CN109096901A - A kind of aqueous leather dope of automobile interior decoration leatherware - Google Patents

A kind of aqueous leather dope of automobile interior decoration leatherware Download PDF

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Publication number
CN109096901A
CN109096901A CN201810803243.7A CN201810803243A CN109096901A CN 109096901 A CN109096901 A CN 109096901A CN 201810803243 A CN201810803243 A CN 201810803243A CN 109096901 A CN109096901 A CN 109096901A
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CN
China
Prior art keywords
component
aqueous
water
interior decoration
automobile interior
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810803243.7A
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Chinese (zh)
Inventor
刘波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Changguan Coatings Co Ltd
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Huizhou Changguan Coatings Co Ltd
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Publication date
Application filed by Huizhou Changguan Coatings Co Ltd filed Critical Huizhou Changguan Coatings Co Ltd
Priority to CN201810803243.7A priority Critical patent/CN109096901A/en
Publication of CN109096901A publication Critical patent/CN109096901A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Abstract

The present invention discloses a kind of aqueous leather dope of automobile interior decoration leatherware, including first component and second component, the first component is based on following parts by weight: aqueous acrylic emulsion 20~40, water-borne dispersions 30~50, cosolvent 5~10, aqueous pigment 5~15, water nano particle 0.5~1, ground wetting agent 0.5~1, defoaming agent 0.2~0.8, deionized water 5~15, the second group are divided into waterborne curing agent, and the waterborne curing agent is modified isocyanate.Use dispersibility, the preferable aqueous acrylic emulsion of mobility and water-borne dispersions as basic performed polymer, two-component coating is constituted with waterborne curing agent, the dispersing aiies such as the nano-titanium dioxide transparent dispersion of aqueous pigment cooperation simultaneously, so that the quality of mixed aqueous leather dope is uniform, good fluidity, it is easy to be sprayed on leather surface, spray the leathering formed is soft, gloss it is soft do not whiten, coating grain it is careful, leather and fur products surface can be made to obtain the feel of cotton stripped thread silk fabric and there is some strength.

Description

A kind of aqueous leather dope of automobile interior decoration leatherware
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of aqueous leather dope of automobile interior decoration leatherware.
Background technique
With the continuous improvement of social and economic level and the enhancing of consumer health, awareness of safety, people are pursuing vapour While vehicle shape and power, the function and aesthetic feeling of automobile interior decoration are also increasingly paid close attention to, pays close attention to the comfort of seating, it is several and more Pay attention in smell, environmental protection and the health hazard problem of interior material, functionalization, green interior leather for automobiles product also therefore will be at The emphasis competitively developed for interior leather for automobiles producer.Currently, for automobile door plate, seat cushion, steering wheel instrument board, compartment inner wall etc. The protection of position leather sheath and decoration mainly copy leather using PVC (polyvinyl chloride) or PU (polyurethane), and copy the table of leather Face modification spraying colouring then needs special leather dope, and this leather dope need to have preferable adhesive force and ductility, have simultaneously The property requirements such as wear-resisting and corrosion-resistant and low VOC, nontoxic.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of automobile interior decoration leatherware aqueous leather dope, in automobile The renovations of leather and fur products such as decorations leather seat, steering wheel leather sheath, corium door-plate paint, change colour, complementary color.
The technical scheme adopted by the invention to achieve the purpose is as follows:
A kind of aqueous leather dope of automobile interior decoration leatherware, including first component and second component, the first component press following weight Part meter:
The second group is divided into waterborne curing agent, and the waterborne curing agent is modified isocyanate.
It further illustrates, the water-borne dispersions are anion aliphatic polyurethane dispersion.
It further illustrates, the cosolvent is one of 3- methoxy methyl propionate, propylene glycol methyl ether acetate Or compound.
It further illustrates, the water nano particle is nano-titanium dioxide transparent dispersion.
It further illustrates, the ground wetting agent is one of BYK-3400, BYK-3410, BYK-3455 or multiple With object.
It further illustrates, the defoaming agent is in BYK-011, BYK-018, BYK-024, BYK-028, BYK-044 One kind or compound.
Further illustrate, the aqueous leather dope the preparation method is as follows: successively weighing aqueous acrylic emulsion, helping Solvent, aqueous special-purpose metal pigment, water nano particle, ground wetting agent, defoaming agent, deionized water are added in stirred tank and mix It stirs evenly, using amine neutralizer adjusting pH value to 7.5-8 or so, obtains first component;In addition modified isocyanate is as second group Point.
It further illustrates, the construction method implementation steps of the aqueous leather dope are as follows:
A. with first component: second component: water=5:1:0.5 ratio is separately added into first component, second component, water in a reservoir, It stirs;
B. a step acquired solution is crossed into 100 mesh filter screens, obtains filtrate, test viscosity, spray can be packed by sticking up to 30 scholar 5s Coating device sprays surface to be treated, stirs if viscosity enters filtrate not up to 30 scholar 5s, to add the water of 5% parts by weight every time It mixes, until viscosity reaches 30 scholar 5s.
C. the leatherware sprayed is placed in 30~50 DEG C of environment and toasts 30~60min drying.
Compared with prior art, the beneficial effects of the present invention are:
Use dispersibility, the preferable aqueous acrylic emulsion of mobility and water-borne dispersions as basis performed polymer, with Waterborne curing agent constitutes two-component coating, while aqueous pigment cooperates with dispersing aiies such as nano-titanium dioxide transparent dispersions, So that the quality of mixed aqueous leather dope is uniform, good fluidity is easy to be sprayed on leather surface, sprays the leather of formation Face is soft, gloss it is naturally soft do not whiten, coating grain it is careful, leather and fur products surface can be made to obtain the feel of cotton stripped thread silk fabric and had Some strength.
Specific embodiment
In order to further understand the content, features and effects of the present invention, hereby enumerating following embodiment explanation.
Embodiment 1
First component is based on following parts by weight: aqueous acrylic emulsion 30, water-borne dispersions 40, propylene glycol methyl ether acetate 6, Aqueous pigment 12, water nano particle 0.5, ground wetting agent 0.7, defoaming agent 0.5, deionized water 11.7;Second group is divided into modification Isocyanates.
Using steps are as follows:
A. aqueous acrylic emulsion, cosolvent, aqueous special-purpose metal pigment, water nano particle, ground profit are successively weighed Humectant, defoaming agent, deionized water are added in stirred tank and are mixed evenly, and adjust pH value to 7.5~8 left sides using amine neutralizer The right side obtains first component;
B. with first component: second component: water=5:1:0.5 ratio be separately added into a reservoir first component, second component and Water stirs;
C. viscosity is tested to step b acquired solution, interval, which adds water and stirs, uniformly makes the viscosity of water reach 30 scholar 5s;
D. b step acquired solution is crossed into 100 mesh filter screens, obtains filtrate, filtrate is packed into spray equipment to leatherware wait locate Reason surface is sprayed, and the leatherware sprayed, which is placed in 30~50 DEG C of environment, toasts 30~60min drying.
Embodiment 2
First component is based on following parts by weight: aqueous acrylic emulsion 30, water-borne dispersions 45, propylene glycol methyl ether acetate 6, Aqueous pigment 10, water nano particle 0.6, ground wetting agent 0.8, defoaming agent 0.5, deionized water 7.1;It is different that second group is divided into modification Cyanate.
Using steps are as follows:
A. aqueous acrylic emulsion, cosolvent, aqueous special-purpose metal pigment, water nano particle, ground profit are successively weighed Humectant, defoaming agent, deionized water are added in stirred tank and are mixed evenly, and adjust pH value to 7.5~8 left sides using amine neutralizer The right side obtains first component;
B. with first component: second component: water=5:1:0.5 ratio distinguishes first component second component and water in a reservoir, fills Divide and stirs evenly;
C. viscosity is tested to step b acquired solution, interval, which adds water and stirs, uniformly makes the viscosity of water reach 30 scholar 5s;
D. b step acquired solution is crossed into 100 mesh filter screens, obtains filtrate, filtrate is packed into spray equipment to leatherware wait locate Reason surface is sprayed, and the leatherware sprayed, which is placed in 30~50 DEG C of environment, toasts 30~60min drying.
Embodiment 3
First component is based on following parts by weight: aqueous acrylic emulsion 35, water-borne dispersions 35, propylene glycol methyl ether acetate 6, Aqueous pigment 10, water nano particle 0.6, ground wetting agent 0.8, defoaming agent 0.5, deionized water 12.1;Second group is divided into modification Isocyanates.
Using steps are as follows:
A. aqueous acrylic emulsion, cosolvent, aqueous special-purpose metal pigment, water nano particle, ground profit are successively weighed Humectant, defoaming agent, deionized water are added in stirred tank and are mixed evenly, and adjust pH value to 7.5~8 left sides using amine neutralizer The right side obtains first component;
B. with first component: second component: water=5:1:0.5 ratio distinguishes first component second component and water in a reservoir, fills Divide and stirs evenly;
C. viscosity is tested to step b acquired solution, interval, which adds water and stirs, uniformly makes the viscosity of water reach 30 scholar 5s;
D. step c acquired solution is crossed into 100 mesh filter screens, obtains filtrate, filtrate is packed into spray equipment to leatherware wait locate Reason surface is sprayed, and the leatherware sprayed, which is placed in 30~50 DEG C of environment, toasts 30~60min drying.
By embodiment 1, into embodiment 3, aqueous leather dope obtained by step b is tested for the property, test result such as table 1.
Table 1
The above is only the preferred embodiments of the present invention, and is not intended to limit the present invention in any form, Any simple modification made to the above embodiment according to the technical essence of the invention, equivalent variations and modification, belong to The range of technical solution of the present invention.

Claims (8)

1. a kind of aqueous leather dope of automobile interior decoration leatherware, including first component and second component, it is characterised in that: the first component is pressed Following parts by weight meter:
The second group is divided into waterborne curing agent, and the waterborne curing agent is modified isocyanate.
2. a kind of aqueous leather dope of automobile interior decoration leatherware according to claim 1, it is characterised in that: the aqueous dispersion Body is anion aliphatic polyurethane dispersion.
3. a kind of aqueous leather dope of automobile interior decoration leatherware according to claim 1, it is characterised in that: the cosolvent is One of 3- methoxy methyl propionate, propylene glycol methyl ether acetate or compound.
4. a kind of aqueous leather dope of automobile interior decoration leatherware according to claim 1, it is characterised in that: the water nano Particle is nano-titanium dioxide transparent dispersion.
5. a kind of aqueous leather dope of automobile interior decoration leatherware according to claim 1, it is characterised in that: the ground wetting Agent is one of BYK-3400, BYK-3410, BYK-3455 or compound.
6. a kind of aqueous leather dope of automobile interior decoration leatherware according to claim 1, it is characterised in that: the defoaming agent is One of BYK-011, BYK-018, BYK-024, BYK-028, BYK-044 or compound.
7. a kind of aqueous leather dope of automobile interior decoration leatherware according to claim 1, which is characterized in that the aqueous leather Paint the preparation method is as follows: successively weigh aqueous acrylic emulsion, cosolvent, aqueous special-purpose metal pigment, water nano particle, Ground wetting agent, defoaming agent, deionized water are added in stirred tank and are mixed evenly, and adjust pH value to 7.5 using amine neutralizer ~8 or so, obtain first component;In addition modified isocyanate is as second component.
8. the aqueous leather dope of a kind of automobile interior decoration leatherware according to claims 1 to 7, which is characterized in that described aqueous The construction method implementation steps of leather dope are as follows:
A. with first component: second component: water=5:1:0.5 ratio is separately added into first component, second component, water in a reservoir, sufficiently It stirs evenly;
B. a step acquired solution is crossed into 100 mesh filter screens, obtains filtrate, test viscosity, spraying dress can be packed by sticking up to 30 scholar 5s It sets and surface to be treated is sprayed, if viscosity enters filtrate stirring not up to 30 scholar 5s to add the water of 5% parts by weight every time, Until viscosity reaches 30 scholar 5s.
C. the leatherware sprayed is placed in 50~60 DEG C of environment and toasts 30~60min drying.
CN201810803243.7A 2018-07-20 2018-07-20 A kind of aqueous leather dope of automobile interior decoration leatherware Pending CN109096901A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810803243.7A CN109096901A (en) 2018-07-20 2018-07-20 A kind of aqueous leather dope of automobile interior decoration leatherware

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810803243.7A CN109096901A (en) 2018-07-20 2018-07-20 A kind of aqueous leather dope of automobile interior decoration leatherware

Publications (1)

Publication Number Publication Date
CN109096901A true CN109096901A (en) 2018-12-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112063227A (en) * 2020-09-09 2020-12-11 佛山市高明绿色德化工有限公司 Water-based gravure leather gloss oil and use method thereof
WO2022088122A1 (en) * 2020-10-30 2022-05-05 河北比尔尼克新材料科技股份有限公司 Water-based paint for leather and preparation method therefor
CN117165167A (en) * 2023-11-02 2023-12-05 山东莱福特皮革制品有限公司 Water-based leather paint for automobile interior leather

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112063227A (en) * 2020-09-09 2020-12-11 佛山市高明绿色德化工有限公司 Water-based gravure leather gloss oil and use method thereof
WO2022088122A1 (en) * 2020-10-30 2022-05-05 河北比尔尼克新材料科技股份有限公司 Water-based paint for leather and preparation method therefor
CN117165167A (en) * 2023-11-02 2023-12-05 山东莱福特皮革制品有限公司 Water-based leather paint for automobile interior leather
CN117165167B (en) * 2023-11-02 2024-03-08 山东莱福特皮革制品有限公司 Water-based leather paint for automobile interior leather

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Application publication date: 20181228