CN109021753A - A kind of high-performance black pigment foil - Google Patents
A kind of high-performance black pigment foil Download PDFInfo
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- CN109021753A CN109021753A CN201810669251.7A CN201810669251A CN109021753A CN 109021753 A CN109021753 A CN 109021753A CN 201810669251 A CN201810669251 A CN 201810669251A CN 109021753 A CN109021753 A CN 109021753A
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- black pigment
- pigment foil
- performance black
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/32—Modified amine-aldehyde condensates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to pigment foil field more particularly to high-performance black pigment foils.The high-performance black pigment foil includes at least coloring layer；The coloring layer prepares raw material, is calculated with mass parts, includes at least: 30~50 parts of acrylic resin；3~15 parts of NC Nitroncellulose；3~12 parts of rosin glycerides；10~40 parts of carbon black；5~20 parts of talcum powder；5~20 parts of plasticizer；50~200 parts of solvent.
Description
Technical field
The present invention relates to pigment foil field more particularly to high-performance black pigment foils.
Background technique
Transfer is a kind of printing technology of special type, usually utilizes adhesive through hot pressing by transfer film, by colour image
Be transferred on the surface of other materials, complete by transfer film colouring coating or color pattern be transferred to other materials surface
Process.
Such transfer film, usually has: 1. heat transfer films (anodized aluminium, gilding film): can be subdivided into aluminium coated
Electrochemical aluminothermic stamping systems, the pigment foil without aluminium coated；2. transfer printing film: the printing coating color diagram usually on film or paper base material
Color pattern is transferred on other materials surface by case by adhesive；3. heat transfer printing carbon tape (digital printing film): being turned by heat
Printer is printed by the color layers hot print on film to the surface of other substrates, forms character pattern.
Currently used heat transfer film is with flowering structure:
First layer is base membrane layer.Basement membrane is generally the mylar of 12~16 μ m-thicks.Mainly play support coating.It is wrapped
Dress form is roll type, is convenient for Continuous maching, storage and transport.
The second layer is abscission layer.The coating of abscission layer is organic siliconresin or wax liquor, and effect is to make color adhesion coating in thermoprint
When can be detached from basement membrane rapidly and be bonded in by scald object on.Abscission layer will have good falling-off effect, otherwise will cause thermoprint face
Color floating, unevenness and other issues.
Third layer is color adhesion coating.Color adhesion coating is to add binder, alcoholic solvent and other fillers etc. based on pigment,
It is mixed in a certain ratio composition.The various colors of color foil depends primarily on the coating and preparation of this layer.
For black pigment foil, more common pigment is black carbon black, still, the formula and preparation process of the prior art
Obtained coloring layer, and its it is easy to appear the phenomenon that carbon black falls off, for producing great inconvenience, meanwhile, it is existing
Some production technology curing times are longer, extend the reaction time, reduce working efficiency.
Summary of the invention
In order to solve the above-mentioned technical problem, the first aspect of the invention provides a kind of high-performance black pigment foil, institute
High-performance black pigment foil is stated, coloring layer is included at least；
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
As a preferred technical solution of the present invention, the high-performance black pigment foil, the high-performance black pigment
Foil includes at least coloring layer；
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
As a preferred technical solution of the present invention, the acrylic resin prepares raw material including at least metering system
Sour methyl esters, methacrylic acid and hydroxyethyl methacrylic acid phosphate.
As a preferred technical solution of the present invention, the acrylic resin is prepared in raw material, methyl methacrylate
The molar ratio of ester, methacrylic acid and hydroxyethyl methacrylic acid phosphate are as follows: (5~10): (0~5): (0.1~1).
As a preferred technical solution of the present invention, the plasticizer is selected from: dibutyl phthalate, O-phthalic
Dioctyl phthalate, acetyl tri-n-butyl citrate, CitroflexA-2, N- ethyl adjacency pair toluenesulfonamide, stearic acid 2-
Butoxyethyl, n-butyl stearate, mono laurate 1,2- propylene glycol ester, glyceryl monolaurate, mono laurate diethylene glycol (DEG) ester,
Lauric acid fourth 2-ethoxyethyl acetate, polyethylene glycol dilaurate, triethyl citrate, tri-n-butyl citrate, three second of acetyl tributyl citrate
Ester, the positive fourth rouge of acetyl tributyl citrate three, acetyl trihexyl citrate, epoxidized methyl acetorieinoleate, epoxidation triglyceride,
Any one or a few mixing in the different monooctyl ester of epoxystearic acid.
As a preferred technical solution of the present invention, the solvent is selected from: ethyl acetate, butyl acetate, benzene, toluene,
Dimethylbenzene, acetone, butanone, cyclohexanone, ethyl alcohol, butanol, methyl ether, ether, butyl ether, ethylene glycol monomethyl ether, ethylene glycol ethyl ether, ethylene glycol
Butyl ether, propylene glycol, glycerine, propylene glycol monomethyl ether, one or more of propylene-glycol ethyl ether, sulfuric acid, hydrochloric acid, formic acid, acetic acid
Mixing.
It further include abscission layer in the high-performance black pigment foil as a preferred technical solution of the present invention, it is described
Abscission layer is adjacent with coloring layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 2~10%；
Amino-compound 0~10%；
Organic solvent surplus；
Above each material quality percentage is 100%.
It further include base membrane layer in the high-performance black pigment foil as a preferred technical solution of the present invention；
The high-performance black pigment foil successively includes base membrane layer, abscission layer, coloring layer；Or the high-performance black face
Expect that foil successively includes base membrane layer, coloring layer.
Another aspect of the present invention provides a kind of preparation process of high-performance black pigment foil, includes at least following step
It is rapid:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
The utility model has the advantages that
1, the phenomenon that carbon black of the coloring layer in the high-performance black pigment foil in the application is not in any picking, i.e.,
Make to be the phenomenon that being still not in picking after rubbing and water logging, thus, provides the beneficial effect of the application.
2, after hydroxyethyl methacrylic acid phosphate being added, the curing time of the application shortens, and improves working efficiency.
Detailed description of the invention
For the further clearer technical solution for understanding the application, reference book attached drawing, but attached drawing only conduct
Reference section, not as the foundation for limiting the application.
Fig. 1 is the high-performance black pigment foil of embodiment 1.
Wherein, 1- coloring layer；2- abscission layer；3- base membrane layer.
Specific embodiment
For the purpose of following detailed description, it should be understood that the present invention can be used various substitutions variation and step it is suitable
Sequence, unless specifically stated on the contrary.In addition, being indicated in the case where in addition in any operational instances or otherwise pointing out
Such as all numbers of the amount of ingredient used in description and claims should be understood in all cases by term
" about " it modifies.Therefore, unless indicated to the contrary, the numerical parameter otherwise illustrated in the following description and appended dependent claims is root
The approximation changed according to the expected performance of the invention to be obtained.It is at least not intended to for the applicable of doctrine of equivalents being limited in
In the scope of the claims, each numerical parameter should at least be given up according to the number of the effective digital of report and by the way that application is common
Enter technology to explain.
Although illustrating that broad range of numberical range and parameter of the invention are approximations, listed in specific example
Numerical value is reported as accurately as possible.However, any numerical value inherently includes the standard deviation by finding in its each self-test measurement
The certain errors necessarily led to.
In addition, it should be understood that any numberical range as described herein, which is intended to include, is included into all subranges therein.Example
Such as, the range of " 1 to 10 " is intended to include all sub- models between (and including) described minimum value 1 and the maximum value 10
It encloses, that is, there is the minimum value equal to or more than 1 and the maximum value equal to or less than 10.
In order to solve the above-mentioned technical problem, the first aspect of the invention provides a kind of high-performance black pigment foil, institute
High-performance black pigment foil is stated, coloring layer is included at least；
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
Preferably, the high-performance black pigment foil, the high-performance black pigment foil include at least coloring layer；
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
Preferably, the acrylic resin prepare raw material including at least methyl methacrylate, methacrylic acid and
Hydroxyethyl methacrylic acid phosphate.
Preferably, the acrylic resin is prepared in raw material, and the acrylic resin prepares raw material including at least first
The molar ratio of base methyl acrylate, methacrylic acid and hydroxyethyl methacrylic acid phosphate are as follows: (5~10): (0~5):
(0.1~1).It is highly preferred that the molar ratio of methyl methacrylate, methacrylic acid and hydroxyethyl methacrylic acid phosphate
Are as follows: (6~7): (3~4): (0.1~0.8).Most preferably, the molar ratio of methyl methacrylate and methacrylic acid are as follows:
6.5:3:0.5.
Applicants have discovered that the mol ratio of unique setting methyl methacrylate and methacrylic acid, it can be in body
Carbon black is fixed in system.Carbon black is prevented to be detached from from system, as colloquial picking produces the performance of product biggish
It influences.In the application, hydroxyethyl methacrylic acid phosphate, which is further added, can further enhance the fixed function to carbon black,
At the same time it can also shorten the curing time of cured layer, efficiency is improved.
In a preferred embodiment, the preparation method of the acrylic resin at least includes the following steps:
Methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile are by certain ratio
Example is added to 500mL and fills in the reaction flask of toluene solvant, and under nitrogen protection, 50~80 DEG C of 3~6h of reaction obtain product,
Obtained product is dissolved in acetone, after being precipitated, being washed in water, is dried in vacuo, obtains acrylic resin.
Preferably, the plasticizer is selected from: dibutyl phthalate, dioctyl phthalate, acetyl tributyl citrate three
N-butyl, CitroflexA-2, N- ethyl adjacency pair toluenesulfonamide, stearic acid 2- butoxyethyl, the positive fourth of stearic acid
Ester, mono laurate 1,2- propylene glycol ester, glyceryl monolaurate, mono laurate diethylene glycol (DEG) ester, lauric acid fourth 2-ethoxyethyl acetate, poly- second two
Alcohol dilaurate, triethyl citrate, tri-n-butyl citrate, acetyl triethyl citrate, the positive fourth rouge of acetyl tributyl citrate three,
Acetyl trihexyl citrate, epoxidized methyl acetorieinoleate, epoxidation triglyceride, appointing in the different monooctyl ester of epoxystearic acid
The mixing for one or more of anticipating.
Preferably, the solvent is selected from: ethyl acetate, butyl acetate, benzene,toluene,xylene, acetone, butanone, hexamethylene
Ketone, ethyl alcohol, butanol, methyl ether, ether, butyl ether, ethylene glycol monomethyl ether, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol, glycerine, third
Glycol methyl ether, the mixing of one or more of propylene-glycol ethyl ether, sulfuric acid, hydrochloric acid, formic acid, acetic acid.
In the application, the coloring layer the preparation method comprises the following steps:
Acrylic resin, NC Nitroncellulose, rosin glycerides, carbon black, talcum powder, plasticizer are mixed and are dissolved in organic solvent
In, after evenly dispersed, obtain coloring layer uses raw material.
It in a preferred embodiment, further include abscission layer in the high-performance black pigment foil, the abscission layer
It is adjacent with coloring layer.
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 2~10%；
Amino-compound 0~10%；
Organic solvent surplus；
Above each material quality percentage is 100%.
Preferably, the abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 5~8%；
Amino-compound 3~7%；
Organic solvent surplus；
Above each material quality percentage is 100%.
Most preferably, the abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 6%；
Amino-compound 5%；
Organic solvent 89%.
Preferably, what the oxide can be enumerated has: carbon black, aluminum oxide, silica, calcium oxide, magnesia,
Zinc oxide, ferrous oxide etc..
Preferably, what the amino-compound can be enumerated has: methyl-etherified melamine resin, alkylated melamine tree
Rouge, high imido grpup melamine resin, butyl ether melmac zoguanamine resin, benzene melamine resin, HUMM- hexa methoxy trimerization
Melamine resin, melamine, aniline, ethyl aniline, ortho-aminotoluene etc..
Preferably, what the organic solvent can be enumerated has: ethyl acetate, butyl acetate, benzene,toluene,xylene, third
Ketone, butanone, cyclohexanone, ethyl alcohol, butanol, methyl ether, ether, butyl ether, ethylene glycol monomethyl ether, ethylene glycol ethyl ether, butyl glycol ether, the third two
Alcohol, glycerine, propylene glycol monomethyl ether, propylene-glycol ethyl ether, sulfuric acid, hydrochloric acid, formic acid, acetic acid etc..
In the application, the abscission layer the preparation method comprises the following steps:
Oxide, amino-compound are mixed and are dissolved in organic solvent, after evenly dispersed, it is former to obtain using for abscission layer
Material.
It in a preferred embodiment, further include base membrane layer in the high-performance black pigment foil；The base membrane layer
It is adjacent with abscission layer.
It in another preferred embodiment, further include base membrane layer in the high-performance black pigment foil；The basement membrane
Layer is directly adjacent with coloring layer.Herein, term " coloring layer " refers to the mixing of single coloring layer and coloring layer and abscission layer
Object, both explanations.
In the application, used base membrane layer is PET film layer.
Another aspect of the present invention provides a kind of preparation process of high-performance black pigment foil, includes at least following step
It is rapid:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
In addition, if without other explanations, it is raw materials used to be all commercially available, bought from the Alibaba Website.
Embodiment 1:
The embodiment of the present invention 1 provides a kind of high-performance black pigment foil, and the black pigment foil successively includes base
Film layer, abscission layer, coloring layer；
The base membrane layer is PET film layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 6%；
Amino-compound 5%；
Organic solvent 89%.
The abscission layer the preparation method comprises the following steps:
Oxide (silica), amino-compound (butyl ether melmac zoguanamine resin) are mixed and are dissolved in organic solvent (third
Glycol methyl ether) in, after evenly dispersed, obtain abscission layer uses raw material.
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
The raw material for preparing of the acrylic resin includes methyl methacrylate, methacrylic acid and hydroxyethyl methyl third
Olefin(e) acid phosphate；
The preparation method of the acrylic resin, at least includes the following steps:
Methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile are by certain ratio
Example is added to 500mL and fills in the reaction flask of toluene solvant, and under nitrogen protection, 80 DEG C of reaction 5h obtain product, by what is obtained
Product dissolves in acetone, after being precipitated, being washed in water, is dried in vacuo, obtains acrylic resin.
Wherein, methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile it
Between molar ratio be 5:2:0.1:0.1.
The plasticizer is dibutyl phthalate；
The solvent is propylene glycol monomethyl ether；
The coloring layer the preparation method comprises the following steps:
Acrylic resin, NC Nitroncellulose, rosin glycerides, carbon black, talcum powder, plasticizer are mixed and are dissolved in organic solvent
In, after evenly dispersed, obtain coloring layer uses raw material.
The preparation process of the high-performance black pigment foil, at least includes the following steps:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
Embodiment 2:
The embodiment of the present invention 2 provides a kind of high-performance black pigment foil, and the black pigment foil successively includes base
Film layer, abscission layer, coloring layer；
The base membrane layer is PET film layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 6%；
Amino-compound 5%；
Organic solvent 89%.
The abscission layer the preparation method comprises the following steps:
Oxide (silica), amino-compound (butyl ether melmac zoguanamine resin) are mixed and are dissolved in organic solvent (third
Glycol methyl ether) in, after evenly dispersed, obtain abscission layer uses raw material.
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
The raw material for preparing of the acrylic resin includes methyl methacrylate, methacrylic acid and hydroxyethyl methyl third
Olefin(e) acid phosphate；
The preparation method of the acrylic resin, at least includes the following steps:
Methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile are by certain ratio
Example is added to 500mL and fills in the reaction flask of toluene solvant, and under nitrogen protection, 80 DEG C of reaction 5h obtain product, by what is obtained
Product dissolves in acetone, after being precipitated, being washed in water, is dried in vacuo, obtains acrylic resin.
Wherein, methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile it
Between molar ratio be 5:2:0.1:0.1.
The plasticizer is dibutyl phthalate；
The solvent is propylene glycol monomethyl ether；
The coloring layer the preparation method comprises the following steps:
Acrylic resin, NC Nitroncellulose, rosin glycerides, carbon black, talcum powder, plasticizer are mixed and are dissolved in organic solvent
In, after evenly dispersed, obtain coloring layer uses raw material.
The preparation process of the high-performance black pigment foil, at least includes the following steps:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
Embodiment 3:
The embodiment of the present invention 3 provides a kind of high-performance black pigment foil, and the black pigment foil successively includes base
Film layer, abscission layer, coloring layer；
The base membrane layer is PET film layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 6%；
Amino-compound 5%；
Organic solvent 89%.
The abscission layer the preparation method comprises the following steps:
Oxide (silica), amino-compound (butyl ether melmac zoguanamine resin) are mixed and are dissolved in organic solvent (third
Glycol methyl ether) in, after evenly dispersed, obtain abscission layer uses raw material.
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
The raw material for preparing of the acrylic resin includes methyl methacrylate, methacrylic acid and hydroxyethyl methyl third
Olefin(e) acid phosphate；
The preparation method of the acrylic resin, at least includes the following steps:
Methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile are by certain ratio
Example is added to 500mL and fills in the reaction flask of toluene solvant, and under nitrogen protection, 80 DEG C of reaction 5h obtain product, by what is obtained
Product dissolves in acetone, after being precipitated, being washed in water, is dried in vacuo, obtains acrylic resin.
Wherein, methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile it
Between molar ratio be 5:2:0.1:0.1.
The plasticizer is dibutyl phthalate；
The solvent is propylene glycol monomethyl ether；
The coloring layer the preparation method comprises the following steps:
Acrylic resin, NC Nitroncellulose, rosin glycerides, carbon black, talcum powder, plasticizer are mixed and are dissolved in organic solvent
In, after evenly dispersed, obtain coloring layer uses raw material.
The preparation process of the high-performance black pigment foil, at least includes the following steps:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
Embodiment 4:
The embodiment of the present invention 4 provides a kind of high-performance black pigment foil, and the black pigment foil successively includes base
Film layer, abscission layer, coloring layer；
The base membrane layer is PET film layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 6%；
Amino-compound 5%；
Organic solvent 89%.
The abscission layer the preparation method comprises the following steps:
Oxide (silica), amino-compound (butyl ether melmac zoguanamine resin) are mixed and are dissolved in organic solvent (third
Glycol methyl ether) in, after evenly dispersed, obtain abscission layer uses raw material.
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
The raw material for preparing of the acrylic resin includes methyl methacrylate, methacrylic acid and hydroxyethyl methyl third
Olefin(e) acid phosphate；
The preparation method of the acrylic resin, at least includes the following steps:
Methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile are by certain ratio
Example is added to 500mL and fills in the reaction flask of toluene solvant, and under nitrogen protection, 80 DEG C of reaction 5h obtain product, by what is obtained
Product dissolves in acetone, after being precipitated, being washed in water, is dried in vacuo, obtains acrylic resin.
Wherein, methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile it
Between molar ratio be 6.5:3:0.5:0.15.
The plasticizer is dibutyl phthalate；
The solvent is propylene glycol monomethyl ether；
The coloring layer the preparation method comprises the following steps:
Acrylic resin, NC Nitroncellulose, rosin glycerides, carbon black, talcum powder, plasticizer are mixed and are dissolved in organic solvent
In, after evenly dispersed, obtain coloring layer uses raw material.
The preparation process of the high-performance black pigment foil, at least includes the following steps:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
Embodiment 5:
The embodiment of the present invention 5 provides a kind of high-performance black pigment foil, and the black pigment foil successively includes base
Film layer, abscission layer, coloring layer；
The base membrane layer is PET film layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 6%；
Amino-compound 5%；
Organic solvent 89%.
The abscission layer the preparation method comprises the following steps:
Oxide (silica), amino-compound (butyl ether melmac zoguanamine resin) are mixed and are dissolved in organic solvent (third
Glycol methyl ether) in, after evenly dispersed, obtain abscission layer uses raw material.
Silica to be replaced are as follows: mesoporous siliceous MCM-41, the mesoporous siliceous MCM-41 are commercially available acquisition,
It is purchased from Nanjing Xian Feng Nono-material Science & Technology Ltd..
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
The raw material for preparing of the acrylic resin includes methyl methacrylate, methacrylic acid and hydroxyethyl methyl third
Olefin(e) acid phosphate；
The preparation method of the acrylic resin, at least includes the following steps:
Methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile are by certain ratio
Example is added to 500mL and fills in the reaction flask of toluene solvant, and under nitrogen protection, 80 DEG C of reaction 5h obtain product, by what is obtained
Product dissolves in acetone, after being precipitated, being washed in water, is dried in vacuo, obtains acrylic resin.
Wherein, methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile it
Between molar ratio be 6.5:3:0.5:0.15.
The plasticizer is dibutyl phthalate；
The solvent is propylene glycol monomethyl ether；
The coloring layer the preparation method comprises the following steps:
Acrylic resin, NC Nitroncellulose, rosin glycerides, carbon black, talcum powder, plasticizer are mixed and are dissolved in organic solvent
In, after evenly dispersed, obtain coloring layer uses raw material.
The preparation process of the high-performance black pigment foil, at least includes the following steps:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
Embodiment 6:
The embodiment of the present invention 6 provides a kind of high-performance black pigment foil, and the black pigment foil successively includes base
Film layer, abscission layer, coloring layer；
The base membrane layer is PET film layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 6%；
Amino-compound 5%；
Organic solvent 89%.
The abscission layer the preparation method comprises the following steps:
Oxide (silica), amino-compound (butyl ether melmac zoguanamine resin) are mixed and are dissolved in organic solvent (third
Glycol methyl ether) in, after evenly dispersed, obtain abscission layer uses raw material.
Silica to be replaced are as follows: mesoporous siliceous MCM-41, the mesoporous siliceous MCM-41 are commercially available acquisition,
It is purchased from Nanjing Xian Feng Nono-material Science & Technology Ltd..
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
The raw material for preparing of the acrylic resin includes methyl methacrylate, methacrylic acid and hydroxyethyl methyl third
Olefin(e) acid phosphate；
The preparation method of the acrylic resin, at least includes the following steps:
Methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile are by certain ratio
Example is added to 500mL and fills in the reaction flask of toluene solvant, and under nitrogen protection, 80 DEG C of reaction 5h obtain product, by what is obtained
Product dissolves in acetone, after being precipitated, being washed in water, is dried in vacuo, obtains acrylic resin.
Wherein, methyl methacrylate, methacrylic acid, hydroxyethyl methacrylic acid phosphate, azodiisobutyronitrile it
Between molar ratio be 6.5:3:0.5:0.15.
The plasticizer is dibutyl phthalate；
The solvent is propylene glycol monomethyl ether；
The carbon black is silane coupler modified carbon black；
The preparation method of the silane coupler modified carbon black at least includes the following steps:
By 10g carbon black in dehydrated alcohol, it is ultrasonically treated 30 minutes, then in the 3- aminopropyl-triethoxy silicon that 1g is added
Alkane increases reaction temperature and dries carbon black to 80 DEG C, 0.5~1h of mechanical stirring, and is ground into 200 mesh powders, obtains silane idol
Join agent modified carbon black.
The coloring layer the preparation method comprises the following steps:
Acrylic resin, NC Nitroncellulose, rosin glycerides, carbon black, talcum powder, plasticizer are mixed and are dissolved in organic solvent
In, after evenly dispersed, obtain coloring layer uses raw material.
The preparation process of the high-performance black pigment foil, at least includes the following steps:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated on abscission layer again
On, finished product is obtained after drying.
Comparative example 1:
Comparative example 1 is with embodiment 1, the difference lies in that not including methyl methacrylate in acrylic resin.
Comparative example 2:
Comparative example 2 is with embodiment 1, the difference lies in that not including methacrylic acid in acrylic resin.
Comparative example 3:
Comparative example 3 is with embodiment 1, the difference lies in that not including hydroxyethyl methacrylic acid phosphate in acrylic resin.
Comparative example 4:
Comparative example 4 is with embodiment 1, the difference lies in that more by the molar ratio between methyl methacrylate, methacrylic acid
It is changed to 1:1.
Comparative example 5:
Comparative example 5 is with embodiment 1, the difference lies in that methacrylic acid is changed to acrylic acid.
Comparative example 6:
Comparative example 6 is with embodiment 1, the difference lies in that methyl methacrylate is changed to acrylic acid.
Comparative example 7:
Comparative example 7 is with embodiment 1, the difference lies in that methyl methacrylate is changed to ethyl methacrylate.
Comparative example 8:
Comparative example 8 is with embodiment 1, the difference lies in that hydroxyethyl methacrylic acid phosphate will be changed to ethoxy first
Base acrylate.
Performance evaluation
Test method is as follows:
1, adhesive tape is respectively adhered on the coloring layer in the product of Examples 1 to 6 and comparative example 1~6, is sufficiently pressed
Pressure, it is ensured that adhesive tape completely covers coloring layer, and then adhesive tape is torn again, and carbon black can or can not be remained on adhesive tape by observing, and does not appoint
What remaining carbon black, is denoted as 0 grade；A small amount of carbon black is remained, is denoted as 1 grade；A large amount of carbon black is remained, is denoted as 2 grades.
2, by the product of Examples 1 to 6 and comparative example 1~6 by repeatedly rub stamp, repeatedly aforesaid operations again, then
Secondary to observe the carbon black that whether erase, not any carbon black is erased, and is denoted as 0 grade；It erases a small amount of carbon black, is denoted as 1 grade；It smears
Fall a large amount of carbon black, is denoted as 2 grades.
3, it after the product of Examples 1 to 6 and comparative example 1~6 to be immersed to 100 DEG C of water process 5h, is weighed again after dry
Multiple aforesaid operations, observe the carbon black that whether can erase, not any carbon black is erased, and is denoted as 0 grade again；It erases a small amount of charcoal
It is black, it is denoted as 1 grade；It erases a large amount of carbon black, is denoted as 2 grades.
Specific data are shown in Table 1.
1 the performance test results of table
| Embodiment | Lose powder grade | Rub stamp picking grade | Immersion picking grade |
| Embodiment 1 | 0 grade | 1 grade | 2 grades |
| Embodiment 2 | 0 grade | 1 grade | 1 grade |
| Embodiment 3 | 0 grade | 1 grade | 1 grade |
| Embodiment 4 | 0 grade | 1 grade | 1 grade |
| Embodiment 5 | 0 grade | 0 grade | 0 grade |
| Embodiment 6 | 0 grade | 0 grade | 0 grade |
| Comparative example 1 | 1 grade | 1 grade | 2 grades |
| Comparative example 2 | 1 grade | 1 grade | 1 grade |
| Comparative example 3 | 1 grade | 1 grade | 1 grade |
| Comparative example 4 | 1 grade | 1 grade | 2 grades |
| Comparative example 5 | 0 grade | 1 grade | 2 grades |
| Comparative example 6 | 1 grade | 1 grade | 1 grade |
| Comparative example 7 | 1 grade | 1 grade | 1 grade |
| Comparative example 8 | 1 grade | 1 grade | 1 grade |
In addition, the abscission layer for the novel black pigment foil that the application obtains has preferable falling-off effect, it is not incumbent out
What floating and other issues.
Claims (10)
1. a kind of high-performance black pigment foil, which is characterized in that the high-performance black pigment foil includes at least coloring layer；
The coloring layer prepares raw material, is calculated with mass parts, includes at least:
2. high-performance black pigment foil as described in claim 1, which is characterized in that the coloring layer prepares raw material, with matter
It measures part to calculate, include at least:
3. high-performance black pigment foil as described in claim 1, which is characterized in that the acrylic resin prepares raw material extremely
It less include methyl methacrylate, methacrylic acid and hydroxyethyl methacrylic acid phosphate.
4. high-performance black pigment foil as claimed in claim 3, which is characterized in that the acrylic resin prepares raw material
In, the molar ratio of methyl methacrylate, methacrylic acid and hydroxyethyl methacrylic acid phosphate are as follows: (5~8): (2~
4): (0.1~1).
5. high-performance black pigment foil as described in claim 1, which is characterized in that the plasticizer is selected from: phthalic acid
Dibutyl ester, dioctyl phthalate, acetyl tri-n-butyl citrate, CitroflexA-2, N- ethyl adjacency pair toluene
Sulfonamide, stearic acid 2- butoxyethyl, n-butyl stearate, mono laurate 1,2- propylene glycol ester, glyceryl monolaurate, list
Diglycol laurate, lauric acid fourth 2-ethoxyethyl acetate, polyethylene glycol dilaurate, triethyl citrate, tri-n-butyl citrate,
Acetyl triethyl citrate, the positive fourth rouge of acetyl tributyl citrate three, acetyl trihexyl citrate, epoxidized methyl acetorieinoleate, ring
Any one or a few mixing in oxidation triglyceride, the different monooctyl ester of epoxystearic acid.
6. high-performance black pigment foil as described in claim 1, which is characterized in that the solvent is selected from: ethyl acetate, acetic acid
Butyl ester, benzene,toluene,xylene, acetone, butanone, cyclohexanone, ethyl alcohol, butanol, methyl ether, ether, butyl ether, ethylene glycol monomethyl ether, second two
Alcohol ether, butyl glycol ether, propylene glycol, glycerine, propylene glycol monomethyl ether, propylene-glycol ethyl ether, sulfuric acid, hydrochloric acid, formic acid, in acetic acid
One or more of mixing.
7. high-performance black pigment foil as described in claim 1, which is characterized in that also wrapped in the high-performance black pigment foil
Abscission layer is included, the abscission layer is adjacent with coloring layer；
The abscission layer prepares raw material, is calculated in mass percent calculation, includes at least:
Oxide 2~10%；
Amino-compound 0~10%；
Organic solvent surplus；
Above each material quality percentage is 100%.
8. high-performance black pigment foil as claimed in claim 7, which is characterized in that the abscission layer prepares raw material, with matter
It measures percentage to calculate, include at least:
Oxide 2~10%；
Amino-compound 0~10%；
Organic solvent surplus；
Above each material quality percentage is 100%.
9. high-performance black pigment foil as described in claim 1, which is characterized in that also wrapped in the high-performance black pigment foil
Include base membrane layer；
The high-performance black pigment foil successively includes base membrane layer, abscission layer, coloring layer；Or the high-performance black pigment foil
It successively include base membrane layer, coloring layer.
10. the preparation process of high-performance black pigment foil as claimed in claim 9, at least includes the following steps:
It first will be disengaged from layer to be uniformly coated on base membrane layer, dry；Then coloring layer is uniformly coated with again on the release layer, is dried
Finished product is obtained after dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810669251.7A CN109021753A (en) | 2018-06-26 | 2018-06-26 | A kind of high-performance black pigment foil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810669251.7A CN109021753A (en) | 2018-06-26 | 2018-06-26 | A kind of high-performance black pigment foil |
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ID=64610972
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| CN201810669251.7A Pending CN109021753A (en) | 2018-06-26 | 2018-06-26 | A kind of high-performance black pigment foil |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113524960A (en) * | 2021-08-02 | 2021-10-22 | 青岛纽丽登包装材料有限公司 | Environment-friendly transfer paper and preparation process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101528477A (en) * | 2006-09-28 | 2009-09-09 | 大日本印刷株式会社 | Decorative sheet |
| CN103834307A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | High peel strength acrylate adhesive |
-
2018
- 2018-06-26 CN CN201810669251.7A patent/CN109021753A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101528477A (en) * | 2006-09-28 | 2009-09-09 | 大日本印刷株式会社 | Decorative sheet |
| CN103834307A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | High peel strength acrylate adhesive |
Non-Patent Citations (2)
| Title |
|---|
| 孙德彬等: "《家具表面装饰工艺技术》", 30 April 2009, 中国轻工业出版社 * |
| 詹益兴: "《现代化工小商品制法大全 第3集》", 31 August 1999, 湖南大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113524960A (en) * | 2021-08-02 | 2021-10-22 | 青岛纽丽登包装材料有限公司 | Environment-friendly transfer paper and preparation process thereof |
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Application publication date: 20181218 |