CN108996817A - A kind of cellular reaction unit in wastewater of construction processing - Google Patents

A kind of cellular reaction unit in wastewater of construction processing Download PDF

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Publication number
CN108996817A
CN108996817A CN201810812181.6A CN201810812181A CN108996817A CN 108996817 A CN108996817 A CN 108996817A CN 201810812181 A CN201810812181 A CN 201810812181A CN 108996817 A CN108996817 A CN 108996817A
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China
Prior art keywords
pipe
plate
cellular
reaction unit
fermentation tank
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CN201810812181.6A
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Chinese (zh)
Inventor
武永峰
袁明慧
魏静
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Jiangsu Institute of Architectural Technology
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Jiangsu Institute of Architectural Technology
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Priority to CN201810812181.6A priority Critical patent/CN108996817A/en
Publication of CN108996817A publication Critical patent/CN108996817A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C18/00—Disintegrating by knives or other cutting or tearing members which chop material into fragments
    • B02C18/0084—Disintegrating by knives or other cutting or tearing members which chop material into fragments specially adapted for disintegrating garbage, waste or sewage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C18/00—Disintegrating by knives or other cutting or tearing members which chop material into fragments
    • B02C18/06—Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives
    • B02C18/14—Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives within horizontal containers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08—Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/14—Separating or sorting of material, associated with crushing or disintegrating with more than one separator
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/30—Aerobic and anaerobic processes

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses the cellular reaction unit in a kind of processing of wastewater of construction, cellular reaction unit includes: pressurization air supply device, diversion pipe, serpentine heating pipe, honeycomb shell, dispersion plate；In cellular reaction unit, solution is flowed into from cellular reaction unit top, under dispersion plate peptizaiton, even into diversion pipe, and sprayed from water conservancy diversion pipe surface through-hole, serpentine heating pipe injection hot steam is mixed with solution, it is promoted to be reacted, being pressurized air supply device is that cellular reaction unit conveys fresh wind, and final solution is promoted to flow out from honeycomb surface of shell equipped with a large amount of through-holes.Cellular reaction unit in a kind of wastewater of construction processing of the present invention, easy to maintain, treatment effeciency is high, and device structure is simple, and operating condition is unrestricted.

Description

A kind of cellular reaction unit in wastewater of construction processing
Technical field
The invention belongs to sewage treatment equipment fields, and in particular to the cellular reaction in a kind of processing of wastewater of construction Device.
Background technique
Existing waste water control, there are still many defects: 1, processing intensity is non-adjustable, and application range relatively narrower, effect is paid no attention to Think；2, processing equipment is not easy cleaning-sterilizing.Sediment is easy accumulation in reaction unit, caking phenomenon easily occurs, this will be right Wastewater treatment efficiency generates certain influence.
Summary of the invention
In order to solve the above technical problem, the present invention provides the cellular reaction dresses in a kind of processing of wastewater of construction It sets, wherein waste water treatment system operating platform；The main water inlet tube 1,14 horizontal layout of primary flow pipe, main water inlet tube 1, main water outlet 14 diameter of pipe is made by 20cm~30cm, by high molecular material, main water inlet tube 1, primary flow pipe 14 respectively at anaerobic fermentation tank 3, Aerobic fermentation tank 6, electrochemical reaction appts 13 are connected to；Pulverizer 2, main water inlet tube 1 and powder are equipped in 1 upper right of main water inlet tube Broken machine 2 is connected to by percolate branch pipe 8；2 side of pulverizer is equipped with anaerobic fermentation tank 3, and 3 top of anaerobic fermentation tank is equipped with methane liter Tracheae 5,3 lower part of anaerobic fermentation tank are equipped with slag notch 12, and anaerobic fermentation tank 3 is connected to pulverizer 2 by feed pipe 4.
Further, this section is the explanation to heretofore described 2 structure of pulverizer.Superposed lower hopper 2-6, Lower part is penetrated through equipped with crushing bin 2-5, crushing bin 2-5 and lower hopper 2-6；Crushing knife 2-4, crushing knife are equipped with inside crushing bin 2-5 2-4 quantity is 2, and arranged opposite；The lower part crushing knife 2-4 is equipped with upper adjustable sieve plate 2-7, and the upper surface adjustable sieve plate 2-7 is equipped with A large amount of through-holes, upper adjustable 15~60 degree of sieve plate 2-7 horizontal sextant angle；The upper lower part adjustable sieve plate 2-7 is equipped with down adjustable sieve plate 2-3, on Adjustable sieve plate 2-7 and under the slit at a distance of 20cm~50cm is formed between adjustable sieve plate 2-3, comminuting matter is fallen under this slit Under the surface adjustable sieve plate 2-3, under the surface adjustable sieve plate 2-3 be equipped with a large amount of through-holes, 15~60 degree of angle with horizontal plane.
Further, this section is the explanation to heretofore described 3 structure of anaerobic fermentation tank.Stirring outside side Motor 3-1 is connect by transmission device with internal agitator arm 3-2；Agitator arm 3-2 and anaerobic fermentation tank 3 are contour, stirring Motor 3-1 drives agitator arm 3-2 rotation.
Further, this section is the explanation to heretofore described medicament mixing device 3-7 structure, the washing positioned at top Pipe 3-7-6, one end are connect with external water pump, and the other end is connect with the lotus spray-head inside medicament mixing device 3-7, lotus flower Spray head lower part is equipped with cellular reactor 3-7-3, and lotus spray-head implements cleaning to the cellular reactor 3-7-3 of lower part；It is described Cellular reactor 3-7-3 section is honeycomb, is vertically arranged and is formed by more honeycomb standpipes, cellular reactor 3-7- 3 up and down；Additive filler pipe 3-7-4, medicament injection pipe 3-7-5 are equipped in the side sluicing pipe 3-7-6；It mixes and fills in medicament It sets and is equipped with temperature sensor 3-7-7 in the middle part of 3-7, connect by conducting wire with control system 15.
Further, this section is the explanation to heretofore described electromagnetic oscillation device 3-7-9 structure.Electromagnetic oscillation device 3-7-9 shell up and down, axis line inside be equipped with vertical arrangement waterproof casing 3-7-9-8, electromagnetic oscillation device 3-7-9 with Intake tunnel 3-7-9-6 is formed between waterproof casing 3-7-9-8, is successively arranged from top to bottom inside waterproof casing 3-7-9-8 Vibration support 3-7-9-1, high-voltage capacitor 3-7-9-2, deuterated tetrachloroethanes isotope ring 3-7-9-3, deuterated tetrachloroethanes are same The plain emitting head 3-7-9-4 in position, ultraviolet emission lamp 3-7-9-5, electromagnetism agitate coil 3-7-9-7, middle-and high-voltage capacitor 3-7-9-2 It is connect with electromagnetism surge coil 3-7-9-7 conducting wire；The deuterated tetrachloroethanes isotope ring 3-7-9-3 is circular, one end with External high pressure gas cylinder connection, the deuterated tetrachloroethanes isotope upper surface ring 3-7-9-3 is sent out equipped with deuterated tetrachloroethanes isotope A 3-7-9-4 is penetrated, deuterated tetrachloroethanes isotope emitting head 3-7-9-4 quantity is 10, deuterated tetrachloroethanes isotope transmitting The head mutual equidistant arrangement of 3-7-9-4 is on deuterated tetrachloroethanes isotope ring 3-7-9-3.
Further, this section is the explanation to heretofore described 13 structure of electrochemical reaction appts.Positioned at one end into Water pot 13-1 is connected to by buffer pool flow pipe 13-2 with filter chamber 13-11；Electrochemical chamber is equipped in the filter chamber lower part 13-11 13-9 is equipped with filter screen 13-10 between filter chamber 13-11 and electrochemical chamber 13-9；Direct current is equipped with inside electrochemical chamber 13-9 Stick 13-4, direct current torch 13-4 are connect with external power supply conducting wire；The lower part electrochemical chamber 13-9 is equipped with mud chamber 13-3, electrochemical chamber Water Ecological Recovery halftone contact screen 13-6 is equipped between 13-9 and mud chamber 13-3, Water Ecological Recovery halftone contact screen 13-6 passes through aquatic State is repaired halftone contact screen bracket 13-7 and is fixedly connected with mud chamber 13-3；The mud chamber lower part 13-3 is equipped with sediment discharge pipe 13- 5。
Further, this section is the explanation to heretofore described 6 structure of aerobic fermentation tank.Heating rod 6- positioned at top 1, it connects to power supply, and connect with 15 polygon control survey of control system；It is equipped with air injection tube 6-2 in the lower part heating rod 6-1, it is empty The gas jet surface pipe 6-2 is equipped with a large amount of through-holes, and air injection tube 6-2 quantity is 10, is mutually equally spaced, air injection tube 6- 2 pipe ranges are 20cm~86cm, and diameter 20cm, the one end air injection tube 6-2 is connected to oxygen hose 9.
Further, this section is the explanation to heretofore described 16 structure of reclamation set.The flocculation deposition apparatus shell Inside body 16-5, most top position be equipped with polymeric aluminum dispersion pipe 16-4, polymeric aluminum dispersion pipe 16-4 rectangular ring structure, quantity 2 It is a, arranged in parallel, it is equipped with spray head on the polymeric aluminum surface dispersion pipe 16-4, spray head direction is downward, the one end polymeric aluminum dispersion pipe 16-4 It is connected to by middle storage tank water pump 16-7 with external middle storage tank 16-6, middle storage tank 16-6 storage polymerization aluminum solutions；In polymeric aluminum point The lower part separate tube 16-4 is equipped with macromolecule current stabilization sieve 16-3, mesh aperture 5mm~16mm, macromolecule current stabilization sieve 16-3 quantity It is 10, multiple macromolecule current stabilization sieve 16-3 or more are superimposed layout；The current stabilization wing is equipped in the macromolecule current stabilization lower part sieve 16-3 " Z " font is presented in plate 16-2, vertical cross section, and the quantity of current stabilization wing plate 16-2 is 10, multiple current stabilization wing plate 16-2 horizontal rows It arranges, is connect by cranking arm with external motor between adjacent current stabilization wing plate 16-2 at a distance of 2cm~6cm, multiple current stabilization wing plate 16-2, outside The concussion of portion's motor driven current stabilization wing plate 16-2 level.
Further, this section is the explanation of heretofore described cellular reaction unit 16-1 internal structure.Dispersion plate 16-1-5 disc, surface are equipped with a large amount of through-holes, and dispersion plate 16-1-5 quantity is 1, is located at the cellular top reaction unit 16-1 End；The lower part a dispersion plate 16-1-5 is equipped with diversion pipe 16-1-2, its underpart is closed, diversion pipe 16-1-2 quantity is 10, is led The surface flow tube 16-1-2 is equipped with a large amount of through-holes；Serpentine heating pipe 16-1-3, serpentine heating pipe are equipped in the periphery diversion pipe 16-1-2 The surface 16-1-3 is equipped with a large amount of through-holes, is connected to external heating device.
Further, this section is the explanation of heretofore described pressurization air supply device 16-1-1 structure.Positioned at one end Air supply motor 16-1-1-1 is connect by belt with air-supply driving wheel 16-1-1-2；The air-supply driving wheel 16-1-1-2 other end It is mechanically connected with fan blade 16-1-1-3, the fan blade 16-1-1-3 quantity is 6, fan blade 16-1-1-3 high score Sub- material, half arc of fan blade 16-1-1-3, multiple fan blade 16-1-1-3 to air-supply driving wheel 16-1-1-2 central axis Inclination, fan blade 16-1-1-3 itself are equipped with fixing axle and in waists；Air inlet is equipped on the top fan blade 16-1-1-3 16-1-1-4, air inlet 16-1-1-4 rectangle 450mm~450mm；The other side fan blade 16-1-1-3 is equipped with air outlet 16-1- 1-5, the other side air outlet 16-1-1-5 are equipped with air duct 16-1-1-6, and the two is connected to by filter screen 16-1-1-7, air duct 16-1- The 1-6 other end is connected to cellular reaction unit 16-1；In air duct, the junction 16-1-1-6 and fan blade 16-1-1-3 is equipped with Maintenance door 16-1-1-8.
Further, this section is the explanation of heretofore described lubricating oil fining device 16-1-1-9 structure.It is located at Lubricating oil refines the oil inlet 16-1-1-9-12 and oil outlet 16-1-1-9-4 for being located at the other end of the one end device 16-1-1-9 Perforation；Additive injection pipe 16-1-1-9-11 is equipped on the right side of oil inlet 16-1-1-9-12；In additive injection pipe 16-1-1- Freon pipe 16-1-1-9-1 is equipped on the right side of 9-11, freon pipe 16-1-1-9-1 annular is equipped with spray on the right side of its annular surface Mouth, the two perforation, nozzle quantity are 20, and multiple nozzles are in its annular surface equidistant arrangement；In freon pipe 16-1-1-9-1 Right side is equipped with impact-absorbing shell 16-1-1-9-10, and there are a large amount of through-holes on the surface impact-absorbing shell 16-1-1-9-10, on impact-absorbing shell 16-1-1-9-10 Pass through conducting wire and control system 15 equipped with fatty acid concentration sensor 16-1-1-9-9, fatty acid concentration sensor 16-1-1-9-9 Connection；Be equipped on the right side of impact-absorbing shell 16-1-1-9-10 stirring motor 16-1-1-9-8, its be waterproofing design, stirring motor 16-1-1- 9-8 transmission shaft passes through filter plate 16-1-1-9-3 and is fixedly connected with the agitator arm 16-1-1-9-5 on right side；The filter plate 16- 1-1-9-3 quantity is 2, surface is equipped with a large amount of through-holes, and filter plate 16-1-1-9-3 is respectively provided at agitator arm 16-1-1-9-5 Both ends；The agitator arm 16-1-1-9-5 is made of rectangle frame, and the rectangle frame is long × wide, and: 10mm × 40mm is horizontally arranged, is high Molecule material, agitator arm 16-1-1-9-5 quantity be 6, multiple agitator arm 16-1-1-9-5 along long side central axis angularly It is rotatably arranged；Fatty acid concentration sensor 16-1-1-9-9 be prior art products, ZFS-45 type fatty acid concentration sensor by Shanghai TM Sensor Co., Ltd.'s production.
Further, this section is the explanation of heretofore described 17 structure of sediment conveying device.Sediment conveying device Frame 17-5 be metal structure, oblong-shaped, sediment conveyor frame 17-5 length be 10m~30m, width be 50cm~ 80cm；The sediment lower part conveyor frame 17-5 is equipped with conveyor support 17-4, quantity is 4 and is divided into two groups, conveying dress It sets the adjustable and bottom of bracket 17-4 height and is equipped with movable pulley.
Further, the filtered fluid plate 3-6 is formed by high molecular material pressing mold, the constituent of filtered fluid plate 3-6 and Manufacturing process is as follows:
One, filtered fluid plate 3-6 constituent:
268.5~493.0 parts of pure water according to parts by weight, 3- methyl-4- (2,6,6- trimethyl-1- base)-3- butene-2 -one 60.3~102.7 parts, poly- (silicomethane) 63.2 that 1- methoxyl group -3,7- bis- [[3- (front three oxygen silicon base) the third oxygen] methyl] blocks~ 172.2 parts, 59.2~76.0 parts of methylvinyldichlorosilane, 62.6~119.1 parts of collagen powder, four hydrogen-based O-phthalic of methyl 65.2~126.5 parts of acid anhydrides, 67.0~122.6 parts of nanoscale lithium zirconate particle, polypropylene and dimethyl methyl ethylene silicon oxygen 62.9~102.6 parts of the polymer of 60.8~102.8 parts of the reaction product of alkane, formaldehyde and 1,3- benzene dimethylamine and phenol, isophthalic The polymer of diacid and terephthalic acids, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl 62.4~85.0 parts, 51.3~87.9 parts of -2 (or 3)-sodium sulfonate of 5- methoxycarbonyl -5- methyl norbornane, 2 methyl valeric acid 50.7~93.2 parts of butyl ester, formaldehyde and chloromethyloxirane and 4, the polymer and N- of 4'- (1- methyl ethylidene) biphenol 59.2~104.5 parts of the polymer of the reaction product of butyl butylamine and diethanol amine, 4- (nine fluoro butoxy) -1- fourth ichthyodin 69.7~113.0 parts of salt, mass concentration is 92.6~146.3 parts of alpha-brominated n-caproic acid of 59mg/L~326mg/L；
Two, the manufacturing process of filtered fluid plate 3-6 comprising the steps of:
Step 1: in double shaft mix reactor, pure water and 3- methyl -4- (2,6,6- trimethyl -1- base) -3- fourth is added Alkene -2- ketone starts the blender in double shaft mix reactor, and setting speed is 61rpm~107rpm, starts double shaft mix Fuel heater in reactor makes temperature rise to 76.5 DEG C~77.0 DEG C, and the [[3- (trimethoxy of 1- methoxyl group -3,7- bis- is added Silicon substrate) the third oxygen] methyl] and sealing end poly- (silicomethane) stir evenly, carry out reaction 53.3~64.7 minutes, be added methyl ethylene Dichlorosilane, being passed through flow is 52.5m3/ min~93.0m3The nitrogen of/min 53.3~64.7 minutes；Later in double shaft mix In reactor be added collagen powder, the fuel heater being again started up in double shaft mix reactor, make temperature rise to 93.2 DEG C~ 126.2 DEG C, 53.2~64.0 minutes are kept the temperature, four hydrogen-based phthalic anhydride of methyl is added, is adjusted in double shaft mix reactor The pH value of solution is 4.6~8.1, keeps the temperature 53.6~293.6 minutes；
Step 2: separately taking nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is surpassed in the case where power is 5.93KW~11.37KW After sonicated 0.59~1.126 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, is added The reaction product for entering polypropylene and dimethyl methyl vinyl silicone that mass concentration is 63mg/L~293mg/L disperses nanometer Grade lithium zirconate particle, starts the fuel heater in double shaft mix reactor, makes solution temperature between 46 DEG C~84 DEG C, open Blender in dynamic double shaft mix reactor, and with 4 × 102Rpm~8 × 102The speed of rpm stirs, and adjusts pH value 4.3 Between~8.9, insulated and stirred 59~126 minutes；Stop reaction later and stand 5.93 × 10~11.37 × 10 minutes, goes to clean Matter；Formaldehyde and 1 is added in suspension, the polymer of 3- benzene dimethylamine and phenol adjusts pH value between 1.3~2.9, and it is heavy to be formed The pure water elution of starch, by centrifuge in revolving speed 4.338 × 103Rpm~9.102 × 103Solid content is obtained under rpm, 2.117×102DEG C~3.279 × 102It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding3~1.102 × 103Mesh, it is spare； Step 3: isophthalic acid and terephthalic acids, -2 methylol -1,3- third of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl are separately taken Nanoscale lithium zirconate particle after polymer and the step 2 processing of glycol, dissipates the irradiation of alpha ray diffraction using acute angle after mixing, The energy of the scattered alpha ray diffraction irradiation of acute angle is 50.7MeV~78.2MeV, dosage is 98.7kGy~138.2kGy, irradiation time It is 62.7~87.2 minutes, obtains the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and neopentyl glycol of character change The polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of 2- ethyl；By isophthalic acid and to benzene two The polymer and nanoscale lithium zirconate of acid, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl Particle mixture is placed in another double shaft mix reactor, starts the fuel heater in double shaft mix reactor, setting 61.2 DEG C~107.5 DEG C of temperature, start the blender in double shaft mix reactor, revolving speed is 53rpm~448rpm, pH adjustment To between 4.7~8.0, it is dehydrated 62.7~76.0 minutes, it is spare；
Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In -2 (or 3)-sodium sulfonate of 5- methoxycarbonyl -5- methyl norbornane of 63mg/L~293mg/L, cocurrent adds to step 1 In double shaft mix reactor, flow acceleration is 198mL/min~926mL/min；Start double shaft mix and react mechanical stirrer, Setting speed is 67rpm~107rpm；Stirring 4~8 minutes；Add 2 methyl valeric acid butyl ester, starting double shaft mix reaction Fuel heater in device is warming up to 97.6 DEG C~134.3 DEG C, and pH is adjusted between 4.6~8.3, is passed through nitrogen ventilatory capacity and is 52.956m3/ min~93.352m3/ min, heat preservation stand 87.5~117.0 minutes；Double shaft mix reactor is again started up to stir Machine is mixed, revolving speed is 62rpm~107rpm, and formaldehyde and chloromethyloxirane and 4,4'- (1- methyl ethylidene) biphenol is added Polymer and N- butyl butylamine and diethanol amine reaction product polymer, and pH is adjusted between 4.6~8.3, Heat preservation stands 86.3~126.7 minutes；
Step 5: the blender in starting double shaft mix reactor, setting speed are 59rpm~126rpm, and starting twin axle stirs The fuel heater in reactor is mixed, sets temperature in double shaft mix reactor as 1.696 × 102DEG C~2.675 × 102 DEG C, 4- (nine fluoro butoxy) -1- fourth sulfonic acid ammonium salt is added, reacts 53.2~64.2 minutes；Alpha-brominated n-caproic acid is added later, Start the fuel heater in double shaft mix reactor, set temperature in double shaft mix reactor as 137.2 DEG C~ 193.0 DEG C, pH is adjusted between 4.6~8.6, and pressure is 0.59MPa~0.6MPa, and the reaction time is 0.4~0.9 hour；It After to be depressurized to gauge pressure be 0MPa, be cooled to 53.2 DEG C~64.2 DEG C and discharge into molding press to get to filtered fluid plate 3-6；
The partial size of the nanoscale lithium zirconate particle is 67 μm~77 μm.
Cellular reaction unit in a kind of wastewater of construction processing of the present invention, the advantage is that use is originally set Standby and working method, work efficiency is high, and equipment production does not generate secondary pollution, environment-friendly high-efficiency, and device structure is simple, maintenance side Just, it can be used under a variety of execution conditions.
Detailed description of the invention
Fig. 1 is the cellular reaction unit total system knot therein in a kind of heretofore described wastewater of construction processing Structure schematic diagram.
Fig. 2 is heretofore described 2 structural schematic diagram of pulverizer.
Fig. 3 is heretofore described 3 structural schematic diagram of anaerobic fermentation tank.
Fig. 4 is heretofore described medicament mixing device 3-7 structural schematic diagram.
Fig. 5 is heretofore described electromagnetic oscillation device 3-7-9 structural schematic diagram.
Fig. 6 is heretofore described 13 structural schematic diagram of electrochemical reaction appts.
Fig. 7 is heretofore described 6 structural schematic diagram of aerobic fermentation tank.
Fig. 8 is heretofore described 16 structural schematic diagram of reclamation set.
Fig. 9 is heretofore described cellular reaction unit 16-1 schematic diagram of internal structure.
Figure 10 is heretofore described pressurization air supply device 16-1-1 structural schematic diagram.
Figure 11 is heretofore described lubricating oil fining device 16-1-1-9 structural schematic diagram.
Figure 12 is heretofore described 17 structural schematic diagram of sediment conveying device.
Figure 13 is that heretofore described filtered fluid plate 3-6 test parameters changes over time figure.
Specific embodiment
With reference to the accompanying drawings and examples to the cellular reaction in a kind of wastewater of construction processing provided by the invention Device is described further.
As shown in Figure 1, being that cellular reaction unit in a kind of heretofore described wastewater of construction processing is therein Overall system architecture schematic diagram.As seen from the figure, percolate branch pipe 8, percolate branch pipe 8 are equipped in 4 vertical portion lower part of feed pipe It is connected to main water inlet tube 1；The aerobic fermentation tank 6 is located at 3 side of anaerobic fermentation tank, and aerobic fermentation tank 6 passes through aerobic fermentation tank Inlet tube 10 is connected to main water inlet tube 1；10 vertical portion top of aerobic fermentation tank inlet tube is equipped with methane riser 5, aerobic hair 6 lower part of fermentation tank is equipped with reclamation set drainpipe 11, and 11 top of reclamation set drainpipe is equipped with reclamation set 16, and reclamation set 16 is logical Reclamation set drainpipe 11 is crossed to be connected to primary flow pipe 14；6 one side lower part of aerobic fermentation tank is equipped with bed mud discharge outlet 7；The electricity Chemical reaction equipment 13 is located at 6 left side of aerobic fermentation tank, and electrochemical reaction appts 13 are accepted by main water inlet tube 1 and sent out from anaerobism The percolate of fermentation tank 3；Aerobic fermentation tank 6 is accepted by main water inlet tube 1 and comes from 13 treatment fluid of electrochemical reaction appts；Control system 15 are located at 3 side of anaerobic fermentation tank.
As shown in Fig. 2, being heretofore described 2 structural schematic diagram of pulverizer.As seen from the figure, adjustable sieve plate 2-3 is left under Side is equipped with powder channel 2-8, and comminuting matter continues to fall from powder channel 2-8；The sieve plate adjuster 2-9 and upper adjustable sieve plate 2-7, under adjustable sieve plate 2-3 mechanical connection, sieve plate adjuster 2-9 to upper adjustable sieve plate 2-7, under adjustable sieve plate 2-3 realize angle It is adjustable, plate spacing is adjustable；Under the lower part adjustable sieve plate 2-3 be equipped with powder push plate 2-1, the powder side push plate 2-1 be equipped with powder push rod 2-2, powder push plate 2-1 and powder push rod 2-2 mechanical connection；The percolate storehouse 2-10 is located at the lower part crushing bin 2-5, with powder Broken storehouse 2-5 perforation, the percolate storehouse bottom 2-10 is equipped with percolate branch pipe 8.
As shown in figure 3, being heretofore described 3 structural schematic diagram of anaerobic fermentation tank.As seen from the figure, in agitator arm 3- 2 waists are equipped with collector mat 3-3, and collector mat 3-3 is connect with external power supply, and collector mat 3-3 provides heat for anaerobic fermentation；It is stirring The lower part impeller 3-2 is equipped with filtered fluid plate 3-6, and filtered fluid plate 3-6, which is realized, to be separated by solid-liquid separation；The medicament mixing device 3-7, which is located at, to be sent 5 side of expects pipe 4 and methane riser, agitator arm 3-2 top.
As shown in figure 4, being heretofore described medicament mixing device 3-7 schematic diagram.As seen from the figure, in cellular reaction The lower part device 3-7-3 is equipped with steam injection pipe 3-7-2, and steam injection pipe 3-7-2 is circular, and upper surface is equipped with a large amount of through-holes, steams Vapour one end injection pipe 3-7-2 is connected to external steam pipeline, cellular reactor 3-7-3 of the steam injection pipe 3-7-2 to top It sprays high-temperature steam and promotes medicament reaction；Confection delivery pipe 3-7-1 is equipped in the bottom medicament mixing device 3-7；Medicament adds Agent is added to be filled into medicament mixing device 3-7 from medicament injection pipe 3-7-5, medicament injection pipe 3-7-5 respectively, steam injection pipe 3- The sprayed high-temperature steam of 7-2 promotes medicament in cellular reactor 3-7-3 internal-response, after from confection delivery pipe 3- 7-1 discharge；Electromagnetic oscillation device 3-7-9 is located at the lower part steam injection pipe 3-7-2.
As shown in figure 5, being heretofore described electromagnetic oscillation device 3-7-9 structural schematic diagram.As seen from the figure, described Ultraviolet emission lamp 3-7-9-5 be located at electromagnetism surge coil 3-7-9-7 and deuterated tetrachloroethanes isotope emitting head 3-7-9-4 it Between, ultraviolet emission lamp 3-7-9-5 cyclic structure is connect with external power supply conducting wire；The ultraviolet emission top lamp 3-7-9-5 is equipped with electromagnetism Coil 3-7-9-7 is agitated, electromagnetism agitates the bottom coil 3-7-9-7 and is equipped with electromagnetic coil, permanent magnet, electromagnetic coil and external electrical The connection of source conducting wire；Electromagnetism agitates and is equipped with vibration rod at the central axes coil 3-7-9-7, and vibration bar magnet material is arranged vertically, outside Circle is equipped with vibration ring, and vibration ring magnet material, is arranged vertically spiral ring structure, and vibration rod is connect with vibration ring bottom.
As shown in fig. 6, being heretofore described 13 structural schematic diagram of electrochemical reaction appts.As seen from the figure, electrochemistry The room side 13-9 is equipped with pond 13-8 after electrochemical treatments, and electrochemical chamber 13-9 passes through pipeline with pond 13-8 after electrochemical treatments It is connected to, pond 13-8 is connected to main water inlet tube 1 after electrochemical treatments.
As shown in fig. 7, being heretofore described 6 structural schematic diagram of aerobic fermentation tank.As seen from the figure, in air injection tube The lower part 6-2 is equipped with steadying plate 6-3, and steadying plate 6-3 is horizontally disposed with and, steadying plate 6-3 equal with 6 cross-sectional sizes of aerobic fermentation tank Surface is equipped with a large amount of through-holes；It is equipped with clear water drain valve 6-5 in the lower part steadying plate 6-3, clear water drain valve 6-5 and aerobic fermentation drain Pipe 6-6 perforation, wherein the upper end aerobic fermentation drainpipe 6-6 is deep into the top steadying plate 6-3；It is set in the side clear water drain valve 6-5 There is bed mud warehouse lid 6-4.
As shown in figure 8, being heretofore described 16 structural schematic diagram of reclamation set.As seen from the figure, in current stabilization wing plate 16- 2 lower parts are equipped with cellular reaction unit 16-1, and cellular reaction unit 16-1 quantity is 20, multiple cellular reaction units 16-1 level equidistantly distributes, at a distance of 10cm~60cm, cellular reaction unit 16- between adjacent cellular reaction unit 16-1 1 is connect by conducting wire with control system 15；The design of the flocculation deposition apparatus shell side's 16-5 cone, open topped, lower part envelope It closes；Water discharge spout 16-8 is located at the middle part of flocculation deposition apparatus shell 16-5 after the processing；Sediment is from bottom pipe and powder Broken machine 2 is connected to.
As shown in figure 9, being heretofore described cellular reaction unit 16-1 schematic diagram of internal structure.As seen from the figure, It is equipped with honeycomb shell 16-1-4 in the periphery serpentine heating pipe 16-1-3, forms channel between the two；The honeycomb shell 16-1-4 table Face is equipped with a large amount of through-holes, and the pressurization air supply device 16-1-1 is located at the bottom cellular reaction unit 16-1, is pressurized air supply device 16-1-1 is that cellular reaction unit 16-1 conveys fresh wind, and pressurization air supply device 16-1-1 promotes solution from honeycomb shell 16- The surface 1-4 through-hole sprays.
It as shown in Figure 10, is heretofore described pressurization air supply device 16-1-1 structural schematic diagram.As seen from the figure, position Air supply motor 16-1-1-1 in one end is connect by belt with air-supply driving wheel 16-1-1-2；Blow driving wheel 16-1-1- 2 other ends and fan blade 16-1-1-3 are mechanically connected, and the fan blade 16-1-1-3 quantity is 6, fan blade 16-1- 1-3 macromolecule material, half arc of fan blade 16-1-1-3, multiple fan blade 16-1-1-3 to air-supply driving wheel 16-1-1-2 Inclined, fan blade 16-1-1-3 itself are equipped with fixing axle and in waists；It is equipped on the top fan blade 16-1-1-3 Air inlet 16-1-1-4, air inlet 16-1-1-4 rectangle 450mm~450mm；The other side fan blade 16-1-1-3 is equipped with outlet air Mouth 16-1-1-5, the other side air outlet 16-1-1-5 are equipped with air duct 16-1-1-6, and the two is connected to by filter screen 16-1-1-7, wind The road 16-1-1-6 other end is connected to cellular reaction unit 16-1；In air duct, 16-1-1-6 is connect with fan blade 16-1-1-3 Place is equipped with maintenance door 16-1-1-8.
It as shown in figure 11, is heretofore described lubricating oil fining device 16-1-1-9 structural schematic diagram.From figure Find out, filling ball 16-1-1-9-6 is equipped between two filter plate 16-1-1-9-3, and filling ball 16-1-1-9-6 quantity is 1000, filling ball 16-1-1-9-6 diameter is greater than filter plate 16-1-1-9-3 through-hole diameter；Filling ball 16-1-1-9-6 is stirred Impeller 16-1-1-9-5 stirring is mixed to be rotated upwardly and downwardly；The dregs of fat outlet 16-1-1-9-2 setting refines device in lubricating oil The bottom 16-1-1-9；The temperature inductor 16-1-1-9-7 setting is led at the top of lubricating oil fining device 16-1-1-9 Conducting wire is crossed to connect with control system 15.
It as shown in figure 12, is heretofore described 17 structural schematic diagram of sediment conveying device.As seen from the figure, sediment Conveyor frame 17-5 is surrounded by conveyer belt 17-3, is equipped with driven wheel, driving wheel before and after conveyer belt 17-3, wherein driving wheel It is connect with drive shaft 17-7, drive shaft 17-7 is connect with transmission driving motor 17-6；Baffle 17- is equipped on the surface conveyer belt 17-3 1, baffle 17-1 quantity is 20, equidistant arrangement, and body feed tank 17-2 is placed between two baffle 17-1；It conveys and fills in sediment The one end frame 17-5 is set equipped with velocity sensor 17-8.
Following embodiment further illustrates the contents of the present invention, and as filtered fluid plate 3-6, it is important set of the invention Part increases the service life of integral device due to its presence, it plays pass for the safety of integral device, even running Key effect.For this purpose, by it is following be embodiment, further verify filtered fluid plate 3-6 of the present invention, what is shown is higher than The physical characteristic of other related patents.
Embodiment 1
Filtered fluid plate 3-6 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in double shaft mix reactor, 268.5 parts of pure water and 3- methyl -4- (2,6,6- trimethyl -1- are added Base) 60.3 parts of-3- butene-2 -one, start the blender in double shaft mix reactor, setting speed 61rpm starts twin shaft Fuel heater in formula stirred reactor makes temperature rise to 76.5 DEG C, and [[3- (the trimethoxy silicon of 1- methoxyl group -3,7- bis- is added Base) the third oxygen] methyl] 63.2 parts of poly- (silicomethane) of sealing end stir evenly, carry out reaction 53.3 minutes, methyl ethylene two is added 59.2 parts of chlorosilane, being passed through flow is 52.5m3The nitrogen of/min 53.3 minutes；It is added in double shaft mix reactor later 62.6 parts of collagen powder, the fuel heater being again started up in double shaft mix reactor makes temperature rise to 93.2 DEG C, heat preservation 53.2 Minute, 65.2 parts of four hydrogen-based phthalic anhydride of methyl is added, the pH value for adjusting solution in double shaft mix reactor is 4.6, Heat preservation 53.6 minutes；
Step 2: separately taking 67.0 parts of nanoscale lithium zirconate particle, by nanoscale lithium zirconate particle power be 5.93KW under ultrasonic wave After processing 0.59 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, mass concentration is added For 63mg/L polypropylene and dimethyl methyl vinyl silicone 60.8 parts of dispersion nanoscale lithium zirconate particles of reaction product, Start the fuel heater in double shaft mix reactor, make solution temperature at 46 DEG C, starts in double shaft mix reactor Blender, and with 4 × 102The speed of rpm stirs, and adjusts pH value 4.3, insulated and stirred 59 minutes；Stop reaction later to stand 5.93 × 10 minutes, remove impurity；Formaldehyde and 1 is added in suspension, 62.9 parts of polymer of 3- benzene dimethylamine and phenol, is adjusted PH value forms the pure water elution of sediment, by centrifuge in revolving speed 4.338 × 10 1.33Solid content is obtained under rpm, 2.117×102It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding3Mesh, it is spare；
Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after polymer 62.4 and the step 2 processing of 3-propanediol, dissipates alpha ray using acute angle after mixing and spreads out Irradiation is penetrated, the energy of the scattered alpha ray diffraction irradiation of acute angle is 50.7MeV, dosage 98.7kGy, irradiation time are 62.7 minutes, is obtained The isophthalic acid and terephthalic acids, -2 methylol -1,3- of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl changed to character The polymer and nanoscale lithium zirconate particle mixture of propylene glycol；By isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol It is placed in the polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of neopentyl glycol 2- ethyl another double In shaft type stirred reactor, starts the fuel heater in double shaft mix reactor, 61.2 DEG C of set temperature, start twin axle Blender in stirred reactor, revolving speed 53rpm, pH are adjusted to 4.7, are dehydrated 62.7 minutes, spare；
Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In 51.3 parts of -2 (or 3)-sodium sulfonate of the 5- methoxycarbonyl -5- methyl norbornane of 63mg/L, cocurrent adds to the twin shaft of step 1 In formula stirred reactor, flow acceleration 198mL/min；Start double shaft mix and react mechanical stirrer, setting speed is 67rpm；Stirring 4 minutes；50.7 parts of 2 methyl valeric acid butyl ester are added, the fuel Heating in double shaft mix reactor is started Device is warming up to 97.6 DEG C, and pH is adjusted to 4.6, and being passed through nitrogen ventilatory capacity is 52.956m3/ min, heat preservation stand 87.5 minutes；Again Secondary starting double shaft mix reacts mechanical stirrer, and formaldehyde and chloromethyloxirane and 4,4'- (1- first is added in revolving speed 62rpm Base ethylidene) biphenol polymer and 59.2 parts of polymer of reaction product of N- butyl butylamine and diethanol amine, and make PH is adjusted to 4.6, and heat preservation stands 86.3 minutes；
Step 5: the blender in starting double shaft mix reactor, setting speed 59rpm start double shaft mix reactor In fuel heater, set temperature in double shaft mix reactor as 1.696 × 102DEG C, 4- (nine fluoro fourth oxygen are added Base) 69.7 parts of -1- fourth sulfonic acid ammonium salt, reacts 53.2 minutes；The alpha-brominated n-caproic acid that mass concentration is 59mg/L is added later 92.6 parts, start the fuel heater in double shaft mix reactor, sets temperature in double shaft mix reactor as 137.2 DEG C, pH is adjusted to 4.6, and pressure 0.59MPa, the reaction time is 0.4 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to 53.2 DEG C discharge into molding press to get to filtered fluid plate 3-6；The partial size of the nanoscale lithium zirconate particle is 67 μm.
Embodiment 2
Filtered fluid plate 3-6 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in double shaft mix reactor, 493.0 parts of pure water and 3- methyl -4- (2,6,6- trimethyl -1- are added Base) 102.7 parts of-3- butene-2 -one, start the blender in double shaft mix reactor, setting speed 107rpm, starting pair Fuel heater in shaft type stirred reactor makes temperature rise to 77.0 DEG C, and the [[3- (trimethoxy of 1- methoxyl group -3,7- bis- is added Silicon substrate) the third oxygen] methyl] 172.2 parts of poly- (silicomethane) of sealing end stir evenly, carry out reaction 64.7 minutes, ethylene methacrylic is added 76.0 parts of base dichlorosilane, being passed through flow is 93.0m3The nitrogen of/min 64.7 minutes；Later in double shaft mix reactor 119.1 parts of collagen powder are added, the fuel heater being again started up in double shaft mix reactor makes temperature rise to 126.2 DEG C, protects 126.5 parts of four hydrogen-based phthalic anhydride of methyl is added in temperature 64.0 minutes, adjusts the pH value of solution in double shaft mix reactor It is 8.1, keeps the temperature 293.6 minutes；
Step 2: separately taking 122.6 parts of nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is ultrasonic in the case where power is 11.37KW After wave is handled 1.126 hours；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, it is dense that quality is added Degree is the polypropylene of 293mg/L and 102.8 parts of dispersion nanoscale lithium zirconates of reaction product of dimethyl methyl vinyl silicone Particle starts the fuel heater in double shaft mix reactor, makes solution temperature between 84 DEG C, and starting double shaft mix is anti- The blender in device is answered, and with 8 × 102The speed of rpm stirs, and adjusts pH value 8.9, insulated and stirred 126 minutes；Stop later Reaction stands 11.37 × 10 minutes, removes impurity；Suspension is added to the polymer of formaldehyde and 1,3- benzene dimethylamine and phenol 102.6 parts, adjustment pH value forms the pure water elution of sediment, by centrifuge in revolving speed 9.102 × 10 2.93Under rpm Solid content is obtained, 3.279 × 102It is dry at a temperature of DEG C, 1.102 × 10 are crossed after grinding3Mesh, it is spare；
Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after 85.0 parts of the polymer of 3-propanediol and step 2 processing, dissipates alpha ray using acute angle after mixing Diffraction irradiation, the energy of the scattered alpha ray diffraction irradiation of acute angle is 78.2MeV, dosage 138.2kGy, irradiation time are 87.2 points Clock obtains the isophthalic acid and terephthalic acids, -2 hydroxyl first of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl of character change The polymer and nanoscale lithium zirconate particle mixture of base -1,3- propylene glycol；By isophthalic acid and terephthalic acids, adipic acid, 1, The polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of 2- ethylene glycol and neopentyl glycol 2- ethyl are set In another double shaft mix reactor, start double shaft mix reactor in fuel heater, 107.5 DEG C of set temperature, Start the blender in double shaft mix reactor, revolving speed 448rpm, pH are adjusted to 8.0, are dehydrated 76.0 minutes, spare；
Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In 87.9 parts of -2 (or 3)-sodium sulfonate of the 5- methoxycarbonyl -5- methyl norbornane of 293mg/L, cocurrent adds to the double of step 1 In shaft type stirred reactor, flow acceleration 926mL/min；Start double shaft mix and react mechanical stirrer, setting speed is 107rpm；Stirring 8 minutes；93.2 parts of 2 methyl valeric acid butyl ester are added, the fuel Heating in double shaft mix reactor is started Device is warming up to 134.3 DEG C, and pH is adjusted to 8.3, and being passed through nitrogen ventilatory capacity is 93.352m3/ min, heat preservation stand 117.0 minutes； It is again started up double shaft mix reaction mechanical stirrer, formaldehyde and chloromethyloxirane and 4,4'- are added in revolving speed 107rpm 104.5 parts of polymer of the reaction product of the polymer and N- butyl butylamine and diethanol amine of (1- methyl ethylidene) biphenol, And pH is made to be adjusted to 8.3, heat preservation stands 126.7 minutes；
Step 5: the blender in starting double shaft mix reactor, setting speed 126rpm, starting double shaft mix reaction Fuel heater in device sets temperature in double shaft mix reactor as 2.675 × 102DEG C, 4- (nine fluoro fourth oxygen are added Base) 113.0 parts of -1- fourth sulfonic acid ammonium salt, reacts 64.2 minutes；The alpha-brominated n-caproic acid that mass concentration is 326mg/L is added later 146.3 parts, start the fuel heater in double shaft mix reactor, set temperature in double shaft mix reactor as 193.0 DEG C, pH is adjusted to 8.6, and pressure 0.6MPa, the reaction time is 0.9 hour；Being depressurized to gauge pressure later is 0MPa, cooling It discharges into molding press to 64.2 DEG C to get to filtered fluid plate 3-6；The partial size of the nanoscale lithium zirconate particle is 77 μm.
Embodiment 3
Filtered fluid plate 3-6 of the present invention is prepared according to the following steps, and according to parts by weight:
Step 1: in double shaft mix reactor, 268.9 parts of pure water and 3- methyl -4- (2,6,6- trimethyl -1- are added Base) 60.9 parts of-3- butene-2 -one, start the blender in double shaft mix reactor, setting speed 61rpm starts twin shaft Fuel heater in formula stirred reactor makes temperature rise to 76.9 DEG C, and [[3- (the trimethoxy silicon of 1- methoxyl group -3,7- bis- is added Base) the third oxygen] methyl] 63.9 parts of poly- (silicomethane) of sealing end stir evenly, carry out reaction 53.9 minutes, methyl ethylene two is added 59.9 parts of chlorosilane, being passed through flow is 52.9m3The nitrogen of/min 53.9 minutes；It is added in double shaft mix reactor later 62.9 parts of collagen powder, the fuel heater being again started up in double shaft mix reactor makes temperature rise to 93.9 DEG C, heat preservation 53.9 Minute, 65.9 parts of four hydrogen-based phthalic anhydride of methyl is added, the pH value for adjusting solution in double shaft mix reactor is 4.9, Heat preservation 53.9 minutes；
Step 2: separately taking 67.9 parts of nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is ultrasonic in the case where power is 5.939KW After wave is handled 0.599 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, it is dense that quality is added Degree is the polypropylene of 63.9mg/L and 60.9 parts of dispersion nanoscale lithium zirconates of reaction product of dimethyl methyl vinyl silicone Particle starts the fuel heater in double shaft mix reactor, makes solution temperature at 46.9 DEG C, starting double shaft mix reaction Blender in device, and with 4.9 × 102The speed of rpm stirs, and adjusts pH value 4.9, insulated and stirred 59.9 minutes；Stop later Only reaction stands 5.93 × 10 minutes, removes impurity；Suspension is added to the polymer of formaldehyde and 1,3- benzene dimethylamine and phenol 62.9 parts, adjustment pH value forms the pure water elution of sediment, by centrifuge in revolving speed 4.338 × 10 1.93Under rpm To solid content, 2.117 × 102It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding3Mesh, it is spare；
Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after polymer 62.9 and the step 2 processing of 3-propanediol, dissipates alpha ray using acute angle after mixing and spreads out Irradiation is penetrated, the energy of the scattered alpha ray diffraction irradiation of acute angle is 50.9MeV, dosage 98.9kGy, irradiation time are 62.9 minutes, is obtained The isophthalic acid and terephthalic acids, -2 methylol -1,3- of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl changed to character The polymer and nanoscale lithium zirconate particle mixture of propylene glycol；By isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol It is placed in the polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of neopentyl glycol 2- ethyl another double In shaft type stirred reactor, starts the fuel heater in double shaft mix reactor, 61.9 DEG C of set temperature, start twin axle Blender in stirred reactor, revolving speed 53rpm, pH are adjusted to 4.9, are dehydrated 62.9 minutes, spare；
Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In 51.9 parts of -2 (or 3)-sodium sulfonate of the 5- methoxycarbonyl -5- methyl norbornane of 63.9mg/L, cocurrent adds to the double of step 1 In shaft type stirred reactor, flow acceleration 198.9mL/min；Start double shaft mix and react mechanical stirrer, setting speed is 67rpm；Stirring 4.9 minutes；50.9 parts of 2 methyl valeric acid butyl ester are added, the fuel Heating in double shaft mix reactor is started Device is warming up to 97.9 DEG C, and pH is adjusted to 4.9, and being passed through nitrogen ventilatory capacity is 52.9m3/ min, heat preservation stand 87.9 minutes；Again Start double shaft mix and react mechanical stirrer, formaldehyde and chloromethyloxirane and 4,4'- (1- methyl is added in revolving speed 62rpm Ethylidene) biphenol polymer and 59.9 parts of polymer of reaction product of N- butyl butylamine and diethanol amine, and make pH 4.9 are adjusted to, heat preservation stands 86.9 minutes；
Step 5: the blender in starting double shaft mix reactor, setting speed 59rpm start double shaft mix reactor In fuel heater, set temperature in double shaft mix reactor as 1.696 × 102DEG C, 4- (nine fluoro fourth oxygen are added Base) 69.9 parts of -1- fourth sulfonic acid ammonium salt, reacts 53.9 minutes；The alpha-brominated n-caproic acid that mass concentration is 59mg/L is added later 92.6 parts, start the fuel heater in double shaft mix reactor, sets temperature in double shaft mix reactor as 137.9 DEG C, pH is adjusted to 4.9, and pressure 0.59MPa, the reaction time is 0.41 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to 53.9 DEG C discharge into molding press to get to filtered fluid plate 3-6；The partial size of the nanoscale lithium zirconate particle is 67 μm.
Reference examples
Reference examples use the component same as the application filtered fluid plate 3-6 of certain commercially available brand, are tested for the property test.
Embodiment 4
The filtered fluid plate 3-6 and reference examples of Examples 1 to 3 same component obtained are tested for the property test, test knot The parameters such as impact resistance enhancing rate, compression strength enhancing rate, anti-yield strength enhancing rate, anticorrosive enhancing rate are carried out after beam Analysis.Data analysis is as shown in table 1.
As seen from Table 1, filtered fluid plate 3-6 of the present invention, obviously higher than the prior art in Specifications The product of production.
Find out in addition, being changed over time in figure from heretofore described filtered fluid plate 3-6 test parameters, Examples 1 to 3 In Specifications, substantially better than the product of prior art production.

Claims (10)

1. the cellular reaction unit in a kind of wastewater of construction processing, which is characterized in that cellular reaction unit (16-1) It include: to be pressurized air supply device (16-1-1), diversion pipe (16-1-2), serpentine heating pipe (16-1-3), honeycomb shell (16-1-4), Dispersion plate (16-1-5)；
Dispersion plate (16-1-5) disc, surface be equipped with a large amount of through-holes, dispersion plate (16-1-5) quantity be 1, be located at it is cellular The top reaction unit (16-1)；Diversion pipe (16-1-2), its underpart closing, diversion pipe are equipped in a dispersion plate lower part (16-1-5) (16-1-2) quantity is 10, and the diversion pipe surface (16-1-2) is equipped with a large amount of through-holes；Snake is equipped in diversion pipe (16-1-2) periphery Shape heating tube (16-1-3), the serpentine heating pipe surface (16-1-3) are equipped with a large amount of through-holes, are connected to external heating device；In snake Shape heating tube (16-1-3) periphery is equipped with honeycomb shell (16-1-4), forms channel between the two；The honeycomb shell (16-1-4) Surface is equipped with a large amount of through-holes, and the pressurization air supply device (16-1-1) is located at the bottom cellular reaction unit (16-1), and pressurization is sent Wind apparatus (16-1-1) is that cellular reaction unit (16-1) conveys fresh wind, pressurization air supply device (16-1-1) promote solution from Honeycomb shell (16-1-4) surface through-hole sprays；
The cellular reaction unit (16-1) is internal in reclamation set (16)；
The reclamation set (16) is located inside wastewater treatment total system；
Cellular reaction unit in a kind of processing of wastewater of construction, wherein wastewater treatment total system includes: main water inlet tube (1), pulverizer (2), anaerobic fermentation tank (3), feed pipe (4), methane riser (5), aerobic fermentation tank (6), bed mud discharge outlet (7), percolate branch pipe (8), oxygen hose (9), aerobic fermentation tank inlet tube (10), reclamation set drainpipe (11), slag notch (12), electrochemical reaction appts (13), primary flow pipe (14), control system (15), reclamation set (16), sediment conveying device (17)；
The main water inlet tube (1), primary flow pipe (14) horizontal layout, main water inlet tube (1), primary flow pipe (14) diameter be 20cm~ 30cm, it is made of high molecular material, main water inlet tube (1), primary flow pipe (14) are respectively at anaerobic fermentation tank (3), aerobic fermentation tank (6), electrochemical reaction appts (13) are connected to；Pulverizer (2), main water inlet tube (1) and powder are equipped in main water inlet tube (1) upper right Broken machine (2) is connected to by percolate branch pipe (8)；Pulverizer (2) side is equipped with anaerobic fermentation tank (3), anaerobic fermentation tank (3) top Equipped with methane riser (5), anaerobic fermentation tank (3) lower part is equipped with slag notch (12), and anaerobic fermentation tank (3) and pulverizer (2) are logical Cross feed pipe (4) connection；Be equipped with percolate branch pipe (8) in feed pipe (4) vertical portion lower part, percolate branch pipe (8) and it is main into Water pipe (1) connection；The aerobic fermentation tank (6) is located at anaerobic fermentation tank (3) side, and aerobic fermentation tank (6) passes through aerobic fermentation Tank inlet tube (10) is connected to main water inlet tube (1)；Aerobic fermentation tank inlet tube (10) vertical portion top is equipped with methane riser (5), aerobic fermentation tank (6) lower part is equipped with reclamation set drainpipe (11), and reclamation set drainpipe (11) top is filled equipped with reuse It sets (16), reclamation set (16) is connected to by reclamation set drainpipe (11) with primary flow pipe (14)；Aerobic fermentation tank (6) side Lower part is equipped with bed mud discharge outlet (7)；The electrochemical reaction appts (13) are located on the left of aerobic fermentation tank (6), electrochemical reaction Device (13) accepts the percolate for coming from anaerobic fermentation tank (3) by main water inlet tube (1)；Aerobic fermentation tank (6) passes through main water inlet (1) is managed to accept from electrochemical reaction appts (13) treatment fluid；Control system (15) is located at anaerobic fermentation tank (3) side；Precipitating Object conveying device (17) is located at pulverizer (2) side, is connected to pulverizer (2).
2. the cellular reaction unit in a kind of wastewater of construction processing according to claim 1, which is characterized in that institute Stating pulverizer (2) includes: powder push plate (2-1), powder push rod (2-2), under adjustable sieve plate (2-3), crushing knife (2-4) crushes Storehouse (2-5), lower hopper (2-6), upper adjustable sieve plate (2-7), powder channel (2-8), sieve plate adjuster (2-9), percolate storehouse (2- 10)；
Superposed lower hopper (2-6), its underpart are equipped with crushing bin (2-5), and crushing bin (2-5) and lower hopper (2-6) are penetrated through； It is equipped with crushing knife (2-4) inside crushing bin (2-5), crushing knife (2-4) quantity is 2, and arranged opposite；Under crushing knife (2-4) Portion is equipped with upper adjustable sieve plate (2-7), and the upper adjustable sieve plate surface (2-7) is equipped with a large amount of through-holes, upper adjustable sieve plate (2-7) horizontal sextant angle 15~60 degree；Upper adjustable sieve plate (2-7) lower part is equipped with down adjustable sieve plate (2-3), upper adjustable sieve plate (2-7) adjustable sieve plate under The slit at a distance of 20cm~50cm is formed between (2-3), comminuting matter falls on down the surface adjustable sieve plate (2-3) under this slit, Under the adjustable sieve plate surface (2-3) be equipped with a large amount of through-holes, 15~60 degree of angle with horizontal plane；Under set on the left of adjustable sieve plate (2-3) There is powder channel (2-8), comminuting matter continues to fall from powder channel (2-8)；The sieve plate adjuster (2-9) and upper adjustable sieve Plate (2-7), under adjustable sieve plate (2-3) mechanical connection, sieve plate adjuster (2-9) to upper adjustable sieve plate (2-7), under adjustable sieve plate (2-3) realizes that adjustable angle, plate spacing is adjustable；Under the adjustable sieve plate lower part (2-3) be equipped with powder push plate (2-1), powder push plate (2- 1) side is equipped with powder push rod (2-2), and powder push plate (2-1) and powder push rod (2-2) are mechanically connected；Percolate storehouse (the 2- 10) it is located at the lower part crushing bin (2-5), is penetrated through with crushing bin (2-5), the percolate storehouse bottom (2-10) is equipped with percolate branch pipe (8)。
3. the cellular reaction unit in a kind of wastewater of construction processing according to claim 2, which is characterized in that institute Stating anaerobic fermentation tank (3) includes: stirring motor (3-1), agitator arm (3-2), collector mat (3-3), cleaning pipe (3-4), clear water It pumps (3-5), filtered fluid plate (3-6), medicament mixing device (3-7)；
Stirring motor (3-1) outside side is connect by transmission device with internal agitator arm (3-2)；Paddle It takes turns (3-2) and anaerobic fermentation tank (3) is contour, stirring motor (3-1) drives agitator arm (3-2) rotation；At agitator arm (3-2) Waist is equipped with collector mat (3-3), and collector mat (3-3) is connect with external power supply, and collector mat (3-3) provides heat for anaerobic fermentation； It is equipped with filtered fluid plate (3-6) in the agitator arm lower part (3-2), filtered fluid plate (3-6), which is realized, to be separated by solid-liquid separation；The medicament mixing dress Set the top that (3-7) is located at feed pipe (4) and methane riser (5) side, agitator arm (3-2).
4. the cellular reaction unit in a kind of wastewater of construction processing according to claim 3, which is characterized in that institute Stating medicament mixing device (3-7) includes: confection delivery pipe (3-7-1), steam injection pipe (3-7-2), cellular reactor (3-7-3), additive filler pipe (3-7-4), medicament injection pipe (3-7-5), sluicing pipe (3-7-6), temperature sensor (3-7- 7), equipment base (3-7-8), electromagnetic oscillation device (3-7-9)；
Sluicing pipe (3-7-6) positioned at top, one end are connect with external water pump, the other end and medicament mixing device (3-7) Internal lotus spray-head connection, lotus spray-head lower part are equipped with cellular reactor (3-7-3), and lotus spray-head is to the cellular of lower part Reactor (3-7-3) implements cleaning；Cellular reactor (3-7-3) section is honeycomb, by more honeycomb standpipes It is vertically arranged composition, cellular reactor (3-7-3) is up and down；Additive filler pipe is equipped in the sluicing pipe side (3-7-6) (3-7-4), medicament injection pipe (3-7-5)；It is equipped with temperature sensor (3-7-7) in the middle part of medicament mixing device (3-7), is passed through Conducting wire is connect with control system (15)；It is equipped with steam injection pipe (3-7-2) in the cellular reactor lower part (3-7-3), steam spray Pipe (3-7-2) annular shape is penetrated, upper surface is equipped with a large amount of through-holes, and steam injection pipe one end (3-7-2) and external steam pipeline connect Logical, steam injection pipe (3-7-2) promotes medicament reaction to the cellular reactor (3-7-3) on top injection high-temperature steam；In medicine The agent mixing arrangement bottom (3-7) is equipped with confection delivery pipe (3-7-1)；Medicament, additive are respectively from medicament injection pipe (3-7- 5), medicament injection pipe (3-7-5) is filled into medicament mixing device (3-7), the sprayed high-temperature steam of steam injection pipe (3-7-2) Promote medicament in cellular reactor (3-7-3) internal-response, after be discharged from confection delivery pipe (3-7-1)；Electromagnetism Vibration device (3-7-9) is located at the lower part steam injection pipe (3-7-2).
5. the cellular reaction unit in a kind of wastewater of construction processing according to claim 4, which is characterized in that institute Stating electromagnetic oscillation device (3-7-9) includes: vibration support (3-7-9-1), high-voltage capacitor (3-7-9-2), deuterated tetrachloroethanes Isotope ring (3-7-9-3), deuterated tetrachloroethanes isotope emitting head (3-7-9-4), ultraviolet emission lamp (3-7-9-5), water inlet Channel (3-7-9-6), electromagnetism agitate coil (3-7-9-7), waterproof casing (3-7-9-8)；
Up and down, axis line inside is equipped with the waterproof casing (3-7-9- of vertical arrangement to electromagnetic oscillation device (3-7-9) shell 8) intake tunnel (3-7-9-6), is formed between electromagnetic oscillation device (3-7-9) and waterproof casing (3-7-9-8), in waterproof casing It is successively arranged vibration support (3-7-9-1), high-voltage capacitor (3-7-9-2), deuterated four chloroethene from top to bottom inside (3-7-9-8) Alkane isotope ring (3-7-9-3), deuterated tetrachloroethanes isotope emitting head (3-7-9-4), ultraviolet emission lamp (3-7-9-5), electricity Magnetic agitates coil (3-7-9-7), and middle-and high-voltage capacitor (3-7-9-2) is connect with electromagnetism surge coil (3-7-9-7) conducting wire；Institute Deuterated tetrachloroethanes isotope ring (3-7-9-3) annular shape is stated, one end is connect with external high pressure gas cylinder, deuterated tetrachloroethanes The isotope ring upper surface (3-7-9-3) is equipped with deuterated tetrachloroethanes isotope emitting head (3-7-9-4), the deuterated same position of tetrachloroethanes Plain emitting head (3-7-9-4) quantity is 10, and deuterated tetrachloroethanes isotope emitting head (3-7-9-4) mutually equidistant arrangement is in deuterium For on tetrachloroethanes isotope ring (3-7-9-3)；The ultraviolet emission lamp (3-7-9-5) is located at electromagnetism surge coil (3-7-9- 7) between deuterated tetrachloroethanes isotope emitting head (3-7-9-4), ultraviolet emission lamp (3-7-9-5) cyclic structure and outside Power lead connection；The ultraviolet emission lamp top (3-7-9-5) is equipped with electromagnetism surge coil (3-7-9-7), and electromagnetism agitates coil (3- 7-9-7) bottom is equipped with electromagnetic coil, permanent magnet, and electromagnetic coil is connect with external power supply conducting wire；Electromagnetism agitates coil (3-7- Vibration rod 9-7) is equipped at central axes, vibration bar magnet material is arranged vertically, and outer ring is equipped with vibration ring, shakes ring magnet material Matter, is arranged vertically spiral ring structure, and vibration rod is connect with vibration ring bottom.
6. the cellular reaction unit in a kind of wastewater of construction processing according to claim 5, which is characterized in that electricity Chemical reaction equipment (13) includes: into water tank (13-1), buffer pool flow pipe (13-2), mud chamber (13-3), direct current torch (13-4), sediment discharge pipe (13-5), Water Ecological Recovery halftone contact screen (13-6), Water Ecological Recovery halftone contact screen bracket (13- 7), pond (13-8) after electrochemical treatments, electrochemical chamber (13-9), filter screen (13-10), filter chamber (13-11), sewage feed liquor It manages (13-12)；
Water inlet tank (13-1) positioned at one end is connected to by buffer pool flow pipe (13-2) with filter chamber (13-11)；In filter chamber The lower part (13-11) is equipped with electrochemical chamber (13-9), and filter screen (13- is equipped between filter chamber (13-11) and electrochemical chamber (13-9) 10)；It is equipped with direct current torch (13-4) inside electrochemical chamber (13-9), direct current torch (13-4) is connect with external power supply conducting wire；Electricity The chemical room lower part (13-9) is equipped with mud chamber (13-3), repairs between electrochemical chamber (13-9) and mud chamber (13-3) equipped with Ecology Multiple halftone contact screen (13-6), Water Ecological Recovery halftone contact screen (13-6) is by Water Ecological Recovery halftone contact screen bracket (13-7) and sinks (13-3) is fixedly connected for shallow lake room；The mud chamber lower part (13-3) is equipped with sediment discharge pipe (13-5)；The side electrochemical chamber (13-9) Equipped with pond after electrochemical treatments (13-8), pond (13-8) is connected by pipeline after electrochemical chamber (13-9) and electrochemical treatments Logical, pond (13-8) is connected to main water inlet tube (1) after electrochemical treatments.
7. the cellular reaction unit in a kind of wastewater of construction processing according to claim 6, which is characterized in that institute Stating aerobic fermentation tank (6) includes: heating rod (6-1), air injection tube (6-2), steadying plate (6-3), bed mud warehouse lid (6-4), clearly Water discharging valve (6-5), aerobic fermentation drainpipe (6-6)；
Heating rod (6-1) positioned at top, connects to power supply, and connect with control system (15) polygon control survey；In heating rod The lower part (6-1) is equipped with air injection tube (6-2), and the air injection tube surface (6-2) is equipped with a large amount of through-holes, air injection tube (6-2) Quantity is 10, is mutually equally spaced, and air injection tube (6-2) pipe range is 20cm~86cm, diameter 20cm, air injection tube The one end (6-2) is connected to oxygen hose (9)；It is equipped with steadying plate (6-3) in the air injection tube lower part (6-2), steadying plate (6-3) is horizontal It is arranged and equal with aerobic fermentation tank (6) cross-sectional sizes, the steadying plate surface (6-3) is equipped with a large amount of through-holes；At steadying plate (6-3) Lower part is equipped with clear water drain valve (6-5), and clear water drain valve (6-5) and aerobic fermentation drainpipe (6-6) are penetrated through, wherein aerobic fermentation The upper end drainpipe (6-6) is deep into the top steadying plate (6-3)；Bed mud warehouse lid (6-4) is equipped in the clear water drain valve side (6-5).
8. the cellular reaction unit in a kind of wastewater of construction processing according to claim 7, which is characterized in that return It include: cellular reaction unit (16-1), current stabilization wing plate (16-2), macromolecule current stabilization sieve (16-3), polymerization with device (16) Aluminium dispersion pipe (16-4), flocculation deposition apparatus shell (16-5), middle storage tank (16-6), middle storage tank water pump (16-7), water after processing Delivery pipe (16-8)；
The flocculation deposition apparatus shell (16-5) is internal, most top position is equipped with polymeric aluminum dispersion pipe (16-4), polymeric aluminum dispersion Manage (16-4) rectangular ring structure, quantity be 2, it is arranged in parallel, the polymeric aluminum dispersion pipe surface (16-4) be equipped with spray head, spray head Direction is downward, and polymeric aluminum dispersion pipe one end (16-4) is connected to by middle storage tank water pump (16-7) with external middle storage tank (16-6), Middle storage tank (16-6) storage polymerization aluminum solutions；It is equipped with macromolecule current stabilization sieve (16-3) in the polymeric aluminum dispersion pipe lower part (16-4), Its mesh aperture 5mm~16mm, macromolecule current stabilization sieve (16-3) quantity are 10, on multiple macromolecule current stabilization sieves (16-3) Lower superposition layout；It is equipped with current stabilization wing plate (16-2) in the macromolecule current stabilization sieve lower part (16-3), " Z " word is presented in vertical cross section Shape, the quantity of current stabilization wing plate (16-2) are 10, and multiple current stabilization wing plates (16-2) are horizontally arranged, adjacent current stabilization wing plate (16-2) it Between at a distance of 2cm~6cm, multiple current stabilization wing plates (16-2) connects by cranking arm with external motor, external motor driving current stabilization wing plate (16-2) horizontal concussion；It is equipped with cellular reaction unit (16-1) in the current stabilization wing plate lower part (16-2), cellular reaction unit (16-1) quantity is 20, surface is equipped with a large amount of through-holes, and multiple cellular reaction unit (16-1) levels equidistantly distribute, adjacent At a distance of 10cm~60cm between cellular reaction unit (16-1), cellular reaction unit (16-1) passes through conducting wire and control system (15) it connects；The square cone design of the flocculation deposition apparatus shell (16-5), open topped, lower part closing；Water after the processing Delivery pipe (16-8) is located at the middle part of flocculation deposition apparatus shell (16-5)；Sediment is from bottom pipe, sediment conveying device (17) it is connected to pulverizer (2).
9. the cellular reaction unit in a kind of wastewater of construction processing according to claim 8, which is characterized in that increase Force feed wind apparatus (16-1-1) includes: air supply motor (16-1-1-1), is blown driving wheel (16-1-1-2), fan blade (16-1- 1-3), air inlet (16-1-1-4), air outlet (16-1-1-5), air duct (16-1-1-6), filter screen (16-1-1-7), maintenance door (16-1-1-8), lubricating oil refine device (16-1-1-9)；
Air supply motor (16-1-1-1) positioned at one end is connect by belt with air-supply driving wheel (16-1-1-2)；Air-supply passes Driving wheel (16-1-1-2) other end and fan blade (16-1-1-3) are mechanically connected, and fan blade (16-1-1-3) quantity is 6, fan blade (16-1-1-3) macromolecule material, half arc of fan blade (16-1-1-3), multiple fan blade (16-1- 1-3) to air-supply driving wheel (16-1-1-2) inclined, fan blade (16-1-1-3) itself is equipped with fixing axle and in waist Portion；It is equipped with air inlet (16-1-1-4) on the fan blade top (16-1-1-3), air inlet (16-1-1-4) rectangle 450mm~ 450mm；The fan blade other side (16-1-1-3) is equipped with air outlet (16-1-1-5), and the other side air outlet (16-1-1-5) is equipped with Air duct (16-1-1-6), the two are connected to by filter screen (16-1-1-7), and air duct (16-1-1-6) other end is reacted with cellular Device (16-1) connection；Maintenance door (16-1-1- is equipped in air duct (16-1-1-6) and the fan blade junction (16-1-1-3) 8)；Lubricating oil fining device (16-1-1-9) is located at lower part low level, accepts blower and leaks lubricating oil；
Lubricating oil fining device (16-1-1-9) includes: freon pipe (16-1-1-9-1), and the dregs of fat export (16-1-1-9-2), Filter plate (16-1-1-9-3), oil outlet (16-1-1-9-4), agitator arm (16-1-1-9-5) fill ball (16-1-1-9- 6), temperature inductor (16-1-1-9-7), stirring motor (16-1-1-9-8), fatty acid concentration sensor (16-1-1-9-9), Impact-absorbing shell (16-1-1-9-10), additive injection pipe (16-1-1-9-11), oil inlet (16-1-1-9-12)；
Positioned at lubricating oil fining one end device (16-1-1-9) oil inlet (16-1-1-9-12) with it is fuel-displaced positioned at the other end Mouth (16-1-1-9-4) perforation；Additive injection pipe (16-1-1-9-11) is equipped on the right side of oil inlet (16-1-1-9-12)；? It is equipped with freon pipe (16-1-1-9-1) on the right side of additive injection pipe (16-1-1-9-11), freon pipe (16-1-1-9-1) ring Shape is equipped with nozzle, the two perforation on the right side of its annular surface, and nozzle quantity is 20, and multiple nozzles are equidistant in its annular surface Arrangement；It is equipped with impact-absorbing shell (16-1-1-9-10) on the right side of freon pipe (16-1-1-9-1), impact-absorbing shell (16-1-1-9-10) table There are a large amount of through-holes in face, and impact-absorbing shell (16-1-1-9-10) is equipped with fatty acid concentration sensor (16-1-1-9-9), fatty acid concentration Sensor (16-1-1-9-9) is connect by conducting wire with control system (15)；Stirring is equipped on the right side of impact-absorbing shell (16-1-1-9-10) Motor (16-1-1-9-8), its be waterproofing design, stirring motor (16-1-1-9-8) transmission shaft pass through filter plate (16-1-1-9- 3) it is fixedly connected with the agitator arm on right side (16-1-1-9-5)；Filter plate (16-1-1-9-3) quantity is 2, surface is set There are a large amount of through-holes, filter plate (16-1-1-9-3) is respectively provided at the both ends agitator arm (16-1-1-9-5)；The agitator arm (16-1-1-9-5) is made of rectangle frame, and the rectangle frame is long × wide, and: 10mm × 40mm is horizontally arranged, macromolecule material, paddle Taking turns (16-1-1-9-5) quantity is 6, and multiple agitator arms (16-1-1-9-5) are angularly rotatably arranged along long side central axis；? Filling ball (16-1-1-9-6) is equipped between two filter plates (16-1-1-9-3), filling ball (16-1-1-9-6) quantity is 1000 A, filling ball (16-1-1-9-6) diameter is greater than filter plate (16-1-1-9-3) through-hole diameter；Fill ball (16-1-1-9-6) by Agitator arm (16-1-1-9-5) stirring is rotated upwardly and downwardly；Dregs of fat outlet (16-1-1-9-2) setting is fine in lubricating oil The bottom (16-1-1-9) is set in makeup；Temperature inductor (16-1-1-9-7) setting refines device (16-1-1- in lubricating oil 9) top is connect by conducting wire with control system (15)；
Sediment conveying device (17) includes: baffle (17-1), body feed tank (17-2), conveyer belt (17-3), conveyor support (17-4), sediment conveyor frame (17-5) transmit driving motor (17-6), drive shaft (17-7), velocity sensor (17-8)；
Sediment conveyor frame (17-5) is metal structure, oblong-shaped, sediment conveyor frame (17-5) length For 10m~30m, width is 50cm~80cm；The sediment conveyor frame lower part (17-5) is equipped with conveyor support (17- 4), quantity is divided into two groups for 4, and the adjustable and bottom of conveyor support (17-4) height is equipped with movable pulley；Sediment conveying dress It sets frame (17-5) to be surrounded by conveyer belt (17-3), driven wheel, driving wheel is equipped with before and after conveyer belt (17-3), wherein driving wheel It is connect with drive shaft (17-7), drive shaft (17-7) is connect with transmission driving motor (17-6)；It is set on the surface conveyer belt (17-3) Have baffle (17-1), baffle (17-1) quantity be 20, equidistant arrangement, body feed tank (17-2) be placed in two baffles (17-1) it Between；Velocity sensor (17-8) is equipped in sediment conveyor frame one end (17-5).
10. the cellular reaction unit in a kind of wastewater of construction processing according to claim 9, which is characterized in that The filtered fluid plate (3-6) is formed by high molecular material pressing mold,
One, the constituent of filtered fluid plate (3-6) is as follows:
268.5~493.0 parts of pure water according to parts by weight, 3- methyl-4- (2,6,6- trimethyl-1- base)-3- butene-2 -one 60.3~102.7 parts, poly- (silicomethane) 63.2 that 1- methoxyl group -3,7- bis- [[3- (front three oxygen silicon base) the third oxygen] methyl] blocks~ 172.2 parts, 59.2~76.0 parts of methylvinyldichlorosilane, 62.6~119.1 parts of collagen powder, four hydrogen-based O-phthalic of methyl 65.2~126.5 parts of acid anhydrides, 67.0~122.6 parts of nanoscale lithium zirconate particle, polypropylene and dimethyl methyl ethylene silicon oxygen 62.9~102.6 parts of the polymer of 60.8~102.8 parts of the reaction product of alkane, formaldehyde and 1,3- benzene dimethylamine and phenol, isophthalic The polymer of diacid and terephthalic acids, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl 62.4~85.0 parts, 51.3~87.9 parts of -2 (or 3)-sodium sulfonate of 5- methoxycarbonyl -5- methyl norbornane, 2 methyl valeric acid 50.7~93.2 parts of butyl ester, formaldehyde and chloromethyloxirane and 4, the polymer and N- of 4'- (1- methyl ethylidene) biphenol 59.2~104.5 parts of the polymer of the reaction product of butyl butylamine and diethanol amine, 4- (nine fluoro butoxy) -1- fourth ichthyodin 69.7~113.0 parts of salt, mass concentration is 92.6~146.3 parts of alpha-brominated n-caproic acid of 59mg/L~326mg/L；
Two, the manufacturing process of filtered fluid plate (3-6) comprising the steps of:
Step 1: in double shaft mix reactor, pure water and 3- methyl -4- (2,6,6- trimethyl -1- base) -3- fourth is added Alkene -2- ketone starts the blender in double shaft mix reactor, and setting speed is 61rpm~107rpm, starts double shaft mix Fuel heater in reactor makes temperature rise to 76.5 DEG C~77.0 DEG C, and the [[3- (trimethoxy of 1- methoxyl group -3,7- bis- is added Silicon substrate) the third oxygen] methyl] and sealing end poly- (silicomethane) stir evenly, carry out reaction 53.3~64.7 minutes, be added methyl ethylene Dichlorosilane, being passed through flow is 52.5m3/ min~93.0m3The nitrogen of/min 53.3~64.7 minutes；Later in double shaft mix In reactor be added collagen powder, the fuel heater being again started up in double shaft mix reactor, make temperature rise to 93.2 DEG C~ 126.2 DEG C, 53.2~64.0 minutes are kept the temperature, four hydrogen-based phthalic anhydride of methyl is added, is adjusted in double shaft mix reactor The pH value of solution is 4.6~8.1, keeps the temperature 53.6~293.6 minutes；
Step 2: separately taking nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is surpassed in the case where power is 5.93KW~11.37KW After sonicated 0.59~1.126 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, is added The reaction product for entering polypropylene and dimethyl methyl vinyl silicone that mass concentration is 63mg/L~293mg/L disperses nanometer Grade lithium zirconate particle, starts the fuel heater in double shaft mix reactor, makes solution temperature between 46 DEG C~84 DEG C, open Blender in dynamic double shaft mix reactor, and with 4 × 102Rpm~8 × 102The speed of rpm stirs, and adjusts pH value 4.3 Between~8.9, insulated and stirred 59~126 minutes；Stop reaction later and stand 5.93 × 10~11.37 × 10 minutes, goes to clean Matter；Formaldehyde and 1 is added in suspension, the polymer of 3- benzene dimethylamine and phenol adjusts pH value between 1.3~2.9, and it is heavy to be formed The pure water elution of starch, by centrifuge in revolving speed 4.338 × 103Rpm~9.102 × 103Solid content is obtained under rpm, 2.117×102DEG C~3.279 × 102It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding3~1.102 × 103Mesh, it is spare；
Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after polymer and the step 2 processing of 3-propanediol, dissipates alpha ray diffraction spoke using acute angle after mixing According to when the energy of the scattered alpha ray diffraction irradiation of acute angle is 50.7MeV~78.2MeV, dosage is 98.7kGy~138.2kGy, irradiates Between be 62.7~87.2 minutes, obtain character change isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 The polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of alcohol 2- ethyl；By isophthalic acid and to benzene The polymer and nanoscale zirconic acid of diacid, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl Lithium particle mixture is placed in another double shaft mix reactor, starts the fuel heater in double shaft mix reactor, if Determine 61.2 DEG C~107.5 DEG C of temperature, start the blender in double shaft mix reactor, revolving speed is 53rpm~448rpm, pH tune It is whole to be dehydrated 62.7~76.0 minutes between 4.7~8.0, it is spare；
Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In -2 (or 3)-sodium sulfonate of 5- methoxycarbonyl -5- methyl norbornane of 63mg/L~293mg/L, cocurrent adds to step 1 In double shaft mix reactor, flow acceleration is 198mL/min~926mL/min；Start double shaft mix and react mechanical stirrer, Setting speed is 67rpm~107rpm；Stirring 4~8 minutes；Add 2 methyl valeric acid butyl ester, starting double shaft mix reaction Fuel heater in device is warming up to 97.6 DEG C~134.3 DEG C, and pH is adjusted between 4.6~8.3, is passed through nitrogen ventilatory capacity and is 52.956m3/ min~93.352m3/ min, heat preservation stand 87.5~117.0 minutes；Double shaft mix reactor is again started up to stir Machine is mixed, revolving speed is 62rpm~107rpm, and formaldehyde and chloromethyloxirane and 4,4'- (1- methyl ethylidene) biphenol is added Polymer and N- butyl butylamine and diethanol amine reaction product polymer, and pH is adjusted between 4.6~8.3, Heat preservation stands 86.3~126.7 minutes；
Step 5: the blender in starting double shaft mix reactor, setting speed are 59rpm~126rpm, and starting twin axle stirs The fuel heater in reactor is mixed, sets temperature in double shaft mix reactor as 1.696 × 102DEG C~2.675 × 102 DEG C, 4- (nine fluoro butoxy) -1- fourth sulfonic acid ammonium salt is added, reacts 53.2~64.2 minutes；Alpha-brominated n-caproic acid is added later, Start the fuel heater in double shaft mix reactor, set temperature in double shaft mix reactor as 137.2 DEG C~ 193.0 DEG C, pH is adjusted between 4.6~8.6, and pressure is 0.59MPa~0.6MPa, and the reaction time is 0.4~0.9 hour；It After to be depressurized to gauge pressure be 0MPa, be cooled to 53.2 DEG C~64.2 DEG C and discharge into molding press to get to filtered fluid plate (3-6)；
The partial size of the nanoscale lithium zirconate particle is 67 μm~77 μm；
Cellular reaction unit in a kind of processing of wastewater of construction, the device working method including the following steps:
Step 1: in medicament mixing device (3-7), system starting, the medicament that confection delivery pipe (3-7-1) releases, with steaming The steam mixing that vapour injection pipe (3-7-2) generates, realizes heat effect, under cellular reactor (3-7-3) facilitation, with The additive reaction that additive filler pipe (3-7-4) is added realizes the maximization of medicament function, ultimately joins anaerobic fermentation In tank (3) tank body；The sediment of generation is sent to pulverizer (2) by sediment conveying device (17) as material is defeated；
Step 2: in pulverizer (2), powering on, from medicament mixing device (3-7), reclamation set (16) precipitating material under Hopper (2-6) enters crushing bin (2-5), the crushing material under crushing knife (2-4) dissection, and smashed material is by above may be used Adjustable sieve plate (2-3) under entering after adjusting sieve plate (2-7) to be dehydrated, under after adjustable sieve plate (2-3) dehydration, dry material passes through powder Material channel (2-8) falls into warehouse where powder push plate (2-1), and powder push rod (2-2) pushes powder push plate (2-1) to send dry material Enter feed pipe (4)；Crush the percolate generated respectively from upper adjustable sieve plate (2-7) through-hole, under adjustable sieve plate (2-3) through-hole enter Percolate storehouse (2-10), and enter main water inlet tube (1) from percolate branch pipe (8)；
Step 3: in anaerobic fermentation tank (3), enter anaerobic fermentation by feed pipe (4) from pulverizer (2) smashed material Tank (3) top carries out anaerobic fermentation, the first of generation under the stirring of agitator arm (3-2) and the heat effect of collector mat (3-3) Alkane gas is discharged from methane riser (5), and the percolate of generation enters the main water inlet tube of lower part (1)；When equipment is cleaned, Fresh water pump (3-5) starting will be implemented to clean inside equipment by cleaning pipe (3-4) clear water；
Step 4: it is internal in electromagnetic oscillation device (3-7-9), external power supply is connected, in high-voltage capacitor (3-7-9-2), permanent magnetic Under iron synergy, electromagnetic coil is promoted to generate vibration magnetic field, and then drives vibration rod, vibration ring high frequency oscillation, and drive electricity Magnetic vibration device (3-7-9) integrally shakes, and promotees to settle by intake tunnel (3-7-9-6) Suspended Matter in Water；At the same time, deuterium Emit deuterated tetrachloroethanes isotope for tetrachloroethanes isotope emitting head (3-7-9-4), further promotees to pass through intake tunnel (3- 7-9-6) Suspended Matter in Water settles；Under the irradiation of cyclic annular ultraviolet emission lamp (3-7-9-5), to by intake tunnel (3-7-9- 6) microorganism carries out effective sterilization processing in water body；
Step 5: in electrochemical reaction appts (13), the percolate from anaerobic fermentation tank (3) passes through oxidation pond water inlet pipe (13- 1) enter electrochemical reaction appts (13), in advance under the dilute sulfuric acid effect in acid solution inlet pipe (13-6), solution ph is brought to 3 ~4；At the same time, from oxidant feed pipe (13-5) enter ferrous iron and hydrogen peroxide solution is aoxidized, sediment from Electrochemical reaction appts (13) base sludge delivery pipe outlet, when treated solution is flowed out from oxidation outlet pipe (13-3), with It reacts from lye inlet pipe (13-4) sodium hydroxide, so that the pH value of solution is increased to 6~8, flows into main water inlet tube (1), in turn Into aerobic fermentation tank (6)；Oxidation-reduction potential instrument (13-2) monitors the oxidation process of electrochemical reaction appts (13) in real time, And it feeds back to control system (15) and carries out degree of oxidation control；
Step 6: in electrochemical reaction appts (13), the percolate from anaerobic fermentation tank (3) passes through sewage inlet tube (13-12) Pass through filter screen (13-10) into water inlet tank (13-1), and by buffer pool flow pipe (13-2) into filter chamber (13-11) Filtration, water body enter electrochemical chamber (13-9), under the action of the DC electric field that direct current torch (13-4) is generated, in water body Organic matter precipitates rapidly；At the same time, water body contacts generation chemistry hair with Water Ecological Recovery halftone contact screen (13-6) and answers, further Promote organic matter precipitating, and fall into mud chamber (13-3), sediment passes through sediment discharge pipe (13-5) outlet；Electrochemical treatments Pond (13-8) enters back into main water inlet tube (1) after water enters electrochemical treatments by electrochemical chamber (13-9) afterwards；
Step 7: in aerobic fermentation tank (6), electrochemical reaction appts (13) treatment fluid is come from, into aerobic fermentation tank (6), with this Meanwhile air injection tube (6-2) sprays bubble to solution, increases solution dissolved oxygen, heating rod (6-1) is controlled in control system (15) Solution is implemented to heat under system, the sludge of generation is discharged from bed mud discharge outlet (7)；
Step 8: in sediment conveying device (17), startup power supply, transmission driving motor (17-6) passes through drive shaft (17-7) band Dynamic conveyer belt (17-3) is mobile, is located at the baffle (17-1) on conveyer belt (17-3) and body feed tank (17-2) is pushed to travel forward；Speed It spends sensor (17-8) and monitors conveyer belt (17-3) working order in real time, and feed back to control system (15)；
Step 9: in reclamation set (16), the pending water of aerobic fermentation drainpipe (6-6) is come from, from flocculation deposition apparatus shell The top (16-5) enters, and meets with polymeric aluminum dispersion pipe (16-4) polymeric aluminum sprayed, and in macromolecule current stabilization sieve (16-3) It is formed under buffer function, falls into the lower part flocculation deposition apparatus shell (16-5)；Make at this time in the horizontal concussion of current stabilization wing plate (16-2) Under, accelerate flocculation reaction under the action of cellular reaction unit (16-1), when current stabilization wing plate (16-2), cellular reaction fill When setting (16-1) and stopping working, organic matter flocculation precipitating is simultaneously discharged from the sludge pipe of bottom, and clear water is arranged from water after the processing at middle part It puts pipe (16-8) and is discharged to primary flow pipe (14) discharge；
Step 10: at cellular reaction unit (16-1), solution is flowed into from the cellular reaction unit top (16-1), in dispersion plate Under (16-1-5) peptizaiton, sprayed even into diversion pipe (16-1-2), and from diversion pipe (16-1-2) surface through-hole, it is snakelike Heating tube (16-1-3) injection hot steam is mixed with solution, it is promoted to be reacted, and pressurization air supply device (16-1-1) is honeycomb Formula reaction unit (16-1) conveys fresh wind, and final solution is promoted to be equipped with a large amount of through-hole streams from the honeycomb shell surface (16-1-4) Out；
Step 11: in pressurization air supply device (16-1-1), powering on, and air supply motor (16-1-1-1) drives fan blade (16- It 1-1-3) rotates, and fresh wind is sent by air duct (16-1-1-6) to cellular reaction unit (16-1)；When overhaul of the equipments, It opens maintenance door (16-1-1-8), equipment is repaired into air duct (16-1-1-6)；
Step 12: device (16-1-1-9) is refined in lubricating oil, is powered on, lubricating oil to be processed is from oil inlet (16-1-1- 9-12) enter lubricating oil fining device (16-1-1-9), additive injection pipe (16-1-1-9-11) spray additive, with to Lubricating oil mixing is handled, the freon that freon pipe (16-1-1-9-1) sprays at the same time cools down mixed liquor, gasifies Atmosphere is spilt into from dregs of fat outlet (16-1-1-9-2) afterwards；Mixed liquor touches impact-absorbing shell (16-1-1-9-10), impact-absorbing shell (16- 1-1-9-10) mixing flow velocity is implemented to buffer and promotes to react；Mixed liquor travels further into two filter plate (16-1-1-9- 3) between, under agitator arm (16-1-1-9-5), filling ball (16-1-1-9-6) synergy, promote lubricant change property Shape, and be discharged from oil outlet (16-1-1-9-4), sediment is discharged from dregs of fat outlet (16-1-1-9-2)；Temperature inductor (16- 1-1-9-7), fatty acid concentration sensor (16-1-1-9-9) is in real time monitored oil product processing quality and feeds back to control system It unites (15), control system (15) controls lubricating oil fining device (16-1-1-9) work according to setup parameter.
CN201810812181.6A 2018-07-23 2018-07-23 A kind of cellular reaction unit in wastewater of construction processing Withdrawn CN108996817A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109987789A (en) * 2019-03-27 2019-07-09 中国科学院大学 Output water modularized processing device is adopted in a kind of more gas conjunctions of coal measures containing organic pollutant

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109987789A (en) * 2019-03-27 2019-07-09 中国科学院大学 Output water modularized processing device is adopted in a kind of more gas conjunctions of coal measures containing organic pollutant

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