CN109137089A - A kind of ramie soak and combination of enzyme preparations object and its application method for ramie raw materials degumming - Google Patents
A kind of ramie soak and combination of enzyme preparations object and its application method for ramie raw materials degumming Download PDFInfo
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
- D01C1/00—Treatment of vegetable material
- D01C1/02—Treatment of vegetable material by chemical methods to obtain bast fibres
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Abstract
A kind of ramie soak and combination of enzyme preparations object and its application method for ramie raw materials degumming, the ramie soak for ramie raw materials degumming includes the fatty alcohol polyoxyethylene ether that mass percent is 0.5%~5% and the sodium alkyl sulfonate that mass percent is 0.5%~2%, remaining is water.When impregnating the ramie raw materials, the temperature of the ramie soak should be maintained at 95 DEG C~100 DEG C.The combination of enzyme preparations object for ramie raw materials degumming is grouped as by each group of following mass percent: 25%~45% pectase, 15%~20% zytase, 10%~15% mannase, 5%~15% rhamnosidase, 20%~25% auxiliary agent.Hemicellulose and pectin are peeled away from fiber from plant cell wall using the method for novel biological degumming agent for ramie raw materials, and by the synergistic effect of various enzymes, depolymerized pectin and hemicellulose.Since biological complex enzyme action condition is mild, the incomplete problem of pectin degrading is fundamentally relieved, the pollution largely with a large amount of highly basic to environment is avoided.
Description
Technical field
The invention belongs to the preparation technical field of ramie, especially a kind of ramie soak for ramie raw materials degumming
With combination of enzyme preparations object and its application method.
Background technique
Ramie is always the emphasis studied as a kind of bast fiber tissue, the degumming tech of ramie raw materials.Traditional ramie
Chemical degumming technique of the retting production substantially based on caustic soda.Although the degummed ramie of this production technology production is able to satisfy
The requirement of ramie comb spins, but there is also degumming long flow path, process is cumbersome, large labor intensity, the disadvantages of energy consumption is high, environmental pollution.
Simultaneously because causing portion of cellulose fibers molecular chain rupture, knot using severe conditions such as strong acid, highly basic, high temperature and pressure kierings
Brilliant degree increases, and causes the problems such as degummed ramie row yielding is low, rigidity is strong, fabric feeling is coarse.Recently as environmental protection and entirely
Journey green processing becomes the necessary condition of Sustainable Development of Enterprises, occurs much improving ramie product to reduce environmental pollution
The degumming tech of quality is studied, but is not carried out industrialization substantially at present.Ramie biological degumming technology can effectively realize ramie
The energy-saving and emission-reduction of degumming production.Currently, application experiment stage of the microbial degumming in ramie textile industry, practical in production
In, slight chemical Degumming need to be aided with toward contact.
Main group of ramie raw materials becomes cellulose, other chemical compositions in addition to fiber rope mainly have pectin, half
Cellulose and lignin, bast industry are known as colloid.Ramie fiber-spinnable in order to obtain, it is necessary to degumming first.The country has had
Biological enzyme is used for the report of China grass degumming, but pure biological enzyme degumming rate not to reach requirement, and needs and other objects
Reason, chemical method collective effect.
Summary of the invention
In view of this, the present invention provides a kind of ramie soaks and combination of enzyme preparations object for ramie raw materials degumming
And its application method, to solve the above problems.
A kind of ramie soak for ramie raw materials degumming comprising the fat that mass percent is 0.5%~5%
The sodium alkyl sulfonate that alcohol polyoxyethylene ether and mass percent are 0.5%~2%, remaining is water.Impregnating the ramie raw materials
When, the temperature of the ramie soak should be maintained at 95 DEG C~100 DEG C.
Further, it is 1%~1.5% that the ramie soak for ramie raw materials degumming, which contains mass percent,
Fatty alcohol polyoxyethylene ether and mass percent be 0.25%~1.25% sodium alkyl sulfonate.
A kind of combination of enzyme preparations object for ramie raw materials degumming, is grouped as by each group of following mass percent:
25%~45% pectase, 15%~20% zytase, 10%~15% mannase, 5%~15% mouse
Lee's glycosidase, 20%~25% auxiliary agent.
Further, the auxiliary agent is grouped as by each group of following mass percent: 40%~60% dodecyl sulphur
Sour sodium, 25%~40% sodium tripolyphosphate, 10%~20% polysorbas20.
A kind of Degumming method for ramie raw materials comprising following steps:
Ramie soak is prepared, which includes the fatty alcohol polyoxy second that mass percent is 0.5%~5%
The sodium alkyl sulfonate that alkene ether and mass percent are 0.5%~2%, remaining is water;
Ramie raw materials are immersed in 4~10h in the ramie soak, and the temperature of the ramie soak be 95 DEG C~
100℃;
After cooling to 60 DEG C~70 DEG C immersed with the ramie soak of ramie raw materials, combination of enzyme preparations object, enzymatic hydrolysis is added
6~12h, wherein the mass percent that the combination of enzyme preparations object accounts for the ramie soak is 0.1%~1%, the enzyme
Preparation compositions are grouped as by each group of following mass percent: 25%~45% pectase, 15%~20% xylan
Enzyme, 10%~15% mannase, 5%~15% rhamnosidase, 20%~25% auxiliary agent;
Room temperature is cooled to, processed ramie raw materials are eluted with water;
It makes after drying to the degummed ramie after degumming.
Further, the ramie soak contains the fatty alcohol polyoxyethylene ether and quality that mass percent is 1.5%
The sodium alkyl sulfonate that percentage is 0.75%.
Further, the ramie raw materials are immersed in 8h in the ramie soak, and the temperature of the ramie soak is
98℃。
It further, should be immersed with the ramie of ramie raw materials when cooling down to the ramie soak immersed with ramie raw materials
Soak is cooled to 65 DEG C, and the mass percent that combination of enzyme preparations object be added accounts for the ramie soak is 0.5%, and
Digest 7.5h.
Further, the combination of enzyme preparations object is grouped as by each group of following mass percent: 30% pectase,
20% zytase, 10% mannase, 15% rhamnosidase, 25% auxiliary agent.
Further, the auxiliary agent is grouped as by each group of following mass percent: 50% lauryl sodium sulfate,
30% sodium tripolyphosphate, 20% polysorbas20.
Compared with prior art, provided by the present invention for the ramie soak and combination of enzyme preparations of ramie raw materials degumming
Object is directed to the physics and chemistry and biological property of ramie raw materials, and the characteristics of combination ramie enterprise production technology, is used using ramie raw materials
The method of novel biological degumming agent from the plant cell wall (being made of pectin, lignin, hemicellulose etc.) hemicellulose with
Pectin is peeled away from fiber, and by the synergistic effect of various enzymes, depolymerized pectin and hemicellulose.Since biological complex enzyme is made
With mild condition, the incomplete problem of pectin degrading is fundamentally relieved, the dirt largely with a large amount of highly basic to environment is avoided
Dye.
Specific embodiment
Specific embodiments of the present invention are further elaborated below.It should be understood that herein to the present invention
The explanation of embodiment is not intended to limit the scope of protection of the present invention.
The ramie soak for ramie raw materials degumming comprising the fat that mass percent is 0.5%~5%
The sodium alkyl sulfonate that alcohol polyoxyethylene ether and mass percent are 0.5%~2%, remaining is water.The aliphatic alcohol polyethenoxy
Ether is also known as polyoxyethylene aliphatic alcohol ether, is the ether as made of polyethylene glycol (PEG) and fatty alcohol condensation, use following general formula
Indicate: RO (CH2CH2O) nH, wherein n is the degree of polymerization, is had not because the degree of polymerization of polyethylene glycol is different with the type of fatty alcohol
Same kind.The fatty alcohol polyoxyethylene ether is characterized in that the ehter bond in molecule is not easy to be destroyed by acid, alkali, so high stability,
Water-soluble preferable, electrolyte-resistant is readily biodegradable, and foam is small.Sodium alkyl sulfonate is a kind of chemical substance, anion table
There is the sulfonic group of a strongly hydrophilic to be linked with alkyl in the active agent molecule structure of face, surface-active is strong, low temperature water-soluble
Good, 2U DEG C contains 32% active matter.When impregnating the ramie raw materials, the temperature of the ramie soak serve it is conclusive, because
This in the present invention, when impregnating the ramie raw materials, the temperature of the ramie soak should be maintained at 95 DEG C~100 DEG C.
In order to which the better immersion effect reached is more advantageous to the degumming of follow-up process that is, so that the ramie is looser, it is preferable that institute
State fatty alcohol polyoxyethylene ether of the ramie soak for ramie raw materials degumming also containing mass percent 1%~1.5% and
0.25%~1.25% sodium alkyl sulfonate.Fatty alcohol polyoxyethylene ether is strong bleeding agent, can be used for various waxes, alternating
Emulsification, the dispersion of substance, prevent from adhering to;Sodium alkyl sulfonate belongs to anionic surfactant, have excellent infiltration, washing,
Wetting, decontamination and emulsification.The two uses simultaneously, has synergistic effect, greatly improves immersion efficiency, mention for post-processing
For good basis.In the present embodiment, the ramie soak contains the aliphatic alcohol polyethenoxy of mass percent 1.5%
Ether and 0.75% sodium alkyl sulfonate.Fatty alcohol polyoxyethylene ether and sodium alkyl sulfonate decontamination, emulsifying effectiveness under high temperature environment
Than increasing by 20 times under room temperature, in ramie soaking process, soak is heated near boiling point, immersion effect can be strengthened, subtracted
The dosage of few fatty alcohol polyoxyethylene ether and sodium alkyl sulfonate, saves raw material, reduces cost.Therefore, the ramie raw materials are 98
DEG C ramie soak impregnates 8h, then is more advantageous to degumming.
The combination of enzyme preparations object for ramie raw materials degumming, is grouped as by each group of following mass percent:
25%~45% pectase, 15%~20% zytase, 10%~15% mannase, 5%~15% mouse
Lee's glycosidase, 20%~25% auxiliary agent.The pectase, which refers to, decomposes plant main component-pectic substance enzyme.Pectase
It is distributed widely in higher plant and microorganism.Xylan (xylan) be it is a kind of be present in it is heterogeneous more in plant cell wall
Sugar accounts for about the 15%~35% of plant cell dry weight, is the main component of plant hemicellulose.Zytase is in nature point
Cloth is extensive, can obtain from animal, plant and microorganism.Zytase can be applied in brewing, feed industry.Xylan
Enzyme can decompose raw material cell wall and beta glucan in brewing or feed industry, reduce the viscosity of material in brewing, promote
The release of active principle, and the non-starch polysaccharide in feed-use grain is reduced, promote being absorbed and utilized for nutriment, and thus
It is easier to take soluble lipids ingredient.Mannase, that is, the 'beta '-mannase is a kind of multi-functional growth accelerator, can be with
Promote the secretion of quasi-insulin growthing factor I GF-I, promotes growth.Rhamnose, also known as 6-deoxy-L-mannose are to deposit extensively
It is one of polysaccharide, glucosides, natural plant gum and the bacterial polysaccharides of plant substance.Preferably, described to be used for ramie raw materials degumming
Combination of enzyme preparations object be grouped as by each group of following mass percent 30% pectase, 20% zytase, 10%
Mannase, 15% rhamnosidase, 25% auxiliary agent.The auxiliary agent is grouped as by each group of following mass percent:
40%~60% lauryl sodium sulfate, 25%~40% sodium tripolyphosphate, 10%~20% polysorbas20.Described ten
Sodium dialkyl sulfate is dissolved in water for white or faint yellow powdery, insensitive to alkali and hard water, and have decontamination, emulsification and
Excellent foaming power.The polysorbas20 is sorbierite and one dehydration, double dehydration compounds and laurate by every mole of sorb
Alcohol and its anhydro compounds and about 20 moles of ethylene oxide are condensed under alkaline condition and are made.In the present embodiment, institute
Auxiliary agent is stated to be grouped as by each group of following mass percent: 50% lauryl sodium sulfate, 30% sodium tripolyphosphate,
20% polysorbas20.Experiment many times shows effectively help ramie to slough part colloid with pectase and zytase,
But always have some remnants.Inventor has surprisingly found that in experimentation, when rhamnosidase and pectase, xylan
Simultaneously in use, after the long period, colloid is almost disposed of entirely for enzyme, mannase.It has been recognised by the inventors that ramie
In the colloid of raw material, containing the nonhydrolyzable substance such as pectase and zytase, and these substances can be by rhamnosidase
It is degraded, these four enzymes use simultaneously, can play synergistic effect, fully erased colloid.Lauryl sodium sulfate,
Sodium tripolyphosphate and polysorbas20 are excellent dispersing agents, these auxiliary agents are used together with enzyme preparation, can make ramie raw materials
More enzyme preparation action sites are exposed, promotes the combination of enzyme preparation and these sites, effectively accelerates the effect of enzyme preparation,
Enzyme preparation dosage is reduced, cost is reduced.
A kind of Degumming method for ramie raw materials comprising following steps:
S1: preparing ramie soak, which includes the fatty alcohol polyoxy that mass percent is 0.5%~5%
The sodium alkyl sulfonate that vinethene and mass percent are 0.5%~2%, remaining is water;
S2: ramie raw materials are immersed in 4~10h in the ramie soak, and the temperature of the ramie soak is 95 DEG C
~100 DEG C;
S3: after cooling to 60 DEG C~70 DEG C immersed with the ramie soak of ramie raw materials, being added combination of enzyme preparations object,
Digest 6~12h, wherein the mass percent that the combination of enzyme preparations object accounts for the ramie soak is 0.1%~1%, institute
It states combination of enzyme preparations object to be grouped as by each group of following mass percent: 25%~45% pectase, 15%~20% wood
Dextranase, 10%~15% mannase, 5%~15% rhamnosidase, 20%~25% auxiliary agent;
S4: cooling to room temperature, and processed ramie raw materials are eluted with water;
S5: it makes after drying to the degummed ramie after degumming.
In step sl, the ramie soak contain mass percent 1.5% fatty alcohol polyoxyethylene ether and
0.75% sodium alkyl sulfonate.The ramie raw materials are immersed in 8h in the ramie soak, and the temperature of the ramie soak
It is 98 DEG C.
It, should be immersed with the ramie of ramie raw materials when cooling down to the ramie soak immersed with ramie raw materials in step S3
Soak is cooled to 65 DEG C, and the mass percent that combination of enzyme preparations object be added accounts for the ramie soak is 0.5%, and
Digest 7.5h.
Production technology of the invention is compared with traditional handicraft, is eliminated binding, dress cage step, is not used strong acid and strong base, post
Cost, and Environmental Safety are saved.
Method for degumming provided by the present invention and traditional chemical Degumming method Experimental comparison:
The Quality Index Analysis of 1 two kinds of Degumming method degummed ramies of table
2 two kinds of Degumming method degummed ramie comb spins each process quality determinations of table
Conclusion (of pressure testing):
Enzymatic degumming raw ramie fiber crops are soft, and fiber dispersion, cohesive force is strong, strongly not than chemical Degumming increase about 10%
Easily broken end has good spinning performance, the semi-products during comb spins are soft, it is bright and clean, without crude phenomenon, resultant yarn is bright and clean,
Filoplume is seldom, and Wu Site tests four quality index of spun yarn: the miscellaneous several reduction amplitudes of Unevenness CV %, details, knot are big, respectively
5.7%, 36.9%, 33%, resultant yarn filoplume also sharp fall 36.6%.
Combined with specific embodiments below, the invention will be further elaborated.
Embodiment 1
A kind of ramie raw materials Degumming method, comprising the following steps:
S11: ramie soak is prepared, wherein the fatty alcohol polyoxyethylene ether containing mass percent 1.5% and 0.75%
Sodium alkyl sulfonate;
S12: 98 DEG C of immersion ramie raw materials 8h of ramie soak made from step S11;
S13: cooling to 65 DEG C for the system of step S12, and combination of enzyme preparations object, enzyme is added according to mass percent 0.5%
Solve 7.5h, wherein the combination of enzyme preparations object is grouped as by each group of following mass percent: 30% pectase, and 20% wood is poly-
Carbohydrase, 10% mannase, 15% rhamnosidase, 25% auxiliary agent;The auxiliary agent by following mass percent each component
Composition: 50% lauryl sodium sulfate, 30% sodium tripolyphosphate, 20% polysorbas20;
S14: cooling to room temperature, and the processed ramie raw materials of step S13 are eluted with water;
S15: degummed ramie is obtained after drying.
Embodiment 2
A kind of ramie raw materials Degumming method, comprising the following steps:
S21: prepare ramie soak, wherein the fatty alcohol polyoxyethylene ether containing mass percent 3% and 2% alkane
Base sodium sulfonate;
S22: 100 DEG C of immersion ramie raw materials 4h of ramie soak made from step S21;
S23: cooling to 70 DEG C for the system of step S22, and combination of enzyme preparations object, enzyme is added according to mass percent 0.1%
Solve 12h, wherein the combination of enzyme preparations object is grouped as by each group of following mass percent: 45% pectase, and 15% wood is poly-
Carbohydrase, 10% mannase, 10% rhamnosidase, 20% auxiliary agent;The auxiliary agent by following mass percent each component
Composition: 40% lauryl sodium sulfate, 40% sodium tripolyphosphate, 20% polysorbas20;
S24: cooling to room temperature, and the processed ramie raw materials of step S23 are eluted with water;
S25: degummed ramie is obtained after drying.
Embodiment 3
A kind of ramie raw materials Degumming method, comprising the following steps:
S31: preparing ramie soak, wherein fatty alcohol polyoxyethylene ether containing mass percent 5% and 0.5%
Sodium alkyl sulfonate;
S32: 95 DEG C of immersion ramie raw materials 10h of ramie soak made from step S31;
S33: cooling to 70 DEG C for the system of step S32, and combination of enzyme preparations object, enzymatic hydrolysis is added according to mass percent 1%
9h, wherein the combination of enzyme preparations object is grouped as by each group of following mass percent: 25% pectase, 20% xylan
Enzyme, 15% mannase, 15% rhamnosidase, 25% auxiliary agent;The auxiliary agent is grouped by each group of following mass percent
At: 50% lauryl sodium sulfate, 40% sodium tripolyphosphate, 10% polysorbas20.
S34: cooling to room temperature, and the processed ramie raw materials of step S33 are eluted with water;
S35: degummed ramie is obtained after drying.
Embodiment 4
A kind of ramie raw materials Degumming method, comprising the following steps:
S41: ramie soak is prepared, wherein the fatty alcohol polyoxyethylene ether containing mass percent 0.5% and 1.5%
Sodium alkyl sulfonate;
S42: 99 DEG C of immersion ramie raw materials 7h of ramie soak made from step S41;
S43: cooling to 64 DEG C for the system of step S42, and combination of enzyme preparations object, enzyme is added according to mass percent 0.8%
Solve 10h, wherein the combination of enzyme preparations object is grouped as by each group of following mass percent: 40% pectase, and 15% wood is poly-
Carbohydrase, 15% mannase, 5% rhamnosidase, 25% auxiliary agent;The auxiliary agent by following mass percent each component
Composition: 60% lauryl sodium sulfate, 20% sodium tripolyphosphate, 20% polysorbas20;
S44: cooling to room temperature, and the processed ramie raw materials of step S43 are eluted with water;
S45: degummed ramie is obtained after drying.
Embodiment 5
A kind of ramie raw materials Degumming method, comprising the following steps:
S51: preparing ramie soak, wherein fatty alcohol polyoxyethylene ether containing mass percent 4% and 0.9%
Sodium alkyl sulfonate;
S52: step S51: 96 DEG C of immersion ramie raw materials 6h of ramie soak obtained are used;
S53: cooling to 67 DEG C for the system of step S52, and combination of enzyme preparations object is added according to mass percent 0.85%,
Digest 11h, wherein the combination of enzyme preparations object is grouped as by each group of following mass percent: 25% pectase, 20% wood
Dextranase, 15% mannase, 15% rhamnosidase, 25% auxiliary agent;The auxiliary agent by following mass percent each group
It is grouped as: 50% lauryl sodium sulfate, 40% sodium tripolyphosphate, 10% polysorbas20;
S54: cooling to room temperature, and the processed ramie raw materials of step S53 are eluted with water;
S55: degummed ramie is obtained after drying.
Compared with prior art, provided by the present invention for the ramie soak and combination of enzyme preparations of ramie raw materials degumming
Object is directed to the physics and chemistry and biological property of ramie raw materials, and the characteristics of combination ramie enterprise production technology, is used using ramie raw materials
The method of novel biological degumming agent from the plant cell wall (being made of pectin, lignin, hemicellulose etc.) hemicellulose with
Pectin is peeled away from fiber, and by the synergistic effect of various enzymes, depolymerized pectin and hemicellulose.Since biological complex enzyme is made
With mild condition, the incomplete problem of pectin degrading is fundamentally relieved, the dirt largely with a large amount of highly basic to environment is avoided
Dye.
The foregoing is merely a prefered embodiment of the invention, is not used to limitation protection scope of the present invention, any in the present invention
Modification, equivalent replacement or improvement in spirit etc., all cover in scope of the presently claimed invention.
Claims (10)
1. a kind of ramie soak for ramie raw materials degumming, it is characterised in that: the ramie for ramie raw materials degumming
Soak includes the fatty alcohol polyoxyethylene ether that mass percent is 0.5%~5% and mass percent is 0.5%~2%
Sodium alkyl sulfonate, remaining is water, when impregnating the ramie raw materials, the temperature of the ramie soak should be maintained at 95 DEG C~
100℃。
2. being used for the ramie soak of ramie raw materials as described in claim 1, it is characterised in that: it is described de- for ramie raw materials
The ramie soak of glue contains the fatty alcohol polyoxyethylene ether of mass percent 1%~1.5% and 0.25%~1.25% alkane
Base sodium sulfonate.
3. a kind of combination of enzyme preparations object for ramie raw materials degumming, it is characterised in that: the enzyme for ramie raw materials degumming
Preparation compositions are grouped as by each group of following mass percent: 25%~45% pectase, 15%~20% xylan
Enzyme, 10%~15% mannase, 5%~15% rhamnosidase, 20%~25% auxiliary agent.
4. as described in claim 1 be used for ramie raw materials degumming combination of enzyme preparations object, it is characterised in that: the auxiliary agent by with
The each group of lower mass percent is grouped as: 40%~60% lauryl sodium sulfate, 25%~40% sodium tripolyphosphate,
10%~20% polysorbas20.
5. a kind of Degumming method for ramie raw materials comprising following steps:
Prepare ramie soak, the ramie soak include mass percent be 0.5%~5% fatty alcohol polyoxyethylene ether and
The sodium alkyl sulfonate that mass percent is 0.5%~2%, remaining is water;
Ramie raw materials are immersed in 4~10h in the ramie soak, and the temperature of the ramie soak is 95 DEG C~100 DEG C;
After cooling to 60 DEG C~70 DEG C immersed with the ramie soak of ramie raw materials, addition combination of enzyme preparations object, enzymatic hydrolysis 6~
12h, wherein the mass percent that the combination of enzyme preparations object accounts for the ramie soak is 0.1%~1%, the enzyme preparation
Composition is grouped as by each group of following mass percent: 25%~45% pectase, 15%~20% zytase,
10%~15% mannase, 5%~15% rhamnosidase, 20%~25% auxiliary agent;
Room temperature is cooled to, processed ramie raw materials are eluted with water;
It makes after drying to the degummed ramie after degumming.
6. being used for the Degumming method of ramie raw materials as claimed in claim 5, it is characterised in that: the ramie soak also contains
The fatty alcohol polyoxyethylene ether of mass percent 1.5% and 0.75% sodium alkyl sulfonate.
7. being used for the Degumming method of ramie raw materials as claimed in claim 5, it is characterised in that: the ramie raw materials are immersed in institute
8h in ramie soak is stated, and the temperature of the ramie soak is 98 DEG C.
8. being used for the Degumming method of ramie raw materials as claimed in claim 5, it is characterised in that: to immersed with ramie raw materials
When ramie soak cools down, 65 DEG C should be cooled to immersed with the ramie soak of ramie raw materials, combination of enzyme preparations object be added
The mass percent for accounting for the ramie soak is 0.5%, and digests 7.5h.
9. as claimed in claim 5 be used for ramie raw materials Degumming method, it is characterised in that: the combination of enzyme preparations object by with
The each group of lower mass percent is grouped as: 30% pectase, 20% zytase, 10% mannase, 15%
Rhamnosidase, 25% auxiliary agent.
10. being used for the Degumming method of ramie raw materials as claimed in claim 5, it is characterised in that: the auxiliary agent is by following quality
The each group of percentage is grouped as: 50% lauryl sodium sulfate, 30% sodium tripolyphosphate, 20% polysorbas20.
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CN116180479A (en) * | 2023-01-05 | 2023-05-30 | 北京石大油源科技开发有限公司 | Lignin and holocellulose separation device and separation method |
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