CN109103105A - Thin film transistor (TFT) and preparation method thereof, display device - Google Patents

Thin film transistor (TFT) and preparation method thereof, display device Download PDF

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Publication number
CN109103105A
CN109103105A CN201810837308.XA CN201810837308A CN109103105A CN 109103105 A CN109103105 A CN 109103105A CN 201810837308 A CN201810837308 A CN 201810837308A CN 109103105 A CN109103105 A CN 109103105A
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Prior art keywords
amorphous silicon
silicon layer
layer
tft
film transistor
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卓恩宗
杨凤云
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HKC Co Ltd
Chongqing HKC Optoelectronics Technology Co Ltd
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HKC Co Ltd
Chongqing HKC Optoelectronics Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742Thin film unipolar transistors
    • H01L29/6675Amorphous silicon or polysilicon transistors
    • H01L29/66765Lateral single gate single channel transistors with inverted structure, i.e. the channel layer is formed after the gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0684Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78651Silicon transistors
    • H01L29/7866Non-monocrystalline silicon transistors
    • H01L29/78663Amorphous silicon transistors
    • H01L29/78669Amorphous silicon transistors with inverted-type structure, e.g. with bottom gate

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Thin Film Transistor (AREA)

Abstract

The present invention relates to a kind of thin film transistor (TFT) and its manufacturing methods, display device, and wherein method includes: offer substrate;Grid is formed on the substrate;Gate insulating layer is formed on the substrate, and the gate insulating layer is made to cover the grid;Amorphous silicon layer is formed on the gate insulating layer;N+ type doped amorphous silicon layer is formed on the amorphous silicon layer;Wherein, the ratio of control doping gas and silicon source is 0.82~1.54 or 1.74~4.1;Source-drain electrode metal layer is formed on the N+ type doped amorphous silicon layer;And the source-drain electrode metal layer, the N+ type doped amorphous silicon layer and the amorphous silicon layer are performed etching, to obtain source electrode and drain electrode.The preparation method of above-mentioned thin film transistor (TFT) can be effectively improved the image retention problem using the display device of the thin film transistor (TFT).

Description

Thin film transistor (TFT) and preparation method thereof, display device
Technical field
The present invention relates to technical field of semiconductors, fill more particularly to a kind of thin film transistor (TFT) and preparation method thereof, display It sets.
Background technique
Traditional amorphous silicon film transistor (a-Si TFT) processing procedure generally use BCE (Back Channel Etching, Carry on the back channel etching) type structure.The infrastructure cost wants low compared to ES (Etching Stop, etch stopper) type structure and technique is simple It is single.But since Back Channel interface state is poor, the leakage current of TFT is larger, easily causes the image retention of display screen (Image Sticking, IS) problem.
Summary of the invention
Based on this, it is necessary to aiming at the problem that traditional thin film transistor (TFT) is easy to cause image retention to display device, mention For a kind of thin film transistor (TFT) and its manufacturing method, display device.
A kind of preparation method of thin film transistor (TFT), comprising:
Substrate is provided;
Grid is formed on the substrate;
Gate insulating layer is formed on the substrate, and the gate insulating layer is made to cover the grid;
Amorphous silicon layer is formed on the gate insulating layer;
N+ type doped amorphous silicon layer is formed on the amorphous silicon layer;Wherein, the ratio of control doping gas and silicon source is 0.82~1.54 or 1.74~4.1;
Source-drain electrode metal layer is formed on the N+ type doped amorphous silicon layer;And
The source-drain electrode metal layer, the N+ type doped amorphous silicon layer and the amorphous silicon layer are performed etching, to obtain Source electrode and drain electrode.
The preparation method of above-mentioned thin film transistor (TFT), when forming N+ type doped amorphous silicon layer by the way that gas and silicon source will be adulterated Ratio is controlled 0.82~1.54 or 1.74~4.1, it can be ensured that the thin film transistor (TFT) that is finally prepared is under light illumination Stability is preferable, has lesser leakage current, so as to be effectively improved the image for the display device for using the thin film transistor (TFT) Residue problem.
The ratio of the doping gas and silicon source is 0.82~1.23 or 2.46~4.1 in one of the embodiments,.
The ratio of the doping gas and silicon source is 2.46~2.79 or 3.28~4.1 in one of the embodiments,.
The doping gas is hydrogen phosphide in one of the embodiments, and the silicon source is silane.
It is described in the step of forming N+ type doped amorphous silicon layer on the amorphous silicon layer in one of the embodiments, Diluent gas can be passed through;The flow of the diluent gas be 24000 milliliters per minute~25000 milliliters per minute;The silicon source Flow be 6200 milliliters per minute~7200 milliliters per minute.
It is described in the step of forming N+ type doped amorphous silicon layer on the amorphous silicon layer in one of the embodiments, The N+ type doped amorphous silicon layer is formed on the amorphous silicon layer using plasma enhanced chemical vapor chemical deposition.
It is described to the source-drain electrode metal layer, the N+ type doped amorphous silicon layer and described in one of the embodiments, The step of amorphous silicon layer performs etching are as follows:
Mask plate is formed on the source-drain electrode metal layer;And
Use twice wet etching and twice dry etch process to the source-drain electrode metal by exposure mask of the mask plate Layer, the N+ type doped amorphous silicon layer and the amorphous silicon layer perform etching;Wherein, in second dry etching, control is penetrated Frequency source power is 2 kilowatts~5 kilowatts, and RF bias power is 7 kilowatts~3 kilowatts, and etch period is 35 seconds~50 seconds, channel region The layer semiconductor thickness of top is 400 angstroms~700 angstroms.
In one of the embodiments, in second dry etching, etching gas includes chlorine and sulfur hexafluoride, chlorine Ratio with sulfur hexafluoride is 1:20~1:50.
A kind of thin film transistor (TFT), comprising:
Substrate;
The grid being formed on the substrate;
It is formed on the substrate and covers the gate insulating layer of the grid;
The amorphous silicon layer being formed on the gate insulating layer;
The N+ type doped amorphous silicon layer being formed on the amorphous silicon layer;And
It is formed on the gate insulating layer and connects with the two sides of the amorphous silicon layer and the N+ type doped amorphous silicon layer The source electrode and drain electrode of touching;
Wherein, the N+ type doped amorphous silicon layer use ratio for 0.82~1.54 or 1.74~4.1 doping gas and Silane is prepared.
A kind of display device, including display panel, the array substrate in the display panel include such as previous embodiment institute The thin film transistor (TFT) stated.
Detailed description of the invention
Fig. 1 is the preparation method of the thin film transistor (TFT) in an embodiment;
Fig. 2 is the device architecture schematic diagram completed after step S120;
Fig. 3 is the device architecture schematic diagram completed after step S130;
Fig. 4 is the device architecture schematic diagram completed after step S140;
Fig. 5 is the device architecture schematic diagram completed after step S150;
Fig. 6 is the device architecture schematic diagram completed after step S160;
Fig. 7 is the device architecture schematic diagram completed after step S170;
Fig. 8 a is the flow chart of a specific embodiment of step S170;
Fig. 8 b is the flow chart of a specific embodiment of the step S720 in Fig. 8 a;
Fig. 9 is that deposition forms the structural schematic diagram after photoresist layer on source-drain electrode metal layer;
Figure 10 is the device architecture schematic diagram completed after step S710;
Figure 11 is the device architecture schematic diagram completed after step S722;
Figure 12 is the device architecture schematic diagram completed after step S724;
Figure 13 is the device architecture schematic diagram completed after step S726;
Figure 14 is the cut-off current of the thin film transistor (TFT) with different amorphous silicon residual thickness and homogeneity with voltage Change curve;
Figure 15 is that cut-off current size of the thin film transistor (TFT) under different voltages in different embodiments corresponds to table.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
In the description of the present invention, it is to be understood that, term " center ", " transverse direction ", "upper", "lower" "left", "right", The orientation or positional relationship of the instructions such as "vertical", "horizontal", "top", "bottom", "inner" and "outside" is side based on the figure Position or positional relationship, are merely for convenience of description of the present invention and simplification of the description, rather than the device or member of indication or suggestion meaning Part must have a particular orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.This Outside, term " first ", " second " etc. are used for description purposes only, and should not be understood as indicating or implying relative importance or hidden The quantity of indicated technical characteristic is indicated containing ground.The feature of " first ", " second " that limit as a result, can be expressed or imply Including one or more this feature.
In the present description and drawings, the reference marker N and P for distributing to layer or region indicate that these layers or region wrap respectively Include a large amount of electronics or hole.Further, the concentration of the reference marker+and-expression dopant of distributing to N or P is higher or lower than The concentration not being assigned in this way in the layer of label.In the description and attached drawing of preferred embodiment below, similar component point Equipped with omitting its redundant description at similar reference marker and this.
Fig. 1 is the flow chart of the preparation method of the thin film transistor (TFT) in an embodiment.Referring to Fig. 1, this method includes following Step:
Step S110, provides substrate.
Substrate can be prepared using the known material in this fields such as glass or plastics.In the present embodiment, with Prepared on substrate device side be it is upper, under opposite side is.
Step S120, forms grid on substrate.
Grid can be prepared using physical vapour deposition (PVD) (Physical Vapor Deposition, PVD) technique. In the present embodiment, grid can be prepared using magnetron sputtering technique.Specifically, the knot of flood is first deposited on substrate Then structure is patterned this layer of structure and required gate structure is finally prepared.The material of grid can be aluminium, copper The combination of one or more of equal conductive materials.Fig. 2 is the structural schematic diagram completed after step S120.In Fig. 2,910 tables Show substrate, 920 indicate grid.
Step S130, forms gate insulating layer on substrate, and gate insulating layer is made to cover grid.
Fig. 3 is the structural schematic diagram completed after step S130.The material of gate insulating layer 930 can be silica or nitrogen SiClx.The material of gate insulating layer 930 may be the combination of silica or silicon nitride.It is appreciated that gate insulating layer 930 It can also be prepared using the known material of other skilled in the art.Gate insulating layer 930 can be enhanced using plasma Chemical vapor deposition method (Plasma Enhanced Chemical Vapor Deposition, PECVD) successive sedimentation is formed.
Step S140, forms amorphous silicon layer on gate insulating layer.
Fig. 4 is the structural schematic diagram completed after step S140.Amorphous silicon (amorphous silicon, a-Si) is also known as nothing Shape silicon, is a kind of form of elemental silicon.Amorphous silicon does not have complete diamond structure cell, and purity is not high, but its fusing point, close Degree and hardness are significantly lower than crystalline silicon.Amorphous silicon layer (a-Si layers) 940 is used as active layer, can equally be enhanced using plasma Chemical vapor deposition method (Plasma Enhanced Chemical Vapor Deposition, PECVD) successive sedimentation is formed.
Step S150 forms N+ type doped amorphous silicon layer on amorphous silicon layer.
Fig. 5 is the structural schematic diagram completed after step S150.Wherein, N+ type doped amorphous silicon layer 950 is formed in amorphous silicon 940 top of layer.In the present embodiment, using plasma enhanced chemical vapor chemical deposition (Plasma Enhanced Chemical Vapor Deposition, PECVD) successive sedimentation forms N+ type doped amorphous silicon layer 940, and during the deposition process, controls The ratio for adulterating gas and silicon source is 0.82~1.54 or 1.74~4.1.Ratio by that will adulterate gas and silicon source controls 0.82~1.54 or 1.74~4.1, it can be ensured that finally formed thin film transistor (TFT) has preferable stability under light illumination.
In one embodiment, doping gas is hydrogen phosphide (PH3), silicon source is silane (SiH4).In the present embodiment, it is depositing In the process, it can be passed through diluent gas such as hydrogen (H simultaneously2), but for traditional processing procedure, it can't be to diluent gas And the flow of silicon source adjusts, and adjust the flow of doping gas only to reach the effect for the ratio for changing doping gas and silicon source Fruit.In one embodiment, control diluent gas flow be 24000 milliliters per minute~25000 milliliters per minute;Control silicon source Flow be 6200 milliliters per minute~7200 milliliters per minute.The N+ type doped amorphous silicon layer 950 and amorphous silicon layer 940 of formation The semiconductor layer of thin film transistor (TFT) is collectively formed.
Step S160 forms source-drain electrode metal layer on N+ type doped amorphous silicon layer.
Source-drain electrode metal layer can equally use physical vapour deposition (PVD) (Physical Vapor Deposition, PVD) work Skill is prepared.For example, source-drain electrode metal layer can be prepared using magnetron sputtering technique.Fig. 6 is after completing step S160 Device architecture schematic diagram.Source-drain electrode metal layer 970 can be prepared using conductive materials such as aluminium, copper and molybdenums.
Step S170 performs etching source-drain electrode metal layer, N+ type doped amorphous silicon layer and amorphous silicon layer, to obtain source electrode And drain electrode.
Thin film transistor (TFT) includes active area and passive region, and wherein passive region surrounds active area.It is thin for being arranged in active area The structures such as the source-drain electrode of film transistor.In etching process, the source above the passive region and channel region by thin film transistor (TFT) is needed Drain metal layer removal, and only retain the metal layer of source drain region.It is also desirable to by above the passive region of thin film transistor (TFT) Semiconductor layer removal, that is, by passive region N+ type doped amorphous silicon layer 950 and amorphous silicon layer 940 etch away.This Outside, it is also necessary to the N+ type doped amorphous silicon layer 950 above the channel region of thin film transistor (TFT) be etched completely, and to above channel region 940 part of amorphous silicon layer removal so that channel region above there are amorphous silicon residual thickness.
Fig. 7 is the structural schematic diagram completed after step S170.Wherein, 970 be source-drain electrode metal layer.In the present embodiment, Groove body is formed on N+ type doped amorphous silicon layer 2950 and amorphous silicon layer 940 to form thin film transistor (TFT) below present groove body Channel 960.Source S and drain D are separately positioned on the two sides of groove body.
The preparation method of above-mentioned thin film transistor (TFT), when forming N+ type doped amorphous silicon layer by the way that gas and silicon source will be adulterated Ratio is controlled 0.82~1.54 or 1.74~4.1, it can be ensured that the thin film transistor (TFT) that is finally prepared is under light illumination Stability is preferable, has lesser leakage current, so as to be effectively improved the image for the display device for using the thin film transistor (TFT) Residue problem.
In one embodiment, in step S150, during the deposition process, control doping gas and silicon source ratio be 0.82~ 1.23 or 2.46~4.1.In another embodiment, in step S150, during the deposition process, control doping gas and silicon source Ratio is 2.46~2.79 or 3.69~4.1.For example, during the deposition process, the ratio that can control doping gas and silicon source is 3.28 2.46.In other examples, the ratio that can control doping gas and silicon source is 2.79 or 3.69, another In embodiment, the ratio that can control doping gas and silicon source is 0.82 or 1.23.
For the beneficial effect that the thin film transistor (TFT) that the preparation method of above-mentioned thin film transistor (TFT) is prepared is better described, under It is obtained behind panel burning attached 24 hours of the thin film transistor (TFT) with different proportion (ratio of doping gas and silicon source) respective Image retention (IS) grade.Same ratio uses two samples and is tested, and adulterating gas and selecting is hydrogen phosphide, and silicon source is silicon Alkane, test result is as follows:
1) when hydrogen phosphide and silicon source ratio are 2.46, IS result is respectively L1S2 and L1S1;
2) when hydrogen phosphide and silicon source ratio are 2.79, IS result is respectively L1S1 and L0S0;
3) when hydrogen phosphide and silicon source ratio are 3.28, IS result is respectively L0S0 and L0S0;
4) when hydrogen phosphide and silicon source ratio are 0.82, IS result is respectively L1S2 and L1S1.
In IS grade, the subsequent number the big, indicates that IS is poorer.Therefore it can be seen that above-mentioned side according to the above results The thin film transistor (TFT) that method is prepared can achieve the purpose that image retention (IS) problem for improving display device.
In one embodiment, include the following steps in step S170, as shown in Figure 8 a.
Step S710 forms patterned photoresist layer on source-drain electrode metal layer.
Firstly, depositing the photoresist layer 90 of a flood on source-drain electrode metal layer, as shown in Figure 9.Photoresist layer uses photoresist It is formed.Secondly, being exposed using gray level mask plate or half rank mask plate to the substrate for being coated with photoresist layer, develop formation packet The photoresist layer of photoresist reserved area, half reserved area of photoresist and photoresist removal area is included, as shown in Figure 10.In Figure 10, grayscale Mask plate 80 includes complete opaque area 84, semi-opaque region 86 and complete transparent area 82.Wherein, opaque area 84 completely corresponds to Photoresist reserved area, namely the source electrode and drain electrode region of the active area corresponding to thin film transistor (TFT);Semi-opaque region 86 corresponds to light Half reserved area of photoresist, namely corresponding to the channel region of thin film transistor (TFT), complete transparent area 82 then corresponds to photoresist and removes area, Correspond to the passive region of thin film transistor (TFT).
Step S720 uses twice wet etching and twice dry etch process to source-drain electrode metal by exposure mask of photoresist layer Layer, N+ type doped amorphous silicon layer and amorphous silicon layer perform etching.
It completes after step S728 and removes the device architecture schematic diagram after photoresist layer referring to Fig. 7.Twice wet etching and Twice dry etching (2Wet 2Dry, abbreviation 2W2D) can be realized using traditional technique.In the present embodiment, mainly pass through Second dry etching process is improved, to realize the improvement to thin-film transistor performance, and then reaches to improve to use and be somebody's turn to do The Image sticking problems of the display device of thin film transistor (TFT).Second dry etching is mainly to the semiconductor layer above channel region It performs etching.Specifically, during second dry etching, control RF source power is 2 kilowatts~5 kilowatts, radio-frequency bias Power is 7 kilowatts~3 kilowatts, and etch period is 35 seconds~50 seconds.It, can be with by controlling second dry etching process The thickness T of semiconductor layer is controlled at 700 angstroms hereinafter, so as to reduce the cut-off current of thin film transistor (TFT), and then improves and make With the figure residue problem of the display panel of the thin film transistor (TFT).Specifically, amorphous silicon residual thickness T is smaller, corresponding thin The cut-off current of film transistor is then smaller, is asked to be effectively improved using the image residue of the display device of the thin film transistor (TFT) Topic.By being adjusted within the above range to source power, bias power and etch period, amorphous silicon residual can be made thick Degree T reaches 700 angstroms hereinafter, such as 600 angstroms or 500 angstroms.For example, in one embodiment, RF source power can be arranged It is 4 kilowatts, RF bias power is set as 4 kilowatts, and etch period is set as 46 seconds, and corresponding amorphous silicon residual thickness can at this time To reach the 550 Izods right side.
In one embodiment, in second dry etching, using chlorine (Cl2) and sulfur hexafluoride (SF6) it is used as etching gas. Also, the ratio of chlorine and sulfur hexafluoride is in 1:20~1:50.It is controlled by the ratio to chlorine and sulfur hexafluoride, it can be with Ensure the homogeneity of amorphous silicon residual layer, and then ensure thin film transistor (TFT) throughout there is uniform cut-off current.Implement one In example, the ratio of chlorine and sulfur hexafluoride is 1:25 or 1:35 or 1:40.Pass through the ratio to chlorine and sulfur hexafluoride It adjusts, may be implemented to control the homogeneity of amorphous silicon residual thickness within ± 200 angstroms.It in one embodiment, can will be non- The homogeneity of crystal silicon residual thickness is controlled in ± 125 angstroms, ± 100 angstroms, even ± 75 angstroms.
In one embodiment, step S720, also 2W2D technical process is included the steps that in as shown in Figure 8 b.Specifically, Including following sub-step:
Step S722 carries out first of wet process quarter to source-drain electrode metal layer using wet-etching technology using photoresist layer as exposure mask Erosion, removal photoresist remove the source-drain electrode metal layer below area.
Figure 11 is the device architecture schematic diagram completed after step S722.First of wet etching process can remove photoresist and go Except the source-drain electrode metal layer 970 of (namely passive region) below area, and retain the source-drain electrode metal layer 970 of active area.First wet Method etching process can't perform etching such as N+ type doped amorphous silicon layer 950 of other layers other than source-drain electrode metal layer 970.Tool Body etching process belong to any technique commonly known, this place does not repeat.
Step S724, using photoresist layer as exposure mask using dry etch process to N+ type doped amorphous silicon layer and amorphous silicon layer into First of dry etching of row, removal photoresist remove N+ type doped amorphous silicon layer and amorphous silicon layer below area.
Figure 12 is the device architecture schematic diagram completed after step S724.First of dry etching process can remove photoresist and go Except the N+ type doped amorphous silicon layer 950 and amorphous silicon layer 940 of (namely passive region) below area, and retain the N+ type doping of active area Amorphous silicon layer 950 and amorphous silicon layer 940.First of dry etching process can't be to the gate insulator of 940 lower section of amorphous silicon layer Layer 930 performs etching.Specifically etching process belongs to any technique commonly known, this place does not repeat.
Step S726 carries out second wet process quarter to source-drain electrode metal layer using wet-etching technology using photoresist layer as exposure mask Erosion removes residual photoresist and source-drain electrode metal layer below half reserved area of photoresist.
Figure 13 is the device architecture schematic diagram completed after step S726.Second wet etching process can remove photoresist half Remaining photoresist layer 90 and source-drain electrode metal layer 970 below reserved area (namely above channel region), so that only existing Source electrode and drain electrode region remains with source-drain electrode metal layer 970.Second dry etching process can't be to source-drain electrode metal layer 970 Such as N+ type doped amorphous silicon layer 950 of other layers in addition performs etching.Specifically etching process belongs to any technique commonly known, This place does not repeat.
Step S728, using photoresist layer as exposure mask using dry etch process to N+ type doped amorphous silicon layer and amorphous silicon layer into Row second dry etching removes the N+ type doped amorphous silicon layer and portion of amorphous silicon layer of half reserved area of photoresist.
Second dry etching process by the agency of in front.
For the beneficial effect that the thin film transistor (TFT) that the preparation method of above-mentioned thin film transistor (TFT) is prepared is better described, under Face combines the test result under different specific embodiments to be illustrated.Figure 14 is with different amorphous silicon residual thickness and uniform The cut-off current Ioff of the thin film transistor (TFT) of property with voltage change curve.In the present embodiment, it is with amorphous silicon residual thickness T The thin film transistor (TFT) of (700 angstroms ± 150 angstroms) is illustrated as a control group (STD).In the present embodiment, amorphous silicon residual is prepared Parameter required for thin film transistor (TFT) with a thickness of (700 angstroms ± 150 angstroms) includes: that RF source power is 3 kilowatts, and bias power is 5 kilowatts, etch period is 40 seconds, and the ratio of chlorine and sulfur hexafluoride is 1:40.Prepare amorphous silicon residual thickness be (700 angstroms ± 125 angstroms) thin film transistor (TFT) required for parameter include: RF source power be 4 kilowatts, bias power be 4 kilowatts, etch period It is 40 seconds, the ratio of chlorine and sulfur hexafluoride is 1:35.In Figure 14, abscissa is voltage, and ordinate is cut-off current;L1 is non- Crystal silicon residual thickness is the current voltage curves of the thin film transistor (TFT) of (700 ± 125) angstrom;L2 is that amorphous silicon residual thickness is The current voltage curves of the thin film transistor (TFT) of (600 ± 125) angstrom;L1 is that amorphous silicon residual thickness is (500 ± 125) angstrom The current voltage curves of thin film transistor (TFT).It can be seen from the figure that amorphous silicon residual thickness is smaller and homogeneity is better, Then the cut-off current of corresponding thin film transistor (TFT) is smaller, so as to bring preferably image residue improvement.Figure 15 is not Table is corresponded to cut-off current size of the thin film transistor (TFT) in embodiment under different voltages.In Figure 15, I (- 20V) indicates voltage Electric current when for -20V, I (- 6V) indicate that electric current when voltage is -6V, I (20V) indicate electric current when voltage is 20V.From Figure 15 In it can also be seen that L3 be located at each curve bottom namely amorphous silicon residual be (500 angstroms ± 125 angstroms) thin film transistor (TFT) With lesser cut-off current namely its can bring preferable image residue improvement.
In order to more intuitively illustrate thin film transistor (TFT) that the preparation method of above-mentioned thin film transistor (TFT) is prepared beneficial under Ditch obtains respective image retention after burning attached 24 hours to the panel with the thin film transistor (TFT) in different embodiments below (IS) grade.It wherein, is not that the thin film transistor (TFT) in the same embodiment is adopted caused by accidentalia for proof result It is tested with two samples, test result is as follows:
1) for amorphous silicon residual thickness at (500 angstroms ± 125 angstroms), IS result is respectively L0S0 and L2S5;
2) for amorphous silicon residual thickness at (700 angstroms ± 150 angstroms), IS result is respectively L3S4 and L5S6.
In IS grade, the subsequent number the big, indicates that IS is poorer.Therefore it can be seen that amorphous silicon according to the above results Residual thickness its image residue grade at (500 angstroms ± 125 angstroms) is significantly lower than image of the thickness at (700 angstroms ± 150 angstroms) Residue Grade namely its with better image residue improvement.It is appreciated that after source electrode and drain electrode is prepared also The preparation for forming passivation layer in device surface, aperture being carried out to passivation layer and carries out electrode (ITO) etc. is needed, to finally obtain The thin film transistor (TFT).
One embodiment of the invention also provides a kind of thin film transistor (TFT), and method described in aforementioned any embodiment is used to prepare It obtains.Specifically, the thin film transistor (TFT) in an embodiment includes substrate 910, the grid being formed on substrate 910 920, is formed in On substrate 910 and covers the gate insulating layer 930 of grid 920, the amorphous silicon layer 940 being formed on gate insulating layer 930, formed In the N+ type doped amorphous silicon layer 950 on amorphous silicon layer 940 and be formed on gate insulating layer 930 and and amorphous silicon layer The source S and drain D that the two sides of 940 and N+ type doped amorphous silicon layer 950 are in contact, referring to Fig. 7.
Substrate 910 can be prepared using the known material in this fields such as glass or plastics.In the present embodiment, with base Prepared on plate 910 device side be it is upper, under opposite side is.The material of grid 920 can be in the conductive materials such as aluminium or copper One or more kinds of combinations.The material of gate insulating layer 930 can be silicon nitride or silica, or silicon nitride With the combination of silica.It is appreciated that gate insulating layer 930 can also using the known material of other skilled in the art come Preparation.
In the present embodiment, N+ type doped amorphous silicon layer 240 uses ratio to mix for 0.82~1.54 or 1.74~4.1 Miscellaneous gas and silane are prepared.In one embodiment, N+ type doped amorphous silicon layer 940 can use ratio for 3.28 or 2.46 Doping gas and silane be prepared.In other examples, N+ type doped amorphous silicon layer 940 can use ratio for 2.79,3.69 or 4.1 doping gas and silane are prepared.In another embodiment, N+ type doped amorphous silicon layer 940 can To use ratio to be prepared for 0.82 or 1.23 doping gas and silane.Therefore the thin film transistor (TFT) have under light illumination compared with Good stability, so as to improve the Image sticking problems of panel.
In one embodiment, the amorphous silicon residual thickness T above the channel region of thin film transistor (TFT) 960 700 angstroms with Under, such as 600 angstroms or 500 angstroms etc., homogeneity can control within ± 200 angstroms.It in one embodiment, can be by amorphous The homogeneity of silicon residual thickness is controlled in ± 125 angstroms, ± 100 angstroms, even ± 75 angstroms.By residual to the amorphous silicon above channel region Thickness and homogeneity is stayed to carry out the Image sticking problems for the display panel that control can be effectively improved using the thin film transistor (TFT), Specific beneficial effect has been described above in aforementioned preparation process.
One embodiment of the invention also provides a kind of display device comprising display panel.Display panel includes array substrate, Thin film transistor (TFT) in the array substrate is using thin film transistor (TFT) described in aforementioned any embodiment, so as to improve display dress The image retention problem set.Display panel can be LCD, OLED, QLED and plasma panel etc..Display panel can be with plane Type panel may be curved face type panel.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (10)

1. a kind of preparation method of thin film transistor (TFT) characterized by comprising
Substrate is provided;
Grid is formed on the substrate;
Gate insulating layer is formed on the substrate, and the gate insulating layer is made to cover the grid;
Amorphous silicon layer is formed on the gate insulating layer;
N+ type doped amorphous silicon layer is formed on the amorphous silicon layer;Wherein, control doping gas and silicon source ratio be 0.82~ 1.54 or 1.74~4.1;
Source-drain electrode metal layer is formed on the N+ type doped amorphous silicon layer;And
The source-drain electrode metal layer, the N+ type doped amorphous silicon layer and the amorphous silicon layer are performed etching, to obtain source electrode And drain electrode.
2. the preparation method of thin film transistor (TFT) according to claim 1, which is characterized in that the ratio of the doping gas and silicon source Example is 0.82~1.23 or 2.46~4.1.
3. the preparation method of thin film transistor (TFT) according to claim 1, which is characterized in that the ratio of the doping gas and silicon source Example is 2.46~2.79 or 3.28~4.1.
4. the preparation method of any thin film transistor (TFT) according to claim 1~3, which is characterized in that the doping gas is Hydrogen phosphide, the silicon source are silane.
5. the preparation method of thin film transistor (TFT) according to claim 1, which is characterized in that described on the amorphous silicon layer In the step of forming N+ type doped amorphous silicon layer, diluent gas can be passed through;The flow of the diluent gas is 24000 milliliters every point Clock~25000 milliliter are per minute;The flow of the silicon source be 6200 milliliters per minute~7200 milliliters per minute.
6. the preparation method of thin film transistor (TFT) according to claim 1, which is characterized in that described on the amorphous silicon layer In the step of forming N+ type doped amorphous silicon layer, formed on the amorphous silicon layer using plasma enhanced chemical vapor chemical deposition The N+ type doped amorphous silicon layer.
7. the preparation method of thin film transistor (TFT) according to claim 1, which is characterized in that described to the source-drain electrode metal The step of layer, the N+ type doped amorphous silicon layer and the amorphous silicon layer perform etching are as follows:
Patterned photoresist layer is formed on the source-drain electrode metal layer;And
Use twice wet etching and twice dry etch process to the source-drain electrode metal layer, institute by exposure mask of the photoresist layer It states N+ type doped amorphous silicon layer and the amorphous silicon layer performs etching;Wherein, in second dry etching, radio frequency source function is controlled Rate is 2 kilowatts~5 kilowatts, and RF bias power is 7 kilowatts~3 kilowatts, and etch period is 35 seconds~50 seconds, above channel region Layer semiconductor thickness is 400 angstroms~700 angstroms.
8. the preparation method of thin film transistor (TFT) according to claim 7, which is characterized in that in second dry etching, Etching gas includes chlorine and sulfur hexafluoride, and the ratio of chlorine and sulfur hexafluoride is 1:20~1:50.
9. a kind of thin film transistor (TFT) characterized by comprising
Substrate;
The grid being formed on the substrate;
It is formed on the substrate and covers the gate insulating layer of the grid;
The amorphous silicon layer being formed on the gate insulating layer;
The N+ type doped amorphous silicon layer being formed on the amorphous silicon layer;And
It is formed in and is in contact with the two sides of the amorphous silicon layer and the N+ type doped amorphous silicon layer on the gate insulating layer Source electrode and drain electrode;
Wherein, the N+ type doped amorphous silicon layer use ratio for 0.82~1.54 or 1.74~4.1 doping gas and silane It is prepared.
10. a kind of display device, including display panel, which is characterized in that the array substrate in the display panel includes as weighed Benefit require 9 described in thin film transistor (TFT).
CN201810837308.XA 2018-07-26 2018-07-26 Thin film transistor (TFT) and preparation method thereof, display device Pending CN109103105A (en)

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