CN109129791A - A kind of production technology of particleboard with zero-formaldehyde emission - Google Patents

A kind of production technology of particleboard with zero-formaldehyde emission Download PDF

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Publication number
CN109129791A
CN109129791A CN201811132022.8A CN201811132022A CN109129791A CN 109129791 A CN109129791 A CN 109129791A CN 201811132022 A CN201811132022 A CN 201811132022A CN 109129791 A CN109129791 A CN 109129791A
Authority
CN
China
Prior art keywords
wood shavings
glue
particleboard
zero
production technology
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811132022.8A
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Chinese (zh)
Inventor
陈秀兰
王丽
王俊伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DARE WOOD BASED PANEL GROUP Co Ltd
Daya Wood Industry (jiangsu) Co Ltd
Original Assignee
DARE WOOD BASED PANEL GROUP Co Ltd
Daya Wood Industry (jiangsu) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DARE WOOD BASED PANEL GROUP Co Ltd, Daya Wood Industry (jiangsu) Co Ltd filed Critical DARE WOOD BASED PANEL GROUP Co Ltd
Priority to CN201811132022.8A priority Critical patent/CN109129791A/en
Publication of CN109129791A publication Critical patent/CN109129791A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27LREMOVING BARK OR VESTIGES OF BRANCHES; SPLITTING WOOD; MANUFACTURE OF VENEER, WOODEN STICKS, WOOD SHAVINGS, WOOD FIBRES OR WOOD POWDER
    • B27L11/00Manufacture of wood shavings, chips, powder, or the like; Tools therefor
    • B27L11/02Manufacture of wood shavings, chips, powder, or the like; Tools therefor of wood shavings or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • B27N1/02Mixing the material with binding agent
    • B27N1/0209Methods, e.g. characterised by the composition of the agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/02Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • B27N3/18Auxiliary operations, e.g. preheating, humidifying, cutting-off

Abstract

The invention belongs to wood processing fields, are related to a kind of production technology of particleboard with zero-formaldehyde emission.Include: timber/broken veneer/section feeds intake → chip → flaking → particle drying → screening → glue compounding and applying → mat formation → precompressed → hot pressing → cutting edge → cooling → quenched → sanding → inspection point etc. → be packed and stored, wherein: in the particle drying step, the wood shavings moisture content after drying is in 1.5-2.5%;It in the glue compounding and applying step, is layered and is glued using watch core layer, surface layer adhesive is no aldehyde rubber made from soybean cake, and sandwich layer adhesive is aqueous polyamide and PMDI.Particieboard obtained by the present invention, without containing poisonous and harmful substances such as free formaldehydes, burst size of methanal is almost 0mg/100g, and mechanical property meets country and company standard, overcomes the deficiency that current particieboard has Form aldehyde release;It is poor to solve the disadvantages that form using the surface layer MDI wood shavings, need to use release agent.Present invention efficiently solves the formaldehyde pollution problems of China's indoor environment, get rid of burst size of methanal for wood-based panel product and provide new solution route.

Description

A kind of production technology of particleboard with zero-formaldehyde emission
Technical field
The invention belongs to wood processing fields, are related to the production of particieboard, in particular to a kind of life of particleboard with zero-formaldehyde emission Production. art.
Background technique
Particieboard is one of the principal item for customizing household plate, is mainly added with timber or non-wood plant fibre raw material Work applies adhesive and other additives at wood shavings (or particle), and assembly forms and through one kind artificial board made of hot pressing.Urea Urea formaldehyde or modified urea-formaldehyde resin are the most commonly used adhesives of current artificial board, and wood-based plate is wide in finishing material indoors General application can release formaldehyde in use process to some extent.There is harm to the health of human body in formaldehyde, with quality of the life Raising and low-carbon environment-friendly theory be rooted in the hearts of the people, consumer wishes to obtain more healthy, more environmentally-friendly high-quality plate.Plane Card is one of most popular plate of having furniture made to order at present, and dosage rapidly increases every year.
Artificial board controls Form aldehyde release, reaches E0Or zero-emission is the target that industry of artificial boards is pursued.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, the purpose of the present invention is disclose a kind of life of particleboard with zero-formaldehyde emission Production method.
Technical solution:
A kind of production technology of particleboard with zero-formaldehyde emission, comprises the following steps, timber/broken veneer/section feeds intake → chips → flaking → Particle drying → screening → glue compounding and applying → mats formation → precompressed → hot pressing → cutting edge → cooling → quenched → sanding → inspection point etc. → It is packed and stored, in which:
In the particle drying step, the wood shavings moisture content after drying is in 1.5-2.5%;
It in the glue compounding and applying step, is layered and is glued using watch core layer, surface layer adhesive is no aldehyde rubber made from soybean cake, and sandwich layer adhesive is water Property polyamide and PMDI;
In the step of mating formation, wood shavings moisture content is in 11-14% after the sizing of surface layer, and wood shavings moisture content is in 7-9% after sandwich layer is glued;
In the slab heat-press step, hot pressing temperature is 180-235 DEG C, using five sections of humidity provinces, hot pressing pressure 0-4MPa.
In the more excellent disclosed example of the present invention, in the glue compounding and applying step, surface layer addition manner is by prepared no aldehyde soybean Glue, waterproofing agent emulsified wax pass through surface layer glue system and surface layer wood shavings uniform stirring;Sandwich layer addition manner is will be aqueous poly- Amide, PMDI, waterproofing agent melt paraffin pass through sandwich layer glue system and sandwich layer wood shavings uniform stirring.
In the more excellent disclosed example of the present invention, in the glue compounding and applying step, resin added of the surface layer without aldehyde soybean glue is over dry table The 11-14% of layer wood shavings quality, 0.5% that waterproofing agent emulsified wax additive amount is over dry surface layer wood shavings quality;The aqueous polyamides of sandwich layer Ten thousand China are purchased from outside the amine 5-8% relative to over dry sandwich layer wood shavings quality, PMDI() it is 3-5kg/m3, the addition of waterproofing agent melt paraffin Measure 0.5% relative to over dry sandwich layer wood shavings quality.
In the more excellent disclosed example of the present invention, in the glue compounding and applying step, the component of no aldehyde soybean glue by mass percentage: The soy meal of 25-40%, the dispersing agent of 3-10%, 0.5% antibacterial mildew inhibitor and excess water.
Wherein, the soy meal was 200-300 mesh, powdery;
The dispersing agent is purchased from Guangzhou Xu Xiang Chemical Co., Ltd., and model NN0-B, it is evenly dispersed that dispersing agent facilitates soy meal In glue, it is not easy to be layered;
The antibacterial mildew inhibitor is purchased from the vast biochemical Co., Ltd in Nantong, and model Xin Ke -01C, antibacterial mildew inhibitor is in order to prevent Rotten, the raising stable storing phase occurs for rubber made from soybean cake.
Further, the preparation steps of no aldehyde soybean glue are as follows:
A, water, stirring plus lye pH adjustment are added in a kettle to 10-12;
B, soy meal and dispersing agent are added while stirring;
C, it is all dispersed in water to soy meal, antibacterial mildew inhibitor is added, stir 20-40min;
D, go out sample.
Beneficial effect
Using particieboard made from the method disclosed in the present, without containing the poisonous and harmful substances such as free formaldehyde, the first of plate Aldehyde burst size is almost 0mg/100g, while its mechanical property meets country and company standard, overcomes current particieboard and contains The deficiency of burst size of methanal;It is poor to solve the disadvantages that form using the surface layer MDI wood shavings, release agent need to be used to increase cost.This hair The bright formaldehyde pollution for efficiently solving the problems, such as China's indoor environment, for wood-based panel product get rid of burst size of methanal provide it is new Solution route.
Specific embodiment
The following describes the present invention in detail with reference to examples, so that those skilled in the art more fully understand this hair It is bright, but the invention is not limited to following embodiments can make to the present invention without departing under the spirit and scope of the present invention More technique adjustments.
Embodiment 1
A kind of production technology of 18mm particleboard with zero-formaldehyde emission, includes the following steps:
1, poplar, eucalyptus etc. are chipped by wood chipping equipment;
2, the wood chip being whittled into is formed to the wood shavings of certain form by chipper;
3, wood shavings are dried, dry moisture control is 1.5~2.5%;
4, the wood shavings after drying are removed excessive wood shavings and too small wood shavings by reciprocating gird, while sieving surface layer wood shavings and sandwich layer plane Flower;
5, carry out impregnation respectively to surface layer wood shavings and sandwich layer wood shavings, sizing is handled: surface layer wood shavings are added respectively by glue system Configured no aldehyde soybean glue 13%(opposite cover's over dry wood shavings), emulsified wax 0.5%(opposite cover's over dry wood shavings);Sandwich layer Wood shavings add aqueous polyamide 6%(with respect to sandwich layer over dry glue by glue system respectively), melt paraffin 0.5%(sandwich layer relatively Over dry wood shavings), PMDI additive amount be 4kg/m3;Component without aldehyde soybean glue is by mass percentage: soy meal, and 30%;Dispersion Agent, 6%;Antibacterial mildew inhibitor, 0.5%;Surplus, water;
6, the watch core layer wood shavings after being glued carry out layer+sandwich layer+upper epidermis layering by pavement system respectively and mat formation, by paving Plate, hot pressing factor 4.5-5s/mm, density 665kg/m is made after filling precompressed, hot pressing3, plate moisture content: 5.0~6.8%;
7, the plate come out from press need to carry out cooling treatment through cooling turnover panel, further increase product since temperature is higher Energy;
8, plate after cooling need to carry out modifier treatment at least 48 hours, balance stress, moisture content etc. in plate, improve it Stability;
9, the plate after quenched carries out sanding processing according to demand, and surface pre-hardening thickness sand is removed;
10, required specification plate is sawn to after sanding;
11, divide etc. and packaging.
By 18mm particleboard with zero-formaldehyde emission performance made from the above production technology by GB/T 17657-2013 " wood-based plate and Face artificial board physicochemical property test method " properties of product to be tested, inspection result is as follows:
Table 1
Performance indicator Zero formaldehyde fibers plate of 18mm 18mm furniture type ordinary particle board professional standard
Density kg/m3 665 ≥600
Plate moisture content % 5.5-6.5 3-13
Internal bond strength Mpa 0.4-0.45 ≥0.35
Table bond strength Mpa 1.2 ≥0.8
Static bending strength Mpa 13.5-14 ≥13
2h thickness swelling rate % 3-4 ≤8
Burst size of methanal mg/100g 0.5 E1≤9 E0≤5
Illustrate: the wood-based plate for using formaldehydeless material to manufacture for adhesive is known as Formaldehyde Free Wood-based Panel.Table 1 uses Extraction method Its plate burst size of methanal is detected, during the growth process due to timber, has trace formaldehyde to stay in wood internal as metabolin, therefore Testing result is not entirely 0, and this trace formaldehyde content will not be done harm to huamn body.
Embodiment 2
A kind of production technology of 9mm particleboard with zero-formaldehyde emission, includes the following steps:
1, poplar, eucalyptus etc. are chipped by wood chipping equipment;
2, the wood chip being whittled into is formed to the wood shavings of certain form by chipper;
3, wood shavings are dried, dry moisture control is 1.6~2.2%;
4, the wood shavings after drying are removed excessive wood shavings and too small wood shavings by reciprocating gird, while sieving surface layer wood shavings and sandwich layer plane Flower;
5, carry out impregnation respectively to surface layer wood shavings and sandwich layer wood shavings, sizing is handled: surface layer wood shavings are added respectively by glue system Configured no aldehyde soybean glue 12%(opposite cover's over dry wood shavings), emulsified wax 0.5%(opposite cover's over dry wood shavings);Sandwich layer Wood shavings add aqueous polyamide 7%(with respect to sandwich layer over dry glue by glue system respectively), melt paraffin 0.5%(sandwich layer relatively Over dry wood shavings), PMDI additive amount be 5kg/m3;Component without aldehyde soybean glue is by mass percentage: soy meal, and 30%;Dispersion Agent, 5%;Antibacterial mildew inhibitor, 0.5%;Surplus, water;
6, the watch core layer wood shavings after being glued carry out layer+sandwich layer+upper epidermis layering by pavement system respectively and mat formation, by paving Plate, hot pressing factor 4.5s/mm, density 660kg/m is made after filling precompressed, hot pressing3, plate moisture content: 5.0~6.5%;
7, the plate come out from press need to carry out cooling treatment through cooling turnover panel, further increase product since temperature is higher Energy;
8, plate after cooling need to carry out modifier treatment at least 48 hours, balance stress, moisture content etc. in plate, improve it Stability;
9, the plate after quenched carries out sanding processing according to demand, and surface pre-hardening thickness sand is removed;
10, required specification plate is sawn to after sanding.
11, divide etc. and packaging.
GB/T 17657-2013 " wood-based plate and decorations are pressed by 9mm particleboard with zero-formaldehyde emission performance made from the above production technology Dough figurine makes foliation method for testing performance " properties of product to be tested, inspection result is as follows:
Table 2
Performance indicator Zero formaldehyde fibers plate of 9mm 9mm furniture type ordinary particle board professional standard
Density kg/m3 660 ≥600
Plate moisture content % 5.5 3-13
Internal bond strength MPa 0.48 ≥0.38
Table bond strength MPa 1.1 ≥0.8
Static bending strength MPa 13.8 ≥13
2h thickness swelling rate % 4.5 ≤8
Burst size of methanal mg/100g 0.5 E1≤9 E0≤5
Illustrate: the wood-based plate for using formaldehydeless material to manufacture for adhesive is known as Formaldehyde Free Wood-based Panel.Table 2 uses Extraction method Its plate burst size of methanal is detected, during the growth process due to timber, has trace formaldehyde to stay in wood internal as metabolin, therefore Testing result is not entirely 0, and this trace formaldehyde content will not be done harm to huamn body.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification is applied directly or indirectly in other relevant technical fields, Similarly it is included within the scope of the present invention.

Claims (7)

1. a kind of production technology of particleboard with zero-formaldehyde emission, comprises the following steps, timber/broken veneer/section feeds intake → is chipped → flaking → particle drying → screening → glue compounding and applying → mats formation → precompressed → hot pressing → cutting edge → cooling → quenched → sanding → inspection point etc. → be packed and stored, it is characterised in that:
In the particle drying step, the wood shavings moisture content after drying is in 1.5-2.5%;
It in the glue compounding and applying step, is layered and is glued using watch core layer, surface layer adhesive is no aldehyde rubber made from soybean cake, and sandwich layer adhesive is water Property polyamide and PMDI;
In the step of mating formation, wood shavings moisture content is in 11-14% after the sizing of surface layer, and wood shavings moisture content is in 7-9% after sandwich layer is glued;
In the slab heat-press step, hot pressing temperature is 180-235 DEG C, using five sections of humidity provinces, hot pressing pressure 0-4MPa.
2. the production technology of particleboard with zero-formaldehyde emission according to claim 1, it is characterised in that: in the glue compounding and applying step, table Layer addition manner is that prepared no aldehyde soybean glue, waterproofing agent emulsified wax is equal by surface layer glue system and surface layer wood shavings Even stirring;Sandwich layer addition manner is to dig aqueous polyamide, PMDI, waterproofing agent melt paraffin by sandwich layer glue system and sandwich layer Flower uniform stirring.
3. the production technology of particleboard with zero-formaldehyde emission according to claim 1, it is characterised in that: in the glue compounding and applying step, table Resin added of the layer without aldehyde soybean glue is the 11-14% of over dry surface layer wood shavings quality, waterproofing agent emulsified wax additive amount is over dry table The 0.5% of layer wood shavings quality;Sandwich layer the aqueous polyamide 5-8% relative to over dry sandwich layer wood shavings quality, PMDI 3-5kg/m3, prevent Aqua melt paraffin additive amount relative to over dry sandwich layer wood shavings quality 0.5%.
4. the production technology of particleboard with zero-formaldehyde emission according to claim 1, it is characterised in that: in the glue compounding and applying step, nothing The component of aldehyde soybean glue is by mass percentage: the soy meal of 25-40%, the dispersing agent of 3-10%, 0.5% antibacterial mildew inhibitor and Excess water.
5. the production technology of particleboard with zero-formaldehyde emission according to claim 4, it is characterised in that: the soy meal was 200- 300 mesh, powdery.
6. the production technology of particleboard with zero-formaldehyde emission according to claim 4, it is characterised in that: the dispersing agent is purchased from Guangzhou Xu Xiang Chemical Co., Ltd., model NN0-B.
7. the production technology of particleboard with zero-formaldehyde emission according to claim 4, it is characterised in that: the antibacterial mildew inhibitor is purchased from south Lead to vast biochemical Co., Ltd, model Xin Ke -01C.
CN201811132022.8A 2018-09-27 2018-09-27 A kind of production technology of particleboard with zero-formaldehyde emission Pending CN109129791A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110014494A (en) * 2019-04-15 2019-07-16 安徽百祺瑞建材科技有限公司 A kind of fire-proof doors and windows combo box plate and its synthetic method
CN110434954A (en) * 2019-08-31 2019-11-12 广东始兴县华洲木业有限公司 A kind of preparation process of zero formaldehyde light granules plate
CN110480784A (en) * 2019-08-11 2019-11-22 广东始兴县华洲木业有限公司 A kind of preparation process of zero formaldehyde log particle board
CN110509386A (en) * 2019-08-11 2019-11-29 广东始兴县华洲木业有限公司 A kind of preparation process of zero formaldehyde moisture-proof granule plate
CN110900775A (en) * 2019-12-18 2020-03-24 南宁科天水性科技有限责任公司 Composite plywood and manufacturing method thereof
CN110978200A (en) * 2019-12-19 2020-04-10 南宁科天水性科技有限责任公司 Composite block board and manufacturing method thereof
CN111002425A (en) * 2019-12-18 2020-04-14 南宁科天水性科技有限责任公司 Wood shaving composite facing ecological board and manufacturing method thereof
CN111571758A (en) * 2020-06-12 2020-08-25 鸿伟木业(仁化)有限公司 Production process of moisture-proof super E0 bamboo chip shaving board

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110014494A (en) * 2019-04-15 2019-07-16 安徽百祺瑞建材科技有限公司 A kind of fire-proof doors and windows combo box plate and its synthetic method
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CN110509386A (en) * 2019-08-11 2019-11-29 广东始兴县华洲木业有限公司 A kind of preparation process of zero formaldehyde moisture-proof granule plate
CN110434954A (en) * 2019-08-31 2019-11-12 广东始兴县华洲木业有限公司 A kind of preparation process of zero formaldehyde light granules plate
CN110900775A (en) * 2019-12-18 2020-03-24 南宁科天水性科技有限责任公司 Composite plywood and manufacturing method thereof
CN111002425A (en) * 2019-12-18 2020-04-14 南宁科天水性科技有限责任公司 Wood shaving composite facing ecological board and manufacturing method thereof
CN110978200A (en) * 2019-12-19 2020-04-10 南宁科天水性科技有限责任公司 Composite block board and manufacturing method thereof
CN111571758A (en) * 2020-06-12 2020-08-25 鸿伟木业(仁化)有限公司 Production process of moisture-proof super E0 bamboo chip shaving board
CN111571758B (en) * 2020-06-12 2021-04-16 鸿伟木业(仁化)有限公司 Production process of moisture-proof super E0 bamboo chip shaving board

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