CN109153611B - Hydrated cured body and method for producing same - Google Patents
Hydrated cured body and method for producing same Download PDFInfo
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- CN109153611B CN109153611B CN201780030377.3A CN201780030377A CN109153611B CN 109153611 B CN109153611 B CN 109153611B CN 201780030377 A CN201780030377 A CN 201780030377A CN 109153611 B CN109153611 B CN 109153611B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
- C04B18/141—Slags
- C04B18/142—Steelmaking slags, converter slags
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/08—Flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
- C04B18/146—Silica fume
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention provides a hydrated cured product with excellent fatigue durability and a manufacturing method thereof. The hydrated solidified body is obtained by solidifying a kneaded material containing an aggregate containing a steel-making slag, a binder solidified by hydration, and water, wherein the aggregate has a maximum dimension of 5mm or more and 60mm or less, a solid volume fraction of coarse aggregate of the aggregate is 50 vol% or more, and a volume fraction of the aggregate in the total volume of the hydrated solidified body is 55 vol% or more.
Description
Technical Field
The present invention relates to a hydrated cured product and a method for producing the same.
Background
Conventionally, a hydrated cured product such as concrete or mortar has been known. In general, the hydrated solidified body is obtained by solidifying a kneaded product containing: aggregates (fine aggregates and coarse aggregates) of different particle sizes such as natural crushed stones and mountain sands; a binding material such as cement which cures by a hydration reaction; and water.
As such a hydrated solidified body, a hydrated solidified body using an aggregate containing a steel-making slag (hereinafter, also referred to as "steel-making slag hydrated solidified body") is known (for example, see patent document 1), which is used for harbor civil engineering materials, road base materials, and the like.
The steel-making slag is a high-specific gravity and hard substance containing a large amount of iron component, and has various particle sizes, and thus can be used in the form of fine aggregate or coarse aggregate. In the case where the steelmaking slag hydrated solidified body is used for a harbor civil engineering material (for example, a wave-absorbing block, a fish reef block), the specific gravity of the harbor civil engineering material can be increased, and therefore the steelmaking slag hydrated solidified body can be said to be a material suitable for the harbor civil engineering material.
Documents of the prior art
Patent document
Patent document 1: japanese laid-open patent publication No. 2006-264045
Disclosure of Invention
Problems to be solved by the invention
In the case where the hydrated cured body is used as, for example, a harbor civil engineering material or a roadbed material, mechanical stress is continuously and repeatedly applied to the hydrated cured body, and the hydrated cured body is fatigued. Therefore, physical properties such as strength and specific gravity, and excellent fatigue durability are required as important characteristics for the hydrated cured product.
The present invention has been made in view of the above circumstances, and an object thereof is to provide a hydrated cured product having excellent fatigue durability and a method for producing the same.
Means for solving the problems
The present inventors have conducted intensive studies to achieve the above object and as a result, have found that the fatigue durability of a hydrated solidified body obtained by using an aggregate satisfying specific conditions as an aggregate containing a steel-making slag is improved, thereby completing the present invention.
Namely, the present invention provides the following [1] to [6 ].
[1] A hydrated solidified body obtained by solidifying a kneaded material containing an aggregate containing a steel-making slag, a binder solidified by hydration, and water, wherein the aggregate has a maximum dimension of 5mm or more and 60mm or less, a solid volume fraction of coarse aggregate of the aggregate is 50% by volume or more, and a volume fraction of the aggregate in the total volume of the hydrated solidified body is 55% by volume or more.
[2] The hydrated solidified body according to the above [1], wherein the binder contains at least one selected from the group consisting of blast furnace slag fine powder and portland cement.
[3] The hydrated solidified body according to the above [1] or [2], wherein the binder contains at least one selected from the group consisting of silica fume and fly ash.
[4] A method for producing a hydrated solidified body, which comprises solidifying a kneaded material comprising an aggregate containing a steel-making slag, a binder that solidifies by a hydration reaction, and water, wherein the aggregate has a maximum dimension of 5mm or more and 60mm or less, the aggregate has a solid volume fraction of coarse aggregate of 50 vol% or more, and the aggregate occupies 55 vol% or more of the total volume of the hydrated solidified body.
[5] The method for producing a hydrated solidified body according to the above [4], wherein the binder contains at least one selected from the group consisting of blast furnace slag fine powder and portland cement.
[6] The method for producing a hydrated solidified body according to the above [4] or [5], wherein the binder contains at least one selected from the group consisting of silica fume and fly ash.
ADVANTAGEOUS EFFECTS OF INVENTION
According to the present invention, a hydrated cured product excellent in fatigue durability and a method for producing the same can be provided.
Detailed Description
[ hydrated cured body ]
The hydrated solidified body of the present invention is a hydrated solidified body obtained by solidifying a kneaded material containing an aggregate containing a steel-making slag, a binder solidified by hydration, and water, wherein the aggregate has a maximum dimension of 5mm or more and 60mm or less, a solid volume fraction of coarse aggregate of the aggregate is 50 vol% or more, and a volume fraction of the aggregate in the total volume of the hydrated solidified body is 55 vol% or more.
The hydrated cured product of the present invention is excellent in fatigue durability. The reason for this is considered as follows.
The hydrated cured product "fatigue" due to repeated application of mechanical stress, and cracks and the like occur. The hydrated cured product of the present invention is expected to have excellent fatigue durability because it is appropriately filled with an aggregate and exhibits an action of preventing the generation and the development of cracks.
The hydrated cured body of the present invention is excellent in fatigue durability and therefore can be suitably used as, for example, harbor civil engineering materials, roadbed materials.
Hereinafter, the hydrated cured product of the present invention will be described, and a method for producing the hydrated cured product of the present invention will also be described.
[ aggregate ]
The aggregate used in the present invention (hereinafter, referred to as "aggregate in the present invention" for convenience) contains steel-making slag. In addition to the steelmaking slag, the aggregate in the present invention may also contain: previously known natural crushed stones and mountain sands; blast furnace slow-cooling slag, blast furnace water granulated slag fine aggregate (for example, aggregate prescribed in JIS A5011-1 "slag aggregate for concrete-part 1: blast furnace slag aggregate", etc., wherein, it may be any other than JIS); examples of the recycled aggregate for concrete include aggregates specified in JIS a 5021 "recycled aggregate for concrete H", JIS a 5022 "concrete using recycled aggregate M", and JIS a 5023 "concrete using recycled aggregate L", and the like, and may include other than JIS.
From the viewpoint of effective utilization of the steel-making slag, the volume ratio (volume ratio) of the steel-making slag in the aggregate in the present invention is preferably 50 volume% or more, more preferably 75 volume% or more, and still more preferably 100 volume%.
As the steel-making slag, not only slag generated in a converter, an electric furnace, a torpedo car, or the like, but also slag pretreated with molten iron, slag generated during stainless steel refining and containing t.cr of 0.5 mass% or more, and the like can be used. The steel-making slag may be etched, and the steel-making slag preferably has a water immersion expansion ratio of 0.5% or less, regardless of the etching method. It is also possible to use the steel-making slag subjected to the air-crushing treatment as a part of the steel-making slag, although the cost becomes high.
Aggregates are classified into fine aggregates and coarse aggregates. Such as JIS A0203: 2014, fine aggregate is aggregate which passes through a 10mm mesh screen and passes through a 5mm mesh screen at least 85% (by mass) (simply referred to as aggregate of less than 5 mm). On the other hand, the coarse aggregate is an aggregate which is retained in a 5mm mesh sieve at 85% by mass or more (simply referred to as an aggregate of 5mm or more).
< maximum dimension >
The maximum size of the aggregate in the present invention is 5mm or more and 60mm or less. Accordingly, the aggregate in the present invention contains at least coarse aggregate.
Here, the maximum size of the aggregate is defined as JIS a 0203: 2014 is a size represented by a nominal size of a sieve having the smallest size among sieves through which 90% or more (by mass) of the aggregate passes.
The relationship between the nominal size and the mesh opening (sieve opening) is described in JIS a 1102: 2014. and JIS Z8801-1: 2006. JIS Z8801-2: 2000 and JIS Z8801-3: 2000, for example, a nominal size of 40mm corresponds to a mesh size of 37.5 mm. Thus, for example, a steel-making slag having a maximum size of 40mm means the following steel-making slag: more than 90 mass% of the steel-making slag passes through the 37.5mm mesh size, and less than 90 mass% of the steel-making slag passes through the 31.5mm mesh size.
The maximum size of the aggregate in the present invention is preferably 10mm or more and 60mm or less because the fatigue durability of the hydrated cured body of the present invention can be further excellent.
The hydrated solidified body of the present invention may contain, in addition to the aggregate of the present invention, an aggregate having a maximum size of more than 60 mm.
< actual product Rate >
The aggregate of the present invention has a solid volume fraction of coarse aggregate of 50 vol% or more. Thus, the hydrated cured product of the present invention is excellent in fatigue durability. The solid volume fraction defined herein is the solid volume fraction of the "coarse aggregate" of the aggregate in the present invention, and the solid volume fraction of the "fine aggregate" of the aggregate in the present invention is not particularly limited.
The actual volume ratio is described in JIS a 1104: in 2006, the aggregate is generally expressed as a net volume ratio per unit volume.
The solid content of the coarse aggregate in the aggregate of the present invention is preferably 55 vol% or more, because the fatigue durability of the hydrated cured product of the present invention can be further improved.
The upper limit of the solid volume fraction of the coarse aggregate in the aggregate of the present invention is not particularly limited, and is, for example, 75 vol% or less, preferably 70 vol% or less.
< volume fraction >
The aggregate of the present invention accounts for 55 vol% or more of the total volume of the hydrated cured product of the present invention. Thus, the hydrated cured product of the present invention is excellent in fatigue durability. The volume fraction defined herein is a concept including not only coarse aggregate but also fine aggregate.
The volume fraction of the aggregate was calculated as follows. First, the volume fractions of the materials such as water, aggregates (coarse aggregates and fine aggregates), binder, and air constituting the hydrated solidified body are determined. Next, a stirring test was carried out in a formulation calculated based on the volume fraction and density of each material (Japanese: り Japanese bench infusion test). After the stirring, the amount of air (unit: volume%) in the hydrated solidified body was measured, and the actual volume fraction of each material including the aggregate was calculated.
The volume fraction of the aggregate in the present invention is preferably more than 55 vol%, more preferably 57 vol% or more, because the fatigue durability of the hydrated cured product of the present invention can be further improved.
On the other hand, the upper limit is not particularly limited, and is, for example, 80 vol% or less, preferably 75 vol% or less.
< Fine aggregate fraction (s/a) >
The fine aggregate content of the aggregate in the present invention is not particularly limited, and is, for example, 30 to 60% by volume, preferably 35 to 55% by volume.
The fine aggregate fraction is a ratio of fine aggregate to aggregate, and is also expressed as "s/a".
The amount of the aggregate to be blended in the present invention is not particularly limited, and may be, for example, 1200 to 3000kg/m as in usual concrete and mortar3Preferably, it is1400~2500kg/m3。
In the present specification, the "blending amount" is per unit volume (1 m)3) The amount (kg) of the hydrated cured product (the same applies hereinafter).
[ adhesive Material ]
The binder used in the present invention and cured by hydration reaction (hereinafter, also referred to as "binder in the present invention" for convenience) is not particularly limited, and conventionally known binders can be used.
The total amount of the binder in the present invention is, for example, 300 to 800kg/m3Preferably 350 to 700kg/m3。
As the binder in the present invention, for example, a binder containing at least one selected from the group consisting of blast furnace slag fine powder and portland cement is preferably cited. The total amount of the additives is, for example, 200 to 700kg/m3Preferably 300 to 680kg/m3。
Examples of the blast furnace slag fine powder include JIS a 6206: 2013, or a fine powder of blast furnace slag for concrete.
Examples of portland cement include JIS R5210: the portland cement specified in 2009.
The binder of the present invention may contain at least one selected from the group consisting of silica fume and fly ash, either in combination with the blast furnace slag fine powder or separately from the blast furnace slag fine powder. The total amount of the additives is, for example, 0 to 300kg/m3Preferably O to 250kg/m3。
Examples of the silica fume include JIS a 6207: 2011 the silica fume for concrete.
Examples of fly ash include fly ash generated in coal thermal power generation, and JIS a 6201: fly ash or fly ash raw powder for concrete, as defined in 2015.
[ Water ]
The water used in the present invention is not particularly limited. The amount of water is, for example, 100 to 350kg/m3Preferably 120 to 300kg/m3。
[ other Components ]
In the present invention, other components may be further used.
For example, in order to ensure workability of a hydrated cured product which has not yet been cured, an admixture such as a water reducing agent which is generally used for concrete may be used.
When the mixture is used, the amount of the mixture is, for example, O to 10000g/m3Preferably O to 7000g/m3。
[ air quantity ]
In the present invention, the amount of air is not particularly limited, and is, for example, 0.5 to 10% by volume, preferably 1 to 8% by volume.
[ mixing and curing ]
In the present invention, the hydrated solidified body of the present invention is obtained by kneading a composition containing the above components to prepare a kneaded product and solidifying the kneaded product.
The kneading, casting, molding, curing and the like in obtaining the hydrated cured product of the present invention can be the same as in the case of ordinary concrete or mortar. The curing is also not particularly limited, and when the curing is accelerated, the treatment with steam or autoclave may be performed as in the case of concrete.
Examples
The present invention will be specifically described below with reference to examples. However, the present invention is not limited thereto.
< comparative examples 1 to 5 and invention examples 1 to 15>
The resulting mixture was kneaded with a mixer in the formulation shown in Table 1 below, and the kneaded mixture was molded in a mold of 10 cm. times.10 cm. times.40 cm. After 2 days, the molded article was demolded and aged in water at 20 ℃ for 28 days to obtain a hydrated cured article.
As the aggregate, steel-making slag is used. More specifically, the molten iron pretreatment slag was used in comparative examples 1 to 5 and inventive examples 1 to 8, and the converter slag was used in inventive examples 9 to 15.
As the blast furnace slag fine powder, JIS a 6206: 2013, or a fine powder of blast furnace slag for concrete. As portland cement, JIS R5210: 2009 regular portland cement. As the silica fume, JIS a 6207: 2011 the silica fume for concrete. As fly ash, JIS a 6201: the fly ash for concrete as defined in 2015.
< evaluation of fatigue durability >
The obtained hydrated cured product was subjected to a bending fatigue test. The loading method is load at three equal points. The upper limit stress (stress intensity ratio) for the load conditions was set to JIS a 1106: the lower limit stress is set to 5% of the upper limit stress, which is 60% of the bending strength measured by the bending strength test method 2006. The repetitive load speed was set to a frequency of 7 Hz.
The number of times until fracture occurred was determined by repeatedly applying a load to the hydrated solidified body under such conditions, and this was taken as the flexural fatigue life. The number of times is more than 1 × 104The next time, the fatigue durability was evaluated to be excellent.
From the results shown in table 1 and fig. 1, it is understood that (1) inventive examples 1 to 15 in which the maximum size of the aggregate is 5mm or more and 60mm or less, (2) the solid content of the coarse aggregate of the aggregate is 50 vol% or more, and (3) the volume content of the aggregate is 55 vol% or more are excellent in fatigue durability.
In comparison with invention examples 1 to 15, invention examples 5 and 9 to 15 in which the solid content of the coarse aggregate was 55 vol% or more were more excellent in fatigue durability as compared with invention examples 1 to 4 and 6 to 8 in which the solid content of the coarse aggregate was not 55 vol% or more.
On the other hand, comparative examples 1 to 5, which do not satisfy one or more of the above (1) to (3), have poor fatigue durability.
< comparative examples 6 to 11 and invention examples 16 to 21>
The resulting mixture was kneaded with a mixer in the formulation shown in Table 2 below, and the kneaded mixture was molded in a mold of 10 cm. times.10 cm. times.40 cm. After 2 days, the molded article was demolded and aged in water at 20 ℃ for 28 days to obtain a hydrated cured article.
As the aggregate, in addition to the steel-making slag, natural crushed stone, sand, blast furnace slow cooling slag, blast furnace granulated slag fine aggregate, and recycled aggregate for concrete (hereinafter, also simply referred to as "recycled aggregate") are used.
As the aggregate other than the steel-making slag, more specifically, natural crushed stone and sand were used in comparative examples 6 to 7 and invention examples 16 to 17, fine aggregate of blast furnace slow cooling slag and blast furnace granulated slag was used in comparative examples 8 to 9 and invention examples 18 to 19, and recycled aggregate for concrete was used in comparative examples 10 to 11 and invention examples 20 to 21. As the steelmaking slag, molten iron is used for pretreatment of the slag.
As the blast furnace slag fine powder, JIS a 6206: 2013, or a fine powder of blast furnace slag for concrete. As portland cement, JIS R5210: ordinary portland cement specified in 2009. As fly ash, JISA 6201: the fly ash for concrete as defined in 2015.
< evaluation of fatigue durability >
The obtained hydrated cured product was subjected to a bending fatigue test. The loading method is load at three equal points. The upper limit stress (stress intensity ratio) of the load conditions was set to be within a range of JIS a 1106: the lower limit stress is set to 5% of the upper limit stress, which is 60% of the bending strength measured by the bending strength test method 2006. The repetitive load speed was set to a frequency of 7 Hz.
Under such conditions, the number of times until fracture occurred was determined by repeatedly applying a load to the hydrated solidified body, and this was taken as the flexural fatigue life. The number of times is more than 1 × 104Next, the fatigue durability was evaluated to be excellent.
From the results shown in table 2, it is clear that invention examples 16 to 21 in which (1) the maximum size of the aggregate is 5mm or more and 60mm or less, (2) the solid volume fraction of the coarse aggregate of the aggregate is 50 vol% or more, and (3) the volume fraction of the aggregate is 55 vol% or more are excellent in fatigue durability.
On the other hand, comparative examples 6 to 11, which do not satisfy one or more of the above (1) to (3), have poor fatigue durability.
Claims (6)
1. A hydrated solidified body obtained by solidifying a kneaded material containing an aggregate containing a steel-making slag, a binder solidified by a hydration reaction, and water,
wherein the maximum size of the aggregate is 40mm or more and 60mm or less,
the aggregate has a solid volume fraction of coarse aggregate of 50 to 70 vol%,
the aggregate occupies 55 vol% or more of the total volume of the hydrated solidified body.
2. The hydrated solidified body of claim 1, wherein the binder material comprises at least one selected from the group consisting of blast furnace slag micropowder and portland cement.
3. The hydrated solidified body of claim 1 or 2, wherein the binder material comprises at least one selected from the group consisting of silica fume and fly ash.
4. A process for producing a hydrated solidified body, which comprises solidifying a kneaded product comprising an aggregate containing a steel-making slag, a binder that solidifies by a hydration reaction, and water,
wherein the maximum size of the aggregate is 40mm or more and 60mm or less,
the aggregate has a solid volume fraction of coarse aggregate of 50 to 70 vol%,
the aggregate occupies 55 vol% or more of the total volume of the hydrated solidified body.
5. The method of manufacturing a hydrated solidified body according to claim 4, wherein the binder material contains at least one selected from the group consisting of blast furnace slag fine powder and portland cement.
6. The method of manufacturing a hydrated solidified body according to claim 4 or 5, wherein the binder material contains at least one selected from the group consisting of silica fume and fly ash.
Applications Claiming Priority (5)
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JP2016110592 | 2016-06-02 | ||
JP2016-110592 | 2016-06-02 | ||
JP2017011956A JP6593358B2 (en) | 2016-06-02 | 2017-01-26 | Hydrated cured body and method for producing the same |
JP2017-011956 | 2017-01-26 | ||
PCT/JP2017/018702 WO2017208844A1 (en) | 2016-06-02 | 2017-05-18 | Hydrated hardened body and method for manufacturing same |
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CN109153611B true CN109153611B (en) | 2022-06-24 |
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JP2002160958A (en) * | 2000-11-17 | 2002-06-04 | Hoshino Sansho:Kk | Water permeable material and water permeable composite material |
JP4438307B2 (en) * | 2003-03-28 | 2010-03-24 | Jfeスチール株式会社 | How to select steelmaking slag for hardened slag |
JP4264288B2 (en) * | 2003-04-21 | 2009-05-13 | 新日本製鐵株式会社 | Production method of asphalt aggregate |
JP4812259B2 (en) * | 2004-03-03 | 2011-11-09 | Jfeスチール株式会社 | Method and block for producing cured body having voids |
JP2006045048A (en) * | 2004-06-30 | 2006-02-16 | Jfe Mineral Co Ltd | Solidified body of steel-making slag and method for producing the same |
JP4736491B2 (en) | 2005-03-23 | 2011-07-27 | Jfeスチール株式会社 | Underwater structure and manufacturing method thereof |
JP2007022869A (en) * | 2005-07-19 | 2007-02-01 | Okumura Corp | Settable composition |
KR20120060743A (en) * | 2010-12-02 | 2012-06-12 | 리싸이클 협동조합 | Method for manufacturing recycling concrete |
JP5035932B2 (en) * | 2010-12-02 | 2012-09-26 | リサイクル協同組合 | Circulating concrete manufacturing method |
KR101138243B1 (en) * | 2011-12-16 | 2012-04-24 | (주)한일 | Composition of ready-mixed concrete using industrial wastes |
JP5954237B2 (en) * | 2012-07-30 | 2016-07-20 | Jfeスチール株式会社 | Method for producing hydrated solid block of steel slag |
JP6065720B2 (en) * | 2013-04-08 | 2017-01-25 | Jfeスチール株式会社 | Method for producing hydrated solid body |
JP6241350B2 (en) * | 2014-03-28 | 2017-12-06 | 新日鐵住金株式会社 | Manufacturing method of large artificial stone |
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TWI639578B (en) | 2018-11-01 |
JP2017218369A (en) | 2017-12-14 |
CN109153611A (en) | 2019-01-04 |
JP6593358B2 (en) | 2019-10-23 |
KR20180136511A (en) | 2018-12-24 |
KR20210022783A (en) | 2021-03-03 |
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