CN109111866A - Modified flexible waterproof sheet of ageing-resistant pvc and preparation method thereof - Google Patents
Modified flexible waterproof sheet of ageing-resistant pvc and preparation method thereof Download PDFInfo
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- CN109111866A CN109111866A CN201810564312.3A CN201810564312A CN109111866A CN 109111866 A CN109111866 A CN 109111866A CN 201810564312 A CN201810564312 A CN 201810564312A CN 109111866 A CN109111866 A CN 109111866A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2427/00—Presence of halogenated polymer
- C09J2427/006—Presence of halogenated polymer in the substrate
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention belongs to waterproof roll technical fields, and in particular to a kind of modified flexible waterproof sheet of ageing-resistant pvc and preparation method thereof.The material includes self-adhesion glue film and the waterproof roll layer that is arranged on the self-adhesion glue film, and the waterproof roll layer includes each component of following parts by weight: 4~6 parts of anion SBR latex, 6~7 parts of anion polychloroprene latex, 30~50 parts of Corvic, 5~10 parts of polyethylene, 20~30 parts of powdered whiting, 20~25 parts of wollastonite, 3~7 parts of barium sulfate, 0.5~1 part of hydrophobing agent, 0.5~1 part of smoke suppressant and 1~2 part of stabilizer.The modified flexible waterproof sheet waterproof performance of ageing-resistant pvc provided by the present invention is good, and ageing-resistant performance is strong.Use temperature range is wide, can be widely applied to the water-proof repairings such as industry, civil building roof covering, roof garden, gutter, rain cover.
Description
Technical field
The invention belongs to waterproof roll technical fields, and in particular to a kind of modified flexible waterproof sheet of ageing-resistant pvc and its
Preparation method.
Background technique
Polymer membranes is to introduce a kind of new waterproof to grow up the later period nineties by developed countries to roll up
Material provides excellent percolation-proof effect to building trade；After 2009 the domestic exploitation for having started polymer membranes and
Using, and be widely popularized quickly, but be modified pitch, low temperature used in waterproof roll majority currently on the market
Shi Yi be hardened embrittlement, high temperature when can trickle, be irradiated intolerant to sunlight, and volatile quantity is big, not environmentally high carcinogenic.
Polyvinyl chloride is vinyl chloride monomer in initiators such as peroxide, azo-compounds, or by certainly under light, heat effect
The polymer being polymerized by base polymerization reaction mechanism.Polyvinyl chloride is poor to the stability of light and heat, at 100 DEG C or more or through length
Time exposure in sunshine will decompose and generate hydrogen chloride, and further autocatalysis is decomposed, and causes to change colour, physical mechanical property
Also decline rapidly, must be added to stabilizer in practical applications to improve the stability to light and heat.
Polyester fiber internal-reinforced PVC waterproof roll material is a kind of thermoplastic PVC roll material, which is with polyester
Fabric makes the poly- of two-sided the polyvinyl chloride plastic bed of material and centre by special extrusion coating methods technique as reinforcing rib
Ester reinforcing rib is combined into one and the macromolecule coiled material that is formed.It is formulated the poly- of the advanced polyvinyl chloride plastic bed of material and reticular structure
Ester fiber fabric combines, and coiled material is made to possess splendid dimensional stability and lower thermal expansion coefficient, and it is directly sudden and violent to promote coiled material
The long-term behaviour of dew in the natural environment.
Summary of the invention
To solve the deficiencies in the prior art, the present invention provides a kind of modified flexible waterproof sheets of ageing-resistant pvc.The present invention
The modified flexible waterproof sheet of provided ageing-resistant pvc have the characteristics that it is ageing-resistant, with good tensile strength and elongation
Rate, shrinking percentage is big, and low temperature flexibility is good, easy for construction.
Technical solution provided by the present invention is as follows:
A kind of modified flexible waterproof sheet of ageing-resistant pvc including self-adhesion glue film and is arranged in anti-on the self-adhesion glue film
Water coiled material layer, the waterproof roll layer include each component of following parts by weight: 4~6 parts of anion SBR latex, 6~7 parts
Anion polychloroprene latex, 30~50 parts of Corvic, 5~10 parts of polyethylene, 20~30 parts of powdered whiting, 20
~25 parts of wollastonite, 3~7 parts of barium sulfate, 0.5~1 part of hydrophobing agent, 0.5~1 part of smoke suppressant and 1~2 part of stabilization
Agent.
The modified flexible waterproof sheet of ageing-resistant pvc provided by the present invention have the characteristics that it is ageing-resistant, with good
Tensile strength and elongation, shrinking percentage is big, and low temperature flexibility is good, easy for construction.
Specifically, the hydrophobing agent is wax emulsion.
Based on the above-mentioned technical proposal, wax emulsion energy material provides excellent hydrophobicity.
Specifically, the smoke suppressant is expansible graphite or SBS.
Based on the above-mentioned technical proposal, expansible graphite or SBS can provide excellent smoke suppressing for material.
Specifically, the stabilizer is the mixture of nano zine oxide, benzophenone and benzotriazole.Preferably 1:1:
1。
Based on the above-mentioned technical proposal, excellent stability can be provided for material.
The present invention also provides a kind of preparation methods of the modified flexible waterproof sheet of ageing-resistant pvc, comprising the following steps:
1) in parts by weight, by 4~6 parts of anion SBR latex, 6~7 parts of anion polychloroprene latex, 30~50
The Corvic, 5~10 parts of polyethylene of part are put into blender, after being uniformly mixed, are heated to 100~120 DEG C,
Heat 20~30min；
2) by 20~30 parts of powdered whiting, 20~25 parts of wollastonite, 3~7 parts of barium sulfate, 0.5~1 part dredge
75~80 DEG C are heated to after aqua, 0.5~1 part of smoke suppressant and 1~2 part of stabilizer mixing, is carried out after mixing by colloid mill
Emulsification, heating temperature is to 120~150 DEG C after emulsification；
3) material is put into extrusion sheet in screw extruder after being cooled to 70~90 DEG C, obtains waterproof roll layer, in institute
Attachment self-adhesion glue film on waterproof roll layer is stated, the modified flexible waterproof sheet of ageing-resistant pvc is obtained.
The modified flexible waterproof sheet of the ageing-resistant pvc that can be prepared through the above technical solution has ageing-resistant spy
Point, with good tensile strength and elongation, shrinking percentage is big, and low temperature flexibility is good, easy for construction.
The modified flexible waterproof sheet waterproof performance of ageing-resistant pvc provided by the present invention is good, and ageing-resistant performance is strong.It uses
Wide temperature range, at 1~15 DEG C can uncoiling construction, in 90 DEG C of fricton-tight and bubbles, corrosion resistance is good.It can be widely applied
In water-proof repairings such as industry, civil building roof covering, roof garden, gutter, rain covers；Construction joint, sedimentation locust, expansion joint, drain gully
Etc. waterproofs；The waterproofs such as underground indoor and outdoor wall, ground, elevator pit；The waterproofs such as kitchen, bathroom, toilet, pond, swimming pool；Metal
The anti-corrosions such as pipeline, fat corruption terrace, anti-corrosion pond.
Specific embodiment
The principles and features of the present invention are described below, and illustrated embodiment is served only for explaining the present invention, is not intended to
It limits the scope of the invention.
Embodiment 1
It is prepared according to the following steps:
1) in parts by weight, by 5 parts of anion SBR latex, 6 parts of anion polychloroprene latex, 40 parts of polychlorostyrene second
Olefine resin, is put into blender 8 parts of polyethylene, after being uniformly mixed, is heated to 110 DEG C, is heated 25min；
2) by 25 parts of powdered whiting, 22 parts of wollastonite, 5 parts of barium sulfate, 0.8 part of hydrophobing agent, 0.8 part of suppression
78 DEG C are heated to after fumicants and the mixing of 1.5 parts of stabilizers, is emulsified after mixing by colloid mill, heating temperature is extremely after emulsification
135℃；
3) material is put into extrusion sheet in screw extruder after being cooled to 80 DEG C, self-adhesion glue film is adhered on sheet material, is obtained
To the modified flexible waterproof sheet 1 of ageing-resistant pvc.
Wherein, hydrophobing agent is wax emulsion.Smoke suppressant is expansible graphite.Stabilizer be nano zine oxide, benzophenone and
The mixture of benzotriazole.
Embodiment 2
It is prepared according to the following steps:
1) in parts by weight, by 6 parts of anion SBR latex, 6 parts of anion polychloroprene latex, 50 parts of polychlorostyrene second
Olefine resin, is put into blender 5 parts of polyethylene, after being uniformly mixed, is heated to 120 DEG C, is heated 20min；
2) by 30 parts of powdered whiting, 20 parts of wollastonite, 7 parts of barium sulfate, 0.5 part of hydrophobing agent, 0.5 part of suppression
75 DEG C are heated to after fumicants and the mixing of 2 parts of stabilizers, is emulsified after mixing by colloid mill, heating temperature is to 150 after emulsification
℃；
3) material is put into extrusion sheet in screw extruder after being cooled to 70 DEG C, self-adhesion glue film is adhered on sheet material, is obtained
To the modified flexible waterproof sheet 2 of ageing-resistant pvc.
Wherein, hydrophobing agent is wax emulsion.Smoke suppressant is SBS.Stabilizer is nano zine oxide, benzophenone and benzotriazole
Mixture.
Embodiment 3
It is prepared according to the following steps:
1) in parts by weight, by 4 parts of anion SBR latex, 7 parts of anion polychloroprene latex, 30 parts of polychlorostyrene second
Olefine resin, is put into blender 10 parts of polyethylene, after being uniformly mixed, is heated to 100 DEG C, is heated 30min；
2) by 20 parts of powdered whiting, 25 parts of wollastonite, 3 parts of barium sulfate, 1 part of hydrophobing agent, 1 part of smoke suppressant
80 DEG C are heated to after mixing with 1 part of stabilizer, is emulsified after mixing by colloid mill, heating temperature is to 120 DEG C after emulsification；
3) material is put into extrusion sheet in screw extruder after being cooled to 90 DEG C, self-adhesion glue film is adhered on sheet material, is obtained
To the modified flexible waterproof sheet 3 of ageing-resistant pvc.
Wherein, hydrophobing agent is wax emulsion.Smoke suppressant is expansible graphite.Stabilizer be nano zine oxide, benzophenone and
The mixture of benzotriazole.
Comparative example 1
1) in parts by weight, by 40 parts of Corvic, 8 parts of polyethylene, be put into blender, be stirred
After uniformly, 110 DEG C are heated to, heats 25min；
2) by 25 parts of powdered whiting, 22 parts of wollastonite, 5 parts of barium sulfate, 0.8 part of hydrophobing agent, 0.8 part of profit
78 DEG C are heated to after humectant, 0.8 part of smoke suppressant, 0.8 part of defoaming agent, 0.8 part of dispersing agent and 1.5 parts of stabilizer mixing,
It is emulsified after mixing by colloid mill, heating temperature is to 135 DEG C after emulsification；
3) material is put into extrusion sheet in screw extruder after being cooled to 80 DEG C, self-adhesion glue film is adhered on sheet material, is obtained
To the modified flexible waterproof sheet 4 of ageing-resistant pvc.
Wherein, hydrophobing agent is wax emulsion.Smoke suppressant is expansible graphite.Stabilizer be nano zine oxide, benzophenone and
The mixture of benzotriazole.
Performance test: to the radiation protection flame retardant type PVC polymer membranes progressive as made from 1-4 of the embodiment of the present invention
It can test.
Test result is as follows
To sum up, the embodiment of the present invention has the following beneficial effects: that each ageing-resistant pvc provided by the present invention is modified flexible anti-
Water coiled material have the characteristics that it is ageing-resistant, and have certain tensile strength and elongation, shrinking percentage of the present invention is big, low temperature flexibility
It is good, it is easy for construction；Compared with comparative example, there is lower tolerable temperature.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of modified flexible waterproof sheet of ageing-resistant pvc, including self-adhesion glue film and the waterproof being arranged on the self-adhesion glue film
Coiled material layer, which is characterized in that the waterproof roll layer includes each component of following parts by weight: 4~6 parts of anion SBR latex,
6~7 parts of anion polychloroprene latex, 30~50 parts of Corvic, 5~10 parts of polyethylene, 20~30 parts of heavy
Calcium carbonate, 20~25 parts of wollastonite, 3~7 parts of barium sulfate, 0.5~1 part of hydrophobing agent, 0.5~1 part of smoke suppressant and 1~
2 parts of stabilizers.
2. the modified flexible waterproof sheet of ageing-resistant pvc according to claim 1, it is characterised in that: the hydrophobing agent is
Wax emulsion.
3. the modified flexible waterproof sheet of ageing-resistant pvc according to claim 1, it is characterised in that: the smoke suppressant is can
Expanded graphite or SBS.
4. the modified flexible waterproof sheet of ageing-resistant pvc according to any one of claims 1 to 3, it is characterised in that: the stabilization
Agent is the mixture of nano zine oxide, benzophenone and benzotriazole.
5. a kind of preparation method of the modified flexible waterproof sheet of ageing-resistant pvc, which comprises the following steps:
1) in parts by weight, by 4~6 parts of anion SBR latex, 6~7 parts of anion polychloroprene latex, 30~50 parts
Corvic, 5~10 parts of polyethylene are put into blender, after being uniformly mixed, are heated to 100~120 DEG C, heating
20~30min；
2) by 20~30 parts of powdered whiting, 20~25 parts of wollastonite, 3~7 parts of barium sulfate, 0.5~1 part hydrophobic
75~80 DEG C are heated to after agent, 0.5~1 part of smoke suppressant and 1~2 part of stabilizer mixing, carries out cream by colloid mill after mixing
Change, heating temperature is to 120~150 DEG C after emulsification；
3) material is put into extrusion sheet in screw extruder after being cooled to 70~90 DEG C, obtains waterproof roll layer, described anti-
Adhere to self-adhesion glue film on water coiled material layer, obtains the modified flexible waterproof sheet of ageing-resistant pvc.
6. the preparation method of the modified flexible waterproof sheet of ageing-resistant pvc according to claim 5, it is characterised in that: described
Hydrophobing agent be wax emulsion.
7. the preparation method of the modified flexible waterproof sheet of ageing-resistant pvc according to claim 5, it is characterised in that: described
Smoke suppressant is expansible graphite or SBS.
8. according to the preparation method of the modified flexible waterproof sheet of any ageing-resistant pvc of claim 5 to 7, feature exists
In: the stabilizer is the mixture of nano zine oxide, benzophenone and benzotriazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810564312.3A CN109111866A (en) | 2018-06-04 | 2018-06-04 | Modified flexible waterproof sheet of ageing-resistant pvc and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810564312.3A CN109111866A (en) | 2018-06-04 | 2018-06-04 | Modified flexible waterproof sheet of ageing-resistant pvc and preparation method thereof |
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| CN109111866A true CN109111866A (en) | 2019-01-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810564312.3A Pending CN109111866A (en) | 2018-06-04 | 2018-06-04 | Modified flexible waterproof sheet of ageing-resistant pvc and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109849453A (en) * | 2019-02-21 | 2019-06-07 | 内蒙古大地云天化工有限公司 | SBS modified asphalt waterproof coiled material is preparing the purposes in erosion resistant coating |
| CN113897145A (en) * | 2021-10-12 | 2022-01-07 | 浙江沃弗建材科技有限公司 | Macromolecular self-adhesive film pre-laid waterproof roll and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN205853510U (en) * | 2016-04-28 | 2017-01-04 | 天津市鹏腾新型建筑材料有限公司 | A kind of self-adhesive waterproof web |
| CN107383410A (en) * | 2017-07-26 | 2017-11-24 | 浙江春明防水建材有限公司 | A kind of CAS applies volume waterproof composite material and preparation method thereof |
| CN107501785A (en) * | 2017-08-16 | 2017-12-22 | 合肥卓立雅工程材料科技有限公司 | A kind of radiation proof flame retardant type PVC polymer membranes and preparation method thereof |
-
2018
- 2018-06-04 CN CN201810564312.3A patent/CN109111866A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN205853510U (en) * | 2016-04-28 | 2017-01-04 | 天津市鹏腾新型建筑材料有限公司 | A kind of self-adhesive waterproof web |
| CN107383410A (en) * | 2017-07-26 | 2017-11-24 | 浙江春明防水建材有限公司 | A kind of CAS applies volume waterproof composite material and preparation method thereof |
| CN107501785A (en) * | 2017-08-16 | 2017-12-22 | 合肥卓立雅工程材料科技有限公司 | A kind of radiation proof flame retardant type PVC polymer membranes and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 孙仕伟 等: "不同抑烟剂对沥青混合料动态性能的", 《新型建筑材料》 * |
| 强涛涛: "《合成革化学品》", 31 July 2016, 中国轻工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109849453A (en) * | 2019-02-21 | 2019-06-07 | 内蒙古大地云天化工有限公司 | SBS modified asphalt waterproof coiled material is preparing the purposes in erosion resistant coating |
| CN113897145A (en) * | 2021-10-12 | 2022-01-07 | 浙江沃弗建材科技有限公司 | Macromolecular self-adhesive film pre-laid waterproof roll and preparation method thereof |
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