CN109021727A - A kind of dry-type ceramic tile paint special - Google Patents

A kind of dry-type ceramic tile paint special Download PDF

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Publication number
CN109021727A
CN109021727A CN201810732712.0A CN201810732712A CN109021727A CN 109021727 A CN109021727 A CN 109021727A CN 201810732712 A CN201810732712 A CN 201810732712A CN 109021727 A CN109021727 A CN 109021727A
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Prior art keywords
ceramic tile
dry
type ceramic
paint special
rubber powder
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CN201810732712.0A
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Inventor
赵晓静
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Hebei Meihe Coating Co Ltd
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Hebei Meihe Coating Co Ltd
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Priority to CN201810732712.0A priority Critical patent/CN109021727A/en
Publication of CN109021727A publication Critical patent/CN109021727A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18Homopolymers or copolymers of tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16Homopolymers or copolymers of vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/20Homopolymers or copolymers of hexafluoropropene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking

Abstract

A kind of dry-type ceramic tile paint special, be made of resin rubber powder, nanometer film forming accelerating, dispersing agent, defoaming agent, pigment, the weight percent of constituent is resin rubber powder: nanometer film forming accelerating: dispersing agent: defoaming agent: pigment is 70.0~90.0%:3.0~8.0%:1.0~5.0%:0.5~3.0%:3.0~25.0%.The application method of this dry-type ceramic tile paint special is: before use, needing to add water that it is made to be dispersed into uniform emulsion, holding is stablized within 48 hours after stopping stirring, can sufficiently meet construction demand.Because improving the filming performance of redisperse lotion using nanometer film forming accelerating, to get rid of coalescing agent and cosolvent, reduce the main source VOC.The redispersible fluorocarbon resin rubber powder of free monomer qualification is selected, and does not generate the dispersing agent of VOC, defoaming agent.Just due to the component environmental-friendly using selection, so that dry-type ceramic tile paint special realizes Diamond Search discharge.

Description

A kind of dry-type ceramic tile paint special
Technical field
The present invention relates to paint fields, more specifically, in particular to a kind of dry-type ceramic tile paint special.
Background technique
With the continuous development of technology, house ornamentation technology is also more and more flourishing, and people have lived in big house, to the finishing in house It is required that also starting growing.If the ceramic tile only only bought from the outside, is restricted from color, can not expire The changeable demand of sufficient user.User can voluntarily change the color of ceramic tile surface paint.Ceramic tile production and processing quotient also increasingly complies with People's is aesthetic, and diversification also occur in type, the color of ceramic tile paint.Therefore ceramic tile paint also become repairs profession by The product of favor.
For the needs for meeting market, in the more than ten years of the beginning of this century, building coating is mainly towards high-performance, environmental protection The directions such as type, long service life are developed.It is base-material that common ceramic tile, which selects high-quality fluorocarbon resin with paint, adds auxiliary agent and various gold Belong to the refined two-component solvent type exterior wall paint of effect pigment, it has fabulous adhesive force, penetration, and has good Chemical resistance and water resistance have an effect to be solidified into a firm entity with the ingredient in ceramic tile by effectively permeating, main The effects of can achieve environmental protection, reducing dust and humidity.But this ceramic tile paint is water paint, wherein most ingredient It is water (accounting for about 60%), solid content only accounts for 40%, it is required to use a large amount of storage tank in storage and use process, and these are stored up The recovery processing of tank is also required to a large amount of manpower and material resources.Cost is undoubtedly increased in this way, and causes the waste of resource, but also Pollute environment.Therefore, a kind of save the cost is needed, the ceramic tile of environmental protection paints.
Summary of the invention
(1) technical problem
Therefore, how to solve the problems, such as that ceramic tile paints existing above-mentioned at high cost, waste of resource, pollution environment, Cheng Liaoben Field technical staff's urgent problem to be solved.
(2) technical solution
In view of the above-mentioned problems, the contents of the present invention are to provide a kind of dry-type ceramic tile paint special, only need to add when in use It can be used after water stirring, easy to operate, at low cost, super-weathering resistance, and volatile organic matter is zero, it is safe and non-toxic.
A kind of dry-type ceramic tile paint special, by resin rubber powder, nanometer film forming accelerating, dispersing agent, defoaming agent, pigment group At the weight percent of constituent is resin rubber powder: nanometer film forming accelerating: dispersing agent: defoaming agent: pigment be 70.0~ 90.0%:3.0~8.0%:1.0~5.0%:0.5~3.0%:3.0~25.0%.
The resin rubber powder uses fluorocarbon resin rubber powder, and in spherical, partial size is between 40~100 μm.The resin glue Fluorine content >=15% in powder, hydroxyl value > 35mg KOH/g, acid value≤3mg KOH/g.The fluorocarbon resin rubber powder using PTFE, One or more of PVDF, FEVE, PVF rubber powder, PTFE, that is, polyflon, PVDF, that is, polyvinylidene fluoride resin, FEVE, that is, polytrifluorochloroethylene/vinyl ether resin, PVF, that is, polyfluoroethylene resin.
The nanometer film forming accelerating is made of silane coupling agent and nanoparticle, wherein silane coupling agent and nanometer two The weight ratio of silica or nanoparticle is 1:4~1:6.The nanometer film forming accelerating is by silane coupling agent and nanoparticle Son proportionally stirs by mixing.The nanoparticle is using in nano silica or nano-titanium dioxide It is a kind of.The partial size of the silane coupling agent and nanoparticle is 10~50nm.The silane coupling agent uses three second of vinyl One of oxysilane, vinyltrimethoxysilane, methacryloxypropyl trimethoxy silane.Due to nanometer at The crosslinked action of film promotor is allowed to and porcelain so that dimensional network structure is presented in the micro-structure of dry-type ceramic tile paint special film Powerful attachment force is formed between brick substrate, film compactness greatly improves, and dry-type ceramic tile paint special can be in room temperature film-forming.
The dispersing agent uses partial size for 10~20 μm of Macrogol 6000, white particulate powder, boiling point > 250 ℃.The dispersing agent uses Macrogol 6000 so that this ceramic tile paint special add water in use, can dissolving resin rubber powder, Coalescence effect is played, while water can be slightly soluble in, is easily dispersed in resin glue powder particle surface, but does not influence resin glue powder Stability;Especially Macrogol 6000 boiling point is high, does not generate VOC in film forming procedure, and can be effectively reduced lotion Minimum film formation temperature.
The defoaming agent uses partial size for 30~50 μm of modification poly(silicon aether), white powdered.The defoaming agent uses The defoaming agent of VOC is not generated.The modified poly(silicon aether) is that polyethers-silicon made from polyglycol ether is introduced in dimethyl-silicon oil molecule Siloxane copolymers, modified poly(silicon aether) surface tension is low, defoaming is rapid, the foam inhibition time is long, at low cost, dosage is few.
The pigment uses coloring earth, can be with the film of acquisition different color after ceramic tile paint special use.
The each component of dry-type ceramic tile paint special is put into turning barrel according to weight percent, turning barrel is stainless steel barrel, with 100 It is uniformly mixed it under the revolving speed of~150 turns/min, after mixing, packaging can be made into finished product dry-type ceramic tile paint special. Paper bag packing, carton package, plastic bag packaging, plastic casing packaging can be used in packaging, but is not limited to above-mentioned form.
The present invention is containing a large amount of F-C key in resin, and bond energy 485kJ/mol is being heated, under light action, F-C key It is difficult to be broken, stability is good, therefore there is dry-type ceramic tile paint special provided by the invention good weatherability and chemically-resistant to be situated between Matter corrosion.In addition, the present invention can not also give birth to due to not adding the organic solvents such as preservative, antifreezing agent, coalescing agent, microorganism It deposits, is truly realized Diamond Search, zero formaldehyde.Compared with traditional glazed tile lacquer, the present invention and substrate adhesive force are stronger, and paint film is more It is firm, more resistant to scuffing, scrubbing resistance.
Because improving the filming performance of redisperse lotion using nanometer film forming accelerating, thus got rid of coalescing agent and Cosolvent reduces the main source VOC.The redispersible fluorocarbon resin rubber powder of free monomer qualification is selected, and does not generate VOC Dispersing agent, defoaming agent.Just due to the component environmental-friendly using selection, so that dry-type ceramic tile paint special realizes Diamond Search row It puts.
The application method of this dry-type ceramic tile paint special is: before use, needing to add water that it is made to be dispersed into uniform emulsus Liquid keeps stablizing within 48 hours, can sufficiently meet construction demand after stopping stirring.The pigment can also add in factory Add, is mixed in pigment uniformly in dry-type ceramic tile paint special;Can also be individually placed, independently of dry powder object in addition to pigments In, the pigment that corresponding color is added at the construction field (site) forms the coating of different colours.
(3) beneficial effect
The beneficial effects of the present invention are: dry-type ceramic tile paint special, compared with conventional glazed tile lacquer, due to anhydrous, storage is steady It is fixed, freight volume can be reduced, convenient transportation transportation cost is low;Due to being solid-state, microorganism can not survive, thus it is anti-not have to addition Rotten agent;Without addition antifreezing agent, anti-settling agent, the pollution of VOC and various preservatives are reduced, reduces these hosts and gives painting film strips The negative effect come.
Specific embodiment
Below with reference to embodiment, the invention will be further described.
A kind of dry-type ceramic tile paint special, by resin rubber powder, nanometer film forming accelerating, dispersing agent, defoaming agent, pigment group At the weight percent of constituent is resin rubber powder: nanometer film forming accelerating: dispersing agent: defoaming agent: pigment be 70.0~ 90.0%:3.0~8.0%:1.0~5.0%:0.5~3.0%:3.0~25.0%.
The resin rubber powder uses fluorocarbon resin rubber powder, and the fluorocarbon resin rubber powder uses PTFE, PVDF, FEVE, PVF glue One or more of powder.
The nanometer film forming accelerating is made of silane coupling agent and nanoparticle, wherein silane coupling agent and nanoparticle The weight ratio of son is 1:4~1:6.The silane coupling agent uses vinyltriethoxysilane, vinyl trimethoxy silicon One of alkane, methacryloxypropyl trimethoxy silane.When silane coupling agent between inorganic between organic interface, Organic matrix-silane coupling agent-inorganic matrix binder course can be formed.The nanoparticle uses nano silica, nanometer One of titanium dioxide.Nano silica may make silane coupling agent and nano silica or nano-titanium dioxide to be formed Organic-inorganic hybrid nanocomposite structure, the organic-inorganic hybrid nanocomposite structure can form with fluorocarbon resin molecule cross-link organic again Matrix-silane coupling agent-inorganic matrix binder course, the binder course can increase coating to the adhesive force of substrate and apply interlayer Binding force.Nano-titanium dioxide mainly increases the weatherability and antibiotic property of film.Due to the crosslinked action of nanometer film forming accelerating, So that dimensional network structure is presented in the micro-structure of dry-type ceramic tile paint special film, it is allowed to be formed between tile substrate powerful Attachment force, film compactness greatly improve, and dry-type ceramic tile paint special can be in room temperature film-forming.
The dispersing agent uses Macrogol 6000, so that this ceramic tile paint special is adding water in use, being capable of dissolving resin Rubber powder plays coalescence effect, while can be slightly soluble in water, is easily dispersed in resin glue powder particle surface, but does not influence resin glue The stability of powder;Especially Macrogol 6000 boiling point is high, does not generate VOC in film forming procedure, and can be effectively reduced The minimum film formation temperature of lotion.
The defoaming agent is using modified poly(silicon aether).The modified poly(silicon aether) is to introduce polyethylene glycol in dimethyl-silicon oil molecule Polyether siloxane copolymers made from ether.
The pigment uses coloring earth, can obtain the ceramic tile paint special film of different color.
The each component of dry-type ceramic tile paint special is put into turning barrel according to weight percent, turning barrel is stainless steel barrel, with 100 It is uniformly mixed it under the revolving speed of~150 turns/min, after mixing, packaging can be made into finished product dry-type ceramic tile paint special. Paper bag packing, carton package, plastic bag packaging, plastic casing packaging can be used in packaging, but is not limited to above-mentioned form.
Traditional liquid coating will use coalescing agent, also use 3% or so cosolvent, coalescing agent be reduce form a film Temperature, cosolvent be assist swollen polymer improve filming performance, in addition will also use some volatile low molecule auxiliary agents and Free monomer in emulsion resin, thus the VOC standard of traditional coating is≤120g/L.Nanometer film forming accelerating is composite Nano Material improves the filming performance and comprehensive performance of coating.Wherein nanometer film forming accelerating plays a major role to enhancing adhesive force, In nanoparticle surface is partially submerged into due to the strong force action with substrate, another part and polymer of nanoparticle Link, so greatly enhancing coating adhesion.
Embodiment one, a kind of dry-type ceramic tile paint special, by resin rubber powder, nanometer film forming accelerating, dispersing agent, defoaming Agent, pigment composition, the weight percent of constituent are resin rubber powder: nanometer film forming accelerating: dispersing agent: defoaming agent: pigment For 70.0%:8.0%:5.0%:1.0%:16.0%.
Embodiment two, a kind of dry-type ceramic tile paint special, by resin rubber powder, nanometer film forming accelerating, dispersing agent, defoaming Agent, pigment composition, the weight percent of constituent are resin rubber powder: nanometer film forming accelerating: dispersing agent: defoaming agent: pigment For 80.0%:5.0%:3.0%:2.0%:10.0%.
Embodiment three, a kind of dry-type ceramic tile paint special, by resin rubber powder, nanometer film forming accelerating, dispersing agent, defoaming Agent, pigment composition, the weight percent of constituent are resin rubber powder: nanometer film forming accelerating: dispersing agent: defoaming agent: pigment For 90.0%:3.0%:1.0%:3.0%:3.0%.
Dry-type ceramic tile paint special made from above three embodiments, before use, being required to that water is added to make its dispersion in equal Even emulsion can keep within 48 hours stable after stopping stirring, can sufficiently meet construction demand.Do not have to when in use another It primes, is directly brushed on cement screedn, adhesion is strong, and alkali resistance, waterproof performance are good.
Pigment in above three embodiments can also add in factory, so that pigment is uniformly mixed in dry-type ceramic tile special With in paint;Can also be individually placed, independently of in dry powder object in addition to pigments, the pigment of corresponding color is added at the construction field (site) Form the coating of different colours.
There are two types of application methods of the invention: the first, spread coating.Ceramic tile surface is cleaned up, so that surface is ashless Dirt is stirred evenly according to the weight ratio of 1:2~1:4 in emulsion without dirt, then by the present invention and water, and then emulsion is direct It brushes to ceramic tile surface, is brushed again after drying 2~3 times.
Second, spray coating method.Ceramic tile surface is cleaned up, so that surface free from dust is without dirt, then by the present invention and water It stirs evenly according to the weight ratio of 1:2~1:4 in emulsion, spray gun is then connected to emulsus liquid storage tank, so that glazed tile lacquer Emulsion forms required decorative pattern by spray gun spraying to ceramic tile surface, sprays again after drying 2~3 times.
In addition, this ceramic tile paint special is applied on plastic cloth, after long-term immersion, taking-up is rubbed with hand rubbing, and film can also jail Gu attachment.This is because being added to the result of nanometer film forming accelerating.
The present invention is not limited to the above-described embodiments, anyone can obtain other various shapes under the inspiration of the present invention The product of formula.It is all according to equivalent changes and modifications within the scope of the patent application of the present invention, all should belong to covering scope of the invention.

Claims (7)

1. a kind of dry-type ceramic tile paint special is made of resin rubber powder, nanometer film forming accelerating, dispersing agent, defoaming agent, pigment, It is characterized by: the weight percent of constituent is resin rubber powder: nanometer film forming accelerating: dispersing agent: defoaming agent: pigment is 70.0~90.0%:3.0~8.0%:1.0~5.0%:0.5~3.0%:3.0~25.0%.
2. a kind of dry-type ceramic tile paint special according to claim 1, it is characterised in that: the resin rubber powder uses fluorine carbon Resin rubber powder, in spherical, partial size is between 40~100 μm;The fluorocarbon resin rubber powder uses PTFE, PVDF, FEVE, PVF One or more of rubber powder.
3. a kind of dry-type ceramic tile paint special according to claim 1, it is characterised in that: the nanometer film forming accelerating is It is made of silane coupling agent and nanoparticle, wherein the weight ratio of silane coupling agent and nano silica or nanoparticle is 1:4~1:6;The nanometer film forming accelerating be silane coupling agent and nanoparticle are proportionally stirred by mixing and At;The nanoparticle uses one of nano silica or nano-titanium dioxide;The silane coupling agent uses ethylene One of ethyl triethoxy silicane alkane, vinyltrimethoxysilane, methacryloxypropyl trimethoxy silane;It is described The partial size of silane coupling agent and nanoparticle is 10~50nm.
4. a kind of dry-type ceramic tile paint special according to claim 1, it is characterised in that: the dispersing agent use partial size for 10~20 μm of Macrogol 6000, white particulate powder.
5. a kind of dry-type ceramic tile paint special according to claim 1, it is characterised in that: the defoaming agent use partial size for 30~50 μm of modification poly(silicon aether), it is white powdered.
6. a kind of dry-type ceramic tile paint special according to claim 1, it is characterised in that: the pigment uses mineral face Material.
7. a kind of dry-type ceramic tile paint special according to claim 1, it is characterised in that: by dry-type ceramic tile paint special Each component puts into turning barrel according to weight percent, and turning barrel is stainless steel barrel, to make its mixing under the revolving speed of 100~150 turns/min Uniformly, after mixing, packaging can be made into finished product dry-type ceramic tile paint special;Packaging can be used paper bag packing, carton package, Plastic bag packaging, plastic casing packaging, but it is not limited to above-mentioned form.
CN201810732712.0A 2018-07-05 2018-07-05 A kind of dry-type ceramic tile paint special Pending CN109021727A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60202156A (en) * 1984-03-28 1985-10-12 Du Pont Mitsui Fluorochem Co Ltd Tetrafluoroethylene copolymer powder coating primer for ceramic substrate
CN103073944A (en) * 2013-01-31 2013-05-01 无锡荷仕达科技有限公司 Nano film-forming accelerant and application thereof
CN105199514A (en) * 2015-10-27 2015-12-30 北京东方雨虹防水技术股份有限公司 Fluorocarbon elastic waterproof paint for metal color steel roofing and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60202156A (en) * 1984-03-28 1985-10-12 Du Pont Mitsui Fluorochem Co Ltd Tetrafluoroethylene copolymer powder coating primer for ceramic substrate
CN103073944A (en) * 2013-01-31 2013-05-01 无锡荷仕达科技有限公司 Nano film-forming accelerant and application thereof
CN105199514A (en) * 2015-10-27 2015-12-30 北京东方雨虹防水技术股份有限公司 Fluorocarbon elastic waterproof paint for metal color steel roofing and preparation method thereof

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Application publication date: 20181218