CN109137514A - A kind of non-ironing cotton fabric and preparation method thereof - Google Patents
A kind of non-ironing cotton fabric and preparation method thereof Download PDFInfo
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- CN109137514A CN109137514A CN201810862816.3A CN201810862816A CN109137514A CN 109137514 A CN109137514 A CN 109137514A CN 201810862816 A CN201810862816 A CN 201810862816A CN 109137514 A CN109137514 A CN 109137514A
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- 239000004744 fabric Substances 0.000 title claims abstract description 80
- 238000010409 ironing Methods 0.000 title claims abstract description 22
- 229920000742 Cotton Polymers 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title description 3
- -1 polysiloxane Polymers 0.000 claims abstract description 27
- 108010022355 Fibroins Proteins 0.000 claims abstract description 18
- 238000005406 washing Methods 0.000 claims abstract description 16
- 229940008099 dimethicone Drugs 0.000 claims abstract description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 11
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 11
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 11
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 108091005804 Peptidases Proteins 0.000 claims abstract description 9
- 239000004365 Protease Substances 0.000 claims abstract description 9
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 9
- 235000019419 proteases Nutrition 0.000 claims abstract description 9
- 241000193744 Bacillus amyloliquefaciens Species 0.000 claims abstract description 8
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 8
- 239000000600 sorbitol Substances 0.000 claims abstract description 8
- 101000693530 Staphylococcus aureus Staphylokinase Proteins 0.000 claims abstract description 7
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzenetricarboxylic Acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 36
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 229910021589 Copper(I) bromide Inorganic materials 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- 150000001412 amines Chemical class 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims description 14
- CVEPFOUZABPRMK-UHFFFAOYSA-N 2-methylprop-2-enoic acid;styrene Chemical compound CC(=C)C(O)=O.C=CC1=CC=CC=C1 CVEPFOUZABPRMK-UHFFFAOYSA-N 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 12
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 12
- 239000006228 supernatant Substances 0.000 claims description 10
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 9
- 230000008859 change Effects 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 7
- 238000000502 dialysis Methods 0.000 claims description 6
- 229940059936 lithium bromide Drugs 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000012265 solid product Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- KIRNHRJGEAFKPM-UHFFFAOYSA-N 5-nitro-1,2,3-benzenetricarboxylic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC(C(O)=O)=C1C(O)=O KIRNHRJGEAFKPM-UHFFFAOYSA-N 0.000 claims description 2
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 108090000790 Enzymes Proteins 0.000 claims description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- 238000005119 centrifugation Methods 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- 108090000623 proteins and genes Proteins 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- 241000193830 Bacillus <bacterium> Species 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 230000037303 wrinkles Effects 0.000 abstract description 4
- NVKJOXRVEKMMHS-UHFFFAOYSA-N 5-nitro-1,2,4-triazol-3-one Chemical compound [O-][N+](=O)C1=NC(=O)N=N1 NVKJOXRVEKMMHS-UHFFFAOYSA-N 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 235000014103 egg white Nutrition 0.000 description 3
- 210000000969 egg white Anatomy 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical group [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 238000007655 standard test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000004855 creaseproofing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical group [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/392—Nitroso compounds; Nitro compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
- D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/45—Shrinking resistance, anti-felting properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of preparation methods of non-ironing cotton fabric, first choice is grafted macromolecule polyalcohol in web surface, it is dipped in the sorbitol solution containing PEG-400 and neopelex and handles 30-50min, it is hydrolyzed after useless silk is completely dissolved with bacillus amyloliquefaciens protease and neutral proteinase, fibroin albumen hydrolyzate is made, by 15-30 parts of fibroin albumen hydrolyzate, 8-16 parts of amino modified polysiloxane, 5- nitro -1, 2, 6-12 parts of 3- benzenetricarboxylic acid, 5-10 parts of dimethicone carry out being mixed to get mixed liquor, by treated, fabric immerses in mixed liquor, moisture is dried after stirring 1-3h, fabric is carried out to dry obtained product.Fabric washing shrinkage produced by the present invention is low, and washing rear stability is good, while fabric has good restorative and flatness, is not easy wrinkle, which is easy to arrange, is comfortable and easy to wear, therefore has extensive prospect as a kind of non-ironing face fabric.
Description
Technical field
The invention belongs to textile technology fields, and in particular to a kind of non-ironing cotton fabric and preparation method thereof.
Background technique
Cotton fabric function admirable, such as good hygroscopicity, good permeability and good hand touch, but elasticity and recovery are poor, wash
It is not easy to arrange after washing, is also easy to produce violent contraction in textile printing and dyeing or take during, is not able to maintain smooth appearance, therefore,
Anti-crease finishing is carried out to cotton fabric, improves its elasticity, improves its dry, hygrometric state wrinkle resistance, it has also become the problem of urgent need to resolve.It passes
The fabric that system crease proofing agent (N- methylol amide class compound) arranges can be decomposed or be released in storage or wearing process
Formaldehyde influences health of human body.With being increasingly enhanced for environmentally protective consciousness, developing natural non-ironing face fabric is that inevitable development becomes
Gesture has great importance.
Summary of the invention
The technical problems to be solved by the invention: it is directed to cotton fabric poor mechanical property, in mechanicals efforts or high temperature
Folding Deformation easily occurs for condition lower fabric, causes fabric must not be without frequent ironing, to influence fabric quality and use the longevity
Life, the present invention provides a kind of preparation methods of non-ironing cotton fabric, improve face in cotton fabric surface grafting macromolecular first
The mechanical property and mechanical strength of material, then by the fabric of macromolecular grafting with containing PEG-400 and neopelex
Sorbitol solution carries out infiltration processing, improves the absorbability to subsequent solvent, then again with fibroin albumen hydrolyzate, amino modified
Polysiloxanes, 5- nitro -1,2,3- benzenetricarboxylic acid, dimethicone carry out soft crease-resistant processing, non-ironing cotton fabric are made.
Technical scheme is as follows:
A kind of preparation method of non-ironing cotton fabric, comprising the following steps:
(1) in round-bottomed flask be added volume ratio be 1:1 ethanol/water solution, fabric is placed in solution be immersed into liquid level with
Under, polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr are sequentially added under the stirring of 100-200r/min revolving speed, are stirred
After mixing 10-20min, three (dimethylamino-propyl) amine and initiator is added, 50-70 DEG C is then raised the temperature to, to reactant
Nitrogen is filled in system carries out reaction under anaerobic, keeps this thermotonus 2-4h, reaction temperature is down to room naturally
Temperature takes out fabric and carries out washing drying to it to get macromolecular grafting fabric；Wherein polyethylene glycol methacrylate-styrene polymer, three
Ethamine, CuBr, three (dimethylamino-propyl) amine and ammonium persulfate molar ratio be (8-15): (3-5): (2-6): (1-5): (1-
3)；
(2) by useless silk be dipped in the sodium bicarbonate solution of 1-2% in 100 DEG C boil in solution handle 20-30min after, will be anti-
It answers object to be cleaned to obtain solid product with water, is dried in 60 DEG C of baking oven；Solids after drying is added 60-65 DEG C
It is dissolved in the saturation lithium-bromide solution of 9.3M, is then loaded into bag filter and dialyses, change a water every 2-3h,
It dialyses 4-6 times altogether, the solution after dialysis is centrifuged with the centrifugal rotational speed of 3000-5000r/min, collect supernatant；Upwards
The neutral protein that final vigor concentration is 50-100U/mL bacillus amyloliquefaciens protease and 30-50U/mL is added in clear liquid
Enzyme is stirred at room temperature processing 1-2h, is then centrifuged solution with the super filter tube that molecular cut off is 10K, collects centrifugation
Liquid out is to get fibroin albumen hydrolyzate；
(3) the grafting fabric of macromolecular made from step (1) is immersed into PEG-400 containing 30-60% and 20-50% detergent alkylate sulphur
Then 30-50min in the sorbitol solution of sour sodium dries the moisture of web surface；
(4) by 15-30 parts of fibroin albumen hydrolyzate made from step (2), 8-16 parts of amino modified polysiloxane, nitro -1 5-,
2,3- 6-12 parts of benzenetricarboxylic acids, 5-10 parts of dimethicone carry out being mixed to get mixed liquor, step (3) treated fabric is immersed
In mixed liquor, moisture is dried after stirring 1-3h, fabric is carried out to dry obtained product.
Further, the initiator is persulfate.
Preferably, the polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr, three (dimethylamino-propyl) amine and over cure
The molar ratio of sour ammonium is 12:4:4:3:2.
Preferably, the final vigor of the bacillus amyloliquefaciens protease and neutral proteinase be respectively 75U/mL and
40U/mL。
Preferably, 22 parts of fibroin albumen hydrolyzate, 12 parts of amino modified polysiloxane, nitro -1 5- in the step (4),
9 parts of 2,3- benzenetricarboxylic acid, 8 parts of dimethicone.
The utility model has the advantages that the present invention provides a kind of preparation methods of non-ironing cotton fabric, first by connecing in web surface
Branch large biological molecule, improves the crosslink density of web surface, improves shrinkage, is then put into containing PEG-400 and 12
In the sorbierite of sodium alkyl benzene sulfonate, improving, fabric is infiltrative while increasing PEG-400 and neopelex pair
The effect of fabric reduces web surface tension, then is dipped in fibroin albumen hydrolyzate, amino modified polysiloxane, 5- nitro-
In 1,2,3- benzenetricarboxylic acid, dimethicone mixed liquor, the pliability and resilience of fabric are improved.By being obtained from test result,
Fabric washing shrinkage produced by the present invention is low, and washing rear stability is good, while fabric has good recovery and flatness, no
Easy wrinkle, the fabric are easy to arrange, are comfortable and easy to wear, therefore have extensive prospect as a kind of non-ironing face fabric.
Specific embodiment
The invention will now be further described with reference to specific embodiments, but examples are merely exemplary, not to this hair
Bright range constitutes any restrictions.It will be understood by those skilled in the art that without departing from the spirit and scope of the invention
Can with the details and forms of the technical scheme of the invention are modified or replaced, but these modification and replacement each fall within it is of the invention
In protection scope.
Embodiment 1
A kind of preparation method of non-ironing cotton fabric, comprising the following steps:
(1) in round-bottomed flask be added volume ratio be 1:1 ethanol/water solution, fabric is placed in solution be immersed into liquid level with
Under, polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr are sequentially added under the stirring of 150r/min revolving speed, are stirred
After 15min, three (dimethylamino-propyl) amine and initiator is added, then raises the temperature to 60 DEG C, is filled with into reaction system
Nitrogen carries out reaction under anaerobic, keeps this thermotonus 3h, and reaction temperature is down to room temperature naturally, takes out fabric
And washing drying is carried out to it and is grafted fabric to get macromolecular；Wherein polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr, three
The molar ratio of (dimethylamino-propyl) amine and ammonium persulfate is 12:4:4:3:2；
(2) by useless silk be dipped in 1.5% sodium bicarbonate solution in 100 DEG C boil in solution handle 25min after, will react
Object is cleaned to obtain solid product with water, is dried in 60 DEG C of baking oven；60-65 DEG C of 9.3M is added in solids after drying
Saturation lithium-bromide solution in dissolved, be then loaded into bag filter and dialyse, change a water every 2-3h, it is saturating altogether
Analysis 5 times, the solution after dialysis is centrifuged with the centrifugal rotational speed of 4000r/min, collects supernatant；It is added most into supernatant
Whole vigor concentration is the neutral proteinase of 75U/mL bacillus amyloliquefaciens protease and 40U/mL, and processing is stirred at room temperature
Then solution is centrifuged by 1.5h with the super filter tube that molecular cut off is 10K, collect the liquid being centrifuged out to get fibroin egg
White hydrolyzate；
(3) the grafting fabric of macromolecular made from step (1) is immersed containing 45% PEG-400 and 35% neopelex
Then 40min in sorbitol solution dries the moisture of web surface；
(4) by 22 parts of fibroin albumen hydrolyzate made from step (2), 12 parts of amino modified polysiloxane, 5- nitro -1,2,3- benzene
Three 9 parts, 8 parts of dimethicone of acid carry out being mixed to get mixed liquor, and step (3) treated fabric is immersed in mixed liquor, is stirred
Moisture is dried after mixing 2h, fabric is carried out to dry obtained product.
The initiator is sodium peroxydisulfate.
Embodiment 2
A kind of preparation method of non-ironing cotton fabric, comprising the following steps:
(1) in round-bottomed flask be added volume ratio be 1:1 ethanol/water solution, fabric is placed in solution be immersed into liquid level with
Under, polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr are sequentially added under the stirring of 100r/min revolving speed, are stirred
After 10min, three (dimethylamino-propyl) amine and initiator is added, then raises the temperature to 50 DEG C, is filled with into reaction system
Nitrogen carries out reaction under anaerobic, keeps this thermotonus 2h, and reaction temperature is down to room temperature naturally, takes out fabric
And washing drying is carried out to it and is grafted fabric to get macromolecular；Wherein polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr, three
The molar ratio of (dimethylamino-propyl) amine and ammonium persulfate is 8:3:2:1:1；
(2) by useless silk be dipped in 1% sodium bicarbonate solution in 100 DEG C boil in solution handle 20min after, by reactant
It is cleaned to obtain solid product with water, be dried in 60 DEG C of baking oven；Solids after drying is added 60-65 DEG C of 9.3M's
It is dissolved in saturation lithium-bromide solution, is then loaded into bag filter and dialyses, change a water every 2-3h, dialysed altogether
4 times, the solution after dialysis is centrifuged with the centrifugal rotational speed of 3000r/min, collects supernatant；It is added into supernatant final
Vigor concentration is the neutral proteinase of 50U/mL bacillus amyloliquefaciens protease and 30U/mL, and processing is stirred at room temperature
Then solution is centrifuged by 1h with the super filter tube that molecular cut off is 10K, collect the liquid being centrifuged out to get fibroin albumen
Hydrolyzate；
(3) the grafting fabric of macromolecular made from step (1) is immersed containing 30% PEG-400 and 20% neopelex
Then 30min in sorbitol solution dries the moisture of web surface；
(4) by 15 parts of fibroin albumen hydrolyzate made from step (2), 8 parts of amino modified polysiloxane, 5- nitro -1,2,3- benzene
Three 6 parts, 5 parts of dimethicone of acid carry out being mixed to get mixed liquor, and step (3) treated fabric is immersed in mixed liquor, is stirred
Moisture is dried after mixing 1-3h, fabric is carried out to dry obtained product.
The initiator is ammonium persulfate.
Embodiment 3
A kind of preparation method of non-ironing cotton fabric, comprising the following steps:
(1) in round-bottomed flask be added volume ratio be 1:1 ethanol/water solution, fabric is placed in solution be immersed into liquid level with
Under, polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr are sequentially added under the stirring of 120r/min revolving speed, are stirred
After 12min, three (dimethylamino-propyl) amine and initiator is added, then raises the temperature to 55 DEG C, is filled with into reaction system
Nitrogen carries out reaction under anaerobic, keeps this thermotonus 2.5h, reaction temperature is down to room temperature naturally, taking-up is knitted
Object simultaneously carries out washing drying to it to get macromolecular grafting fabric；Wherein polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr,
The molar ratio of three (dimethylamino-propyl) amine and ammonium persulfate is 10:3.5:3:2:1.5；
(2) by useless silk be dipped in 1.2% sodium bicarbonate solution in 100 DEG C boil in solution handle 22min after, will react
Object is cleaned to obtain solid product with water, is dried in 60 DEG C of baking oven；60-65 DEG C of 9.3M is added in solids after drying
Saturation lithium-bromide solution in dissolved, be then loaded into bag filter and dialyse, change a water every 2-3h, it is saturating altogether
Analysis 5 times, the solution after dialysis is centrifuged with the centrifugal rotational speed of 3500r/min, collects supernatant；It is added most into supernatant
Whole vigor concentration is the neutral proteinase of 60U/mL bacillus amyloliquefaciens protease and 35U/mL, and processing is stirred at room temperature
Then solution is centrifuged by 1.2h with the super filter tube that molecular cut off is 10K, collect the liquid being centrifuged out to get fibroin egg
White hydrolyzate；
(3) the grafting fabric of macromolecular made from step (1) is immersed containing 40% PEG-400 and 30% neopelex
Then 35min in sorbitol solution dries the moisture of web surface；
(4) by 20 parts of fibroin albumen hydrolyzate made from step (2), 10 parts of amino modified polysiloxane, 5- nitro -1,2,3- benzene
Three 8 parts, 6 parts of dimethicone of acid carry out being mixed to get mixed liquor, and step (3) treated fabric is immersed in mixed liquor, is stirred
Moisture is dried after mixing 1.2h, fabric is carried out to dry obtained product.
The initiator is potassium peroxydisulfate.
Embodiment 4
A kind of preparation method of non-ironing cotton fabric, comprising the following steps:
(1) in round-bottomed flask be added volume ratio be 1:1 ethanol/water solution, fabric is placed in solution be immersed into liquid level with
Under, polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr are sequentially added under the stirring of 200r/min revolving speed, are stirred
After 20min, three (dimethylamino-propyl) amine and initiator is added, then raises the temperature to 50-70 DEG C, is filled into reaction system
Entering nitrogen carries out reaction under anaerobic, keeps this thermotonus 4h, reaction temperature is down to room temperature naturally, taking-up is knitted
Object simultaneously carries out washing drying to it to get macromolecular grafting fabric；Wherein polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr,
The molar ratio of three (dimethylamino-propyl) amine and ammonium persulfate is 15:5:6:5:3；
(2) by useless silk be dipped in 2% sodium bicarbonate solution in 100 DEG C boil in solution handle 30min after, by reactant
It is cleaned to obtain solid product with water, be dried in 60 DEG C of baking oven；Solids after drying is added 60-65 DEG C of 9.3M's
It is dissolved in saturation lithium-bromide solution, is then loaded into bag filter and dialyses, change a water every 2-3h, dialysed altogether
6 times, the solution after dialysis is centrifuged with the centrifugal rotational speed of 5000r/min, collects supernatant；It is added into supernatant final
Vigor concentration is the neutral proteinase of 50-100U/mL bacillus amyloliquefaciens protease and 50U/mL, and place is stirred at room temperature
2h is managed, solution is centrifuged with the super filter tube that molecular cut off is 10K then, collects the liquid being centrifuged out to get fibroin egg
White hydrolyzate；
(3) the grafting fabric of macromolecular made from step (1) is immersed containing 60% PEG-400 and 50% neopelex
Then 50min in sorbitol solution dries the moisture of web surface；
(4) by 30 parts of fibroin albumen hydrolyzate made from step (2), 16 parts of amino modified polysiloxane, 5- nitro -1,2,3- benzene
Three 12 parts, 10 parts of dimethicone of acid carry out being mixed to get mixed liquor, and step (3) treated fabric is immersed in mixed liquor,
Moisture is dried after stirring 3h, fabric is carried out to dry obtained product.
The initiator is ammonium persulfate.
Fabric produced by the present invention is subjected to following performance test,
Elastic index: ASTM D 3107-2003 " standard test method of stretch yarn weaving object stretch performance "；
Ultimate strength: ASTM D 5035- 2003 " standard test method (galley proof method) of textile fabric ultimate strength and elongation "；
Washing shrinkage: AATCC 135- 2004 " change in size of the fabric after home washings "；
Tearing brute force: " impact pendulnm method measures tearing brute force (Elmendorf) "；
Flatness: AATCC 124- 2006 " appearance for repeating fabric after home washings ".
Test result is as shown in table 1, obtains from table 1, and fabric washing shrinkage produced by the present invention is low, and washing rear stability is good
It is good, while fabric has good restorative and flatness, is not easy wrinkle, which is easy to arrange, is comfortable and easy to wear, therefore conduct
A kind of non-ironing face fabric has extensive prospect.
Table 1
Claims (5)
1. a kind of preparation method of non-ironing cotton fabric, which comprises the following steps:
(1) in round-bottomed flask be added volume ratio be 1:1 ethanol/water solution, fabric is placed in solution be immersed into liquid level with
Under, polyethylene glycol methacrylate-styrene polymer, triethylamine, CuBr are sequentially added under the stirring of 100-200r/min revolving speed, are stirred
After mixing 10-20min, three (dimethylamino-propyl) amine and initiator is added, 50-70 DEG C is then raised the temperature to, to reactant
Nitrogen is filled in system carries out reaction under anaerobic, keeps this thermotonus 2-4h, reaction temperature is down to room naturally
Temperature takes out fabric and carries out washing drying to it to get macromolecular grafting fabric；Wherein polyethylene glycol methacrylate-styrene polymer, three
Ethamine, CuBr, three (dimethylamino-propyl) amine and ammonium persulfate molar ratio be (8-15): (3-5): (2-6): (1-5): (1-
3)；
(2) by useless silk be dipped in the sodium bicarbonate solution of 1-2% in 100 DEG C boil in solution handle 20-30min after, will be anti-
It answers object to be cleaned to obtain solid product with water, is dried in 60 DEG C of baking oven；Solids after drying is added 60-65 DEG C
It is dissolved in the saturation lithium-bromide solution of 9.3M, is then loaded into bag filter and dialyses, change a water every 2-3h,
It dialyses 4-6 times altogether, the solution after dialysis is centrifuged with the centrifugal rotational speed of 3000-5000r/min, collect supernatant；Upwards
The neutral protein that final vigor concentration is 50-100U/mL bacillus amyloliquefaciens protease and 30-50U/mL is added in clear liquid
Enzyme is stirred at room temperature processing 1-2h, is then centrifuged solution with the super filter tube that molecular cut off is 10K, collects centrifugation
Liquid out is to get fibroin albumen hydrolyzate；
(3) the grafting fabric of macromolecular made from step (1) is immersed into PEG-400 containing 30-60% and 20-50% detergent alkylate sulphur
Then 30-50min in the sorbitol solution of sour sodium dries the moisture of web surface；
(4) by 15-30 parts of fibroin albumen hydrolyzate made from step (2), 8-16 parts of amino modified polysiloxane, nitro -1 5-,
2,3- 6-12 parts of benzenetricarboxylic acids, 5-10 parts of dimethicone carry out being mixed to get mixed liquor, step (3) treated fabric is immersed
In mixed liquor, moisture is dried after stirring 1-3h, fabric is carried out to dry obtained product.
2. a kind of preparation method of non-ironing cotton fabric according to claim 1, which is characterized in that the initiator was
Sulfate.
3. a kind of preparation method of non-ironing cotton fabric according to claim 1, which is characterized in that the polyethylene glycol first
Base acrylate, triethylamine, CuBr, three (dimethylamino-propyl) amine and ammonium persulfate molar ratio be 12:4:4:3:2.
4. a kind of preparation method of non-ironing cotton fabric according to claim 1, which is characterized in that the starch liquefacation bud
The final vigor of spore Bacillus protease and neutral proteinase is respectively 75U/mL and 40U/mL.
5. a kind of preparation method of non-ironing cotton fabric according to claim 1, which is characterized in that in the step (4)
22 parts of fibroin albumen hydrolyzate, 12 parts of amino modified polysiloxane, 9 parts, 8 parts of dimethicone of 5- nitro -1,2,3- benzenetricarboxylic acid.
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