CN107574001A - Water base lubricant for food filling production line - Google Patents
Water base lubricant for food filling production line Download PDFInfo
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- CN107574001A CN107574001A CN201710939288.2A CN201710939288A CN107574001A CN 107574001 A CN107574001 A CN 107574001A CN 201710939288 A CN201710939288 A CN 201710939288A CN 107574001 A CN107574001 A CN 107574001A
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Abstract
For the water base lubricant of food filling production line, it is characterized in that the lubricant is composed of the following components：It is branched the parts by weight of 13 carbon Guerbet alcohol APEO 35；Polysorbate40 or the parts by weight of polysorbate60 35；The parts by weight of oleoyl triethanol amine 0.7~1.5；The parts by weight of propane diols atactic polyether (PPE) 7~15；The parts by weight of polyethylene glycol 35, the degree of polymerization of the polyethylene glycol is 400~2000；The weight ratio of water, the water and other all components sums is 3~3.5.
Description
Technical field
The present invention relates to the lubricant of lubricant, more particularly, to food cans assembling production lines.
Background technology
In existing food filling production line, the movements of food containers by conveyer belt automatic control, continuously run.Its is defeated
Band generally stainless steel flat plate chain is sent, must be using automatic spray come to stainless steel flat plate chain in order to ensure production line smoothness
It is lubricated.And there is higher stability in hard water, restraining and sterilizing bacteria, foam characteristic, crack resistance and low temperature pumpmg quality.In
State patent CN200710033004X discloses the water base lubricant for food filling production line, using triethanolamine oleate, three
The compositions such as monoethanolamine, although the document this point out its provide water base lubricant have higher stability in hard water, restraining and sterilizing bacteria,
Foam characteristic, crack resistance and low temperature pumpmg quality, but improved constantly with the running speed of high-speed canning system in recent years, its property
It can not meet the requirement of high-speed canning system, and in fact, in above-mentioned properties, most important is exactly lubricity
Can, the prescription of various water base lubricants is researched and developed on the basis of greasy property after improving spray.
The tribological Properties of Chinese document --- propane diols polyethers and the oleoyl triethanol amine compounding aqueous solution are (yellow precious
Into, Beijing Jiaotong University's Specialized Master Degree paper, in June, 2015) in disclose using propane diols polyethers and the ethanol of oleoyl three
The water base lubricant of amine compounding, but the as shown by data disclosed in the document, when the concentration of combination solution reaches 5-10% its
Lubricant effect is ideal, but in actual applications, in order to adapt to the requirement of high-speed production lines and reduce use cost, typically all
Need row coating again after lubricant stoste is diluted into 100-200 times.Therefore a kind of new food filling that can be applied to is provided to give birth to
The water base lubricant of producing line turns into urgent problem to be solved in the prior art.
The content of the invention
To solve the problems of the prior art, the technical solution adopted by the present invention is：
The water base lubricant for food filling production line is provided, it is characterized in that the lubricant is by following components group
Into：It is branched 13 carbon Guerbet alcohol APEO 3-5 parts by weight；Polysorbate40 or polysorbate60 3-5 parts by weight；The ethanol of oleoyl three
The parts by weight of amine 0.7~1.5；The parts by weight of propane diols atactic polyether (PPE) 7~15；Polyethylene glycol 3-5 parts by weight, the poly- second two
The degree of polymerization of alcohol is 400~2000；The weight ratio of water, the water and other all components sums is 3~3.5；The collateralization
The molecular formula of 13 carbon Guerbet alcohol APEOs is as follows：
RO(GH2CH2O)xH；
R=iso-C13H27, x=8,9 or 10.
The described water base lubricant for food filling production line, it is characterized in that it is preferred that propane diols atactic polyether 9-11 weights
Measure part, the parts by weight of oleoyl triethanol amine 0.9~1.1.
The described water base lubricant for food filling production line, it is characterized in that the water is deionized water.
The described water base lubricant for food filling production line, it is characterized in that the specification of the propane diols atactic polyether
For PPE-1500.
The described water base lubricant for food filling production line, it is characterized in that it is preferred that polysorbate60.
The described water base lubricant for food filling production line, it is characterized in that the polyethylene glycol is preferably poly- second two
Alcohol 2000.
The described water base lubricant for food filling production line, it is characterized in that 13 carbon Guerbet alcohols of the collateralization
APEO is preferably in BASF Lutensol TO8, BASF Lutensol TO9, BASF Lutensol TO10
It is one or more of.
The described water base lubricant for food filling production line, its speciality are that the compound method of the lubricant is,
The polyethylene glycol of recipe quantity is dissolved in recipe quantity water and obtains polyglycol solution, by oleoyl triethanol amine, propane diols atactic polyether,
Be branched 13 carbon Guerbet alcohol APEOs, polysorbate40 or polysorbate60 mixing after under stirring add polyethylene glycol it is molten
Liquid, continue stirring until homogeneous produce.
Provided by the present invention for the water base lubricant of food filling production line, document report propane diols polyethers with
On the basis of oleoyl triethanol amine compounding water base lubricant, being found surprisingly that, which increases a small amount of carbon Guerbet alcohol of collateralization 13, gathers
After oxygen vinethene, polyethylene glycol, polysorbate40 or polysorbate60, the performance of water base lubricant can be significantly improved, will especially lubricated
After agent high dilution, additionally it is possible to keep higher greasy property, it is can apply to the high speed food that new development in recent years goes out
Filling production lines.When carrying out option screening it was found that preferable polyethylene glycol 2000 and polysorbate60 can be significantly improved more
The greasy property of lubricant.In addition in experimenting, we find out that, the polyethylene glycol that only adds in the range of recipe quantity of the present invention, branch
The carbon Guerbet alcohol APEO of chainization 13, polysorbate40 or polysorbate60 can just significantly improve the greasy property of lubricant, due to
The raw material that water base lubricant provided by the invention uses is nontoxic water-soluble component, can be used for food filling production line.
Embodiment
With reference to specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to
This.
The water-base chain lubricant provided in the embodiment of the present invention is prepared in the following ways
1) polyethylene glycol (PET) of recipe quantity is dissolved in recipe quantity water and obtains polyglycol solution
2) recipe quantity oleoyl triethanol amine (TO), propane diols atactic polyether (PPE), 13 carbon Guerbet alcohols of collateralization are gathered
Oxygen vinethene mixes with polysorbate40 or polysorbate60
3) mixed liquor of step 2) is added in polyglycol solution under stirring, lasting stirring turns into transparent and homogeneous
Liquid.
Water is deionized water, and the weight ratio of deionized water and other left and right component sums is unified for 3.3.
Be branched 13 carbon Guerbet alcohol APEOs for BASF Lutensol TO8, Lutensol TO9,
One or more in Lutensol TO10.
The PPE specifications are PPE-1500.
Example formulations see the table below (unit：g)
It is standby afterwards that the lubricant that embodiment 1~12 is obtained each dilutes 30 and 200 times (v/v) with deionized water.Separately take
Oleoyl triethanol amine (TO) is with propane diols atactic polyether (PPE) according to 1:9 weight after mixing than adding 3.3 times of weight deionizations
As a comparison case 1 after water dilution.
Detect the test of the lubricity of embodiment 1.
Carry out simulating the measure of lubricity on four-ball extreme pressure tester.The grinding defect diameter of ball is measured, grinding defect diameter is smaller
Show that greasy property is better.
Method:Steel ball is separately fixed in the upper ball base and oil box of four-ball tester.Lubricant is entered by certain volume multiple
Poured into after row dilution in oil box, allow it to cover steel ball and reach the joint of pressure ring and nut.The oil box for installing sample and ball
It is placed in below the upper ball base of four-ball extreme pressure tester to center, circular disk rack is put among lubricating cup and lead, releases loading
Simultaneously the load (0kg or 10kg) as defined in is added on ball lever.After loading, start motor and press stopwatch simultaneously, from starting to
The experimental period of closing is 10 seconds.Every time after experiment, the grinding defect diameter of the both direction in length and breadth of any one steel ball in measuring box,
Average..Wherein steel ball used in experiment is the GCr15 steel balls of II class precisions, and diameter 12.7mm, HRC (Rockwell hardness) are 64-
66, produced and provided by Shanghai Steel Ball Plant
Grinding defect diameter result such as following table (unit under different experimental conditions：mm)
It is above-mentioned test result indicates that, using lubricant provided in an embodiment of the present invention, the equal table when being lubricated property is tested
Reveal preferable performance, and when lubricant is diluted into 200 times, its greasy property is still good, and from above-mentioned data
As can be seen that using the greasy property for the embodiment 2,3,6,7 being preferably formulated apparently higher than other embodiment.Comparative example 1~3
Greasy property be significantly lower than each embodiment, illustrate embodiment by optimization formula, be greatly improved based on PPE and TO
The greasy property of lubricant after dilution.Wherein comparative example 2~4 is added without 13 carbon of collateralization respectively on the basis of embodiment 6
Guerbet alcohol APEO, polysorbate60 and PET6000, this hair is can be seen that from the experimental data for combining comparative example 2~4
Each component in the side of daylight can produce the lubricant effect that synergy improves lubricant when being lubricated performance test.
Claims (6)
1. for the water base lubricant of food filling production line, it is characterized in that the lubricant is composed of the following components：
It is branched 13 carbon Guerbet alcohol APEO 3-5 parts by weight；Polysorbate40 or polysorbate60 3-5 parts by weight；The second of oleoyl three
The parts by weight of hydramine 0.7~1.5；The parts by weight of propane diols atactic polyether (PPE) 7~15；Polyethylene glycol 3-5 parts by weight, the poly- second
The degree of polymerization of glycol is 400~2000；The weight ratio of water, the water and other all components sums is 3~3.5；The side chain
The molecular formula for changing 13 carbon Guerbet alcohol APEOs is as follows：
RO(CH2CH2O)xH；
R=iSO-C13H27, x=8,9 or 10.
2. it is used for the water base lubricant of food filling production line as claimed in claim 1, it is characterized in that it is preferred that propane diols is random
Polyethers 9-11 parts by weight, the parts by weight of oleoyl triethanol amine 0.9~1.1.
3. as claimed in claim 1 or 2 be used for food filling production line water base lubricant, it is characterized in that the propane diols without
The specification for advising polyethers is PPE-1500.
4. it is used for the water base lubricant of food filling production line as claimed in claim 1 or 2, it is characterized in that it is preferred that polysorbate60.
5. it is used for the water base lubricant of food filling production line as claimed in claim 1 or 2, it is characterized in that the polyethylene glycol
Preferably polyethylene glycol 2000.
6. it is used for the water base lubricant of food filling production line as claimed in claim 5, it is characterized in that 13 carbon of the collateralization
Guerbet alcohol APEO is preferably BASF Lutensol TO8, BASF Lutensol TO9, BASF
One or more in Lutensol TO10.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710939288.2A CN107574001B (en) | 2017-10-11 | 2017-10-11 | Water base lubricant for food filling production line |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710939288.2A CN107574001B (en) | 2017-10-11 | 2017-10-11 | Water base lubricant for food filling production line |
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| CN107574001A true CN107574001A (en) | 2018-01-12 |
| CN107574001B CN107574001B (en) | 2018-10-12 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977264A (en) * | 2018-09-04 | 2018-12-11 | 罗粉继 | A kind of total synthesis water-base cutting fluid |
Citations (4)
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|---|---|---|---|---|
| CN102482603A (en) * | 2009-09-01 | 2012-05-30 | 慕尼黑克吕伯尔润滑器两合公司 | Water-based lubricants |
| CN105886094A (en) * | 2016-04-22 | 2016-08-24 | 广州泰晟生物科技有限公司 | Water-based chain plate lubricating agent for soft beverage packages and preparation method of water-based chain plate lubricating agent |
| CN106190522A (en) * | 2016-07-28 | 2016-12-07 | 中国科学院兰州化学物理研究所 | As organic salt that water lubrication additive uses and preparation method thereof |
| CN106497667A (en) * | 2016-11-01 | 2017-03-15 | 南通科星化工有限公司 | A kind of water-base cutting fluid and preparation method thereof |
-
2017
- 2017-10-11 CN CN201710939288.2A patent/CN107574001B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102482603A (en) * | 2009-09-01 | 2012-05-30 | 慕尼黑克吕伯尔润滑器两合公司 | Water-based lubricants |
| CN105886094A (en) * | 2016-04-22 | 2016-08-24 | 广州泰晟生物科技有限公司 | Water-based chain plate lubricating agent for soft beverage packages and preparation method of water-based chain plate lubricating agent |
| CN106190522A (en) * | 2016-07-28 | 2016-12-07 | 中国科学院兰州化学物理研究所 | As organic salt that water lubrication additive uses and preparation method thereof |
| CN106497667A (en) * | 2016-11-01 | 2017-03-15 | 南通科星化工有限公司 | A kind of water-base cutting fluid and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 黄宝成: "丙二醇聚醚与油酰三乙醇胺复配水溶液的摩擦学性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅱ辑》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977264A (en) * | 2018-09-04 | 2018-12-11 | 罗粉继 | A kind of total synthesis water-base cutting fluid |
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Effective date of registration: 20201222 Address after: 224000 23 / F (b), Huidu building, Xindu West Road, Yandu District, Yancheng City, Jiangsu Province Patentee after: Jiangsu Yandu Baiming Agricultural Co.,Ltd. Address before: Tianjin Agricultural College, 22 Jinjing Road, Xiqing District, Tianjin, 300384 Patentee before: Tianjin Agricultural University |
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