CN109054511A - A kind of konjaku glucomannan farm implements anticorrosive paint and preparation method thereof - Google Patents
A kind of konjaku glucomannan farm implements anticorrosive paint and preparation method thereof Download PDFInfo
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- CN109054511A CN109054511A CN201810793228.9A CN201810793228A CN109054511A CN 109054511 A CN109054511 A CN 109054511A CN 201810793228 A CN201810793228 A CN 201810793228A CN 109054511 A CN109054511 A CN 109054511A
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- konjaku glucomannan
- anticorrosive paint
- farm implements
- preparation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/02—Dextran; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to a kind of konjaku glucomannan farm implements anticorrosive paints and preparation method thereof.The preparation method of konjaku glucomannan farm implements anticorrosive paint, including pre-dispersed, grinding distribution, tune are standby and purification is packed.The present invention is with konjaku glucomannan, linseed oil, stearic acid, the materials such as mica powder and zeolite powder are main component, the hydrophily having using konjaku glucomannan, thickening property, stability, and distinctive gel characteristic, obtain the anticorrosive paint that konjaku glucomannan is green safe and effect is excellent, the densification that can be formed using this anticorrosive paint in farm implements metal surface, the extremely low protective film in gap, and the safety that konjaku glucomannan is pure natural, good antirust property is made, it is highly-safe, simple process and low-cost anticorrosive paint, there is very big application potential in Material Field.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, and in particular to a kind of konjaku glucomannan farm implements anticorrosive paint and
Preparation method.
Background technique
Usually because the vapor in air causes it to get rusty when metal master of farm implements and products thereof part is placed.It adopts at present
There are the derusting methods such as hand cleaning, acid pickling and rust removing, sandblasting shot-peening with the main means of derusting, but there are one by these derusting methods person
Fixed defect: hand cleaning large labor intensity, construction field is narrow, low efficiency, at high cost, and derusting effect is undesirable, and serious shadow
Ring human health；Acid pickling and rust removing is also easy to produce " cross lose " and " hydrogen excessively ", and be also easy to produce it is secondary get rusty, the discharging of waste liquid of pickling is easily made
At environmental pollution；Sandblasting, shot peening equipment investment are big, at high cost, it is difficult to play a role.Smear common paint rust-proof effect
Difference, and the problem of metal surface is got rusty still cannot get effective solution, and smear anticorrosive paint can be very good to solve it is this kind of
Problem.Antirust paint is that one kind can protect metal surfaces from the chemistry of atmosphere, seawater etc. or the coating of electrochemical corrosion, main to use
In the antirust of the metals such as bridge, ship, pipeline.
Currently, there are many type in the market for anticorrosive paint, but using effect is bad, and cost of manufacture is high.In traditional paint
Contain a large amount of volatile organic matters, have certain injury to environmental and human health impacts, and rust-preventing characteristic is bad, by the outdoor sun
, often there is peeling paint, influences the problem of painting effect in the influence of the long-time irradiation and other natural climates of light.
Application No. is 201310518090.9 patent of invention " a kind of antiseptic and rustproof paint " (applyings date: 2013.10.28)
It is prepared for a kind of antiseptic and rustproof paint with rosin phenolic resin, mica powder, zeolite powder and talcum powder etc. for main material, is made
Standby raw material are easy to obtain, at low cost, and paint on metal, alleviate to a certain extent because of rainy season or institute of being exposed to the sun for a long time
Caused metal and paint corrosion and oxidation, are suitble in rugged environment.But rust-proof effect is limited, is not able to satisfy daily inhabitation
To the effective protection demand of farm implements under environment.
Application No. is 201310566210.2 patent of invention " a kind of anticorrosive paint and preparation method thereof " (applying date:
2013.11.14) it is prepared for a kind of with Petropols, alkyd resin, solvent naphtha, oil-containing calcium powder, kaolin, iron oxide red urges dry
Agent etc. is the antiseptic and rustproof paint of main material, and the preparation cost of raw material is cheap, economical and practical, contains one in oil-containing calcium powder
Partial solvent naphtha, when production, can also reduce the additional amount of solvent naphtha, more reduce the cost of production.But its drying power, attachment
It is no difference compared with traditional paint on power and resistance to salt water.
Application No. is 201510977976.9 patent of invention " a kind of Environment-friendlyantirust antirust paint " (applying date:
2015.12.23 it is prepared for one kind) with rosin phenolic resin, mica powder, zeolite powder, talcum powder, wollastonite in powder etc. is main material
Anticorrosive paint, prepare that raw material are more environmentally friendly, and adhesive capacity is preferable, do not fall off, without dry and cracked.But higher cost, it is not inconsistent
The requirement of large-scale serial production is closed, and cannot realize the corrosion protection to farm implements in the presence of a harsh environment.
Summary of the invention
The object of the present invention is to provide a kind of konjaku glucomannan farm implements anticorrosive paints different from existing paint.
The preparation method of konjaku glucomannan farm implements anticorrosive paint of the present invention, it is characterised in that preparation step is as follows:
(1) pre-dispersed: by weight, to take 5-10 parts of konjaku glucomannan, 8-14 parts of linseed oil, 2-5 parts of stearic acid, mica powder
16-20 parts, 6-8 parts of zeolite powder, 3-6 parts of aluminium oxide, 2-6 parts of chlorinated paraffin, 6-9 parts of trbasic zinc phosphate, 20-25 parts of water mixing, obtain
Mixed liquor；
(2) grinding distribution: the mixed liquor after will be pre-dispersed obtains slurry by grinding distribution equipment grinding distribution；
(3) it adjusts standby: antirust agent 5-10 parts being added in slurry；
(4) it purification packaging: is packed after filtering, finished product konjaku glucomannan farm implements anticorrosive paint.
Advantages of the present invention and usefulness: the present invention is with konjaku glucomannan, linseed oil, stearic acid, mica powder and boiling
The materials such as mountain flour are main component, and natural macromolecule amylose --- konjaku glucomannan is main component, konjaku glucomannan
It (KGM) is by mannose and glucose with β-Isosorbide-5-Nitrae glucosides key connection linear polymer, in certain glycosyls of its molecule
On side chain, it is connected with acetyl group, the molecular proportion of glucose and mannose is 1:(1.5 ~ 1.7), molecular weight may be up to 106, glue
Degree is high, is dissolved in water, and dilation is big in water, has specific bioactivity.KGM has hydrophily, thickening property, stability etc. more
Kind characteristic.In recent years, natural polymer is widely used in Material Field, the waste being on the one hand used in production
It recycles, reduces the pollution of environment；Another aspect natural polymer shows more excellent material property, same with this
When, also solve the problem in many materials safety.Using natural plant polyose as novel product raw material at
For hot spot in recent years, the present invention utilizes the distinctive gel characteristic of konjaku glucomannan, obtains konjaku glucomannan green
Safety and the excellent anticorrosive paint of effect, the densification that can be formed using this anticorrosive paint in farm implements metal surface, gap are extremely low
Protective film and the pure natural safety of konjaku glucomannan, are made good antirust property, highly-safe, simple process and cost
Cheap anticorrosive paint has very big application potential in Material Field.Konjaku glucomannan farm implements anticorrosive paint of the invention
The results are shown in Table 1 with having paint correlated performance test comparison on the market.
The konjaku glucomannan farm implements anticorrosive paint of the invention of table 1 and have on the market paint correlated performance test comparison
As a result
By above-mentioned test comparison, konjaku glucomannan farm implements anticorrosive paint of the invention, in antirust ability, safety, raw material
All other anticorrosive paints are more excellent more on the market in the indexs such as price and potential market, and the farm implements that can become the majority of consumers' selection are anti-
Rust paint.
Specific embodiment
In order to sufficiently disclose konjaku glucomannan farm implements anticorrosive paint of the present invention, below with reference to embodiment to the present invention make into
One step is described in detail.
Embodiment 1, a kind of preparation method of konjaku glucomannan farm implements anticorrosive paint, comprising the following steps:
(1) pre-dispersed: to take 5 parts of konjaku glucomannan, 8 parts of linseed oil, 2 parts of stearic acid, 16 parts of mica powder, 6 parts of zeolite powder, oxidation
3 parts of aluminium, 2 parts of chlorinated paraffin, 6 parts of trbasic zinc phosphate, 20 parts of water mixing, obtain mixed liquor；
(2) grinding distribution: the mixed liquor after will be pre-dispersed obtains slurry by JYS/T high-efficiency sand making machine grinding distribution；
(3) it adjusts standby: 5 parts of antirust agent being added in slurry；
(4) it purification packaging: by XYM chamber filter press, is packed after filtering, finished product konjaku glucomannan farm implements antirust oil
Paint.
Embodiment 2, a kind of preparation method of konjaku glucomannan anticorrosive paint, comprising the following steps:
(1) pre-dispersed: to take 7 parts of konjaku glucomannan, 10 parts of linseed oil, 4 parts of stearic acid, 18 parts of mica powder, 7 parts of zeolite powder, oxygen
Change 5 parts of aluminium, 4 parts of chlorinated paraffin, 7 parts of trbasic zinc phosphate, 22 parts of water mixing, obtains mixed liquor；
(2) grinding distribution: the mixed liquor after will be pre-dispersed obtains slurry by JYS/T high-efficiency sand making machine grinding distribution；
(3) it adjusts standby: 7 parts of antirust agent being added in slurry；
(4) it purification packaging: by XYM chamber filter press, is packed after filtering, finished product konjaku glucomannan farm implements antirust oil
Paint.
Embodiment 3, a kind of preparation method of konjaku glucomannan anticorrosive paint, comprising the following steps:
(1) pre-dispersed: to take 10 parts of konjaku glucomannan, 14 parts of linseed oil, 5 parts of stearic acid, 20 parts of mica powder, 8 parts of zeolite powder, oxygen
Change 6 parts of aluminium, 6 parts of chlorinated paraffin, 9 parts of trbasic zinc phosphate, 25 parts of water mixing, obtains mixed liquor；
(2) grinding distribution: the mixed liquor after will be pre-dispersed obtains slurry by JYS/T high-efficiency sand making machine grinding distribution；
(3) it adjusts standby: 10 parts of antirust agent being added in slurry；
(4) it purification packaging: by XYM chamber filter press, is packed after filtering, finished product konjaku glucomannan farm implements antirust oil
Paint.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, is all covered by the present invention.
Claims (5)
1. a kind of preparation method of konjaku glucomannan farm implements anticorrosive paint, it is characterised in that preparation step is as follows:
(1) pre-dispersed: by weight, to take 5-10 parts of konjaku glucomannan, 8-14 parts of linseed oil, 2-5 parts of stearic acid, mica powder
16-20 parts, 6-8 parts of zeolite powder, 3-6 parts of aluminium oxide, 2-6 parts of chlorinated paraffin, 6-9 parts of trbasic zinc phosphate, 20-25 parts of water mixing, obtain
Mixed liquor；
(2) grinding distribution: the mixed liquor after will be pre-dispersed obtains slurry by grinding distribution equipment grinding distribution；
(3) it adjusts standby: antirust agent 5-10 parts being added in slurry；
(4) it purification packaging: is packed after filtering, finished product konjaku glucomannan farm implements anticorrosive paint.
2. a kind of preparation method of konjaku glucomannan farm implements anticorrosive paint according to claim 1, it is characterised in that institute
It states pre-dispersed: taking 5 parts of konjaku glucomannan, 8 parts of linseed oil, 2 parts of stearic acid, 16 parts of mica powder, 6 parts of zeolite powder, aluminium oxide 3
Part, 2 parts of chlorinated paraffin, 6 parts of trbasic zinc phosphate, 20 parts of water mixing, obtain mixed liquor.
3. a kind of preparation method of konjaku glucomannan farm implements anticorrosive paint according to claim 1, it is characterised in that institute
It states pre-dispersed: taking 7 parts of konjaku glucomannan, 10 parts of linseed oil, 4 parts of stearic acid, 18 parts of mica powder, 7 parts of zeolite powder, aluminium oxide 5
Part, 4 parts of chlorinated paraffin, 7 parts of trbasic zinc phosphate, 22 parts of water mixing, obtain mixed liquor.
4. a kind of preparation method of konjaku glucomannan farm implements anticorrosive paint according to claim 1, it is characterised in that institute
It states pre-dispersed: taking 10 parts of konjaku glucomannan, 14 parts of linseed oil, 5 parts of stearic acid, 20 parts of mica powder, 8 parts of zeolite powder, aluminium oxide 6
Part, 6 parts of chlorinated paraffin, 9 parts of trbasic zinc phosphate, 25 parts of water mixing, obtain mixed liquor.
5. the konjaku glucomannan farm implements anticorrosive paint that either as described in claim 1-4 prepared by method.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810793228.9A CN109054511A (en) | 2018-07-19 | 2018-07-19 | A kind of konjaku glucomannan farm implements anticorrosive paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810793228.9A CN109054511A (en) | 2018-07-19 | 2018-07-19 | A kind of konjaku glucomannan farm implements anticorrosive paint and preparation method thereof |
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| CN109054511A true CN109054511A (en) | 2018-12-21 |
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| CN201810793228.9A Pending CN109054511A (en) | 2018-07-19 | 2018-07-19 | A kind of konjaku glucomannan farm implements anticorrosive paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3771706A1 (en) * | 2019-08-02 | 2021-02-03 | Frank Walz- und Schmiedetechnik GmbH | Composition for coating a component of an agricultural or gardening machine, use therefor, coated component, agricultural or gardening machine comprising the same, and method of making such component |
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| CN1354210A (en) * | 2000-11-17 | 2002-06-19 | 华中农业大学 | Konjaku coating and adhesive and production process thereof |
| CN101235238A (en) * | 2008-01-21 | 2008-08-06 | 福建农林大学 | Environmental protection dope and its preparation method |
| CN102863850A (en) * | 2012-09-04 | 2013-01-09 | 福建农林大学 | Disposable rain-proof antibacterial shoe covers and preparation method thereof |
| CN104672994A (en) * | 2015-03-07 | 2015-06-03 | 西南林业大学 | Film coating agent as well as preparation method and application thereof |
| CN104927074A (en) * | 2015-07-03 | 2015-09-23 | 福建农林大学 | Konjac glucomannan sticking membrane used for sanitary travel sleeping bag and preparation method for konjac glucomannan sticking membrane |
| CN105860845A (en) * | 2016-04-29 | 2016-08-17 | 周华庆 | Anti-rust paint for metal |
| CN105962481A (en) * | 2016-05-27 | 2016-09-28 | 福建农林大学 | Konjac glucomannan membrane haze-prevention mask |
-
2018
- 2018-07-19 CN CN201810793228.9A patent/CN109054511A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1354210A (en) * | 2000-11-17 | 2002-06-19 | 华中农业大学 | Konjaku coating and adhesive and production process thereof |
| CN101235238A (en) * | 2008-01-21 | 2008-08-06 | 福建农林大学 | Environmental protection dope and its preparation method |
| CN102863850A (en) * | 2012-09-04 | 2013-01-09 | 福建农林大学 | Disposable rain-proof antibacterial shoe covers and preparation method thereof |
| CN104672994A (en) * | 2015-03-07 | 2015-06-03 | 西南林业大学 | Film coating agent as well as preparation method and application thereof |
| CN104927074A (en) * | 2015-07-03 | 2015-09-23 | 福建农林大学 | Konjac glucomannan sticking membrane used for sanitary travel sleeping bag and preparation method for konjac glucomannan sticking membrane |
| CN105860845A (en) * | 2016-04-29 | 2016-08-17 | 周华庆 | Anti-rust paint for metal |
| CN105962481A (en) * | 2016-05-27 | 2016-09-28 | 福建农林大学 | Konjac glucomannan membrane haze-prevention mask |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3771706A1 (en) * | 2019-08-02 | 2021-02-03 | Frank Walz- und Schmiedetechnik GmbH | Composition for coating a component of an agricultural or gardening machine, use therefor, coated component, agricultural or gardening machine comprising the same, and method of making such component |
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Application publication date: 20181221 |
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