CN108982145A - A kind of vehicular unified platform collecting soil collection, detection, improvement - Google Patents
A kind of vehicular unified platform collecting soil collection, detection, improvement Download PDFInfo
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- CN108982145A CN108982145A CN201810586197.XA CN201810586197A CN108982145A CN 108982145 A CN108982145 A CN 108982145A CN 201810586197 A CN201810586197 A CN 201810586197A CN 108982145 A CN108982145 A CN 108982145A
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- 239000002689 soil Substances 0.000 title claims abstract description 53
- 238000001514 detection method Methods 0.000 title claims abstract description 27
- 230000006872 improvement Effects 0.000 title claims abstract description 27
- 239000002680 soil gas Substances 0.000 claims abstract description 37
- 238000002203 pretreatment Methods 0.000 claims abstract description 14
- 238000005070 sampling Methods 0.000 claims abstract description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005527 soil sampling Methods 0.000 claims abstract description 8
- 238000005067 remediation Methods 0.000 claims abstract description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 5
- 239000000969 carrier Substances 0.000 claims abstract description 4
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 claims abstract 7
- 238000005553 drilling Methods 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 239000010720 hydraulic oil Substances 0.000 claims description 8
- 239000000523 sample Substances 0.000 description 15
- 238000003900 soil pollution Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000013459 approach Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- ZBJWWKFMHOAPNS-UHFFFAOYSA-N loretin Chemical compound C1=CN=C2C(O)=C(I)C=C(S(O)(=O)=O)C2=C1 ZBJWWKFMHOAPNS-UHFFFAOYSA-N 0.000 description 1
- 229950010248 loretin Drugs 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000002414 normal-phase solid-phase extraction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/04—Devices for withdrawing samples in the solid state, e.g. by cutting
- G01N1/08—Devices for withdrawing samples in the solid state, e.g. by cutting involving an extracting tool, e.g. core bit
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
- G01N23/22—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material
- G01N23/223—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by irradiating the sample with X-rays or gamma-rays and by measuring X-ray fluorescence
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N2030/022—Column chromatography characterised by the kind of separation mechanism
- G01N2030/025—Gas chromatography
Abstract
The present invention provides a kind of collection soil collections, detection, the vehicular unified platform of improvement, including vehicle, it is described interior equipped with power device and portable drill, vehicle provides power to portable drill by power device, the soil sampling drill for soil sample used for portable drill is also equipped on the vehicle, drill bit is injected for the SOIL GAS chisel bit of SOIL GAS sampling and for soil remediation and the biliquid of improvement, the car is additionally provided with the XRF pedotheque pretreating device that pre-treatment is carried out to pedotheque, the XRF tester that sample after pre-treatment is tested, the GC-MS sample introduction pretreating device of pre-treatment is carried out to SOIL GAS, the GC-MS tester that SOIL GAS after pre-treatment is tested, current carriers nitrogen cylinder as GC-MS tester.
Description
Technical field
The present invention relates to Soil K+adsorption instrument field, especially a kind of collection soil collection, detection, the vehicular of improvement are integrated
Change platform.
Background technique
Soil is difficult regenerated resources, will be made when harmful substance contents are more than the self-purification capacity of soil itself in soil
Soil property and deterioration, lead to soil pollution.Simultaneously center of the soil as land system, not only in own system into
Row energy and substance circulation, while mass exchange is also constantly carried out between water, atmosphere and organism, once it pollutes, it is whole
A ecosystem can all be destroyed, the final health for damaging people.Since soil self purification activity is slow and extremely limited, soil is dirty
The features such as there is concealment, cumulative bad and irreversibilities again is contaminated, therefore for timely discovery, monitoring and the improvement of soil pollution
It is very necessary.
The soil contamination problem in China is extremely serious at present, and contaminated arable land has reached 40,000,000 hectares according to statistics, soil
Pollution type multiplicity shows the old and new's pollutant and deposits, the situation of organo-mineral complexing pollution.Therefore to dirty in polluted soil
The accurate detection and improvement of dye substance propose very high requirement.Accurate testing requirements scientific can either be chosen in contaminated site
Soil, underground water simultaneously carry out systematic sampling, under the reliability for guaranteeing sampling can type and content to polluter into
Row is quantitative to be analyzed with timely accurate.According to accurate detection result and corresponding geological environment, and timely sharing dependency number
According to the improvement that each domain expert carries out adaptation to local conditions could be combined, so that soil pollution is timely and effectively controlled and administered.
The country generally acquires pedotheque, SOIL GAS using probing or installation sampled well and laboratory is sent to carry out soil at present
The conventional method of earth detection.Not only the device is complicated for this method, operation difficulty is big, the duty cycle is long, but also the soil-like acquired
Product and SOIL GAS cannot be detected timely, generally require a few days even several weeks can just be obtained in the lab as a result,
Pedotheque and SOIL GAS be by being easy to be lost after a long time placement or rotten simultaneously, largely effects on the reliability of measurement and accurate
Property.This hysteresis quality often makes soil remediation miss Best Times, especially when urgent leakage accident occurs, rapidly may be used
The sampling leaned on, analysis and pointedly administer the diffusion that could prevent to pollute.According to investigation, membrane interface detector at present
(Membrane Interface Probe, MIP) can carry out the measurement of sxemiquantitative to the volatile organic matter in soil in real time,
The range of pollution can be determined rapidly.But MIP detection limit for height, resolution ratio are low, poor anti jamming capability, and cannot detect in soil
The content of inorganic pollution can not provide soil pollution complete accurate data.Simultaneously because the complexity of soil pollution, needle
Often various aspects associated specialist will be needed in time in conjunction with live geological environment and accurate pollution condition data to the improvement of property
Shared relevant information and data, and the platform of timely sharing soil information in this way is not domestic at present also perfect.
Summary of the invention
Goal of the invention: the technical problem to be solved by the present invention is in view of the deficiencies of the prior art, provide a kind of collection soil
Acquisition, detection, the vehicular unified platform administered.
In order to solve the above-mentioned technical problems, the present invention provides a kind of collection soil collections, the vehicular one of detection, improvement
Change platform, including vehicle, described interior equipped with power device and portable drill, vehicle gives portable drill to provide by power device
Power is also equipped on the vehicle and takes for what portable drill used for the soil sampling drill of soil sample, for SOIL GAS
The SOIL GAS chisel bit of sample and drill bit is injected for soil remediation and the biliquid of improvement.
The power device includes positioned at interior gearbox and the power takeoff being connected on gearbox, power takeoff connection
Drilling machine main pump, drilling machine main pump connect hydraulic oil container, and hydraulic oil container is connected to connection frame, and connection frame connects quick connector, fast grafting
Head connection hydraulic connecting pipe, hydraulic connecting pipe connect portable drill.
The present invention, the interior XRF pedotheque pretreating device being equipped with to pedotheque progress pre-treatment.
The present invention, it is described interior equipped with the XRF tester tested the sample after pre-treatment.
The present invention, the interior GC-MS sample introduction pretreating device being equipped with to SOIL GAS progress pre-treatment.
The present invention, it is described interior equipped with the GC-MS tester tested the SOIL GAS after pre-treatment and as GC-
The current carriers nitrogen cylinder of MS tester.
The present invention, the XRF tester and GC-MS tester are all connected to computer.
The vehicle-mounted churn of a kind of acquisition pedotheque and SOIL GAS of the invention can be each using box car as carrier
Kind is switched fast between work-yard, and drilling machine is transported with the speed of vehicle, improves the efficiency and speed of sampling.
The vehicle-mounted churn of a kind of acquisition pedotheque and SOIL GAS of the invention, wherein drilling machine by inserting mode from case fastly
Formula vehicle obtains full hydraulic power resources, and drilling depth highest can reach 15m, is not necessarily to mating installation diesel engine.Rig operations
Simply, mobility strong, it is noiseless to detecting instrument in compartment in sampling.
The vehicle-mounted churn of a kind of acquisition pedotheque and SOIL GAS of the invention can be realized by more bit change to soil
Earth surface layer sample, deep layer sample.
The vehicle-mounted churn of a kind of acquisition pedotheque and SOIL GAS of the invention, can be by more bit change to SOIL GAS
Carry out in-situ acquisition.
The vehicle-mounted churn of a kind of acquisition pedotheque and SOIL GAS of the invention can inject drill bit by replacement biliquid
Timely in-situ immobilization is carried out to contaminated soil.
The detection method of a kind of vehicular detection pedotheque and SOIL GAS of the invention, is bored by replacement biliquid injection
Head, drill bit, which is squeezed into stratum, needs repair place, carries out emergency repair by the injected chemical medicament of drill bit, including to soil solids sample
Product use portable X-Ray Fluorescence spectrum (X Ray Fluorescence, XRF) analytic approach, and this method is easy to operate, the time
It is short, lose small, accuracy height.
The detection method of a kind of vehicular detection pedotheque and SOIL GAS of the invention, including to SOIL GAS using portable
Formula gas phase-chromatographic mass spectrometry (Gas Chromatography-Mass Spectrometer, GC-MS) method, by the SOIL GAS of acquisition
It is tested by headspace sampling or air seal syringe, this method is to each volatile organic component high resolution, detection
Limit low, accuracy height.
The vehicular unified platform of a kind of collection soil collection, detection, improvement of the invention, is included in the end PC and mobile terminal
The Sharing of Soil Information Data software platform of exploitation can upload the geological conditions and testing result to cloud data of contaminated soil in time
Library, comparative analysis by big data and associated specialist timely handling suggestion, can propose be directed to the improvement of contaminated soil
The solution of property.
Detailed description of the invention
The present invention is done with reference to the accompanying drawings and detailed description and is further illustrated, it is of the invention above-mentioned or
Otherwise advantage will become apparent.
Schematic diagram when Fig. 1 is the vehicle-mounted churn work of a kind of acquisition pedotheque of the invention and SOIL GAS;
Vehicular platform schematic diagram when Fig. 2 is a kind of detection pedotheque of the invention and SOIL GAS;
Label declaration in schematic diagram:
1, box car;2, power takeoff;3, drilling machine main pump;4, hydraulic oil container;5, connection frame;6, quick connector;7, hydraulic company
Adapter tube;8, portable drill;9, soil sampling drill;10, SOIL GAS chisel bit;11, biliquid injects drill bit;12, XRF soil
Sample pretreatment device;13, XRF tester;14, nitrogen cylinder;15, GC-MS sample introduction pretreating device;16, GC-MS is tested
Instrument;17, end is collected and shared to computer data.
Specific embodiment
It elaborates below in conjunction with attached drawing to the present invention.
As shown in Figure 1, Figure 2, a kind of collection soil collection of the present embodiment, detection, improvement vehicular unified platform, including compartment
Formula vehicle 1 is used as carrier;Power takeoff 2, drilling machine main pump 3 and hydraulic oil container 4 are used as power source;Connection frame 5, quick connector 6 and hydraulic
Energy transform device of the connecting tube as portable drill 7;Power takeoff 2 connects drilling machine main pump 3, and drilling machine main pump 3 connects hydraulic oil
Case 4, hydraulic oil container 4 are connected to connection frame 5, and connection frame 5 connects quick connector 6, and quick connector 6 connects hydraulic connecting pipe 7, hydraulic
Connecting tube 7 connects portable drill 8.Soil sampling drill 9 is attached to portable drill 7 and carries out soil shallow-layer, deep layer sampling;
SOIL GAS chisel bit 10 is attached to portable drill 7 and carries out SOIL GAS sampling;Biliquid injection drill bit 11 is attached to portable
Churn 7 carries out soil remediation and administers;The pedotheque that soil sampling drill 9 is obtained handles dress before XRF pedotheque
Set 12 carry out pre-treatments;Pedotheque will be obtained by XRF pedotheque pretreating device 12 to survey in XRF tester 13
Examination;Current carriers of the nitrogen cylinder 14 as GC-MS tester 16, the SOIL GAS that SOIL GAS chisel bit 10 is obtained pass through GC-
Enter GC-MS tester 16 after 15 pre-treatment of MS sample introduction pretreating device to test;By XRF tester 13 and GC-MS tester 16
The data of survey can upload to computer data and collect and share end 17, and storage arrives cloud database, it is special to share to soil investigation field
Family injects drill bit 11 by biliquid and fills chemical reagent, be connected to portable into the handling suggestion of excessive data comparison and expert
Drilling machine 7 carries out soil remediation and improvement.
In the present invention, soil sampling drill uses 2.25 inches of outer diameter of geotome bar, is taken by outer metal drill pipe and interior PVC
Sample pipe composition;The metal drill pipe and inner oil tube that SOIL GAS chisel bit is 2.25 inches of outer diameter take tracheae to form;Biliquid injection is bored
The metal drill pipe for the multichannel that head is 2.5 inches.
In the present invention, XRF pedotheque pretreating device: by soil pack, except root, the platform of smooth placement;
XRF tester: Olympus Corp's product can be selected;
GC-MS pretreating device is concentration trace object, provides measurement accuracy and sensitivity.It mainly include that solvent extracts
Take, Solid Phase Extraction, microblogging extraction etc. operating devices and platform;
GC-MS tester selects portable/vehicular gas chromatograph-mass spectrometer (GC-MS) (portable GC-MS), by gas phase color
Spectrometer and mass spectrograph, carrier gas and internal standard gas bottle, high-vacuum pump and control electronics, battery, keyboard, display and
Probe composition.Direct injected may be implemented in portable GC-MS, entirely appropriate to work at the scene.
Specifically, pesticide tank car accident has occurred on highway, the large area leakage of toxic pesticides is caused.At scene
Reason personnel can drive box car 1 and reach scene rapidly, according to the geographical location of wind direction and scene, determine sampled point.Using just
The mobility for taking churn 8 acquires SOIL GAS sample using acquisition soil sampling drill 9 rapidly, utilizes SOIL GAS chisel bit 10
Acquire SOIL GAS.The pedotheque of acquirement is directly after the XRF pedotheque pretreating device 12 on box car 1 is handled, in XRF
It is tested on tester;The SOIL GAS sample of acquirement is directly after the GC-MS sample introduction pretreating device 15 on box car 1 is handled;?
It is tested on GC-MS tester 16;The result of test can be uploaded directly into computer data and collect and share end 17.So as to fast
Speed determines the range of pollution and the depth of soil pollution.The geological condition at testing result and scene can be collected by computer data
Cloud database concurrency, which is uploaded to, with shared end 17 gives related fields expert, it is special according to the comparing result of big data and related fields
The opinion of family determines that resolution is injection nanometer ferron as emergent management mode, by ferrous sulfate medicament (FeSO4) note
Enter to the one intracavitary of biliquid injection drill bit 11, by sodium borohydride (NaBH4) it is injected into the another intracavitary of biliquid injection drill bit, pass through
Biliquid injection drill bit is squeezed into contaminated soil to be processed by portable drill 8, carries out in-situ injection improvement and rehabilitating soil.It utilizes
A kind of collection soil collection of the invention, detection, improvement vehicular unified platform can handle similar leakage in time rapidly
Accident.
The present invention provides a kind of collection soil collections, the vehicular unified platform of detection, improvement, implement the technology
There are many method and approach of scheme, the above is only a preferred embodiment of the present invention, it is noted that for the art
Those of ordinary skill for, various improvements and modifications may be made without departing from the principle of the present invention, these change
It also should be regarded as protection scope of the present invention into retouching.The available prior art of each component part being not known in the present embodiment adds
To realize.
Claims (7)
1. the vehicular unified platform of a kind of collection soil collection, detection, improvement, which is characterized in that including vehicle (1), the vehicle
Interior to be equipped with power device and portable drill (8), vehicle provides power to portable drill by power device, also matches on the vehicle
There are the soil sampling drill (9) for soil sample used for portable drill, the SOIL GAS sampling for SOIL GAS sampling
Drill bit (10) and for soil remediation and the biliquid of improvement injection drill bit (11).
2. the vehicular unified platform of a kind of collection soil collection according to claim 1, detection, improvement, feature exist
In the power device includes positioned at interior gearbox and the power takeoff (2) being connected on gearbox, and power takeoff (2) is even
It connects drilling machine main pump (3), drilling machine main pump (3) connects hydraulic oil container (4), and hydraulic oil container (4) is connected to connection frame (5), connection frame (5)
It connects quick connector (6), quick connector (6) connects hydraulic connecting pipe (7), and hydraulic connecting pipe (7) connects portable drill (8).
3. the vehicular unified platform of a kind of collection soil collection according to claim 2, detection, improvement, feature exist
In the interior XRF pedotheque pretreating device (12) being equipped with to pedotheque progress pre-treatment.
4. the vehicular unified platform of a kind of collection soil collection according to claim 3, detection, improvement, feature exist
In described interior equipped with the XRF tester (13) tested the sample after pre-treatment.
5. the vehicular unified platform of a kind of collection soil collection according to claim 4, detection, improvement, feature exist
In the interior GC-MS sample introduction pretreating device (15) being equipped with to SOIL GAS progress pre-treatment.
6. the vehicular unified platform of a kind of collection soil collection according to claim 5, detection, improvement, feature exist
In described interior equipped with the GC-MS tester (16) tested the SOIL GAS after pre-treatment and as GC-MS tester
(16) current carriers nitrogen cylinder (14).
7. the vehicular unified platform of a kind of collection soil collection according to claim 6, detection, improvement, feature exist
In the XRF tester (13) and GC-MS tester (16) are all connected to computer.
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Cited By (7)
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CN110618154A (en) * | 2019-10-25 | 2019-12-27 | 王典 | Automatic soil pollution diagnosis device |
CN111537266A (en) * | 2020-05-06 | 2020-08-14 | 生态环境部南京环境科学研究所 | Collection, breakage, freeze-drying, collection in soil pretreatment device of an organic whole |
CN112557090A (en) * | 2020-12-25 | 2021-03-26 | 徐州徐工环境技术有限公司 | Operation method for carrying out field detection by adopting polluted site detection vehicle |
CN112903858A (en) * | 2021-01-25 | 2021-06-04 | 江苏省环境科学研究院 | Quick detection device of soil organic pollutant |
CN113092513A (en) * | 2021-04-14 | 2021-07-09 | 江苏省环境科学研究院 | Rapid detection device and method for heavy metals in soil sample |
CN113238027A (en) * | 2021-05-08 | 2021-08-10 | 中国环境科学研究院 | Portable soil pollutant monitoring devices |
WO2022134384A1 (en) * | 2020-12-25 | 2022-06-30 | 徐州徐工环境技术有限公司 | Multifunctional integrated special vehicle for treating contaminated site |
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