CN109053289A - A kind of compound controlled release fertilizer granules of graphene and preparation method thereof - Google Patents
A kind of compound controlled release fertilizer granules of graphene and preparation method thereof Download PDFInfo
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- CN109053289A CN109053289A CN201811092446.6A CN201811092446A CN109053289A CN 109053289 A CN109053289 A CN 109053289A CN 201811092446 A CN201811092446 A CN 201811092446A CN 109053289 A CN109053289 A CN 109053289A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/45—Form not covered by groups C05G5/10 - C05G5/18, C05G5/20 - C05G5/27, C05G5/30 - C05G5/38 or C05G5/40, e.g. soluble or permeable packaging
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to technical field of pesticide preparations, more particularly to a kind of compound controlled release fertilizer granules of graphene, including nucleome and the inclusion enclave coated to nucleome, the inclusion enclave is mixed with by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to the mass ratio of 5:3:2:1.The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, the slow release drug is the vector pharmaceutical formulation handled by coating, and the vector pharmaceutical formulation is that graphene and pesticide active ingredient are mixed according to the mass ratio of 3-6:1.Fertilizer granules of the invention have fertilizer efficiency fast and stable, and the slow lasting feature of desinsection drug effect improves the duration of pesticide and fertilizer, achieve the purpose that or basically reach once to be administered not having in whole season refertilize and spray.
Description
Technical field
The present invention relates to technical field of pesticide preparations, and in particular to a kind of compound controlled release fertilizer granules of graphene and its system
Preparation Method.
Background technique
Medicine fertilizer be pesticide and fertilizer are formulated according to a certain percentage to mix, and by certain technology by fertilizer and
Pesticide is stable in specific compound system and the novel ecological compound fertilizer of formation, generally makees the carrier of pesticide with fertilizer.Medicine
Fertilizer has both the effective component of pesticide and fertilizer, and applied once had not only been able to satisfy crop to the needs of N,P,K fertilizers, but also can
The pest for endangering plant is killed, thus, it can be achieved that two operating procedures in field are combined into one, this not only saves labour
Power, and reduce the consumption of time and the energy.
In medicine fertilizer system, the raw medicine of pesticide generally cannot be used directly, it is necessary to which processing is configured to various types of preparations,
It can use.At present using the use of earliest, maximum dosage being pulvis, since it can directly spread fertilizer over the fields or mix native use, work efficiency is high,
It without water, is used particularly suitable for the mountain area of drought and water shortage or upper level and forest land, but the disadvantage of pulvis is that easy drift is dirty
Environment is contaminated, pesticide efficacy is low, and general only 20% pulvis is deposited on target organism, and in addition blade face adhesion is poor,
It is easily blown off or by rain drop erosion, and the drug effect phase is shorter.Therefore since the 1970s, the production of pulvis and make
With on a declining curve.Instead granule.Granule is maintaining the advantage that pulvis is easy to use, work efficiency is high, and gram
The low disadvantage of the easy drift pollution environment of pulvis, effective rate of utilization is taken.
But this kind of granule release time is short, Free up Memory is uncontrollable, it is therefore desirable to a kind of with slow releasing function
Granula, burst size, release time and Free up Memory are controllable, and by effective component according to preset concentration and time
(needing to formulate according to the prevention and control of plant diseases, pest control) continues and is slowly released into environment, and can maintain for a long time one it is specific
Concentration.
A kind of Bactericide fertilizer granule containing Fluoxastrobin is disclosed in license notification number CN102674956B, it is this
Granule is using fertilizer as carrier, by the mixing granulations such as Fluoxastrobin and carrier, filler, corrosion inhibiter and binder, obtains having and remove
The particle of bacterium and fertilizer efficiency, still, the essence of this medicine fertilizer particle are no different with the effect separately applied, only have certain sustained release
The incubation period of drug effect and fertilizer efficiency can be appropriately extended in effect, be extremely difficult to answer the controlled-release function of medicine fertilizer efficiency energy in technical effect
It is poor with effect.
License notification number CN104151088B disclose a kind of medicine fertilizer slow-release preparation, and preparation method thereof and application side
Pesticide imidacloprid, bacteria remover fludioxonil and compound fertilizer are mixed with patent medicine fertilizer particle by method, the technical solution, have fertilizer efficiency
The preferable feature of foot, desinsection bacteria-eliminating efficacy, but because similar with the preparation method of previous public technology scheme, at controlled release
Reason aspect still remains deficiency.
Summary of the invention
Aiming at the problems existing in the prior art, the present invention provides a kind of compound controlled release fertilizer granules of graphene and its
Preparation method, the type fertilizer granules are handled by special film-coating technique, have fertilizer efficiency fast and stable, and desinsection drug effect is slowly held
Long feature improves the duration of pesticide and fertilizer, reaches or basically reaches once to be administered and does not have in whole season to refertilize and spray
Purpose.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of compound controlled release fertilizer granules of graphene, the fertilizer granules include nucleome and are coated to nucleome
Inclusion enclave, the inclusion enclave by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to 5:3:2:1 quality
Than being mixed with;
The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, and weight shared by each raw material
Number are as follows: 13-17 parts of slow release drug, 45-65 parts of overlay film fertilizer, 2-5 parts of sustained release agent, 1-3 parts of water-retaining agent, 25-35 parts of filler;
The slow release drug is the vector pharmaceutical formulation handled by coating, wherein the vector pharmaceutical formulation is stone
Black alkene and pesticide active ingredient are mixed according to the mass ratio of 3-6:1.
Preferably, the nucleome is made of the raw material of following parts by weight: 15 parts of slow release drug, delays 55 parts of overlay film fertilizer
Release 3.5 parts of agent, 2 parts of water-retaining agent, 30 parts of filler.
Preferably, the pesticide active ingredient is respectively Insecticides (tech) & Herbicides (tech), different efficiency type raw medicines in bacteria remover;
Insecticide is selected from avermectin, ivermectin, multiple killing teichomycin, Diacloden, thiacloprid, flufenoxuron, capillary, quinoline mite
Ether, Nitenpyram, gamma cyhalothrin, fenvalerate, effective cypermethrin, cypermethrin, decis, Fenpropathrin,
Biphenthrin, ethofenprox, Buprofezin, Acetamiprid, Nitenpyram, butene-fipronil, lufenuron, flubenzuron, chlorfluazuron, fluorine worm
Urea, diflubenzuron, chlopyrifos, Hostathion, phoxim, methidathion, diazinon, carbosulfan, Bassa, tebufenozide, Mobucin,
One of Envidor, fenpyroximate, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, propargite any a variety of are used cooperatively
The combination of drug;
Herbicide be selected from Acetochlor, pretilachlor, butachlor, fenoxapropPethyl, Quizalotop-ethyl, haloxyfop-r-methyl,
One of efficient fluazifop, cyhalofop-butyl, isopropyl methoxalamine, clomazone, oxadiazon any a variety of are used cooperatively
The combination of drug;
Fungicide, which is selected from, dislikes imidazoles, Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, difenoconazole, propiconazole, three
One of oxazolone, epoxiconazole, Flusilazole, Tebuconazole, hexaconazole, olefin conversion, Flutriafol, dimethomorph any a variety of are matched
Close the combination for using drug.
Preferably, the coated fertilizer that the vector pharmaceutical formulation uses is composed of the following raw materials by weight: refining castor oil
47 parts, 35 parts of linseed oil, 14 parts of hydroxymethyl starch, 8 parts of cyclodextrin, 2.7 parts of atoleine, 4.8 parts of polyvinyl alcohol, dodecyl
1.5 parts of benzene sulfonic acid calcium, 16 parts of deionized water.
Preferably, the overlay film fertilizer the preparation method comprises the following steps: according to mass fraction, 15 parts of fertilizer are heated in autoclave
To 90-100 DEG C, 4.3 parts of polyethylene waxes, 5 parts of methyl methacrylates, 2 parts of hydroxy-ethyl acrylates and 0.4 part of polyoxy is then added
Ethylene castor oil is sufficiently stirred reaction 18-22min, obtains mixture A, by 2 parts of acrylamido sodium isopropyl xanthates, 1.4 parts
Brij-35 and 50 parts of deionized waters are mixed evenly, and obtain mixture B, by mixture A and mixture B points
It is not put into emulsifying kettle by different feed inlets, 30-40min is handled with the temperature high speed dispersion higher than 100 DEG C, then will
Product is cooled to be discharged lower than 50 DEG C, dry, is granulated, is obtained overlay film fertilizer.
Preferably, the fertilizer contains the constant element fertilizer of 90wt% and 10% trace-element fertilizer;Macroelement
Fertilizer includes nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, fertiliser containing magnesium and sulfur fertilizer;Trace-element fertilizer include boron fertilizer, molydbenum fertilizer, zinc fertilizer, copper fertilizer, manganese fertilizer and
Iron fertilizer.
Preferably, the sustained release agent Lauxite, polyacrylamide, Arabic gum, in polybutadiene butanediol ester extremely
Few one kind.
Preferably, the water-retaining agent is polyacrylic resin or polyacrylamide water-absorbing resin.
Preferably, the component of the filler includes: kaolin, clay, polyvinylpyrrolidone and N, N- methylenediourea,
Four mass ratio is 8:4:1:1.
The present invention also provides the preparation methods of the compound controlled release fertilizer granules of above-mentioned graphene, include the following steps:
(1) prepare coated fertilizer each component according to mass fraction, component raw material is added in sealed reaction kettle, heat
To 85-95 DEG C, with the revolving speed decentralized processing 10-14min of 350-400r/min, it is spare to obtain coating agent;
(2) pesticide active ingredient is dissolved in organic solvent or water and obtains clear solution, for use, if the micro- liquid of pesticide
Solvent can not used;Then graphene is put into impregnate in the pesticide solution and is adsorbed, filtered, it is dry, internal-suction type drug is obtained,
It is spare;
(3) internal-suction type drug is put into coating machine, is first preheated, then by coating agent in a manner of atomizing spraying packet
Internal-suction type medical surfaces are overlying on, after the solidification of coating agent natural cooling, obtain slow release drug, it is spare;
(4) component of filler is mixed according to mass ratio, the deionized water for accounting for packing quality 30% is added, stirs to get material
Then slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler is added in slurry into slurry, be quickly granulated after stirring, then
It is dried with 80-85 DEG C of temperature, it is spare to obtain nucleome;
(5) after mixing the raw material components of inclusion enclave according to mass ratio, the deionization for accounting for solid quality 20-25% is added
Water is sufficiently stirred to obtain package slurry, the nucleome for wrapping up slurry and upper step is mixed according to the mass ratio of 1:5, in blender
In 5-8min stirred with the revolving speed of 300-350r/min, it is then dry with 35-40 DEG C of thermostatic, it is multiple to obtain required graphene
Close controlled release fertilizer granules.
The present invention have it is following the utility model has the advantages that
The compound controlled release fertilizer granules of graphene provided by the invention, first have pesticide active ingredient with graphene
Effect solidification absorption, then vector pharmaceutical formulation carries out coating processing again, then by slow release drug, overlay film fertilizer, sustained release agent, guarantor
Aqua, filler mixing granulation form nucleome, finally coat again to nucleome, the medicine fertilizer obtained by this technical solution
Grain object, desinsection drug effect slow, lasting feature quick, stable with comprehensive fertilizer efficiency;Fertilizer is subjected to coating processing simultaneously, is mentioned
The high stability of fertilizer, so that fertilizer becomes stable, persistently.
Wherein, sustained release agent is used in nucleome, and also includes polyvinylpyrrolidone and N in the filler used, and N- is sub-
The sustained release agents constituents such as two urea of methyl, therefore, the slow release effect of fertilizer clearly, fertilizer efficiency more persistently;In addition to drop
Low fertilizer efficiency hides the phase, is applying initial stage fast onset fertilizer efficiency, the permeability of inclusion enclave used in the present invention is preferable, Er Qietong
It crosses and carries out moisture absorption, water conservation using water-retaining agent, to promote the quick dissolution and dissolution of fertilizer efficiency substance.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of compound controlled release fertilizer granules of graphene of the present embodiment, the fertilizer granules include nucleome and to nucleome
The inclusion enclave coated, the inclusion enclave is by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to 5:
The mass ratio of 3:2:1 is mixed with;
The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, and weight shared by each raw material
Number are as follows: 13 parts of slow release drug, 45 parts of overlay film fertilizer, 2 parts of sustained release agent, 1 part of water-retaining agent, 25 parts of filler;
The slow release drug is the vector pharmaceutical formulation handled by coating, wherein the vector pharmaceutical formulation is stone
Black alkene and pesticide active ingredient are mixed according to the mass ratio of 3:1.
Wherein, the pesticide active ingredient is respectively Insecticides (tech) & Herbicides (tech), different efficiency type raw medicines in bacteria remover;
Insecticide is selected from avermectin, ivermectin, multiple killing teichomycin, Diacloden, thiacloprid, flufenoxuron, capillary, quinoline mite
Ether, Nitenpyram, gamma cyhalothrin, fenvalerate, effective cypermethrin, cypermethrin, decis, Fenpropathrin,
Biphenthrin, ethofenprox, Buprofezin, Acetamiprid, Nitenpyram, butene-fipronil, lufenuron, flubenzuron, chlorfluazuron, fluorine worm
Urea, diflubenzuron, chlopyrifos, Hostathion, phoxim, methidathion, diazinon, carbosulfan, Bassa, tebufenozide, Mobucin,
One of Envidor, fenpyroximate, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, propargite any a variety of are used cooperatively
The combination of drug;
Herbicide be selected from Acetochlor, pretilachlor, butachlor, fenoxapropPethyl, Quizalotop-ethyl, haloxyfop-r-methyl,
One of efficient fluazifop, cyhalofop-butyl, isopropyl methoxalamine, clomazone, oxadiazon any a variety of are used cooperatively
The combination of drug;
Fungicide, which is selected from, dislikes imidazoles, Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, difenoconazole, propiconazole, three
One of oxazolone, epoxiconazole, Flusilazole, Tebuconazole, hexaconazole, olefin conversion, Flutriafol, dimethomorph any a variety of are matched
Close the combination for using drug.
Wherein, the coated fertilizer that the vector pharmaceutical formulation uses is composed of the following raw materials by weight: refining castor oil 47
Part, 35 parts of linseed oil, 14 parts of hydroxymethyl starch, 8 parts of cyclodextrin, 2.7 parts of atoleine, 4.8 parts of polyvinyl alcohol, detergent alkylate
1.5 parts of sulfoacid calcium, 16 parts of deionized water.
Wherein, the overlay film fertilizer the preparation method comprises the following steps: according to mass fraction, 15 parts of fertilizer are heated in autoclave
90 DEG C, 4.3 parts of polyethylene waxes, 5 parts of methyl methacrylates, 2 parts of hydroxy-ethyl acrylates and 0.4 part of polyoxyethylene castor is then added
Sesame oil is sufficiently stirred reaction 18min, mixture A is obtained, by 2 parts of acrylamido sodium isopropyl xanthates, 1.4 parts of dodecyls
Polyglycol ether and 50 parts of deionized waters are mixed evenly, and obtain mixture B, mixture A and mixture B are passed through not respectively
Same feed inlet is put into emulsifying kettle, is handled 30min with the temperature high speed dispersion higher than 100 DEG C, is then cooled to product
It is discharged lower than 50 DEG C, it is dry, it is granulated, obtains overlay film fertilizer.
Wherein, the fertilizer contains the constant element fertilizer of 90wt% and 10% trace-element fertilizer;Macroelement fertilizer
Material includes nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, fertiliser containing magnesium and sulfur fertilizer;Trace-element fertilizer includes boron fertilizer, molydbenum fertilizer, zinc fertilizer, copper fertilizer, manganese fertilizer and iron
Fertilizer.
Wherein, the sustained release agent Lauxite, polyacrylamide, Arabic gum, in polybutadiene butanediol ester at least
It is a kind of.
Wherein, the water-retaining agent is polyacrylic resin or polyacrylamide water-absorbing resin.
Wherein, the component of the filler includes: kaolin, clay, polyvinylpyrrolidone and N, N- methylenediourea, and four
The mass ratio of person is 8:4:1:1.
The present invention also provides the preparation methods of the compound controlled release fertilizer granules of above-mentioned graphene, include the following steps:
(1) prepare coated fertilizer each component according to mass fraction, component raw material is added in sealed reaction kettle, heat
To 85 DEG C, with the revolving speed decentralized processing 10min of 350r/min, it is spare to obtain coating agent;
(2) pesticide active ingredient is dissolved in organic solvent or water and obtains clear solution, for use, if the micro- liquid of pesticide
Solvent can not used;Then graphene is put into impregnate in the pesticide solution and is adsorbed, filtered, it is dry, internal-suction type drug is obtained,
It is spare;
(3) internal-suction type drug is put into coating machine, is first preheated, then by coating agent in a manner of atomizing spraying packet
Internal-suction type medical surfaces are overlying on, after the solidification of coating agent natural cooling, obtain slow release drug, it is spare;
(4) component of filler is mixed according to mass ratio, the deionized water for accounting for packing quality 30% is added, stirs to get material
Then slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler is added in slurry into slurry, be quickly granulated after stirring, then
It is dried with 80 DEG C of temperature, it is spare to obtain nucleome;
(5) after mixing the raw material components of inclusion enclave according to mass ratio, the deionized water for accounting for solid quality 20% is added,
Be sufficiently stirred to obtain package slurry, the nucleome for wrapping up slurry and upper step mixed according to the mass ratio of 1:5, in blender with
The revolving speed of 300r/min stirs 5min, then dry with 35 DEG C of thermostatic, obtains the compound controlled release medicine fertilizer of required graphene
Granula.
Embodiment 2
A kind of compound controlled release fertilizer granules of graphene of the present embodiment, the fertilizer granules include nucleome and to nucleome
The inclusion enclave coated, the inclusion enclave is by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to 5:
The mass ratio of 3:2:1 is mixed with;
The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, and weight shared by each raw material
Number are as follows: 17 parts of slow release drug, 65 parts of overlay film fertilizer, 5 parts of sustained release agent, 3 parts of water-retaining agent, 35 parts of filler;
The slow release drug is the vector pharmaceutical formulation handled by coating, wherein the vector pharmaceutical formulation is stone
Black alkene and pesticide active ingredient are mixed according to the mass ratio of 6:1.
Wherein, the pesticide active ingredient is respectively Insecticides (tech) & Herbicides (tech), different efficiency type raw medicines in bacteria remover;
Insecticide is selected from avermectin, ivermectin, multiple killing teichomycin, Diacloden, thiacloprid, flufenoxuron, capillary, quinoline mite
Ether, Nitenpyram, gamma cyhalothrin, fenvalerate, effective cypermethrin, cypermethrin, decis, Fenpropathrin,
Biphenthrin, ethofenprox, Buprofezin, Acetamiprid, Nitenpyram, butene-fipronil, lufenuron, flubenzuron, chlorfluazuron, fluorine worm
Urea, diflubenzuron, chlopyrifos, Hostathion, phoxim, methidathion, diazinon, carbosulfan, Bassa, tebufenozide, Mobucin,
One of Envidor, fenpyroximate, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, propargite any a variety of are used cooperatively
The combination of drug;
Herbicide be selected from Acetochlor, pretilachlor, butachlor, fenoxapropPethyl, Quizalotop-ethyl, haloxyfop-r-methyl,
One of efficient fluazifop, cyhalofop-butyl, isopropyl methoxalamine, clomazone, oxadiazon any a variety of are used cooperatively
The combination of drug;
Fungicide, which is selected from, dislikes imidazoles, Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, difenoconazole, propiconazole, three
One of oxazolone, epoxiconazole, Flusilazole, Tebuconazole, hexaconazole, olefin conversion, Flutriafol, dimethomorph any a variety of are matched
Close the combination for using drug.
Wherein, the coated fertilizer that the vector pharmaceutical formulation uses is composed of the following raw materials by weight: refining castor oil 47
Part, 35 parts of linseed oil, 14 parts of hydroxymethyl starch, 8 parts of cyclodextrin, 2.7 parts of atoleine, 4.8 parts of polyvinyl alcohol, detergent alkylate
1.5 parts of sulfoacid calcium, 16 parts of deionized water.
Wherein, the overlay film fertilizer the preparation method comprises the following steps: according to mass fraction, 15 parts of fertilizer are heated in autoclave
100 DEG C, 4.3 parts of polyethylene waxes, 5 parts of methyl methacrylates, 2 parts of hydroxy-ethyl acrylates and 0.4 part of polyoxyethylene is then added
Castor oil is sufficiently stirred reaction 22min, mixture A is obtained, by 2 parts of acrylamido sodium isopropyl xanthates, 1.4 parts of dodecanes
Base polyglycol ether and 50 parts of deionized waters are mixed evenly, and obtain mixture B, mixture A and mixture B are passed through respectively
Different feed inlets are put into emulsifying kettle, handle 40min with the temperature high speed dispersion higher than 100 DEG C, then that product is cooling
It is dry to lower than 50 DEG C discharges, it is granulated, obtains overlay film fertilizer.
Wherein, the fertilizer contains the constant element fertilizer of 90wt% and 10% trace-element fertilizer;Macroelement fertilizer
Material includes nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, fertiliser containing magnesium and sulfur fertilizer;Trace-element fertilizer includes boron fertilizer, molydbenum fertilizer, zinc fertilizer, copper fertilizer, manganese fertilizer and iron
Fertilizer.
Wherein, the sustained release agent Lauxite, polyacrylamide, Arabic gum, in polybutadiene butanediol ester at least
It is a kind of.
Wherein, the water-retaining agent is polyacrylic resin or polyacrylamide water-absorbing resin.
Wherein, the component of the filler includes: kaolin, clay, polyvinylpyrrolidone and N, N- methylenediourea, and four
The mass ratio of person is 8:4:1:1.
The present invention also provides the preparation methods of the compound controlled release fertilizer granules of above-mentioned graphene, include the following steps:
(1) prepare coated fertilizer each component according to mass fraction, component raw material is added in sealed reaction kettle, heat
To 95 DEG C, with the revolving speed decentralized processing 14min of 400r/min, it is spare to obtain coating agent;
(2) pesticide active ingredient is dissolved in organic solvent or water and obtains clear solution, for use, if the micro- liquid of pesticide
Solvent can not used;Then graphene is put into impregnate in the pesticide solution and is adsorbed, filtered, it is dry, internal-suction type drug is obtained,
It is spare;
(3) internal-suction type drug is put into coating machine, is first preheated, then by coating agent in a manner of atomizing spraying packet
Internal-suction type medical surfaces are overlying on, after the solidification of coating agent natural cooling, obtain slow release drug, it is spare;
(4) component of filler is mixed according to mass ratio, the deionized water for accounting for packing quality 30% is added, stirs to get material
Then slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler is added in slurry into slurry, be quickly granulated after stirring, then
It is dried with 85 DEG C of temperature, it is spare to obtain nucleome;
(5) after mixing the raw material components of inclusion enclave according to mass ratio, the deionized water for accounting for solid quality 25% is added,
Be sufficiently stirred to obtain package slurry, the nucleome for wrapping up slurry and upper step mixed according to the mass ratio of 1:5, in blender with
The revolving speed of 350r/min stirs 8min, then dry with 40 DEG C of thermostatic, obtains the compound controlled release medicine fertilizer of required graphene
Granula.
Embodiment 3
A kind of compound controlled release fertilizer granules of graphene of the present embodiment, the fertilizer granules include nucleome and to nucleome
The inclusion enclave coated, the inclusion enclave is by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to 5:
The mass ratio of 3:2:1 is mixed with;
The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, and weight shared by each raw material
Number are as follows: 15 parts of slow release drug, 55 parts of overlay film fertilizer, 3.5 parts of sustained release agent, 2 parts of water-retaining agent, 30 parts of filler;
The slow release drug is the vector pharmaceutical formulation handled by coating, wherein the vector pharmaceutical formulation is stone
Black alkene and pesticide active ingredient are mixed according to the mass ratio of 4.5:1.
Wherein, the pesticide active ingredient is respectively Insecticides (tech) & Herbicides (tech), different efficiency type raw medicines in bacteria remover;
Insecticide is selected from avermectin, ivermectin, multiple killing teichomycin, Diacloden, thiacloprid, flufenoxuron, capillary, quinoline mite
Ether, Nitenpyram, gamma cyhalothrin, fenvalerate, effective cypermethrin, cypermethrin, decis, Fenpropathrin,
Biphenthrin, ethofenprox, Buprofezin, Acetamiprid, Nitenpyram, butene-fipronil, lufenuron, flubenzuron, chlorfluazuron, fluorine worm
Urea, diflubenzuron, chlopyrifos, Hostathion, phoxim, methidathion, diazinon, carbosulfan, Bassa, tebufenozide, Mobucin,
One of Envidor, fenpyroximate, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, propargite any a variety of are used cooperatively
The combination of drug;
Herbicide be selected from Acetochlor, pretilachlor, butachlor, fenoxapropPethyl, Quizalotop-ethyl, haloxyfop-r-methyl,
One of efficient fluazifop, cyhalofop-butyl, isopropyl methoxalamine, clomazone, oxadiazon any a variety of are used cooperatively
The combination of drug;
Fungicide, which is selected from, dislikes imidazoles, Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, difenoconazole, propiconazole, three
One of oxazolone, epoxiconazole, Flusilazole, Tebuconazole, hexaconazole, olefin conversion, Flutriafol, dimethomorph any a variety of are matched
Close the combination for using drug.
Wherein, the coated fertilizer that the vector pharmaceutical formulation uses is composed of the following raw materials by weight: refining castor oil 47
Part, 35 parts of linseed oil, 14 parts of hydroxymethyl starch, 8 parts of cyclodextrin, 2.7 parts of atoleine, 4.8 parts of polyvinyl alcohol, detergent alkylate
1.5 parts of sulfoacid calcium, 16 parts of deionized water.
Wherein, the overlay film fertilizer the preparation method comprises the following steps: according to mass fraction, 15 parts of fertilizer are heated in autoclave
95 DEG C, 4.3 parts of polyethylene waxes, 5 parts of methyl methacrylates, 2 parts of hydroxy-ethyl acrylates and 0.4 part of polyoxyethylene castor is then added
Sesame oil is sufficiently stirred reaction 20min, mixture A is obtained, by 2 parts of acrylamido sodium isopropyl xanthates, 1.4 parts of dodecyls
Polyglycol ether and 50 parts of deionized waters are mixed evenly, and obtain mixture B, mixture A and mixture B are passed through not respectively
Same feed inlet is put into emulsifying kettle, is handled 35min with the temperature high speed dispersion higher than 100 DEG C, is then cooled to product
It is discharged lower than 50 DEG C, it is dry, it is granulated, obtains overlay film fertilizer.
Wherein, the fertilizer contains the constant element fertilizer of 90wt% and 10% trace-element fertilizer;Macroelement fertilizer
Material includes nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, fertiliser containing magnesium and sulfur fertilizer;Trace-element fertilizer includes boron fertilizer, molydbenum fertilizer, zinc fertilizer, copper fertilizer, manganese fertilizer and iron
Fertilizer.
Wherein, the sustained release agent Lauxite, polyacrylamide, Arabic gum, in polybutadiene butanediol ester at least
It is a kind of.
Wherein, the water-retaining agent is polyacrylic resin or polyacrylamide water-absorbing resin.
Wherein, the component of the filler includes: kaolin, clay, polyvinylpyrrolidone and N, N- methylenediourea, and four
The mass ratio of person is 8:4:1:1.
The present invention also provides the preparation methods of the compound controlled release fertilizer granules of above-mentioned graphene, include the following steps:
(1) prepare coated fertilizer each component according to mass fraction, component raw material is added in sealed reaction kettle, heat
To 90 DEG C, with the revolving speed decentralized processing 12min of 375r/min, it is spare to obtain coating agent;
(2) pesticide active ingredient is dissolved in organic solvent or water and obtains clear solution, for use, if the micro- liquid of pesticide
Solvent can not used;Then graphene is put into impregnate in the pesticide solution and is adsorbed, filtered, it is dry, internal-suction type drug is obtained,
It is spare;
(3) internal-suction type drug is put into coating machine, is first preheated, then by coating agent in a manner of atomizing spraying packet
Internal-suction type medical surfaces are overlying on, after the solidification of coating agent natural cooling, obtain slow release drug, it is spare;
(4) component of filler is mixed according to mass ratio, the deionized water for accounting for packing quality 30% is added, stirs to get material
Then slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler is added in slurry into slurry, be quickly granulated after stirring, then
It is dried with 83 DEG C of temperature, it is spare to obtain nucleome;
(5) after mixing the raw material components of inclusion enclave according to mass ratio, the deionized water for accounting for solid quality 22% is added,
Be sufficiently stirred to obtain package slurry, the nucleome for wrapping up slurry and upper step mixed according to the mass ratio of 1:5, in blender with
The revolving speed of 330r/min stirs 6.5min, then dry with 38 DEG C of thermostatic, obtains the compound controlled release medicine fertilizer of required graphene
Granule.
Embodiment 4
A kind of compound controlled release fertilizer granules of graphene of the present embodiment, the fertilizer granules include nucleome and to nucleome
The inclusion enclave coated, the inclusion enclave is by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to 5:
The mass ratio of 3:2:1 is mixed with;
The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, and weight shared by each raw material
Number are as follows: 14 parts of slow release drug, 50 parts of overlay film fertilizer, 3 parts of sustained release agent, 1.5 parts of water-retaining agent, 28 parts of filler;
The slow release drug is the vector pharmaceutical formulation handled by coating, wherein the vector pharmaceutical formulation is stone
Black alkene and pesticide active ingredient are mixed according to the mass ratio of 3.5:1.
Wherein, the pesticide active ingredient is respectively Insecticides (tech) & Herbicides (tech), different efficiency type raw medicines in bacteria remover;
Insecticide is selected from avermectin, ivermectin, multiple killing teichomycin, Diacloden, thiacloprid, flufenoxuron, capillary, quinoline mite
Ether, Nitenpyram, gamma cyhalothrin, fenvalerate, effective cypermethrin, cypermethrin, decis, Fenpropathrin,
Biphenthrin, ethofenprox, Buprofezin, Acetamiprid, Nitenpyram, butene-fipronil, lufenuron, flubenzuron, chlorfluazuron, fluorine worm
Urea, diflubenzuron, chlopyrifos, Hostathion, phoxim, methidathion, diazinon, carbosulfan, Bassa, tebufenozide, Mobucin,
One of Envidor, fenpyroximate, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, propargite any a variety of are used cooperatively
The combination of drug;
Herbicide be selected from Acetochlor, pretilachlor, butachlor, fenoxapropPethyl, Quizalotop-ethyl, haloxyfop-r-methyl,
One of efficient fluazifop, cyhalofop-butyl, isopropyl methoxalamine, clomazone, oxadiazon any a variety of are used cooperatively
The combination of drug;
Fungicide, which is selected from, dislikes imidazoles, Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, difenoconazole, propiconazole, three
One of oxazolone, epoxiconazole, Flusilazole, Tebuconazole, hexaconazole, olefin conversion, Flutriafol, dimethomorph any a variety of are matched
Close the combination for using drug.
Wherein, the coated fertilizer that the vector pharmaceutical formulation uses is composed of the following raw materials by weight: refining castor oil 47
Part, 35 parts of linseed oil, 14 parts of hydroxymethyl starch, 8 parts of cyclodextrin, 2.7 parts of atoleine, 4.8 parts of polyvinyl alcohol, detergent alkylate
1.5 parts of sulfoacid calcium, 16 parts of deionized water.
Wherein, the overlay film fertilizer the preparation method comprises the following steps: according to mass fraction, 15 parts of fertilizer are heated in autoclave
93 DEG C, 4.3 parts of polyethylene waxes, 5 parts of methyl methacrylates, 2 parts of hydroxy-ethyl acrylates and 0.4 part of polyoxyethylene castor is then added
Sesame oil is sufficiently stirred reaction 19min, mixture A is obtained, by 2 parts of acrylamido sodium isopropyl xanthates, 1.4 parts of dodecyls
Polyglycol ether and 50 parts of deionized waters are mixed evenly, and obtain mixture B, mixture A and mixture B are passed through not respectively
Same feed inlet is put into emulsifying kettle, is handled 33min with the temperature high speed dispersion higher than 100 DEG C, is then cooled to product
It is discharged lower than 50 DEG C, it is dry, it is granulated, obtains overlay film fertilizer.
Wherein, the fertilizer contains the constant element fertilizer of 90wt% and 10% trace-element fertilizer;Macroelement fertilizer
Material includes nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, fertiliser containing magnesium and sulfur fertilizer;Trace-element fertilizer includes boron fertilizer, molydbenum fertilizer, zinc fertilizer, copper fertilizer, manganese fertilizer and iron
Fertilizer.
Wherein, the sustained release agent Lauxite, polyacrylamide, Arabic gum, in polybutadiene butanediol ester at least
It is a kind of.
Wherein, the water-retaining agent is polyacrylic resin or polyacrylamide water-absorbing resin.
Wherein, the component of the filler includes: kaolin, clay, polyvinylpyrrolidone and N, N- methylenediourea, and four
The mass ratio of person is 8:4:1:1.
The present invention also provides the preparation methods of the compound controlled release fertilizer granules of above-mentioned graphene, include the following steps:
(1) prepare coated fertilizer each component according to mass fraction, component raw material is added in sealed reaction kettle, heat
To 88 DEG C, with the revolving speed decentralized processing 11min of 360r/min, it is spare to obtain coating agent;
(2) pesticide active ingredient is dissolved in organic solvent or water and obtains clear solution, for use, if the micro- liquid of pesticide
Solvent can not used;Then graphene is put into impregnate in the pesticide solution and is adsorbed, filtered, it is dry, internal-suction type drug is obtained,
It is spare;
(3) internal-suction type drug is put into coating machine, is first preheated, then by coating agent in a manner of atomizing spraying packet
Internal-suction type medical surfaces are overlying on, after the solidification of coating agent natural cooling, obtain slow release drug, it is spare;
(4) component of filler is mixed according to mass ratio, the deionized water for accounting for packing quality 30% is added, stirs to get material
Then slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler is added in slurry into slurry, be quickly granulated after stirring, then
It is dried with 82 DEG C of temperature, it is spare to obtain nucleome;
(5) after mixing the raw material components of inclusion enclave according to mass ratio, the deionized water for accounting for solid quality 21% is added,
Be sufficiently stirred to obtain package slurry, the nucleome for wrapping up slurry and upper step mixed according to the mass ratio of 1:5, in blender with
The revolving speed of 310r/min stirs 6min, then dry with 36 DEG C of thermostatic, obtains the compound controlled release medicine fertilizer of required graphene
Granula.
Embodiment 5
A kind of compound controlled release fertilizer granules of graphene of the present embodiment, the fertilizer granules include nucleome and to nucleome
The inclusion enclave coated, the inclusion enclave is by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to 5:
The mass ratio of 3:2:1 is mixed with;
The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, and weight shared by each raw material
Number are as follows: 16 parts of slow release drug, 60 parts of overlay film fertilizer, 4 parts of sustained release agent, 2.5 parts of water-retaining agent, 32 parts of filler;
The slow release drug is the vector pharmaceutical formulation handled by coating, wherein the vector pharmaceutical formulation is stone
Black alkene and pesticide active ingredient are mixed according to the mass ratio of 5:1.
Wherein, the pesticide active ingredient is respectively Insecticides (tech) & Herbicides (tech), different efficiency type raw medicines in bacteria remover;
Insecticide is selected from avermectin, ivermectin, multiple killing teichomycin, Diacloden, thiacloprid, flufenoxuron, capillary, quinoline mite
Ether, Nitenpyram, gamma cyhalothrin, fenvalerate, effective cypermethrin, cypermethrin, decis, Fenpropathrin,
Biphenthrin, ethofenprox, Buprofezin, Acetamiprid, Nitenpyram, butene-fipronil, lufenuron, flubenzuron, chlorfluazuron, fluorine worm
Urea, diflubenzuron, chlopyrifos, Hostathion, phoxim, methidathion, diazinon, carbosulfan, Bassa, tebufenozide, Mobucin,
One of Envidor, fenpyroximate, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, propargite any a variety of are used cooperatively
The combination of drug;
Herbicide be selected from Acetochlor, pretilachlor, butachlor, fenoxapropPethyl, Quizalotop-ethyl, haloxyfop-r-methyl,
One of efficient fluazifop, cyhalofop-butyl, isopropyl methoxalamine, clomazone, oxadiazon any a variety of are used cooperatively
The combination of drug;
Fungicide, which is selected from, dislikes imidazoles, Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, difenoconazole, propiconazole, three
One of oxazolone, epoxiconazole, Flusilazole, Tebuconazole, hexaconazole, olefin conversion, Flutriafol, dimethomorph any a variety of are matched
Close the combination for using drug.
Wherein, the coated fertilizer that the vector pharmaceutical formulation uses is composed of the following raw materials by weight: refining castor oil 47
Part, 35 parts of linseed oil, 14 parts of hydroxymethyl starch, 8 parts of cyclodextrin, 2.7 parts of atoleine, 4.8 parts of polyvinyl alcohol, detergent alkylate
1.5 parts of sulfoacid calcium, 16 parts of deionized water.
Wherein, the overlay film fertilizer the preparation method comprises the following steps: according to mass fraction, 15 parts of fertilizer are heated in autoclave
98 DEG C, 4.3 parts of polyethylene waxes, 5 parts of methyl methacrylates, 2 parts of hydroxy-ethyl acrylates and 0.4 part of polyoxyethylene castor is then added
Sesame oil is sufficiently stirred reaction 21min, mixture A is obtained, by 2 parts of acrylamido sodium isopropyl xanthates, 1.4 parts of dodecyls
Polyglycol ether and 50 parts of deionized waters are mixed evenly, and obtain mixture B, mixture A and mixture B are passed through not respectively
Same feed inlet is put into emulsifying kettle, is handled 38min with the temperature high speed dispersion higher than 100 DEG C, is then cooled to product
It is discharged lower than 50 DEG C, it is dry, it is granulated, obtains overlay film fertilizer.
Wherein, the fertilizer contains the constant element fertilizer of 90wt% and 10% trace-element fertilizer;Macroelement fertilizer
Material includes nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, fertiliser containing magnesium and sulfur fertilizer;Trace-element fertilizer includes boron fertilizer, molydbenum fertilizer, zinc fertilizer, copper fertilizer, manganese fertilizer and iron
Fertilizer.
Wherein, the sustained release agent Lauxite, polyacrylamide, Arabic gum, in polybutadiene butanediol ester at least
It is a kind of.
Wherein, the water-retaining agent is polyacrylic resin or polyacrylamide water-absorbing resin.
Wherein, the component of the filler includes: kaolin, clay, polyvinylpyrrolidone and N, N- methylenediourea, and four
The mass ratio of person is 8:4:1:1.
The present invention also provides the preparation methods of the compound controlled release fertilizer granules of above-mentioned graphene, include the following steps:
(1) prepare coated fertilizer each component according to mass fraction, component raw material is added in sealed reaction kettle, heat
To 92 DEG C, with the revolving speed decentralized processing 13min of 385r/min, it is spare to obtain coating agent;
(2) pesticide active ingredient is dissolved in organic solvent or water and obtains clear solution, for use, if the micro- liquid of pesticide
Solvent can not used;Then graphene is put into impregnate in the pesticide solution and is adsorbed, filtered, it is dry, internal-suction type drug is obtained,
It is spare;
(3) internal-suction type drug is put into coating machine, is first preheated, then by coating agent in a manner of atomizing spraying packet
Internal-suction type medical surfaces are overlying on, after the solidification of coating agent natural cooling, obtain slow release drug, it is spare;
(4) component of filler is mixed according to mass ratio, the deionized water for accounting for packing quality 30% is added, stirs to get material
Then slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler is added in slurry into slurry, be quickly granulated after stirring, then
It is dried with 80-85 DEG C of temperature, it is spare to obtain nucleome;
(5) after mixing the raw material components of inclusion enclave according to mass ratio, the deionized water for accounting for solid quality 24% is added,
Be sufficiently stirred to obtain package slurry, the nucleome for wrapping up slurry and upper step mixed according to the mass ratio of 1:5, in blender with
The revolving speed of 340r/min stirs 7min, then dry with 38 DEG C of thermostatic, obtains the compound controlled release medicine fertilizer of required graphene
Granula.
Comparative example 1
Except removing graphene, raw material and content, preparation step are consistent with embodiment 1.
Comparative example 2
Other than vector pharmaceutical formulation does not carry out coating processing, raw material and content, preparation step are consistent with embodiment 1.
Comparative example 3
Other than saving fertilizer coating processing, raw material and content, preparation step are consistent with embodiment 1.
Comparative example 4
Except removing inclusion enclave, raw material and content, preparation step are consistent with embodiment 1.
Performance test
Pesticide active ingredient in embodiment 1 and comparative example 1-4 is unified for dinotefuran, respectively by graphene made from it
Compound controlled release fertilizer granules are tested.
The compound controlled release fertilizer granules of graphene for verifying embodiment 1-5 and comparative example 1-4 imitate the prevention and treatment of the snout moth's larva of rice
Fruit.Respectively at 5 days, 10 days, 20 days, 30 days, 60 days and 90 days control efficiency to snout moth's larva.As a result statistics is as shown in table 1 below.
The Contact toxicity measurement result (death rate: %) of 1 snout moth's larva of table
As shown in Table 1, the compound controlled release fertilizer granules release of graphene of the invention is stablized, and the lasting period is long, while by
Comparative example 1, comparative example 3 and comparative example 4 will make it is found that by after graphene, the processing of vector pharmaceutical formulation coating and inclusion enclave removal
The release time of fertilizer granules shortens, and the lasting period shortens.
Using effect of the fertilizer granules of embodiment 1 and comparative example 1-4 to rice is as shown in table 2.
Table 2
In conclusion the present invention provides compound controlled release fertilizer granules of a kind of graphene and preparation method thereof, the type medicine
Fertilizer granular formulation is handled by special film-coating technique, has fertilizer efficiency fast and stable, and the slow lasting feature of desinsection drug effect improves agriculture
The duration of medicine and fertilizer achievees the purpose that or basically reaches once to be administered not having in whole season refertilize and spray.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of compound controlled release fertilizer granules of graphene, which is characterized in that the fertilizer granules include nucleome and to nucleome
The inclusion enclave coated, the inclusion enclave is by sodium alginate, carboxymethyl chitosan, polyvinyl alcohol, neutral bentonite according to 5:
The mass ratio of 3:2:1 is mixed with;
The nucleome is made of slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, and parts by weight shared by each raw material
Are as follows: 13-17 parts of slow release drug, 45-65 parts of overlay film fertilizer, 2-5 parts of sustained release agent, 1-3 parts of water-retaining agent, 25-35 parts of filler;
The slow release drug is the vector pharmaceutical formulation handled by coating, wherein the vector pharmaceutical formulation is graphene
It is mixed with pesticide active ingredient according to the mass ratio of 3-6:1.
2. the compound controlled release fertilizer granules of graphene according to claim 1, which is characterized in that the nucleome is by following heavy
Measure the raw material composition of part: 15 parts of slow release drug, 55 parts of overlay film fertilizer, 3.5 parts of sustained release agent, 2 parts of water-retaining agent, 30 parts of filler.
3. the compound controlled release fertilizer granules of graphene according to claim 1, which is characterized in that the pesticide active ingredient
Respectively Insecticides (tech) & Herbicides (tech), different efficiency type raw medicines in bacteria remover;
Insecticide be selected from avermectin, ivermectin, multiple killing teichomycin, Diacloden, thiacloprid, flufenoxuron, capillary, fenazaquin,
Nitenpyram, gamma cyhalothrin, fenvalerate, effective cypermethrin, cypermethrin, decis, Fenpropathrin, biphenyl
Pyrethroids, Buprofezin, Acetamiprid, Nitenpyram, butene-fipronil, lufenuron, flubenzuron, chlorfluazuron, flufenoxuron, removes ethofenprox
Worm urea, chlopyrifos, Hostathion, phoxim, methidathion, diazinon, carbosulfan, Bassa, tebufenozide, Mobucin, spiral shell mite
One of ester, fenpyroximate, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, propargite are any a variety of with the use of drug
Combination;
Herbicide is selected from Acetochlor, pretilachlor, butachlor, fenoxapropPethyl, Quizalotop-ethyl, haloxyfop-r-methyl, smart pyrrole
One of fluorine diclofop-methyl, cyhalofop-butyl, isopropyl methoxalamine, clomazone, oxadiazon are any a variety of with the use of drug
Combination;
Fungicide, which is selected from, dislikes imidazoles, Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, difenoconazole, propiconazole, triazole
One of ketone, epoxiconazole, Flusilazole, Tebuconazole, hexaconazole, olefin conversion, Flutriafol, dimethomorph any a variety of cooperate
Use the combination of drug.
4. the compound controlled release fertilizer granules of graphene according to claim 1, which is characterized in that the vector pharmaceutical formulation
The coated fertilizer used is composed of the following raw materials by weight: 47 parts of refining castor oil, 35 parts of linseed oil, 14 parts of hydroxymethyl starch,
8 parts of cyclodextrin, 2.7 parts of atoleine, 4.8 parts of polyvinyl alcohol, 1.5 parts of calcium dodecyl benzene sulfonate, 16 parts of deionized water.
5. the compound controlled release fertilizer granules of graphene according to claim 1, which is characterized in that the system of the overlay film fertilizer
Preparation Method are as follows: according to mass fraction, 15 parts of fertilizer are heated to 90-100 DEG C in autoclave, 4.3 parts of polyethylene are then added
Reaction 18- is sufficiently stirred in wax, 5 parts of methyl methacrylates, 2 parts of hydroxy-ethyl acrylates and 0.4 part of Emulsifier EL-60
22min obtains mixture A, and by 2 parts of acrylamido sodium isopropyl xanthates, 1.4 parts of Brij-35s and 50 parts are gone
Ionized water is mixed evenly, and obtains mixture B, and mixture A and mixture B are passed through different feed inlets respectively and put into cream
Change in kettle, 30-40min is handled with the temperature high speed dispersion higher than 100 DEG C, then product is cooled to and is discharged lower than 50 DEG C, is done
It is dry, it is granulated, obtains overlay film fertilizer.
6. the compound controlled release fertilizer granules of graphene according to claim 5, which is characterized in that the fertilizer contains
The constant element fertilizer of 90wt% and 10% trace-element fertilizer;Constant element fertilizer includes nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, fertiliser containing magnesium
And sulfur fertilizer;Trace-element fertilizer includes boron fertilizer, molydbenum fertilizer, zinc fertilizer, copper fertilizer, manganese fertilizer and iron fertilizer.
7. the compound controlled release fertilizer granules of graphene according to claim 1, which is characterized in that the sustained release agent ureaformaldehyde tree
At least one of rouge, polyacrylamide, Arabic gum, polybutadiene butanediol ester.
8. the compound controlled release fertilizer granules of graphene according to claim 1, which is characterized in that the water-retaining agent is poly- third
Olefin(e) acid sodium resin or polyacrylamide water-absorbing resin.
9. the compound controlled release fertilizer granules of graphene according to claim 1, which is characterized in that the group subpackage of the filler
Include: kaolin, clay, polyvinylpyrrolidone and N, N- methylenediourea, four mass ratio are 8:4:1:1.
10. the preparation method of the compound controlled release fertilizer granules of graphene according to claim 1-8, feature exist
In including the following steps:
(1) prepare coated fertilizer each component according to mass fraction, component raw material is added in sealed reaction kettle, is heated to
85-95 DEG C, with the revolving speed decentralized processing 10-14min of 350-400r/min, it is spare to obtain coating agent;
(2) pesticide active ingredient is dissolved in organic solvent or water and obtains clear solution, for use, if the micro- liquid of pesticide can be with
Without using solvent;Then graphene is put into impregnate in the pesticide solution and is adsorbed, filtered, it is dry, internal-suction type drug is obtained, it is standby
With;
(3) internal-suction type drug is put into coating machine, is first preheated, be then coated on coating agent in a manner of atomizing spraying
Internal-suction type medical surfaces obtain slow release drug after the solidification of coating agent natural cooling, spare;
(4) component of filler is mixed according to mass ratio, the deionized water for accounting for packing quality 30% is added, stirs to get slurry,
Then into slurry be added slow release drug, overlay film fertilizer, sustained release agent, water-retaining agent, filler, quickly stirring after be granulated, then with
80-85 DEG C of temperature drying, it is spare to obtain nucleome;
(5) after mixing the raw material components of inclusion enclave according to mass ratio, the deionized water for accounting for solid quality 20-25% is added,
Be sufficiently stirred to obtain package slurry, the nucleome for wrapping up slurry and upper step mixed according to the mass ratio of 1:5, in blender with
The revolving speed of 300-350r/min stirs 5-8min, then dry with 35-40 DEG C of thermostatic, obtains the compound control of required graphene
Release the drug fertilizer granular formulation.
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CN110317099A (en) * | 2019-07-16 | 2019-10-11 | 福建省农业科学院土壤肥料研究所 | FenoxapropPethyl is improving utilization rate of nitrogen fertilizer and/or is reducing the application in nitrogen loss |
CN111642515A (en) * | 2020-06-01 | 2020-09-11 | 南京师范大学 | Cyhalothrin nano slow-release pesticide preparation and preparation method thereof |
CN111727964A (en) * | 2020-06-01 | 2020-10-02 | 南京师范大学 | Avermectin nano slow-release pesticide preparation and preparation method thereof |
CN112772670A (en) * | 2020-12-17 | 2021-05-11 | 南京师范大学 | Preparation method of quaternary composite nano controlled release system |
CN115093279A (en) * | 2022-06-20 | 2022-09-23 | 北京十玉农业科技有限公司 | Special fertilizer for cucumber nanocarbon humic acid |
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