CN108977264A - A kind of total synthesis water-base cutting fluid - Google Patents

A kind of total synthesis water-base cutting fluid Download PDF

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Publication number
CN108977264A
CN108977264A CN201811026319.6A CN201811026319A CN108977264A CN 108977264 A CN108977264 A CN 108977264A CN 201811026319 A CN201811026319 A CN 201811026319A CN 108977264 A CN108977264 A CN 108977264A
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China
Prior art keywords
cutting fluid
propylene glycol
water
polyether
polypropylene glycol
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Pending
Application number
CN201811026319.6A
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Chinese (zh)
Inventor
白玉
张旭
武建强
张树龙
常志新
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Luo Fenji
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Luo Fenji
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Priority to CN201811026319.6A priority Critical patent/CN108977264A/en
Publication of CN108977264A publication Critical patent/CN108977264A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18—Anti-foaming property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A kind of total synthesis water-base cutting fluid, it is characterized in that the cutting fluid is by oleoyl triethanol amine, propylene glycol atactic polyether, butanol atactic polyether, propylene glycol block polyether, triethanolamine borate, aliphatic amine polyoxyethylene ether, ethoxy lauryl imidazoline, polypropylene glycol and the water of surplus composition, the oleoyl triethanol amine, propylene glycol is without silicon polyethers, butanol atactic polyether, propylene glycol block polyether, triethanolamine borate, aliphatic amine polyoxyethylene ether, ethoxy lauryl imidazoline, the weight ratio of polypropylene glycol is 1:4~6:2~3:3~5:1.5~2.5:3~5:1~1.5:5~8.

Description

A kind of total synthesis water-base cutting fluid
Technical field
The present invention relates to cutting fluids.
Background technique
Metal material needs in tool when carrying out machining manufacturing and is cut, injects between the metal material that is ground Metalworking coolant, abbreviation cutting fluid.The performance indicator of cutting fluid mainly will in terms of cooling, lubrication, cleaning, antirust etc. four into Row evaluation.Existing metalworking fluid is divided into oil type (Straight oil) and aqua type (Water by medium condition fluid).It is serious by the cutting fluid pollution problem scrapped although wherein oil base cutting fluid appearance is more early, it has used gradually It is restricted.Water-base cutting fluid obtains, also known as total synthesis water-base on the basis of water-soluble additive after a large amount of water dilutions are added Cutting fluid is increasingly becoming the emphasis of cutting fluid exploitation since total synthesis water-base cutting fluid has excellent cooling effect.Ideal water Base cutting fluid should have excellent cooling, lubrication, antirust and cleaning function；Itself answer it is nontoxic to environment without dirt；The property of cutting fluid Matter stabilization, long service life；In a state of use, the cutting fluid after dilution should be transparent or semitransparent liquid, convenient for observation Machining state.Chinese patent CN2017109392878 discloses a kind of water-base chain lubricant, compounding propylene glycol polyethers with A small amount of 13 carbon Guerbet alcohol polyoxyethylene ether of collateralization, hydroxypropyl methyl cellulose are increased on the basis of oleoyl triethanol amine And triethyl citrate, and point out that the lubricant can keep preferable greasy property under conditions of high dilution.However by In application difference, when which is used for cutting fluid, extreme pressure property, antirust cleaning performance are not able to satisfy and cut Cut the job requirement of liquid.Therefore how on the basis of existing water base lubricant to improve formula and obtain a kind of performance and preferably close entirely At water-base cutting fluid become urgent problem to be solved in the prior art.
Summary of the invention
To solve the above problem in the prior art, the present invention provides a kind of total synthesis water-base cutting fluids, it is characterized in that The cutting fluid is by oleoyl triethanol amine, propylene glycol atactic polyether, butanol atactic polyether, propylene glycol block polyether, triethanolamine Borate, aliphatic amine polyoxyethylene ether, the water composition of ethoxy lauryl imidazoline, polypropylene glycol and surplus, the oleoyl Triethanolamine, propylene glycol atactic polyether, butanol atactic polyether, propylene glycol block polyether, triethanolamine borate, fatty amine polyoxy Vinethene, ethoxy lauryl imidazoline, polypropylene glycol weight ratio be 1:4~6:2~3:3~5:1.5~2.5:3~5: 1~1.5:5~8.
The total synthesis water-base cutting fluid, it is characterized in that the oleoyl triethanol amine, propylene glycol without silicon polyethers, butanol without Polyethers, propylene glycol block polyether, triethanolamine borate, aliphatic amine polyoxyethylene ether are advised, ethoxy lauryl imidazoline gathers The weight ratio of propylene glycol is 1:5:2.5:4:2:4:1~1.5:6~7.
The total synthesis water-base cutting fluid, it is characterized in that the water content of the cutting fluid is 20%~99% (wt).It is excellent It is selected as 95%~99%.
The total synthesis water-base cutting fluid, it is characterized in that the propylene glycol atactic polyether specification is PPE1500；The fourth The specification of alcohol atactic polyether is BPE1000；The propylene glycol block polyether specification is L42 or L43；The aliphatic amine polyoxyethylene Ether is lauryl amine polyoxyethylene ether, and the specification of the aliphatic amine polyoxyethylene ether is preferably AC1210 or AC1215；It is described poly- Propylene glycol is polypropylene glycol 600, polypropylene glycol 1000, polypropylene glycol 1500 or polypropylene glycol 2000, preferably polypropylene glycol 1000.
A kind of water base lubricant of a kind of total synthesis water-base cutting fluid provided by the invention, it is poly- in propylene glycol reported in the literature Ether is compounded with oleoyl triethanol amine can be used as water base lubricant on the basis of, be found surprisingly that, part propylene glycol randomly gathered Ether replaces with butanol atactic polyether and propylene glycol block polyether, and triethanolamine borate, aliphatic amine polyoxyethylene ether, hydroxyl is added After ethyl lauryl imidazoline, polypropylene glycol, the stoste that can be used as water-base cutting fluid is used, and what is obtained after being diluted cuts It cuts liquid and is being able to maintain higher greasy property and extreme pressure property in conventional diluted concentration (water content 95%~99%), So as to by the way of high dilution, reducing the use of cutting liquid stock solution in general use occasion, use cost is reduced, And lower dilution is used when needing heavy duty cutting, to give full play to the extreme pressure property of cutting fluid.Furthermore corrosion experiment table Bright cutting fluid provided by the invention has good rustless property, and cutting liquid stock solution (water content 20%) has good storage steady Qualitative, cutting fluid after dilution is able to maintain higher clarity.In experimenting, we find out that, and prescription of the present invention is only added It measures each component in range and realizes said effect, and in defoaming, corrosivity, rust-preventing characteristic test, it is only real using the present invention Apply example cutting fluid can by whole test specifications in prescription each component to improve the inhibition of cutting fluid after dilution, antirust and Defoaming effect produces synergistic effect.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below, but protection scope of the present invention is not limited to This.
The water-base cutting fluid provided in the embodiment of the present invention is prepared in the following ways
1) by the polypropylene glycol of recipe quantity (PPG), triethanolamine borate (BN), ethoxy lauryl imidazoline (DC) Aliphatic amine polyoxyethylene ether (AC) is dissolved in recipe quantity water and obtains solution (1)
2) by recipe quantity oleoyl triethanol amine (TO), propylene glycol atactic polyether (PPE) butanol atactic polyether (BPE) and the third two Alcohol block polyether (BP) mixing
3) solution (1) is added under stirring in the mixed liquor of step 2), lasting stirring becomes transparent and homogeneous liquid.
Water is deionized water, and the weight ratio of the sum of deionized water and other all components is unified for 4:1.
Propylene glycol atactic polyether (PPE) specification is PPE-1500.
The specification of butanol atactic polyether (BPE) is BPE-1000, the specification of propylene glycol block polyether is L42 or L43.
The ethoxy lauryl imidazoline (CAS:16058-17-6), i.e. 4,5- dihydro -2- dodecyl -1H- miaow Azoles -1- ethyl alcohol.
Polypropylene glycol is selected from polypropylene glycol 600 (PPG600), polypropylene glycol 1000 (PPG1000), polypropylene glycol 1500 (PPG1500) or polypropylene glycol 2000 (PPG2000)
Aliphatic amine polyoxyethylene ether is lauryl amine polyoxyethylene ether, and specification is AC1210 or AC1215,
More than
Example formulations see the table below (unit: parts by weight)
After the cutting fluid that embodiment and comparative example obtain respectively is diluted to water content 99%, 95% (wt) with deionized water It is spare.
Detect the test of 1. lubricity of embodiment
The measurement of simulation lubricity is carried out on four-ball extreme pressure tester.The grinding defect diameter of ball is measured, grinding defect diameter is smaller Show that greasy property is better.
Method: steel ball is separately fixed in the upper ball base and oil box of four-ball tester.Embodiment is cut with what comparative example obtained It cuts after liquid is diluted by certain volume multiple and pours into oil box, it is allowed to cover steel ball and reach the joint of pressure ring and nut. The oil box center for installing sample and ball is placed in the upper ball base of four-ball extreme pressure tester in the following, among lubricating cup and guide post Circular disk rack is put, load lever is released and defined load is added on ball.Continue 30min, test temperature is 25 DEG C ± 5 DEG C. Every time after test, the grinding defect diameter of the both direction in length and breadth of any one steel ball, is averaged in measuring box.Wherein used in test Steel ball is the GCr15 steel ball of II class precision, and diameter 12.7mm, HRC (Rockwell hardness) are 64-66, is mentioned by Shanghai Steel Ball Plant's production For.
According to the requirement in GBT6144-2010, maximum nothing is detected using the method (revolving speed 1440r/min) in GBT3142 Seizing load PBValue
Grinding defect diameter result such as following table (unit: mm) under different experimental conditions
It is above-mentioned the experimental results showed that, using lubricant provided in an embodiment of the present invention, the equal table in the test of being lubricated property Reveal preferable performance, and when lubricant is diluted to water content 99%, greasy property is still good, and from above-mentioned number As can be seen that being apparently higher than other embodiments using the greasy property for the embodiment 3~5 being preferably formulated in.Comparative example 1 Greasy property and extreme pressure property are significantly lower than each embodiment, illustrate embodiment by optimization formula, the cutting fluid made is dilute Greasy property and extreme pressure property after releasing are significantly improved.The formula of comparative example 2~5 is deleted on the basis of embodiment 5 Constituent part, but showing from experimental data can to the property of entire cutting fluid after each component is comprehensive in technical solution of the present invention Apparent influence can be produced, especially influence dilution for many times and lubrication and extreme pressure property when top load.
Detect 2 transparency of embodiment, defoaming, corrosion test, rust-preventing characteristic test
According to method specified in GBT6144-2010 and standard (L-MAH), cut to what each embodiment and comparative example obtained It cuts liquid (being diluted to water content 95%) and carries out transparency, pH value, defoaming, corrosion test, rust-preventing characteristic test, it is as a result as follows.
The experimental results showed that the cutting fluid that embodiment obtains can be qualified in items test, it is each to compare in comparative example Example is unqualified in defoaming test, remaining comparative example fails all to test by corrosion test and rust-preventing characteristic.

Claims (6)

1. a kind of total synthesis water-base cutting fluid, it is characterized in that the cutting fluid is by oleoyl triethanol amine, propylene glycol atactic polyether, fourth Alcohol atactic polyether, propylene glycol block polyether, triethanolamine borate, aliphatic amine polyoxyethylene ether, ethoxy dodecyl imidazole The water of quinoline, polypropylene glycol and surplus forms, and the oleoyl triethanol amine, propylene glycol are without silicon polyethers, butanol atactic polyether, propylene glycol Block polyether, triethanolamine borate, aliphatic amine polyoxyethylene ether, the weight of ethoxy lauryl imidazoline, polypropylene glycol Than for 1:4~6:2~3:3~5:1.5~2.5:3~5:1~1.5:5~8.
2. total synthesis water-base cutting fluid as described in claim 1, it is characterized in that the oleoyl triethanol amine, propylene glycol are randomly gathered Ether, butanol atactic polyether, propylene glycol block polyether, triethanolamine borate, aliphatic amine polyoxyethylene ether, ethoxy dodecyl Imidazoline, polypropylene glycol weight ratio be 1:5:2.5:4:2:4:1~1.5:6~7.
3. total synthesis water-base cutting fluid as claimed in claim 1 or 2, it is characterized in that the propylene glycol atactic polyether specification is PPE1500；The specification of the butanol atactic polyether is BPE1000；The propylene glycol block polyether specification is L42 or L43, described Aliphatic amine polyoxyethylene ether is lauryl amine polyoxyethylene ether；The polypropylene glycol is polypropylene glycol 600, polypropylene glycol 1000, gathers Propylene glycol 1500 or polypropylene glycol 2000.
4. total synthesis water-base cutting fluid as claimed in claim 3, it is characterized in that the specification of the aliphatic amine polyoxyethylene ether is excellent It is selected as AC1210 or AC1215, the preferred polypropylene glycol 1000 of polypropylene glycol.
5. total synthesis water-base cutting fluid as claimed in claim 3, it is characterized in that the water content of the cutting fluid be 20%~ 99% (wt).
6. total synthesis water-base cutting fluid as claimed in claim 3, it is characterized in that the water content of the cutting fluid is preferably 95% ~99%.
CN201811026319.6A 2018-09-04 2018-09-04 A kind of total synthesis water-base cutting fluid Pending CN108977264A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023209144A1 (en) 2022-04-29 2023-11-02 Totalenergies Onetech Aqueous lubricant for metalworking

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Publication number Priority date Publication date Assignee Title
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FR3135092A1 (en) * 2022-04-29 2023-11-03 Totalenergies Onetech AQUEOUS LUBRICANT FOR METAL WORKING

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