CN109010885A - A kind of essence emulsion gel composition and its preparation and application - Google Patents
A kind of essence emulsion gel composition and its preparation and application Download PDFInfo
- Publication number
- CN109010885A CN109010885A CN201811078378.8A CN201811078378A CN109010885A CN 109010885 A CN109010885 A CN 109010885A CN 201811078378 A CN201811078378 A CN 201811078378A CN 109010885 A CN109010885 A CN 109010885A
- Authority
- CN
- China
- Prior art keywords
- essence
- preparation
- emulsion gel
- parts
- regenerated cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
Abstract
The present invention relates to a kind of essence emulsion gel composition and its preparations and application, and in parts by weight, raw material components include: regenerated cellulose suspension, essence, gelling agent.Preparation: regenerated cellulose and essence prepare essence/cellulose lotion of stable dispersion, and addition can obtain so, cured preparation solid-state essence emulsion gel.The present invention use biological material prepare essence emulsion gel, green, environmental protection, safety, have biocompatibility and can biodegradability, can be used for indoor type solid pleasant smell agent, have potential using value in fields such as biological medicine, cosmetics, food.
Description
Technical field
The invention belongs to type solid pleasant smell agent and its preparation and application field, in particular to a kind of essence emulsion gel composition
And its it prepares and applies.
Background technique
Perfume can not only give the fine smell of people and enjoy, while can also assign people's feelings of romance.Solid air
At the beginning of freshener appears in external 70 generations earliest, it is mainly used for car, household bedroom or parlor restaurant and other Colosseums
Institute.The basic principle of the product is: the components such as essence, emulsifier being mixed, water and thickener form solid colloidal object, this is gluey
Object is placed in air, to achieve the purpose that make air fragrant, pure and fresh.In recent years, solidifying using biological material preparation lotion
Glue has been to be concerned by more and more people for type solid pleasant smell agent.One side biological material emulsion gel is green safe, to skin
For more sensitive Asian, biological material is safer.Biomass emulsion gel can be used as bioactivity
Substance and functional materials carrier, especially protein and polysaccharide emulsion gel, it is verified that being used for solid freshener (king
Development [J] the science and technology in enterprise and development of Kui hall solid air freshening agent, 2004 (1): 22-24.).On the other hand using biology
Matter can be biodegradable, and energy conservation and environmental protection is suitble to conservation culture.Therefore, a kind of emulsion gel based on biological material is developed
Type solid pleasant smell agent is of great significance.
Pickering lotion refers to the lotion for replacing conventional surfactant stable using solid particle.With traditionally make
It is compared with the lotion of surfactant, Pickering has many advantages, such as small dosage, small toxicity to human body, no pollution to the environment.
Therefore, Pickering lotion has huge application value (Berton- in fields such as chemical industry, cosmetics, biological medicines
Carabin C C, K.Annual review of food science and technology,2015,6:
263-297.).Cellulose is that content is most abundant in nature, is distributed widest boiomacromolecule.Jiang Yang etc. uses dissolution again
Raw method is prepared for regenerated cellulose, and yield is high, and suspension stability is good, finds simultaneously, and regenerated cellulose can be used for stablizing
Pickering lotion has very broad application prospect (Jiang, Yang, et al. " Cellulose- in fields such as daily use chemicals
rich oleogels prepared with an emulsion-templated approach."Food
Hydrocolloids 77(2018):460-464.)。
Polysaccharide (Curdlan, also known as can obtain so) is the extracellular straight chain by bacterial fermentation production without branch β-(1, the 3) Portugal-D-
Glycan is a kind of green safe thermal gels, and curdlan in 1996 is authenticated by United States Food and Drag Administration (FDA),
It is used as additive (Cui Yuan Changchun University of Science and Technology, 2013.) in daily use chemicals.But do not have surface-active so due to that can obtain, it is unable to shape
At stable lotion, therefore limit the application that can be obtained so on emulsion gel.
The type solid pleasant smell agent main component that existing market uses is (the patents such as essence, seaweed glue, surfactant
CN201610869660.2), it is widely used in various living scenes.Studies have shown that living compared to the surface of small molecule
Property agent, solid particle formed Pickering lotion it is safer, be not easy to cause allergic symptom, be suitable for skin sensitivity Asia
Crowd.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of type solid pleasant smell agent and its preparations and application, overcome existing skill
Art easily causes the defect of human allergy, and the present invention prepares Pickering cream by emulsion stabilizer of regenerated cellulose solid particle
Liquid, addition can obtain so as gelling agent, be oily phase with essence, prepare solid essence polysaccharide emulsion gel, be used for indoor air
Aromatic, green, environmental protection, safety have huge application prospect.
A kind of essence emulsion gel composition of the invention, in parts by weight, raw material components include:
43-99 parts of regenerated cellulose suspension；
0.1-50 parts of essence；
1-7 parts of gelling agent.
The regenerated cellulose suspension is regenerated cellulose particles suspension.
The gelling agent is that can obtain so.
The essence is natural essence.
The natural essence is one of Mint Essence, lavender oil, flavoring rose essence, lemon extract, cream jasmin france
Or it is several.A kind of preparation method of essence emulsion gel composition of the invention, comprising:
(1) then essence not soluble in water is added as oil in the regeneration nano-cellulose suspension for taking different quality containing
Phase, homogeneous obtain Pickering lotion；
(2) gelling agent will be added in above-mentioned Pickering lotion, stirs, solidify to get solid-state essence emulsion gel.
The preferred embodiment of above-mentioned preparation method is as follows:
The mass fraction of regenerated cellulose suspension is 0.1%-4% in the step (1).
In the step (1) in Pickering emulsion components, the mass fraction of oily phase is 0.1%-50%.
Homogeneous revolving speed is 3000rpm-10000rpm, homogenizing time 1-5min in the step (1).
In the step (2) in emulsion gel component, gel agent content is 1%-7% in water phase.
It is cured as being heating and curing in the step (2) or ultrasonic curing.
It is described to be heating and curing to specifically refer to be heated to 50-90 DEG C, 0.2-5h is kept the temperature, is subsequently cooled to 20-0 DEG C.
The ultrasonic curing are as follows: use cell disruptor, ultrasonic power 50-1000W, ultrasonic time 1-5min.
A kind of application of essence emulsion gel composition of the invention, the application as type solid pleasant smell agent.
Beneficial effect
For the present composition using regenerated cellulose particles as emulsion stabilizer, essence is oily phase, preparation Pickering cream
Liquid, gelling agent, which is added, can obtain so, stir, solidification, to obtain a kind of solid or semisolid product, which includes healthy, green
Color, environmental protection may be used as indoor type solid pleasant smell agent, have huge application prospect；Use surfactant steady with existing
Fixed type solid pleasant smell agent is compared, and the present invention stablizes Pickering lotion using solids (regeneration nano-cellulose) and prepares admittedly
Body aromatic is not easy to cause the generation of allergic symptom, safer, reliably.
The essence emulsion gel that the present invention uses biological material to prepare, green, safety, the stabilizer and gelling agent used
For polysaccharide macro-molecular, there is biocompatibility and biodegradability, can be used for the fields such as solid freshener.
Detailed description of the invention
Fig. 1-3 is the essence emulsion gel rheology characterization for respectively being embodiment 1-3 preparation；(storage modulus is (real in figure
Point) it is greater than loss modulus, show that emulsion gel has class solidity matter)；
Fig. 4 is essence emulsion gel prepared by embodiment 1.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, those skilled in the art
Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Range.
The preparation of regenerated cellulose suspension is equal in embodiment are as follows: 2g wood-pulp board is added in three-necked flask, be added 6mL go from
The phosphoric acid that sub- water and 100mL concentration are 85%, stirs at 0 DEG C and obtains cellulose solution for 24 hours, be added to 500mL deionized water
The middle wadding fibrous element of regeneration, stirring are centrifuged to pH=7, obtain the regenerated cellulose suspension of different quality containing.
Embodiment 1
In parts by weight:
Mass fraction is 68 parts of 0.5% regenerated cellulose suspension；
30 parts of Peppermint essential oil；
Gelling agent can obtain so 2 parts；
The regenerated cellulose suspension of corresponding parts by weight is taken, Peppermint essential oil is added, is turned in homogenizer with 5000rpm
Fast homogenous disperse 3min to get arrive stable Peppermint essential oil Pickering lotion.Being added in lotion can obtain so, stirring, 70 DEG C of guarantors
Warm 1h is cooled to 20 DEG C, keeps the temperature 0.5h, prepares essence emulsion gel.
The essence gel of 1mm thickness is taken to be placed on the plate of 50mm, control shape becomes 1%, shear velocity 0.1Hz-10Hz.
By test, essence emulsion gel gel modulus is 1020Pa.
Embodiment 2
In parts by weight:
Mass fraction is 67 parts of regenerated cellulose suspension of 0.3%；
30 parts of Rosa Damascana；
Gelling agent can obtain so 3 parts；
The regenerated cellulose suspension of corresponding number is taken, Rosa Damascana is added, it is equal with the revolving speed of 5000rpm in homogenizer
Matter disperses 2min to get stable Peppermint essential oil Pickering lotion is arrived.Being added in lotion can obtain so, stirring, ultrasound, power
300W, time 1min, prepare essence emulsion gel, and essence emulsion gel gel modulus is 1150Pa.
Embodiment 3
In parts by weight:
Mass fraction is 87 parts of regenerated cellulose suspension of 0.4%；
10 parts of Mint Essence；
Gelling agent can obtain so 3 parts；
The regenerated cellulose suspension of corresponding number is taken, lemon is added, it is equal with the revolving speed of 8000rpm in homogenizer
Matter disperses 3min to get stable Peppermint essential oil Pickering lotion is arrived.Being added in lotion can obtain so, stirring, ultrasound, power
500W, time 1min prepare essence emulsion gel.Essence emulsion gel gel modulus is 2310Pa.
Claims (10)
1. a kind of essence emulsion gel composition, in parts by weight, raw material components include:
43-99 parts of regenerated cellulose suspension；
0.1-50 parts of essence；
1-7 parts of gelling agent.
2. composition according to claim 1, which is characterized in that the mass fraction of the regenerated cellulose suspension is
0.1%-4%.
3. composition according to claim 1, which is characterized in that the gelling agent is that can obtain so, and essence is natural essence.
4. composition according to claim 3, which is characterized in that the natural essence is Mint Essence, lavender oil, rose
One or more of rare essence, lemon extract, cream jasmin france.
5. a kind of preparation method of essence emulsion gel composition as described in claim 1, comprising:
(1) regenerated cellulose suspension is taken, essence is then added, homogeneous obtains Pickering lotion；
(2) gelling agent will be added in above-mentioned Pickering lotion, stirs, solidify to get type solid pleasant smell agent.
6. preparation method according to claim 5, which is characterized in that homogeneous revolving speed is 3000rpm- in the step (1)
10000rpm, homogenizing time 1-5min.
7. preparation method according to claim 5, which is characterized in that be cured as being heating and curing in the step (2) or ultrasound
Solidification.
8. preparation method according to claim 7, which is characterized in that it is described to be heating and curing to be specially to be heated to 50-90 DEG C,
0.2-5h is kept the temperature, is subsequently cooled to 20-0 DEG C.
9. preparation method according to claim 7, which is characterized in that the ultrasonic curing are as follows: use cell disruptor, ultrasound
Power is 50-1000W, ultrasonic time 1-5min.
10. a kind of application of essence emulsion gel composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811078378.8A CN109010885A (en) | 2018-09-13 | 2018-09-13 | A kind of essence emulsion gel composition and its preparation and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811078378.8A CN109010885A (en) | 2018-09-13 | 2018-09-13 | A kind of essence emulsion gel composition and its preparation and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109010885A true CN109010885A (en) | 2018-12-18 |
Family
ID=64622484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811078378.8A Pending CN109010885A (en) | 2018-09-13 | 2018-09-13 | A kind of essence emulsion gel composition and its preparation and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109010885A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111671961A (en) * | 2020-07-16 | 2020-09-18 | 江西中医药大学 | Compound plant essential oil air freshener and preparation method thereof |
| CN113875970A (en) * | 2021-09-10 | 2022-01-04 | 东华大学 | Polysaccharide-based emulsion gel and preparation method thereof |
| CN114569474A (en) * | 2022-03-09 | 2022-06-03 | 山东省食品发酵工业研究设计院 | Vitamin E nanoemulsion and preparation method thereof |
| CN115551558A (en) * | 2020-05-19 | 2022-12-30 | 宝洁公司 | Method for making freshening compositions comprising particles suspended in structured aqueous compositions |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20150082870A (en) * | 2014-01-08 | 2015-07-16 | 주식회사 코스메카코리아 | A water-in-oil pickering emulsion cosmetic composition and process of the preparation thereof |
| CN104968374A (en) * | 2012-10-26 | 2015-10-07 | 陶氏环球技术有限责任公司 | Aqueous fragrance release gels |
| CN105838501A (en) * | 2016-03-29 | 2016-08-10 | 南京工业大学 | Slow-release essence microcapsule and preparation method thereof |
| CN108064976A (en) * | 2017-12-21 | 2018-05-25 | 东华大学 | A kind of method that polysaccharide emulsion gel is prepared using Pickering lotions |
-
2018
- 2018-09-13 CN CN201811078378.8A patent/CN109010885A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104968374A (en) * | 2012-10-26 | 2015-10-07 | 陶氏环球技术有限责任公司 | Aqueous fragrance release gels |
| KR20150082870A (en) * | 2014-01-08 | 2015-07-16 | 주식회사 코스메카코리아 | A water-in-oil pickering emulsion cosmetic composition and process of the preparation thereof |
| CN105838501A (en) * | 2016-03-29 | 2016-08-10 | 南京工业大学 | Slow-release essence microcapsule and preparation method thereof |
| CN108064976A (en) * | 2017-12-21 | 2018-05-25 | 东华大学 | A kind of method that polysaccharide emulsion gel is prepared using Pickering lotions |
Non-Patent Citations (4)
| Title |
|---|
| 丁安伟等: "《中药资源综合利用与产品开发》", 30 April 2013 * |
| 白世贞等: "《基础商品学》", 30 June 2014, 中国财富出版社 * |
| 蒋阳等: "Cellulose-rich oleogels prepared with an emulsion-templated approach", 《FOOD HYDROCOLLOIDS》 * |
| 薛巍等: "《生物医用水凝胶》", 31 December 2012 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115551558A (en) * | 2020-05-19 | 2022-12-30 | 宝洁公司 | Method for making freshening compositions comprising particles suspended in structured aqueous compositions |
| CN111671961A (en) * | 2020-07-16 | 2020-09-18 | 江西中医药大学 | Compound plant essential oil air freshener and preparation method thereof |
| CN113875970A (en) * | 2021-09-10 | 2022-01-04 | 东华大学 | Polysaccharide-based emulsion gel and preparation method thereof |
| CN113875970B (en) * | 2021-09-10 | 2024-04-12 | 东华大学 | Polysaccharide-based emulsion gel and preparation method thereof |
| CN114569474A (en) * | 2022-03-09 | 2022-06-03 | 山东省食品发酵工业研究设计院 | Vitamin E nanoemulsion and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109010885A (en) | A kind of essence emulsion gel composition and its preparation and application | |
| Tang et al. | Microencapsulation properties of soy protein isolate and storage stability of the correspondingly spray-dried emulsions | |
| CN108752603A (en) | A kind of preparation method of starch base Pickering emulsion gels | |
| JP2006045491A (en) | Functional material, method for producing functional material, functional member and environment modification apparatus using the functional material | |
| CN104257519A (en) | Pineapple leaf nanocellulose moisturizing skin-whitening washing gel mask and preparation method thereof | |
| CN108618146A (en) | By the phytosterol nanoemulsions and the preparation method and application thereof of soybean protein-steviol glycoside stable composition | |
| Yang et al. | An investigation into the application of konjac glucomannan as a flavor encapsulant | |
| Feng et al. | Adjusting the interfacial property and emulsifying property of cellulose nanofibrils by ultrasonic treatment combined with gelatin addition | |
| CN110743472A (en) | Essential oil microcapsule composition, essential oil microcapsule and preparation method thereof | |
| CN109316439A (en) | A kind of suspension maintenance Essence containing Crithmum maritimum stem cell | |
| CN104800124A (en) | Cosmetic raw material composition for preventing skin aging and cosmetics containing same | |
| CN106236605A (en) | Porous microsphere and preparation method thereof, application | |
| CN105769601A (en) | Walnut enzyme whitening and nourishing mud mask and preparation method thereof | |
| CN106380524B (en) | A kind of preparation method and applications of cold water soluble composite modified starch | |
| CN102718990A (en) | Method for preparing high-stable sweet potato pectin emulsion | |
| CN109453071A (en) | A kind of rosemary bacteriostatic hand sanitizer and preparation method thereof | |
| CN108902326A (en) | A kind of novel soybean milk powder formula | |
| CN102423289A (en) | Beautifying membrane capable of complete absorption | |
| CN107812223A (en) | A kind of air freshener | |
| CN113100417B (en) | Food-grade Pickering emulsion with stable pollen grains and preparation method thereof | |
| CN105748358A (en) | Aquilaria agallocha essence activating lotion and preparation method thereof | |
| CN109453040A (en) | A kind of nanoscale wormwood odor type facial mask basal liquid and preparation method thereof | |
| CN108578262A (en) | A kind of production method of the moisturizing lipstick containing alkannin liposome | |
| CN114432221A (en) | Lifting and tightening anti-aging essence and preparation method thereof | |
| CN1891205A (en) | Glossy ganoderma nutrient cream and its preparing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181218 |
|
| RJ01 | Rejection of invention patent application after publication |