CN109021538A - A kind of preparation method of resin extender interfacial agent - Google Patents
A kind of preparation method of resin extender interfacial agent Download PDFInfo
- Publication number
- CN109021538A CN109021538A CN201810887966.XA CN201810887966A CN109021538A CN 109021538 A CN109021538 A CN 109021538A CN 201810887966 A CN201810887966 A CN 201810887966A CN 109021538 A CN109021538 A CN 109021538A
- Authority
- CN
- China
- Prior art keywords
- interfacial agent
- mixture
- preparation
- resin extender
- stirred
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Abstract
The invention discloses a kind of preparation methods of resin extender interfacial agent, the following steps are included: S1: raw material weighing: weighing pentyl acetate, titanate coupling agent, fatty alcohol polyoxyethylene ether, calcium carbonate, butyl acetate according to the proportion, wait to be used；S2: it is stirred: mixing is stirred to pentyl acetate and fatty alcohol polyoxyethylene ether, the first mixture is made, then calcium carbonate and butyl acetate are stirred mixing, the second mixture is made, the first mixture and the second mixture are finally stirred mixing, and titanate coupling agent is added and stirs evenly, third mixture is made.The present invention is tested by appearance, dissolubility and the surface tension to interfacial agent sample, can be recognized the quality of interfacial agent sample in time, be controlled the quality of interfacial agent sample, prevent interfacial agent inferior from coming into the market.
Description
Technical field
The present invention relates to the preparation technical field of interfacial agent more particularly to a kind of resin extender interfacial agents
Preparation method.
Background technique
Interfacial agent is also known as surfactant, refers to that the interface state that can make its solution system on a small quantity, which is added, to be occurred obviously
The substance of variation has fixed hydrophilic lipophilic group, can align on the surface of solution, the molecular structure of surfactant
With amphipathic: one end is hydrophilic radical, and the other end is hydrophobic grouping；Hydrophilic radical is often polar group, as carboxylic acid, sulfonic acid,
Sulfuric acid, amino or amido and its salt, hydroxyl, amide groups, ehter bond etc. also can be used as polar hydrophilic group；And hydrophobic grouping Chang Weifei
Polarity hydrocarbon chain, such as 8 above hydrocarbon chains of carbon atom, surfactant is divided into ionic surfactant, and (including cationic surface is living
Property agent and anionic surfactant), nonionic surface active agent, amphoteric surfactant, compound surfactant, other
Surfactant etc., through retrieving, it is living that the patent document of application number 201711063286.8 discloses a kind of resin extender interface
Property agent preparation method, by following material composition: pentyl acetate, rhamnolipid, n-butanol, ethylene glycol, polyvinyl alcohol, silane are even
Join agent, fatty alcohol polyoxyethylene ether, butyl acetate.Interfacial agent produced by the present invention can effectively improve nothing
Using effect of the machine filler in resin improves the filling usage amount of inorganic filler, reduces whole cost, has fine
Popularizing value, but the preparation method of this interfacial agent is not easy to after preparing interfacial agent to interface
The quality of activating agent is tested, and is not easy to control the quality of interfacial agent.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of preparations of resin extender interfacial agent
Method.
A kind of preparation method of resin extender interfacial agent proposed by the present invention, comprising the following steps:
S1: pentyl acetate, titanate coupling agent, fatty alcohol polyoxyethylene ether, carbonic acid raw material weighing: are weighed according to the proportion
Calcium, butyl acetate, are waited to be used；
S2: it is stirred: mixing is stirred to pentyl acetate and fatty alcohol polyoxyethylene ether, the first mixture is made,
Then calcium carbonate and butyl acetate are stirred mixing, the second mixture are made, finally by the first mixture
It is stirred mixing with the second mixture, and titanate coupling agent is added and stirs evenly, third mixture is made；
S3: heating reaction: third mixture described in S2 is put into consersion unit, and the temperature of consersion unit is 50-
65 DEG C, the reaction time is set as 50-60min；
S4: cooling: the third mixture heating described in the S3 after the reaction was completed, cools down the mixture after reaction
Interfacial agent sample is made in cooling；
S5: it examines: testing to the quality of interfacial agent sample described in S4, can be prepared by setting after the assay was approved
Rouge filler interfacial agent；
S6: packaging: packing resin extender described in S5 with interfacial agent, storage storage.
Preferably, in the S1, using weighing equipment successively to pentyl acetate, titanate coupling agent, fatty alcohol polyoxy second
Alkene ether, calcium carbonate, butyl acetate are weighed, and are put into storage container and are kept in after the completion of weighing.
Preferably, in the S2, pentyl acetate and fatty alcohol polyoxyethylene ether are put into blender, mixing time setting
For 30min, blender revolving speed is 270 turns/min.
Preferably, in the S3, third mixture described in S2 is put into reaction kettle, the temperature of consersion unit is
52-62 DEG C, the reaction time is set as 53-58min.
Preferably, in the S5,30mL interfacial agent sample is taken to put into 60mL colorimetric cylinder, estimates its appearance, it is qualified
Interfacial agent sample be free flowing liquid or paste.
Preferably, it in the S5, measures 10mL interfacial agent sample and puts into beaker, 220mL is added into beaker and steams
Distilled water is stirred the object in beaker with stirring rod, observing interface activating agent sample situation miscible with water is observed, to interface
The dissolubility of activating agent sample is tested.
Preferably, it in the S5, is touched by SY/T5549-1990 surfactant liquid and lifts method measurement interfacial agent sample
Surface tension.
Preferably, in the S6, barreled is carried out with interfacial agent to resin extender, and carry out encapsulation process, deposited in
At cool place is dry.
Beneficial effects of the present invention: being tested by appearance, dissolubility and the surface tension to interfacial agent sample,
The quality that can recognize interfacial agent sample in time, controls the quality of interfacial agent sample, prevents boundary inferior
Face activating agent comes into the market.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment
A kind of preparation method of resin extender interfacial agent is proposed in the present embodiment, comprising the following steps:
S1: pentyl acetate, titanate coupling agent, fatty alcohol polyoxyethylene ether, carbonic acid raw material weighing: are weighed according to the proportion
Calcium, butyl acetate, are waited to be used；
S2: it is stirred: mixing is stirred to pentyl acetate and fatty alcohol polyoxyethylene ether, the first mixture is made,
Then calcium carbonate and butyl acetate are stirred mixing, the second mixture are made, finally by the first mixture
It is stirred mixing with the second mixture, and titanate coupling agent is added and stirs evenly, third mixture is made；
S3: heating reaction: third mixture described in S2 is put into consersion unit, and the temperature of consersion unit is 50-
65 DEG C, the reaction time is set as 50-60min；
S4: cooling: the third mixture heating described in the S3 after the reaction was completed, cools down the mixture after reaction
Interfacial agent sample is made in cooling；
S5: it examines: testing to the quality of interfacial agent sample described in S4, can be prepared by setting after the assay was approved
Rouge filler interfacial agent；
S6: packaging: packing resin extender described in S5 with interfacial agent, storage storage.
In the present embodiment, in S1, using weighing equipment successively to pentyl acetate, titanate coupling agent, fatty alcohol polyoxy second
Alkene ether, calcium carbonate, butyl acetate are weighed, and are put into storage container and are kept in after the completion of weighing, in S2,
Pentyl acetate and fatty alcohol polyoxyethylene ether are put into blender, mixing time is set as 30min, and blender revolving speed is 270
Turn/min, in S3, the third mixture in S2 is put into reaction kettle, the temperature of consersion unit is 52-62 DEG C, and the reaction time sets
It is set to 53-58min, in S5, takes 30mL interfacial agent sample to put into 60mL colorimetric cylinder, estimate its appearance, qualified interface
Activating agent sample is free flowing liquid or paste, in S5, measures 10mL interfacial agent sample and puts into beaker, to beaker
Interior addition 220mL distilled water is stirred the object in beaker with stirring rod, observes observing interface activating agent sample and water is mutual
Molten situation tests to the dissolubility of interfacial agent sample, in S5, touches and mentions by SY/T5549-1990 surfactant liquid
The method of rising measures interfacial agent sample surfaces tension, in S6, carries out barreled with interfacial agent to resin extender, and be sealed
Processing, in a cool and dry place, the beneficial effects of the invention are as follows pass through appearance, dissolubility and the table to interfacial agent sample for storage
Face tension is tested, and can recognize the quality of interfacial agent sample in time, is carried out to the quality of interfacial agent sample
Control, prevents interfacial agent inferior from coming into the market.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of preparation method of resin extender interfacial agent, which comprises the following steps:
S1: pentyl acetate, titanate coupling agent, fatty alcohol polyoxyethylene ether, calcium carbonate, two raw material weighing: are weighed according to the proportion
2-Butoxyethyl acetate waits to be used；
S2: it is stirred: mixing is stirred to pentyl acetate and fatty alcohol polyoxyethylene ether, the first mixture is made, then
Calcium carbonate and butyl acetate are stirred mixing, the second mixture is made, finally by the first mixture and the
Two mixtures are stirred mixing, and titanate coupling agent is added and stirs evenly, and third mixture is made；
S3: heating reaction: third mixture described in S2 is put into consersion unit, and the temperature of consersion unit is 50-65 DEG C,
Reaction time is set as 50-60min；
S4: cooling: the third mixture heating described in the S3 after the reaction was completed, carries out cooling drop to the mixture after reaction
Interfacial agent sample is made in temperature；
S5: it examines: testing to the quality of interfacial agent sample described in S4, can be prepared by resin after the assay was approved and fill out
Material uses interfacial agent；
S6: packaging: packing resin extender described in S5 with interfacial agent, storage storage.
2. a kind of preparation method of resin extender interfacial agent according to claim 1, which is characterized in that the S1
In, using weighing equipment successively to pentyl acetate, titanate coupling agent, fatty alcohol polyoxyethylene ether, calcium carbonate, diethylene glycol fourth
Ether acetate is weighed, and is put into storage container and is kept in after the completion of weighing.
3. a kind of preparation method of resin extender interfacial agent according to claim 1, which is characterized in that the S2
In, pentyl acetate and fatty alcohol polyoxyethylene ether are put into blender, mixing time is set as 30min, and blender revolving speed is
270 turns/min.
4. a kind of preparation method of resin extender interfacial agent according to claim 1, which is characterized in that the S3
In, third mixture described in S2 is put into reaction kettle, the temperature of consersion unit is 52-62 DEG C, and the reaction time is set as
53-58min。
5. a kind of preparation method of resin extender interfacial agent according to claim 1, which is characterized in that the S5
In, it takes 30mL interfacial agent sample to put into 60mL colorimetric cylinder, estimates its appearance, qualified interfacial agent sample is freely
Working fluid or paste.
6. a kind of preparation method of resin extender interfacial agent according to claim 1, which is characterized in that the S5
In, it measures 10mL interfacial agent sample and puts into beaker, 220mL distilled water is added into beaker, with stirring rod in beaker
Object be stirred, observe observing interface activating agent sample situation miscible with water, to the dissolubility of interfacial agent sample into
Performing check.
7. a kind of preparation method of resin extender interfacial agent according to claim 1, which is characterized in that the S5
In, it is touched by SY/T5549-1990 surfactant liquid and lifts method measurement interfacial agent sample surfaces tension.
8. a kind of preparation method of resin extender interfacial agent according to claim 1, which is characterized in that the S6
In, barreled is carried out with interfacial agent to resin extender, and carry out encapsulation process, storage is in a cool and dry place.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810887966.XA CN109021538A (en) | 2018-08-07 | 2018-08-07 | A kind of preparation method of resin extender interfacial agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810887966.XA CN109021538A (en) | 2018-08-07 | 2018-08-07 | A kind of preparation method of resin extender interfacial agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109021538A true CN109021538A (en) | 2018-12-18 |
Family
ID=64649685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810887966.XA Pending CN109021538A (en) | 2018-08-07 | 2018-08-07 | A kind of preparation method of resin extender interfacial agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109021538A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4210571A (en) * | 1978-09-28 | 1980-07-01 | Nl Industries, Inc. | Surfactants and their use as coupling agents in thermosetting polymers |
| CN107140871A (en) * | 2017-07-04 | 2017-09-08 | 陶华东 | A kind of artificial marble levelling agent |
| CN107815084A (en) * | 2017-11-02 | 2018-03-20 | 安徽迈高化工科技有限公司 | A kind of preparation method of resin extender interfacial agent |
-
2018
- 2018-08-07 CN CN201810887966.XA patent/CN109021538A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4210571A (en) * | 1978-09-28 | 1980-07-01 | Nl Industries, Inc. | Surfactants and their use as coupling agents in thermosetting polymers |
| CN107140871A (en) * | 2017-07-04 | 2017-09-08 | 陶华东 | A kind of artificial marble levelling agent |
| CN107815084A (en) * | 2017-11-02 | 2018-03-20 | 安徽迈高化工科技有限公司 | A kind of preparation method of resin extender interfacial agent |
Non-Patent Citations (1)
| Title |
|---|
| 杨龙 主编: "《精细化工产品分析检测设计与实施》", 30 June 2012, 武汉理工大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103361195B (en) | Cleaning-waxing-integrated washing agent for automobile and preparation method thereof | |
| CN101948555B (en) | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder | |
| CN103497339A (en) | Hydroxyl polyether-terminated polydimethylsiloxane and blue light emulsion of hydroxyl polyether-terminated polydimethylsiloxane as well as preparation method of blue light emulsion | |
| JP5422155B2 (en) | Liquid detergent composition | |
| CN105199512B (en) | A kind of water-based hydrophobic agent and preparation method thereof | |
| CN105886170A (en) | Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof | |
| CN104356377A (en) | Polyether-type refining agent and preparation method | |
| CN106833918B (en) | Quantitative fabric softening detergent | |
| US20100234270A1 (en) | Organic Cleaning Composition | |
| CN109021538A (en) | A kind of preparation method of resin extender interfacial agent | |
| CN104233805B (en) | A kind of yarn sizing agent | |
| CN108391661A (en) | A kind of broad-spectrum pesticide aqueous suspension agent special assistant and preparation method thereof | |
| CN102408957B (en) | High-property pulp-shaped fluorescent whitening agent and preparation method thereof | |
| JP2012205567A (en) | Antifoaming agent for use in fermentation | |
| CN106675875B (en) | A kind of ceramics paraffin removal cleaning agent and preparation method thereof | |
| CN105885549A (en) | Waterproof rubber coating formula and preparation method of waterproof rubber coating | |
| CN105860677A (en) | Rubber coating formula and preparation method thereof | |
| CN105838133B (en) | Emulsion detergent for ink and preparation method thereof | |
| CN106906059A (en) | A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application | |
| CN106519782A (en) | Paint scavenger and preparation method thereof | |
| WO2019123343A1 (en) | Laundry detergent composition | |
| CN104560055B (en) | A kind of lysotropic liquid crystal and its production and use | |
| CN110484182B (en) | Photo-thermal dual-curing black shading resin composition and preparation method thereof | |
| JP2010047656A (en) | Liquid detergent composition | |
| JP5422154B2 (en) | Liquid detergent composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181218 |