CN109055863A - A kind of the low-carbon alloy Steel material and heat treatment method of oil drilling hook - Google Patents
A kind of the low-carbon alloy Steel material and heat treatment method of oil drilling hook Download PDFInfo
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- CN109055863A CN109055863A CN201811087358.7A CN201811087358A CN109055863A CN 109055863 A CN109055863 A CN 109055863A CN 201811087358 A CN201811087358 A CN 201811087358A CN 109055863 A CN109055863 A CN 109055863A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
- C21D1/28—Normalising
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D3/00—Diffusion processes for extraction of non-metals; Furnaces therefor
- C21D3/02—Extraction of non-metals
- C21D3/04—Decarburising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
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- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
The trade mark of a kind of low-carbon alloy Steel material of oil drilling hook, the cast steel low-carbon alloy steel is ZG25CrNiMo, and each chemical component is by weight percentage are as follows: carbon 0.22 ~ 0.30%, silicon 0.40 ~ 0.70%, manganese 0.60 ~ 1.00%.Chromium 0.75 ~ 1.00, nickel 0.40 ~ 0.70%, molybdenum 0.25 ~ 0.35%, phosphorus≤0.025%, sulphur≤0.025%, copper≤0.30%, surplus are iron.Heat treatment method are as follows: diffusion annealing processing :+high temperature normalizing processing+modifier treatment.There is the present invention excellent intensity and toughness to combine, and solve the problems, such as that poor hook coupler body cast product comprehensive performance, high tenacity and high-wearing feature cannot get both.
Description
Technical field
The invention belongs to Parts of Petroleum Machinery materials, are related specifically to well drilling hoisting system hook low-carbon alloy steel
Material and heat treatment method.
Background technique
Drilling well hoisting hook is the important component in oil drilling, for promoting drilling rod with conveying drilling fluid, due to
Its promotion load is big, and up and down, receiving alternate stress is needed repeatedly in operation, and operating condition is extremely severe, it is prone to which fatigue is split
Line destroys, and causes serious safety accident.In order to guarantee the safety of product, it is desirable that hoisting system of rig hook material is having
While higher-strength, also there are good plasticity and toughness properties, it is necessary to meet API 8C standard.
Conventional lift systems suspension hook is very high to comprehensive mechanical property index request since safety coefficient is very high, it is desirable that even tissue
It is fine and closely woven, generally use steel alloy forged material.And oil drilling hook is bulky, and it is complex-shaped, it is difficult to adopt forging technology,
Casting material can only be used, this just needs that suitable low-carbon alloy steel is selected to realize desired height by specific heat treatment method
Strong high tenacity performance.Ordinary carbon steel or steel alloy are generallyd use both at home and abroad at present, since cast structure is coarse, material fragility is big,
The problem of generally existing toughness deficiency, it is necessary to the deficiency of material property is made up by subsequent heat treatment.
Summary of the invention
The object of the present invention is to provide a kind of well drilling hoisting system hook coupler body casting low-carbon alloy Steel material and
There is excellent intensity and toughness to combine for heat treatment method, the material, solve that hook coupler body cast product comprehensive performance is poor, high-ductility
The problem of property and high-wearing feature cannot get both.
To achieve the above object, the technical solution of the present invention is as follows:
A kind of low-carbon alloy Steel material of oil drilling hook, it is characterised in that: the trade mark of the cast steel low-carbon alloy steel is
ZG25CrNiMo, each chemical component is by weight percentage are as follows: carbon 0.22 ~ 0.30%, silicon 0.40 ~ 0.70%, manganese 0.60 ~ 1.00%.Chromium
0.75 ~ 1.00, nickel 0.40 ~ 0.70%, molybdenum 0.25 ~ 0.35%, phosphorus≤0.025%, sulphur≤0.025%, copper≤0.30%, surplus is iron.
A kind of low-carbon alloy steel material heat treatment method of oil drilling hook, it is characterised in that:
Method includes the following steps:
(1) diffusion annealing is handled: low-carbon alloy steel hook casting to be processed being put into heating furnace, is heated to 940 ± 10 DEG C
Heat preservation cools to 300 DEG C of taking-ups with the furnace after 4-5 hours and cools down in air.
(2) high temperature normalizing is handled: the low-carbon alloy steel hook casting that step 1 processing is completed being put into heating furnace, is heated
To 900 ± 10 DEG C, 4-5 hours are kept the temperature after steel alloy internal and external temperature reaches consistent, it is then air-cooled.
(3) modifier treatment: the low-carbon alloy steel hook casting that step 2 processing is completed is put into heating furnace, is heated to 870 ± 10
DEG C, 3.5-4 hours are kept the temperature after steel alloy internal and external temperature reaches consistent, takes out 1-1.5 points of pre-cooling in air then water cooling
1.5-2 point places into quenching oil and is cooled to 120 DEG C or so of surface and places into tempering furnace, 680-720 DEG C is heated to, wait close
Heat preservation 6-7 hours, then takes out air-cooled after golden steel internal and external temperature reaches consistent.
The invention has the following outstanding advantages:
(1) low-carbon alloy steel ZG25CrNiMo material of the invention, at diffusion annealing+high temperature normalizing+modifier treatment heat
Reason method obtains tempered sorbite tissue, and material is made to be provided simultaneously with higher intensity and higher toughness;
(2) due to after material heat treatment even tissue it is fine and closely woven, tissue rank after fully achieving forging solves complicated big
Type component can not forge, and the technical problem of mechanical property requirements is not achieved using casting.
Specific embodiment
Below with reference to embodiment, embodiments of the present invention are described further.
Embodiment 1
The founding materials of one block of ZG25CrNiMo steel alloy are chosen, the main component of the steel is shown in Table 2, is diffused to alloy cast steel
Annealing+high temperature normalizing+modifier treatment, compares its intensity and impact property
The chemical component (mass percent %) of 2 ZG25CrNiMo steel alloy of table
Grade of steel | C | Si | Mn | Cr | Ni | Mo | P | S | Cu | Fe |
ZG25CrNiMo | 0.28 | 0.55 | 0.80 | 0.85 | 0.60 | 0.25 | 0.015 | 0.0020 | 0.3 | Surplus |
Heat treatment process is as follows:
(1) ZG25CrNiMo low-carbon alloy steel cast steel sample to be processed is put into heating furnace and is diffused annealing, added
Heat carries out 4 ~ 5h of heat preservation to 940 DEG C, and subsequent blowing out is cooled to room temperature to 300 DEG C hereinafter, taking out in air.
(2) the ZG25CrNiMo low-carbon alloy steel cast steel sample after diffusion annealing is put into heating furnace, is heated to 900 DEG C
It keeps the temperature 4h and carries out high temperature normalizing.
(3) the ZG25CrNiMo low-carbon alloy steel cast steel sample after high temperature normalizing is put into heating furnace, is heated to 870 DEG C
Rapid cooling in water is taken out after heat preservation 3h to be quenched.
(4) quenched ZG25CrNiMo low-carbon alloy steel cast steel sample is put into heating furnace, is heated to 700 DEG C of heat preservations
Rapid cooling in water is taken out after 5h carries out high tempering processing.Then 3 impact toughness samples and 3 strength specimens are taken respectively, it is real
It tests data and is shown in Table 4.
4 embodiment of table, 1 intensity and plasticity and toughness experimental result
Test piece number (Test pc No.) | Tensile strength Rm (MPa) | Yield strength Rel (MPa) | Elongation percentage A % | Contraction percentage of area Z % | - 45 DEG C of Charpy impact Akv (J) |
1# | 710 | 520 | 18 | 52 | 36 |
2# | 680 | 500 | 20 | 55 | 40 |
3# | 690 | 505 | 20 | 54 | 42 |
API 8C technical indicator | 620 | 415 | 18 | 35 | 27 |
Embodiment 2
The steel of one piece of ZG25CrNiMo low-carbon alloy steel are chosen, the main component of the steel is shown in Table 5.Alloy cast steel is diffused
Annealing+high temperature normalizing+modifier treatment, compares its intensity and impact property
The chemical component (mass percent %) of 5 ZG25CrNiMo steel alloy of table
Grade of steel | C | Si | Mn | Cr | Ni | Mo | P | S | Cu | Fe |
ZG25CrNiMo | 0.26 | 0.4 | 0.6 | 1.0 | 0.7 | 0.30 | 0.025 | 0.0020 | 0.2 | Surplus |
Heat treatment process is as follows:
(1) ZG25CrNiMo low-carbon alloy steel cast steel sample to be processed is put into heating furnace and is diffused annealing by (1),
It is heated to 940 DEG C and carries out 4 ~ 5h of heat preservation, subsequent blowing out is cooled to room temperature to 300 DEG C hereinafter, taking out in air.
(2) the ZG25CrNiMo low-carbon alloy steel cast steel sample after diffusion annealing is put into heating furnace, is heated to 910 DEG C
It keeps the temperature 4h and carries out high temperature normalizing.
(3) the ZG25CrNiMo low-carbon alloy steel cast steel sample after high temperature normalizing is put into heating furnace, is heated to 860 DEG C
Rapid cooling in water is taken out after heat preservation 3h to be quenched.
(4) quenched ZG25CrNiMo low-carbon alloy steel cast steel sample is put into heating furnace, is heated to 690 DEG C of heat preservations
Rapid cooling in water is taken out after 5h carries out high tempering processing.Then 3 impact toughness samples and 3 strength specimens are taken respectively, it is real
It tests data and is shown in Table 7.
7 embodiment of table, 2 intensity and plasticity and toughness experimental result
Test piece number (Test pc No.) | Tensile strength Rm (MPa) | Yield strength Rel (MPa) | Elongation percentage A % | Contraction percentage of area Z % | - 45 DEG C of Charpy impact Akv (J) |
1# | 720 | 540 | 18 | 50 | 38 |
2# | 690 | 510 | 19 | 54 | 42 |
3# | 705 | 500 | 19 | 55 | 40 |
API 8C technical indicator | 620 | 415 | 18 | 35 | 27 |
Embodiment 3
The steel of one piece of ZG25CrNiMo low-carbon alloy steel are chosen, the main component of the steel is shown in Table 8.Alloy cast steel is diffused
Annealing+high temperature normalizing+modifier treatment, compares its intensity and impact property
The chemical component (mass percent %) of 8 ZG25CrNiMo steel alloy of table
Grade of steel | C | Si | Mn | Cr | Ni | Mo | P | S | Cu | Fe |
ZG25CrNiMo | 0.22 | 0.7 | 1.0 | 0.75 | 0.4 | 0.35 | 0.010 | 0.0020 | 0.1 | Surplus |
Heat treatment process is as follows:
(1) ZG25CrNiMo low-carbon alloy steel cast steel sample to be processed is put into heating furnace and is diffused annealing, added
Heat carries out 4 ~ 5h of heat preservation to 930 DEG C, and subsequent blowing out is cooled to room temperature to 300 DEG C hereinafter, taking out in air.
(2) the ZG25CrNiMo low-carbon alloy steel cast steel sample after diffusion annealing is put into heating furnace, is heated to 910 DEG C
It keeps the temperature 4h and carries out high temperature normalizing.
(3) the ZG25CrNiMo low-carbon alloy steel cast steel sample after high temperature normalizing is put into heating furnace, is heated to 870 DEG C
Rapid cooling in water is taken out after heat preservation 3h to be quenched.
(4) quenched ZG25CrNiMo low-carbon alloy steel cast steel sample is put into heating furnace, is heated to 710 DEG C of heat preservations
Rapid cooling in water is taken out after 5h carries out high tempering processing.Then 3 impact toughness samples and 3 strength specimens are taken respectively, it is real
It tests data and is shown in Table 10.
10 embodiment of table, 3 intensity and plasticity and toughness experimental result
Test piece number (Test pc No.) | Tensile strength Rm (MPa) | Yield strength Rel (MPa) | Elongation percentage A % | Contraction percentage of area Z % | - 45 DEG C of Charpy impact Akv (J) |
1# | 715 | 550 | 18 | 50 | 40 |
2# | 680 | 505 | 20 | 55 | 45 |
3# | 690 | 510 | 19 | 52 | 38 |
API 8C technical indicator | 620 | 415 | 18 | 35 | 27 |
In summary three embodiments, from the data of table 4, table 7 and table 10 can be seen that by 940 ± 10 DEG C of diffusion annealings+
The sample of+680-720 DEG C of temperings of 900 ± 10 DEG C of normalizing+870 ± 10 DEG C quenchings, yield strength (Rel), tensile strength
(Rm), elongation percentage (A), -29 DEG C of ballistic works (Akv), all mechanical performance indexs all reach API 8C technical requirement.
It is related in the structural transformation that 420 ± 10 DEG C of temperature tempering occur after steel alloy carburizing and quenching, 420 ± 10 DEG C of tempering
The sample of processing, the cemetite lamellae quantity being precipitated from martensite is more and nodularization takes place, and a phase starts to reply.Through X-ray
And scanning electron microscope analysis, organize the mixture formed for fine acicular ferrite and granuliform carbide, i.e. secondary troostite.
The above is only non-limiting embodiment of the invention, for those of ordinary skill in the art, not
Under the premise of being detached from the invention design and not making creative work, various modifications and improvements can be made, these are all
It belongs to the scope of protection of the present invention.
Claims (2)
1. a kind of low-carbon alloy Steel material of oil drilling hook, it is characterised in that: the trade mark of the cast steel low-carbon alloy steel is
ZG25CrNiMo, each chemical component is by weight percentage are as follows: carbon 0.22 ~ 0.30%, silicon 0.40 ~ 0.70%, manganese 0.60 ~ 1.00%, chromium
0.75 ~ 1.00, nickel 0.40 ~ 0.70%, molybdenum 0.25 ~ 0.35%, phosphorus≤0.025%, sulphur≤0.025%, copper≤0.30%, surplus is iron.
2. a kind of low-carbon alloy steel material heat treatment method of oil drilling hook, it is characterised in that:
Method includes the following steps:
(1) diffusion annealing is handled: low-carbon alloy steel hook casting to be processed being put into heating furnace, is heated to 940 ± 10 DEG C
Heat preservation cools to 300 DEG C of taking-ups with the furnace after 4-5 hours and cools down in air;
(2) high temperature normalizing is handled: the low-carbon alloy steel hook casting that step 1 processing is completed being put into heating furnace, is heated to 900
± 10 DEG C, 4-5 hours are kept the temperature after steel alloy internal and external temperature reaches consistent, it is then air-cooled;
(3) modifier treatment: the low-carbon alloy steel hook casting that step 2 processing is completed is put into heating furnace, is heated to 870 ± 10
DEG C, 3.5-4 hours are kept the temperature after steel alloy internal and external temperature reaches consistent, takes out 1-1.5 points of pre-cooling in air then water cooling
1.5-2 point places into quenching oil and is cooled to 120 DEG C or so of surface and places into tempering furnace, 680-720 DEG C is heated to, wait close
Heat preservation 6-7 hours, then takes out air-cooled after golden steel internal and external temperature reaches consistent.
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CN201811087358.7A CN109055863A (en) | 2018-09-18 | 2018-09-18 | A kind of the low-carbon alloy Steel material and heat treatment method of oil drilling hook |
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CN201811087358.7A CN109055863A (en) | 2018-09-18 | 2018-09-18 | A kind of the low-carbon alloy Steel material and heat treatment method of oil drilling hook |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111434589A (en) * | 2019-01-11 | 2020-07-21 | 宝山钢铁股份有限公司 | Wear-resistant alloy steel scraper tooth and assembly thereof |
CN111534762A (en) * | 2020-06-12 | 2020-08-14 | 铁科(北京)轨道装备技术有限公司 | Wear-resistant steel and heat treatment process and preparation method thereof |
CN111850246A (en) * | 2020-06-30 | 2020-10-30 | 锦州捷通铁路机械股份有限公司 | Heat treatment method for improving elongation after fracture of C-grade steel |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60138055A (en) * | 1983-12-26 | 1985-07-22 | Daido Steel Co Ltd | Material for tool joint and drill collar |
CN105714042A (en) * | 2014-12-05 | 2016-06-29 | 重庆永林机械设备有限公司 | Steel casting heat treatment technology |
CN106011396A (en) * | 2016-07-08 | 2016-10-12 | 杭州汽轮铸锻有限公司 | Quenching method for improving mechanical property of large forging |
-
2018
- 2018-09-18 CN CN201811087358.7A patent/CN109055863A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60138055A (en) * | 1983-12-26 | 1985-07-22 | Daido Steel Co Ltd | Material for tool joint and drill collar |
CN105714042A (en) * | 2014-12-05 | 2016-06-29 | 重庆永林机械设备有限公司 | Steel casting heat treatment technology |
CN106011396A (en) * | 2016-07-08 | 2016-10-12 | 杭州汽轮铸锻有限公司 | Quenching method for improving mechanical property of large forging |
Non-Patent Citations (2)
Title |
---|
彭松涛 等: "铸造ZG25CrNiMo游车吊钩的熔炼工艺", 《铸造技术》 * |
闵艳平: "钩体力学性能不合格原因分析及防止措施", 《金属加工(热加工)》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111434589A (en) * | 2019-01-11 | 2020-07-21 | 宝山钢铁股份有限公司 | Wear-resistant alloy steel scraper tooth and assembly thereof |
CN111534762A (en) * | 2020-06-12 | 2020-08-14 | 铁科(北京)轨道装备技术有限公司 | Wear-resistant steel and heat treatment process and preparation method thereof |
CN111850246A (en) * | 2020-06-30 | 2020-10-30 | 锦州捷通铁路机械股份有限公司 | Heat treatment method for improving elongation after fracture of C-grade steel |
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Application publication date: 20181221 |