CN108997761A - A kind of precision-investment casting rosin basic mode material and preparation method thereof - Google Patents

A kind of precision-investment casting rosin basic mode material and preparation method thereof Download PDF

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Publication number
CN108997761A
CN108997761A CN201810939167.2A CN201810939167A CN108997761A CN 108997761 A CN108997761 A CN 108997761A CN 201810939167 A CN201810939167 A CN 201810939167A CN 108997761 A CN108997761 A CN 108997761A
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CN
China
Prior art keywords
parts
rosin
paraffin
eva
high pressure
Prior art date
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Pending
Application number
CN201810939167.2A
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Chinese (zh)
Inventor
董寅生
周长军
唐荣俊
唐荣彪
周文星
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINGHUA XINGDONG CAST STEEL Co Ltd
Southeast University
Original Assignee
XINGHUA XINGDONG CAST STEEL Co Ltd
Southeast University
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Application filed by XINGHUA XINGDONG CAST STEEL Co Ltd, Southeast University filed Critical XINGHUA XINGDONG CAST STEEL Co Ltd
Priority to CN201810939167.2A priority Critical patent/CN108997761A/en
Publication of CN108997761A publication Critical patent/CN108997761A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00Compositions of natural resins; Compositions of derivatives thereof
    • C08L93/04Rosin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C7/00Patterns; Manufacture thereof so far as not provided for in other classes
    • B22C7/02Lost patterns
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

Abstract

The invention discloses a kind of precision-investment casting rosin basic mode material and preparation method thereof, the rosin basic mode material is mainly prepared by the raw material of following parts by weight: 7~9 parts of rosin, 43~51 parts of newtrexes, 27~30 parts of paraffin, 9~11 parts of microwaxes, 2~5 parts of high pressure polyethylenes, 1~4 part of ethylene-vinyl acetate copolymer (EVA).Preparation method are as follows: under heating conditions, various raw materials are mixed evenly into transparent liquid, cooling obtains after filtering.Rosin basic mode stream disclosed by the invention moves property and good moldability, and thermal expansion coefficient is small and stablizes, and has certain intensity and surface hardness, does not chemically react with paint adhesion agent, and being coated with property is good, good welding performance, has good comprehensive performance.

Description

A kind of precision-investment casting rosin basic mode material and preparation method thereof
Technical field
The present invention relates to precision-investment casting production easily fusible pattern pattern wax material used, cast more particularly to a kind of precision-investment It makes with rosin basic mode material and preparation method thereof.
Background technique
Precision-investment casting is a kind of near net-shaped liquid metal moulding process.Its processing step is made of wax material The apperance for the implements cast out welds running gate system in apperance and prepares wax-pattern, then repeats in dip-coating in wax pattern surface Several layers of fireproof coating, and after successively sanding, drying and hardening, fusible pattern therein is melted with heating means such as steam and hot water and is gone It is demoulded, all fusing is lost wax-pattern, only surplus shell, then pours into molten metal from sprue gate, removes fireproof coating type after cooling Shell just obtains required metal casting.
Due to the accurate size of casting obtained by this way, corner angle are clear, surface is smooth, close to zero pendant most End form state, thus be a kind of Near net shape casting process, therefore also known as hot investment casting.
Precision-investment casting is very widely used in the industrial production.It is applicable not only to the various alloys of various types Casting, and the casting dimension produced is accurate, surface quality is higher than other casting methods or even other casting methods are difficult to Complexity, the high temperature resistant, the casting for being not easy to processing cast, can be used model casting.
In precision-investment casting production, wax-pattern is the apperance for forming casting type chamber, to obtain dimensional accuracy and surface Highly polished casting, first wax-pattern should inherently have high dimensional accuracy and surface smoothness.And wax-pattern manufacturing process The middle factor for influencing wax-pattern dimensional accuracy is more complicated, and technological parameter is more, so wax-pattern dimensional accuracy variation range is bigger. In addition, the performance of wax-pattern itself should also make the processes such as subsequent shell processed simple and easy as far as possible.To obtain the wax-pattern of high quality, remove The die mould that should have had (mold of compacting wax-pattern) is outside, it is necessary to select suitable pattern-making material (abbreviation mould material) and reasonably make Mold technique.
As melted module precise casting technology continues to develop, the technical standard of various precision castings is more and more tighter, so to mould material Technical requirements and performance it is also higher and higher.Currently, model casting precision castings towards integration, be thinning and enlargement hair Exhibition, the compacting of wax-pattern and the design of die mould encounter new challenge, it is desirable that mould material shrinking percentage is small, good stability of the dimension, mobility Good, flexural strength height, hardness height, surface is smooth and there is wetability refractory material to be made to be easily adhered to model surface.
Summary of the invention
Goal of the invention: being one of the critical component in aircraft engine and gas turbine because of no surplus precision castings blade, So mould material is the most important thing for improving precision castings surface quality and casting dimension stability.Based on the deficiencies of the prior art, originally It is good that the purpose of invention is to provide a kind of surface smoothness, and dimensional accuracy is high, high specific surface area, the small fusible pattern essence of temperature dependency Close casting rosin basic mode material and preparation method thereof.
Technical solution: to achieve the goals above, the invention discloses a kind of precision-investment casting rosin basic mode material, Mainly it is made of the raw material of following parts by weight:
7~9 parts of rosin, 43~51 parts of newtrexes, 27~30 parts of paraffin, 9~11 parts of microwaxes, 2~5 parts of poly- second of high pressure Alkene, 1~4 part of ethylene-vinyl acetate copolymer (EVA).
It is preferred that the rosin is primary rosin, newtrex is 140# newtrex, and paraffin is 60# paraffin, and microwax is 85# microwax.
Further preferably, component of the precision-investment casting with rosin basic mode material mainly by following weight ratio is made At:
7 parts of primary rosins, 43 parts of 140# newtrexes, 27 parts of 60# paraffin, 9 parts of 85# microwaxes, 2 parts of high pressure polyethylenes, 1 Part EVA.
As another preferred embodiment, the precision-investment casting is with rosin basic mode material mainly by the component of following weight ratio It is made:
9 parts of primary rosins, 51 parts of 140# newtrexes, 30 parts of 60# paraffin, 11 parts of 85# microwaxes, 5 parts of high pressure polyethylenes, 4 parts of EVA.
The present invention also provides the precision-investment casting preparation methods of rosin basic mode material, comprising the following steps:
(1) rosin, newtrex, paraffin, microwax, high pressure polyethylene and EVA are weighed in proportion;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into change paraffin pan, power transmission is melted;
(3) as mould material melts, it is gradually added into paraffin, makes (the 7- of height the remaining paraffin pan height of mould material 8)/10;
(4) before mould material is completely melt, it is passed through compressed air, accelerates the dissolution of high pressure polyethylene and EVA, excludes polymerization pine The bubble that perfume generates;
(5) have a power failure when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then after being stirred, When mould material temperature degree drops to 180 DEG C -200 DEG C, by mould material filter to get.
Before mould material described in step (4) is completely melt, i.e., when mould material melts 90% or so.
The time of stirring described in step (5) is 25-35 minutes, and filtering is filtered using 150#-200# sieve.
Technical effect: compared with the existing technology, rosin basic mode stream disclosed by the invention moves property and good moldability, thermal expansion Coefficient is small and stablizes, and has certain intensity and surface hardness, does not chemically react with paint adhesion agent, being coated with property is good, weldability Can be good, there is good comprehensive performance.
Specific embodiment
According to following embodiments, the present invention may be better understood.And as it will be easily appreciated by one skilled in the art that embodiment Described specific test result is merely to illustrate the present invention, without that should will not limit sheet described in claims Invention further explains the present invention below with reference to embodiment.
Embodiment 1:
(1) 7 parts of primary rosin, 51 parts of 140# newtrex, 27 parts of 60# paraffin, 10 parts of microwax, high pressure are weighed in proportion 3 parts and 2 parts of EVA of polyethylene;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into stainless steel paraffin pan, power transmission is melted Change;
(3) as mould material melts, it is gradually added into paraffin, makes (the 7- of height the remaining paraffin pan height of mould material 8)/10 or so;
(4) when mould material fusing 90% or so, insertion compressed air hose is passed through a small amount of compressed air, accelerates high pressure polyethylene With the dissolution of EVA, the bubble that newtrex generates is excluded;
(5) it when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then is stirred 30 minutes After have a power failure, mould material is filled into clean stainless steel disc with 150#-200# sieve when mould material temperature degree drops to 180 DEG C -200 DEG C Interior, wax ingot is stand-by.
Mould material performance: 94 DEG C of drop point, linear shrinkage 0.5%, bending strength 4.5MPa.
Embodiment 2:
(1) 9 parts of primary rosin, 43 parts of 140# newtrex, 30 parts of 60# paraffin, 9 parts of microwax, high pressure are weighed in proportion 2 parts and 3 parts of EVA of polyethylene;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into stainless steel paraffin pan, power transmission is melted Change;
(3) as mould material melts, it is gradually added into paraffin, makes (the 7- of height the remaining paraffin pan height of mould material 8)/10 or so;
(4) when mould material fusing 90% or so, insertion compressed air hose is passed through a small amount of compressed air, accelerates high pressure polyethylene With the dissolution of EVA, the bubble that newtrex generates is excluded;
(5) it when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then is stirred 30 minutes After have a power failure, mould material is filled into clean stainless steel disc with 150#-200# sieve when mould material temperature degree drops to 180 DEG C -200 DEG C Interior, wax ingot is stand-by.
Mould material performance: 89 DEG C of drop point, linear shrinkage 0.75%, bending strength 3.4MPa.
Embodiment 3:
(1) 8 parts of primary rosin, 48 parts of 140# newtrex, 28 parts of 60# paraffin, 11 parts of microwax, high pressure are weighed in proportion 4 parts and 1 part of EVA of polyethylene;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into stainless steel paraffin pan, power transmission is melted Change;
(3) as mould material melts, it is gradually added into paraffin, makes (the 7- of height the remaining paraffin pan height of mould material 8)/10 or so;
(4) when mould material fusing 90% or so, insertion compressed air hose is passed through a small amount of compressed air, accelerates high pressure polyethylene With the dissolution of EVA, the bubble that newtrex generates is excluded;
(5) it when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then is stirred 30 minutes After have a power failure, mould material is filled into clean stainless steel disc with 150#-200# sieve when mould material temperature degree drops to 180 DEG C -200 DEG C Interior, wax ingot is stand-by.
Mould material performance: 91 DEG C of drop point, linear shrinkage 0.62%, bending strength 3.7MPa.
Embodiment 4:
(1) 8 parts of primary rosin, 45 parts of 140# newtrex, 27 parts of 60# paraffin, 9 parts of microwax, high pressure are weighed in proportion 5 parts and 4 parts of EVA of polyethylene;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into stainless steel paraffin pan, power transmission is melted Change;
(3) as mould material melts, it is gradually added into paraffin, makes (the 7- of height the remaining paraffin pan height of mould material 8)/10 or so;
(4) when mould material fusing 90% or so, insertion compressed air hose is passed through a small amount of compressed air, accelerates high pressure polyethylene With the dissolution of EVA, the bubble that newtrex generates is excluded;
(5) it when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then is stirred 30 minutes After have a power failure, mould material is filled into clean stainless steel disc with 150#-200# sieve when mould material temperature degree drops to 180 DEG C -200 DEG C Interior, wax ingot is stand-by.
Mould material performance: 91 DEG C of drop point, linear shrinkage 0.77%, bending strength 4.1MPa.
Embodiment 5:
(1) 7 parts of primary rosin, 43 parts of 140# newtrex, 27 parts of 60# paraffin, 9 parts of microwax, high pressure are weighed in proportion 2 parts and 1 part of EVA of polyethylene;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into stainless steel paraffin pan, power transmission is melted Change;
(3) as mould material melts, it is gradually added into paraffin, makes (the 7- of height the remaining paraffin pan height of mould material 8)/10 or so;
(4) when mould material fusing 90% or so, insertion compressed air hose is passed through a small amount of compressed air, accelerates high pressure polyethylene With the dissolution of EVA, the bubble that newtrex generates is excluded;
(5) it when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then is stirred 25 minutes After have a power failure, mould material is filled into clean stainless steel disc with 150#-200# sieve when mould material temperature degree drops to 180 DEG C -200 DEG C Interior, wax ingot is stand-by.
Mould material performance: 88 DEG C of drop point, linear shrinkage 0.65%, bending strength 3.3MPa.
Embodiment 6:
(1) 9 parts of primary rosin, 51 parts of 140# newtrex, 30 parts of 60# paraffin, 11 parts of microwax, high pressure are weighed in proportion 5 parts and 4 parts of EVA of polyethylene;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into stainless steel paraffin pan, power transmission is melted Change;
(3) as mould material melts, it is gradually added into paraffin, makes (the 7- of height the remaining paraffin pan height of mould material 8)/10 or so;
(4) when mould material fusing 90% or so, insertion compressed air hose is passed through a small amount of compressed air, accelerates high pressure polyethylene With the dissolution of EVA, the bubble that newtrex generates is excluded;
(5) it when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then is stirred 35 minutes After have a power failure, mould material is filled into clean stainless steel disc with 150#-200# sieve when mould material temperature degree drops to 180 DEG C -200 DEG C Interior, wax ingot is stand-by.
Mould material performance: 92 DEG C of drop point, linear shrinkage 0.7%, bending strength 4.2MPa.

Claims (7)

1. a kind of precision-investment casting rosin basic mode material, which is characterized in that it is mainly prepared by the raw material of following parts by weight It forms:
7~9 parts of rosin, 43~51 parts of newtrexes, 27~30 parts of paraffin, 9~11 parts of microwaxes, 2~5 parts of high pressure polyethylenes, 1 ~4 parts of ethylene-vinyl acetate copolymers (EVA).
2. precision-investment casting according to claim 1 rosin basic mode material, which is characterized in that the rosin is level-one pine Perfume (or spice), newtrex are 140# newtrex, and paraffin is 60# paraffin, and microwax is 85# microwax.
3. precision-investment casting according to claim 1 rosin basic mode material, which is characterized in that it is mainly by following heavy The raw material of amount number is prepared: 7 parts of primary rosins, 43 parts of 140# newtrexes, 27 parts of 60# paraffin, 9 parts of 85# microwaxes, and 2 Part high pressure polyethylene, 1 part of EVA.
4. precision-investment casting according to claim 1 rosin basic mode material, which is characterized in that it is mainly by following heavy The raw material of amount number is prepared: 9 parts of primary rosins, 51 parts of 140# newtrexes, 30 parts of 60# paraffin, 11 parts of 85# microwaxes, and 5 Part high pressure polyethylene, 4 parts of EVA.
5. the preparation method of any one of claim 1-4 precision-investment casting rosin basic mode material, which is characterized in that including Following steps:
(1) rosin, newtrex, paraffin, microwax, high pressure polyethylene and EVA are weighed in proportion;
(2) high pressure polyethylene-EVA- microwax-newtrex-rosin is sequentially loaded into change paraffin pan, power transmission is melted;
(3) as mould material melts, be gradually added into paraffin, make (7-8) of height the remaining paraffin pan height of mould material/ 10;
(4) before mould material is completely melt, it is passed through compressed air, accelerates the dissolution of high pressure polyethylene and EVA, newtrex is excluded and produces Raw bubble;
(5) have a power failure when liquid surface bubble excludes substantially and high pressure polyethylene, EVA all dissolve, then after being stirred, to mould When material temperature degree drops to 180 DEG C -200 DEG C, by mould material filter to get.
6. the precision-investment casting according to claim 5 preparation method of rosin basic mode material, which is characterized in that step (4) before mould material described in is completely melt, i.e., when mould material melts 90% or so.
7. the precision-investment casting according to claim 5 preparation method of rosin basic mode material, which is characterized in that step (5) time of stirring described in is 25-35 minutes, and filtering is filtered using 150#-200# sieve.
CN201810939167.2A 2018-08-17 2018-08-17 A kind of precision-investment casting rosin basic mode material and preparation method thereof Pending CN108997761A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109735118A (en) * 2019-01-05 2019-05-10 青岛马基泰商贸有限公司 A kind of environment protection colour sealing wax and preparation method thereof, application
CN109759543A (en) * 2019-01-04 2019-05-17 丁勇 A kind of copper casted sculpture method for casting production
CN109880697A (en) * 2019-03-13 2019-06-14 东莞理工学院 A kind of special type candle wax material and special type candle

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Publication number Priority date Publication date Assignee Title
CN1281873A (en) * 2000-08-17 2001-01-31 上海交通大学 Ultra-fine mould material for lost wax process of adornment
CN102876054A (en) * 2012-09-03 2013-01-16 广西大学 Packing mold material used in investment precision casting

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1281873A (en) * 2000-08-17 2001-01-31 上海交通大学 Ultra-fine mould material for lost wax process of adornment
CN102876054A (en) * 2012-09-03 2013-01-16 广西大学 Packing mold material used in investment precision casting

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109759543A (en) * 2019-01-04 2019-05-17 丁勇 A kind of copper casted sculpture method for casting production
CN109735118A (en) * 2019-01-05 2019-05-10 青岛马基泰商贸有限公司 A kind of environment protection colour sealing wax and preparation method thereof, application
CN109735118B (en) * 2019-01-05 2023-10-24 青岛马基泰商贸有限公司 Environment-friendly color sealing wax and preparation method and application thereof
CN109880697A (en) * 2019-03-13 2019-06-14 东莞理工学院 A kind of special type candle wax material and special type candle

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Application publication date: 20181214