CN109082067A - A kind of light-weight environment-friendly ear tag and preparation method thereof - Google Patents
A kind of light-weight environment-friendly ear tag and preparation method thereof Download PDFInfo
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- CN109082067A CN109082067A CN201810961919.5A CN201810961919A CN109082067A CN 109082067 A CN109082067 A CN 109082067A CN 201810961919 A CN201810961919 A CN 201810961919A CN 109082067 A CN109082067 A CN 109082067A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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Abstract
The present invention provides a kind of light-weight environment-friendly ear tag and preparation method thereof; it is related to ear tag technical field, light-weight environment-friendly ear tag includes the raw material of following parts by weight: ABS resin, ACR resin, PE wax, titanium dioxide, PVC-SG5 resin, nm-class active calcium carbonate, expanded and vitrified small ball, floating bead, active carbon, nano zine oxide, tourmaline powder, corn stover, ceramic matric composite, stabilizer, antioxidant, compatilizer, plasticizer and curing agent；Preparation method is the following steps are included: (1) weighs raw material；(2) ball mill mixing is prepared；(3) mixture a is prepared；(4) mixture b is prepared；(5) it squeezes, be molded；Ear tag produced by the present invention has the advantages that lightweight, environmental protection and corrosion resistant.
Description
Technical field:
The invention belongs to ear tag technical fields, and in particular to a kind of light-weight environment-friendly ear tag and preparation method thereof.
Background technique:
Ear tag is one of mark of animal, for proving the identity of livestock, carries the mark of livestock individual information, be affixed by
Livestock ear.
The material for making ear tag is mostly plastics, and the processing mode of plastics is predominantly filled and burned, and pollutes environment, Ying Xun
Other environment-friendly materials are looked for reduce the usage amount of plastics.
Since the environment of livestock life is mostly environment damp and hot, that air permeability is poor, bacterium easy to breed and bad smell is issued,
Ear tag on existing livestock reduces the service life of ear tag normal use in this environment using being easy to be corroded.
Further, since ear tag is mounted on the ear of livestock more, if overweight be easy to cause to damage to livestock, especially in livestock
During the external world is put in a suitable place to breed.
Summary of the invention:
In order to solve the above technical problem, the present invention provides a kind of light-weight environment-friendly ear tag and preparation method thereof, ears obtained
Mark has the advantages that lightweight, environmental protection and corrosion resistant.
The present invention provides the following technical solutions:
A kind of light-weight environment-friendly ear tag, the raw material including following parts by weight: 60-80 parts of ABS resin, 50-70 parts of ACR resin,
0.8-1.2 parts of PE wax, 1-3 parts of titanium dioxide, 45-53 parts of PVC-SG5 resin, 10-20 parts of nm-class active calcium carbonate, expansion vitrification are micro-
12-16 parts of pearl, 9-13 parts of floating bead, 2-5 parts of active carbon, 4-8 parts of nano zine oxide, 10-12 parts of tourmaline powder, corn stover 3-5
Part, 6-14 parts of ceramic matric composite, 0.3-0.5 parts of stabilizer, 0.2-0.4 parts of antioxidant, 0.2-0.6 parts of compatilizer, plasticising
0.1-0.5 parts and curing agent 0.3-0.7 parts of agent.
PE wax is added in raw material, PE wax has good lubricant effect, can improve the release property of resin.
It is added to titanium dioxide in raw material, has the characteristics that sterilization, antifouling, deodorization, nontoxic and performance are stable.
Be added to nm-class active calcium carbonate in raw material, nanometer silicon carbide have good fire resistance, large specific surface area, hardness it is high,
The feature that wearability is good and thermal coefficient is low.
Expanded and vitrified small ball, expanded and vitrified small ball internal porous, surface vitreous closing, with lightweight are added in raw material
The characteristics of.
Floating bead is added in raw material, floating bead has the advantages that light, intensity is high, wear-resisting and resistant to high temperature.
Active carbon is added in raw material, active carbon is porous structure, can purify air.
Nano zine oxide is added in raw material, nano zine oxide there can be the growth for inhibiting bacterium as anti-biotic material.
Tourmaline powder is added in raw material, tourmaline powder can discharge negative aeroion, help to purify air.
Corn stover is added in raw material, corn stover achievees the purpose that cycling and reutilization as Wastes of Crops, reduces
The dosages of plastics.
Be added to ceramic matric composite in raw material, ceramic matric composite has high temperature resistant, wearability is good, intensity is high and
The advantages of good corrosion resistance.
Preferably, the raw material including following parts by weight: 65 parts of ABS resin, 50 parts of ACR resin, 0.8 part of PE wax, titanium dioxide 2
Part, 49 parts of PVC-SG5 resin, 12 parts of nm-class active calcium carbonate, 13 parts of expanded and vitrified small ball, 9 parts of floating bead, active carbon 5 part, nanometer
8 parts of zinc oxide, 12 parts of tourmaline powder, 3 parts of corn stover, 6 parts of ceramic matric composite, 0.3 part of stabilizer, 0.4 part of antioxidant,
0.3 part of compatilizer, 0.2 part of plasticizer and 0.4 part of curing agent.
Preferably, the raw material including following parts by weight: 70 parts of ABS resin, 60 parts of ACR resin, 1 part of PE wax, titanium dioxide 2
Part, 49 parts of PVC-SG5 resin, 15 parts of nm-class active calcium carbonate, 14 parts of expanded and vitrified small ball, 11 parts of floating bead, 3.5 parts of active carbon,
6 parts of nano zine oxide, 11 parts of tourmaline powder, 4 parts of corn stover, 10 parts of ceramic matric composite, 0.4 part of stabilizer, antioxidant
0.3 part, 0.4 part of compatilizer, 0.3 part of plasticizer and 0.5 part of curing agent.
Preferably, the stabilizer is odium stearate.
Preferably, the antioxidant is antioxidant 1076 or antioxidant 164.
Preferably, the compatilizer is maleic anhydride graft compatilizer.
Preferably, the plasticizer is dioctyl phthalate.
Preferably, the curing agent is diaminodiphenylmethane.
A kind of preparation method of light-weight environment-friendly ear tag, comprising the following steps:
(1) raw material is weighed according to the parts by weight of light-weight environment-friendly ear tag raw material；
(2) expanded and vitrified small ball, floating bead, active carbon and corn stover are uniformly mixed, and are put into ball mill, Ball-milling Time is
8-12h, ball milling temperature are 20-30 DEG C, and revolving speed is 500-700r/min, and being milled to powder diameter is 200-300 mesh to get ball milling
Mixing；
(3) ABS resin, ACR resin, PVC-SG5 resin, PE wax, stabilizer and antioxidant are added to mixing and blending machine
In, 20-30min is mixed under the conditions of 70-80 DEG C, obtains mixture a；
(4) addition of titanium dioxide, nm-class active calcium carbonate, nano zine oxide, tourmaline powder and ceramic matric composite is stirred
It mixes in machine, 10-20min is mixed under the conditions of 80-100 DEG C, obtain mixture b；；
(5) by the ball mill mixing in step (2), the mixture a in step (3), the mixture b in step (4) and residue
Raw material is put into centrifuge, and revolving speed is 1000-1200r/min, and stirring 20-40min enters back into twin-screw after mixing
Extruder is squeezed into molten condition, is expressed into injection molding machine after mixing melts completely, the injection molding at 300 DEG C.
Compared with prior art, the beneficial effects of the present invention are:
1, ear tag produced by the present invention has the advantages that lightweight, environmental protection and corrosion resistant.
2, heretofore described stabilizer is odium stearate, is conducive to the stability of material for improving ear tag.
3, heretofore described antioxidant be antioxidant 1076 or antioxidant 164, can delay or inhibit ear tag aoxidize into
Row, to prevent ear tag aging and prolong its service life.
4, heretofore described compatilizer promotes not phase by intermolecular bonding force for maleic anhydride graft compatilizer
The two kinds of polymer of appearance is combined together, and then achievees the purpose that stabilized blends.
5, heretofore described plasticizer is dioctyl phthalate, so that the ear tag plasticizing effect enhancing of preparation, also
Enhance its flexibility, is more easier to process.
6, heretofore described curing agent is diaminodiphenylmethane, the lightweight ring after diaminodiphenylmethane solidifies
Ear tag is protected, lightweight and corrosion resistance are enhanced.
Specific embodiment:
Embodiment 1
A kind of light-weight environment-friendly ear tag, the raw material including following weight: ABS resin 65kg, ACR resin 50kg, PE wax
0.8kg, titanium dioxide 2kg, PVC-SG5 resin 49kg, nm-class active calcium carbonate 12kg, expanded and vitrified small ball 13kg, floating bead 9kg,
Active carbon 5kg, nano zine oxide 8kg, tourmaline powder 12kg, corn stover 3kg, ceramic matric composite 6kg, stabilizer
0.3kg, antioxidant 0.4kg, compatilizer 0.3kg, plasticizer 0.2kg and curing agent 0.4kg.
PE wax is added in raw material, PE wax has good lubricant effect, can improve the release property of resin.
It is added to titanium dioxide in raw material, has the characteristics that sterilization, antifouling, deodorization, nontoxic and performance are stable.
Be added to nm-class active calcium carbonate in raw material, nanometer silicon carbide have good fire resistance, large specific surface area, hardness it is high,
The feature that wearability is good and thermal coefficient is low.
Expanded and vitrified small ball, expanded and vitrified small ball internal porous, surface vitreous closing, with lightweight are added in raw material
The characteristics of.
Floating bead is added in raw material, floating bead has the advantages that light, intensity is high, wear-resisting and resistant to high temperature.
Active carbon is added in raw material, active carbon is porous structure, can purify air.
Nano zine oxide is added in raw material, nano zine oxide there can be the growth for inhibiting bacterium as anti-biotic material.
Tourmaline powder is added in raw material, tourmaline powder can discharge negative aeroion, help to purify air.
Corn stover is added in raw material, corn stover achievees the purpose that cycling and reutilization as Wastes of Crops, reduces
The dosages of plastics.
Be added to ceramic matric composite in raw material, ceramic matric composite has high temperature resistant, wearability is good, intensity is high and
The advantages of good corrosion resistance.
A kind of preparation method of light-weight environment-friendly ear tag, comprising the following steps:
(1) raw material is weighed according to the weight of light-weight environment-friendly ear tag raw material；
(2) expanded and vitrified small ball, floating bead, active carbon and corn stover are uniformly mixed, and are put into ball mill, Ball-milling Time is
8-12h, ball milling temperature are 20-30 DEG C, and revolving speed is 500-700r/min, and being milled to powder diameter is 200-300 mesh to get ball milling
Mixing；
(3) ABS resin, ACR resin, PVC-SG5 resin, PE wax, stabilizer and antioxidant are added to mixing and blending machine
In, 20-30min is mixed under the conditions of 70-80 DEG C, obtains mixture a；
(4) addition of titanium dioxide, nm-class active calcium carbonate, nano zine oxide, tourmaline powder and ceramic matric composite is stirred
It mixes in machine, 10-20min is mixed under the conditions of 80-100 DEG C, obtain mixture b；；
(5) by the ball mill mixing in step (2), the mixture a in step (3), the mixture b in step (4) and residue
Raw material is put into centrifuge, and revolving speed is 1000-1200r/min, and stirring 20-40min enters back into twin-screw after mixing
Extruder is squeezed into molten condition, is expressed into injection molding machine after mixing melts completely, the injection molding at 300 DEG C.
Stabilizer is odium stearate, is conducive to the stability of material for improving ear tag.
Antioxidant is antioxidant 1076 or antioxidant 164, the progress that can delay or inhibit ear tag to aoxidize, to prevent ear tag
Aging simultaneously prolongs its service life.
Compatilizer is maleic anhydride graft compatilizer, by intermolecular bonding force, promotes incompatible two kinds of polymer
It is combined together, and then achievees the purpose that stabilized blends.
Plasticizer is dioctyl phthalate, so that the ear tag plasticizing effect enhancing of preparation, also enhances its flexibility,
It is more easier to process.
Curing agent is diaminodiphenylmethane, the light-weight environment-friendly ear tag after diaminodiphenylmethane solidifies, lightweight
Enhanced with corrosion resistance.
Ear tag produced by the present invention has the advantages that lightweight, environmental protection and corrosion resistant.
Embodiment 2
A kind of light-weight environment-friendly ear tag, the raw material including following weight: ABS resin 60kg, ACR resin 50kg, PE wax
0.8kg, titanium dioxide 1kg, PVC-SG5 resin 45kg, nm-class active calcium carbonate 10kg, expanded and vitrified small ball 12kg, floating bead 9kg,
Active carbon 2kg, nano zine oxide 4kg, tourmaline powder 10kg, corn stover 3kg, ceramic matric composite 6kg, stabilizer
0.3kg, antioxidant 0.2kg, compatilizer 0.2kg, plasticizer 0.1kg and curing agent 0.3kg.
PE wax is added in raw material, PE wax has good lubricant effect, can improve the release property of resin.
It is added to titanium dioxide in raw material, has the characteristics that sterilization, antifouling, deodorization, nontoxic and performance are stable.
Be added to nm-class active calcium carbonate in raw material, nanometer silicon carbide have good fire resistance, large specific surface area, hardness it is high,
The feature that wearability is good and thermal coefficient is low.
Expanded and vitrified small ball, expanded and vitrified small ball internal porous, surface vitreous closing, with lightweight are added in raw material
The characteristics of.
Floating bead is added in raw material, floating bead has the advantages that light, intensity is high, wear-resisting and resistant to high temperature.
Active carbon is added in raw material, active carbon is porous structure, can purify air.
Nano zine oxide is added in raw material, nano zine oxide there can be the growth for inhibiting bacterium as anti-biotic material.
Tourmaline powder is added in raw material, tourmaline powder can discharge negative aeroion, help to purify air.
Corn stover is added in raw material, corn stover achievees the purpose that cycling and reutilization as Wastes of Crops, reduces
The dosages of plastics.
Be added to ceramic matric composite in raw material, ceramic matric composite has high temperature resistant, wearability is good, intensity is high and
The advantages of good corrosion resistance.
A kind of preparation method of light-weight environment-friendly ear tag, comprising the following steps:
(1) raw material is weighed according to the weight of light-weight environment-friendly ear tag raw material；
(2) expanded and vitrified small ball, floating bead, active carbon and corn stover are uniformly mixed, and are put into ball mill, Ball-milling Time is
8-12h, ball milling temperature are 20-30 DEG C, and revolving speed is 500-700r/min, and being milled to powder diameter is 200-300 mesh to get ball milling
Mixing；
(3) ABS resin, ACR resin, PVC-SG5 resin, PE wax, stabilizer and antioxidant are added to mixing and blending machine
In, 20-30min is mixed under the conditions of 70-80 DEG C, obtains mixture a；
(4) addition of titanium dioxide, nm-class active calcium carbonate, nano zine oxide, tourmaline powder and ceramic matric composite is stirred
It mixes in machine, 10-20min is mixed under the conditions of 80-100 DEG C, obtain mixture b；；
(5) by the ball mill mixing in step (2), the mixture a in step (3), the mixture b in step (4) and residue
Raw material is put into centrifuge, and revolving speed is 1000-1200r/min, and stirring 20-40min enters back into twin-screw after mixing
Extruder is squeezed into molten condition, is expressed into injection molding machine after mixing melts completely, the injection molding at 300 DEG C.
Stabilizer is odium stearate, is conducive to the stability of material for improving ear tag.
Antioxidant is antioxidant 1076 or antioxidant 164, the progress that can delay or inhibit ear tag to aoxidize, to prevent ear tag
Aging simultaneously prolongs its service life.
Compatilizer is maleic anhydride graft compatilizer, by intermolecular bonding force, promotes incompatible two kinds of polymer
It is combined together, and then achievees the purpose that stabilized blends.
Plasticizer is dioctyl phthalate, so that the ear tag plasticizing effect enhancing of preparation, also enhances its flexibility,
It is more easier to process.
Curing agent is diaminodiphenylmethane, the light-weight environment-friendly ear tag after diaminodiphenylmethane solidifies, lightweight
Enhanced with corrosion resistance.
Ear tag produced by the present invention has the advantages that lightweight, environmental protection and corrosion resistant.
Embodiment 3
A kind of light-weight environment-friendly ear tag, the raw material including following weight: ABS resin 80kg, ACR resin 70kg, PE wax
1.2kg, titanium dioxide 3kg, PVC-SG5 resin 53kg, nm-class active calcium carbonate 20kg, expanded and vitrified small ball 16kg, floating bead 13kg,
Active carbon 5kg, nano zine oxide 8kg, tourmaline powder 12kg, corn stover 5kg, ceramic matric composite 14kg, stabilizer
0.5kg, antioxidant 0.4kg, compatilizer 0.6kg, plasticizer 0.5kg and curing agent 0.7kg.
PE wax is added in raw material, PE wax has good lubricant effect, can improve the release property of resin.
It is added to titanium dioxide in raw material, has the characteristics that sterilization, antifouling, deodorization, nontoxic and performance are stable.
Be added to nm-class active calcium carbonate in raw material, nanometer silicon carbide have good fire resistance, large specific surface area, hardness it is high,
The feature that wearability is good and thermal coefficient is low.
Expanded and vitrified small ball, expanded and vitrified small ball internal porous, surface vitreous closing, with lightweight are added in raw material
The characteristics of.
Floating bead is added in raw material, floating bead has the advantages that light, intensity is high, wear-resisting and resistant to high temperature.
Active carbon is added in raw material, active carbon is porous structure, can purify air.
Nano zine oxide is added in raw material, nano zine oxide there can be the growth for inhibiting bacterium as anti-biotic material.
Tourmaline powder is added in raw material, tourmaline powder can discharge negative aeroion, help to purify air.
Corn stover is added in raw material, corn stover achievees the purpose that cycling and reutilization as Wastes of Crops, reduces
The dosages of plastics.
Be added to ceramic matric composite in raw material, ceramic matric composite has high temperature resistant, wearability is good, intensity is high and
The advantages of good corrosion resistance.
A kind of preparation method of light-weight environment-friendly ear tag, comprising the following steps:
(1) raw material is weighed according to the weight of light-weight environment-friendly ear tag raw material；
(2) expanded and vitrified small ball, floating bead, active carbon and corn stover are uniformly mixed, and are put into ball mill, Ball-milling Time is
8-12h, ball milling temperature are 20-30 DEG C, and revolving speed is 500-700r/min, and being milled to powder diameter is 200-300 mesh to get ball milling
Mixing；
(3) ABS resin, ACR resin, PVC-SG5 resin, PE wax, stabilizer and antioxidant are added to mixing and blending machine
In, 20-30min is mixed under the conditions of 70-80 DEG C, obtains mixture a；
(4) addition of titanium dioxide, nm-class active calcium carbonate, nano zine oxide, tourmaline powder and ceramic matric composite is stirred
It mixes in machine, 10-20min is mixed under the conditions of 80-100 DEG C, obtain mixture b；；
(5) by the ball mill mixing in step (2), the mixture a in step (3), the mixture b in step (4) and residue
Raw material is put into centrifuge, and revolving speed is 1000-1200r/min, and stirring 20-40min enters back into twin-screw after mixing
Extruder is squeezed into molten condition, is expressed into injection molding machine after mixing melts completely, the injection molding at 300 DEG C.
Stabilizer is odium stearate, is conducive to the stability of material for improving ear tag.
Antioxidant is antioxidant 1076 or antioxidant 164, the progress that can delay or inhibit ear tag to aoxidize, to prevent ear tag
Aging simultaneously prolongs its service life.
Compatilizer is maleic anhydride graft compatilizer, by intermolecular bonding force, promotes incompatible two kinds of polymer
It is combined together, and then achievees the purpose that stabilized blends.
Plasticizer is dioctyl phthalate, so that the ear tag plasticizing effect enhancing of preparation, also enhances its flexibility,
It is more easier to process.
Curing agent is diaminodiphenylmethane, the light-weight environment-friendly ear tag after diaminodiphenylmethane solidifies, lightweight
Enhanced with corrosion resistance.
Ear tag produced by the present invention has the advantages that lightweight, environmental protection and corrosion resistant.
Embodiment 4
A kind of light-weight environment-friendly ear tag, the raw material including following weight: ABS resin 70kg, ACR resin 60kg, PE wax 1kg,
Titanium dioxide 2kg, PVC-SG5 resin 49kg, nm-class active calcium carbonate 15kg, expanded and vitrified small ball 14kg, floating bead 11kg, active carbon
3.5kg, nano zine oxide 6kg, tourmaline powder 11kg, corn stover 4kg, ceramic matric composite 10kg, stabilizer 0.4kg,
Antioxidant 0.3kg, compatilizer 0.4kg, plasticizer 0.3kg and curing agent 0.5kg.
PE wax is added in raw material, PE wax has good lubricant effect, can improve the release property of resin.
It is added to titanium dioxide in raw material, has the characteristics that sterilization, antifouling, deodorization, nontoxic and performance are stable.
Be added to nm-class active calcium carbonate in raw material, nanometer silicon carbide have good fire resistance, large specific surface area, hardness it is high,
The feature that wearability is good and thermal coefficient is low.
Expanded and vitrified small ball, expanded and vitrified small ball internal porous, surface vitreous closing, with lightweight are added in raw material
The characteristics of.
Floating bead is added in raw material, floating bead has the advantages that light, intensity is high, wear-resisting and resistant to high temperature.
Active carbon is added in raw material, active carbon is porous structure, can purify air.
Nano zine oxide is added in raw material, nano zine oxide there can be the growth for inhibiting bacterium as anti-biotic material.
Tourmaline powder is added in raw material, tourmaline powder can discharge negative aeroion, help to purify air.
Corn stover is added in raw material, corn stover achievees the purpose that cycling and reutilization as Wastes of Crops, reduces
The dosages of plastics.
Be added to ceramic matric composite in raw material, ceramic matric composite has high temperature resistant, wearability is good, intensity is high and
The advantages of good corrosion resistance.
A kind of preparation method of light-weight environment-friendly ear tag, comprising the following steps:
(1) raw material is weighed according to the weight of light-weight environment-friendly ear tag raw material；
(2) expanded and vitrified small ball, floating bead, active carbon and corn stover are uniformly mixed, and are put into ball mill, Ball-milling Time is
8-12h, ball milling temperature are 20-30 DEG C, and revolving speed is 500-700r/min, and being milled to powder diameter is 200-300 mesh to get ball milling
Mixing；
(3) ABS resin, ACR resin, PVC-SG5 resin, PE wax, stabilizer and antioxidant are added to mixing and blending machine
In, 20-30min is mixed under the conditions of 70-80 DEG C, obtains mixture a；
(4) addition of titanium dioxide, nm-class active calcium carbonate, nano zine oxide, tourmaline powder and ceramic matric composite is stirred
It mixes in machine, 10-20min is mixed under the conditions of 80-100 DEG C, obtain mixture b；；
(5) by the ball mill mixing in step (2), the mixture a in step (3), the mixture b in step (4) and residue
Raw material is put into centrifuge, and revolving speed is 1000-1200r/min, and stirring 20-40min enters back into twin-screw after mixing
Extruder is squeezed into molten condition, is expressed into injection molding machine after mixing melts completely, the injection molding at 300 DEG C.
Stabilizer is odium stearate, is conducive to the stability of material for improving ear tag.
Antioxidant is antioxidant 1076 or antioxidant 164, the progress that can delay or inhibit ear tag to aoxidize, to prevent ear tag
Aging simultaneously prolongs its service life.
Compatilizer is maleic anhydride graft compatilizer, by intermolecular bonding force, promotes incompatible two kinds of polymer
It is combined together, and then achievees the purpose that stabilized blends.
Plasticizer is dioctyl phthalate, so that the ear tag plasticizing effect enhancing of preparation, also enhances its flexibility,
It is more easier to process.
Curing agent is diaminodiphenylmethane, the light-weight environment-friendly ear tag after diaminodiphenylmethane solidifies, lightweight
Enhanced with corrosion resistance.
Ear tag produced by the present invention has the advantages that lightweight, environmental protection and corrosion resistant.
1, ear tag made from embodiment 1, embodiment 2, embodiment 3 and embodiment 4 and existing ear tag on the market are carried out
It is tested for the property, test result is as shown in table 1:
Table 1
2, ear tag made from embodiment 1, embodiment 2, embodiment 3 and embodiment 4 and existing ear tag on the market are soaked
Bubble 30 days in 10% sodium hydroxide solution, then by ear tag made from embodiment 1, embodiment 2, embodiment 3 and embodiment 4 with
And existing ear tag on the market carries out the performance test in table 1 again, test result is as follows shown in table 2:
Table 2
3, ear tag made from embodiment 1, embodiment 2, embodiment 3 and embodiment 4 and existing ear tag on the market are soaked
Bubble is 30 days in 10% sulfuric acid solution, then by ear tag made from embodiment 1, embodiment 2, embodiment 3 and embodiment 4 and now
The ear tag for having on the market carries out the performance test in table 1 again, and test result is as follows shown in table 3:
Table 3
4, it can be seen that the embodiment 1 after soda acid is tested from the data of each index measured, embodiment 2, implement
It is small that example 3 compares the existing ear tag overall performance fall on the market after soda acid is tested with ear tag made from embodiment 4,
And on indices, ear tag made from embodiment 1, embodiment 2, embodiment 3 and embodiment 4 is superior to existing ear on the market
Mark.
5, by mass measurement, ear tag made from embodiment 1, embodiment 2, embodiment 3 and embodiment 4 is than on the market
Ear tag is light.
6, it can be seen that embodiment 1 from the data of each index measured and be superior to embodiment 2, embodiment 3, embodiment 4
With comparative example 1, illustrate the composition of raw materials of light-weight environment-friendly ear tag of the present invention and the reasonability of preparation method.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of light-weight environment-friendly ear tag, which is characterized in that the raw material including following parts by weight: 60-80 parts of ABS resin, ACR resin
50-70 parts, it is 0.8-1.2 parts of PE wax, 1-3 parts of titanium dioxide, 45-53 parts of PVC-SG5 resin, 10-20 parts of nm-class active calcium carbonate, swollen
Swollen glass bead 12-16 parts, 9-13 parts of floating bead, 2-5 parts of active carbon, 4-8 parts of nano zine oxide, 10-12 parts of tourmaline powder, corn
3-5 parts of stalk, 6-14 parts of ceramic matric composite, 0.3-0.5 parts of stabilizer, 0.2-0.4 parts of antioxidant, compatilizer 0.2-0.6
Part, 0.1-0.5 parts of plasticizer and 0.3-0.7 parts of curing agent.
2. light-weight environment-friendly ear tag according to claim 1, which is characterized in that the raw material including following parts by weight: ABS resin
65 parts, 50 parts of ACR resin, 0.8 part of PE wax, 2 parts of titanium dioxide, 49 parts of PVC-SG5 resin, 12 parts of nm-class active calcium carbonate, expansion
13 parts of glass bead, 9 parts of floating bead, 5 parts of active carbon, 8 parts of nano zine oxide, 12 parts of tourmaline powder, 3 parts of corn stover, ceramic base
6 parts of composite material, 0.3 part of stabilizer, 0.4 part of antioxidant, 0.3 part of compatilizer, 0.2 part of plasticizer and 0.4 part of curing agent.
3. light-weight environment-friendly ear tag according to claim 1, which is characterized in that the raw material including following parts by weight: ABS resin
70 parts, 60 parts of ACR resin, 1 part of PE wax, 2 parts of titanium dioxide, 49 parts of PVC-SG5 resin, 15 parts of nm-class active calcium carbonate, expansion glass
Change 14 parts of microballon, 11 parts of floating bead, 3.5 parts of active carbon, 6 parts of nano zine oxide, 11 parts of tourmaline powder, 4 parts of corn stover, ceramic base
10 parts of composite material, 0.4 part of stabilizer, 0.3 part of antioxidant, 0.4 part of compatilizer, 0.3 part of plasticizer and 0.5 part of curing agent.
4. light-weight environment-friendly ear tag according to claim 1, it is characterised in that: the stabilizer is odium stearate.
5. light-weight environment-friendly ear tag according to claim 1, it is characterised in that: the antioxidant is antioxidant 1076 or antioxygen
Agent 164.
6. light-weight environment-friendly ear tag according to claim 1, it is characterised in that: the compatilizer is that maleic anhydride grafting is compatible
Agent.
7. light-weight environment-friendly ear tag according to claim 1, it is characterised in that: the plasticizer is that phthalic acid two is pungent
Ester.
8. light-weight environment-friendly ear tag according to claim 1, it is characterised in that: the curing agent is diaminodiphenylmethane.
9. a kind of preparation method of the light-weight environment-friendly ear tag as described in any one of claim 1-8, which is characterized in that packet
Include following steps:
(1) raw material is weighed according to the parts by weight of light-weight environment-friendly ear tag raw material；
(2) expanded and vitrified small ball, floating bead, active carbon and corn stover are uniformly mixed, and are put into ball mill, Ball-milling Time 8-
12h, ball milling temperature are 20-30 DEG C, and revolving speed is 500-700r/min, and being milled to powder diameter is that 200-300 mesh is mixed to get ball milling
Material；
(3) ABS resin, ACR resin, PVC-SG5 resin, PE wax, stabilizer and antioxidant are added in mixing and blending machine,
20-30min is mixed under the conditions of 70-80 DEG C, obtains mixture a；
(4) blender is added in titanium dioxide, nm-class active calcium carbonate, nano zine oxide, tourmaline powder and ceramic matric composite
In, 10-20min is mixed under the conditions of 80-100 DEG C, obtains mixture b；；
(5) by the ball mill mixing in step (2), the mixture a in step (3), mixture b and surplus stock in step (4)
It puts into centrifuge, revolving speed is 1000-1200r/min, and stirring 20-40min enters back into twin-screw extrusion after mixing
Machine is squeezed into molten condition, is expressed into injection molding machine after mixing melts completely, the injection molding at 300 DEG C.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000041179A1 (en) * | 1998-12-28 | 2000-07-13 | Shishiai-Kabushikigaisha | Precision device |
| CN201788524U (en) * | 2010-05-21 | 2011-04-06 | 中兴通讯股份有限公司 | Animal ear tag |
| CN102040786A (en) * | 2010-12-30 | 2011-05-04 | 佛山市顺德区圆融新材料有限公司 | Antiflaming PVC (poly vinyl chloride)/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
| CN102690510A (en) * | 2012-05-15 | 2012-09-26 | 刘庆 | Animal ear tag capable of performing photoluminescence |
| CN105754281A (en) * | 2016-03-09 | 2016-07-13 | 苏州莱特复合材料有限公司 | ABS (acrylonitrile butadiene styrene) and PVC (polyvinyl chloride) alloy and preparation method thereof |
-
2018
- 2018-08-22 CN CN201810961919.5A patent/CN109082067A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000041179A1 (en) * | 1998-12-28 | 2000-07-13 | Shishiai-Kabushikigaisha | Precision device |
| CN201788524U (en) * | 2010-05-21 | 2011-04-06 | 中兴通讯股份有限公司 | Animal ear tag |
| CN102040786A (en) * | 2010-12-30 | 2011-05-04 | 佛山市顺德区圆融新材料有限公司 | Antiflaming PVC (poly vinyl chloride)/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
| CN102690510A (en) * | 2012-05-15 | 2012-09-26 | 刘庆 | Animal ear tag capable of performing photoluminescence |
| CN105754281A (en) * | 2016-03-09 | 2016-07-13 | 苏州莱特复合材料有限公司 | ABS (acrylonitrile butadiene styrene) and PVC (polyvinyl chloride) alloy and preparation method thereof |
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