CN109136582A - A kind of device and method improving Electro Slag Remelting Steel Solidification Quality reduction element segregation - Google Patents
A kind of device and method improving Electro Slag Remelting Steel Solidification Quality reduction element segregation Download PDFInfo
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- CN109136582A CN109136582A CN201811220595.6A CN201811220595A CN109136582A CN 109136582 A CN109136582 A CN 109136582A CN 201811220595 A CN201811220595 A CN 201811220595A CN 109136582 A CN109136582 A CN 109136582A
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- crystallizer
- looped pipeline
- solenoid valve
- gas
- bottom plate
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/16—Remelting metals
- C22B9/18—Electroslag remelting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D7/00—Casting ingots, e.g. from ferrous metals
- B22D7/12—Appurtenances, e.g. for sintering, for preventing splashing
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Abstract
A kind of raising Electro Slag Remelting Steel Solidification Quality of the invention reduces the device and method of element segregation.Equipment includes gas supply system, looped pipeline system and smelting system, and gas supply system is made of storage cylinder, pressure reducing valve, pressure stabilizing table and gas-guide tube;Looped pipeline system is made of inlet end solenoid valve, inlet end solenoid valve controller, looped pipeline, outlet side solenoid valve and outlet side solenoid valve controller;Smelting system includes crystallizer, and crystalliser feet is provided with bottom plate;The gas-guide tube is connect with circulating line;The described looped pipeline system fitting be arranged between crystallizer and bottom plate or it is embedding in a crystallizer or it is embedding in the soleplate.Method are as follows: when melting obtains the air gap caused by molten bath forms ingot casting between ingot casting and crystallizer, helium is filled with into air gap from crystalliser feet using looped pipeline system, increase cooling water to ingot casting cooling effect using the stronger capacity of heat transmission of helium, ingredient is uniform, the preferable high quality ESR ingot of Solidification Quality to obtain.
Description
Technical field:
The invention belongs to metallurgy and casting technology fields, and in particular to a kind of raising Electro Slag Remelting Steel Solidification Quality reduction element is inclined
The device and method of analysis.
Background technique:
In recent years, equipment manufacture level in China's is continuously improved, and extremely manufacturing becomes a prominent skill of equipment manufacture
Art development trend, one of them is towards super large direction and develops, the equipment enlargement of the fields such as electric power, petrochemical industry, metallurgy, complication pair
Heavy casting and forging industry proposes requirements at the higher level.Following a period of time will be that China promotes industrialized critical period, electric power, stone
The industries such as change, metallurgy, ship, aviation will all continue fast development, breed the Unprecedented demands to heavy casting and forging among these.
Significantly supply falls short of demand for heavy casting and forging in the world at present, and the heavy casting and forgings manufacturing enterprise such as JSW, bucket mountain heavy industry is all
It is full production, this proposes new challenge to the development of China's equipment manufacture in recent years, by external heavy casting and forging,
At high price, the delivery cycle is long, and crucial moment, the external technology blockage to China, and limits outlet, therefore greatly develop
The high-quality heavy casting and forging of China's proprietary technology, is of great significance.
Electroslag remelting process since its equipment requirement is low, and have the advantage that simultaneously pure metal, dense structure, at
Divide uniform, any surface finish, while with excellent product performance, the stability of technique and the reproducibility of quality are high, and produce
Flexibly, various ingot shapes can be produced.Electroslag remelting process is there are two important feature, it may be assumed that the continuity of electroslag metallurgy with it is stackable
Property, electroslag remelting can be by replacement consutrode continuous production, and can pass through multiple devices one large size of continuous production simultaneously
Component, these characteristics determine important function of the electroslag remelting process on production heavy casting and forging.
For forging rolling performance, the machining property etc. for improving large-scale casting ingot, large-scale casting ingot generallys use high alloy or height
Steel grade of carbon content, such as high-carbon steel, high-temperature nickel-base alloy etc., these steel grades are in electroslag remelting production process, due to molten steel
Ingredient multiplicity, especially alloying element or carbon element content is higher, since the solubility of these elements is in liquid and solid steel
Difference leads to that selective freezing has occurred when ingot solidification, it is uneven (segregation) to cause steel ingot internal component, and with steel ingot
Increase and the extension of setting time, this component segregation just more seriously, control the bad ingot casting report for possibly even causing to produce
Useless, this certainly will will affect the economic benefit of steel mill.Therefore, a large amount of research has been carried out for the control of large-scale casting ingot component segregation.
In the existing production technology of large-scale casting ingot, due to using protective gas as protective gas or not using argon gas,
Molten steel after solidification, due to volume contraction, can form one layer of air gap, when air or argon gas enter gas between crystallizer and steel ingot
After gap, since its capacity of heat transmission is poor, cooling water can be reduced to the cooling effect of ingot casting, extend the cooling time of ingot casting, from
And make ingot composition segregation aggravation, influence the Solidification Quality of Electro Slag Remelting Steel.Therefore, the equipment of appropriate adjustment electroslag remelting, in air gap
The stronger gas of the middle filling capacity of heat transmission very must for preferably playing the effect of electroslag remelting in the production process of steel ingots
It wants.
Summary of the invention:
The purpose of the present invention is overcoming above-mentioned the shortcomings of the prior art, in order to improve the solidifying of electroslag remelting production ingot casting
Stereoplasm amount reduces component segregation, the device and method for improving Electro Slag Remelting Steel Solidification Quality reduction element segregation is provided, using loop pipe
Road system is smoothly filled with helium into the air gap between ingot casting and crystallizer from crystalliser feet, stronger thermally conductive using helium
Ability increases cooling water to the cooling effect of ingot casting, to obtain the more uniform high quality ESR ingot of ingredient.
To achieve the above object, the invention adopts the following technical scheme:
A kind of equipment for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, including gas supply system, looped pipeline system
System and smelting system, in which:
The gas supply system is made of storage cylinder, pressure reducing valve, pressure stabilizing table and gas-guide tube, the storage cylinder with lead
Tracheae connection, the storage cylinder bottle mouth position setting pressure reducing valve and pressure stabilizing table;
The looped pipeline system is by inlet end solenoid valve, inlet end solenoid valve controller, looped pipeline, outlet side electricity
Magnet valve and outlet side solenoid valve controller composition, the looped pipeline are arranged symmetrically an air inlet and one along horizontal center line
A gas outlet;The circulating line air inlet is provided with inlet end solenoid valve, and the inlet end solenoid valve is connected with air inlet
Solenoid valve controller is held, the circulating line gas outlet is provided with outlet side solenoid valve, the outlet side solenoid valve connection
There is outlet side solenoid valve controller;
The smelting system is made of consutrode, high temperature molten bath and crystallizer, and the crystalliser feet is provided with
Bottom plate;
The gas supply system is connect with looped pipeline system, specifically, the gas-guide tube and circulating line connect
It connects;
The described looped pipeline system fitting be arranged between crystallizer and bottom plate or it is embedding in a crystallizer, or be embedded in bottom
In plate.
After the installation is completed, the center of the crystallizer, looped pipeline system, bottom plate and consutrode is maintained at same
On vertical line.Wherein, the gas supply system, looped pipeline system and smelting system junction using stainless steel lock ring or
Flanged joint.
The looped pipeline shape is identical as mold shape, specially round or rectangle, the looped pipeline table
Face is equipped with equally distributed gas vent.
The looped pipeline setting gas vent is contacted with guaranteeing the air gap between crystallizer and the ingot casting of formation.
The vent shape is circle, rectangle or narrow annular channel.
It when the looped pipeline is arranged between crystallizer and bottom plate, and is bonded, is seamlessly connected with crystallizer and bottom plate,
The looped pipeline exterior surface dimension is consistent with crystallizer exterior surface dimension, inner surface size and internal surface of crystallizer size one
Cause, lower surface is concordant with crystallizer lower surface, the described gas vent setting in looped pipeline inner surface, the looped pipeline and
Crystallizer is fitted closely with bottom plate, seamless interfacing;
The looped pipeline it is embedding in a crystallizer when, the looped pipeline exterior surface dimension is than crystallizer outer surface ruler
Very little small, inner surface size is consistent with internal surface of crystallizer size, and lower surface is concordant with crystallizer lower surface, and the gas vent is set
It sets in looped pipeline inner surface, the looped pipeline is fitted closely with crystallizer, and seamless interfacing is placed on bottom plate;
The looped pipeline it is embedding in the soleplate when, the looped pipeline exterior surface dimension is than internal surface of crystallizer size
Unanimously, inner surface size is smaller than internal surface of crystallizer size, and upper surface is concordant with plate upper surface, and the gas vent setting exists
Looped pipeline upper surface, the looped pipeline are fitted closely with bottom plate, seamless interfacing;
Using the equipment for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, improving Electro Slag Remelting Steel Solidification Quality is reduced
The method of element segregation, includes the following steps:
(1) melting starts, and consutrode, which slowly melts, initially forms high temperature molten bath, and high temperature molten bath is under the action of cooling water
Start slow solidification, with the progress of solidification, forms ingot casting height and be continuously increased, while forming one between ingot casting and crystallizer
Enclose air gap;
(2) after air gap is formed, helium is fed into air gap using gas supply system, helium is made to pass through looped pipeline table
Face gas vent is uniformly passed through in air gap, and the parameter of inlet end solenoid valve controller Yu outlet side solenoid valve controller is arranged, with
Guarantee that inlet end solenoid valve and outlet side solenoid valve can make helium pressure in air gap be maintained at 0.1~1MPa;
(3) after parameter regulation is good, pressure reducing valve is opened, adjusting pressure stabilizing indicates number, guarantees that helium stablizes supply;
(4) after melting, power-off cooling stops gas supply.
Beneficial effects of the present invention:
The device and method that a kind of raising Electro Slag Remelting Steel Solidification Quality of the invention reduces element segregation use looped pipeline system
It unites and is filled with helium in the air gap between crystallizer and remelting ingot casting, due to the helium capacity of heat transmission with higher, effectively mention
High cooling effect of the cooling water to ingot casting, especially is conducive to improve in the reflow process of large-scale casting ingot and high alloy steel grade
Electro Slag Remelting Steel Solidification Quality reduces element segregation, preferably plays the superiority of electroslag remelting production high quality ingot casting.
Detailed description of the invention:
Fig. 1 is the main view for improving Electro Slag Remelting Steel Solidification Quality and reducing the equipment of element segregation of the invention, looped pipeline
System is mounted between crystallizer and bottom plate;
Fig. 2 is the main view for improving Electro Slag Remelting Steel Solidification Quality and reducing the equipment of element segregation of the invention, looped pipeline
System is embedding in a crystallizer;
Fig. 3 is the main view for improving Electro Slag Remelting Steel Solidification Quality and reducing the equipment of element segregation of the invention, looped pipeline
System is embedding in the soleplate;
Fig. 4 is the circular annular form pipe-line system main view that upper surface of the invention is uniformly distributed circular exhausting-gas hole;
Fig. 5 is the circular annular form pipe-line system main view that inner surface of the invention is uniformly distributed rectangle gas vent;
Fig. 6 is the circular annular form pipe-line system main view that inner surface of the invention has circular row air cleft;
Fig. 7 is the rectangular ring pipe-line system main view that inner surface of the invention is uniformly distributed rectangle gas vent;
Wherein:
1- looped pipeline;The outlet side 2- solenoid valve controller;The outlet side 3- solenoid valve;4- inlet end solenoid valve;5- air inlet
Hold solenoid valve controller;6- ingot casting;7- crystallizer;8- consutrode;9- high temperature molten bath;10- bottom plate;11- gas-guide tube;12- is steady
Press table;13- pressure reducing valve;14- storage cylinder.
Specific embodiment:
Below with reference to embodiment, the present invention is described in further detail.
In order to preferably explain the present invention, in order to understand, with reference to the accompanying drawing, by specific embodiment, to this hair
It is bright to be described in detail.
Embodiment 1
A kind of equipment for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, main view is as shown in Fig. 2, include that gas supplies
Answer system, looped pipeline system and smelting system, in which:
The gas supply system is made of storage cylinder 14, pressure reducing valve 13, pressure stabilizing table 12 and gas-guide tube 11, the storage
Gas cylinder 14 is connect with gas-guide tube 11,14 bottle mouth position of the storage cylinder setting pressure reducing valve 13 and pressure stabilizing table 12;
The looped pipeline system is by inlet end solenoid valve 4, inlet end solenoid valve controller 5, looped pipeline 1, outlet
Hold solenoid valve 3 and outlet side solenoid valve controller 2 to form, the looped pipeline 1 along horizontal center line be arranged symmetrically one into
Port and a gas outlet;The circulating line air inlet is provided with inlet end solenoid valve 4, the inlet end solenoid valve 4
It is connected with inlet end solenoid valve controller 5, the circulating line gas outlet is provided with outlet side solenoid valve 3, the outlet
End solenoid valve 3 is connected with outlet side solenoid valve controller 2;
The smelting system is made of consutrode 8, high temperature molten bath 9 and crystallizer 7, and 7 bottom of crystallizer is set
It is equipped with bottom plate 10;
The gas supply system is connect with looped pipeline system, specifically, the gas-guide tube 11 and circulating line
Connection;
The looped pipeline system fitting is in crystallizer 7;
Equipment according to it is above-mentioned after the installation is completed, the crystallizer 7, looped pipeline system, bottom plate 10 and consutrode 8
Center is maintained on same vertical line, wherein gas supply system, looped pipeline system and smelting system junction be not using
Rust steel lock ring or flanged joint;
1 shape of looped pipeline is identical as 7 shape of crystallizer, is round, described looped pipeline 1 in the present embodiment
Surface is equipped with equally distributed rectangle gas vent, and circular annular form pipe-line system main view is as shown in Figure 5;
The looped pipeline 1 is in crystallizer 7, and 1 exterior surface dimension of looped pipeline is than 7 outer surface of crystallizer
Size is small, and inner surface size is consistent with 7 inner surface size of crystallizer, and lower surface is concordant with 7 lower surface of crystallizer, the exhaust
Hole is arranged in 1 inner surface of looped pipeline, and the looped pipeline 1 is fitted closely with crystallizer 7, and seamless interfacing is placed on bottom plate 10
On.
In the present embodiment:
The gas vent of 1 surface of looped pipeline setting may be round or circular row air cleft, when for circular exhausting-gas hole,
Circular annular form pipe-line system main view is as shown in figure 4, when for circular row air cleft, circular annular form pipe-line system main view such as Fig. 6
It is shown;
1 shape of looped pipeline is identical as 7 shape of crystallizer, can also be rectangle, when for rectangle, and looped pipeline
Rectangular ring pipe-line system main view when 1 inner surface is uniformly distributed rectangle gas vent is as shown in Figure 7;
The looped pipeline 1 may also be arranged between crystallizer 7 and bottom plate 10, or in bottom plate 10, when setting exists
When between crystallizer 7 and bottom plate 10, the raising Electro Slag Remelting Steel Solidification Quality reduce element segregation equipment main view as shown in Figure 1,
Looped pipeline 1 is bonded with crystallizer 7 and bottom plate 10, seamless connection, outside 1 exterior surface dimension of looped pipeline and crystallizer 7
Surface size is consistent, and inner surface size is consistent with 7 inner surface size of crystallizer, and lower surface is concordant with 7 lower surface of crystallizer, described
Gas vent be arranged in 1 inner surface of looped pipeline, the looped pipeline 1 is fitted closely with crystallizer 7 and bottom plate 10, seamless right
It connects;
When the equipment that the looped pipeline 1 is in bottom plate 10, which reduces element segregation
Main view is as shown in figure 3,1 exterior surface dimension of looped pipeline is more consistent than 7 inner surface size of crystallizer, inner surface size ratio
7 inner surface size of crystallizer is small, and upper surface is concordant with 10 upper surface of bottom plate, and table is arranged on looped pipeline 1 in the gas vent
Face, the looped pipeline 1 are fitted closely with bottom plate 10, seamless interfacing.
Using the equipment for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, improving Electro Slag Remelting Steel Solidification Quality is reduced
The method of element segregation, includes the following steps:
(1) it closes a floodgate and powers, melting starts, and consutrode 8 uses 718 high-temperature nickel-base alloys, its ingredient such as 1 institute of table before melting
Showing, slowly fusing initially forms high temperature molten bath 9 to consutrode 8, and high temperature molten bath 9 starts slow solidification under the action of cooling water,
It with the progress of solidification, forms 6 height of ingot casting and is continuously increased, while forming a circle air gap between ingot casting 6 and crystallizer 7;
(2) after air gap is formed, helium is fed into air gap using gas supply system, helium is made to pass through looped pipeline 1
Uniformly be passed through in air gap, and the parameter of inlet end solenoid valve controller 5 Yu outlet side solenoid valve controller 2 be set, with guarantee into
Gas end solenoid valve 4 and outlet side solenoid valve 3 can make helium pressure in air gap be maintained at 0.15MPa;
(3) after parameter regulation is good, pressure reducing valve 13 is opened, adjusts 12 registration of pressure stabilizing table, guaranteeing that helium stablizes supply is 1L/
min;
(4) after melting, power-off cooling stops gas supply.
Along the diametrical direction of ingot casting after melting, chemical component point is carried out in the center of circle, 1/2 radius, edge sampling
Analysis, the results are shown in Table 2, can be seen that from the data of table 2 using the 718 high-temperature nickel-base alloy ingot casting of equipment melting, changes
It studies point uniformly, there is no generation segregation.
Chemical component before 1 718 high-temperature nickel-base alloy melting of table, wt%
The chemical component of different location, wt% after 2 718 high-temperature nickel-base alloy melting of table
Claims (7)
1. a kind of equipment for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, which is characterized in that including gas supply system, ring
Shape pipe-line system and smelting system, in which:
The gas supply system is made of storage cylinder, pressure reducing valve, pressure stabilizing table and gas-guide tube, the storage cylinder and gas-guide tube
Connection, the storage cylinder bottle mouth position setting pressure reducing valve and pressure stabilizing table;
The looped pipeline system is by inlet end solenoid valve, inlet end solenoid valve controller, looped pipeline, outlet side solenoid valve
It is formed with outlet side solenoid valve controller, the looped pipeline is arranged symmetrically an air inlet along horizontal center line and one goes out
Port;The circulating line air inlet is provided with inlet end solenoid valve, and the inlet end solenoid valve is connected with inlet end electricity
Magnetic valve controller, the circulating line gas outlet are provided with outlet side solenoid valve, and the outlet side solenoid valve is connected with out
Gas end solenoid valve controller;
The smelting system is made of consutrode, high temperature molten bath and crystallizer, and the crystalliser feet is provided with bottom plate;
The gas supply system is connect with looped pipeline system, specifically, the gas-guide tube is connect with circulating line;
The described looped pipeline system fitting be arranged between crystallizer and bottom plate or it is embedding in a crystallizer or it is embedding in the soleplate.
2. the equipment according to claim 1 for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, which is characterized in that described
Looped pipeline shape it is identical as mold shape, specially round or rectangle, the looped pipeline surface is equipped with uniformly point
The gas vent of cloth.
3. the equipment according to claim 2 for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, which is characterized in that described
Vent shape be circle, rectangle or narrow annular channel.
4. the equipment according to claim 1 for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, which is characterized in that described
Looped pipeline when being arranged between crystallizer and bottom plate, and be bonded with crystallizer and bottom plate, seamless connection, the loop pipe
Road exterior surface dimension is consistent with crystallizer exterior surface dimension, and inner surface size is consistent with internal surface of crystallizer size, lower surface with
Crystallizer lower surface is concordant, and the gas vent setting is at looped pipeline inner surface, the looped pipeline and crystallizer and bottom
Plate fits closely, seamless interfacing.
5. the equipment according to claim 1 for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, which is characterized in that described
Looped pipeline it is embedding in a crystallizer when, the looped pipeline exterior surface dimension is smaller than crystallizer exterior surface dimension, inner surface
Size is consistent with internal surface of crystallizer size, and lower surface is concordant with crystallizer lower surface, and the gas vent is arranged in loop pipe
Road inner surface, the looped pipeline are fitted closely with crystallizer, and seamless interfacing is placed on bottom plate.
6. the equipment according to claim 1 for improving Electro Slag Remelting Steel Solidification Quality and reducing element segregation, which is characterized in that described
Looped pipeline it is embedding in the soleplate when, the looped pipeline exterior surface dimension is more consistent than internal surface of crystallizer size, inner surface
Size is smaller than internal surface of crystallizer size, and upper surface is concordant with plate upper surface, and the gas vent is arranged on looped pipeline
Surface, the looped pipeline are fitted closely with bottom plate, seamless interfacing.
7. the equipment for reducing element segregation using raising Electro Slag Remelting Steel Solidification Quality described in claim 1, improves Electro Slag Remelting Steel solidification
The method of quality reduction element segregation, which comprises the steps of:
(1) melting starts, and consutrode, which slowly melts, initially forms high temperature molten bath, and high temperature molten bath starts under the action of cooling water
Slow solidification forms ingot casting height and is continuously increased with the progress of solidification, while a circle gas is formed between ingot casting and crystallizer
Gap;
(2) after air gap is formed, helium is fed into air gap using gas supply system, arranges helium by looped pipeline surface
Stomata is uniformly passed through in air gap, and the parameter of inlet end solenoid valve controller Yu outlet side solenoid valve controller is arranged, to guarantee
Inlet end solenoid valve and outlet side solenoid valve can make helium pressure in air gap be maintained at 0.1~1MPa;
(3) after parameter regulation is good, pressure reducing valve is opened, adjusting pressure stabilizing indicates number, guarantees that helium stablizes supply;
(4) after melting, power-off cooling stops gas supply.
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CN201811220595.6A CN109136582B (en) | 2018-10-19 | 2018-10-19 | Equipment and method for improving solidification quality of electroslag steel and reducing element segregation |
Applications Claiming Priority (1)
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CN201811220595.6A CN109136582B (en) | 2018-10-19 | 2018-10-19 | Equipment and method for improving solidification quality of electroslag steel and reducing element segregation |
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CN109136582B CN109136582B (en) | 2020-07-10 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113351838A (en) * | 2021-05-17 | 2021-09-07 | 西部超导材料科技股份有限公司 | Gas cooling device, control system and control method for preparing titanium alloy ingots |
CN115213362A (en) * | 2022-08-12 | 2022-10-21 | 南通蓝天彩钢结构工程有限公司 | Cooling device for continuous casting billet crystallizer |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106756081A (en) * | 2016-12-27 | 2017-05-31 | 钢铁研究总院 | The preparation method of big specification Ti Al Nb series alloy fines crystalline substance ingot casting |
-
2018
- 2018-10-19 CN CN201811220595.6A patent/CN109136582B/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106756081A (en) * | 2016-12-27 | 2017-05-31 | 钢铁研究总院 | The preparation method of big specification Ti Al Nb series alloy fines crystalline substance ingot casting |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113351838A (en) * | 2021-05-17 | 2021-09-07 | 西部超导材料科技股份有限公司 | Gas cooling device, control system and control method for preparing titanium alloy ingots |
CN115213362A (en) * | 2022-08-12 | 2022-10-21 | 南通蓝天彩钢结构工程有限公司 | Cooling device for continuous casting billet crystallizer |
CN115213362B (en) * | 2022-08-12 | 2022-12-20 | 南通蓝天彩钢结构工程有限公司 | Cooling device for continuous casting billet crystallizer |
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