CN109130376A - A kind of environment-friendly type aqueous plastic material - Google Patents
A kind of environment-friendly type aqueous plastic material Download PDFInfo
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- CN109130376A CN109130376A CN201811041633.1A CN201811041633A CN109130376A CN 109130376 A CN109130376 A CN 109130376A CN 201811041633 A CN201811041633 A CN 201811041633A CN 109130376 A CN109130376 A CN 109130376A
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- B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
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Abstract
The invention discloses a kind of environment-friendly type aqueous plastic materials, including the foundation base, plastic resilient layer and anti-slip layer set gradually from the bottom to top, foundation base uses concrete or pitch material, plastic resilient layer includes following components according to the mass fraction: cement: 13-19 parts, aqueous polymer emulsion: 19-21 parts, base-material lotion: 3-9 parts, resin liquid: 3-8 parts, silica: 11-14 parts, alcohol-soluble acrylate: 4-8 parts, toughener: 10-14 parts, coupling agent: 6-9 parts, plastic cement auxiliary agent: 10-13 parts;Anti-slip layer includes following components according to the mass fraction: cement: 6-9 parts, pigments and fillers: and 13-18 parts, solvent: 9-14 parts, nano silica: 10-19 parts, butyl acrylate: 8-13 parts, anti-slip layer auxiliary agent: 13-19 parts, colored EPDM particle: 30-37 parts.
Description
Technical field
The present invention relates to plastic material technical fields, particularly relate to a kind of environment-friendly type aqueous plastic material.
Background technique
Domestic most plastic cement race tracks or plastics product sports apparatus are using the poly- of one pack system or bi-component at present
Urethane material, belongs to heavy metal ion catalyst system, middle in material to have the toxic substances such as free TDI, heavy metal ion
Volatile organic solvent used in matter and process of deployment.Free TDI, that is, toluene di-isocyanate(TDI) is beyond 0.5% meeting pair
Human body damages, mainly sensitization and stimulation, ocular pain easily occurs, sheds tears, conjunctival congestion, uncomfortable in chest, out of breath, heavy breathing
The symptoms such as asthma, red papules bring great body harm to user, and there are certain menaces to environmental protection;
In order to improve this status, the invention proposes a kind of environment-friendly type aqueous plastic materials.
Summary of the invention
The technical problem to be solved by the present invention is to propose a kind of environment-friendly type water for the above disadvantage of the existing technology
Property plastic material, eliminates the possibility being hazardous to the human body, protects environment, structure is simple, easy to maintain.
The technical solution that the present invention solves the above technical problem is:
A kind of environment-friendly type aqueous plastic material, including the foundation base, plastic resilient layer and anti-slip layer set gradually from the bottom to top,
Foundation base uses concrete or pitch material, and plastic resilient layer includes following components according to the mass fraction: cement: 13-19 parts, water
Property polymer emulsion: 19-21 parts, base-material lotion: 3-9 parts, resin liquid: 3-8 parts, silica: 11-14 parts, alcohol-soluble propylene
Acid ester resin: 4-8 parts, toughener: 10-14 parts, coupling agent: 6-9 parts, plastic cement auxiliary agent: 10-13 parts;Anti-slip layer presses mass fraction
Meter includes following components: cement: 6-9 parts, pigments and fillers: and 13-18 parts, solvent: 9-14 parts, nano silica: 10-19 parts, third
Olefin(e) acid butyl ester: 8-13 parts, anti-slip layer auxiliary agent: 13-19 parts, colored EPDM particle: 30-37 parts;
Base-material lotion is one of acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion;Resin
Liquid is one of alkyd resin liquid or liquid phenolic resin;Toughener is acrylic rubber, carboxy nitrile rubber, neoprene rubber
One of glue, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is in polyethylene, polyvinyl chloride or haloflex
It is one or more.
The technical solution that the present invention further limits is:
Environment-friendly type aqueous plastic material above-mentioned, plastic cement auxiliary agent be mixing mass ratio be 2:1.5:1 plasticiser, antioxidant and
The mixture of anti-virus agent;Anti-slip layer auxiliary agent be mixing mass ratio be 1:2:1 plasticiser, antioxidant, UV resistant agent and anti-
The mixture of toxic agent.
Environment-friendly type aqueous plastic material above-mentioned, is connected to a fixed between plastic resilient layer and foundation base by binder,
The binder includes following components according to the mass fraction: resin aqueous emulsion: 22-29 parts, silicon carbide micro-powder: and 21-25 parts, carbonic acid
Sub- third rouge: 10-17 parts, styrene: 3-9 parts, 2- butanone cyclohexanone: 1-3 parts, acetone: 3-10 parts, allyl alcohol: 4-7 parts, nitro
Ethane: 1-4 parts, ethylene glycol: 3-8 parts, crosslinking agent: 3-10 parts, coalescing agent: 11-15 parts, defoaming agent: 2-5 parts, solvent: 7-12
Part.
Environment-friendly type aqueous plastic material above-mentioned, silicon carbide micro-powder is black silicon carbide and partial size is 2-6 μm;Crosslinking agent is poly-
One of ethylene or haloflex;Coalescing agent is one in ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propylene glycol
Kind;Defoaming agent is one or more of organosilicon, organosiloxane or amide;The solvent is water.
Environment-friendly type aqueous plastic material above-mentioned, foundation base use concrete or pitch material, and plastic resilient layer presses quality
Number meter includes following components: cement: 13 parts, aqueous polymer emulsion: and 19 parts, base-material lotion: 3 parts, resin liquid: 3 parts, dioxy
SiClx: 11 parts, alcohol-soluble acrylate: 4 parts, toughener: 10 parts, coupling agent: 6 parts, plastic cement auxiliary agent: 10 parts;Anti-slip layer
According to the mass fraction include following components: cement: 6 parts, pigments and fillers: 13 parts, solvent: 9 parts, nano silica: 10 parts, propylene
Acid butyl ester: 8 parts, anti-slip layer auxiliary agent: 13 parts, colored EPDM particle: 30 parts;
Base-material lotion is one of acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion;Resin
Liquid is one of alkyd resin liquid or liquid phenolic resin;Toughener is acrylic rubber, carboxy nitrile rubber, neoprene rubber
One of glue, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is in polyethylene, polyvinyl chloride or haloflex
It is one or more.
Environment-friendly type aqueous plastic material above-mentioned, foundation base use concrete or pitch material, and plastic resilient layer presses quality
Number meter includes following components: cement: 19 parts, aqueous polymer emulsion: and 21 parts, base-material lotion: 9 parts, resin liquid: 8 parts, dioxy
SiClx: 14 parts, alcohol-soluble acrylate: 8 parts, toughener: 14 parts, coupling agent: 9 parts, plastic cement auxiliary agent: 13 parts;Described
Anti-slip layer includes following components according to the mass fraction: cement: 9 parts, pigments and fillers: and 18 parts, solvent: 14 parts, nano silica: 19
Part, butyl acrylate: 13 parts, anti-slip layer auxiliary agent: 19 parts, colored EPDM particle: 37 parts;
Base-material lotion is one of acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion;Resin
Liquid is one of alkyd resin liquid or liquid phenolic resin;Toughener is acrylic rubber, carboxy nitrile rubber, neoprene rubber
One of glue, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is in polyethylene, polyvinyl chloride or haloflex
It is one or more.
Environment-friendly type aqueous plastic material above-mentioned, foundation base use concrete or pitch material, and plastic resilient layer presses quality
Number meter includes following components: cement: 16 parts, aqueous polymer emulsion: and 20 parts, base-material lotion: 6 parts, resin liquid: 5 parts, dioxy
SiClx: 12 parts, alcohol-soluble acrylate: 6 parts, toughener: 12 parts, coupling agent: 8 parts, plastic cement auxiliary agent: 12 parts;Anti-slip layer
According to the mass fraction include following components: cement: 7 parts, pigments and fillers: 15 parts, solvent: 11 parts, nano silica: 16 parts, third
Olefin(e) acid butyl ester: 11 parts, anti-slip layer auxiliary agent: 15 parts, colored EPDM particle: 35 parts;
Base-material lotion is one of acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion;Resin
Liquid is one of alkyd resin liquid or liquid phenolic resin;Toughener is acrylic rubber, carboxy nitrile rubber, neoprene rubber
One of glue, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is in polyethylene, polyvinyl chloride or haloflex
It is one or more.
Be using technical solution of the present invention beneficial effect: the present invention is using resin aqueous emulsion as the main of binder
The characteristics of ingredient enhances binder integral into film strength, while resin aqueous emulsion changes brittleness in plastic resilient layer,
Make the material integrally intensity with higher, and have preferable tensile strength and elongation, tensile strength is greater than 1.4MPa, elongation
Rate is greater than 150%, and comprehensive performance is preferable, and the plastic cement race track is at low cost, and intensity is high, and elongation percentage is big, and without weight in raw material
The noxious materials such as metal or TDI, it is environmentally protective, it is harmless.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of environment-friendly type aqueous plastic materials, including foundation base, the plastic resilient set gradually from the bottom to top
Layer and anti-slip layer, foundation base use concrete or pitch material, and plastic resilient layer includes following components according to the mass fraction: water
Mud: 13 parts, aqueous polymer emulsion: 19 parts, base-material lotion: 3 parts, resin liquid: 3 parts, silica: 11 parts, alcohol-soluble propylene
Acid ester resin: 4 parts, toughener: 10 parts, coupling agent: 6 parts, plastic cement auxiliary agent: 10 parts;Anti-slip layer includes following according to the mass fraction
Component: cement: 6 parts, pigments and fillers: 13 parts, solvent: 9 parts, nano silica: 10 parts, butyl acrylate: 8 parts, anti-slip layer helps
Agent: 13 parts, colored EPDM particle: 30 parts;
Base-material lotion is one of acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion;Resin
Liquid is one of alkyd resin liquid or liquid phenolic resin;Toughener is acrylic rubber, carboxy nitrile rubber, neoprene rubber
One of glue, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is in polyethylene, polyvinyl chloride or haloflex
It is one or more;
Plastic cement auxiliary agent is the mixture of plasticiser, antioxidant and anti-virus agent that mixing mass ratio is 2:1.5:1;Anti-slip layer auxiliary agent
For the mixture of plasticiser, antioxidant, UV resistant agent and anti-virus agent that mixing mass ratio is 1:2:1;
It is connected to a fixed between plastic resilient layer and foundation base by binder, which includes with the following group according to the mass fraction
Point: resin aqueous emulsion: 22 parts, silicon carbide micro-powder: 21 parts, polypropylene carbonate rouge: 10 parts, styrene: 3 parts, 2- butanone cyclohexanone:
1 part, acetone: 3 parts, allyl alcohol: 4 parts, nitroethane: 1 part, ethylene glycol: 3 parts, crosslinking agent: 3 parts, coalescing agent: 11 parts, defoaming
Agent: 2 parts, solvent: 7 parts;
Environment-friendly type aqueous plastic material, silicon carbide micro-powder is black silicon carbide and partial size is 2 μm;Crosslinking agent is that polyethylene or chlorination are poly-
One of ethylene;Coalescing agent is one of ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propylene glycol;Defoaming agent is
One or more of organosilicon, organosiloxane or amide;The solvent is water.
Embodiment 2
The present embodiment provides a kind of environment-friendly type aqueous plastic materials, including foundation base, the plastic resilient set gradually from the bottom to top
Layer and anti-slip layer, foundation base use concrete or pitch material, and plastic resilient layer includes following components according to the mass fraction: water
Mud: 19 parts, aqueous polymer emulsion: 21 parts, base-material lotion: 9 parts, resin liquid: 8 parts, silica: 14 parts, alcohol-soluble propylene
Acid ester resin: 8 parts, toughener: 14 parts, coupling agent: 9 parts, plastic cement auxiliary agent: 13 parts;The anti-slip layer wraps according to the mass fraction
Include following components: cement: 9 parts, pigments and fillers: 18 parts, solvent: 14 parts, nano silica: 19 parts, butyl acrylate: 13 parts,
Anti-slip layer auxiliary agent: 19 parts, colored EPDM particle: 37 parts;
Base-material lotion is one of acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion;Resin
Liquid is one of alkyd resin liquid or liquid phenolic resin;Toughener is acrylic rubber, carboxy nitrile rubber, neoprene rubber
One of glue, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is in polyethylene, polyvinyl chloride or haloflex
It is one or more;
Plastic cement auxiliary agent is the mixture of plasticiser, antioxidant and anti-virus agent that mixing mass ratio is 2:1.5:1;Anti-slip layer auxiliary agent
For the mixture of plasticiser, antioxidant, UV resistant agent and anti-virus agent that mixing mass ratio is 1:2:1;
It is connected to a fixed between plastic resilient layer and foundation base by binder, which includes with the following group according to the mass fraction
Point: resin aqueous emulsion: 29 parts, silicon carbide micro-powder: 25 parts, polypropylene carbonate rouge: 17 parts, styrene: 9 parts, 2- butanone cyclohexanone:
3 parts, acetone: 10 parts, allyl alcohol: 7 parts, nitroethane: 4 parts, ethylene glycol: 8 parts, crosslinking agent: 10 parts, coalescing agent: 15 parts, disappear
Infusion: 5 parts, solvent: 12 parts;
Environment-friendly type aqueous plastic material, silicon carbide micro-powder is black silicon carbide and partial size is 6 μm;Crosslinking agent is that polyethylene or chlorination are poly-
One of ethylene;Coalescing agent is one of ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propylene glycol;Defoaming agent is
One or more of organosilicon, organosiloxane or amide;The solvent is water.
Embodiment 3
The present embodiment provides a kind of environment-friendly type aqueous plastic materials, including foundation base, the plastic resilient set gradually from the bottom to top
Layer and anti-slip layer, foundation base use concrete or pitch material, and plastic resilient layer includes following components according to the mass fraction: water
Mud: 16 parts, aqueous polymer emulsion: 20 parts, base-material lotion: 6 parts, resin liquid: 5 parts, silica: 12 parts, alcohol-soluble propylene
Acid ester resin: 6 parts, toughener: 12 parts, coupling agent: 8 parts, plastic cement auxiliary agent: 12 parts;Anti-slip layer includes following according to the mass fraction
Component: cement: 7 parts, pigments and fillers: 15 parts, solvent: 11 parts, nano silica: 16 parts, butyl acrylate: 11 parts, anti-slip layer
Auxiliary agent: 15 parts, colored EPDM particle: 35 parts;
Base-material lotion is one of acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion;Resin
Liquid is one of alkyd resin liquid or liquid phenolic resin;Toughener is acrylic rubber, carboxy nitrile rubber, neoprene rubber
One of glue, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is in polyethylene, polyvinyl chloride or haloflex
It is one or more;
Plastic cement auxiliary agent is the mixture of plasticiser, antioxidant and anti-virus agent that mixing mass ratio is 2:1.5:1;Anti-slip layer auxiliary agent
For the mixture of plasticiser, antioxidant, UV resistant agent and anti-virus agent that mixing mass ratio is 1:2:1;
It is connected to a fixed between plastic resilient layer and foundation base by binder, which includes with the following group according to the mass fraction
Point: resin aqueous emulsion: 25 parts, silicon carbide micro-powder: 23 parts, polypropylene carbonate rouge: 14 parts, styrene: 6 parts, 2- butanone cyclohexanone:
2 parts, acetone: 8 parts, allyl alcohol: 5 parts, nitroethane: 2 parts, ethylene glycol: 6 parts, crosslinking agent: 7 parts, coalescing agent: 13 parts, defoaming
Agent: 4 parts, solvent: 11 parts;
Environment-friendly type aqueous plastic material, silicon carbide micro-powder is black silicon carbide and partial size is 4 μm;Crosslinking agent is that polyethylene or chlorination are poly-
One of ethylene;Coalescing agent is one of ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol or propylene glycol;Defoaming agent is
One or more of organosilicon, organosiloxane or amide;The solvent is water.
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape
At technical solution, fall within the scope of protection required by the present invention.
Claims (7)
1. a kind of environment-friendly type aqueous plastic material, including foundation base, the plastic resilient layer and anti-skidding set gradually from the bottom to top
Layer, it is characterised in that: the foundation base use concrete or pitch material, the plastic resilient layer include according to the mass fraction with
Lower component: cement: 13-19 parts, aqueous polymer emulsion: 19-21 parts, base-material lotion: 3-9 parts, resin liquid: 3-8 parts, titanium dioxide
Silicon: 11-14 parts, alcohol-soluble acrylate: 4-8 parts, toughener: 10-14 parts, coupling agent: 6-9 parts, plastic cement auxiliary agent: 10-
13 parts;The anti-slip layer includes following components according to the mass fraction: cement: 6-9 parts, pigments and fillers: and 13-18 parts, solvent: 9-14
Part, nano silica: 10-19 parts, butyl acrylate: 8-13 parts, anti-slip layer auxiliary agent: 13-19 parts, colored EPDM particle: 30-
37 parts;
The base-material lotion is one in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind;The resin liquid is one of alkyd resin liquid or liquid phenolic resin;The toughener is acrylic rubber, carboxylic
One of base nitrile rubber, neoprene, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is polyethylene, gathers
One of vinyl chloride or haloflex are a variety of.
2. environment-friendly type aqueous plastic material according to claim 1, it is characterised in that: the plastic cement auxiliary agent is mixing quality
Than the mixture for the plasticiser of 2:1.5:1, antioxidant and anti-virus agent;It is 1 that the anti-slip layer auxiliary agent, which is mixing mass ratio:
The plasticiser of 2:1, antioxidant, UV resistant agent and anti-virus agent mixture.
3. environment-friendly type aqueous plastic material according to claim 1, it is characterised in that: the plastic resilient layer and basal plane
It is connected to a fixed between layer by binder, described binder includes following components according to the mass fraction: water-base resin cream
Liquid: 22-29 parts, silicon carbide micro-powder: 21-25 parts, polypropylene carbonate rouge: 10-17 parts, styrene: 3-9 parts, 2- butanone cyclohexanone: 1-
3 parts, acetone: 3-10 parts, allyl alcohol: 4-7 parts, nitroethane: 1-4 parts, ethylene glycol: 3-8 parts, crosslinking agent: 3-10 parts, film forming helps
Agent: 11-15 parts, defoaming agent: 2-5 parts, solvent: 7-12 parts.
4. environment-friendly type aqueous plastic material according to claim 3, it is characterised in that: the silicon carbide micro-powder is black carbonization
Silicon and partial size are 2-6 μm;The crosslinking agent is one of polyethylene or haloflex;The coalescing agent is ethylene glycol ethyl ethers
One of ether, butyl glycol ether, ethylene glycol or propylene glycol;The defoaming agent is in organosilicon, organosiloxane or amide
It is one or more of;The solvent is water.
5. environment-friendly type aqueous plastic material according to claim 1, it is characterised in that: the foundation base using concrete or
Pitch material, the plastic resilient layer includes following components according to the mass fraction: cement: 13 parts, aqueous polymer emulsion: 19
Part, base-material lotion: 3 parts, resin liquid: 3 parts, silica: 11 parts, alcohol-soluble acrylate: 4 parts, toughener: 10 parts,
Coupling agent: 6 parts, plastic cement auxiliary agent: 10 parts;The anti-slip layer includes following components according to the mass fraction: cement: 6 parts, face is filled out
Material: 13 parts, solvent: 9 parts, nano silica: 10 parts, butyl acrylate: 8 parts, anti-slip layer auxiliary agent: 13 parts, colored EPDM
Grain: 30 parts;
The base-material lotion is one in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind;The resin liquid is one of alkyd resin liquid or liquid phenolic resin;The toughener is acrylic rubber, carboxylic
One of base nitrile rubber, neoprene, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is polyethylene, gathers
One of vinyl chloride or haloflex are a variety of.
6. environment-friendly type aqueous plastic material according to claim 1, it is characterised in that: the foundation base using concrete or
Pitch material, the plastic resilient layer includes following components according to the mass fraction: cement: 19 parts, aqueous polymer emulsion: 21
Part, base-material lotion: 9 parts, resin liquid: 8 parts, silica: 14 parts, alcohol-soluble acrylate: 8 parts, toughener: 14 parts,
Coupling agent: 9 parts, plastic cement auxiliary agent: 13 parts;The anti-slip layer includes following components according to the mass fraction: cement: 9 parts, face is filled out
Material: 18 parts, solvent: 14 parts, nano silica: 19 parts, butyl acrylate: 13 parts, anti-slip layer auxiliary agent: 19 parts, colored EPDM
Particle: 37 parts;
The base-material lotion is one in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind;The resin liquid is one of alkyd resin liquid or liquid phenolic resin;The toughener is acrylic rubber, carboxylic
One of base nitrile rubber, neoprene, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is polyethylene, gathers
One of vinyl chloride or haloflex are a variety of.
7. environment-friendly type aqueous plastic material according to claim 1, it is characterised in that: the foundation base using concrete or
Pitch material, the plastic resilient layer includes following components according to the mass fraction: cement: 16 parts, aqueous polymer emulsion: 20
Part, base-material lotion: 6 parts, resin liquid: 5 parts, silica: 12 parts, alcohol-soluble acrylate: 6 parts, toughener: 12 parts,
Coupling agent: 8 parts, plastic cement auxiliary agent: 12 parts;The anti-slip layer includes following components according to the mass fraction: cement: 7 parts, face is filled out
Material: 15 parts, solvent: 11 parts, nano silica: 16 parts, butyl acrylate: 11 parts, anti-slip layer auxiliary agent: 15 parts, colored EPDM
Particle: 35 parts;
The base-material lotion is one in acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or PVAc emulsion
Kind;The resin liquid is one of alkyd resin liquid or liquid phenolic resin;The toughener is acrylic rubber, carboxylic
One of base nitrile rubber, neoprene, chlorosulfonated polyethylene or ABS resin;The coupling agent stated is polyethylene, gathers
One of vinyl chloride or haloflex are a variety of.
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Cited By (1)
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CN112322023A (en) * | 2020-11-23 | 2021-02-05 | 浙江锦润生物科技有限公司 | Environment-friendly plastic additive and preparation method thereof |
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