CN109137600A - A kind of preparation method of vanadium doping antibacterial papermaking material - Google Patents
A kind of preparation method of vanadium doping antibacterial papermaking material Download PDFInfo
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- CN109137600A CN109137600A CN201811060792.6A CN201811060792A CN109137600A CN 109137600 A CN109137600 A CN 109137600A CN 201811060792 A CN201811060792 A CN 201811060792A CN 109137600 A CN109137600 A CN 109137600A
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- parts
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- vanadium doping
- antibacterial
- preparation
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- 239000000463 material Substances 0.000 title claims abstract description 72
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 52
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 51
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 28
- 238000003756 stirring Methods 0.000 claims abstract description 28
- 230000003115 biocidal effect Effects 0.000 claims abstract description 26
- 229940088710 antibiotic agent Drugs 0.000 claims abstract description 25
- 108090000790 Enzymes Proteins 0.000 claims abstract description 16
- 102000004190 Enzymes Human genes 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 241000609240 Ambelania acida Species 0.000 claims abstract description 10
- 239000010905 bagasse Substances 0.000 claims abstract description 10
- 238000000855 fermentation Methods 0.000 claims abstract description 10
- 230000004151 fermentation Effects 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 244000025254 Cannabis sativa Species 0.000 claims abstract description 9
- 229920008262 Thermoplastic starch Polymers 0.000 claims abstract description 9
- 230000018044 dehydration Effects 0.000 claims abstract description 9
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 9
- 238000005360 mashing Methods 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 9
- 239000004628 starch-based polymer Substances 0.000 claims abstract description 9
- 238000000926 separation method Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 20
- -1 filters Substances 0.000 claims description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 229940088598 enzyme Drugs 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 14
- 239000002518 antifoaming agent Substances 0.000 claims description 14
- 239000000945 filler Substances 0.000 claims description 14
- 230000001376 precipitating effect Effects 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 10
- RTRXLVQDWQKTCL-UHFFFAOYSA-N 1-methyl-1h-imidazol-1-ium;propane-1-sulfonate Chemical compound C[NH+]1C=CN=C1.CCCS([O-])(=O)=O RTRXLVQDWQKTCL-UHFFFAOYSA-N 0.000 claims description 9
- UBKHHFOBCZFFKL-UHFFFAOYSA-N cyclopenta[c]pyran Chemical compound C1=COC=C2C=CC=C21 UBKHHFOBCZFFKL-UHFFFAOYSA-N 0.000 claims description 9
- 229920001661 Chitosan Polymers 0.000 claims description 8
- 241000233866 Fungi Species 0.000 claims description 8
- 241000235342 Saccharomycetes Species 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical compound NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 claims description 8
- 238000005282 brightening Methods 0.000 claims description 8
- 238000004513 sizing Methods 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 7
- 108010059892 Cellulase Proteins 0.000 claims description 7
- 239000000783 alginic acid Substances 0.000 claims description 7
- 235000010443 alginic acid Nutrition 0.000 claims description 7
- 229920000615 alginic acid Polymers 0.000 claims description 7
- 229960001126 alginic acid Drugs 0.000 claims description 7
- 150000004781 alginic acids Chemical class 0.000 claims description 7
- 239000000908 ammonium hydroxide Substances 0.000 claims description 7
- 239000001110 calcium chloride Substances 0.000 claims description 7
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 7
- 229940106157 cellulase Drugs 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000012265 solid product Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N anhydrous quinoline Natural products N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 2
- 229960003677 chloroquine Drugs 0.000 claims description 2
- WHTVZRBIWZFKQO-UHFFFAOYSA-N chloroquine Natural products ClC1=CC=C2C(NC(C)CCCN(CC)CC)=CC=NC2=C1 WHTVZRBIWZFKQO-UHFFFAOYSA-N 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 238000001802 infusion Methods 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract description 7
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 29
- 241000894006 Bacteria Species 0.000 description 22
- 230000000845 anti-microbial effect Effects 0.000 description 11
- 239000004599 antimicrobial Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- IQXJCCZJOIKIAD-UHFFFAOYSA-N 1-(2-methoxyethoxy)hexadecane Chemical compound CCCCCCCCCCCCCCCCOCCOC IQXJCCZJOIKIAD-UHFFFAOYSA-N 0.000 description 1
- RWWUFTQVKMNRQN-UHFFFAOYSA-N 3-bromo-2-chloroquinoline Chemical compound C1=CC=C2C=C(Br)C(Cl)=NC2=C1 RWWUFTQVKMNRQN-UHFFFAOYSA-N 0.000 description 1
- 244000061520 Angelica archangelica Species 0.000 description 1
- 208000016583 Anus disease Diseases 0.000 description 1
- 235000007650 Aralia spinosa Nutrition 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 241001343274 Dichrostachys spicata Species 0.000 description 1
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- 235000001287 Guettarda speciosa Nutrition 0.000 description 1
- 244000062250 Kaempferia rotunda Species 0.000 description 1
- 235000013422 Kaempferia rotunda Nutrition 0.000 description 1
- 229920003266 Leaf® Polymers 0.000 description 1
- 244000297531 Lespedeza cuneata Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 241000612118 Samolus valerandi Species 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241001671204 Stemona Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 241000949456 Zanthoxylum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229950009789 cetomacrogol 1000 Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical class C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/12—Defoamers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Pest Control & Pesticides (AREA)
- Paper (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to papermaking field of new material preparation, particularly with regard to a kind of preparation method of vanadium doping antibacterial papermaking material；A kind of preparation method of vanadium doping antibacterial papermaking material disclosed in the method for the present invention, grass stalk, stalk, bagasse, carboxymethyl cellulose and water are added to beater mashing and stir into slurries by this method, then it heats, so that the fiber separation in paddle liquid, then thermoplastic starch and fermenting enzyme are added in system, it is condensed after fermentation, dehydration forms paste, then vanadium doping anti-biotic material and various auxiliary agents are added, it stirs evenly, coating, dehydrates, suppresses, cuts, packs, a kind of vanadium doping antibacterial papermaking material can be obtained.
Description
Technical field
The present invention relates to field of material preparation, particularly with regard to a kind of preparation method of vanadium doping antibacterial papermaking material.
Background technique
Paper material is widely used, from daily necessities, arrives industrial production, logistics, everywhere its visible figure.Paper
Entire 50% or more packaging material is accounted for paperboard packaging material.Anti-bacteria paper is with inhibition bacterium, mould and paper product pest ability
Functional paper.The exploitation and development of Anti-microbial paper material also receive the common concern of people.
CN105484102A provides a kind of papermaking antibacterial agent, is made from the following raw materials in parts by weight: dithiocyano-methane
28g, dibenzoyl peroxide 20g, dodecyl sodium sulfate 45g, cetomacrogol 1000 24.0g, formaldehyde 12g, preparation method packet
It includes following steps: will first mix each raw material, stir evenly to get the present invention has excellent antibacterial effect, and user
Just.
CN104894912A discloses a kind of paper technology, by main material, paper making additive and papermaking mould three parts system
At the main material including following parts by weight: 10-30 parts of needlebush, 8-24 parts of reed, 5-15 parts of wheat straw, bagasse 10-26
Part, 6-18 parts of cellucotton and 30-50 parts of starch, the paper making additive including following parts by weight: 3-8 parts of sizing agent, defoaming agent 4-6
Part, 5-10 parts of brightening agent, 2-5 parts of bacteriostasis antibiosis agent and 6-12 parts of filler aqueous suspension, the papermaking including following parts by weight is mould
Bacterium: 1-3 parts of white-rot fungi, 2-5 parts of zytase and 3-6 parts of saccharomycete；The paper technology paper is flat and smooth, and softness has light
Pool has good anti-ink, the performances such as water resistant is anticorrosive.
CN105148146A discloses a kind of moist antibacterial toilet paper and its manufacturing method.A kind of moist antibacterial toilet paper includes fountain solution
With the non-woven material being immersed in fountain solution, non-woven material is acid fiber by polylactic, the 4- by the 25-28% in terms of fibre weight
6% flax fiber, surplus are wet toilet paper body paper made of the paper making pulp of wood pulp cellulose composition, and fountain solution is by following weight
The raw material of part accesses appropriate bacillus subtilis and carries out the fermentation liquid obtained after fermented and cultured: 5-10 parts of corn stigmas, 15-20 portions of snakes
Machine tool, 8-10 parts of Radix Angelicae Sinensis, the 10-15 parts of roots of Dahurain angelica, the 10-12 parts of tubers of stemona, 20-30 portions of folium artemisiae argyis, 5-10 parts of bunge pricklyash leafs, 5-10 parts of kaempferia galamgas,
20-30 parts of pilose bushclover herbs, 15-20 portions of folium isatidis, 3-5 parts of citric acids, 10-15 portions of coconut oil, 15-20 parts of orange peels, 400-500 parts
Water.The present invention have many advantages, such as dispersion performance it is good, it is biodegradable, alleviate disease of anus.
The above patent and the mode of prior art preparation antibacterial papermaking material are mainly using paper as germicide carriers, in paper
It opens surface and is coated or sprays anti-biotic material；Most of these fungicide are that metal ion or other small organic molecules are antibacterial
Agent is easily separated from or dissolves out, and is easy to generate harm to the health of user.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of preparation methods of vanadium doping antibacterial papermaking material.
A kind of preparation method of vanadium doping antibacterial papermaking material, technology of preparing scheme are as follows:
It is according to mass fraction, 5-20 parts of grass stalk, 10-14 parts of stalk, 12-28 parts of bagasse, 2-8 parts of carboxymethyls are fine
Dimension element and 50-80 parts of water are added to beater mashing and stir into slurries, are then heated to 90-105 DEG C, keep the temperature 1-5h, so that
30-50 parts of thermoplastic starch are added in system by the fiber separation in paddle liquid, stir 10-30min, are then added 1-5 parts
Fermenting enzyme, 30-50 DEG C of temperature control after mixing evenly, ferment 10-40h；After completing fermentation, then washing precipitating is added 1-10 parts
Vanadium doping anti-biotic material and 5-10 parts of filler, raw material is agglomerated, and is then carried out dehydration and is formed paste, then adds 1-5 parts
Defoaming agent and 3-8 parts of brightening agents stir evenly, and continue to be beaten 10-30min, then add 5-10 parts of sizing agents, stir evenly, apply
Cloth is dehydrated, suppresses, cuts, is packed, and a kind of vanadium doping antibacterial papermaking material can be obtained.
The vanadium doping anti-biotic material is prepared in accordance with the following methods:
According to mass fraction, by 0.01-0.1 parts of 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquine of 1-5 parts of 6-
Quinoline -4- dicarbonyl chloride, 0.05-0.5 parts of aminoguanidine sulfonate, 1-5 parts of 5- benzofurane -2- formyl chloride and the two of 0.5-2 parts
Chlorine vanadyl is added in reaction kettle, and temperature control is to subzero 5-10 DEG C, after mixing evenly, 400-1000 parts of the concentrated sulfuric acid, mixing is added
100 parts of chitosan is added in reaction kettle after uniformly, subzero 10-20 DEG C of temperature control, 10-30h is reacted, then by reaction system
Precipitating in acetone is poured into, is then neutralized with ammonium hydroxide, filters, solid product is washed to neutrality,
100 parts of the solid obtained, 1-10 parts of calcium chloride and 0.1-5 parts of alginic acid are placed in 400-1000 parts of isopropanol
In, 40-60 DEG C of temperature control, 5-10h is reacted, then solvent evaporated, can be obtained the vanadium doping anti-biotic material.
The fermenting enzyme is cellulase, white-rot fungi, lignoenzyme, zytase and saccharomycete proportionally 1:
0.2-0.8:0.5-1:0.1-0.8:0.6-1.8 is uniformly mixed and obtains.
The filler is titanium dioxide or talcum powder or Paris white.
The defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether or polyoxyethylene polyoxy propyl alcohol amidogen ether or polyoxy
Propylene glycerin ether.
A kind of preparation method of vanadium doping antibacterial papermaking material disclosed in the method for the present invention, this method by grass stalk, stalk,
Bagasse, carboxymethyl cellulose and water are added to beater mashing and stir into slurries, then heat, so that the fiber in paddle liquid point
From, then thermoplastic starch and fermenting enzyme are added in system, are condensed after fermentation, dehydration form paste, then add
Vanadium doping anti-biotic material and various auxiliary agents, stir evenly, and coating is dehydrated, suppresses, cuts, packed, can be obtained described
A kind of vanadium doping antibacterial papermaking material；This method uses 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquinoline -4- carbonyl of 6-
Acyl chlorides, aminoguanidine sulfonate, 5- benzofurane -2- formyl chloride and dichloro vanadyl change chitosan under the conditions of the concentrated sulfuric acid
Property, a kind of vanadium doping anti-biotic material is obtained, this kind of antibacterial agent uses in paper product, it is not easy to it is detached from or dissolves out, it will not be to use
The health of person generates harm.
Specific embodiment
The invention is described further below by specific embodiment:
Embodiment 1
A kind of preparation method of vanadium doping antibacterial papermaking material, technology of preparing scheme are as follows:
According to mass fraction, by 10 parts of grass stalk, 12 parts of stalk, 18 parts of bagasse, 4 parts of carboxymethyl celluloses and 60 parts
Water be added to beater mashing and stir into slurries, be then heated to 95 DEG C, keep the temperature 3h, will so that the fiber separation in paddle liquid
40 parts of thermoplastic starch are added in system, stir 20min, 3 parts of fermenting enzyme are then added, after mixing evenly 40 DEG C of temperature control,
Ferment 20h；After completing fermentation, then washing precipitating is added 5 parts of vanadium doping anti-biotic material and 8 parts of filler, raw material is coagulated
It is poly-, it then carries out dehydration and forms paste, then add 3 parts of defoaming agent and 5 parts of brightening agents stir evenly, continue to be beaten 20min,
Then 8 parts of sizing agents are added, are stirred evenly, is coated with, is dehydrated, suppresses, cuts, packs, a kind of vanadium can be obtained
Adulterate antibacterial papermaking material.
The vanadium doping anti-biotic material is prepared in accordance with the following methods:
According to mass fraction, by 0.03 part of 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquinoline -4- carbonyl of 3 parts of 6-
Acyl chlorides, 0.1 part of aminoguanidine sulfonate, 3 parts of 5- benzofurane -2- formyl chloride and 1 part of dichloro vanadyl are added to reaction kettle
In, temperature control is to subzero 7 DEG C, after mixing evenly, 800 parts of the concentrated sulfuric acid is added, is after mixing added to 100 parts of chitosan
In reaction kettle, subzero 15 DEG C of temperature control, 18h is reacted, reaction system is then poured into precipitating in acetone, is then neutralized with ammonium hydroxide, mistake
Filter, solid product is washed to neutrality,
100 parts of the solid obtained, 5 parts of calcium chloride and 2 parts of alginic acid are placed in 800 parts of isopropanol, and 48 DEG C of temperature control,
7h is reacted, then solvent evaporated, can be obtained the vanadium doping anti-biotic material.
The fermenting enzyme is cellulase, white-rot fungi, lignoenzyme, zytase and saccharomycete proportionally 1:
0.5:0.8:0.4:1.2 is uniformly mixed and obtains.
The filler is titanium dioxide.
The defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether.
The Anti-microbial paper material of this experiment preparation is 5.1mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 7.2mm.
Embodiment 2
A kind of preparation method of vanadium doping antibacterial papermaking material, technology of preparing scheme are as follows:
According to mass fraction, by 5 parts of grass stalk, 10 parts of stalk, 12 parts of bagasse, 2 parts of carboxymethyl celluloses and 50 parts
Water be added to beater mashing and stir into slurries, be then heated to 90 DEG C, keep the temperature 1h, will so that the fiber separation in paddle liquid
30 parts of thermoplastic starch are added in system, stir 10min, 1 part of fermenting enzyme are then added, after mixing evenly 30 DEG C of temperature control,
Ferment 10h；After completing fermentation, then washing precipitating is added 1 part of vanadium doping anti-biotic material and 5 parts of filler, raw material is coagulated
It is poly-, it then carries out dehydration and forms paste, then add 1 part of defoaming agent and 3 parts of brightening agents stir evenly, continue to be beaten 10min,
Then 5 parts of sizing agents are added, are stirred evenly, is coated with, is dehydrated, suppresses, cuts, packs, a kind of vanadium can be obtained
Adulterate antibacterial papermaking material.
The vanadium doping anti-biotic material is prepared in accordance with the following methods:
According to mass fraction, by 0.01 part of 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquinoline -4- carbonyl of 1 part of 6-
Acyl chlorides, 0.05 part of aminoguanidine sulfonate, 1 part of 5- benzofurane -2- formyl chloride and 0.5 part of dichloro vanadyl are added to reaction
In kettle, temperature control is to subzero 5 DEG C, after mixing evenly, 400 parts of the concentrated sulfuric acid is added, 100 parts of chitosan is added after mixing
Into reaction kettle, subzero 10 DEG C of temperature control, 10h is reacted, reaction system is then poured into precipitating in acetone, is then neutralized with ammonium hydroxide,
Filtering, solid product is washed to neutrality,
100 parts of the solid obtained, 1 part of calcium chloride and 0.1 part of alginic acid are placed in 400 parts of isopropanol, temperature control 40
DEG C, 5h is reacted, then solvent evaporated, can be obtained the vanadium doping anti-biotic material.
The fermenting enzyme is cellulase, white-rot fungi, lignoenzyme, zytase and saccharomycete proportionally 1:
0.2:0.5:0.1:0.6 is uniformly mixed and obtains.
The filler is talcum powder.
The defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether.
The Anti-microbial paper material of this experiment preparation is 4.8mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 6.7mm.
Embodiment 3
A kind of preparation method of vanadium doping antibacterial papermaking material, technology of preparing scheme are as follows:
According to mass fraction, by 20 parts of grass stalk, 14 parts of stalk, 28 parts of bagasse, 8 parts of carboxymethyl celluloses and 80 parts
Water be added to beater mashing and stir into slurries, be then heated to 105 DEG C, keep the temperature 5h, will so that the fiber separation in paddle liquid
50 parts of thermoplastic starch are added in system, stir 30min, 5 parts of fermenting enzyme are then added, after mixing evenly 50 DEG C of temperature control,
Ferment 40h；After completing fermentation, then washing precipitating is added 10 parts of vanadium doping anti-biotic material and 10 parts of filler, raw material is coagulated
It is poly-, it then carries out dehydration and forms paste, then add 5 parts of defoaming agent and 8 parts of brightening agents stir evenly, continue to be beaten 30min,
Then 10 parts of sizing agents are added, are stirred evenly, is coated with, is dehydrated, suppresses, cuts, packs, a kind of vanadium can be obtained
Adulterate antibacterial papermaking material.
The vanadium doping anti-biotic material is prepared in accordance with the following methods:
According to mass fraction, by 0.1 part of 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquinoline -4- carbonyl acyl of 5 parts of 6-
Chlorine, 0.5 part of aminoguanidine sulfonate, 5 parts of 5- benzofurane -2- formyl chloride and 2 parts of dichloro vanadyl are added in reaction kettle,
Temperature control is to subzero 10 DEG C, after mixing evenly, 1000 parts of the concentrated sulfuric acid is added, is after mixing added to 100 parts of chitosan
In reaction kettle, subzero 20 DEG C of temperature control, 30h is reacted, reaction system is then poured into precipitating in acetone, is then neutralized with ammonium hydroxide, mistake
Filter, solid product is washed to neutrality,
100 parts of the solid obtained, 10 parts of calcium chloride and 5 parts of alginic acid are placed in 1000 parts of isopropanol, temperature control 60
DEG C, 10h is reacted, then solvent evaporated, can be obtained the vanadium doping anti-biotic material.
The fermenting enzyme is cellulase, white-rot fungi, lignoenzyme, zytase and saccharomycete proportionally 1:
0.8:1:0.8:1.8 is uniformly mixed and obtains.
The filler is Paris white.
The defoaming agent is polypropylene glycerol aether.
The Anti-microbial paper material of this experiment preparation is 5.5mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 7.7mm.
Embodiment 4
A kind of preparation method of vanadium doping antibacterial papermaking material, technology of preparing scheme are as follows:
According to mass fraction, by 5 parts of grass stalk, 10 parts of stalk, 12 parts of bagasse, 2 parts of carboxymethyl celluloses and 50 parts
Water be added to beater mashing and stir into slurries, be then heated to 90 DEG C, keep the temperature 1h, will so that the fiber separation in paddle liquid
30 parts of thermoplastic starch are added in system, stir 10min, 1 part of fermenting enzyme are then added, after mixing evenly 30 DEG C of temperature control,
Ferment 10h；After completing fermentation, then washing precipitating is added 1 part of vanadium doping anti-biotic material and 5 parts of filler, raw material is coagulated
It is poly-, it then carries out dehydration and forms paste, then add 1 part of defoaming agent and 3 parts of brightening agents stir evenly, continue to be beaten 10min,
Then 5 parts of sizing agents are added, are stirred evenly, is coated with, is dehydrated, suppresses, cuts, packs, a kind of vanadium can be obtained
Adulterate antibacterial papermaking material.
The vanadium doping anti-biotic material is prepared in accordance with the following methods:
According to mass fraction, by 0.01 part of 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquinoline -4- carbonyl of 1 part of 6-
Acyl chlorides, 0.05 part of aminoguanidine sulfonate, 5 parts of 5- benzofurane -2- formyl chloride and 0.5 part of dichloro vanadyl are added to reaction
In kettle, temperature control is to subzero 10 DEG C, after mixing evenly, 1000 parts of the concentrated sulfuric acid is added, after mixing adds 100 parts of chitosan
Enter into reaction kettle, subzero 20 DEG C of temperature control, react 16h, reaction system is then poured into precipitating in acetone, then in ammonium hydroxide
With, filtering washs solid product to neutrality,
100 parts of the solid obtained, 1 part of calcium chloride and 5 parts of alginic acid are placed in 400 parts of isopropanol, and 60 DEG C of temperature control,
5h is reacted, then solvent evaporated, can be obtained the vanadium doping anti-biotic material.
The fermenting enzyme is cellulase, white-rot fungi, lignoenzyme, zytase and saccharomycete proportionally 1:
0.8:0.5:0.1:0.6 is uniformly mixed and obtains.
The filler is Paris white.
The defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether.
The Anti-microbial paper material of this experiment preparation is 5.2mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 7.5mm.
Embodiment 5
A kind of preparation method of vanadium doping antibacterial papermaking material, technology of preparing scheme are as follows:
According to mass fraction, by 20 parts of grass stalk, 14 parts of stalk, 28 parts of bagasse, 8 parts of carboxymethyl celluloses and 80 parts
Water be added to beater mashing and stir into slurries, be then heated to 105 DEG C, keep the temperature 5h, will so that the fiber separation in paddle liquid
50 parts of thermoplastic starch are added in system, stir 30min, 5 parts of fermenting enzyme are then added, after mixing evenly 50 DEG C of temperature control,
Ferment 40h；After completing fermentation, then washing precipitating is added 10 parts of vanadium doping anti-biotic material and 10 parts of filler, raw material is coagulated
It is poly-, it then carries out dehydration and forms paste, then add 5 parts of defoaming agent and 8 parts of brightening agents stir evenly, continue to be beaten 30min,
Then 10 parts of sizing agents are added, are stirred evenly, is coated with, is dehydrated, suppresses, cuts, packs, a kind of vanadium can be obtained
Adulterate antibacterial papermaking material.
The vanadium doping anti-biotic material is prepared in accordance with the following methods:
According to mass fraction, by 0.1 part of 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquinoline -4- carbonyl acyl of 4 parts of 6-
Chlorine, 0.5 part of aminoguanidine sulfonate, 1 part of 5- benzofurane -2- formyl chloride and 2 parts of dichloro vanadyl are added in reaction kettle,
Temperature control is to subzero 5 DEG C, after mixing evenly, 600 parts of the concentrated sulfuric acid is added, is after mixing added to 100 parts of chitosan instead
It answers in kettle, subzero 10 DEG C of temperature control, reacts 18h, reaction system is then poured into precipitating in acetone, is then neutralized with ammonium hydroxide, filter,
Solid product is washed to neutrality,
100 parts of the solid obtained, 8 parts of calcium chloride and 0.2 part of alginic acid are placed in 1000 parts of isopropanol, temperature control 60
DEG C, 5h is reacted, then solvent evaporated, can be obtained the vanadium doping anti-biotic material.
The fermenting enzyme is cellulase, white-rot fungi, lignoenzyme, zytase and saccharomycete proportionally 1:
0.2:0.5:0.1:1.8 is uniformly mixed and obtains.
The filler is titanium dioxide.
The defoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether.
The Anti-microbial paper material of this experiment preparation is 5.3mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 7.4mm.
Comparative example 1
1- propyl sulfonic acid -3- methylimidazole villaumite, the other the same as in Example 1 is not added.
The Anti-microbial paper material of this experiment preparation is 4.1mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 6.3mm.
Comparative example 2
The bromo- 2- chloroquinoline -4- dicarbonyl chloride of 6-, the other the same as in Example 1 is not added.
The Anti-microbial paper material of this experiment preparation is 3.8mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 4.2mm.
Comparative example 3
Aminoguanidine sulfonate, the other the same as in Example 1 is not added.
The Anti-microbial paper material of this experiment preparation is 4.2mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 5.1mm.
Comparative example 4
5- benzofurane -2- formyl chloride, the other the same as in Example 1 is not added.
The Anti-microbial paper material of this experiment preparation is 3.6mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 4.8mm.
Comparative example 5
Dichloro vanadyl, the other the same as in Example 1 is not added.
The Anti-microbial paper material of this experiment preparation is 4.1mm to the antibacterial circle of gramnegative bacterium, thin to Gram-positive
The antibacterial circle of bacterium is 2.5mm.
Claims (5)
1. a kind of preparation method of vanadium doping antibacterial papermaking material, technology of preparing scheme are as follows:
It is according to mass fraction, 5-20 parts of grass stalk, 10-14 parts of stalk, 12-28 parts of bagasse, 2-8 parts of carboxymethyls are fine
Dimension element and 50-80 parts of water are added to beater mashing and stir into slurries, are then heated to 90-105 DEG C, keep the temperature 1-5h, so that
30-50 parts of thermoplastic starch are added in system by the fiber separation in paddle liquid, stir 10-30min, are then added 1-5 parts
Fermenting enzyme, 30-50 DEG C of temperature control after mixing evenly, ferment 10-40h；After completing fermentation, then washing precipitating is added 1-10 parts
Vanadium doping anti-biotic material and 5-10 parts of filler, raw material is agglomerated, and is then carried out dehydration and is formed paste, then adds 1-5 parts
Defoaming agent and 3-8 parts of brightening agents stir evenly, and continue to be beaten 10-30min, then add 5-10 parts of sizing agents, stir evenly, apply
Cloth is dehydrated, suppresses, cuts, is packed, and a kind of vanadium doping antibacterial papermaking material can be obtained.
2. a kind of preparation method of vanadium doping antibacterial papermaking material according to claim 1, it is characterised in that: the vanadium
Doping anti-biotic material is prepared in accordance with the following methods:
According to mass fraction, by 0.01-0.1 parts of 1- propyl sulfonic acid -3- methylimidazole villaumite, the bromo- 2- chloroquine of 1-5 parts of 6-
Quinoline -4- dicarbonyl chloride, 0.05-0.5 parts of aminoguanidine sulfonate, 1-5 parts of 5- benzofurane -2- formyl chloride and the two of 0.5-2 parts
Chlorine vanadyl is added in reaction kettle, and temperature control is to subzero 5-10 DEG C, after mixing evenly, 400-1000 parts of the concentrated sulfuric acid, mixing is added
100 parts of chitosan is added in reaction kettle after uniformly, subzero 10-20 DEG C of temperature control, 10-30h is reacted, then by reaction system
Precipitating in acetone is poured into, is then neutralized with ammonium hydroxide, filters, solid product is washed to neutrality, 100 parts of the solid obtained, 1-
The alginic acid of 10 parts of calcium chloride and 0.1-5 part is placed in 400-1000 parts of isopropanol, 40-60 DEG C of temperature control, reacts 5-
10h, then solvent evaporated, can be obtained the vanadium doping anti-biotic material.
3. a kind of preparation method of vanadium doping antibacterial papermaking material according to claim 1, it is characterised in that: the hair
Ferment enzyme is cellulase, white-rot fungi, lignoenzyme, zytase and saccharomycete proportionally 1:0.2-0.8:0.5-1:0.1-
0.8:0.6-1.8 is uniformly mixed and obtains.
4. a kind of preparation method of vanadium doping antibacterial papermaking material according to claim 1, it is characterised in that: described fills out
Material is titanium dioxide or talcum powder or Paris white.
5. a kind of preparation method of vanadium doping antibacterial papermaking material according to claim 1, it is characterised in that: described disappears
Infusion is polyoxyethylene polyoxypropylene pentaerythrite ether or polyoxyethylene polyoxy propyl alcohol amidogen ether or polypropylene glycerol aether.
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| CN110644278A (en) * | 2019-10-22 | 2020-01-03 | 新疆弘瑞达纤维有限公司 | Environment-friendly paper and preparation method thereof |
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