CN109096606A - A kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and its manufacturing method - Google Patents

A kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and its manufacturing method Download PDF

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Publication number
CN109096606A
CN109096606A CN201810782450.9A CN201810782450A CN109096606A CN 109096606 A CN109096606 A CN 109096606A CN 201810782450 A CN201810782450 A CN 201810782450A CN 109096606 A CN109096606 A CN 109096606A
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parts
resistant
temperature
flame
wrapping layer
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赵家玉
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Tongling Special Cable Co Ltd
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Tongling Special Cable Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/382Boron-containing compounds and nitrogen
    • C08K2003/385Binary compounds of nitrogen with boron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Insulated Conductors (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and its manufacturing methods, it is characterized in that, including following parts by weight raw material: 30-40 parts of polypropylene, 22-30 parts of polyurethane, 12-18 parts of Kynoar, 18-25 parts of ethylene propylene diene rubber, 10-20 parts of mineral wool, 18-26 parts of phenolic resin, 12-22 parts of epoxy resin, 8-15 parts of boron nitride, 6-12 parts of dolomite dust, 8-12 parts of silicon dioxide powder, 5-10 parts of aeroge, 4-8 parts of zirconium diboride, 3-6 parts of UV resistant agent, 2-5 parts of age resister, 8-14 parts of hydroxyethyl cellulose aqueous solution, 8-12 parts of tungsten carbide, 15-22 parts of zinc acrylate resin, 4-8 parts of crosslinking agent, 5-8 parts of coupling agent, 10-14 parts of nano active light calcium;A kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer of the present invention, it is main raw material(s) by esters, rubber, add the auxiliary materials such as silicon dioxide powder, zirconium diboride, crosslinking agent, coupling agent, cable wrapping layer obtained has the complex functions such as fire-retardant, high temperature resistant, anticorrosion, production cost has been saved, it being capable of large-scale promotion use.

Description

A kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and its manufacturing method
Technical field
The present invention relates to technical field of cable, and in particular to a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and its Manufacturing method.
Background technique
In the manufacture processing of present cable, cable core outer layer has the wrapping layer of layer 2-4, and the effect of different layers is different, has Be it is corrosion-resistant, have plenty of high temperature resistant, have plenty of flame-retardant layer, manufacture craft is more complicated, and production cost is relatively high, produces Often weight is bigger for cable, and after high-altitude is set up, over time, cable is sagging, there is some potential safety problems.
Summary of the invention
The purpose of the present invention is to solve the above-mentioned problems, provide a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and Its manufacturing method, the wrapping layer outside cable core is by a variety of esters mixed once mixings, then carries out that glass is added when secondary mixing mixing The auxiliary materials such as glass cotton, boron nitride, aeroge, zirconium dioxide make the wrapping layer of manufacture while having fire-retardant, high temperature resistant, anti-corrosion The function of erosion, weight are also relatively lighter.
To achieve the goals above, the present invention is achieved by the following technical solutions: a kind of flame-resistant high-temperature-resistant anticorrosion Cable wrapping layer forms: 30-40 parts of polypropylene, 22-30 parts of polyurethane, Kynoar 12- according to the raw material of following parts by weight 18 parts, 18-25 parts of ethylene propylene diene rubber, 10-20 parts of mineral wool, 18-26 parts of phenolic resin, 12-22 parts of epoxy resin, boron nitride 8-15 parts, 6-12 parts of dolomite dust, 8-12 parts of silicon dioxide powder, 5-10 parts of aeroge, 4-8 parts of zirconium diboride, UV resistant agent 3-6 parts, 2-5 parts of age resister, 8-14 parts of hydroxyethyl cellulose aqueous solution, 8-12 parts of tungsten carbide, zinc acrylate resin 15-22 Part, 4-8 parts of crosslinking agent, 5-8 parts of coupling agent, 10-14 parts of nano active light calcium.
Further, a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer forms: poly- third according to the raw material of following parts by weight 33-37 parts of alkene, 25-28 parts of polyurethane, 14-16 parts of Kynoar, 20-23 parts of ethylene propylene diene rubber, 12-18 parts of mineral wool, 20-25 parts of phenolic resin, 14-20 parts of epoxy resin, 10-14 parts of boron nitride, 7-11 parts of dolomite dust, silicon dioxide powder 9-11 Part, 6-9 parts of aeroge, 5-7 parts of zirconium diboride, 4-5 parts of UV resistant agent, 3-4 parts of age resister, hydroxyethyl cellulose aqueous solution 9-13 parts, 9-11 parts of tungsten carbide, 17-20 parts of zinc acrylate resin, 5-7 parts of crosslinking agent, 6-7 parts of coupling agent, nano active light calcium 11-13 parts.
Further, a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer forms: poly- third according to the raw material of following parts by weight 35 parts of alkene, 26 parts of polyurethane, 15 parts of Kynoar, 22 parts of ethylene propylene diene rubber, 15 parts of mineral wool, 22 parts of phenolic resin, ring 17 parts of oxygen resin, 12 parts of boron nitride, 9 parts of dolomite dust, 10 parts of silicon dioxide powder, 8 parts of aeroge, 6 parts of zirconium diboride, uvioresistant 4.5 parts of line agent, 12 parts of hydroxyethyl cellulose aqueous solution, 10 parts of tungsten carbide, 18 parts of zinc acrylate resin, is handed over 3.5 parts of age resister Join 6 parts of agent, 6.5 parts of coupling agent, 12 parts of nano active light calcium.
A kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and its manufacturing method, include the following steps:
S1, by the ratio polypropylene, polyurethane, Kynoar, ethylene propylene diene rubber, phenolic resin, epoxy resin, propylene Sour zinc resin is added in kneading machine, stirs evenly, and is kneaded 40-50min, obtains primary material, melting temperature is maintained at 140-150 ℃;
S2, by the ratio mineral wool, boron nitride, dolomite dust, silicon dioxide powder, aeroge, zirconium diboride, uvioresistant Primary material is added in agent, age resister, crosslinking agent, coupling agent, tungsten carbide, hydroxyethyl cellulose aqueous solution, nano active light calcium Middle mixing 30-40min, obtains secondary raw material, and melting temperature is maintained at 80-100 DEG C;
S3, the secondary raw material for obtaining S2 are put into pelletizer and are granulated, and obtain flame-resistant high-temperature-resistant anticorrosion cable wrapping layer, are granulated Machine extruder temperature is controlled at 60-70 DEG C.
In summary the invention has the following advantages: flame-resistant high-temperature-resistant anticorrosion cable packet prepared by the present invention Covering layer, it is light-weight, while there is fire-retardant, high temperature resistant, etch-proof effect, production cost has been saved, process flow is reduced, has been fitted Large-scale promotion is closed to use.
Specific embodiment
Specific embodiment 1: a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer is formed according to the raw material of following parts by weight: 30 parts of polypropylene, 22 parts of polyurethane, 12 parts of Kynoar, 18 parts of ethylene propylene diene rubber, 10 parts of mineral wool, phenolic resin 18 Part, resists 12 parts of epoxy resin, 8 parts of boron nitride, 6 parts of dolomite dust, 8 parts of silicon dioxide powder, 5 parts of aeroge, 4 parts of zirconium diboride 3 parts of ultraviolet light agent, 2 parts of age resister, 8 parts of hydroxyethyl cellulose aqueous solution, 8 parts of tungsten carbide, 15 parts of zinc acrylate resin, crosslinking 4 parts of agent, 5 parts of coupling agent, 10 parts of nano active light calcium.
A kind of manufacturing method of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer are as follows:
S1, by the ratio polypropylene, polyurethane, Kynoar, ethylene propylene diene rubber, phenolic resin, epoxy resin, propylene Sour zinc resin is added in kneading machine, stirs evenly, and is kneaded 40min, obtains primary material, melting temperature is maintained at 140 DEG C;
S2, by the ratio mineral wool, boron nitride, dolomite dust, silicon dioxide powder, aeroge, zirconium diboride, uvioresistant Primary material is added in agent, age resister, crosslinking agent, coupling agent, tungsten carbide, hydroxyethyl cellulose aqueous solution, nano active light calcium Middle mixing 30min, obtains secondary raw material, and melting temperature is maintained at 80 DEG C;
S3, the secondary raw material for obtaining S2 are put into pelletizer and are granulated, and obtain flame-resistant high-temperature-resistant anticorrosion cable wrapping layer, are granulated Machine extruder temperature is controlled at 60 DEG C.
Specific embodiment 2: a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer is formed according to following raw material: poly- 35 parts of propylene, 26 parts of polyurethane, 15 parts of Kynoar, 22 parts of ethylene propylene diene rubber, 15 parts of mineral wool, 22 parts of phenolic resin, 17 parts of epoxy resin, 12 parts of boron nitride, 9 parts of dolomite dust, 10 parts of silicon dioxide powder, 8 parts of aeroge, 6 parts of zirconium diboride, anti-purple 4.5 parts of outside line agent, 3.5 parts of age resister, 12 parts of hydroxyethyl cellulose aqueous solution, 10 parts of tungsten carbide, 18 parts of zinc acrylate resin, 6 parts of crosslinking agent, 6.5 parts of coupling agent, 12 parts of nano active light calcium.
A kind of manufacturing method of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer are as follows:
S1, by the ratio polypropylene, polyurethane, Kynoar, ethylene propylene diene rubber, phenolic resin, epoxy resin, propylene Sour zinc resin is added in kneading machine, stirs evenly, and is kneaded 45min, obtains primary material, melting temperature is maintained at 145 DEG C;
S2, by the ratio mineral wool, boron nitride, dolomite dust, silicon dioxide powder, aeroge, zirconium diboride, uvioresistant Primary material is added in agent, age resister, crosslinking agent, coupling agent, tungsten carbide, hydroxyethyl cellulose aqueous solution, nano active light calcium Middle mixing 35min, obtains secondary raw material, and melting temperature is maintained at 90 DEG C;
S3, the secondary raw material for obtaining S2 are put into pelletizer and are granulated, and obtain flame-resistant high-temperature-resistant anticorrosion cable wrapping layer, are granulated Machine extruder temperature is controlled at 65 DEG C.
Specific embodiment 3: a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer is formed according to following raw material: poly- 40 parts of propylene, 30 parts of polyurethane, 18 parts of Kynoar, 25 parts of ethylene propylene diene rubber, 20 parts of mineral wool, 26 parts of phenolic resin, 22 parts of epoxy resin, 12 parts of dolomite dust, 12 parts of silicon dioxide powder, 10 parts of aeroge, 8 parts of zirconium diboride, resists 15 parts of boron nitride 6 parts of ultraviolet light agent, 14 parts of hydroxyethyl cellulose aqueous solution, 12 parts of tungsten carbide, 22 parts of zinc acrylate resin, is handed over 5 parts of age resister Join 8 parts of agent, 8 parts of coupling agent, 14 parts of nano active light calcium.
A kind of manufacturing method of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer are as follows:
S1, by the ratio polypropylene, polyurethane, Kynoar, ethylene propylene diene rubber, phenolic resin, epoxy resin, propylene Sour zinc resin is added in kneading machine, stirs evenly, and is kneaded 50min, obtains primary material, melting temperature is maintained at 150 DEG C;
S2, by the ratio mineral wool, boron nitride, dolomite dust, silicon dioxide powder, aeroge, zirconium diboride, uvioresistant Primary material is added in agent, age resister, crosslinking agent, coupling agent, tungsten carbide, hydroxyethyl cellulose aqueous solution, nano active light calcium Middle mixing 40min, obtains secondary raw material, and melting temperature is maintained at 100 DEG C;
S3, the secondary raw material for obtaining S2 are put into pelletizer and are granulated, and obtain flame-resistant high-temperature-resistant anticorrosion cable wrapping layer, are granulated Machine extruder temperature is controlled at 70 DEG C.
Embodiment provided above is better embodiment of the invention, only is used to facilitate to illustrate the present invention, not to this hair It is bright to make any form of restriction, any those of ordinary skill in the art, if not departing from the proposed skill of the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from technical feature content of the invention, in the range of still falling within the technology of the present invention feature.

Claims (4)

1. a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer, which is characterized in that be made of raw material from the following weight: polypropylene 30-40 parts, 22-30 parts of polyurethane, 12-18 parts of Kynoar, 18-25 parts of ethylene propylene diene rubber, 10-20 parts of mineral wool, phenol 18-26 parts of urea formaldehyde, 12-22 parts of epoxy resin, 8-15 parts of boron nitride, 6-12 parts of dolomite dust, 8-12 parts of silicon dioxide powder, gas 5-10 parts of gel, 4-8 parts of zirconium diboride, 3-6 parts of UV resistant agent, 2-5 parts of age resister, hydroxyethyl cellulose aqueous solution 8-14 Part, 8-12 parts of tungsten carbide, 15-22 parts of zinc acrylate resin, 4-8 parts of crosslinking agent, 5-8 parts of coupling agent, nano active light calcium 10-14 Part.
2. a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer according to claim 1, which is characterized in that by following weight The raw material of part is made: 33-37 parts of polypropylene, 25-28 parts of polyurethane, 14-16 parts of Kynoar, ethylene propylene diene rubber 20-23 Part, 12-18 parts of mineral wool, 20-25 parts of phenolic resin, 14-20 parts of epoxy resin, 10-14 parts of boron nitride, dolomite dust 7-11 Part, 9-11 parts of silicon dioxide powder, 6-9 parts of aeroge, 5-7 parts of zirconium diboride, 4-5 parts of UV resistant agent, 3-4 parts of age resister, 9-13 parts of hydroxyethyl cellulose aqueous solution, 9-11 parts of tungsten carbide, 17-20 parts of zinc acrylate resin, 5-7 parts of crosslinking agent, coupling agent 6-7 parts, 11-13 parts of nano active light calcium.
3. a kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer according to claim 2, which is characterized in that by following weight The raw material composition of part: 35 parts of polypropylene, 26 parts of polyurethane, 15 parts of Kynoar, 22 parts of ethylene propylene diene rubber, mineral wool 15 Part, 22 parts of phenolic resin, 17 parts of epoxy resin, 12 parts of boron nitride, 9 parts of dolomite dust, 10 parts of silicon dioxide powder, 8 parts of aeroge, 6 parts of zirconium diboride, 4.5 parts of UV resistant agent, 3.5 parts of age resister, 12 parts of hydroxyethyl cellulose aqueous solution, 10 parts of tungsten carbide, 18 parts of zinc acrylate resin, 6 parts of crosslinking agent, 6.5 parts of coupling agent, 12 parts of nano active light calcium.
4. a kind of manufacturing method of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer according to claim 1 to 3, special Sign is, includes the following steps:
S1, by the ratio polypropylene, polyurethane, Kynoar, ethylene propylene diene rubber, phenolic resin, epoxy resin, propylene Sour zinc resin is added in kneading machine, stirs evenly, and is kneaded 40-50min, obtains primary material, melting temperature is maintained at 140-150 ℃;
S2, by the ratio mineral wool, boron nitride, dolomite dust, silicon dioxide powder, aeroge, zirconium diboride, uvioresistant Primary material is added in agent, age resister, crosslinking agent, coupling agent, tungsten carbide, hydroxyethyl cellulose aqueous solution, nano active light calcium Middle mixing 30-40min, obtains secondary raw material, and melting temperature is maintained at 80-100 DEG C;
S3, the secondary raw material for obtaining S2 are put into pelletizer and are granulated, and obtain flame-resistant high-temperature-resistant anticorrosion cable wrapping layer, are granulated Machine extruder temperature is controlled at 60-70 DEG C.
CN201810782450.9A 2018-07-17 2018-07-17 A kind of flame-resistant high-temperature-resistant anticorrosion cable wrapping layer and its manufacturing method Pending CN109096606A (en)

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN113583336A (en) * 2021-07-23 2021-11-02 江阴市海江高分子材料有限公司 Heat-resistant flexible semiconductive shielding PP cable material and preparation method thereof
CN116705409A (en) * 2023-08-03 2023-09-05 湖南华菱线缆股份有限公司 Medium-voltage fireproof cable

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CN105733094A (en) * 2016-03-31 2016-07-06 安徽富悦达电子有限公司 High strength impact-resistant cable
CN105924768A (en) * 2016-04-21 2016-09-07 安徽万泰电缆有限公司 Flame-retardant and wear-resistant polypropylene cable material

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CN105733094A (en) * 2016-03-31 2016-07-06 安徽富悦达电子有限公司 High strength impact-resistant cable
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113583336A (en) * 2021-07-23 2021-11-02 江阴市海江高分子材料有限公司 Heat-resistant flexible semiconductive shielding PP cable material and preparation method thereof
CN116705409A (en) * 2023-08-03 2023-09-05 湖南华菱线缆股份有限公司 Medium-voltage fireproof cable
CN116705409B (en) * 2023-08-03 2023-09-29 湖南华菱线缆股份有限公司 Medium-voltage fireproof cable

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