CN108996815A

CN108996815A - A kind of concrete mixing plant wastewater recycling device

Info

Publication number: CN108996815A
Application number: CN201810810888.3A
Authority: CN
Inventors: 袁明慧; 武永峰
Original assignee: Jiangsu Institute of Architectural Technology
Current assignee: Jiangsu Institute of Architectural Technology
Priority date: 2018-07-23
Filing date: 2018-07-23
Publication date: 2018-12-14

Abstract

The invention discloses a kind of concrete mixing plant wastewater recycling devices, are equipped with macromolecule current stabilization sieve, mesh aperture 5mm~16mm in polymeric aluminum dispersion pipe lower part, macromolecule current stabilization sieve quantity is 10, and multiple macromolecule current stabilization sieves are superimposed layout up and down；It is equipped with current stabilization wing plate in macromolecule current stabilization sieve lower part, " Z " font is presented in vertical cross section, and current stabilization wing plate is connect by cranking arm with external motor, and external motor drives the concussion of current stabilization wing plate level；Electric and magnetic oscillation stick is equipped in current stabilization wing plate lower part, electric and magnetic oscillation stick quantity is 20, polymeric aluminum dispersion pipe one end is connected to by middle storage tank water pump with external middle storage tank, middle storage tank storage polymerization aluminum solutions, a kind of concrete mixing plant wastewater recycling device of the present invention, easy to maintain, treatment effeciency is high, device structure is simple, and operating condition is unrestricted.

Description

A kind of concrete mixing plant wastewater recycling device

Technical field

The invention belongs to construction equipment fields, and in particular to a kind of concrete mixing plant wastewater recycling device.

Background technique

Domestic concrete mixing plant wastewater treatment method generally uses sedimentation basin, thickener, ceramic filter tiles pond etc. at present Processing method also has a small number of producers by the way of flocculation sedimentation+Turbulent Flow jet-flow bed+cellular reactor.Flocculation refers to original After water is uniformly added into flocculant in a mixer, into module sink filter flocculation zone perforate rotational flow flocculation tank, water flow is by more In the perforation rotational flow flocculation tank of a grid composition, eddy flow, flocculant and water Quick uniform are formed after the entrance of pool wall tangential direction It is mixed to form wadding body, it can be for different needs, the targeted selection function flocculant of different quality；Precipitating refers to using slope Depositing technology, water enter slope sedimentation basin by bottom, flow downward from down, and impurity particle is sunken to numerous slope bottoms, along oblique Slope freely glides, and clear water is collected by catch basin in Chi Ding and flows into filtering ponds, and sludge is collected at sedimentation basin bottom by perforated sludge discharge pipe, fixed When be discharged into sludge concentration tank.Often there is flocculant in existing flocculation deposition apparatus and pulp water stirring is uneven, and precipitating is not thorough The problem of, while difficulty is discharged in the sludge of place of settling, it be easy to cause the bridging of spoil disposal nozzle, serious influence flocculation sedimentation work Make.

Summary of the invention

In order to solve the above technical problem, the present invention provides a kind of concrete mixing plant wastewater recycling device, wherein coagulation Soil mixing station waste water treatment system operating platform includes: main water inlet tube 1, pulverizer 2, anaerobic fermentation tank 3, feed pipe 4, methane liter Tracheae 5, aerobic fermentation tank 6, bed mud discharge outlet 7, percolate branch pipe 8, oxygen hose 9, aerobic fermentation tank inlet tube 10, reclamation set Drainpipe 11, slag notch 12, advanced oxidation pond 13, primary flow pipe 14, control system 15, reclamation set 16；The main water inlet tube 1,14 horizontal layout of primary flow pipe, main water inlet tube 1,14 diameter of primary flow pipe are made by 20cm~30cm, by high molecular material, main Water inlet pipe 1, primary flow pipe 14 are connected to respectively at anaerobic fermentation tank 3, aerobic fermentation tank 6, advanced oxidation pond 13；In main water inlet tube 1 Upper right is equipped with pulverizer 2, and main water inlet tube 1 is connected to pulverizer 2 by percolate branch pipe 8；2 side of pulverizer is equipped with anaerobism Fermentor 3,3 top of anaerobic fermentation tank are equipped with methane riser 5, and 3 lower part of anaerobic fermentation tank is equipped with slag notch 12, anaerobic fermentation tank 3 are connected to pulverizer 2 by feed pipe 4；4 vertical portion lower part of feed pipe be equipped with percolate branch pipe 8, percolate branch pipe 8 with Main water inlet tube 1 is connected to；The aerobic fermentation tank 6 is located at 3 side of anaerobic fermentation tank, aerobic fermentation tank 6 by aerobic fermentation tank into Liquid pipe 10 is connected to main water inlet tube 1；10 vertical portion top of aerobic fermentation tank inlet tube is equipped with methane riser 5, aerobic fermentation 6 lower part of tank is equipped with reclamation set drainpipe 11, and 11 top of reclamation set drainpipe is equipped with reclamation set 16, and reclamation set 16 passes through Reclamation set drainpipe 11 is connected to primary flow pipe 14；6 one side lower part of aerobic fermentation tank is equipped with bed mud discharge outlet 7；It is described advanced Oxidation pond 13 is located at 6 left side of aerobic fermentation tank, and the infiltration from anaerobic fermentation tank 3 is accepted by main water inlet tube 1 in advanced oxidation pond 13 Filtrate；Aerobic fermentation tank 6 is accepted by main water inlet tube 1 and comes from 13 treatment fluid of advanced oxidation pond；Control system 15 is located at anaerobism hair 3 side of fermentation tank.

Further, this section is the explanation to heretofore described 2 structure of pulverizer.The pulverizer 2 includes: that powder pushes away Plate 2-1, powder push rod 2-2, under adjustable sieve plate 2-3, crushing knife 2-4, crushing bin 2-5, lower hopper 2-6, upper adjustable sieve plate 2-7, Powder channel 2-8, sieve plate adjuster 2-9, percolate storehouse 2-10；

Superposed lower hopper 2-6, its underpart are penetrated through equipped with crushing bin 2-5, crushing bin 2-5 and lower hopper 2-6；Crushing bin 2- 5 inside are equipped with crushing knife 2-4, and crushing knife 2-4 quantity is 2, and arranged opposite；The lower part crushing knife 2-4 is equipped with upper adjustable sieve plate 2-7, the upper surface adjustable sieve plate 2-7 be equipped with a large amount of through-holes, upper adjustable 15~60 degree of sieve plate 2-7 horizontal sextant angle；Upper adjustable sieve plate 2-7 Lower part is equipped with down adjustable sieve plate 2-3, upper adjustable sieve plate 2-7 and under formed at a distance of the narrow of 20cm~50cm between adjustable sieve plate 2-3 Seam, comminuting matter falls on down the surface adjustable sieve plate 2-3 under this slit, under the surface adjustable sieve plate 2-3 be equipped with a large amount of through-holes, with 15~60 degree of horizontal plane angle；Under be equipped with powder channel 2-8 on the left of adjustable sieve plate 2-3, comminuting matter continues from powder channel 2-8 It falls；The sieve plate adjuster 2-9 and upper adjustable sieve plate 2-7, under adjustable sieve plate 2-3 be mechanically connected, sieve plate adjuster 2-9 is to upper Adjustable sieve plate 2-7, under adjustable sieve plate 2-3 realize that adjustable angle, plate spacing is adjustable；Under the lower part adjustable sieve plate 2-3 pushed away equipped with powder Plate 2-1, the powder side push plate 2-1 are mechanically connected equipped with powder push rod 2-2, powder push plate 2-1 and powder push rod 2-2；The infiltration Filtrate storehouse 2-10 is located at the lower part crushing bin 2-5, penetrates through with crushing bin 2-5, and the percolate storehouse bottom 2-10 is equipped with percolate branch pipe 8。

Further, this section is the explanation to heretofore described 3 structure of anaerobic fermentation tank.The anaerobic fermentation tank 3 wraps It includes: stirring motor 3-1, agitator arm 3-2, collector mat 3-3, cleaning pipe 3-4, fresh water pump 3-5, filtered fluid plate 3-6, medicament mixing Device 3-7；

Stirring motor 3-1 outside side is connect by transmission device with internal agitator arm 3-2；Agitator arm 3-2 Contour with anaerobic fermentation tank 3, stirring motor 3-1 drives agitator arm 3-2 rotation；Collector mat is equipped in agitator arm 3-2 waist 3-3, collector mat 3-3 are connect with external power supply, and collector mat 3-3 provides heat for anaerobic fermentation；It is equipped in the lower part agitator arm 3-2 Filtered fluid plate 3-6, filtered fluid plate 3-6, which is realized, to be separated by solid-liquid separation；The medicament mixing device 3-7 is located at feed pipe 4 and methane rises gas 5 side of pipe, agitator arm 3-2 top.

Further, this section is the explanation to heretofore described medicament mixing device 3-7 structure, the medicament mixing dress Setting 3-7 includes: confection delivery pipe 3-7-1, steam injection pipe 3-7-2, cellular reactor 3-7-3, additive filler pipe 3-7-4, medicament injection pipe 3-7-5, sluicing pipe 3-7-6, temperature sensor 3-7-7, equipment base 3-7-8；

Sluicing pipe 3-7-6 positioned at top, one end connects with external water pump, the other end with inside medicament mixing device 3-7 Lotus spray-head connection, lotus spray-head lower part be equipped with cellular reactor 3-7-3, cellular reactor of the lotus spray-head to lower part 3-7-3 implements cleaning；The cellular reactor 3-7-3 section is honeycomb, is vertically arranged group by more honeycomb standpipes At cellular reactor 3-7-3 is up and down；Additive filler pipe 3-7-4, medicament injection are equipped in the side sluicing pipe 3-7-6 Pipe 3-7-5；It is equipped with temperature sensor 3-7-7 in the middle part of medicament mixing device 3-7, is connect by conducting wire with control system 15； It is equipped with steam injection pipe 3-7-2 in the lower part cellular reactor 3-7-3, steam injection pipe 3-7-2 is circular, and upper surface is equipped with A large amount of through-holes, steam one end injection pipe 3-7-2 are connected to external steam pipeline, and steam injection pipe 3-7-2 is to the cellular of top Reactor 3-7-3 sprays high-temperature steam and promotes medicament reaction；Confection delivery pipe 3- is equipped in the bottom medicament mixing device 3-7 7-1；Medicament, additive are filled into medicament mixing device 3-7 from medicament injection pipe 3-7-5, medicament injection pipe 3-7-5 respectively, The sprayed high-temperature steam of steam injection pipe 3-7-2 promotes medicament in cellular reactor 3-7-3 internal-response, after from mixing Medicament delivery pipe 3-7-1 discharge.

Further, this section is the explanation to heretofore described 13 structure of advanced oxidation pond.The advanced oxidation pond 13 Include: oxidation pond water inlet pipe 13-1, oxidation-reduction potential instrument 13-2, aoxidize outlet pipe 13-3, lye inlet pipe 13-4, oxidant into Expects pipe 13-5, acid solution inlet pipe 13-6；

Oxidation pond water inlet pipe 13-1 positioned at 13 side of advanced oxidation pond, is connected to main water inlet tube 1, and by main water inlet tube 1 with Anaerobic fermentation tank 3 is connected to；The oxidation pond top water inlet pipe 13-1 is equipped with acid solution inlet pipe 13-6, the two connection；Positioned at advanced oxidation pond The oxidation outlet pipe 13-3 of 13 other sides, is connected to main water inlet tube 1, oxidation outlet pipe 13-3 by main water inlet tube 1 with it is aerobic Fermentor 6 is connected to；It aoxidizes the top outlet pipe 13-3 and is equipped with lye inlet pipe 13-4, the two connection；13 top of advanced oxidation pond is equipped with Oxidant feed pipe 13-5, the two connection；Oxidation-reduction potential instrument 13-2 is connect with 15 polygon control survey of control system.

Further, this section is the explanation to heretofore described 6 structure of aerobic fermentation tank.The aerobic fermentation tank 6 wraps It includes: heating rod 6-1, air injection tube 6-2, steadying plate 6-3, bed mud warehouse lid 6-4, clear water drain valve 6-5, aerobic fermentation drainpipe 6-6；

Heating rod 6-1 positioned at top, connects to power supply, and connect with 15 polygon control survey of control system；At heating rod 6-1 Portion is equipped with air injection tube 6-2, and the surface air injection tube 6-2 is equipped with a large amount of through-holes, and air injection tube 6-2 quantity is 10, phase It is mutually equally spaced, air injection tube 6-2 pipe range is 20cm~86cm, diameter 20cm, the one end air injection tube 6-2 and oxygen hose 9 connections；Be equipped with steadying plate 6-3 in the lower part air injection tube 6-2, steadying plate 6-3 it is horizontally disposed and with 6 section of aerobic fermentation tank Equal in magnitude, the surface steadying plate 6-3 is equipped with a large amount of through-holes；Clear water drain valve 6-5, clear water discharge are equipped in the lower part steadying plate 6-3 Valve 6-5 and aerobic fermentation drainpipe 6-6 is penetrated through, and wherein the upper end aerobic fermentation drainpipe 6-6 is deep into the top steadying plate 6-3；? The clear water side drain valve 6-5 is equipped with bed mud warehouse lid 6-4.

Further, this section is the explanation to heretofore described 16 structure of reclamation set.Reclamation set 16 includes: electromagnetism Vibrating head 16-1, current stabilization wing plate 16-2, macromolecule current stabilization sieve 16-3, polymeric aluminum dispersion pipe 16-4, flocculation deposition apparatus shell 16-5, middle storage tank 16-6, middle storage tank water pump 16-7, water discharge spout 16-8 after processing；

Inside the flocculation deposition apparatus shell 16-5, most top position be equipped with polymeric aluminum dispersion pipe 16-4, polymeric aluminum dispersion pipe 16- 4 rectangular ring structures, quantity be 2, it is arranged in parallel, the polymeric aluminum surface dispersion pipe 16-4 be equipped with spray head, spray head direction is downward, Polymeric aluminum one end dispersion pipe 16-4 is connected to by middle storage tank water pump 16-7 with external middle storage tank 16-6, and middle storage tank 16-6 storage is poly- Close aluminum solutions；It is equipped with macromolecule current stabilization sieve 16-3, mesh aperture 5mm~16mm in the polymeric aluminum lower part dispersion pipe 16-4, it is high Molecule current stabilization sieve 16-3 quantity is 10, and multiple macromolecule current stabilization sieve 16-3 or more are superimposed layout；It is sieved in macromolecule current stabilization It nets the lower part 16-3 and is equipped with current stabilization wing plate 16-2, " Z " font is presented in vertical cross section, and the quantity of current stabilization wing plate 16-2 is 10, more A current stabilization wing plate 16-2 is horizontally arranged, passes through between adjacent current stabilization wing plate 16-2 at a distance of 2cm~6cm, multiple current stabilization wing plate 16-2 It cranks arm and is connect with external motor, external motor drives the concussion of current stabilization wing plate 16-2 level；Electricity is equipped in the current stabilization lower part wing plate 16-2 Magnetic vibration stick 16-1, electric and magnetic oscillation stick 16-1 quantity are 20, and multiple electric and magnetic oscillation stick 16-1 levels equidistantly distribute, adjacent electricity It is connect by conducting wire with control system 15 between magnetic vibration stick 16-1 at a distance of 10cm~60cm, electric and magnetic oscillation stick 16-1；The wadding The design of the retrogradation shallow lake device housing side 16-5 cone, open topped, lower part closing；Water discharge spout 16-8 is located at flocculation after the processing The middle part of settler shell 16-5；Sediment is connected to from bottom pipe with pulverizer 2；

The reclamation set 16 is located inside concrete mixing plant waste water treatment system.

Further, the filtered fluid plate 3-6 is formed by high molecular material pressing mold, the constituent of filtered fluid plate 3-6 and Manufacturing process is as follows:

One, filtered fluid plate 3-6 constituent:

268.5~493.0 parts of pure water according to parts by weight, 3- methyl-4- (2,6,6- trimethyl-1- base)-3- butene-2 -one 60.3~102.7 parts, poly- (silicomethane) 63.2 that 1- methoxyl group -3,7- bis- [[3- (front three oxygen silicon base) the third oxygen] methyl] blocks~ 172.2 parts, 59.2~76.0 parts of methylvinyldichlorosilane, 62.6~119.1 parts of collagen powder, four hydrogen-based O-phthalic of methyl 65.2~126.5 parts of acid anhydrides, 67.0~122.6 parts of nanoscale lithium zirconate particle, polypropylene and dimethyl methyl ethylene silicon oxygen 62.9~102.6 parts of the polymer of 60.8~102.8 parts of the reaction product of alkane, formaldehyde and 1,3- benzene dimethylamine and phenol, isophthalic The polymer of diacid and terephthalic acids, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl 62.4~85.0 parts, 51.3~87.9 parts of -2 (or 3)-sodium sulfonate of 5- methoxycarbonyl -5- methyl norbornane, 2 methyl valeric acid 50.7~93.2 parts of butyl ester, formaldehyde and chloromethyloxirane and 4, the polymer and N- of 4'- (1- methyl ethylidene) biphenol 59.2~104.5 parts of the polymer of the reaction product of butyl butylamine and diethanol amine, 4- (nine fluoro butoxy) -1- fourth ichthyodin 69.7~113.0 parts of salt, mass concentration is 92.6~146.3 parts of alpha-brominated n-caproic acid of 59mg/L~326mg/L；

Two, the manufacturing process of filtered fluid plate 3-6 comprising the steps of:

Step 1: in double shaft mix reactor, pure water and 3- methyl -4- (2,6,6- trimethyl -1- base) -3- fourth is added Alkene -2- ketone starts the blender in double shaft mix reactor, and setting speed is 61rpm~107rpm, starts double shaft mix Fuel heater in reactor makes temperature rise to 76.5 DEG C~77.0 DEG C, and the [[3- (trimethoxy of 1- methoxyl group -3,7- bis- is added Silicon substrate) the third oxygen] methyl] and sealing end poly- (silicomethane) stir evenly, carry out reaction 53.3~64.7 minutes, be added methyl ethylene Dichlorosilane, being passed through flow is 52.5m³/ min~93.0m³The nitrogen of/min 53.3~64.7 minutes；Later in double shaft mix In reactor be added collagen powder, the fuel heater being again started up in double shaft mix reactor, make temperature rise to 93.2 DEG C~ 126.2 DEG C, 53.2~64.0 minutes are kept the temperature, four hydrogen-based phthalic anhydride of methyl is added, is adjusted in double shaft mix reactor The pH value of solution is 4.6~8.1, keeps the temperature 53.6~293.6 minutes；

Step 2: separately taking nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is surpassed in the case where power is 5.93KW~11.37KW After sonicated 0.59~1.126 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, is added The reaction product for entering polypropylene and dimethyl methyl vinyl silicone that mass concentration is 63mg/L~293mg/L disperses nanometer Grade lithium zirconate particle, starts the fuel heater in double shaft mix reactor, makes solution temperature between 46 DEG C~84 DEG C, open Blender in dynamic double shaft mix reactor, and with 4 × 10²Rpm~8 × 10²The speed of rpm stirs, and adjusts pH value 4.3 Between~8.9, insulated and stirred 59~126 minutes；Stop reaction later and stand 5.93 × 10~11.37 × 10 minutes, goes to clean Matter；Formaldehyde and 1 is added in suspension, the polymer of 3- benzene dimethylamine and phenol adjusts pH value between 1.3~2.9, and it is heavy to be formed The pure water elution of starch, by centrifuge in revolving speed 4.338 × 10³Rpm~9.102 × 10³Solid content is obtained under rpm, 2.117×10²DEG C~3.279 × 10²It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding³~1.102 × 10³Mesh, it is spare； Step 3: isophthalic acid and terephthalic acids, -2 methylol -1,3- third of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl are separately taken Nanoscale lithium zirconate particle after polymer and the step 2 processing of glycol, dissipates the irradiation of alpha ray diffraction using acute angle after mixing, The energy of the scattered alpha ray diffraction irradiation of acute angle is 50.7MeV~78.2MeV, dosage is 98.7kGy~138.2kGy, irradiation time It is 62.7~87.2 minutes, obtains the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and neopentyl glycol of character change The polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of 2- ethyl；By isophthalic acid and to benzene two The polymer and nanoscale lithium zirconate of acid, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl Particle mixture is placed in another double shaft mix reactor, starts the fuel heater in double shaft mix reactor, setting 61.2 DEG C~107.5 DEG C of temperature, start the blender in double shaft mix reactor, revolving speed is 53rpm~448rpm, pH adjustment To between 4.7~8.0, it is dehydrated 62.7~76.0 minutes, it is spare；

Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In -2 (or 3)-sodium sulfonate of 5- methoxycarbonyl -5- methyl norbornane of 63mg/L~293mg/L, cocurrent adds to step 1 In double shaft mix reactor, flow acceleration is 198mL/min~926mL/min；Start double shaft mix and react mechanical stirrer, Setting speed is 67rpm~107rpm；Stirring 4~8 minutes；Add 2 methyl valeric acid butyl ester, starting double shaft mix reaction Fuel heater in device is warming up to 97.6 DEG C~134.3 DEG C, and pH is adjusted between 4.6~8.3, is passed through nitrogen ventilatory capacity and is 52.956m³/ min~93.352m³/ min, heat preservation stand 87.5~117.0 minutes；Double shaft mix reactor is again started up to stir Machine is mixed, revolving speed is 62rpm~107rpm, and formaldehyde and chloromethyloxirane and 4,4'- (1- methyl ethylidene) biphenol is added Polymer and N- butyl butylamine and diethanol amine reaction product polymer, and pH is adjusted between 4.6~8.3, Heat preservation stands 86.3~126.7 minutes；

Step 5: the blender in starting double shaft mix reactor, setting speed are 59rpm~126rpm, and starting twin axle stirs The fuel heater in reactor is mixed, sets temperature in double shaft mix reactor as 1.696 × 10²DEG C~2.675 × 10² DEG C, 4- (nine fluoro butoxy) -1- fourth sulfonic acid ammonium salt is added, reacts 53.2~64.2 minutes；Alpha-brominated n-caproic acid is added later, Start the fuel heater in double shaft mix reactor, set temperature in double shaft mix reactor as 137.2 DEG C~ 193.0 DEG C, pH is adjusted between 4.6~8.6, and pressure is 0.59MPa~0.6MPa, and the reaction time is 0.4~0.9 hour；It After to be depressurized to gauge pressure be 0MPa, be cooled to 53.2 DEG C~64.2 DEG C and discharge into molding press to get to filtered fluid plate 3-6；

The partial size of the nanoscale lithium zirconate particle is 67 μm~77 μm.

A kind of concrete mixing plant wastewater recycling device of the present invention, the advantage is that using this equipment and work side Method, work efficiency is high, and equipment production does not generate secondary pollution, environment-friendly high-efficiency, and device structure is simple, easy to maintain, can be more It is used under kind execution conditions.

Detailed description of the invention

Fig. 1 is a kind of heretofore described concrete mixing plant wastewater recycling device overall system architecture schematic diagram therein.

Fig. 2 is heretofore described 2 structural schematic diagram of pulverizer.

Fig. 3 is heretofore described 3 structural schematic diagram of anaerobic fermentation tank.

Fig. 4 is heretofore described medicament mixing device 3-7 structural schematic diagram.

Fig. 5 is heretofore described 13 structural schematic diagram of advanced oxidation pond.

Fig. 6 is heretofore described 6 structural schematic diagram of aerobic fermentation tank.

Fig. 7 is heretofore described 16 structural schematic diagram of reclamation set.

Fig. 8 is that heretofore described filtered fluid plate 3-6 test parameters changes over time figure.

Specific embodiment

A kind of concrete mixing plant wastewater recycling device provided by the invention is made into one with reference to the accompanying drawings and examples Walk explanation.

As shown in Figure 1, being a kind of heretofore described concrete mixing plant wastewater recycling device overall system architecture therein Schematic diagram.As seen from the figure, the main water inlet tube 1,14 horizontal layout of primary flow pipe, main water inlet tube 1,14 diameter of primary flow pipe are 20cm~30cm, it is made of high molecular material, main water inlet tube 1, primary flow pipe 14 are respectively at anaerobic fermentation tank 3, aerobic fermentation tank 6, advanced oxidation pond 13 is connected to；It is equipped with pulverizer 2 in 1 upper right of main water inlet tube, main water inlet tube 1 and pulverizer 2 pass through diafiltration Liquid branch pipe 8 is connected to；2 side of pulverizer is equipped with anaerobic fermentation tank 3, and 3 top of anaerobic fermentation tank is equipped with methane riser 5, anaerobism hair 3 lower part of fermentation tank is equipped with slag notch 12, and anaerobic fermentation tank 3 is connected to pulverizer 2 by feed pipe 4；Under 4 vertical portion of feed pipe Portion is equipped with percolate branch pipe 8, and percolate branch pipe 8 is connected to main water inlet tube 1；The aerobic fermentation tank 6 is located at anaerobic fermentation tank 3 one Side, aerobic fermentation tank 6 are connected to by aerobic fermentation tank inlet tube 10 with main water inlet tube 1；10 vertical portion of aerobic fermentation tank inlet tube Point top is equipped with methane riser 5, and 6 lower part of aerobic fermentation tank is equipped with reclamation set drainpipe 11, on reclamation set drainpipe 11 Portion is equipped with reclamation set 16, and reclamation set 16 is connected to by reclamation set drainpipe 11 with primary flow pipe 14；Aerobic fermentation tank 6 one Side lower part is equipped with bed mud discharge outlet 7；The advanced oxidation pond 13 is located at 6 left side of aerobic fermentation tank, and advanced oxidation pond 13 passes through master Water inlet pipe 1 accepts the percolate from anaerobic fermentation tank 3；Aerobic fermentation tank 6 is accepted by main water inlet tube 1 and comes from advanced oxidation pond 13 treatment fluids；Control system 15 is located at 3 side of anaerobic fermentation tank.

As shown in Fig. 2, being heretofore described 2 structural schematic diagram of pulverizer.As seen from the figure, superposed lower hopper 2-6, its underpart are penetrated through equipped with crushing bin 2-5, crushing bin 2-5 and lower hopper 2-6；Crushing knife 2-4 is equipped with inside crushing bin 2-5, Crushing knife 2-4 quantity is 2, and arranged opposite；The lower part crushing knife 2-4 is equipped with upper adjustable sieve plate 2-7, upper adjustable sieve plate 2-7 table Face be equipped with a large amount of through-holes, upper adjustable 15~60 degree of sieve plate 2-7 horizontal sextant angle；The upper lower part adjustable sieve plate 2-7 is equipped with down adjustable sieve plate 2-3, upper adjustable sieve plate 2-7 and under form the slit at a distance of 20cm~50cm between adjustable sieve plate 2-3, comminuting matter is from this slit Under fall on down the surface adjustable sieve plate 2-3, under the surface adjustable sieve plate 2-3 be equipped with a large amount of through-holes, 15~60 degree of angle with horizontal plane； Under be equipped with powder channel 2-8 on the left of adjustable sieve plate 2-3, comminuting matter continues to fall from powder channel 2-8；The sieve plate adjuster 2-9 and upper adjustable sieve plate 2-7, under adjustable sieve plate 2-3 be mechanically connected, sieve plate adjuster 2-9 to upper adjustable sieve plate 2-7, under it is adjustable Sieve plate 2-3 realizes that adjustable angle, plate spacing is adjustable；Under the lower part adjustable sieve plate 2-3 be equipped with powder push plate 2-1, powder push plate 2-1 mono- Side is mechanically connected equipped with powder push rod 2-2, powder push plate 2-1 and powder push rod 2-2；The percolate storehouse 2-10 is located at crushing bin The lower part 2-5 is penetrated through with crushing bin 2-5, and the percolate storehouse bottom 2-10 is equipped with percolate branch pipe 8.

As shown in figure 3, being heretofore described 3 structural schematic diagram of anaerobic fermentation tank.As seen from the figure, it is located at outside side Stirring motor 3-1, connect by transmission device with internal agitator arm 3-2；Agitator arm 3-2 and anaerobic fermentation tank 3 etc. Height, stirring motor 3-1 drive agitator arm 3-2 rotation；Agitator arm 3-2 waist be equipped with collector mat 3-3, collector mat 3-3 with External power supply connection, collector mat 3-3 provide heat for anaerobic fermentation；Filtered fluid plate 3-6, mistake are equipped in the lower part agitator arm 3-2 Filtrate plate 3-6, which is realized, to be separated by solid-liquid separation；The medicament mixing device 3-7 is located at 5 side of feed pipe 4 and methane riser, paddle Take turns the top of 3-2.

As shown in figure 4, being heretofore described medicament mixing device 3-7 schematic diagram.As seen from the figure, washing positioned at top Pipe 3-7-6 is washed, one end is connect with external water pump, and the other end is connect with the lotus spray-head inside medicament mixing device 3-7, lotus Flower spray head lower part is equipped with cellular reactor 3-7-3, and lotus spray-head implements cleaning to the cellular reactor 3-7-3 of lower part；Institute Stating cellular reactor 3-7-3 section is honeycomb, is vertically arranged and is formed by more honeycomb standpipes, cellular reactor 3- 7-3 is up and down；Additive filler pipe 3-7-4, medicament injection pipe 3-7-5 are equipped in the side sluicing pipe 3-7-6；It is mixed in medicament It is equipped with temperature sensor 3-7-7 in the middle part of device 3-7, is connect by conducting wire with control system 15；In cellular reactor 3-7-3 Lower part is equipped with steam injection pipe 3-7-2, and steam injection pipe 3-7-2 is circular, and upper surface is equipped with a large amount of through-holes, steam injection pipe The one end 3-7-2 is connected to external steam pipeline, and steam injection pipe 3-7-2 sprays high temperature to the cellular reactor 3-7-3 on top The reaction of steam promotion medicament；Confection delivery pipe 3-7-1 is equipped in the bottom medicament mixing device 3-7；Medicament, additive difference It is filled into medicament mixing device 3-7 from medicament injection pipe 3-7-5, medicament injection pipe 3-7-5, steam injection pipe 3-7-2 is sprayed High-temperature steam promotes medicament in cellular reactor 3-7-3 internal-response out, after arranged from confection delivery pipe 3-7-1 Out.

As shown in figure 5, being heretofore described 13 structural schematic diagram of advanced oxidation pond.As seen from the figure, it is located at advanced oxygen The oxidation pond water inlet pipe 13-1 for changing 13 side of pond, is connected to main water inlet tube 1, and is connected by main water inlet tube 1 and anaerobic fermentation tank 3 It is logical；The oxidation pond top water inlet pipe 13-1 is equipped with acid solution inlet pipe 13-6, the two connection；Oxidation positioned at 13 other side of advanced oxidation pond Outlet pipe 13-3 is connected to main water inlet tube 1, and oxidation outlet pipe 13-3 is connected to by main water inlet tube 1 with aerobic fermentation tank 6；Oxygen The top water pipe 13-3 is dissolved equipped with lye inlet pipe 13-4, the two connection；13 top of advanced oxidation pond is equipped with oxidant feed pipe 13- 5, the two connection；Oxidation-reduction potential instrument 13-2 is connect with 15 polygon control survey of control system.

As shown in fig. 6, being heretofore described 6 structural schematic diagram of aerobic fermentation tank.As seen from the figure, adding positioned at top Hot pin 6-1, connects to power supply, and connect with 15 polygon control survey of control system；Air injection tube is equipped in the lower part heating rod 6-1 6-2, the surface air injection tube 6-2 are equipped with a large amount of through-holes, and air injection tube 6-2 quantity is 10, are mutually equally spaced, air spray Penetrating pipe 6-2 pipe range is 20cm~86cm, and diameter 20cm, the one end air injection tube 6-2 is connected to oxygen hose 9；It is sprayed in air The lower part pipe 6-2 is equipped with steadying plate 6-3, and steadying plate 6-3 is horizontally disposed with and, steadying plate 6- equal with 6 cross-sectional sizes of aerobic fermentation tank 3 surfaces are equipped with a large amount of through-holes；It is equipped with clear water drain valve 6-5 in the lower part steadying plate 6-3, clear water drain valve 6-5 and aerobic fermentation are arranged Water pipe 6-6 perforation, wherein the upper end aerobic fermentation drainpipe 6-6 is deep into the top steadying plate 6-3；In the side clear water drain valve 6-5 Equipped with bed mud warehouse lid 6-4.

As shown in fig. 7, being heretofore described 16 structural schematic diagram of reclamation set.As seen from the figure, the flocculation sedimentation Inside device housing 16-5, most top position is equipped with polymeric aluminum dispersion pipe 16-4, polymeric aluminum dispersion pipe 16-4 rectangular ring structure, number Amount for 2, it is arranged in parallel, the polymeric aluminum surface dispersion pipe 16-4 be equipped with spray head, spray head direction is downward, polymeric aluminum dispersion pipe 16-4 One end is connected to by middle storage tank water pump 16-7 with external middle storage tank 16-6, middle storage tank 16-6 storage polymerization aluminum solutions；It is polymerizeing The aluminium lower part dispersion pipe 16-4 is equipped with macromolecule current stabilization sieve 16-3, mesh aperture 5mm~16mm, macromolecule current stabilization sieve 16-3 Quantity is 10, and multiple macromolecule current stabilization sieve 16-3 or more are superimposed layout；It is equipped in the macromolecule current stabilization lower part sieve 16-3 steady Wing plate 16-2 is flowed, " Z " font is presented in vertical cross section, and the quantity of current stabilization wing plate 16-2 is 10, multiple current stabilization wing plate 16-2 water Flat raft column, at a distance of 2cm~6cm between adjacent current stabilization wing plate 16-2, multiple current stabilization wing plate 16-2 are by cranking arm and external motor connects It connects, external motor drives the concussion of current stabilization wing plate 16-2 level；Electric and magnetic oscillation stick 16-1, electromagnetism are equipped in the current stabilization lower part wing plate 16-2 Vibrating head 16-1 quantity is 20, and multiple electric and magnetic oscillation stick 16-1 levels equidistantly distribute, between adjacent electric and magnetic oscillation stick 16-1 At a distance of 10cm~60cm, electric and magnetic oscillation stick 16-1 is connect by conducting wire with control system 15；The flocculation deposition apparatus shell 16- The design of 5 side's cones, open topped, lower part closing；Water discharge spout 16-8 is located at flocculation deposition apparatus shell 16-5 after the processing Middle part；Sediment is connected to from bottom pipe with pulverizer 2；The reclamation set 16 is located at concrete mixing plant wastewater treatment system System is internal.

Following embodiment further illustrates the contents of the present invention, and as filtered fluid plate 3-6, it is important set of the invention Part increases the service life of integral device due to its presence, it plays pass for the safety of integral device, even running Key effect.For this purpose, by it is following be embodiment, further verify filtered fluid plate 3-6 of the present invention, what is shown is higher than The physical characteristic of other related patents.

Embodiment 1

Filtered fluid plate 3-6 of the present invention is prepared according to the following steps, and according to parts by weight:

Step 1: in double shaft mix reactor, 268.5 parts of pure water and 3- methyl -4- (2,6,6- trimethyl -1- are added Base) 60.3 parts of-3- butene-2 -one, start the blender in double shaft mix reactor, setting speed 61rpm starts twin shaft Fuel heater in formula stirred reactor makes temperature rise to 76.5 DEG C, and [[3- (the trimethoxy silicon of 1- methoxyl group -3,7- bis- is added Base) the third oxygen] methyl] 63.2 parts of poly- (silicomethane) of sealing end stir evenly, carry out reaction 53.3 minutes, methyl ethylene two is added 59.2 parts of chlorosilane, being passed through flow is 52.5m³The nitrogen of/min 53.3 minutes；It is added in double shaft mix reactor later 62.6 parts of collagen powder, the fuel heater being again started up in double shaft mix reactor makes temperature rise to 93.2 DEG C, heat preservation 53.2 Minute, 65.2 parts of four hydrogen-based phthalic anhydride of methyl is added, the pH value for adjusting solution in double shaft mix reactor is 4.6, Heat preservation 53.6 minutes；

Step 2: separately taking 67.0 parts of nanoscale lithium zirconate particle, by nanoscale lithium zirconate particle power be 5.93KW under ultrasonic wave After processing 0.59 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, mass concentration is added For 63mg/L polypropylene and dimethyl methyl vinyl silicone 60.8 parts of dispersion nanoscale lithium zirconate particles of reaction product, Start the fuel heater in double shaft mix reactor, make solution temperature at 46 DEG C, starts in double shaft mix reactor Blender, and with 4 × 10²The speed of rpm stirs, and adjusts pH value 4.3, insulated and stirred 59 minutes；Stop reaction later to stand 5.93 × 10 minutes, remove impurity；Formaldehyde and 1 is added in suspension, 62.9 parts of polymer of 3- benzene dimethylamine and phenol, is adjusted PH value forms the pure water elution of sediment, by centrifuge in revolving speed 4.338 × 10 1.3³Solid content is obtained under rpm, 2.117×10²It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding³Mesh, it is spare；

Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after polymer 62.4 and the step 2 processing of 3-propanediol, dissipates alpha ray using acute angle after mixing and spreads out Irradiation is penetrated, the energy of the scattered alpha ray diffraction irradiation of acute angle is 50.7MeV, dosage 98.7kGy, irradiation time are 62.7 minutes, is obtained The isophthalic acid and terephthalic acids, -2 methylol -1,3- of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl changed to character The polymer and nanoscale lithium zirconate particle mixture of propylene glycol；By isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol It is placed in the polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of neopentyl glycol 2- ethyl another double In shaft type stirred reactor, starts the fuel heater in double shaft mix reactor, 61.2 DEG C of set temperature, start twin axle Blender in stirred reactor, revolving speed 53rpm, pH are adjusted to 4.7, are dehydrated 62.7 minutes, spare；

Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In 51.3 parts of -2 (or 3)-sodium sulfonate of the 5- methoxycarbonyl -5- methyl norbornane of 63mg/L, cocurrent adds to the twin shaft of step 1 In formula stirred reactor, flow acceleration 198mL/min；Start double shaft mix and react mechanical stirrer, setting speed is 67rpm；Stirring 4 minutes；50.7 parts of 2 methyl valeric acid butyl ester are added, the fuel Heating in double shaft mix reactor is started Device is warming up to 97.6 DEG C, and pH is adjusted to 4.6, and being passed through nitrogen ventilatory capacity is 52.956m³/ min, heat preservation stand 87.5 minutes；Again Secondary starting double shaft mix reacts mechanical stirrer, and formaldehyde and chloromethyloxirane and 4,4'- (1- first is added in revolving speed 62rpm Base ethylidene) biphenol polymer and 59.2 parts of polymer of reaction product of N- butyl butylamine and diethanol amine, and make PH is adjusted to 4.6, and heat preservation stands 86.3 minutes；

Step 5: the blender in starting double shaft mix reactor, setting speed 59rpm start double shaft mix reactor In fuel heater, set temperature in double shaft mix reactor as 1.696 × 10²DEG C, 4- (nine fluoro fourth oxygen are added Base) 69.7 parts of -1- fourth sulfonic acid ammonium salt, reacts 53.2 minutes；The alpha-brominated n-caproic acid that mass concentration is 59mg/L is added later 92.6 parts, start the fuel heater in double shaft mix reactor, sets temperature in double shaft mix reactor as 137.2 DEG C, pH is adjusted to 4.6, and pressure 0.59MPa, the reaction time is 0.4 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to 53.2 DEG C discharge into molding press to get to filtered fluid plate 3-6；The partial size of the nanoscale lithium zirconate particle is 67 μm.

Embodiment 2

Step 1: in double shaft mix reactor, 493.0 parts of pure water and 3- methyl -4- (2,6,6- trimethyl -1- are added Base) 102.7 parts of-3- butene-2 -one, start the blender in double shaft mix reactor, setting speed 107rpm, starting pair Fuel heater in shaft type stirred reactor makes temperature rise to 77.0 DEG C, and the [[3- (trimethoxy of 1- methoxyl group -3,7- bis- is added Silicon substrate) the third oxygen] methyl] 172.2 parts of poly- (silicomethane) of sealing end stir evenly, carry out reaction 64.7 minutes, ethylene methacrylic is added 76.0 parts of base dichlorosilane, being passed through flow is 93.0m³The nitrogen of/min 64.7 minutes；Later in double shaft mix reactor 119.1 parts of collagen powder are added, the fuel heater being again started up in double shaft mix reactor makes temperature rise to 126.2 DEG C, protects 126.5 parts of four hydrogen-based phthalic anhydride of methyl is added in temperature 64.0 minutes, adjusts the pH value of solution in double shaft mix reactor It is 8.1, keeps the temperature 293.6 minutes；

Step 2: separately taking 122.6 parts of nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is ultrasonic in the case where power is 11.37KW After wave is handled 1.126 hours；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, it is dense that quality is added Degree is the polypropylene of 293mg/L and 102.8 parts of dispersion nanoscale lithium zirconates of reaction product of dimethyl methyl vinyl silicone Particle starts the fuel heater in double shaft mix reactor, makes solution temperature between 84 DEG C, and starting double shaft mix is anti- The blender in device is answered, and with 8 × 10²The speed of rpm stirs, and adjusts pH value 8.9, insulated and stirred 126 minutes；Stop later Reaction stands 11.37 × 10 minutes, removes impurity；Suspension is added to the polymer of formaldehyde and 1,3- benzene dimethylamine and phenol 102.6 parts, adjustment pH value forms the pure water elution of sediment, by centrifuge in revolving speed 9.102 × 10 2.9³Under rpm Solid content is obtained, 3.279 × 10²It is dry at a temperature of DEG C, 1.102 × 10 are crossed after grinding³Mesh, it is spare；

Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after 85.0 parts of the polymer of 3-propanediol and step 2 processing, dissipates alpha ray using acute angle after mixing Diffraction irradiation, the energy of the scattered alpha ray diffraction irradiation of acute angle is 78.2MeV, dosage 138.2kGy, irradiation time are 87.2 points Clock obtains the isophthalic acid and terephthalic acids, -2 hydroxyl first of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl of character change The polymer and nanoscale lithium zirconate particle mixture of base -1,3- propylene glycol；By isophthalic acid and terephthalic acids, adipic acid, 1, The polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of 2- ethylene glycol and neopentyl glycol 2- ethyl are set In another double shaft mix reactor, start double shaft mix reactor in fuel heater, 107.5 DEG C of set temperature, Start the blender in double shaft mix reactor, revolving speed 448rpm, pH are adjusted to 8.0, are dehydrated 76.0 minutes, spare；

Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In 87.9 parts of -2 (or 3)-sodium sulfonate of the 5- methoxycarbonyl -5- methyl norbornane of 293mg/L, cocurrent adds to the double of step 1 In shaft type stirred reactor, flow acceleration 926mL/min；Start double shaft mix and react mechanical stirrer, setting speed is 107rpm；Stirring 8 minutes；93.2 parts of 2 methyl valeric acid butyl ester are added, the fuel Heating in double shaft mix reactor is started Device is warming up to 134.3 DEG C, and pH is adjusted to 8.3, and being passed through nitrogen ventilatory capacity is 93.352m³/ min, heat preservation stand 117.0 minutes； It is again started up double shaft mix reaction mechanical stirrer, formaldehyde and chloromethyloxirane and 4,4'- are added in revolving speed 107rpm 104.5 parts of polymer of the reaction product of the polymer and N- butyl butylamine and diethanol amine of (1- methyl ethylidene) biphenol, And pH is made to be adjusted to 8.3, heat preservation stands 126.7 minutes；

Step 5: the blender in starting double shaft mix reactor, setting speed 126rpm, starting double shaft mix reaction Fuel heater in device sets temperature in double shaft mix reactor as 2.675 × 10²DEG C, 4- (nine fluoro fourth oxygen are added Base) 113.0 parts of -1- fourth sulfonic acid ammonium salt, reacts 64.2 minutes；The alpha-brominated n-caproic acid that mass concentration is 326mg/L is added later 146.3 parts, start the fuel heater in double shaft mix reactor, set temperature in double shaft mix reactor as 193.0 DEG C, pH is adjusted to 8.6, and pressure 0.6MPa, the reaction time is 0.9 hour；Being depressurized to gauge pressure later is 0MPa, cooling It discharges into molding press to 64.2 DEG C to get to filtered fluid plate 3-6；The partial size of the nanoscale lithium zirconate particle is 77 μm.

Embodiment 3

Step 1: in double shaft mix reactor, 268.9 parts of pure water and 3- methyl -4- (2,6,6- trimethyl -1- are added Base) 60.9 parts of-3- butene-2 -one, start the blender in double shaft mix reactor, setting speed 61rpm starts twin shaft Fuel heater in formula stirred reactor makes temperature rise to 76.9 DEG C, and [[3- (the trimethoxy silicon of 1- methoxyl group -3,7- bis- is added Base) the third oxygen] methyl] 63.9 parts of poly- (silicomethane) of sealing end stir evenly, carry out reaction 53.9 minutes, methyl ethylene two is added 59.9 parts of chlorosilane, being passed through flow is 52.9m³The nitrogen of/min 53.9 minutes；It is added in double shaft mix reactor later 62.9 parts of collagen powder, the fuel heater being again started up in double shaft mix reactor makes temperature rise to 93.9 DEG C, heat preservation 53.9 Minute, 65.9 parts of four hydrogen-based phthalic anhydride of methyl is added, the pH value for adjusting solution in double shaft mix reactor is 4.9, Heat preservation 53.9 minutes；

Step 2: separately taking 67.9 parts of nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is ultrasonic in the case where power is 5.939KW After wave is handled 0.599 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, it is dense that quality is added Degree is the polypropylene of 63.9mg/L and 60.9 parts of dispersion nanoscale lithium zirconates of reaction product of dimethyl methyl vinyl silicone Particle starts the fuel heater in double shaft mix reactor, makes solution temperature at 46.9 DEG C, starting double shaft mix reaction Blender in device, and with 4.9 × 10²The speed of rpm stirs, and adjusts pH value 4.9, insulated and stirred 59.9 minutes；Stop later Only reaction stands 5.93 × 10 minutes, removes impurity；Suspension is added to the polymer of formaldehyde and 1,3- benzene dimethylamine and phenol 62.9 parts, adjustment pH value forms the pure water elution of sediment, by centrifuge in revolving speed 4.338 × 10 1.9³Under rpm To solid content, 2.117 × 10²It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding³Mesh, it is spare；

Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after polymer 62.9 and the step 2 processing of 3-propanediol, dissipates alpha ray using acute angle after mixing and spreads out Irradiation is penetrated, the energy of the scattered alpha ray diffraction irradiation of acute angle is 50.9MeV, dosage 98.9kGy, irradiation time are 62.9 minutes, is obtained The isophthalic acid and terephthalic acids, -2 methylol -1,3- of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl changed to character The polymer and nanoscale lithium zirconate particle mixture of propylene glycol；By isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol It is placed in the polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of neopentyl glycol 2- ethyl another double In shaft type stirred reactor, starts the fuel heater in double shaft mix reactor, 61.9 DEG C of set temperature, start twin axle Blender in stirred reactor, revolving speed 53rpm, pH are adjusted to 4.9, are dehydrated 62.9 minutes, spare；

Step 4: the isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 that the character that step 3 is obtained changes - 2 methylols of alcohol 2- ethyl -1,3-PD polymer and nanoscale lithium zirconate particle mixture, adding to mass concentration is In 51.9 parts of -2 (or 3)-sodium sulfonate of the 5- methoxycarbonyl -5- methyl norbornane of 63.9mg/L, cocurrent adds to the double of step 1 In shaft type stirred reactor, flow acceleration 198.9mL/min；Start double shaft mix and react mechanical stirrer, setting speed is 67rpm；Stirring 4.9 minutes；50.9 parts of 2 methyl valeric acid butyl ester are added, the fuel Heating in double shaft mix reactor is started Device is warming up to 97.9 DEG C, and pH is adjusted to 4.9, and being passed through nitrogen ventilatory capacity is 52.9m³/ min, heat preservation stand 87.9 minutes；Again Start double shaft mix and react mechanical stirrer, formaldehyde and chloromethyloxirane and 4,4'- (1- methyl is added in revolving speed 62rpm Ethylidene) biphenol polymer and 59.9 parts of polymer of reaction product of N- butyl butylamine and diethanol amine, and make pH 4.9 are adjusted to, heat preservation stands 86.9 minutes；

Step 5: the blender in starting double shaft mix reactor, setting speed 59rpm start double shaft mix reactor In fuel heater, set temperature in double shaft mix reactor as 1.696 × 10²DEG C, 4- (nine fluoro fourth oxygen are added Base) 69.9 parts of -1- fourth sulfonic acid ammonium salt, reacts 53.9 minutes；The alpha-brominated n-caproic acid that mass concentration is 59mg/L is added later 92.6 parts, start the fuel heater in double shaft mix reactor, sets temperature in double shaft mix reactor as 137.9 DEG C, pH is adjusted to 4.9, and pressure 0.59MPa, the reaction time is 0.41 hour；Being depressurized to gauge pressure later is 0MPa, is cooled to 53.9 DEG C discharge into molding press to get to filtered fluid plate 3-6；The partial size of the nanoscale lithium zirconate particle is 67 μm.

Reference examples

Reference examples use the component same as the application filtered fluid plate 3-6 of certain commercially available brand, are tested for the property test.

Embodiment 4

The filtered fluid plate 3-6 and reference examples of Examples 1 to 3 same component obtained are tested for the property test, test knot The parameters such as impact resistance enhancing rate, compression strength enhancing rate, anti-yield strength enhancing rate, anticorrosive enhancing rate are carried out after beam Analysis.Data analysis is as shown in table 1.

As seen from Table 1, filtered fluid plate 3-6 of the present invention, obviously higher than the prior art in Specifications The product of production.

Find out in addition, being changed over time in figure from heretofore described filtered fluid plate 3-6 test parameters, Examples 1 to 3 In Specifications, substantially better than the product of prior art production.

Claims

1. a kind of concrete mixing plant wastewater recycling device, which is characterized in that reclamation set (16) includes: electric and magnetic oscillation stick (16- 1), current stabilization wing plate (16-2), macromolecule current stabilization sieve (16-3), polymeric aluminum dispersion pipe (16-4), flocculation deposition apparatus shell (16-5), middle storage tank (16-6), middle storage tank water pump (16-7), water discharge spout (16-8) after processing；

The flocculation deposition apparatus shell (16-5) is internal, most top position is equipped with polymeric aluminum dispersion pipe (16-4), polymeric aluminum dispersion Manage (16-4) rectangular ring structure, quantity be 2, it is arranged in parallel, the polymeric aluminum dispersion pipe surface (16-4) be equipped with spray head, spray head Direction is downward, and polymeric aluminum dispersion pipe one end (16-4) is connected to by middle storage tank water pump (16-7) with external middle storage tank (16-6), Middle storage tank (16-6) storage polymerization aluminum solutions；It is equipped with macromolecule current stabilization sieve (16-3) in the polymeric aluminum dispersion pipe lower part (16-4), Its mesh aperture 5mm~16mm, macromolecule current stabilization sieve (16-3) quantity are 10, on multiple macromolecule current stabilization sieves (16-3) Lower superposition layout；It is equipped with current stabilization wing plate (16-2) in the macromolecule current stabilization sieve lower part (16-3), " Z " word is presented in vertical cross section Shape, the quantity of current stabilization wing plate (16-2) are 10, and multiple current stabilization wing plates (16-2) are horizontally arranged, adjacent current stabilization wing plate (16-2) it Between at a distance of 2cm~6cm, multiple current stabilization wing plates (16-2) connects by cranking arm with external motor, external motor driving current stabilization wing plate (16-2) horizontal concussion；It is equipped with electric and magnetic oscillation stick (16-1) in the current stabilization wing plate lower part (16-2), electric and magnetic oscillation stick (16-1) quantity Be 20, multiple electric and magnetic oscillation stick (16-1) levels equidistantly distribute, between adjacent electric and magnetic oscillation stick (16-1) at a distance of 10cm~ 60cm, electric and magnetic oscillation stick (16-1) are connect by conducting wire with control system (15)；Flocculation deposition apparatus shell (16-5) side Cone design, open topped, lower part closing；Water discharge spout (16-8) is located at flocculation deposition apparatus shell (16-5) after the processing Middle part；Sediment is connected to from bottom pipe with pulverizer (2)；

The reclamation set (16) is located inside concrete mixing plant waste water treatment system.

2. a kind of concrete mixing plant wastewater recycling device according to claim 1, which is characterized in that concrete mixing plant Waste water treatment system includes: main water inlet tube (1), pulverizer (2), anaerobic fermentation tank (3), feed pipe (4), methane riser (5), Aerobic fermentation tank (6), bed mud discharge outlet (7), percolate branch pipe (8), oxygen hose (9), aerobic fermentation tank inlet tube (10), reuse Device drainpipe (11), slag notch (12), advanced oxidation pond (13), primary flow pipe (14), control system (15), reclamation set (16)；

The main water inlet tube (1), primary flow pipe (14) horizontal layout, main water inlet tube (1), primary flow pipe (14) diameter be 20cm~ 30cm, it is made of high molecular material, main water inlet tube (1), primary flow pipe (14) are respectively at anaerobic fermentation tank (3), aerobic fermentation tank (6), advanced oxidation pond (13) are connected to；Pulverizer (2), main water inlet tube (1) and pulverizer are equipped in main water inlet tube (1) upper right (2) it is connected to by percolate branch pipe (8)；Pulverizer (2) side is equipped with anaerobic fermentation tank (3), and anaerobic fermentation tank (3) top is equipped with Methane riser (5), anaerobic fermentation tank (3) lower part are equipped with slag notch (12), and anaerobic fermentation tank (3) is with pulverizer (2) by sending Expects pipe (4) connection；Percolate branch pipe (8), percolate branch pipe (8) and main water inlet tube are equipped in feed pipe (4) vertical portion lower part (1) it is connected to；The aerobic fermentation tank (6) is located at anaerobic fermentation tank (3) side, aerobic fermentation tank (6) by aerobic fermentation tank into Liquid pipe (10) is connected to main water inlet tube (1)；Aerobic fermentation tank inlet tube (10) vertical portion top is equipped with methane riser (5), Aerobic fermentation tank (6) lower part is equipped with reclamation set drainpipe (11), and reclamation set drainpipe (11) top is equipped with reclamation set (16), reclamation set (16) is connected to by reclamation set drainpipe (11) with primary flow pipe (14)；Under aerobic fermentation tank (6) side Portion is equipped with bed mud discharge outlet (7)；The advanced oxidation pond (13) is located on the left of aerobic fermentation tank (6), and advanced oxidation pond (13) are logical It crosses main water inlet tube (1) and accepts the percolate for coming from anaerobic fermentation tank (3)；Aerobic fermentation tank (6) by main water inlet tube (1) accept come From advanced oxidation pond (13) treatment fluid；Control system (15) is located at anaerobic fermentation tank (3) side.

3. a kind of concrete mixing plant wastewater recycling device according to claim 2, which is characterized in that the pulverizer (2) include: powder push plate (2-1), powder push rod (2-2), under adjustable sieve plate (2-3), crushing knife (2-4), crushing bin (2-5), Lower hopper (2-6), upper adjustable sieve plate (2-7), powder channel (2-8), sieve plate adjuster (2-9), percolate storehouse (2-10)；

Superposed lower hopper (2-6), its underpart are equipped with crushing bin (2-5), and crushing bin (2-5) and lower hopper (2-6) are penetrated through； It is equipped with crushing knife (2-4) inside crushing bin (2-5), crushing knife (2-4) quantity is 2, and arranged opposite；Under crushing knife (2-4) Portion is equipped with upper adjustable sieve plate (2-7), and the upper adjustable sieve plate surface (2-7) is equipped with a large amount of through-holes, upper adjustable sieve plate (2-7) horizontal sextant angle 15~60 degree；Upper adjustable sieve plate (2-7) lower part is equipped with down adjustable sieve plate (2-3), upper adjustable sieve plate (2-7) adjustable sieve plate under The slit at a distance of 20cm~50cm is formed between (2-3), comminuting matter falls on down the surface adjustable sieve plate (2-3) under this slit, Under the adjustable sieve plate surface (2-3) be equipped with a large amount of through-holes, 15~60 degree of angle with horizontal plane；Under set on the left of adjustable sieve plate (2-3) There is powder channel (2-8), comminuting matter continues to fall from powder channel (2-8)；The sieve plate adjuster (2-9) and upper adjustable sieve Plate (2-7), under adjustable sieve plate (2-3) mechanical connection, sieve plate adjuster (2-9) to upper adjustable sieve plate (2-7), under adjustable sieve plate (2-3) realizes that adjustable angle, plate spacing is adjustable；Under the adjustable sieve plate lower part (2-3) be equipped with powder push plate (2-1), powder push plate (2- 1) side is equipped with powder push rod (2-2), and powder push plate (2-1) and powder push rod (2-2) are mechanically connected；Percolate storehouse (the 2- 10) it is located at the lower part crushing bin (2-5), is penetrated through with crushing bin (2-5), the percolate storehouse bottom (2-10) is equipped with percolate branch pipe (8)。

4. a kind of concrete mixing plant wastewater recycling device according to claim 3, which is characterized in that the anaerobic fermentation Tank (3) includes: stirring motor (3-1), agitator arm (3-2), collector mat (3-3), cleaning pipe (3-4), fresh water pump (3-5), mistake Filtrate plate (3-6), medicament mixing device (3-7)；

Stirring motor (3-1) outside side is connect by transmission device with internal agitator arm (3-2)；Paddle It takes turns (3-2) and anaerobic fermentation tank (3) is contour, stirring motor (3-1) drives agitator arm (3-2) rotation；At agitator arm (3-2) Waist is equipped with collector mat (3-3), and collector mat (3-3) is connect with external power supply, and collector mat (3-3) provides heat for anaerobic fermentation； It is equipped with filtered fluid plate (3-6) in the agitator arm lower part (3-2), filtered fluid plate (3-6), which is realized, to be separated by solid-liquid separation；The medicament mixing dress Set the top that (3-7) is located at feed pipe (4) and methane riser (5) side, agitator arm (3-2).

5. a kind of concrete mixing plant wastewater recycling device according to claim 4, which is characterized in that the medicament mixing Device (3-7) includes: confection delivery pipe (3-7-1), steam injection pipe (3-7-2), and cellular reactor (3-7-3) adds Add agent filler pipe (3-7-4), medicament injection pipe (3-7-5), sluicing pipe (3-7-6), temperature sensor (3-7-7), equipment base (3-7-8)；

Sluicing pipe (3-7-6) positioned at top, one end are connect with external water pump, the other end and medicament mixing device (3-7) Internal lotus spray-head connection, lotus spray-head lower part are equipped with cellular reactor (3-7-3), and lotus spray-head is to the cellular of lower part Reactor (3-7-3) implements cleaning；Cellular reactor (3-7-3) section is honeycomb, by more honeycomb standpipes It is vertically arranged composition, cellular reactor (3-7-3) is up and down；Additive filler pipe is equipped in the sluicing pipe side (3-7-6) (3-7-4), medicament injection pipe (3-7-5)；It is equipped with temperature sensor (3-7-7) in the middle part of medicament mixing device (3-7), is passed through Conducting wire is connect with control system (15)；It is equipped with steam injection pipe (3-7-2) in the cellular reactor lower part (3-7-3), steam spray Pipe (3-7-2) annular shape is penetrated, upper surface is equipped with a large amount of through-holes, and steam injection pipe one end (3-7-2) and external steam pipeline connect Logical, steam injection pipe (3-7-2) promotes medicament reaction to the cellular reactor (3-7-3) on top injection high-temperature steam；In medicine The agent mixing arrangement bottom (3-7) is equipped with confection delivery pipe (3-7-1)；Medicament, additive are respectively from medicament injection pipe (3-7- 5), medicament injection pipe (3-7-5) is filled into medicament mixing device (3-7), the sprayed high-temperature steam of steam injection pipe (3-7-2) Promote medicament in cellular reactor (3-7-3) internal-response, after be discharged from confection delivery pipe (3-7-1).

6. a kind of concrete mixing plant wastewater recycling device according to claim 5, which is characterized in that the advanced oxidation Pond (13) includes: oxidation pond water inlet pipe (13-1), and oxidation-reduction potential instrument (13-2) aoxidizes outlet pipe (13-3), lye inlet pipe (13-4), oxidant feed pipe (13-5), acid solution inlet pipe (13-6)；

Oxidation pond water inlet pipe (13-1) positioned at advanced oxidation pond (13) side, is connected to, and pass through main water inlet with main water inlet tube (1) Pipe (1) is connected to anaerobic fermentation tank (3)；The oxidation pond water inlet pipe top (13-1) is equipped with acid solution inlet pipe (13-6), the two connection；Position Oxidation outlet pipe (13-3) in advanced oxidation pond (13) other side, is connected to main water inlet tube (1), aoxidizes outlet pipe (13-3) It is connected to by main water inlet tube (1) with aerobic fermentation tank (6)；It aoxidizes the outlet pipe top (13-3) and is equipped with lye inlet pipe (13-4), two Person's connection；Advanced oxidation pond (13) top is equipped with oxidant feed pipe (13-5), the two connection；Oxidation-reduction potential instrument (13-2) It is connect with control system (15) polygon control survey.

7. a kind of concrete mixing plant wastewater recycling device according to claim 6, which is characterized in that the aerobic fermentation Tank (6) includes: heating rod (6-1), air injection tube (6-2), steadying plate (6-3), bed mud warehouse lid (6-4), clear water drain valve (6- 5), aerobic fermentation drainpipe (6-6)；

Heating rod (6-1) positioned at top, connects to power supply, and connect with control system (15) polygon control survey；In heating rod The lower part (6-1) is equipped with air injection tube (6-2), and the air injection tube surface (6-2) is equipped with a large amount of through-holes, air injection tube (6-2) Quantity is 10, is mutually equally spaced, and air injection tube (6-2) pipe range is 20cm~86cm, diameter 20cm, air injection tube The one end (6-2) is connected to oxygen hose (9)；It is equipped with steadying plate (6-3) in the air injection tube lower part (6-2), steadying plate (6-3) is horizontal It is arranged and equal with aerobic fermentation tank (6) cross-sectional sizes, the steadying plate surface (6-3) is equipped with a large amount of through-holes；At steadying plate (6-3) Lower part is equipped with clear water drain valve (6-5), and clear water drain valve (6-5) and aerobic fermentation drainpipe (6-6) are penetrated through, wherein aerobic fermentation The upper end drainpipe (6-6) is deep into the top steadying plate (6-3)；Bed mud warehouse lid (6-4) is equipped in the clear water drain valve side (6-5).

8. a kind of concrete mixing plant wastewater recycling device according to claim 7, which is characterized in that the filtered fluid plate (3-6) is formed by high molecular material pressing mold, and the constituent of filtered fluid plate (3-6) is as follows:

268.5~493.0 parts of pure water according to parts by weight, 3- methyl-4- (2,6,6- trimethyl-1- base)-3- butene-2 -one 60.3~102.7 parts, poly- (silicomethane) 63.2 that 1- methoxyl group -3,7- bis- [[3- (front three oxygen silicon base) the third oxygen] methyl] blocks~ 172.2 parts, 59.2~76.0 parts of methylvinyldichlorosilane, 62.6~119.1 parts of collagen powder, four hydrogen-based O-phthalic of methyl 65.2~126.5 parts of acid anhydrides, 67.0~122.6 parts of nanoscale lithium zirconate particle, polypropylene and dimethyl methyl ethylene silicon oxygen 62.9~102.6 parts of the polymer of 60.8~102.8 parts of the reaction product of alkane, formaldehyde and 1,3- benzene dimethylamine and phenol, isophthalic The polymer of diacid and terephthalic acids, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl 62.4~85.0 parts, 51.3~87.9 parts of -2 (or 3)-sodium sulfonate of 5- methoxycarbonyl -5- methyl norbornane, 2 methyl valeric acid 50.7~93.2 parts of butyl ester, formaldehyde and chloromethyloxirane and 4, the polymer and N- of 4'- (1- methyl ethylidene) biphenol 59.2~104.5 parts of the polymer of the reaction product of butyl butylamine and diethanol amine, 4- (nine fluoro butoxy) -1- fourth ichthyodin 69.7~113.0 parts of salt, mass concentration is 92.6~146.3 parts of alpha-brominated n-caproic acid of 59mg/L~326mg/L.

9. a kind of concrete mixing plant wastewater recycling device according to claim 8, which is characterized in that filtered fluid plate (3- 6) manufacturing process comprising the steps of:

Step 2: separately taking nanoscale lithium zirconate particle, and nanoscale lithium zirconate particle is surpassed in the case where power is 5.93KW~11.37KW After sonicated 0.59~1.126 hour；Nanoscale lithium zirconate particle is added in another double shaft mix reactor, is added The reaction product for entering polypropylene and dimethyl methyl vinyl silicone that mass concentration is 63mg/L~293mg/L disperses nanometer Grade lithium zirconate particle, starts the fuel heater in double shaft mix reactor, makes solution temperature between 46 DEG C~84 DEG C, open Blender in dynamic double shaft mix reactor, and with 4 × 10²Rpm~8 × 10²The speed of rpm stirs, and adjusts pH value 4.3 Between~8.9, insulated and stirred 59~126 minutes；Stop reaction later and stand 5.93 × 10~11.37 × 10 minutes, goes to clean Matter；Formaldehyde and 1 is added in suspension, the polymer of 3- benzene dimethylamine and phenol adjusts pH value between 1.3~2.9, and it is heavy to be formed The pure water elution of starch, by centrifuge in revolving speed 4.338 × 10³Rpm~9.102 × 10³Solid content is obtained under rpm, 2.117×10²DEG C~3.279 × 10²It is dry at a temperature of DEG C, 0.338 × 10 is crossed after grinding³~1.102 × 10³Mesh, it is spare；

Step 3: separately taking isophthalic acid and terephthalic acids, -2 methylol -1 of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl, Nanoscale lithium zirconate particle after polymer and the step 2 processing of 3-propanediol, dissipates alpha ray diffraction spoke using acute angle after mixing According to when the energy of the scattered alpha ray diffraction irradiation of acute angle is 50.7MeV~78.2MeV, dosage is 98.7kGy~138.2kGy, irradiates Between be 62.7~87.2 minutes, obtain character change isophthalic acid and terephthalic acids, adipic acid, 1,2- ethylene glycol and new penta 2 The polymer and nanoscale lithium zirconate particle mixture of -2 methylol -1,3- propylene glycol of alcohol 2- ethyl；By isophthalic acid and to benzene The polymer and nanoscale zirconic acid of diacid, -2 methylol -1,3- propylene glycol of adipic acid, 1,2- ethylene glycol and neopentyl glycol 2- ethyl Lithium particle mixture is placed in another double shaft mix reactor, starts the fuel heater in double shaft mix reactor, if Determine 61.2 DEG C~107.5 DEG C of temperature, start the blender in double shaft mix reactor, revolving speed is 53rpm~448rpm, pH tune It is whole to be dehydrated 62.7~76.0 minutes between 4.7~8.0, it is spare；

Step 5: the blender in starting double shaft mix reactor, setting speed are 59rpm~126rpm, and starting twin axle stirs The fuel heater in reactor is mixed, sets temperature in double shaft mix reactor as 1.696 × 10²DEG C~2.675 × 10² DEG C, 4- (nine fluoro butoxy) -1- fourth sulfonic acid ammonium salt is added, reacts 53.2~64.2 minutes；Alpha-brominated n-caproic acid is added later, Start the fuel heater in double shaft mix reactor, set temperature in double shaft mix reactor as 137.2 DEG C~ 193.0 DEG C, pH is adjusted between 4.6~8.6, and pressure is 0.59MPa~0.6MPa, and the reaction time is 0.4~0.9 hour；It After to be depressurized to gauge pressure be 0MPa, be cooled to 53.2 DEG C~64.2 DEG C and discharge into molding press to get to filtered fluid plate (3-6)；

The partial size of the nanoscale lithium zirconate particle is 67 μm~77 μm.

10. a kind of concrete mixing plant wastewater recycling device according to claim 9, which is characterized in that device work Method including the following steps:

Step 1: in medicament mixing device (3-7), system starting, the medicament that confection delivery pipe (3-7-1) releases, with steaming The steam mixing that vapour injection pipe (3-7-2) generates, realizes heat effect, under cellular reactor (3-7-3) facilitation, with The additive reaction that additive filler pipe (3-7-4) is added realizes the maximization of medicament function, ultimately joins anaerobic fermentation In tank (3) tank body；The sediment of generation is transported to pulverizer (2) as material；

Step 2: in pulverizer (2), powering on, from medicament mixing device (3-7), reclamation set (16) precipitating material under Hopper (2-6) enters crushing bin (2-5), the crushing material under crushing knife (2-4) dissection, and smashed material is by above may be used Adjustable sieve plate (2-3) under entering after adjusting sieve plate (2-7) to be dehydrated, under after adjustable sieve plate (2-3) dehydration, dry material passes through powder Material channel (2-8) falls into warehouse where powder push plate (2-1), and powder push rod (2-2) pushes powder push plate (2-1) to send dry material Enter feed pipe (4)；Crush the percolate generated respectively from upper adjustable sieve plate (2-7) through-hole, under adjustable sieve plate (2-3) through-hole enter Percolate storehouse (2-10), and enter main water inlet tube (1) from percolate branch pipe (8)；

Step 3: in anaerobic fermentation tank (3), enter anaerobic fermentation by feed pipe (4) from pulverizer (2) smashed material Tank (3) top carries out anaerobic fermentation, the first of generation under the stirring of agitator arm (3-2) and the heat effect of collector mat (3-3) Alkane gas is discharged from methane riser (5), and the percolate of generation enters the main water inlet tube of lower part (1)；When equipment is cleaned, Fresh water pump (3-5) starting will be implemented to clean inside equipment by cleaning pipe (3-4) clear water；

Step 4: in advanced oxidation pond (13), the percolate from anaerobic fermentation tank (3) by oxidation pond water inlet pipe (13-1) into Enter advanced oxidation pond (13), in advance under the dilute sulfuric acid effect in acid solution inlet pipe (13-6), solution ph is brought to 3~4；With this Meanwhile solution is aoxidized from oxidant feed pipe (13-5) ferrous iron entered and hydrogen peroxide, sediment is from advanced oxidation Pond (13) base sludge delivery pipe outlet when treated solution is flowed out from oxidation outlet pipe (13-3), and comes from lye inlet pipe The reaction of (13-4) sodium hydroxide flows into main water inlet tube (1) so that the pH value of solution is increased to 6~8, and then enters aerobic fermentation Tank (6)；Oxidation-reduction potential instrument (13-2) monitors the oxidation process of advanced oxidation pond (13) in real time, and feeds back to control system (15) degree of oxidation control is carried out；

Step 5: in aerobic fermentation tank (6), coming from advanced oxidation pond (13) treatment fluid, same with this into aerobic fermentation tank (6) When, air injection tube (6-2) sprays bubble to solution, increases solution dissolved oxygen, and heating rod (6-1) is controlled in control system (15) Under solution is implemented to heat, the sludge of generation is discharged from bed mud discharge outlet (7)；

Step 6: in reclamation set (16), the pending water of aerobic fermentation drainpipe (6-6) is come from, from flocculation deposition apparatus shell The top (16-5) enters, and meets with polymeric aluminum dispersion pipe (16-4) polymeric aluminum sprayed, and in macromolecule current stabilization sieve (16-3) It is formed under buffer function, falls into the lower part flocculation deposition apparatus shell (16-5)；Make at this time in the horizontal concussion of current stabilization wing plate (16-2) Under, accelerate flocculation reaction under the action of the concussion of electric and magnetic oscillation stick (16-1) circumference, when current stabilization wing plate (16-2), electric and magnetic oscillation When stick (16-1) stops working, organic matter flocculation precipitating is simultaneously discharged from the sludge pipe of bottom, and clear water is arranged from water after the processing at middle part It puts pipe (16-8) and is discharged to primary flow pipe (14) discharge.