CN109130374A - A kind of antistatic and antibacterial textile fabric and preparation method thereof - Google Patents

A kind of antistatic and antibacterial textile fabric and preparation method thereof Download PDF

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Publication number
CN109130374A
CN109130374A CN201811010923.XA CN201811010923A CN109130374A CN 109130374 A CN109130374 A CN 109130374A CN 201811010923 A CN201811010923 A CN 201811010923A CN 109130374 A CN109130374 A CN 109130374A
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Prior art keywords
fabric
antistatic
antibacterial
outer shell
textile fabric
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CN201811010923.XA
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CN109130374B (en
Inventor
曾朝辉
姚湘
谭艳林
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Xiangtan University
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Longshan Jaoba Mei Handicraft Fabrics Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • B32B2262/065Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14Mixture of at least two fibres made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21Anti-static
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A kind of antistatic and antibacterial textile fabric, is made of, which is characterized in that the fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber fabric, outer shell fabric;The antistatic and antibacterial textile fabric is further impregnated into the compound hydrosol of antistatic and antibacterial after binding the fabric by adhesive and the outer shell fabric to be infiltrated, and is then dried, is baked the antistatic and antibacterial textile fabric described in obtaining.The present invention uses unique dual antistatic technology and antimicrobial technology, it is prepared and a kind of has both antistatic and antibiotic effect textile fabric, it solves the problems, such as toy, the electrostatic hazard in fabrics production and later period sale, show and easily adsorb and gather in the process dust, the addition based on antibacterial material uses simultaneously, the preparation-obtained product of the present invention has certain antibacterial activity, improves the safety of product.

Description

A kind of antistatic and antibacterial textile fabric and preparation method thereof
Technical field:
The invention belongs to field of fabric producing technology, and in particular to a kind of antistatic and antibacterial textile fabric and preparation method thereof.
Background technique:
With the progress of science and technology and the raising of living standards of the people, people are in production and life to the function of textile Property proposes more and higher requirement, such as the comfort, aesthetics, health of product, if environmentally protective, if can Meet outstanding industry requirement etc..In order to meet the market demand of functional textile, accelerate functional textile exploitation and Research, many scientific research institutions and enterprise accelerate the research steps of functional textile.Such as have softness, heat preservation, hydroscopic fast-drying, The textile of the comfortable function of the features such as Waterproof Breathable;Has the features such as fire-retardant, antistatic, waterproof, antiultraviolet, antibacterial Household and fabrics for industrial use.
Textile in production and processing and use easily because rubbing and incuding generation electrostatic, and the resistance of conventional fibrous materials Rate is 1010Ω cm or more, generated charge are not easy loss.Electrostatic phenomenon is still unknown in cellulose fibre processing It is aobvious;The electrostatic interference of protein fibre is with regard to more serious.Although wool fibre has higher equilibrium moisture regain, but its mass specific resistance Reach highest in natural fiber;The resistivity of the universal lower synthetic fibers of regain is up to 1414Ω cm or more, electricity Lotus accumulation phenomena is more significant.Wool manufacturing production in textile material electrification phenomenon often will lead to fiber winding or blocking parts, Semi-products or yarn is scared, broken end, Warp opening is unclear when weaving, and fabric folds phenomena such as uneven, influences the smooth of production It carries out;In use, the accumulation of electrostatic charge easily causes dust to adhere to, clothes tangle limbs and generate adherency sense of discomfort textile. For hand woven product or fabric toy, for weaver, there are certain injuries, such as static guiding for the presence of electrostatic PH value of blood is caused to rise, calcium content reduces in blood, calcium content increases in urine, blood glucose rise, the decline of vitamin C content etc., And electrostatic also causes dust to adsorb and gather, and seriously affects image appearance and the sale of fabrics class product.
In addition, major consumers crowd detects towards children population according to scientific research personnel: disappearing for toy production After the toy that poison is crossed is played 10 days to baby, the bacteria colonies number on plastic toy is up to more than 3000, up to close on wooden toy 5000, and it is unexpectedly a up to more than 20,000 on the toy of fur production, it also detected Escherichia coli, hepatitis type B virus in toy The problem of equal pathogenic microorganisms, pollution level is even more serious than clothes, bedding and tableware etc. therefore child stings toy, should Paid attention to.Therefore, there is also urgent demands for the anti-microbial property of fabrics or braiding type toy.
In the prior art, more for individual antistatic textile fabric research, for example, application for a patent for invention CN201310685527.8 is related to a kind of antistatic textile fabric, is made of fabric, outer shell fabric, the internal layer each component Parts by weight be 65 ~ 82 parts of pure cotton, 8 ~ 22 parts of silk, antistatic silk interweave 10 ~ 23 parts;The parts by weight of the surface layer each component Number is 61 ~ 79 parts of bamboo fibre, 11 ~ 19 parts of cotton fiber, 12 ~ 28 parts of spandex fibre.Antistatic textile fabric of the present invention is quiet with resisting Electricity Functional avoids fabric since material easily generates electrostatic between skin below for dehydration, and structure is simple, and fabric can be effectively reduced Coefficient of friction reduces the yield of electrostatic charge in friction, static electricity resistance with higher.Application for a patent for invention CN201110436608.5 discloses a kind of Antistatic nylon textile.The single fiber surface of the textile is covered with epithelium resin Layer, and epithelium resin layer is crosslinked the polyether polyurethane resin reacted and fluorine system by the end group with nylon fiber Resin is formed.The initial stage of the textile, which is charged by friction, is pressed in 2000V hereinafter, water repellent degree is at 4 grades or more, refuse oil content 4 grades with On;Home washings 20 are charged by friction pressure 2500V hereinafter, water repellent degree at 3 grades or more, refuses oil content at 3 grades or more after returning.The present invention fills out The blank that nylon textile cannot have both antistatic property, water and oil repellant performance simultaneously is mended.Application for a patent for invention CN201511028832.5 provides a kind of antibacterial fabric and preparation method thereof, and antibacterial fabric provided by the invention passes through Silver nano-grain is deposited on the textile of carried titanium dioxide to obtain;The present invention by first depositing titanium dioxide on the textile Titanium, and the pattern of the titanium dioxide deposited is flower pattern, then silver nano-grain is deposited on to the weaving of carried titanium dioxide again On product, so that the washability for the antibacterial fabric that the present invention obtains is good, and the method for preparing textile is simple, the production cycle Short, the three wastes are few.Xu Huashan etc. introduces resistance aiming at the problem that comprehensive performance of flame-retardant and anti-static fabric cannot be met the requirements Fire-retardant principle, the fire retardant mechanism of action, preparation and the flame retardant property evaluation of textile material are fired, and to the system of flame-retardant and anti-static fabric Preparation Method and points for attention are summarized (weaving report the 7th phase in 2016).
Antistatic and antibacterial characteristics textile materials are had both it is found that not yet producing at present based on the above prior art, it is special Be not for toy manufacturer or hand-made braiding production for staple market meaning have both it is antistatic and The textile fabric of antibacterial characteristics.And this be exactly current toy, braiding, cloth spinning process product production in urgent need to resolve the technical issues of.
Summary of the invention:
Based on development does not have both antistatic and antibacterial characteristics textile materials in the prior art, be not well positioned to meet toy, Braiding and the production of cloth spinning process product and the market demand, the present invention is intended to provide a kind of antistatic and antibacterial textile fabric and its preparation Method, the textile fabric have good antistatic property, can be avoided cloth textile fabric in further production process Electrostatic phenomenon, for handicraft, practitioner is more friendly, and the product processed is not easy to adsorb and gather dust, has antibacterial Effect, can preferably protect the health of consumer.
In order to solve the above technical problems, the present invention uses following technological means:
A kind of antistatic and antibacterial textile fabric, is made of, which is characterized in that the fabric fabric, outer shell fabric It is made of pure cotton and intertexture with antistatic silk, the outer shell fabric is made of bamboo fibre and cotton fiber.
Antistatic and antibacterial textile fabric the fabric is binded by adhesive and the outer shell fabric.
The antistatic and antibacterial textile fabric is sticking the fabric by adhesive and the outer shell fabric Further be impregnated into the antistatic and compound hydrosol of antibacterial and infiltrated after conjunction, then dry, bake obtain it is described resist it is quiet Electricity and antibacterial textile fabric.
The fabric is to be interwoven using pure cotton as warp using intertexture with antistatic silk as weft, the outer layer surface Material is to be interwoven using bamboo fibre as warp by weft of cotton fiber.The specification that pure cotton described in fabric uses for 16.0-17.1 tex, the intertexture are 1.8-2.3tex with the specification of antistatic silk;In outer shell fabric, the rule of the bamboo fibre Lattice are 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex.
The described antistatic and compound hydrosol of antibacterial is prepared with the following method:
The polyethylene glycol of the isopropanol of 5-7 parts by weight, the nano-ZnO of 1-2 parts by weight and 2-3 parts by weight is dissolved in by step 1 In 80-85 DEG C of water of 100 parts by weight, then with glacial acetic acid according to 1:(1-1.5) volume ratio mix, it is molten to obtain compound acetic acid Liquid;
2-5 parts by weight chitosan is dissolved into the compound acetum that step 1 is prepared, obtains chitosan vinegar by step 2 Acid solution, then by the AgNO of 0.8-2 parts by weight3It is dissolved into chitosan-acetic acid solution that obtain Chitosan-Silver composite antibacterial molten Liquid;
80-90 parts by weight ethyl orthosilicate is added to step 2 preparation under high velocity agitation with 1 drop/sec of speed by step 3 In obtained Chitosan-Silver composite antibacterial solution, magnetic stirrer is quickly stirred 3 hours at room temperature, obtains Chitosan-Silver- SiO2The compound hydrosol, i.e., described antistatic and compound hydrosol of antibacterial.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk;It is warp with bamboo fibre Line interweaves to obtain outer shell fabric as weft using cotton fiber;
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric;
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates by step 3, then drying, It bakes and obtains the antistatic and antibacterial textile fabric.
The drying refers to dries 20-30 minutes at 80-85 DEG C;The baking, which refers to, bakes 5-8 at 120-130 DEG C Minute.
Based on above technical scheme, the present invention has following advantages and beneficial effects:
Firstly, inventor is based on antistatic and antibacterial demand present in toy and fabrics processing, preparation one is originally proposed Kind has both antistatic and antibiotic effect textile fabric, to solve toy, the electrostatic hazard in fabrics production and later period Sale shows the problem of easily adsorbing in the process and gather dust, while the addition based on antibacterial material uses, prepared by the present invention Obtained product has certain antibacterial activity, and poisonous and hazardous ingredient is not used in present invention production, to consumer safety, It is friendly.
Secondly, the present invention uses dual antistatic treatment technology, uses and interweave with anti-in fabric production process Electrostatic silk is weft, has good electric conductivity, can sufficiently be discharged in production and product use process since friction is led The phenomenon that electrostatic of cause gathers, on the other hand, the present invention also use the antistatic and compound hydrosol of antibacterial, wherein being added to has Silver ion, nano zine oxide of excellent conductive performance etc. are also beneficial to the diffusion of electrostatic, will not generate the phenomenon that electrostatic gathers.
Again, compound using chitosan and silver ion in the present invention, the two cooperation synergistic effect, so that fabric is with good Antibacterial functions.
In conclusion the present invention use unique dual antistatic technology and antimicrobial technology, be prepared one kind have both it is anti- The textile fabric of electrostatic and antibiotic effect solves toy, the electrostatic hazard in fabrics production and later period sale, showed The problem of easily adsorbing in journey and gather dust, while the addition based on antibacterial material uses, the preparation-obtained product of the present invention Have certain antibacterial activity, improves the safety of product.
Specific embodiment:
Embodiment 1: a kind of antistatic and antibacterial textile fabric is made of, which is characterized in that described fabric, outer shell fabric Fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk;It is warp with bamboo fibre Line interweaves to obtain outer shell fabric as weft using cotton fiber;
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric;
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates by step 3, then drying, It bakes and obtains the antistatic and antibacterial textile fabric.
The drying refers to dries 20 minutes at 85 DEG C;The baking refers to be baked 5 minutes at 130 DEG C.
The specification that pure cotton described in fabric uses is 16.0-17.1 tex, the rule to interweave with antistatic silk Lattice are 1.8-2.3tex;In outer shell fabric, the specification of the bamboo fibre is 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex。
The described antistatic and compound hydrosol of antibacterial is prepared with the following method:
The polyethylene glycol of the isopropanol of 6 parts by weight, the nano-ZnO of 2 parts by weight and 3 parts by weight is dissolved in 100 weight by step 1 In 80-85 DEG C of the water of part, is then mixed with glacial acetic acid according to the volume ratio of 1:1, obtain compound acetum;
4 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan acetic acid by step 2 Solution, then by the AgNO of 1 parts by weight3It is dissolved into chitosan-acetic acid solution and obtains Chitosan-Silver composite antibacterial solution;
85 parts by weight ethyl orthosilicates are added to step 2 under high velocity agitation with 1 drop/sec of speed and are prepared by step 3 Chitosan-Silver composite antibacterial solution in, magnetic stirrer quickly stirs 3 hours at room temperature, obtains Chitosan-Silver-SiO2It is multiple Heshui colloidal sol, i.e., described antistatic and compound hydrosol of antibacterial.
Embodiment 2: a kind of antistatic and antibacterial textile fabric is made of fabric, outer shell fabric, which is characterized in that The fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk;It is warp with bamboo fibre Line interweaves to obtain outer shell fabric as weft using cotton fiber;
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric;
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates by step 3, then drying, It bakes and obtains the antistatic and antibacterial textile fabric.
The drying refers to dries 30 minutes at 80 DEG C;The baking refers to be baked 8 minutes at 120 DEG C.
The specification that pure cotton described in fabric uses is 16.0-17.1 tex, the rule to interweave with antistatic silk Lattice are 1.8-2.3tex;In outer shell fabric, the specification of the bamboo fibre is 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex。
The described antistatic and compound hydrosol of antibacterial is prepared with the following method:
The polyethylene glycol of the isopropanol of 7 parts by weight, the nano-ZnO of 1 parts by weight and 2 parts by weight is dissolved in 100 weight by step 1 In 80-85 DEG C of the water of part, is then mixed with glacial acetic acid according to the volume ratio of 1:1.5, obtain compound acetum;
5 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan acetic acid by step 2 Solution, then by the AgNO of 2 parts by weight3It is dissolved into chitosan-acetic acid solution and obtains Chitosan-Silver composite antibacterial solution;
80 parts by weight ethyl orthosilicates are added to step 2 under high velocity agitation with 1 drop/sec of speed and are prepared by step 3 Chitosan-Silver composite antibacterial solution in, magnetic stirrer quickly stirs 3 hours at room temperature, obtains Chitosan-Silver-SiO2It is multiple Heshui colloidal sol, i.e., described antistatic and compound hydrosol of antibacterial.
Embodiment 3: a kind of antistatic and antibacterial textile fabric is made of fabric, outer shell fabric, which is characterized in that The fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk;It is warp with bamboo fibre Line interweaves to obtain outer shell fabric as weft using cotton fiber;
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric;
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates by step 3, then drying, It bakes and obtains the antistatic and antibacterial textile fabric.
The drying refers to dries 20 minutes at 85 DEG C;The baking refers to be baked 8 minutes at 120 DEG C.
The specification that pure cotton described in fabric uses is 16.0-17.1 tex, the rule to interweave with antistatic silk Lattice are 1.8-2.3tex;In outer shell fabric, the specification of the bamboo fibre is 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex。
The described antistatic and compound hydrosol of antibacterial is prepared with the following method:
The polyethylene glycol of the isopropanol of 5 parts by weight, the nano-ZnO of 2 parts by weight and 3 parts by weight is dissolved in 100 weight by step 1 In 80-85 DEG C of the water of part, is then mixed with glacial acetic acid according to the volume ratio of 1:1, obtain compound acetum;
3 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan acetic acid by step 2 Solution, then by the AgNO of 0.9 parts by weight3It is dissolved into chitosan-acetic acid solution and obtains Chitosan-Silver composite antibacterial solution;
85 parts by weight ethyl orthosilicates are added to step 2 under high velocity agitation with 1 drop/sec of speed and are prepared by step 3 Chitosan-Silver composite antibacterial solution in, magnetic stirrer quickly stirs 3 hours at room temperature, obtains Chitosan-Silver-SiO2It is multiple Heshui colloidal sol, i.e., described antistatic and compound hydrosol of antibacterial.
Embodiment 4: antistatic test
With reference to textile machine and textile industry standard FZ/T 01042-1996 " textile material antistatic property electrostatic pressure half-life period Measurement " on II fabric induction type electro static instrument (having an area of Instrument Ltd. in Wenzhou) of FY342E- the induced voltage of test fabric and Half-life period, wherein being compared using following comparative example 1 as reference, concrete outcome such as the following table 1:
The antistatic test result of table 1
Sample Induced voltage (V) Half-life period (s)
Comparative example 1 3200.0 8.50
Embodiment 1 2735.5 1.25
Embodiment 2 2698.0 1.10
Wherein comparative example 1 are as follows: a kind of textile fabric is made of fabric, outer shell fabric, which is characterized in that in described Shell fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.The woven face The preparation method of material includes the following steps: step 1: using pure cotton as warp, interweaving to obtain using intertexture with antistatic silk as weft interior Shell fabric;Using bamboo fibre as warp, interweave to obtain outer shell fabric as weft using cotton fiber;Step 2 leads to the fabric It crosses adhesive and the outer shell fabric binds to obtain the textile fabric.
By the result of the above table 1 it is found that preparation-obtained antistatic and antibacterial textile fabric of the invention, quiet using resisting Electricity and the compound hydrosol processing of antibacterial, induced voltage and half-life period are obviously reduced, i.e., antistatic performance has obtained greatly Improve, illustrate antistatic and antibacterial textile fabric surface of the invention can quick loss charge, assemble it can not.Compared to not Using the textile fabric of the compound hydrosol processing of antistatic and antibacterial, antistatic property has obtained greatly being promoted.
Embodiment 5: antibacterial tests
Main antibacterial characteristics of the invention are handled from the compound hydrosol of antistatic and antibacterial, thus based on antibacterial activity verifying It needs, following comparative testing example is arranged in inventor:
Comparative example 2: silver-SiO2The compound hydrosol is prepared with the following method: step 1, by the isopropyl of 5 parts by weight The polyethylene glycol of alcohol, the nano-ZnO of 2 parts by weight and 3 parts by weight is dissolved in 80-85 DEG C of water of 100 parts by weight, then with ice Acetic acid is mixed according to the volume ratio of 1:1, obtains compound acetum;Step 2, by the AgNO of 0.9 parts by weight3It is dissolved into step In the one compound acetum being prepared, silver ion composite antibacterial solution is obtained;Step 3, by 85 parts by weight ethyl orthosilicates It is added under high velocity agitation with 1 drop/sec of speed in the silver ion composite antibacterial solution that step 2 is prepared, at room temperature magnetic Power blender quickly stirs 3 hours, obtains silver-SiO2The compound hydrosol.
Comparative example 3: chitosan-SiO2The compound hydrosol is prepared with the following method: step 1, by 6 weight The isopropanol, the nano-ZnO of 2 parts by weight and the polyethylene glycol of 3 parts by weight of part are dissolved in 80-85 DEG C of water of 100 parts by weight, It is then mixed with glacial acetic acid according to the volume ratio of 1:1, obtains compound acetum;4 parts by weight chitosans are dissolved by step 2 In the compound acetum that step 1 is prepared, chitosan-acetic acid solution is obtained;Step 3, by 85 parts by weight ethyl orthosilicates It is added under high velocity agitation with 1 drop/sec of speed in the chitosan-acetic acid solution that step 2 is prepared, magnetic force stirs at room temperature It mixes machine quickly to stir 3 hours, obtains chitosan-SiO2The compound hydrosol.
Same pieces of cloth are carried out to Escherichia coli, Pseudomonas aeruginosa, staphylococcus aureus processing respectively, are then respectively put into The embodiment of the present invention 1,2, in the compound hydrosol solution of comparative test 2 and 3, the time is 15 minutes, counts big in each processing group The sterilizing rate of enterobacteria, Pseudomonas aeruginosa, staphylococcus aureus, concrete outcome such as the following table 2:
2 antibacterial tests result of table
Escherichia coli Staphylococcus aureus Pseudomonas aeruginosa
Embodiment 1 100% 100% 100%
Embodiment 2 99.8% 100% 99.7%
Comparative example 2 92.5% 87.3% 85.5%
Comparative example 3 77.7% 75.3% 70.3%
Test result based on the above table 2 it is found that the compound hydrosol of antistatic and antibacterial of the invention due to using silver ion And chitosan, the two cooperate, synergistic effect so that its with good sterilization and anti-microbial property, compared to individually using silver from The comparative example 2 of son and the comparative example 3 for individually using chitosan, bactericidal effect is greatly improved.The above examination Test the result shows that, in the compound hydrosol of antistatic and antibacterial between silver ion and chitosan have synergistic effect, can be significant Enhance the anti-microbial property of fabric.

Claims (8)

1. a kind of antistatic and antibacterial textile fabric, is made of, which is characterized in that the inner layer surface fabric, outer shell fabric Material is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber;It is described antistatic and The fabric of antibacterial textile fabric is binded by adhesive and the outer shell fabric;The antistatic and antibacterial weaving Fabric is further impregnated into antistatic and antibacterial after binding the fabric by adhesive and the outer shell fabric and answers It is infiltrated in Heshui colloidal sol, then dries, bakes the antistatic and antibacterial textile fabric described in obtaining.
2. according to claim 1 antistatic and antibacterial textile fabric, which is characterized in that the fabric is with pure cotton It for warp, is interwoven using intertexture with antistatic silk as weft, the outer shell fabric is to be with cotton fiber using bamboo fibre as warp Weft is interwoven.
3. according to claim 1 or 2 antistatic and antibacterial textile fabric, which is characterized in that described in fabric For the specification that pure cotton uses for 16.0-17.1 tex, the intertexture is 1.8-2.3tex with the specification of antistatic silk;Outer shell fabric In, the specification of the bamboo fibre is 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex.
4. according to claim 1 or 2 antistatic and antibacterial textile fabric, which is characterized in that described antistatic and antibacterial The compound hydrosol is prepared with the following method:
The polyethylene glycol of the isopropanol of 5-7 parts by weight, the nano-ZnO of 1-2 parts by weight and 2-3 parts by weight is dissolved in by step 1 In 80-85 DEG C of water of 100 parts by weight, then with glacial acetic acid according to 1:(1-1.5) volume ratio mix, it is molten to obtain compound acetic acid Liquid;
2-5 parts by weight chitosan is dissolved into the compound acetum that step 1 is prepared, obtains chitosan vinegar by step 2 Acid solution, then by the AgNO of 0.8-2 parts by weight3It is dissolved into chitosan-acetic acid solution that obtain Chitosan-Silver composite antibacterial molten Liquid;
80-90 parts by weight ethyl orthosilicate is added to step 2 preparation under high velocity agitation with 1 drop/sec of speed by step 3 In obtained Chitosan-Silver composite antibacterial solution, magnetic stirrer is quickly stirred 3 hours at room temperature, obtains Chitosan-Silver- SiO2The compound hydrosol, i.e., described antistatic and compound hydrosol of antibacterial.
5. -2 described in any item antistatic and antibacterial textile fabrics according to claim 1, which is characterized in that it is described antistatic and The preparation method of antibacterial textile fabric includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk;It is warp with bamboo fibre Line interweaves to obtain outer shell fabric as weft using cotton fiber;
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric;
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates by step 3, then drying, It bakes and obtains the antistatic and antibacterial textile fabric.
6. according to claim 5 antistatic and antibacterial textile fabric, which is characterized in that the drying refers in 80-85 It is dried 20-30 minutes at DEG C;The baking refers to be baked 5-8 minutes at 120-130 DEG C.
7. a kind of prepare of any of claims 1-6 antistatic and antibacterial textile fabric method, which is characterized in that Include the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk;It is warp with bamboo fibre Line interweaves to obtain outer shell fabric as weft using cotton fiber;
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric;
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates by step 3, then drying, It bakes and obtains the antistatic and antibacterial textile fabric.
8. the preparation method of antistatic and antibacterial textile fabric according to claim 7, which is characterized in that the drying is Finger is dried 20-30 minutes at 80-85 DEG C;The baking refers to be baked 5-8 minutes at 120-130 DEG C.
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CN109774282A (en) * 2019-03-15 2019-05-21 广州市拓新纺织科技有限公司 A kind of fire resisting antibacterial type Curtain cloth and preparation method thereof
CN112026320A (en) * 2020-09-04 2020-12-04 周鹏 Textile fabric with antistatic and antibacterial functions and preparation method thereof
CN112721347A (en) * 2020-12-22 2021-04-30 江苏翔鹰纺织科技有限公司 Production process of anti-static antibacterial textile fabric
CN113802383A (en) * 2021-09-16 2021-12-17 苏州同构科技有限公司 Antistatic flexible fabric and preparation method and application thereof
CN114834108A (en) * 2022-05-19 2022-08-02 东莞市科迪实业有限公司 Composite non-woven fabric and preparation method thereof
CN115352138A (en) * 2022-09-06 2022-11-18 浙江宏都寝具有限公司 Antistatic bedding fabric and preparation process thereof
CN115627640A (en) * 2022-09-08 2023-01-20 广东莱竣电子科技有限公司 Flame-retardant antibacterial fabric and preparation method thereof

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Cited By (10)

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Publication number Priority date Publication date Assignee Title
CN109774282A (en) * 2019-03-15 2019-05-21 广州市拓新纺织科技有限公司 A kind of fire resisting antibacterial type Curtain cloth and preparation method thereof
CN112026320A (en) * 2020-09-04 2020-12-04 周鹏 Textile fabric with antistatic and antibacterial functions and preparation method thereof
CN112026320B (en) * 2020-09-04 2023-04-18 普宁市晨盛纺织有限公司 Textile fabric with antistatic and antibacterial functions and preparation method thereof
CN112721347A (en) * 2020-12-22 2021-04-30 江苏翔鹰纺织科技有限公司 Production process of anti-static antibacterial textile fabric
CN113802383A (en) * 2021-09-16 2021-12-17 苏州同构科技有限公司 Antistatic flexible fabric and preparation method and application thereof
CN114834108A (en) * 2022-05-19 2022-08-02 东莞市科迪实业有限公司 Composite non-woven fabric and preparation method thereof
CN114834108B (en) * 2022-05-19 2024-03-29 东莞市科迪实业有限公司 Composite non-woven fabric and preparation method thereof
CN115352138A (en) * 2022-09-06 2022-11-18 浙江宏都寝具有限公司 Antistatic bedding fabric and preparation process thereof
CN115352138B (en) * 2022-09-06 2023-09-29 浙江宏都寝具有限公司 Antistatic bedding fabric and preparation process thereof
CN115627640A (en) * 2022-09-08 2023-01-20 广东莱竣电子科技有限公司 Flame-retardant antibacterial fabric and preparation method thereof

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