CN108981201A - Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system - Google Patents
Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system Download PDFInfo
- Publication number
- CN108981201A CN108981201A CN201810605390.3A CN201810605390A CN108981201A CN 108981201 A CN108981201 A CN 108981201A CN 201810605390 A CN201810605390 A CN 201810605390A CN 108981201 A CN108981201 A CN 108981201A
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- China
- Prior art keywords
- endothermic reaction
- reaction device
- ammonolysis craft
- heat
- ammonia
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- 238000004146 energy storage Methods 0.000 title claims abstract description 26
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 title claims abstract description 10
- 238000010248 power generation Methods 0.000 title abstract description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 72
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 34
- 238000006243 chemical reaction Methods 0.000 claims abstract description 29
- 238000005915 ammonolysis reaction Methods 0.000 claims abstract description 28
- 230000010412 perfusion Effects 0.000 claims abstract description 21
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 17
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 14
- 238000004176 ammonification Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 2
- 229910001119 inconels 625 Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 229910002092 carbon dioxide Inorganic materials 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000001569 carbon dioxide Substances 0.000 description 5
- 238000007086 side reaction Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
- Y02E10/44—Heat exchange systems
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- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system.Supercritical CO2The amino thermochemical energy-storage system of solar heat power generation system, ammonolysis craft endothermic reaction device 3 on reflected light path including the heliostat field 1 that reflected sunlight is arranged in, ammonolysis craft endothermic reaction device 3 and First Heat Exchanger 4 are erected on collection thermal tower 2, and ammonolysis craft endothermic reaction device 3, First Heat Exchanger 4 are sequentially connected between Pressure of Ambient Temperature holding vessel 7 with the first appendix 5 and the first perfusion tube 6；Pressure of Ambient Temperature holding vessel 7, the second heat exchanger 10, synthesis ammonia exothermic reactor 11 between be sequentially connected with the second appendix 8 and the second perfusion tube 9；It synthesizes and is equipped between ammonia exothermic reactor 11 and power plant 12 with supercritical CO2For the heat-exchange circulating device of working medium.
Description
Technical field
The present invention relates to a kind of heat chemistry energy storage reactors.
Background technique
Solar light-heat power-generation station owner will use sensible heat energy-storage system, low, cost that there is energy storage densities in the world at present
The problems such as high and low temperature solidification, pyrolytic and corrosion.Heat chemistry energy storage carries out heat absorption and heat release by reversible thermal chemical reaction
Cyclic process, energy density is high, energy loss is few and storage temperature is low.Heat chemistry energy-storage system (amino thermochemical based on ammonia
Energy-storage system) because it is without side reaction, it can store at normal temperature, be considered one of the system of most application prospect.
Summary of the invention
The present invention to overcome the energy density of traditional sensible heat energy-storage system and energy storage efficiency it is low, reduce energy-storage system to temperature
Requirement it is harsh, generate the disadvantages of side reaction, a kind of novel heat chemistry energy-storage system is provided.
The technical solution adopted by the present invention to solve the technical problems is:
Supercritical CO2The amino thermochemical energy-storage system of solar heat power generation system, it is characterised in that: setting is being reflected too
Ammonolysis craft endothermic reaction device 3 on the reflected light path of the heliostat field 1 of sunlight, ammonolysis craft endothermic reaction device 3 and First Heat Exchanger 4
Be erected on collection thermal tower 2, ammonolysis craft endothermic reaction device 3, First Heat Exchanger 4, between Pressure of Ambient Temperature holding vessel 7 with the first appendix
5 and first perfusion tube 6 be sequentially connected；Pressure of Ambient Temperature holding vessel 7, the second heat exchanger 10 are synthesized and are used between ammonia exothermic reactor 11
Second appendix 8 and the second perfusion tube 9 are sequentially connected；It synthesizes and is equipped between ammonia exothermic reactor 11 and power plant 12 with overcritical
CO2For the heat-exchange circulating device of working medium.
Liquefied ammonia is transported to ammonolysis craft endothermic reaction device 3 by the first perfusion tube 6 by Pressure of Ambient Temperature holding vessel 7；Ammonolysis craft is inhaled
Thermal reactor 3 absorbs the heat from heliostat field 1, is nitrogen and hydrogen by constituents, then nitrogen and hydrogen are passed through the
One appendix 5 is transported to Pressure of Ambient Temperature holding vessel 7；Nitrogen and hydrogen are transported to conjunction by the second appendix 8 by normal temperature storage tank 7
Nitrogen and hydrogen are synthesized ammonia by ammonification exothermic reactor 11, synthesis ammonia exothermic reactor 11, then pass through the second perfusion tube 9 for liquid
Ammonia is transported to Pressure of Ambient Temperature holding vessel 7；Ammonolysis craft endothermic reaction device 3, First Heat Exchanger 4, Pressure of Ambient Temperature holding vessel 7, second are changed
Hot device 10, synthesis ammonia exothermic reactor 11 constitute a closed cycle.
Amino thermochemical energy-storage system of the invention, heliostat field 1 dispose at a certain angle, and sunlight is reflected into ammonia point
Desorb thermal reactor 3；Ammonolysis craft endothermic reaction device 3 is can-like structure, and both ends are spherical arc, ammonolysis craft endothermic reaction device 3
Bottom end connect by the first appendix 5 and the first perfusion tube 6 with First Heat Exchanger 4, ammonolysis craft endothermic reaction device 3 and first changes
On the whole steel construction for being supported on collection thermal tower 2 of hot device 4；First Heat Exchanger 4 passes through the first appendix 5 and the first perfusion tube 6
It is connect with Pressure of Ambient Temperature holding vessel 7, Pressure of Ambient Temperature holding vessel 7 is can-like structure, and two end faces are spherical arcs；Pass through room temperature
The second appendix 8 and the second perfusion tube 9 of pressure storage 7 are connect with the upper and lower ends of synthesis ammonia exothermic reactor 11 again, are closed
Ammonification exothermic reactor 11 is connect finally by heat-exchange circulating device with power plant 12；Ammonolysis craft endothermic reaction device 3, First Heat Exchanger
4, Pressure of Ambient Temperature holding vessel 7, the second heat exchanger 10 and synthesis ammonia exothermic reactor 11 constitute a closed cycle, by synthesizing ammonia
Reaction Carry out heat chemistry energy storage；Synthesize ammonia exothermic reactor 11 and power plant
Heat-exchange circulating device between 12 uses supercritical carbon dioxide (S-CO2) it is cycle fluid, it is used for S-CO2Bretton power generation follows
Ring.
Heat chemistry energy-storage system of the invention mainly passes through 11 liang of ammonia exothermic reactor of ammonolysis craft endothermic reaction device 2 and synthesis
Pass through ammonia synthesis reaction between a reactor Ammonia circulation is carried out, ammonia heat release is synthesized
With supercritical carbon dioxide (S-CO between reactor 11 and power plant 122) it is that working medium completes circulation.Two reactors and all companies
The material for connecing conduit (comprising the first appendix 5 and the first perfusion tube 6, the second appendix 8 and the second perfusion tube 9) is
Inconel 625, ammonolysis craft endothermic reaction device 2 and 11 inside of synthesis ammonia exothermic reactor are uniformly urged filled with iron-based synthesis ammonia
Catalyst particles, normal temperature storage tank 7 are stainless steel material.
The structure of amino solar heat chemical energy storage system is as shown in Figure 1.Liquid ammonia is flowed out from holding vessel, by heat exchange
Device absorbs solar energy into endothermic reaction device, while carrying out the ammonolysis craft endothermic reaction
It reacts nitrogen generated and hydrogen to be back in holding vessel by heat exchanger, and spontaneously carries out gas with liquid ammonia at normal temperature
Liquid two-phase laminated flow.If it exists when power generation needs, nitrogen and hydrogen are flowed out from holding vessel, by heat exchanger, into exothermic reaction
Device carries out ammonia synthesis reaction Supercritical carbon dioxide (S- is heated simultaneously
CO2) working medium, it is used for S-CO2Bretton power generation cycle.The heat chemistry energy-storage system not only solves existing for traditional energy-storage system
Energy storage density is low, the solidification of cost high and low temperature, pyrolytic and the problems such as corrosion, and with no side reaction, can store up at normal temperature
The advantages that depositing.
The beneficial effects of the present invention are: the energy density of the heat chemistry energy-storage system based on ammonia is high, energy loss is few and stores up
It is low to deposit temperature, because it is without side reaction, can store at normal temperature, operability is high.
Detailed description of the invention
Fig. 1 is system construction drawing of the invention；
Fig. 2 is the principle schematic diagram of synthesis ammonia exothermic reactor of the invention；
Fig. 3 is the partial enlargement diagram of Fig. 2 circled portion.
Specific embodiment
Technical solution of the present invention is further illustrated with reference to the accompanying drawing.
1. heliostat field in figure, 2. collection thermal towers, 3. ammonolysis craft endothermic reaction devices, 4. First Heat Exchanger, 5 first appendix, 6.
First perfusion tube, 7. Pressure of Ambient Temperature holding vessels, 8. second appendixs, 9. second perfusion tubes, 10. second heat exchangers, 11. synthesis
Ammonia exothermic reactor, 12. power plant.Supercritical CO of the invention2The amino thermochemical energy-storage system of solar heat power generation system,
It is characterized in that: the ammonolysis craft endothermic reaction device 3 on the reflected light path of the heliostat field 1 of reflected sunlight is set, ammonolysis craft is inhaled
Thermal reactor 3 and First Heat Exchanger 4 are erected on collection thermal tower 2, ammonolysis craft endothermic reaction device 3, First Heat Exchanger 4, Pressure of Ambient Temperature
It is sequentially connected between holding vessel 7 with the first appendix 5 and the first perfusion tube 6；Pressure of Ambient Temperature holding vessel 7, closes second heat exchanger 10
It is sequentially connected between ammonification exothermic reactor 11 with the second appendix 8 and the second perfusion tube 9；Synthesize ammonia exothermic reactor 11 and electricity
It is equipped between factory 12 with supercritical CO2The heat-exchange circulating device of working medium.It is S-CO that heat-exchange circulating device, which uses,2Bretton power generation follows
Ring, with supercritical carbon dioxide (S-CO2) it is cycle fluid.
Liquefied ammonia is transported to ammonolysis craft endothermic reaction device 3 by the first perfusion tube 6 by Pressure of Ambient Temperature holding vessel 7；Ammonolysis craft is inhaled
Thermal reactor 3 absorbs the heat from heliostat field 1, is nitrogen and hydrogen by constituents, then nitrogen and hydrogen are passed through the
One appendix 5 is transported to Pressure of Ambient Temperature holding vessel 7；Nitrogen and hydrogen are transported to conjunction by the second appendix 8 by normal temperature storage tank 7
Nitrogen and hydrogen are synthesized ammonia by ammonification exothermic reactor 11, synthesis ammonia exothermic reactor 11, then pass through the second perfusion tube 9 for liquid
Ammonia is transported to Pressure of Ambient Temperature holding vessel 7；Ammonolysis craft endothermic reaction device 3, First Heat Exchanger 4, Pressure of Ambient Temperature holding vessel 7, second are changed
Hot device 10, synthesis ammonia exothermic reactor 11 constitute a closed cycle.Pass through ammonia synthesis reaction Carry out heat chemistry energy storage；Supercritical carbon dioxide (S-CO2) it is cycle fluid, it is used for S-CO2Bretton hair
Electricity circulation.
Content described in this specification embodiment is only enumerating to the way of realization of inventive concept, protection of the invention
Range should not be construed as being limited to the specific forms stated in the embodiments, and protection scope of the present invention is also and in art technology
Personnel conceive according to the present invention it is conceivable that equivalent technologies mean.
Claims (2)
1. supercritical CO2The amino thermochemical energy-storage system of positive energy heat generating system, it is characterised in that: be arranged in reflected sunlight
Heliostat field (1) reflected light path on ammonolysis craft endothermic reaction device (3), ammonolysis craft endothermic reaction device (3) and first heat exchange
Device (4) be erected at collection thermal tower (2) on, ammonolysis craft endothermic reaction device (3), First Heat Exchanger (4), Pressure of Ambient Temperature holding vessel (7) it
Between be sequentially connected with the first appendix (5) and the first perfusion tube (6)；Pressure of Ambient Temperature holding vessel (7), closes the second heat exchanger (10)
It is sequentially connected between ammonification exothermic reactor (11) with the second appendix (8) and the second perfusion tube (9)；Synthesize ammonia exothermic reactor
(11) it is equipped between power plant (12) with supercritical CO2For the heat-exchange circulating device of working medium.
2. ammonolysis craft endothermic reaction device (2), synthesis ammonia exothermic reactor (11), the first appendix (5), the first perfusion tube (6), the
The material of two appendixs (8) and the second perfusion tube (9) is Inconel 625, and ammonolysis craft endothermic reaction device (2) and synthesis ammonia are put
Thermal reactor (11) is internal to be uniformly filled with iron-based synthetic ammonia catalyst particle, and normal temperature storage tank is stainless steel material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810605390.3A CN108981201A (en) | 2018-06-13 | 2018-06-13 | Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810605390.3A CN108981201A (en) | 2018-06-13 | 2018-06-13 | Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system |
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| Publication Number | Publication Date |
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| CN108981201A true CN108981201A (en) | 2018-12-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810605390.3A Pending CN108981201A (en) | 2018-06-13 | 2018-06-13 | Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110205637A (en) * | 2019-07-03 | 2019-09-06 | 浙江工业大学 | A kind of amino solar heat chemical solids oxide electrolysis water hydrogen generating system |
| CN110243086A (en) * | 2019-07-03 | 2019-09-17 | 浙江工业大学 | Solar heat chemical energy storage system based on self-heating ammonia synthesis reactor heat recovery |
| CN112983582A (en) * | 2021-04-01 | 2021-06-18 | 浙江工业大学 | Kalina coupling power generation system and process based on solar amino thermal chemical energy storage |
| CN113005475A (en) * | 2021-03-12 | 2021-06-22 | 浙江工业大学 | System and process for solar high-temperature water electrolysis coupling hydrogen production based on amino thermochemical energy storage |
| CN113184806A (en) * | 2021-05-28 | 2021-07-30 | 浙江工业大学 | Solar ammonia decomposition hydrogen production system and process method |
| CN114353365A (en) * | 2022-01-06 | 2022-04-15 | 福州大学 | Solar-driven distributed energy system |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632438A (en) * | 2004-12-22 | 2005-06-29 | 华南理工大学 | Amino thermochemical high temperature energy storage method and apparatus therefor |
| CN102400867A (en) * | 2010-09-08 | 2012-04-04 | 中国科学院工程热物理研究所 | Supercritical CO2 (carbon dioxide) solar thermal generating system with heat accumulating function |
| CN106931657A (en) * | 2017-03-28 | 2017-07-07 | 华南理工大学 | A kind of solar energy high temperature storage and release system based on thermochemical method |
| CN208720539U (en) * | 2018-06-13 | 2019-04-09 | 浙江工业大学 | Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system |
-
2018
- 2018-06-13 CN CN201810605390.3A patent/CN108981201A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632438A (en) * | 2004-12-22 | 2005-06-29 | 华南理工大学 | Amino thermochemical high temperature energy storage method and apparatus therefor |
| CN102400867A (en) * | 2010-09-08 | 2012-04-04 | 中国科学院工程热物理研究所 | Supercritical CO2 (carbon dioxide) solar thermal generating system with heat accumulating function |
| CN106931657A (en) * | 2017-03-28 | 2017-07-07 | 华南理工大学 | A kind of solar energy high temperature storage and release system based on thermochemical method |
| CN208720539U (en) * | 2018-06-13 | 2019-04-09 | 浙江工业大学 | Supercritical CO2The amino thermochemical energy storage reactor of solar heat power generation system |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110205637A (en) * | 2019-07-03 | 2019-09-06 | 浙江工业大学 | A kind of amino solar heat chemical solids oxide electrolysis water hydrogen generating system |
| CN110243086A (en) * | 2019-07-03 | 2019-09-17 | 浙江工业大学 | Solar heat chemical energy storage system based on self-heating ammonia synthesis reactor heat recovery |
| CN113005475A (en) * | 2021-03-12 | 2021-06-22 | 浙江工业大学 | System and process for solar high-temperature water electrolysis coupling hydrogen production based on amino thermochemical energy storage |
| CN112983582A (en) * | 2021-04-01 | 2021-06-18 | 浙江工业大学 | Kalina coupling power generation system and process based on solar amino thermal chemical energy storage |
| CN113184806A (en) * | 2021-05-28 | 2021-07-30 | 浙江工业大学 | Solar ammonia decomposition hydrogen production system and process method |
| CN114353365A (en) * | 2022-01-06 | 2022-04-15 | 福州大学 | Solar-driven distributed energy system |
| CN114353365B (en) * | 2022-01-06 | 2023-12-19 | 福州大学 | Solar-driven distributed energy system |
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