefore, it in the case where fibrous material is Filamentous, carries out gas steaming setting and is particularly suitable.Even that is, in silk
In the case that the fiber roll of shape is heated in the state of, also heat can be made throughout to wound interior using saturated vapor
The fibrous material of side, therefore the film of organic silicone elastomer can be effectively formed.
In addition, the atmosphere around fibrous material is filled up by saturated vapor in the case where carrying out gas steaming setting, so as to
The generation etc. of inhibitory activity oxygen.Avoided the function of damage, embrittlement caused by the influence of active oxygen etc. well as a result,
Property fiber.
It can be only by operating and being fixed with the fiber of the film of the elastomer silicone containing aluminium oxide particles as described above
Material constitutes functional fiber, can also combine the fibrous material and other fibers and constitute functional fiber.
Functional fiber obtained from process more than is put by having aluminium oxide particles so as to assign infrared ray
It penetrates function and deodorizing antibiotic function can be assigned.That is, the functional fiber without assigning infrared emission function one by one respectively
It can effectively be obtained with deodorizing antibiotic function.
In addition, by the way that the average grain diameter of aluminium oxide particles is set as above-mentioned range, to even if aluminium oxide particles be made to consolidate
In fibrous material, also can be avoided the flexibility of the fibrous material, feel reduces.In addition, even if utilizing above-mentioned organosilicon
The film of elastomer makes such aluminium oxide particles be bonded to the surface of fibrous material, is also able to suppress the volume increasing of the fibrous material
Greatly, absorb-discharge humid is inhibited to reduce.
In turn, the film of above-mentioned elastomer silicone can follow the deformation of fibrous material and stretch comfortablely, therefore can
Maintain the state for being bonded to the surface of the fibrous material securely.Therefore, even washing when in water, in medicament to fiber
In the case that material applies frictional force etc., it is also able to suppress sur-face peeling of the elastomer silicone from the fibrous material.Pass through this
Sample makes the film for the elastomer silicone for being bonded to fibrous material securely contain aluminium oxide particles, thus attached by the aluminium oxide particles
For the above-mentioned function of adding there is a situation where reducing to be suppressed due tos washing of functional fiber etc., duration is also excellent.
According to the above, which can maintain excellent heat insulating ability and deodorizing antibiotic, Er Qieke for a long time
Effectively obtain.
In addition, as described above, the film of elastomer silicone, which mainly passes through the mechanisms such as anchoring effect, is bonded to undulation degree
The surface of material.Thus, for example, in the case that fibrous material uses natural series fiber, most of functions in the natural series fiber
Group exists with the state for not generating the chemical bonds such as covalent bond with the film of elastomer silicone.Therefore, functional fiber is contaminated
When color, the functional group in natural series fiber can sufficiently react with dyestuff, can be avoided uneven color and catch dye well
Material.Even in addition, in water, in the case wheres apply frictional force etc. to hydrophobization fiber in medicament, can also press down in dyeing
Sur-face peeling of the film of elastomer silicone processed from natural series fiber.
That is, dyeability is excellent, is also easy in the case that functional fiber has the fibrous material being made of natural series fiber
Carry out piece dyeing.As a result, it is possible to using functional fiber as stock in the state of being unstained, not sewing, based in sight
The information for the popular colour collected before sale is dyed, is sewed etc. with its original sample, to rapidly carry out fiber system
Product.That is, the commodity for accurately capturing vertiginous popular colour, popular pattern can be provided within short delivery date, reduce
Bad inventory can make the sewing product that functional fiber is utilized cost effective to realize the effective use of resource.
Having enumerated embodiment appropriate among the above, the present invention will be described, but the present invention is not limited to above-mentioned embodiment party
Formula, it is of course possible to carry out various changes without departing from the scope of the subject in the invention.
Embodiment
Hereinafter, being described in detail by embodiment to the present invention, but the present invention is not limited to these embodiments.
To obtained from the film of elastomer silicone of the formation containing aluminium oxide particles on fibrous material as shown below
The embodiment of functional fiber is illustrated.
Fabric A1, braided fabric A2 is made in the form of the fibrous material formed by the raw material A of cotton 100%.A1 is to be made to make
With 173 pieces/inch of the organizine of 60 monofilament, 84 pieces/inch of tram of satin fabric of 40 monofilament is used.A2 is single using 40
The round rib-loop knitting (Off ラ イ ス) of 30 inches of 18 needle is made in silk.
Braided fabric will be made in the form of the fibrous material that raw material B made of 80 to 20 is blended is formed by cotton and Tencel
B1.B1 is the round rib-loop knitting that 18 inches of 19 needle is made using 40 monofilament.
In these fibrous materials, desizing/concise, bleaching is carried out first to A1.In addition, respectively being moved back first to A2, B1
Slurry/concise, bleaching, dehydration, drying.
Then, it is impregnated in above-mentioned fibrous material respectively comprising above-mentioned " X-51-1318 " 30g/L and above-mentioned
After aqueous liquid dispersion prepared by the mode of " KB-ASN " 50g/L, liquid discharge is carried out.Make the aqueous liquid dispersion of attachment as a result,
Weight is 70% relative to the ratio (pick-up rate) of the weight of the fibrous material before dipping.Use the heat setter pair of day star corporation
These fibrous materials carry out 1 point of drying process in 30 seconds at 150 DEG C.
Then, in the fibrous material after drying process, for A1, using the baking machine of Shandong Engineering Co., Ltd,
After carrying out heat treatment in 2 minutes at 170 DEG C, implements shrink-resistant finish, obtain functional fiber.On the other hand, for A2, B1,
Using above-mentioned heat setter, heat treatment in 2 minutes is carried out at 170 DEG C, obtains functional fiber.
Obtained functional fiber will be operated in this way as embodiment.On the other hand, will not have above-mentioned containing to aoxidize
The fibrous material of the film of the elastomer silicone of aluminum particulate is as comparative example.
<infrared emission function>
Fibrous material A1, A2 of fibrous material (functional fiber) A1, A2, B1 and comparative example to the above embodiments,
B1 carries out infrared emission function test using measurement device 10 shown in FIG. 1.Measurement device 10 has the 1st sink 12, heating
Device 14, the 2nd sink 16, container 18 and moisture recorder 20.Heater 14 is arranged in the inside of the 1st sink 12, utilizes the heating
The temperature for the warm water being stored in the 1st sink 12 is maintained 35 DEG C~38 DEG C of the body temperature for being equivalent to people by device 14.
2nd sink 16 is disposed in the 1st sink 12 in such a way that the water surface of opening portion periphery from the 1st sink 12 is outstanding.
The warm water being stored in the 2nd sink 16 as a result, is maintained temperature identical with the warm water being stored in the 1st sink 12.
Container 18 is formed by stainless steel (SUS430, SUS410), and swims in the water surface of the 2nd sink 16.In container 18
The bottom surface of inside attaches the fabric 22 of polyester, and the test film 24 and comparative example of the fibrous material of embodiment are loaded on the fabric 22
Fibrous material test film 26.In this way by between the bottom surface of container 18 and test film 24,26 across fabric 22, so as to
It is enough hot without unevenly transmitting to test film 24,26 from the warm water being stored in the 2nd sink 16.
Moisture recorder 20 have infrared camera, the infrared camera from 22 opposite sides of fabric to institute as above
The test film 24,26 being placed on stating in container 18, can measure the temperature change of the test film 24,26 at regular intervals.It needs
It is noted that model " FLIR E60 " of the moisture recorder 20 using FLIR Systems Japan K.K..
Using the measurement device 10, the temperature (X) of the test film 24 of embodiment, the test film 26 of comparative example are measured respectively
The surface temperature of temperature (Y) and the warm water in the 2nd sink 16.By their measurement result and the reality calculated by the measurement result
The difference (X-Y) for applying the temperature (Y) of the temperature (X) of the test film 24 of example and the test film 26 of comparative example is shown in table 1.
[table 1]
According to table 1, the test film 24 of embodiment all shows the examination higher than comparative example in any heating time
Test the temperature of piece 26.Therefore, the functional fiber of present embodiment is same by the infrared ray for absorbing with being radiated well by human body
The infrared ray of the wavelength of sample is simultaneously released again, shows excellent heat insulating ability.
<deodorization>
To the coupons of the B1 of embodiment, the evaluation of the deodorization to ammonia, isovaleric acid, nonenyl aldehyde is carried out.Deodorization to ammonia
Property measured as follows according to instrument analysis (detection tube method) specified in general civic organization's fibre technology evaluation consultation.It needs
It is noted that before washing coupons and by above-mentioned washing methods carried out 100 times washing after coupons this two
Person carries out measurement below.
It is sealed firstly, coupons 2.4g is put into the Taide pulling bag (Tedlar bag) of 5L.Then, using injection
Stink odor gas 3L is injected into the pulling bag of Taide to become defined initial concentration by device.It is small to inject stink odor gas 2
Shi Hou is measured by concentration of the detection pipe to the stink odor gas of Taide pulling bag.In addition to coupons not being put into Taide
It other than in pulling bag, is subjected to the same test (blank test), the slip of stink odor is found out by following formula (1).Ammonia it is initial
Concentration is 100ppm.
Slip (%)={ (measurement when having used sample behind measured value -2 hours of the blank test after 2 hours
Value)/blank test after 2 hours measured value × 100... (1)
Gas specified in consultation is evaluated according to general civic organization's fibre technology to the deodoriging properties of isovaleric acid, nonenyl aldehyde
Phase chromatography is evaluated as follows.Coupons 1.2g is put into the conical flask of 500mL, to become defined initial concentration
Mode the ethanol solution of stink odor is added dropwise and is sealed.It is sampled after 2 hours using syringe, utilizes gas chromatograph
The concentration of instrument measurement stink odor.Other than coupons not being put into conical flask, it is subjected to the same test (blank examination
Test), the slip of stink odor is found out by above-mentioned formula (1).In addition, isovaleric acid and the respective initial concentration of nonenyl aldehyde are about
14ppm、4ppm。
Above test result is shown in table 2.
[table 2]
According to table 2, the functional fiber of present embodiment is equal to stink odor any in ammonia, isovaleric acid, nonenyl aldehyde
Show sufficient deodorization.In addition we know, which can sufficiently maintain even if having carried out after 100 washings
Above-mentioned deodorization continues excellent deodorization.
<antibiotic property>
To the coupons of the B1 of embodiment, the antibacterial to staphylococcus aureus, Pseudomonas aeruginosa, Morakot this Salmonella is evaluated
Property.Specifically, the evaluation passes through JIS L 1902:2008 " the antibiotic property test method and antibacterial effect of fibre " 10.1
Bacterium solution absorption process measures bactericidal activity value.It should be noted that the coupons before washing and passing through above-mentioned washing methods
Both coupons after having carried out 100 washings carry out the measurement.Measurement result about bactericidal activity value is shown in table 3.
It should be noted that in the case that bactericidal activity value is 0 or more, it is believed that have fungistatic effect.
[table 3]
According to table 3, the functional fiber of present embodiment is 0 or more to the bactericidal activity value of above-mentioned any bacterium,
Even if bactericidal activity value is also maintained in above-mentioned range after having carried out 100 washings.That is, the functional fiber show it is excellent
Different antibiotic property, and the antibiotic property can be continuously available.
<absorb-discharge humid>
To the B1 in the fibrous material of Examples and Comparative Examples, according to general juridical person Fang Jian quality evaluation mechanism
BOKEN method evaluates absorb-discharge humid (moisture rate).Specifically, firstly, by the examination for the above-mentioned fibrous material that 20cm square is made
It tests piece to expose to the open air in the environment of 40 DEG C × 90% (RH) 4 hours, thus makes the test film moisture absorption.Thereafter, 20 DEG C × 65%
(RH) it is exposed to the open air in the environment of 4 hours, thus makes test film moisture releasing.At this point, every weight (g) Jing Guo 1 hour measurement test piece, by
The variation of the weight finds out absorb-discharge humid (moisture rate) (%).It the results are shown in table 4.It should be noted that 40 DEG C × 90%
(RH) environment is the high temperature and humidity state of the temperature and humidity in clothes when slightly moving close to people.20 DEG C × 65% (RH)
Environment be close to outside air temperature standard state.
[table 4]
According to table 4, the absorb-discharge humid of the fibrous material of the absorb-discharge humid and comparative example of the fibrous material of embodiment is
Same degree.That is, the functional fiber of present embodiment can assign infrared emission function and deodorizing antibiotic function without dropping
The original absorb-discharge humid of low fibrous material.
<rapid-drying properties>
In order to evaluate rapid-drying properties, rapid-drying properties as shown below are carried out to the B1 in the fibrous material of Examples and Comparative Examples and are tried
It tests.
Firstly, measurement makes weight of the test film of the B1 of Examples and Comparative Examples under 105 ° after drying 2 hours (after dry
Fibrous material weight).Then, these tests are washed using the household electricity rinsing maching " VH-30S " of Toshiba Corporation
Piece.Specifically, in a manner of becoming 1kg relative to water 30L measurement sample, i.e. in a manner of as 1 to 30 bath raio, by water
And measurement sample is put into sink.At this point, water temperature is set as 30~40 DEG C.In addition, being set as strong water for wash conditions
It flows and 1 washing is made to be 30 minutes.
Thereafter, measurement has carried out 5 minutes dewatered weight (fibrous material weight after dehydration).Then, by the test
Piece makes it dry the interior extension that temperature is 25 ° ± 1 °, humidity is 55% ± 5% (RH) is dry.At this point, every survey by the stipulated time
Determine the weight (hanging fibrous material weight in dry) of test film.
After above-mentioned drying fibrous material weight and dehydration after fibrous material weight difference be dewatered test film contained by
The weight (moisture weight after dehydration) of some moisture.Therefore, the moisture containing ratio of test film when extension dry drying time is 0 minute
(%) is fibrous material weight (g) after moisture weight (g)/drying after dehydration.In addition, each test film for hanging dry drying time
Moisture containing ratio (%) is fiber after (fibrous material weight (g) after fibrous material weight (g)-is dry in extension drying)/drying
Material weight (g).To the moisture containing ratio of the test films of the Examples and Comparative Examples calculated in this way with hang together with dry drying time
It is shown in table 5.
[table 5]
According to table 5, firstly, at the time of extension dry drying time is 0 minute, in the state of only dehydration, embodiment
Fibrous material moisture containing ratio lower than comparative example fibrous material moisture containing ratio.Thus, it can be known that present embodiment
Functional fiber, which is inhibited, absorbs water when washing washing to which there is a situation where be swollen.
In addition, for moisture containing ratio reduces the dry drying time of extension needed for 10%, the fibrous material of embodiment
It is 83.0 minutes, and the fibrous material of comparative example is 107.0 minutes.That is, the extension of the fibrous material of embodiment does drying time phase
Drying time dry for the extension of the fibrous material of comparative example shortens 20%.Therefore, the functional fiber of present embodiment with not
The fibrous material of processing is compared, and can be improved rapid-drying properties.
Claims (2)
1. a kind of functional fiber, which is characterized in that it has the function of to impart the fibre of infrared emission and deodorizing antibiotic function
Material is tieed up,
The aluminium oxide particles that it is 1 μm~10 μm containing average grain diameter that at least part surface of the fibrous material, which is fixed with, have
The film of machine silicone elastomer,
The film of the elastomer silicone as principal component and has siloxanes bone using the polyoxyethylene alkyl ether of carbon number 12~15
Frame.
2. a kind of manufacturing method of functional fiber, which is characterized in that the functional fiber, which has, imparts infrared emission
The fibrous material of function and deodorizing antibiotic function,
The manufacturing method includes
The process that the fibrous material is impregnated in aqueous liquid dispersion, the aqueous liquid dispersion are made with the polyoxy of carbon number 12~15
Vinyl alkyl ether is the particle of principal component and the elastomer silicone with siloxane backbone and average grain diameter is 1 μm~10 μ
Made of the aluminium oxide particles dispersion of m；With
Make by heat be crosslinked between the particle to the elastomer silicone made of it is membranaceous and include institute
State aluminium oxide particles the elastomer silicone be bonded to the fibrous material at least part surface process.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2016/065003 WO2017199421A1 (en) | 2016-05-20 | 2016-05-20 | Functional fiber and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109154132A true CN109154132A (en) | 2019-01-04 |
Family
ID=60325862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680085873.4A Pending CN109154132A (en) | 2016-05-20 | 2016-05-20 | Functional fiber and its manufacturing method |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20190203408A1 (en) |
| JP (1) | JPWO2017199421A1 (en) |
| CN (1) | CN109154132A (en) |
| MX (1) | MX2018014199A (en) |
| WO (1) | WO2017199421A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3911786A4 (en) * | 2019-01-16 | 2023-05-03 | Hologenix, LLC | Cellulose and semi-cellulose based fibers and yarns embedded with mineral particles and methods of making the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02182968A (en) * | 1988-12-30 | 1990-07-17 | Toyo Kogyo Kk | Production of pile fabric having excellent heat-insulation |
| CN104278357A (en) * | 2014-10-14 | 2015-01-14 | 安徽天鹅科技实业（集团）有限公司 | Cotton fibers capable of releasing far infrared negative ions and production method of cotton fibers |
| CN105229220A (en) * | 2013-05-15 | 2016-01-06 | Ventex株式会社 | For the sheets of fabric of the clothes of irradiating biological energy |
| CN105246513A (en) * | 2013-05-24 | 2016-01-13 | 日本爱克兰工业株式会社 | Functional microparticles and resin product containing same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0369675A (en) * | 1989-08-07 | 1991-03-26 | Teijin Ltd | Wear-resistant far infrared ray-radiating synthetic fiber |
| JP2003230779A (en) * | 2002-02-12 | 2003-08-19 | Nissan Motor Co Ltd | Cushion material and interior material for vehicle consisting of the same |
| KR101475320B1 (en) * | 2011-12-09 | 2014-12-22 | 강양식 | Functional fabric and manufacture method thereof |
| CN105793488B (en) * | 2013-12-03 | 2018-04-27 | Kb都筑株式会社 | Upgraded fiber and its manufacture method |
-
2016
- 2016-05-20 WO PCT/JP2016/065003 patent/WO2017199421A1/en active Application Filing
- 2016-05-20 MX MX2018014199A patent/MX2018014199A/en unknown
- 2016-05-20 US US16/303,021 patent/US20190203408A1/en not_active Abandoned
- 2016-05-20 CN CN201680085873.4A patent/CN109154132A/en active Pending
- 2016-05-20 JP JP2018518037A patent/JPWO2017199421A1/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02182968A (en) * | 1988-12-30 | 1990-07-17 | Toyo Kogyo Kk | Production of pile fabric having excellent heat-insulation |
| CN105229220A (en) * | 2013-05-15 | 2016-01-06 | Ventex株式会社 | For the sheets of fabric of the clothes of irradiating biological energy |
| CN105246513A (en) * | 2013-05-24 | 2016-01-13 | 日本爱克兰工业株式会社 | Functional microparticles and resin product containing same |
| CN104278357A (en) * | 2014-10-14 | 2015-01-14 | 安徽天鹅科技实业（集团）有限公司 | Cotton fibers capable of releasing far infrared negative ions and production method of cotton fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2017199421A1 (en) | 2019-03-14 |
| MX2018014199A (en) | 2019-04-22 |
| US20190203408A1 (en) | 2019-07-04 |
| WO2017199421A1 (en) | 2017-11-23 |
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