CN109082150A - A kind of drawing gouache color and preparation method thereof - Google Patents
A kind of drawing gouache color and preparation method thereof Download PDFInfo
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- CN109082150A CN109082150A CN201810749503.7A CN201810749503A CN109082150A CN 109082150 A CN109082150 A CN 109082150A CN 201810749503 A CN201810749503 A CN 201810749503A CN 109082150 A CN109082150 A CN 109082150A
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- calcium carbonate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
Abstract
The invention discloses a kind of drawing gouache colors and preparation method thereof, its raw material includes dispersible pigment color paste, clay, nanometer titanium dioxide, adhesive, coalescing agent, surfactant, thickener, wetting dispersing agent, fungicide and water, it further include nano zine oxide, nanometer calcium carbonate, wetting dispersing agent is contained hydrophilic group by intramolecular and at least formed containing the organo-silicon compound there are two hydrophobic group with natrosol；Preparation method: each raw material is weighed by formula rate, dispersible pigment color paste, clay, nanometer titanium dioxide, nano zine oxide, nanometer calcium carbonate, some adhesive, wetting dispersing agent, part of the surface activating agent and water are mixed, then remaining adhesive, remaining surfactant, thickener, coalescing agent and fungicide are added, mixing to get；The present invention can be realized in high and low temperature alternative, alternation of wetting and drying, winter alternates with summer environment it is not easy to crack, be not easy mouldy, and it is stronger to be also able to maintain preferable color, covering power.
Description
Technical field
The invention belongs to gouache colors of painting under field of pigments, more particularly to outdoor high and low temperature alternative, alternation of wetting and drying phenomenon
Application, and in particular to a kind of drawing gouache color and preparation method thereof.
Background technique
Pigment are the abbreviations of gouache, China there are many address such as " publicity color ", with acrylic paints (or " be concentrated
Advertisement paint "), the pigment that uses commonly referred to as drawing gouache color weaker compared to covering power, while being likely present resistance to
There is cracking, Signs of Mould in time property, chromatic aberration is big etc. especially in high and low temperature alternative, alternation of wetting and drying, winter alternates with summer environment
The defect of aspect.
Such as Chinese invention patent CN101186782A, the fine arts gouache color that it discloses a kind of containing nano dye and
Manufacturing method, it is characterized in that formula rate is based on number: nano dye starches 1-5 parts, 10-30 parts of pigment powder, lithopone 15-40
Part, 2-12 parts of Arabic gum, peach gum 20-35 parts natural, 2-10 parts of glycerol, 0.2-2 parts of sodium benzoate, phenoxetol 0.1-2
Part, 10-15 parts of distilled water first take natural peach gum, Arabic gum to be put into heating, stirring, dissolution in formula distilled water, bonding are made
Agent glue；Nano dye slurry is added in adhesive glue, pigment powder adds lithopone, glycerol, benzoic acid after mixing evenly
Sodium, phenoxetol are stirred into coarse particles；Above-mentioned coarse particles are added in the hopper of three-roll grinder and are ground, the material of grinding
Liquid stream enters in material storage barrel to get finished product.This patent realizes the enhancing of color, tinting strength, tinting power etc. by the way that nano dye slurry is added,
Although also achieving certain weather resistance, there are still high and low temperature alternative, alternation of wetting and drying, winters alternates with summer under outdoor environment
Cracking, Signs of Mould in environment, the defect that chromatic aberration is big, covering power is poor etc., the gouache color that is unfavorable for painting are used for
The application of outdoor mural painting.
For another example Chinese invention patent CN106221343A, it discloses a kind of weather-proof drawing gouache color of nanoscale and its systems
Preparation Method, comprising: 20-30 parts of peach gum, 5-10 parts of clay, 4-10 parts of nano-titanium dioxide, 3-10 parts of phthalocyanine green G, Fast Yellow G
5-12 parts, 6-15 parts of Monododecylphosphate potassium, 10-18 parts of fatty acid distribution of coconut oil diglycollic amide, 2-6 parts of mannuronic acid,
1-3 parts of fungicide, 6-14 parts of guar gum, 3-9 parts of hydroxyethyl cellulose, 4-10 parts of alumina silicate, 6-12 parts of ethylene glycol, three ethyl alcohol
2-5 parts of amine, 40-80 parts of water；Although this patent realizes certain covering power enhancing, the chromatic aberration under high humidity, hot environment
The advantages that small, but for outdoor high and low temperature alternative, alternation of wetting and drying, in winter alternates with summer environment pigment improved stability but very
It is small, however it remains phenomena such as cracking, be mouldy, and there is also certain discoloration problems.
Summary of the invention
The technical problem to be solved by the present invention is to overcome deficiency in the prior art, a kind of improved drawing pigment are provided
Pigment, can be realized in high and low temperature alternative, alternation of wetting and drying, winter alternates with summer environment it is not easy to crack, be not easy mouldy, and can also protect
It is stronger to hold preferable color, covering power.
The present invention also provides a kind of preparation methods of gouache color of painting.
In order to solve the above technical problems, a kind of technical solution that the present invention takes is as follows:
A kind of drawing gouache color, raw material include dispersible pigment color paste, clay, nanometer titanium dioxide, adhesive, coalescing agent,
Surfactant, thickener, wetting dispersing agent, fungicide and water, the raw material further include nano zine oxide, nanometer calcium carbonate,
The molar ratio of the nanometer titanium dioxide, the nano zine oxide and the nanometer calcium carbonate is 0.5-2 ︰ 0.5-2 ︰ 1, described
Wetting dispersing agent contains hydrophilic group and the organo-silicon compound of hydrophobic group and cellulose ethoxy at least containing there are two by intramolecular
Ether composition, the 1 ︰ 0.5-5 of molar ratio of the organo-silicon compound and the natrosol.
In the present invention, the dispersible pigment color paste can be dispersible pigment color paste commonly used in the prior art, be not specifically limited herein.
For example including but be not limited to black, red, blue, green, Huang is equal (and to may particularly include various types of pigment, with Clariant organic pigment
For, it specifically may include black L0086, red L3875, red L3885, MaroonL3920, MaroonL3980, red L4120 is red
L3880HD, red L3910HD, red L4039, red L4040, red L4045, blue L6480, blue L6482, blue L6495F, blue L6360 are blue
L6385, blue L6470, red K3580, red K3911HD, red K4180, red K5011).A specific aspect according to the present invention, institute
Stating dispersible pigment color paste is phthalocyanine green G, is purchased from Clariant organic pigment Hostaperm phthalocyanine green G NX green 7.
Some preferred aspects according to the present invention, the nanometer titanium dioxide, the nano zine oxide and the nano-calcium carbonate
The average grain diameter of calcium is respectively 10-50nm.
Some preferred aspects according to the present invention, the organo-silicon compound rub with feeding intake for the natrosol
You are 1 ︰ 0.5-3 of ratio.It is highly preferred that the 1 ︰ 1-2 of molar ratio of the organo-silicon compound and the natrosol.
Some preferred aspects according to the present invention, the organo-silicon compound are selected from polyether-modified polydimethylsiloxanes
Alkane, N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane and N- (β-aminoethyl)-γ-aminopropyltriethoxy diethoxy
One of silane or a variety of combinations.
It is further preferred that the organo-silicon compound are selected from polyether-modified dimethyl silicone polymer, N- (β-ammonia second
Base) at least two in-γ-aminopropyltriethoxy dimethoxysilane and N- (β-aminoethyl)-γ-aminopropyltriethoxy diethoxy silane
The combination of kind.
Some preferred aspects according to the present invention, it is the wetting dispersing agent and the nanometer titanium dioxide, described nano oxidized
Zinc and total molar ratio of the nanometer calcium carbonate are 0.02-0.1 ︰ 1.It is highly preferred that the wetting dispersing agent is received with described
Total molar ratio of rice titanium dioxide, the nano zine oxide and the nanometer calcium carbonate is 0.04-0.08 ︰ 1.
Some preferred aspects according to the present invention, the coalescing agent are ethylene glycol and/or 2,2,4- trimethyls 1,3- penta
Monoisobutyrate.
Some preferred aspects according to the present invention, the surfactant is by Monododecylphosphate potassium, coconut oil fat
Sour diglycollic amide is combined according to 1 ︰ 1.5-3 of mass ratio.
Some preferred aspects according to the present invention, described adhesive are in peach gum, Arabic gum and guar gum
One or more combinations.It is highly preferred that described adhesive is at least two in peach gum, Arabic gum and guar gum
Combination.
Some preferred aspects according to the present invention, the thickener are triethanolamine.
More according to the present invention specific and preferred aspect, in terms of mass percentage, in the raw material, the pigment
Mill base accounts for 8-22%, the clay accounts for 2-6%, the nanometer titanium dioxide accounts for 1-5%, the nano zine oxide accounts for 1-5%, described
Nanometer calcium carbonate accounts for 2-6%, described adhesive accounts for 10-20%, the coalescing agent accounts for 3-8%, the surfactant accounts for 2-
6%, the thickener accounts for 2-5%, the wetting dispersing agent accounts for 0.5-5%, the fungicide 1-3% is accounted for and the water accounts for 30-
50%.
Another technical solution provided by the invention: a kind of preparation method of drawing gouache color described above, the system
Preparation Method includes the following steps: to weigh each raw material by formula rate, by the dispersible pigment color paste, the clay, the Nanometer Titanium Dioxide
Powder, the nano zine oxide, the nanometer calcium carbonate, part described adhesive, the wetting dispersing agent, the part surface are living
Property agent and water mixing, then by remaining described adhesive, the remaining surfactant, the thickener, described
Coalescing agent and the fungicide are added, and the drawing gouache color is made in mixing.
Due to the use of above technical scheme, the invention has the following advantages over the prior art:
The present invention is compounded by the nano zine oxide and nanometer calcium carbonate of special ratios with nanometer titanium dioxide, in combination with spy
Fixed wetting dispersing agent, so that the drawing gouache color of preparation is not easy in high and low temperature alternative, alternation of wetting and drying, winter alternates with summer environment
It cracks, be not easy mouldy, and be also able to maintain preferable color, covering power is strong, and then may insure the permanent of drawing gouache color
It is durable, it is suitble to the application of mural painting under outdoor environment.
Specific embodiment
Above scheme is described further below in conjunction with specific embodiment；It should be understood that these embodiments are for illustrating
The basic principles, principal features and advantages of the present invention, and the present invention is not by the scope limitation of following embodiment；It is used in embodiment
Implementation condition further adjustment can be done according to specific requirement, the implementation condition being not specified is usually the item in routine experiment
Part.
In following, unless otherwise specified, all raw materials are both from conventional method system commercially available or by this field
It is standby and obtain.In following embodiments, fungicide is purchased from the NK-201 of Changzhou Xin Nuoke Chemical Co., Ltd., and polyether-modified is poly-
Dimethyl siloxane is the BYK-UV3510 of Germany Bi Ke；Phthalocyanine green G is purchased from Clariant organic pigment Hostaperm phthalein
Dark green GNX green 7, it is following described in nanometer titanium dioxide, the nano zine oxide and the nanometer calcium carbonate average grain diameter difference
For 40nm.
Embodiment 1
The present embodiment provides a kind of drawing gouache color, composition of raw materials includes: 15 parts of phthalocyanine green G, 4 parts of clay, nano-titanium
3 parts of white powder, 3 parts of nano zine oxide, 4 parts of nanometer calcium carbonate, 10 parts of peach gum, 5 parts of Arabic gum, 5 parts of ethylene glycol, single dodecyl
1.3 parts of phosphate potassium, 2.7 parts of fatty acid distribution of coconut oil diglycollic amide, 3.4 parts of triethanolamine, polyether-modified polydimethylsiloxanes
0.15 part of alkane, 0.3 part of natrosol, kills at 0.15 part of N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane
2 parts and 41 parts of water of microbial inoculum.
Preparation method includes: to weigh above-mentioned each raw material by formula rate, by the phthalocyanine green G, the clay, the nanometer
Titanium dioxide, the nano zine oxide, the nanometer calcium carbonate, 1/2 peach gum, 1/2 Arabic gum, the polyethers
Modified dimethyl silicone polymer, the N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, the cellulose hydroxyl
Ethylether, the 1/2 Monododecylphosphate potassium, the 1/2 fatty acid distribution of coconut oil diglycollic amide and water mixing,
Then by the remaining peach gum, the remaining Arabic gum, the remaining Monododecylphosphate potassium, remaining institute
It states fatty acid distribution of coconut oil diglycollic amide, the triethanolamine, the ethylene glycol and the fungicide to be added, mixing, is made described
Drawing gouache color.
Embodiment 2
The present embodiment provides a kind of drawing gouache color, composition of raw materials includes: 14 parts of phthalocyanine green G, 4 parts of clay, nano-titanium
4 parts of white powder, 3 parts of nano zine oxide, 4 parts of nanometer calcium carbonate, 8 parts of peach gum, 7 parts of Arabic gum, 5 parts of ethylene glycol, single dodecyl
1 part of phosphate potassium, 3 parts of fatty acid distribution of coconut oil diglycollic amide, 2.2 parts of triethanolamine, polyether-modified dimethyl silicone polymer
0.15 part, 0.17 part of N- (β-aminoethyl)-γ-aminopropyltriethoxy diethoxy silane, 0.48 part of natrosol, sterilization
2 parts and 42 parts of water of agent.
Preparation method includes: to weigh above-mentioned each raw material by formula rate, by the phthalocyanine green G, the clay, the nanometer
Titanium dioxide, the nano zine oxide, the nanometer calcium carbonate, 1/2 peach gum, 1/2 Arabic gum, the polyethers
Modified dimethyl silicone polymer, the N- (β-aminoethyl)-γ-aminopropyltriethoxy diethoxy silane, the cellulose hydroxyl
Ethylether, the 1/3 Monododecylphosphate potassium, the 1/2 fatty acid distribution of coconut oil diglycollic amide and water mixing,
Then by the remaining peach gum, the remaining Arabic gum, the remaining Monododecylphosphate potassium, remaining institute
It states fatty acid distribution of coconut oil diglycollic amide, the triethanolamine, the ethylene glycol and the fungicide to be added, mixing, is made described
Drawing gouache color.
Embodiment 3
The present embodiment provides a kind of drawing gouache color, composition of raw materials includes: 17 parts of phthalocyanine green G, 4 parts of clay, nano-titanium
4 parts of white powder, 4 parts of nano zine oxide, 4 parts of nanometer calcium carbonate, 5 parts of peach gum, 9 parts of guar gum, 4 parts of ethylene glycol, single dodecyl
1.6 parts of phosphate potassium, 2.4 parts of fatty acid distribution of coconut oil diglycollic amide, 3.04 parts of triethanolamine, polyether-modified polydimethylsiloxanes
0.17 part of alkane, 0.64 part of natrosol, kills at 0.15 part of N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane
2 parts and 39 parts of water of microbial inoculum.
Preparation method includes: to weigh above-mentioned each raw material by formula rate, by the phthalocyanine green G, the clay, the nanometer
Titanium dioxide, the nano zine oxide, the nanometer calcium carbonate, 1/3 peach gum, 1/3 guar gum, the polyethers
Modified dimethyl silicone polymer, the N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, the cellulose hydroxyl
Ethylether, the 1/2 Monododecylphosphate potassium, the 1/2 fatty acid distribution of coconut oil diglycollic amide and water mixing,
Then by the remaining peach gum, the remaining guar gum, the remaining Monododecylphosphate potassium, remaining institute
It states fatty acid distribution of coconut oil diglycollic amide, the triethanolamine, the ethylene glycol and the fungicide to be added, mixing, is made described
Drawing gouache color.
Comparative example 1
Substantially with embodiment 1, difference, which is only that in raw material, is not added nano zine oxide, nanometer calcium carbonate.
Comparative example 2
Substantially with embodiment 1, difference, which is only that in raw material, is not added nano zine oxide.
Comparative example 3
Substantially with embodiment 1, difference, which is only that in raw material, is not added nanometer calcium carbonate.
Comparative example 4
Substantially with embodiment 1, difference is only that in raw material that natrosol is only added in wetting dispersing agent.
Application Example
Drawing gouache color obtained by above-described embodiment 1-3 and comparative example 1-4 is used to outdoor wall to draw a picture, one
The situation of change of continuous observation monitoring drawing gouache color film layer, it is as shown in table 1 below to measure its each performance in year.
In following, severe cracking: I, general to crack: II, slight to crack: III, no cracking: IV.
Severe is mouldy: i, general mouldy: II, slight mouldy: iii, without mouldy: IV.
Table 1
Color difference △ E: it is measured by color difference meter.
Gloss retention: hand-held Grossmeters is reached by style, angle is 60 degree, and bottom plate is blackboard.
Simulate outdoor environment and carry out cold cycling treatment: the simulated assembly sample of 3 300mm × 300mm of preparation is (in cement
Draw a picture on base substrate), high low temperature cycles test is carried out under conditions of placing it in -45 DEG C~85 DEG C.Warm variable Rate is no more than 30
DEG C/h, 1h is at least kept at -45 DEG C and 75 DEG C, the one cycle period is no more than 10h, carries out 400 cycle periods altogether.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention, it is all according to the present invention
Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of drawing gouache color, raw material includes dispersible pigment color paste, clay, nanometer titanium dioxide, adhesive, coalescing agent, table
Face activating agent, thickener, wetting dispersing agent, fungicide and water, which is characterized in that the raw material further includes nano zine oxide, receives
Rice calcium carbonate, the molar ratio of the nanometer titanium dioxide, the nano zine oxide and the nanometer calcium carbonate are 0.5-2 ︰
0.5-2 ︰ 1, the wetting dispersing agent by intramolecular contain hydrophilic group and at least containing there are two hydrophobic group organo-silicon compound with
Natrosol composition, the 1 ︰ 0.5-5 of molar ratio of the organo-silicon compound and the natrosol.
2. drawing gouache color according to claim 1, which is characterized in that the nanometer titanium dioxide, described nano oxidized
The average grain diameter of zinc and the nanometer calcium carbonate is respectively 10-50nm.
3. drawing gouache color according to claim 1, which is characterized in that the organo-silicon compound are to change selected from polyethers
Dimethyl silicone polymer, N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane and N- (β-aminoethyl)-γ-ammonia of property
One of hydroxypropyl methyl diethoxy silane or a variety of combinations.
4. drawing gouache color according to claim 3, which is characterized in that the organo-silicon compound are to change selected from polyethers
Dimethyl silicone polymer, N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane and N- (β-aminoethyl)-γ-ammonia of property
At least two combination in hydroxypropyl methyl diethoxy silane.
5. drawing gouache color according to claim 1, which is characterized in that the wetting dispersing agent and the Nanometer Titanium Dioxide
Total molar ratio of powder, the nano zine oxide and the nanometer calcium carbonate is 0.02-0.1 ︰ 1.
6. drawing gouache color according to claim 1, which is characterized in that the coalescing agent be ethylene glycol and/or 2,
2,4- trimethyl 1,3- pentanediol mono isobutyrate.
7. drawing gouache color according to claim 1, which is characterized in that the surfactant is by single dodecyl phosphorus
Acid esters potassium, fatty acid distribution of coconut oil diglycollic amide are combined according to 1 ︰ 1.5-3 of mass ratio.
8. drawing gouache color according to claim 1, which is characterized in that described adhesive is selected from peach gum, Arab
One of glue and guar gum or a variety of combinations；And/or the thickener is triethanolamine.
9. drawing gouache color according to claim 1, which is characterized in that in terms of mass percentage, in the raw material,
The dispersible pigment color paste accounts for 8-22%, the clay accounts for 2-6%, the nanometer titanium dioxide accounts for 1-5%, the nano zine oxide accounts for 1-5%,
The nanometer calcium carbonate accounts for 2-6%, described adhesive accounts for 10-20%, the coalescing agent accounts for 3-8%, the surfactant accounts for 2-
6%, the thickener accounts for 2-5%, the wetting dispersing agent accounts for 0.5-5%, the fungicide 1-3% is accounted for and the water accounts for 30-50%.
10. the preparation method for gouache color of painting described in a kind of any one of claim 1-9 claim, feature exist
In the preparation method includes the following steps: to weigh each raw material by formula rate, by the dispersible pigment color paste, clay, described
Nanometer titanium dioxide, the nano zine oxide, the nanometer calcium carbonate, part described adhesive, the wetting dispersing agent, part institute
Surfactant and water mixing are stated, then by remaining described adhesive, the remaining surfactant, the thickening
Agent, the coalescing agent and the fungicide are added, and the drawing gouache color is made in mixing.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115960494A (en) * | 2023-02-20 | 2023-04-14 | 杭州米娅嗨米文化有限公司 | Application of ionic liquid, pigment and preparation method of pigment |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221343A (en) * | 2016-08-09 | 2016-12-14 | 苏州冰心文化用品有限公司 | A kind of nanoscale weather-proof drawing gouache color and preparation method thereof |
| CN107163651A (en) * | 2017-04-11 | 2017-09-15 | 苏州冰心文化用品有限公司 | A kind of durable nanometer assistant agent oil colour of anti-mildew and preparation method |
-
2018
- 2018-07-10 CN CN201810749503.7A patent/CN109082150A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221343A (en) * | 2016-08-09 | 2016-12-14 | 苏州冰心文化用品有限公司 | A kind of nanoscale weather-proof drawing gouache color and preparation method thereof |
| CN107163651A (en) * | 2017-04-11 | 2017-09-15 | 苏州冰心文化用品有限公司 | A kind of durable nanometer assistant agent oil colour of anti-mildew and preparation method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115960494A (en) * | 2023-02-20 | 2023-04-14 | 杭州米娅嗨米文化有限公司 | Application of ionic liquid, pigment and preparation method of pigment |
| CN115960494B (en) * | 2023-02-20 | 2023-12-15 | 杭州米娅嗨米文化有限公司 | Application of ionic liquid, pigment and preparation method thereof |
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