CN108977611A - A kind of converter hot metal containing low silicon converting method using cast steel recrement - Google Patents

A kind of converter hot metal containing low silicon converting method using cast steel recrement Download PDF

Info

Publication number
CN108977611A
CN108977611A CN201811010495.0A CN201811010495A CN108977611A CN 108977611 A CN108977611 A CN 108977611A CN 201811010495 A CN201811010495 A CN 201811010495A CN 108977611 A CN108977611 A CN 108977611A
Authority
CN
China
Prior art keywords
recrement
cast steel
steel
hot metal
metal containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811010495.0A
Other languages
Chinese (zh)
Other versions
CN108977611B (en
Inventor
周虎
徐刚
赵建宏
邓宏达
何船
钟兴云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Iron and Steel Group Kunming Iron and Steel Co Ltd
Original Assignee
Wuhan Iron and Steel Group Kunming Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan Iron and Steel Group Kunming Iron and Steel Co Ltd filed Critical Wuhan Iron and Steel Group Kunming Iron and Steel Co Ltd
Priority to CN201811010495.0A priority Critical patent/CN108977611B/en
Publication of CN108977611A publication Critical patent/CN108977611A/en
Application granted granted Critical
Publication of CN108977611B publication Critical patent/CN108977611B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/30Regulating or controlling the blowing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

The invention discloses a kind of converter hot metal containing low silicon converting methods using cast steel recrement, by the way that cast steel recrement is added in converting process, to improve the slugging condition that blows, make the early slugging of converter energy in smelting low-silicon molten iron converting process, change slag and changed slag, dephosphorization efficiency significantly improves.Clinker, which covers molten steel face to advantageously reduce completely, returns the dry steel bonding problem with oxygen rifle, fire door, petticoat pipe caused by splash etc., reduces iron and steel stock loss, reduce a ton steel consumption, labor intensity is reduced, save the cost is conducive to and improves production security, there is good application value.

Description

A kind of converter hot metal containing low silicon converting method using cast steel recrement
Technical field
The invention belongs to bessemerize technical field, and in particular to a kind of converter hot metal containing low silicon blowing using cast steel recrement Method.
Background technique
Very big economic benefit can be brought to iron and steel enterprise using hot metal containing low silicon in the production of modern age large blast furnace.Blast furnace iron The siliceous every reduction by 0.1% of water, can be improved yield 1.0% ~ 1.5%.The U.S., Japan, European Countries large blast furnace the silicon of molten iron contain Amount has all reduced.But it is compared with normal siliceous molten iron-steelmaking, in smelting process, decarburizing reaction shifts to an earlier date hot metal containing low silicon, the oxygen of carbon Change the oxidation prior to silicon, SiO in clinker2It is difficult to be enriched with, the dicalcium silicate more early occurred in initial stage slag hinders lime again Melt, keeps Primary period slag making difficult, dephosphorization effect is poor.Supplementing silicon source for converter is to solve to exist in hot metal containing low silicon converting process Problems method the most direct, ferrosilicon, river sand, silica as supplement silicon source have certain industrial practice.But silicon Iron itself is expensive, and river sand, silica content are complicated and the thawing time is long, all not as the ideal chose of supplement silicon source.
In actual operation, it when oxygen lance position is as low as certain degree, or uses a certain low rifle position to blow for a long time, melts Decarbonization rate is fast in pond, and FeO consumption is more, and the content of TFe can be reduced, and cause slag to return dry, metal expulsion events are serious.Thus into One step causes the major accidents such as steel adhesion on oxygen lance, not only increases processing cost, also affects going on smoothly for production.
When bessemerizing, due to heat affluence, it is excessively high to will lead to furnace temperature, and furnace lining is easy by impingment corrosion.And it is blowing Dephosphorisation reaction is stronger to the sensibility of temperature during refining, and the distribution ratio decline of phosphorus, causes containing in molten steel under the high temperature conditions Phosphorus amount is more difficult to drop to requirement or less.The gas being dissolved in molten steel increases, to influence the quality of steel.And due to molten steel of tapping Temperature is excessively high, be easy to cause casting accident.
For this purpose, researching and developing a kind of converter hot metal containing low silicon converting method right and wrong using cast steel recrement for being able to solve the above problem Chang Guanjian's.
Summary of the invention
The purpose of the present invention is to provide a kind of converter hot metal containing low silicon converting methods using cast steel recrement.
The object of the present invention is achieved like this, comprising the following steps:
1) steel scrap is first added in converter and is blended into molten iron again, oxygen lance position is set as 180 ~ 220cm, starts to light a fire;
2) start to blow after lighting a fire successfully, while cast steel recrement being added in converter by high hopper, and continue to blow to first Slag is formed, and reduces oxygen lance position to 160 ~ 180cm, slag material is added;
3) after entering blowing final period, oxygen lance position is reduced to 100 ~ 120cm, reaches to molten steel composition and smelts steel grade requirement and temperature Up to when smelting steel grade tapping temperature, stop oxygen blast, tapping immediately.
Compared with prior art, the invention has the following advantages:
1) SiO is added in converter steelmaking process in the present invention2The cast steel recrement of rich content, i.e., fundamentally solve converter Low brought a series of problems of silicone content in smelting, while the cast steel recrement as industry byproduct being made to turn waste into wealth, not only Resource has been vitalized, while having decreased the pollution of environment.
2) the cast steel recrement that the present invention is added during bessemerizing is advantageously reduced to return to do and be made with splash rich in TFe At oxygen rifle, fire door, petticoat pipe etc. steel bonding problem, reduce iron and steel stock loss, reduce labor intensity, be conducive to save the cost and Production security is improved, there is good application value.
3) steel scrap is added as coolant in the present invention before blowing, so that converter is reached thermal balance in converting process, reaches To qualified temperature.The consumption of iron and steel stock, slag making materials and oxygen, and the iron ore than using in common process can be reduced Cooling effect stability, splash is few, and dephosphorization effect is good.
4) the cast steel recrement that the present invention is added during bessemerizing contains a large amount of Al2O3, MnO and CaO, can replace Generation a part slag material so that in smelting process slag material slump in demand, while save the cost, but also more than cast steel Slag maximum resource utilization.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated, but the present invention is limited in any way, Based on present invention teach that it is made it is any transform or replace, all belong to the scope of protection of the present invention.
Converter hot metal containing low silicon converting method of the present invention using cast steel recrement the following steps are included:
1) steel scrap is first added in converter and is blended into molten iron again, oxygen lance position is set as 180 ~ 220cm, starts to light a fire;
2) start to blow after lighting a fire successfully, while cast steel recrement being added in converter by high hopper, and continue to blow to first Slag is formed, and reduces oxygen lance position to 160 ~ 180cm, slag material is added;
3) after entering blowing final period, oxygen lance position is reduced to 100 ~ 120cm, reaches to molten steel composition and smelts steel grade requirement and temperature Up to when smelting steel grade tapping temperature, stop oxygen blast, tapping immediately.
The silicone content of molten iron described in step 1) is lower than 0.15%.
Cast steel recrement described in step 2 is added in 5min after starting blowing and is finished.
Cast steel recrement described in step 2 includes the ingredient of following weight ratio: SiO223%-30%, TFe 20~25%、 Al2O312%-14%、MnO18% –21%、CaO15~20%。
The adding manner of slag material described in step 2 is that point 8 ~ 12 batches are added, and the weight that every batch of is added is molten iron 0.1%~0.4%。
Slag material described in step 2 includes the ingredient of following weight ratio: lime 50 ~ 60%, light dolomite 30 ~ 40%, water chestnut Magnesium ball 5 ~ 10%.
The oxygen supply constant pressure of the oxygen rifle is 0.78 ~ 0.82MPa.
The flow of the oxygen rifle is 22800 ~ 24000m3/h。
The weight of steel scrap described in step 1) is the 4% ~ 14% of molten iron.
The weight of cast steel recrement described in step 2 is the 0.75 ~ 1% of molten iron.
Embodiment 1
1) steel scrap is first added in converter and is blended into molten iron again, oxygen lance position is set as 180cm, starts to light a fire;The silicon of the molten iron Content is 0.05%;The weight of the steel scrap is the 4% of molten iron;The oxygen supply constant pressure of the oxygen rifle is 0.78Mpa;The oxygen The flow of rifle is 22800m3/h;
2) start to blow after lighting a fire successfully, while cast steel recrement being added in converter by high hopper, and continue to blow to first Slag is formed, and reduces oxygen lance position to 160cm, slag material is added;The cast steel recrement has added in 5min after starting blowing Finish.The cast steel recrement includes the ingredient of following weight ratio: SiO228%, TFe 22%, Al2O313%, MnO18%, CaO19%. The adding manner of the slag material is that point 8 batches are added, and the weight that every batch of is added is the 0.1% of molten iron.The slag material Ingredient including following weight ratio: lime 50%, light dolomite 40%, magnesite ball 10%.The weight of the cast steel recrement is iron The 0.75% of water.
3) after entering blowing final period, oxygen lance position is reduced to 100cm, reaches to molten steel composition and smelts steel grade requirement and temperature Up to when smelting steel grade tapping temperature, stop oxygen blast, tapping immediately.
Embodiment 2
1) steel scrap is first added in converter and is blended into molten iron again, oxygen lance position is set as 190cm, starts to light a fire;The silicon of the molten iron Content is 0.08%;The weight of the steel scrap is the 8% of molten iron;The oxygen supply constant pressure of the oxygen rifle is 0.79MPa;The oxygen The flow of rifle is 23000m3/h;
2) start to blow after lighting a fire successfully, while cast steel recrement being added in converter by high hopper, and continue to blow to first Slag is formed, and reduces oxygen lance position to 170cm, slag material is added;The cast steel recrement has added in 5min after starting blowing Finish.The cast steel recrement includes the ingredient of following weight ratio: SiO230%, TFe 25%, Al2O312%, MnO18%, CaO15%.The adding manner of the slag material is that point 9 batches are added, and the weight that every batch of is added is the 0.2% of molten iron.It is described Slag material include following weight ratio ingredient: lime 55%, light dolomite 38%, magnesite ball 7%.The cast steel recrement Weight is the 0.85% of molten iron.
3) after entering blowing final period, oxygen lance position is reduced to 105cm, reaches to molten steel composition and smelts steel grade requirement and temperature Up to when smelting steel grade tapping temperature, stop oxygen blast, tapping immediately.
Embodiment 3
1) steel scrap is first added in converter and is blended into molten iron again, oxygen lance position is set as 200cm, starts to light a fire;The silicon of the molten iron Content is 0.1%;The weight of the steel scrap is the 10% of molten iron;The oxygen supply constant pressure of the oxygen rifle is 0.81MPa;The oxygen The flow of rifle is 23500m3/h;
2) start to blow after lighting a fire successfully, while cast steel recrement being added in converter by high hopper, and continue to blow to first Slag is formed, and reduces oxygen lance position to 175cm, slag material is added;The cast steel recrement has added in 5min after starting blowing Finish.The cast steel recrement includes the ingredient of following weight ratio: SiO223%, TFe 22%, Al2O314%, MnO21%, CaO20%. The adding manner of the slag material is that point 10 batches are added, and the weight that every batch of is added is the 0.3% of molten iron.The slag making Material includes the ingredient of following weight ratio: lime 58%, light dolomite 37%, magnesite ball 5%.The weight of the cast steel recrement is The 0.9% of molten iron.
3) after entering blowing final period, oxygen lance position is reduced to 110cm, reaches to molten steel composition and smelts steel grade requirement and temperature Up to when smelting steel grade tapping temperature, stop oxygen blast, tapping immediately.
Embodiment 4
1) steel scrap is first added in converter and is blended into molten iron again, oxygen lance position is set as 220cm, starts to light a fire;The silicon of the molten iron Content is 0.15%;The weight of the steel scrap is the 14% of molten iron;The oxygen supply constant pressure of the oxygen rifle is 0.82MPa;Described The flow of oxygen rifle is 24000m3/h;
2) start to blow after lighting a fire successfully, while cast steel recrement being added in converter by high hopper, and continue to blow to first Slag is formed, and reduces oxygen lance position to 180cm, slag material is added;The cast steel recrement has added in 5min after starting blowing Finish.The cast steel recrement includes the ingredient of following weight ratio: SiO226%, TFe 24%, Al2O314%, MnO18%, CaO18%. The adding manner of the slag material is that point 12 batches are added, and the weight that every batch of is added is the 0.4% of molten iron.The slag making Material includes the ingredient of following weight ratio: lime 60%, light dolomite 30%, magnesite ball 10%.The weight of the cast steel recrement is The 1% of molten iron.
3) after entering blowing final period, oxygen lance position is reduced to 120cm, reaches to molten steel composition and smelts steel grade requirement and temperature Up to when smelting steel grade tapping temperature, stop oxygen blast, tapping immediately.
Test example 1
E furnace uses traditional handicraft in following tests example, and F furnace uses the converting method of embodiment 3.
In April, 2017, the new district E furnace furnace crown of falling top of the slag fettling 4 times are tapped face furnace crown fettling 3 times, each fettling sand dosage 2 tons, totally 14 tons;The F furnace furnace crown of falling top of the slag fettling 2 times is tapped face furnace crown fettling 1 time, each 2 tons of fettling sand dosage, 6 tons totally;4 Month F furnace ratio E furnace uses 8 tons of fettling sand less.It is calculated by 2300 yuan of ∕ tons of fettling sand, F furnace year-on-year E furnace in April saves 18400 yuan.
Test example 2
In April, 2017, new district E furnace steel output are 8.6 ten thousand tons, and steel technology is 1076kg ∕ tons of steel;F furnace steel output is 9 Ten thousand tons, steel technology is 1072kg ∕ tons of steel.It is calculated by the processing cost that the every drop 1kg iron and steel stock of ton steel saves 2 yuan, F furnace 4 The moon, E furnace saved 720,000 yuan on year-on-year basis.
Test example 3
In April, 2017, new district E furnace weight rifle consume 20, and F furnace weight rifle consumes 12, and F furnace year-on-year E furnace weight rifle in April is few 8.

Claims (10)

1. a kind of converter hot metal containing low silicon converting method using cast steel recrement, it is characterised in that the following steps are included:
1) steel scrap is first added in converter and is blended into molten iron again, oxygen lance position is set as 180 ~ 220cm, starts to light a fire;
2) start to blow after lighting a fire successfully, while cast steel recrement being added in converter by high hopper, and continue to blow to first Slag is formed, and reduces oxygen lance position to 160 ~ 180cm, slag material is added;
3) after entering blowing final period, oxygen lance position is reduced to 100 ~ 120cm, reaches to molten steel composition and smelts steel grade requirement and temperature Up to when smelting steel grade tapping temperature, stop oxygen blast, tapping immediately.
2. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that step 1) The silicone content of the molten iron is lower than 0.15%.
3. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that step 2 The cast steel recrement is added in 5min after starting blowing and is finished.
4. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that step 2 The cast steel recrement includes the ingredient of following weight ratio: SiO223%-30%、TFe 20~25%、Al2O312%-14%、MnO18% –21%、CaO15~20%。
5. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that step 2 The adding manner of the slag material is that point 8 ~ 12 batches are added, and the weight that every batch of is added is the 0.1% ~ 0.4% of molten iron.
6. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that step 2 The slag material includes the ingredient of following weight ratio: lime 50 ~ 60%, light dolomite 30 ~ 40%, magnesite ball 5 ~ 10%.
7. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that described The oxygen supply constant pressure of oxygen rifle is 0.78 ~ 0.82MPa.
8. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that described The flow of oxygen rifle is 22800 ~ 24000m3/h。
9. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that step 1) The weight of the steel scrap is the 4% ~ 14% of molten iron.
10. the converter hot metal containing low silicon converting method according to claim 1 using cast steel recrement, it is characterised in that step 2 The weight of the cast steel recrement is the 0.75 ~ 1% of molten iron.
CN201811010495.0A 2018-08-31 2018-08-31 Converter low-silicon molten iron blowing method using cast steel residues Active CN108977611B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811010495.0A CN108977611B (en) 2018-08-31 2018-08-31 Converter low-silicon molten iron blowing method using cast steel residues

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811010495.0A CN108977611B (en) 2018-08-31 2018-08-31 Converter low-silicon molten iron blowing method using cast steel residues

Publications (2)

Publication Number Publication Date
CN108977611A true CN108977611A (en) 2018-12-11
CN108977611B CN108977611B (en) 2020-04-28

Family

ID=64547908

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811010495.0A Active CN108977611B (en) 2018-08-31 2018-08-31 Converter low-silicon molten iron blowing method using cast steel residues

Country Status (1)

Country Link
CN (1) CN108977611B (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101117651A (en) * 2006-07-31 2008-02-06 宝山钢铁股份有限公司 Converting process for converter low-silicon molten iron
CN102994689A (en) * 2012-11-30 2013-03-27 武钢集团昆明钢铁股份有限公司 Method for heat application of low-alkalinity casting residue in steel-making
CN103555878A (en) * 2013-11-25 2014-02-05 武钢集团昆明钢铁股份有限公司 Safe and high-efficient low-silicon molten-ion blowing process
CN103710484A (en) * 2014-01-06 2014-04-09 鞍钢股份有限公司 Silicon recycling method for controlling casting residue to be recycled to low-silicon steel
CN104711388A (en) * 2015-02-04 2015-06-17 北京科技大学 Low-silicon molten iron blowing method
CN105219913A (en) * 2015-11-10 2016-01-06 湖南华菱湘潭钢铁有限公司 A kind of method optimizing converter slag-making

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101117651A (en) * 2006-07-31 2008-02-06 宝山钢铁股份有限公司 Converting process for converter low-silicon molten iron
CN102994689A (en) * 2012-11-30 2013-03-27 武钢集团昆明钢铁股份有限公司 Method for heat application of low-alkalinity casting residue in steel-making
CN103555878A (en) * 2013-11-25 2014-02-05 武钢集团昆明钢铁股份有限公司 Safe and high-efficient low-silicon molten-ion blowing process
CN103710484A (en) * 2014-01-06 2014-04-09 鞍钢股份有限公司 Silicon recycling method for controlling casting residue to be recycled to low-silicon steel
CN104711388A (en) * 2015-02-04 2015-06-17 北京科技大学 Low-silicon molten iron blowing method
CN105219913A (en) * 2015-11-10 2016-01-06 湖南华菱湘潭钢铁有限公司 A kind of method optimizing converter slag-making

Also Published As

Publication number Publication date
CN108977611B (en) 2020-04-28

Similar Documents

Publication Publication Date Title
CN103205524B (en) Method for smelting low-sulfur steel from semi-steel
CN110373511A (en) A kind of converter smelting process of low lime consumption
CN105525055B (en) A kind of control method of converter less-slag melting carbon period splash
CN106544467B (en) A kind of high alloy Low-phosphorus Steel method in high molten iron proportion electric furnace smelting
CN109280731A (en) The method of the high phosphorus hot metal production steel of converter terminal P≤0.01% is smelted using few slag charge
CN108913837A (en) A kind of high scrap ratio smelting process of converter
CN100469898C (en) Alkaline oxygen converter steelmaking slagging fluxing agent and its preparing method and slagging method
CN103333981A (en) Method for smelting high-silicon molten iron by using limestone as slagging material
CN102212643A (en) Converter less-slag smelting process
CN105779682B (en) A kind of technique of utilization lime stone smelting stainless steel in dephosphorization converter
CN104762435B (en) A kind of method for improving converter hot metal ratio and reducing smelting cost
CN105671248A (en) Smelting method of converter efficient dephosphorization
CN110117689A (en) A method of based on high-silicon molten iron converter double slag process low phosphorus steel by smelting
CN112609034A (en) Method for efficiently dephosphorizing low-temperature steel tapping in later period of converter
CN106282477A (en) A kind of smelting process of ultra-low phosphoretic steel
CN109423533B (en) Full molten iron converter smelting control method
CN113293260A (en) Efficient dephosphorization process method using fly ash as converter slagging agent
CN104726645A (en) Dephosphorization method of mid-high phosphorus semisteel
CN108624734A (en) A method of decarbonized slag circulatory stove number in control converter less-slag melting technique
CN105177217B (en) A kind of technique for reducing the converter smelting slag quantity of slag
CN107034334A (en) The double slag melting methods of half steel of the quick slagging of falling stove
CN101649370B (en) Method for smelting first batch after fettling of converter
CN101864508B (en) Steel making method of convertor with small slag quantity
CN109112250B (en) Gasification dephosphorization and cyclic utilization method in semi-steel smelting converter final slag furnace
CN114480773B (en) Production control method for reducing production cycle of converter and improving production efficiency of converter

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant