CN109112892A - A kind of degradable environment-friendly type internal lining paper - Google Patents
A kind of degradable environment-friendly type internal lining paper Download PDFInfo
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- CN109112892A CN109112892A CN201811164044.2A CN201811164044A CN109112892A CN 109112892 A CN109112892 A CN 109112892A CN 201811164044 A CN201811164044 A CN 201811164044A CN 109112892 A CN109112892 A CN 109112892A
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
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- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of degradable environment-friendly type internal lining paper provided by the invention is additionally provided with crystallite wax coating including original paper layer, the barrier layer that is covered in original paper layer upper surface, the chitosan coat for being covered in original paper layer lower surface between the original paper layer and barrier layer.The present invention also provides the preparation methods of above-mentioned degradable environment-friendly type internal lining paper.The internal lining paper is mainly made by natural material, it is degradable, it not can cause environmental pollution, it joined the materials such as Eucalyptus, nano silver in body paper simultaneously, has the effect of antibacterial, ensure that the cleaning of cigarette, while joined the thicker stalk of fiber and silica, calcium silicates, zeolite powder etc., there is preferable waterproof effect.
Description
Technical field
The present invention relates to cigarette material field, in particular to a kind of degradable environment-friendly type internal lining paper.
Background technique
Cigarette lining paper belongs to one of cigarette auxiliary material, and cigarette lining paper is to be packaged in Cigarette and cigarette packet is small
Paper between box, main function is mainly moisture-proof, anti-mildew, keeps cigarette fragrance, is essential in cigarette package
Auxiliary material.
Existing cigarette lining paper classification substantially has following several:
Common printed type internal lining paper: be by aluminium foil and lining paper it is compound after, simply printed in aluminium foil surface, technique letter
Single appearance kind tone is single.And have aluminium foil participation, not environmentally.
Common transfevent internal lining paper: it is direct and lining paper is compound with vacuum aluminum-coated transfer membrane, it is printed after removing, this printing technology
Same color is single but compound instead of traditional aluminium foil, under the premise of not losing metallic luster, equally also reduces cost,
And environmental protection, but cigarette fragrance protectiveness can be poor, is also more commonly used cigarette packaging paper currently on the market.
Radium-shine transfer internal lining paper: compound by internal lining paper and the radium-shine vacuum aluminum-coated transfer membrane of PET, OPP, this mode is being removed
After have laser effect, lucuriant in design after printing, excellent.But cigarette fragrance protectiveness can be same poor.This product is mostly
Higher gears cigarette packet uses, higher cost.
The first tobacco lining paper simple production process and maturation, the market competitiveness is weak, not high added value.And not ring
It protects, but there is splendid fragrance protectiveness due to there is the participation of aluminium foil compound.Relative to the first, second of tobacco lining paper replaces
Traditional aluminium foil is compound, and technique improves to some extent, but will appear that cigarette wrap molding is poor, flue gas distributes comparatively fast in producing, and falls aluminium
Etc. various bad phenomenons, product appearance is influenced.Relative to first two product, though the third tobacco lining paper added value is high,
Market demand is little, and it is a kind of wasting of resources that packaging is also excessively luxurious, simultaneously because flue gas distributes also very fast without aluminium foil.
Summary of the invention
Technical problem: in order to solve the defects of prior art, the present invention provides a kind of degradable environment-friendly type internal lining papers.
Technical solution: a kind of degradable environment-friendly type internal lining paper provided by the invention, including original paper layer, be covered on original paper layer
The barrier layer on surface, the chitosan coat for being covered in original paper layer lower surface are additionally provided with crystallite between the original paper layer and barrier layer
Wax coating；The original paper layer is at least made of the components of following parts: 40-60 parts of stalk, 20-50 parts of Eucalyptus, bamboo 10-20
Part, 2-4 parts of zeolite powder, 1-3 parts of calcium silicates, 1-3 parts of bentonite, 1-3 parts of peppermint, 1-3 parts of folium artemisiae argyi, 4-6 parts of seaweed glue, agar 4-
6 parts, 4-6 parts of nano silica, 1-3 parts of nano silver, 1-3 parts of aloe extract, 2-4 parts of licorice, capejasmine extract
1-3 parts, 1-3 parts of Herba Lophatheri extract.
The barrier layer is film layer made of biodegradable material, and the film layer that the biodegradable material is constituted is poly-
Lactic acid film layer, starch base film layer, poly butylene succinate film layer, polyhydroxyalkanoates film layer, pla-pcl film layer, titanium dioxide
One of carbon copolymer aliphatic acid ester carbonate film layer, aliphatic-aromatic copolyester film layer.
The original paper layer is at least made of the components of following parts: 50 parts of stalk, 35 parts of Eucalyptus, 15 parts of bamboo, zeolite
3 parts of powder, 2 parts of calcium silicates, 2 parts of bentonite, 2 parts of peppermint, 2 parts of folium artemisiae argyi, 5 parts of seaweed glue, 5 parts of agar, 5 parts of nano silica,
2 parts of nano silver, 2 parts of aloe extract, 3 parts of licorice, 2 parts of capejasmine extract, 2 parts of Herba Lophatheri extract.
The present invention also provides the preparation methods of above-mentioned degradable environment-friendly type internal lining paper, comprising the following steps:
(1) preparation of body paper:
(1.1) water that stalk, Eucalyptus, bamboo, peppermint, folium artemisiae argyi are added 2-3 times is decocted, is filtered, filtrate is stand-by；It takes
It is soaking with sodium hydroxide 8 hours of 1% that the concentration of 16 times of parts by weight, which is added, in filter residue, is heated to boiling, small fire boiling 2 hours, so
Washing insoluble matter is to colourless afterwards, then the aqueous sodium carbonate that the hydrochloric acid and concentration for being 5% with concentration are 4% washs repeatedly, until
The pH value of insoluble matter is 7 ± 0.2, dries insoluble matter then to get plant fiber；
(1.2) plant fiber, peppermint, folium artemisiae argyi are put into the broken machine size degradation of waterpower, then are made machine, play concentration control in 3.5-
4.5%, slurry is made in 66~740SR in beating degree；
(1.3) zeolite powder, calcium silicates, bentonite are uniformly mixed, are ground into 40-60 mesh powder, add seaweed glue,
Agar stirs evenly, and dries to obtain mixture；
(1.4) it adds mixture into material, adds nano silica, nano silver, aloe extract, Radix Glycyrrhizae and extract
Object, capejasmine extract, Herba Lophatheri extract, stir evenly, and filtrate and suitable water in step (2.1) is added and is adjusted to solid content
For 2.6-3.5%, it is heated to 65-72 DEG C, by the material mixed up through wet end and press section drainage and formation, l Water Paper page enters preceding dry rank
Section；
(1.5) suction dehydration is carried out to l Water Paper after molding under the vacuum condition of 0.05-0.08Mpa, then electric heating drum
Dry 5-6min is air-dried, carries out press polish on ray machine finally to get body paper；
(2) crystallite wax coating, drying are coated in body paper upper surface；Barrier layer is coated in crystallite wax coating upper surface again, is dried
It is dry；Again body paper lower surface coating chitosan coat to get.
The utility model has the advantages that internal lining paper provided by the invention is mainly made by natural material, and it is degradable, dirt will not be caused to environment
Dye, while joined the materials such as Eucalyptus, nano silver in body paper, have the effect of antibacterial, ensure that the cleaning of cigarette, adds simultaneously
The thicker stalk of fiber and silica, calcium silicates, zeolite powder etc. are entered, there is preferable waterproof effect.
It is equipped with chitosan coat on body paper surface, mainly uses high density chitosan, chitosan is that a kind of natural biological is high
Bioactive molecule can enhance the immunity of human body, have the function of adjuvant treatment to some diseases, while chitosan is with good
Moisture retention, film forming, biocidal property and good mechanical strength, additionally it is possible to which tar adsorption, nicotine play moist-keeping flavouring, improve and inhale
The effect of taste.
It is equipped with crystallite wax coating on body paper surface, any solvent is free of using microwax, it is pollution-free, it is nuisanceless, and it is solid
It is fast to change speed, operating characteristics is high, as long as heat seeling coating, cooling can play adhesive property, and there is no VOC to remain.
Specific embodiment
The present invention is further illustrated below.
In the present invention:
Aloe extract, licorice, capejasmine extract, Herba Lophatheri extract the preparation method comprises the following steps: by aloe, sweet
Grass, cape jasmine or lophatherum gracile are placed in water, and are heated to 80-85 DEG C, extract 1h；In triplicate；Extracting solution be evaporated to get.It is aloe, sweet
The amount ratio of grass, cape jasmine or lophatherum gracile and water is 5kg:25L.
Embodiment 1
Degradable environment-friendly type internal lining paper including original paper layer, the barrier layer that is covered in original paper layer upper surface, is covered in original paper layer
The chitosan coat of lower surface is additionally provided with crystallite wax coating between the original paper layer and barrier layer；The original paper layer at least by with
The component of lower parts by weight is made: 40 parts of stalk, 50 parts of Eucalyptus, 10 parts of bamboo, 2 parts of zeolite powder, 3 parts of calcium silicates, 1 part of bentonite,
It is 3 parts of peppermint, 1 part of folium artemisiae argyi, 6 parts of seaweed glue, 4 parts of agar, 6 parts of nano silica, 1 part of nano silver, 3 parts of aloe extract, sweet
2 parts of careless extract, 3 parts of capejasmine extract, 1 part of Herba Lophatheri extract.
The barrier layer is film layer made of biodegradable material, and the film layer that the biodegradable material is constituted is poly-
Lactic acid film layer.
The preparation method of above-mentioned degradable environment-friendly type internal lining paper, comprising the following steps:
(1) preparation of body paper:
(1.1) water that stalk, Eucalyptus, bamboo, peppermint, folium artemisiae argyi are added 2-3 times is decocted, is filtered, filtrate is stand-by；It takes
It is soaking with sodium hydroxide 8 hours of 1% that the concentration of 16 times of parts by weight, which is added, in filter residue, is heated to boiling, small fire boiling 2 hours, so
Washing insoluble matter is to colourless afterwards, then the aqueous sodium carbonate that the hydrochloric acid and concentration for being 5% with concentration are 4% washs repeatedly, until
The pH value of insoluble matter is 7 ± 0.2, dries insoluble matter then to get plant fiber；
(1.2) plant fiber, peppermint, folium artemisiae argyi are put into the broken machine size degradation of waterpower, then are made machine, play concentration control in 3.5-
4.5%, slurry is made in 66~740SR in beating degree；
(1.3) zeolite powder, calcium silicates, bentonite are uniformly mixed, are ground into 40-60 mesh powder, add seaweed glue,
Agar stirs evenly, and dries to obtain mixture；
(1.4) it adds mixture into material, adds nano silica, nano silver, aloe extract, Radix Glycyrrhizae and extract
Object, capejasmine extract, Herba Lophatheri extract, stir evenly, and filtrate and suitable water in step (2.1) is added and is adjusted to solid content
For 2.6-3.5%, it is heated to 65-72 DEG C, by the material mixed up through wet end and press section drainage and formation, l Water Paper page enters preceding dry rank
Section；
(1.5) suction dehydration is carried out to l Water Paper after molding under the vacuum condition of 0.05-0.08Mpa, then electric heating drum
Dry 5-6min is air-dried, carries out press polish on ray machine finally to get body paper；
(2) crystallite wax coating, drying are coated in body paper upper surface；Barrier layer is coated in crystallite wax coating upper surface again, is dried
It is dry；Again body paper lower surface coating chitosan coat to get.
Embodiment 2
Degradable environment-friendly type internal lining paper including original paper layer, the barrier layer that is covered in original paper layer upper surface, is covered in original paper layer
The chitosan coat of lower surface is additionally provided with crystallite wax coating between the original paper layer and barrier layer；The original paper layer at least by with
The component of lower parts by weight is made: 60 parts of stalk, 20 parts of Eucalyptus, 20 parts of bamboo, 4 parts of zeolite powder, 1 part of calcium silicates, 3 parts of bentonite,
It is 1 part of peppermint, 3 parts of folium artemisiae argyi, 4 parts of seaweed glue, 6 parts of agar, 4 parts of nano silica, 3 parts of nano silver, 1 part of aloe extract, sweet
4 parts of careless extract, 1 part of capejasmine extract, 3 parts of Herba Lophatheri extract.
The barrier layer is film layer made of biodegradable material, and the film layer that the biodegradable material is constituted is to form sediment
Powder base membrane layer.
Preparation method is the same as embodiment 1.
Embodiment 3
Degradable environment-friendly type internal lining paper including original paper layer, the barrier layer that is covered in original paper layer upper surface, is covered in original paper layer
The chitosan coat of lower surface is additionally provided with crystallite wax coating between the original paper layer and barrier layer；The original paper layer at least by with
The component of lower parts by weight is made: 50 parts of stalk, 35 parts of Eucalyptus, 15 parts of bamboo, 3 parts of zeolite powder, 2 parts of calcium silicates, 2 parts of bentonite,
It is 2 parts of peppermint, 2 parts of folium artemisiae argyi, 5 parts of seaweed glue, 5 parts of agar, 5 parts of nano silica, 2 parts of nano silver, 2 parts of aloe extract, sweet
3 parts of careless extract, 2 parts of capejasmine extract, 2 parts of Herba Lophatheri extract.
The barrier layer is film layer made of biodegradable material, and the film layer that the biodegradable material is constituted is poly-
Succinic acid-butanediol ester film layer.
Preparation method is the same as embodiment 1.
Test its performance:
Claims (4)
1. a kind of degradable environment-friendly type internal lining paper, it is characterised in that: including original paper layer, be covered in the barrier of original paper layer upper surface
Layer, the chitosan coat for being covered in original paper layer lower surface, are additionally provided with crystallite wax coating between the original paper layer and barrier layer；It is described
Original paper layer is at least made of the components of following parts: 40-60 parts of stalk, 20-50 parts of Eucalyptus, 10-20 parts of bamboo, zeolite powder 2-
4 parts, 1-3 parts of calcium silicates, 1-3 parts of bentonite, 1-3 parts of peppermint, 1-3 parts of folium artemisiae argyi, 4-6 parts of seaweed glue, 4-6 parts of agar, nanometer two
4-6 parts of silica, 1-3 parts of nano silver, 1-3 parts of aloe extract, 2-4 parts of licorice, 1-3 parts of capejasmine extract, henon bamboo
1-3 parts of leaf extract.
2. a kind of degradable environment-friendly type internal lining paper according to claim 1, it is characterised in that: the barrier layer is that biology can
Film layer made of degradable material, the film layer that the biodegradable material is constituted are polylactic acid film layer, starch base film layer, polybutadiene
Sour butanediol ester film layer, polyhydroxyalkanoates film layer, pla-pcl film layer, carbon dioxide copolymer aliphatic acid ester carbonate film layer,
One of aliphatic-aromatic copolyester film layer.
3. a kind of degradable environment-friendly type internal lining paper according to claim 1, it is characterised in that: the original paper layer at least by with
The component of lower parts by weight is made: 50 parts of stalk, 35 parts of Eucalyptus, 15 parts of bamboo, 3 parts of zeolite powder, 2 parts of calcium silicates, 2 parts of bentonite,
It is 2 parts of peppermint, 2 parts of folium artemisiae argyi, 5 parts of seaweed glue, 5 parts of agar, 5 parts of nano silica, 2 parts of nano silver, 2 parts of aloe extract, sweet
3 parts of careless extract, 2 parts of capejasmine extract, 2 parts of Herba Lophatheri extract.
4. a kind of preparation method of degradable environment-friendly type internal lining paper described in claim 1, it is characterised in that: including following step
It is rapid:
(1) preparation of body paper:
(1.1) water that stalk, Eucalyptus, bamboo, peppermint, folium artemisiae argyi are added 2-3 times is decocted, is filtered, filtrate is stand-by；Take filter residue
The concentration that 16 times of parts by weight are added is soaking with sodium hydroxide 8 hours of 1%, is heated to boiling, small fire boiling 2 hours, then water
Insoluble matter is washed to colourless, then the aqueous sodium carbonate that the hydrochloric acid and concentration for being 5% with concentration are 4% washs repeatedly, until insoluble
The pH value of object is 7 ± 0.2, dries insoluble matter then to get plant fiber；
(1.2) plant fiber, peppermint, folium artemisiae argyi are put into the broken machine size degradation of waterpower, then are made machine, beaten concentration and control in 3.5-4.5%,
Slurry is made in 66~740SR in beating degree；
(1.3) zeolite powder, calcium silicates, bentonite are uniformly mixed, are ground into 40-60 mesh powder, add seaweed glue, fine jade
Rouge stirs evenly, and dries to obtain mixture；
(1.4) it adds mixture into material, adds nano silica, nano silver, aloe extract, licorice, Cape jasmine
Seed extract, Herba Lophatheri extract, stir evenly, and filtrate and suitable water in step (2.1) is added is adjusted to solid content and be
2.6-3.5% is heated to 65-72 DEG C, and by the material mixed up through wet end and press section drainage and formation, l Water Paper page enters the preceding dry stage；
(1.5) suction dehydration is carried out to l Water Paper after molding under the vacuum condition of 0.05-0.08Mpa, then electric heating air blast is dry
Dry 5-6min carries out press polish on ray machine finally to get body paper；
(2) crystallite wax coating, drying are coated in body paper upper surface；Barrier layer, drying are coated in crystallite wax coating upper surface again；Again
Body paper lower surface coating chitosan coat to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811164044.2A CN109112892A (en) | 2018-10-04 | 2018-10-04 | A kind of degradable environment-friendly type internal lining paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811164044.2A CN109112892A (en) | 2018-10-04 | 2018-10-04 | A kind of degradable environment-friendly type internal lining paper |
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| CN109112892A true CN109112892A (en) | 2019-01-01 |
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ID=64857304
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| CN201811164044.2A Pending CN109112892A (en) | 2018-10-04 | 2018-10-04 | A kind of degradable environment-friendly type internal lining paper |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111576091A (en) * | 2020-05-21 | 2020-08-25 | 安徽顺彤包装材料有限公司 | Degradable cigarette packaging paper and preparation method thereof |
| CN113881106A (en) * | 2021-11-17 | 2022-01-04 | 广州市欣竹不干胶材料有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
| CN114411448A (en) * | 2022-01-21 | 2022-04-29 | 上海烟草集团有限责任公司 | Base paper containing tobacco lining and preparation method thereof |
| US11401661B2 (en) | 2017-11-14 | 2022-08-02 | J & J Green Paper, Inc. | Recyclable composition for waterproofing paper utilizing a plant derived wax, pellets of the composition, recyclable waterproof paper laminate including the composition, recyclable hot beverage cup including the laminate, pod for making hot beverages including the laminate, and drinking straw including the laminate |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11401661B2 (en) | 2017-11-14 | 2022-08-02 | J & J Green Paper, Inc. | Recyclable composition for waterproofing paper utilizing a plant derived wax, pellets of the composition, recyclable waterproof paper laminate including the composition, recyclable hot beverage cup including the laminate, pod for making hot beverages including the laminate, and drinking straw including the laminate |
| CN111576091A (en) * | 2020-05-21 | 2020-08-25 | 安徽顺彤包装材料有限公司 | Degradable cigarette packaging paper and preparation method thereof |
| CN113881106A (en) * | 2021-11-17 | 2022-01-04 | 广州市欣竹不干胶材料有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
| CN114411448A (en) * | 2022-01-21 | 2022-04-29 | 上海烟草集团有限责任公司 | Base paper containing tobacco lining and preparation method thereof |
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