CN108977174A - A kind of dust suppressant - Google Patents
A kind of dust suppressant Download PDFInfo
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- CN108977174A CN108977174A CN201811104311.7A CN201811104311A CN108977174A CN 108977174 A CN108977174 A CN 108977174A CN 201811104311 A CN201811104311 A CN 201811104311A CN 108977174 A CN108977174 A CN 108977174A
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Abstract
The invention discloses a kind of dust suppressants, belong to dust suppressant technical field.The present invention is using luffa as raw material, the absorption property that the characteristics of making full use of its three-dimensional spongelike structure and polyacrylamide have, open the duct between few fibers beam, it is allowed to become coarse, in large intestine villiform pattern, section is loose porous, improve adhesion effect, the dopamine of addition can be aoxidized by water-soluble oxygen, occur to can express high affine adhesive attraction from poly- cross-linking reaction, improve whole biocompatibility and degradation property, for soil or plant absorption, dust is gradually embedded ground or is stable at other environment, achievees the effect that stablize for a long time dirt admittedly;The effects of pretreatment chitosan liquid and sodium alginate in the compound adjuvant of the present invention, good overall effect is formed, and can formed a film in dust surface cure after natural drying, prevents the generation of fugitive dust.The present invention solves the problems, such as that the dust suppression low efficiency of currently used dust suppressant, duration are short.
Description
Technical field
The invention belongs to dust suppressant technical fields, and in particular to a kind of dust suppressant.
Background technique
As the dust on the roads of one of the source of atmospheric pollution, existing governing measure is mainly street cleaning and watering is most often
Dust-suppression method is sprayed by road pavement, increases pavement humidity to inhibit dust on the roads, or nothing is added in sprinkling truck
Machine salt dust suppressant extends anti-dust effect with this to increase the road surface wet time.Its main function is by wet
Increase the water capacity of dried dust, density increases and is bonded to biggish particle.That sprinkles water is easy to operate, but winter is easy knot
Ice, summer evaporation is fast, and effective dust suppression time is insufficient half an hour, and water consumption is big.Micronic dust content after moisture evaporation can increase severely
600%.
Road surface watering and lowering dust can inhibit fugitive dust in the case where road surface is wet, however after moisture evaporation, and dust again can be
Wheel roll and air-flow under the action of enter in atmosphere, i.e., anti-dust effect is unsustainable after road surface is dry.It is long-term to keep road surface
It is wet to greatly increase cost of labor and water consumption, while increasing sprinkling frequency and can also improve the dosage of fossil fuel.Inorganic salts
Class dust suppressant (CaCl2、MgCl2Deng) cheap, it is widely used as Road dust suppressant, but can excessively lead using such dust suppressant
Cause the negative consequences such as the salinization of soil, road of mating formation corrosion.
Chemical dust suppressant it is various in style, the primary raw material for compounding has inorganic low molecular compound, organic low molecular
Compound and high-molecular compound.The cost of the inorganic matters such as calcium chloride, magnesium chloride, aluminium chloride, sodium sulphate, waterglass is low, uses
Conveniently, antifreezing effect is good, but anti-dust effect is not good enough, corrodes metal, contaminated soil, intolerant to rain-out.Ethylene glycol, a contracting diethyl
The organic matters such as glycol, glycerine can infiltrate, be adsorbed in dust particles surface, have and absorb moisture, keep moisture and reduce solidifying
The effect of solid point, but have the shortcomings that durability is poor, it can not solve the problems, such as natural evaporation and rain-out.Cinder is oily, wooden slag is oily,
Shale residual oil, light oil, heavy oil, coal tar, reconciliation residual oil, soft resin and fluxed bitumen still fall within low molecule organic matter, to powder
Dirt particle surface has preferable infiltration, absorption and a degree of film forming coating function, but there are apparent corrosion resistance and suppressions
The disadvantages of dirt low efficiency.Therefore a kind of dust suppressant that dust suppression is high-efficient need to be developed.
Summary of the invention
The technical problems to be solved by the invention: short for the dust suppression low efficiency of currently used dust suppressant, duration
The problem of, a kind of dust suppressant is provided.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of dust suppressant, including following component: 20 ~ 30 parts of plantain starch, 5 ~ 8 parts of molar substitution degrees, 3 ~ 7 parts of dispersing agents, 2 ~ 5
Part preservative, 1 ~ 4 part of defoaming agent, 40 ~ 60 parts of water, further includes: 25 ~ 40 parts of compound dust suppression material, 12 ~ 20 parts of composite auxiliary materials.
The preparation method of the compound dust suppression material, includes the following steps:
(1) it takes luffa to pulverize and sieve, takes sieving particle boiling water blanching, filter out be added to 6 ~ 10 times of granular mass of sieving while hot
NaOH solution is mixed, and is stored at room temperature, and filters, and in 35 ~ 60 DEG C, takes filter residue 6:1 ~ 3:12 in mass ratio ~ 20 that hexichol first is added
Ketone, ethanol solution are mixed, and obtain mixture, in a nitrogen atmosphere, 6:0.1:3:15 ~ 25 take mixture, (NH in mass ratio4)2Fe(SO4)2, acrylic acid, ethanol solution mixing, ultraviolet radiation graft processing, discharging, obtain base-material, take base-material with mix washing lotion clean,
Combined processing luffa is obtained, it is spare;
(2) in 40 ~ 60 DEG C, 3:1 ~ 2:40 ~ 60 take multi-walled carbon nanotube, Dopamine hydrochloride, deionized water mixing to stir in mass ratio
It mixes, 4 ~ 7 times of multi-walled carbon nanotube quality of reagent A mixing is added, ultrasonication is stirred at room temperature, and centrifugal treating takes centrifugation object
It is dry, dried object is obtained, takes dried object 5 ~ 8:1:30 in mass ratio ~ 50 that triethylamine, toluene is added in ice-water bath stirring, drying is added
The bromo isobutyl acylbromide of amount of substance 15 ~ 20%, stirring, obtains brominated product, takes brominated product 1:0.08:20 ~ 30:0.3 in mass ratio
Copper bromide, reagent B is added, styrene benzene sulfonic acid sodium salt is mixed, in 35 ~ 55 DEG C, ultrasonication is stood, and centrifugation takes centrifugation object
Washing, obtains composite modified carbon nanomaterial;
(3) 5 ~ 8:1:0.1 in mass ratio takes spare combined processing luffa, composite modified carbon nanomaterial, polyvinyl pyrrole
Alkanone mixing, ball milling obtain ball milling material, and the sea-mussel mucin for taking ball milling material that 4 ~ 8 times of ball milling material quality is added mixes to get compound suppression
Dirt material.
Mixing washing lotion in the step (1): 3:16 ~ 25 take HCl solution, ethanol solution mixing to get mixed in mass ratio
Close washing lotion.
Reagent A in the step (2): 7 ~ 12:2 in mass ratio take Tris-HCl buffer, sodium citrate mixing to get
Reagent A.
Reagent B in the step (3): 5:2 ~ 4 take dimethylformamide, acetonitrile mixing to get reagent B by volume.
The preparation of the composite auxiliary material: in 30 ~ 45 DEG C, in mass ratio 1:1 ~ 3:12 ~ 18 take laureth sodium sulfovinate,
Dodecyldimethylammonium hydroxide inner salt, water are mixed, and obtain mixture, take mixture 8 ~ 15:1:1 in mass ratio ~ 3:0.1 that sea is added
Mosanom, pretreatment chitosan liquid, dimethicone mixing, shearing dispersion is to get composite auxiliary material.
The pretreatment chitosan liquid: in 30 ~ 50 DEG C, 1:0.1:20 ~ 40 take chitosan, gelatin, water mixing in mass ratio
Stirring, heat preservation are stood, and obtain mixed liquid, take mixed liquid 6 ~ 10:1 in mass ratio that soybean lecithin mixing is added to get pretreatment chitosan
Liquid.
The dispersing agent: 1:3 ~ 6 take the double stearoylketene amine mixing of microcrystalline wax, vinyl to get dispersing agent in mass ratio.
The preservative: 5:1 ~ 3 take sodium benzoate, potassium sorbate mixing to get preservative in mass ratio.
The defoaming agent: polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether, appointing in dimethyl silicone polymer
It anticipates one kind.
The present invention is compared with other methods, and advantageous effects are:
(1) what the characteristics of present invention is using luffa as raw material, makes full use of its three-dimensional spongelike structure and polyacrylamide had
Absorption property, the photosensitizer benzophenone of addition capture the hydrogen on luffa surface and form macromolecular certainly under ultraviolet light
By base, and then cause the graft reaction with acrylic acid, open the duct between few fibers beam, be allowed to become coarse, is in large intestine
Villiform pattern, section is loose porous, improves adhesion effect, plays good carrier function to other ingredients, meanwhile, it can be to powder
The ion exchange that dirt generates electrostatic attraction, is retained under humidification simultaneously, so that this system has good suction-operated, addition
Dopamine can be aoxidized by water-soluble oxygen, occur to can express high affine adhesive attraction, be oxidized first from poly- cross-linking reaction
For DOPA quinone, then Semiquinone Radicals are generated after aoxidizing, be finally cross-linked to form poly-dopamine, cooperation pretreatment chitosan liquid can shape
At three-dimensional crosslinked network, absorption package can be carried out to dust after use, and a small amount of mussel mucin added can also assist handing over
Connection forms microbiological skeleton, and whole biocompatibility and degradation property can be improved, and is soil or plant absorption, by powder
Dirt is gradually embedded ground or is stable at other environment, achievees the effect that stablize for a long time dirt admittedly;
(2) polymerizable to form good crosslinking the effects of pretreatment chitosan liquid and sodium alginate in the compound adjuvant of the present invention
Reticular structure, chitosan contained therein, Lecithin Content charge density are big, and stronger affinity can be generated between ion, is made
Internal compound dust suppression material and the interaction of other ingredients, form good overall effect, by coalescence, cohere the effects of can be fast
Speed is captured and by particle dust and is firmly adsorbed, and can be formed a film in dust surface cure after natural drying, and the hair of fugitive dust is prevented
It is raw.
Specific embodiment
Mixing washing lotion: 3:16 ~ 25 ethanol solution that takes the HCl solution of concentration 0.1mol/L, volume fraction 70% in mass ratio
Mixing is to get mixing washing lotion.
Dispersing agent: 1:3 ~ 6 take the double stearoylketene amine mixing of microcrystalline wax, vinyl to get dispersing agent in mass ratio.
Defoaming agent: polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether, any one in dimethyl silicone polymer
Kind.
Preservative: 5:1 ~ 3 take sodium benzoate, potassium sorbate mixing to get preservative in mass ratio.
Reagent A: 7 ~ 12:2 in mass ratio takes the Tris-HCl buffer that pH is 7.8 ~ 8.2, sodium citrate to mix to get examination
Agent A.
Reagent B: 5:2 ~ 4 take dimethylformamide, acetonitrile mixing to get reagent B by volume.
Pre-process chitosan liquid: in 30 ~ 50 DEG C, 1:0.1:20 ~ 40 take chitosan, gelatin, deionized water mixed in mass ratio
It closes, with 400 ~ 600r/min, 40 ~ 60min of magnetic agitation, heat preservation stands 1 ~ 3h, obtains mixed liquid, mixed liquid 6 ~ 10:1 in mass ratio is taken to add
Enter soybean lecithin mixing to get pretreatment chitosan liquid.
The preparation method of compound dust suppression material, includes the following steps:
(1) it takes luffa to crushed 80 meshes in pulverizer, takes sieving particle after 3 ~ 6min of boiling water blanching, filter out addition while hot
To sieving 6 ~ 10 times of granular mass concentration 0.01mol/L NaOH solution mixing, with 400 ~ 700r/min magnetic agitation 30 ~
55min is stored at room temperature 1 ~ 3h, filtering, in 35 ~ 60 DEG C, takes filter residue 6:1 ~ 3:12 in mass ratio ~ 20 that benzophenone, volume is added
The ethanol solution of score 70% mixes, and with 500 ~ 800r/min, 35 ~ 60min of magnetic agitation, obtains mixture, in a nitrogen atmosphere, presses
Mass ratio 6:0.1:3:15 ~ 25 take mixture, (NH4)2Fe(SO4)2, acrylic acid, volume fraction be 40% ethanol solution mix,
It is placed in ultraviolet radiation graft reactor and 100 ~ 140min is reacted with the uv power of 100W, discharging obtains base-material, and base-material is taken to mix
Washing lotion is cleaned 2 ~ 4 times, and combined processing luffa is obtained, spare;
(2) in 40 ~ 60 DEG C, 3:1 ~ 2:40 ~ 60 in mass ratio take multi-walled carbon nanotube, Dopamine hydrochloride, deionized water in container
4 ~ 7 times of multi-walled carbon nanotube quality of reagent A mixing is added after 700 ~ 1000r/min magnetic agitation, 30 ~ 55min in mixing,
It moves to supersonic oscillations instrument and 8 ~ 15min is handled with 45 ~ 55kHz frequency ultrasonic wave, then room temperature is with 350 ~ 600r/min magnetic agitation
After 25 ~ 60min, with 3000 ~ 4000r/min, 6 ~ 10min of centrifugal treating, takes centrifugation object in 50 ~ 70 DEG C of 3 ~ 5h of oven drying, obtain dry
Dry object takes dried object 5 ~ 8:1:30 in mass ratio ~ 50 that triethylamine, toluene is added and stirs 20 ~ 45min in ice-water bath, drying is added
The bromo isobutyl acylbromide of amount of substance 15 ~ 20% obtains brominated product with 400 ~ 600r/min, 1 ~ 3h of magnetic agitation, take brominated product by
Mass ratio 1:0.08:20 ~ 30:0.3 is added copper bromide, reagent B, mixes to styrene benzene sulfonic acid sodium salt, in 35 ~ 55 DEG C, with 55 ~
65kHz frequency ultrasonic wave handle 12 ~ 20min after, stand 1 ~ 3h, move to centrifuge with 2500 ~ 4000r/min centrifugation 10 ~
15min takes centrifugation object to be washed with water 2 ~ 4 times, obtains composite modified carbon nanomaterial;
(3) 5 ~ 8:1:0.1 in mass ratio takes spare combined processing luffa, composite modified carbon nanomaterial, polyvinyl pyrrole
Alkanone is mixed in ball grinder, with 350 ~ 550r/min, 2 ~ 4h of ball milling, obtains ball milling material, takes ball milling material that 4 ~ 8 times of ball milling material quality is added
Mass fraction 0.1% sea-mussel mucin be uniformly mixed to get compound dust suppression material.
The preparation of composite auxiliary material: in 30 ~ 45 DEG C, 1:1 ~ 3:12 ~ 18 in mass ratio take laureth sodium sulfovinate, 12
Alkyl dimethyl betaine, deionized water are mixed in container, with 350 ~ 550r/min, 30 ~ 55min of magnetic agitation, obtain mixture,
Take mixture 8 ~ 15:1:1 in mass ratio ~ 3:0.1 that sodium alginate, pretreatment chitosan liquid, dimethicone mixing is added, with
8 ~ 15min is to get composite auxiliary material for 2000 ~ 3000r/min shearing dispersion.
A kind of dust suppressant, according to the mass fraction, including following component: 20 ~ 30 parts of plantain starch, 5 ~ 8 parts of ethoxy Guars
Glue, 3 ~ 7 parts of dispersing agents, 2 ~ 5 portions of preservatives, 1 ~ 4 part of defoaming agent, 40 ~ 60 parts of water, 25 ~ 40 parts of compound dust suppression material, 12 ~ 20 parts it is multiple
Close auxiliary material.
A kind of preparation method of dust suppressant, includes the following steps:
(1) according to the mass fraction, including following component: 20 ~ 30 parts of plantain starch, 5 ~ 8 parts of molar substitution degrees, 3 ~ 7 parts of dispersions
Agent, 2 ~ 5 portions of preservatives, 1 ~ 4 part of defoaming agent, 40 ~ 60 parts of water, 25 ~ 40 parts of compound dust suppression material, 12 ~ 20 parts of composite auxiliary materials;
(2) in 45 ~ 55 DEG C, plantain starch, molar substitution degree, dispersing agent, water, compound dust suppression material is first taken to mix in reaction kettle,
With 400 ~ 600r/min, 40 ~ 55min of magnetic agitation, composite auxiliary material, preservative, defoaming agent mixing are added, is cooled to 20 ~ 35
DEG C, with 700 ~ 1000r/min magnetic agitation, 1 ~ 3h to get dust suppressant.
Mixing washing lotion: 3:16 in mass ratio takes the ethanol solution of the HCl solution of concentration 0.1mol/L, volume fraction 70% mixed
It closes to get mixing washing lotion.
Dispersing agent: 1:3 in mass ratio takes the double stearoylketene amine mixing of microcrystalline wax, vinyl to get dispersing agent.
Defoaming agent: polypropylene glycerol aether.
Preservative: 5:1 in mass ratio takes sodium benzoate, potassium sorbate mixing to get preservative.
Reagent A: 7:2 in mass ratio takes the Tris-HCl buffer that pH is 7.8, sodium citrate to mix to get reagent A.
Reagent B: 5:2 takes dimethylformamide, acetonitrile mixing to get reagent B by volume.
Pre-process chitosan liquid: in 30 DEG C, 1:0.1:20 in mass ratio takes chitosan, gelatin, deionized water mixing, with
400r/min magnetic agitation 40min, heat preservation stand 1h, obtain mixed liquid, take mixed liquid 6:1 in mass ratio that soybean lecithin mixing is added,
Up to pretreatment chitosan liquid.
The preparation method of compound dust suppression material, includes the following steps:
(1) it takes luffa to crushed 80 meshes in pulverizer, takes sieving particle after boiling water blanching 3min, filter out be added to while hot
The NaOH solution mixing of the concentration 0.01mol/L of 6 times of granular mass of sieving, with 400r/min magnetic agitation 30min, is stored at room temperature
1h, filtering take filter residue 6:1:12 in mass ratio that the ethanol solution mixing of benzophenone, volume fraction 70% is added in 35 DEG C, with
500r/min magnetic agitation 35min, obtains mixture, and in a nitrogen atmosphere, 6:0.1:3:15 in mass ratio takes mixture, (NH4)2Fe(SO4)2, acrylic acid, volume fraction be 40% ethanol solution mix, be placed in ultraviolet radiation graft reactor with the ultraviolet of 100W
Optical power reacts 100min, and discharging obtains base-material, takes base-material to be cleaned 2 times with mixing washing lotion, obtains combined processing luffa, spare;
(2) in 40 DEG C, 3:1:40 in mass ratio takes multi-walled carbon nanotube, Dopamine hydrochloride, deionized water to mix in container, with
After 700r/min magnetic agitation 30min, be added 4 times of multi-walled carbon nanotube quality reagent A mixing, move to supersonic oscillations instrument with
After 45kHz frequency ultrasonic wave handles 8min, then room temperature is with 350r/min magnetic agitation 25min, with 3000r/min centrifugal treating
6min takes centrifugation object in 50 DEG C of oven drying 3h, obtains dried object, takes dried object 5:1:30 in mass ratio that triethylamine, toluene is added
20min is stirred in ice-water bath, the bromo isobutyl acylbromide that dried object quality 15% is added obtains bromination with 400r/min magnetic agitation 1h
Product takes brominated product 1:0.08:20:0.3 in mass ratio that copper bromide, reagent B is added, mixes to styrene benzene sulfonic acid sodium salt, in
35 DEG C, with 55kHz frequency ultrasonic wave handle 12min after, stand 1h, move to centrifuge with 2500r/min be centrifuged 10min, take from
Heart object is washed with water 2 times, obtains composite modified carbon nanomaterial;
(3) 5:1:0.1 in mass ratio takes spare combined processing luffa, composite modified carbon nanomaterial, polyvinylpyrrolidine
Ketone is mixed in ball grinder, with 350r/min ball milling 2h, obtains ball milling material, takes ball milling material that the mass fraction of 4 times of ball milling material quality is added
0.1% sea-mussel mucin is uniformly mixed to get compound dust suppression material.
The preparation of composite auxiliary material: in 30 DEG C, 1:1:12 in mass ratio takes laureth sodium sulfovinate, dimethyl
Base glycine betaine, deionized water are mixed in container, with 350r/min magnetic agitation 30min, are obtained mixture, are taken mixture in mass ratio
Sodium alginate, pretreatment chitosan liquid, dimethicone mixing is added in 8:1:1:0.1, shears dispersion 8min with 2000r/min,
Up to composite auxiliary material.
A kind of dust suppressant, according to the mass fraction, including following component: 20 parts of plantain starch, 5 parts of molar substitution degrees, 3 parts
Dispersing agent, 2 portions of preservatives, 1 part of defoaming agent, 40 parts of water, 25 parts of compound dust suppression material, 12 parts of composite auxiliary materials.
A kind of preparation method of dust suppressant, includes the following steps:
Including following component (1) according to the mass fraction: 20 parts of plantain starch, 5 parts of molar substitution degrees, 3 parts of dispersing agents, 2 parts it is anti-
Rotten agent, 1 part of defoaming agent, 40 parts of water, 25 parts of compound dust suppression material, 12 parts of composite auxiliary materials;
(2) in 45 DEG C, plantain starch, molar substitution degree, dispersing agent, water, compound dust suppression material is first taken to mix in reaction kettle, with
400r/min magnetic agitation 40min adds composite auxiliary material, preservative, defoaming agent mixing, 20 DEG C is cooled to, with 700r/min
Magnetic agitation 1h is to get dust suppressant.
Mixing washing lotion: 3:20 in mass ratio takes the ethanol solution of the HCl solution of concentration 0.1mol/L, volume fraction 70% mixed
It closes to get mixing washing lotion.
Dispersing agent: 1:5 in mass ratio takes the double stearoylketene amine mixing of microcrystalline wax, vinyl to get dispersing agent.
Defoaming agent: polyoxyethylene polyoxypropylene glycerin ether.
Preservative: 5:2 in mass ratio takes sodium benzoate, potassium sorbate mixing to get preservative.
Reagent A: 11:2 in mass ratio takes the Tris-HCl buffer that pH is 8, sodium citrate to mix to get reagent A.
Reagent B: 5:2 takes dimethylformamide, acetonitrile mixing to get reagent B by volume.
Pre-process chitosan liquid: in 40 DEG C, 1:0.1:30 in mass ratio takes chitosan, gelatin, deionized water mixing, with
500r/min magnetic agitation 50min, heat preservation stand 2h, obtain mixed liquid, take mixed liquid 8:1 in mass ratio that soybean lecithin mixing is added,
Up to pretreatment chitosan liquid.
The preparation method of compound dust suppression material, includes the following steps:
(1) it takes luffa to crushed 80 meshes in pulverizer, takes sieving particle after boiling water blanching 5min, filter out be added to while hot
The NaOH solution mixing of the concentration 0.01mol/L of 8 times of granular mass of sieving, with 500r/min magnetic agitation 40min, is stored at room temperature
2h, filtering take filter residue 6:2:18 in mass ratio that the ethanol solution mixing of benzophenone, volume fraction 70% is added in 50 DEG C, with
600r/min magnetic agitation 50min, obtains mixture, and in a nitrogen atmosphere, 6:0.1:3:20 in mass ratio takes mixture, (NH4)2Fe(SO4)2, acrylic acid, volume fraction be 40% ethanol solution mix, be placed in ultraviolet radiation graft reactor with the ultraviolet of 100W
Optical power reacts 120min, and discharging obtains base-material, takes base-material to be cleaned 3 times with mixing washing lotion, obtains combined processing luffa, spare;
(2) in 50 DEG C, 3:1.5:50 in mass ratio takes multi-walled carbon nanotube, Dopamine hydrochloride, deionized water to mix in container, with
After 800r/min magnetic agitation 45min, be added 5 times of multi-walled carbon nanotube quality reagent A mixing, move to supersonic oscillations instrument with
After 50kHz frequency ultrasonic wave handles 12min, then room temperature is with 400r/min magnetic agitation 50min, with 3500r/min centrifugal treating
8min takes centrifugation object in 60 DEG C of oven drying 4h, obtains dried object, takes dried object 6:1:40 in mass ratio that triethylamine, toluene is added
35min is stirred in ice-water bath, the bromo isobutyl acylbromide that dried object quality 18% is added obtains bromination with 500r/min magnetic agitation 2h
Product takes brominated product 1:0.08:25:0.3 in mass ratio that copper bromide, reagent B is added, mixes to styrene benzene sulfonic acid sodium salt, in
45 DEG C, with 60kHz frequency ultrasonic wave handle 18min after, stand 2h, move to centrifuge with 3000r/min be centrifuged 12min, take from
Heart object is washed with water 3 times, obtains composite modified carbon nanomaterial;
(3) 6:1:0.1 in mass ratio takes spare combined processing luffa, composite modified carbon nanomaterial, polyvinylpyrrolidine
Ketone is mixed in ball grinder, with 450r/min ball milling 3h, obtains ball milling material, takes ball milling material that the mass fraction of 6 times of ball milling material quality is added
0.1% sea-mussel mucin is uniformly mixed to get compound dust suppression material.
The preparation of composite auxiliary material: in 40 DEG C, 1:2:16 in mass ratio takes laureth sodium sulfovinate, dimethyl
Base glycine betaine, deionized water are mixed in container, with 450r/min magnetic agitation 45min, are obtained mixture, are taken mixture in mass ratio
Sodium alginate, pretreatment chitosan liquid, dimethicone mixing is added in 12:1:2:0.1, is sheared and is dispersed with 2500r/min
13min is to get composite auxiliary material.
A kind of dust suppressant, according to the mass fraction, including following component: 25 parts of plantain starch, 6 parts of molar substitution degrees, 5 parts
Dispersing agent, 4 portions of preservatives, 3 parts of defoaming agents, 50 parts of water, 30 parts of compound dust suppression material, 18 parts of composite auxiliary materials.
A kind of preparation method of dust suppressant, includes the following steps:
Including following component (1) according to the mass fraction: 25 parts of plantain starch, 6 parts of molar substitution degrees, 5 parts of dispersing agents, 4 parts it is anti-
Rotten agent, 3 parts of defoaming agents, 50 parts of water, 30 parts of compound dust suppression material, 18 parts of composite auxiliary materials;
(2) in 50 DEG C, plantain starch, molar substitution degree, dispersing agent, water, compound dust suppression material is first taken to mix in reaction kettle, with
500r/min magnetic agitation 45min adds composite auxiliary material, preservative, defoaming agent mixing, 30 DEG C is cooled to, with 900r/min
Magnetic agitation 2h is to get dust suppressant.
Mixing washing lotion: 3:25 in mass ratio takes the ethanol solution of the HCl solution of concentration 0.1mol/L, volume fraction 70% mixed
It closes to get mixing washing lotion.
Dispersing agent: 1:6 in mass ratio takes the double stearoylketene amine mixing of microcrystalline wax, vinyl to get dispersing agent.
Defoaming agent: dimethyl silicone polymer.
Preservative: 5:3 in mass ratio takes sodium benzoate, potassium sorbate mixing to get preservative.
Reagent A: 12:2 in mass ratio takes the Tris-HCl buffer that pH is 8.2, sodium citrate to mix to get reagent A.
Reagent B: 5:4 takes dimethylformamide, acetonitrile mixing to get reagent B by volume.
Pre-process chitosan liquid: in 50 DEG C, 1:0.1:40 in mass ratio takes chitosan, gelatin, deionized water mixing, with
600r/min magnetic agitation 60min, heat preservation stand 3h, obtain mixed liquid, take mixed liquid 10:1 in mass ratio that soybean lecithin mixing is added,
Up to pretreatment chitosan liquid.
The preparation method of compound dust suppression material, includes the following steps:
(1) it takes luffa to crushed 80 meshes in pulverizer, takes sieving particle after boiling water blanching 6min, filter out be added to while hot
The NaOH solution mixing of the concentration 0.01mol/L of 10 times of granular mass of sieving, with 700r/min magnetic agitation 55min, room temperature is quiet
3h is set, is filtered, in 60 DEG C, takes filter residue 6:3:20 in mass ratio that the ethanol solution mixing of benzophenone, volume fraction 70% is added,
With 800r/min magnetic agitation 60min, obtain mixture, in a nitrogen atmosphere, 6:0.1:3:25 in mass ratio take mixture,
(NH4)2Fe(SO4)2, acrylic acid, volume fraction be 40% ethanol solution mix, be placed in ultraviolet radiation graft reactor with 100W's
Uv power reacts 140min, and discharging obtains base-material, takes base-material to be cleaned 4 times with mixing washing lotion, obtains combined processing luffa, standby
With;
(2) in 60 DEG C, 3:2:60 in mass ratio takes multi-walled carbon nanotube, Dopamine hydrochloride, deionized water to mix in container, with
After 1000r/min magnetic agitation 55min, 7 times of multi-walled carbon nanotube quality of reagent A mixing is added, moves to supersonic oscillations instrument
15min is handled with 55kHz frequency ultrasonic wave, then after room temperature is with 600r/min magnetic agitation 60min, at 4000r/min centrifugation
10min is managed, takes centrifugation object in 70 DEG C of oven drying 5h, obtains dried object, take dried object 8:1:50 in mass ratio that triethylamine, first is added
Benzene stirs 45min in ice-water bath, and the bromo isobutyl acylbromide that dried object quality 20% is added obtains bromine with 600r/min magnetic agitation 3h
Change product, take brominated product 1:0.08:30:0.3 in mass ratio that copper bromide, reagent B is added, mixes to styrene benzene sulfonic acid sodium salt,
In 55 DEG C, after handling 20min with 65kHz frequency ultrasonic wave, 3h is stood, centrifuge is moved to 4000r/min and is centrifuged 15min, take
Centrifugation object is washed with water 4 times, obtains composite modified carbon nanomaterial;
(3) 8:1:0.1 in mass ratio takes spare combined processing luffa, composite modified carbon nanomaterial, polyvinylpyrrolidine
Ketone is mixed in ball grinder, with 550r/min ball milling 4h, obtains ball milling material, takes ball milling material that the mass fraction of 8 times of ball milling material quality is added
0.1% sea-mussel mucin is uniformly mixed to get compound dust suppression material.
The preparation of composite auxiliary material: in 45 DEG C, 1:3:18 in mass ratio takes laureth sodium sulfovinate, dimethyl
Base glycine betaine, deionized water are mixed in container, with 550r/min magnetic agitation 55min, are obtained mixture, are taken mixture in mass ratio
Sodium alginate, pretreatment chitosan liquid, dimethicone mixing is added in 15:1:3:0.1, is sheared and is dispersed with 3000r/min
15min is to get composite auxiliary material.
A kind of dust suppressant, according to the mass fraction, including following component: 30 parts of plantain starch, 8 parts of molar substitution degrees, 7 parts
Dispersing agent, 5 portions of preservatives, 4 parts of defoaming agents, 60 parts of water, 40 parts of compound dust suppression material, 20 parts of composite auxiliary materials.
A kind of preparation method of dust suppressant, includes the following steps:
Including following component (1) according to the mass fraction: 30 parts of plantain starch, 8 parts of molar substitution degrees, 7 parts of dispersing agents, 5 parts it is anti-
Rotten agent, 4 parts of defoaming agents, 60 parts of water, 40 parts of compound dust suppression material, 20 parts of composite auxiliary materials;
(2) in 55 DEG C, plantain starch, molar substitution degree, dispersing agent, water, compound dust suppression material is first taken to mix in reaction kettle, with
600r/min magnetic agitation 55min adds composite auxiliary material, preservative, defoaming agent mixing, 35 DEG C is cooled to, with 1000r/min
Magnetic agitation 3h is to get dust suppressant.
Comparative example 1: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking compound dust suppression material.
Comparative example 2: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking composite auxiliary material.
Comparative example 3: the dust suppressant of company of Daliang City production.
After being diluted with water 3 times (2 times of weight are added in the test embodiment of the present invention and comparative example gained dust suppressant stoste respectively
Water) performance of keeping humidity, and simultaneously investigate sprinkling dust suppression agent solution after soil sample surface film forming, using water as compare, tie
Fruit is shown in Table 1.
Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
Moisturizing rate (%) | 28.89 | 26.34 | 27.32 | 24.42 | 24.12 | 15.66 |
Film forming | It is excellent | It is excellent | It is excellent | Difference | It is excellent | Difference |
Dust suppression efficiency is one of most important performance indicator of dust suppressant.The value of dust suppression efficiency is bigger, shows that anti-dust effect is got over
It is good.With reference to Environment Protect in China industry association standard " T/CAEPI 7-2017 water-soluble road dust suppressant ", each sample is carried out
It tests three times, acquires average PM2.5 dust suppression efficiency (%), PM10 dust suppression efficiency (%) respectively, the results are shown in Table 2.
Table 2
Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
PM2.5 dust suppression efficiency | 94.11 | 93.14 | 93.53 | 87.53 | 88.13 | 73.04 |
PM10 dust suppression efficiency | 89.03 | 88.25 | 88.65 | 84.24 | 84.98 | 11.85 |
Dust suppressant of the present invention has excellent performance of keeping humidity, and moisturizing rate also has excellent film forming, energy 23% or more
Enough consolidation film forming form block, effectively avoid reentrainment of dust.PM2.5 dust suppression efficiency reaches 92% or more, PM10 dust suppression efficiency all
Reach 87% or more, is more advantageous to the improvement and protection of environment.It is worth promoting.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention
Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of dust suppressant, according to the mass fraction, including following component: 20 ~ 30 parts of plantain starch, 5 ~ 8 parts of molar substitution degrees,
3 ~ 7 parts of dispersing agents, 2 ~ 5 portions of preservatives, 1 ~ 4 part of defoaming agent, 40 ~ 60 parts of water, which is characterized in that further include: 25 ~ 40 parts of compound suppressions
Dirt material, 12 ~ 20 parts of composite auxiliary materials.
2. a kind of dust suppressant according to claim 1, which is characterized in that the preparation method of the compound dust suppression material, including such as
Lower step:
(1) it takes luffa to pulverize and sieve, takes sieving particle boiling water blanching, filter out be added to 6 ~ 10 times of granular mass of sieving while hot
NaOH solution is mixed, and is stored at room temperature, and filters, and in 35 ~ 60 DEG C, takes filter residue 6:1 ~ 3:12 in mass ratio ~ 20 that hexichol first is added
Ketone, ethanol solution are mixed, and obtain mixture, in a nitrogen atmosphere, 6:0.1:3:15 ~ 25 take mixture, (NH in mass ratio4)2Fe(SO4)2, acrylic acid, ethanol solution mixing, ultraviolet radiation graft processing, discharging, obtain base-material, take base-material with mix washing lotion clean,
Combined processing luffa is obtained, it is spare;
(2) in 40 ~ 60 DEG C, 3:1 ~ 2:40 ~ 60 take multi-walled carbon nanotube, Dopamine hydrochloride, deionized water mixing to stir in mass ratio
It mixes, 4 ~ 7 times of multi-walled carbon nanotube quality of reagent A mixing is added, ultrasonication is stirred at room temperature, and centrifugal treating takes centrifugation object
It is dry, dried object is obtained, takes dried object 5 ~ 8:1:30 in mass ratio ~ 50 that triethylamine, toluene is added in ice-water bath stirring, drying is added
The bromo isobutyl acylbromide of amount of substance 15 ~ 20%, stirring, obtains brominated product, takes brominated product 1:0.08:20 ~ 30:0.3 in mass ratio
Copper bromide, reagent B is added, styrene benzene sulfonic acid sodium salt is mixed, in 35 ~ 55 DEG C, ultrasonication is stood, and centrifugation takes centrifugation object
Washing, obtains composite modified carbon nanomaterial;
(3) 5 ~ 8:1:0.1 in mass ratio takes spare combined processing luffa, composite modified carbon nanomaterial, polyvinyl pyrrole
Alkanone mixing, ball milling obtain ball milling material, and the sea-mussel mucin for taking ball milling material that 4 ~ 8 times of ball milling material quality is added mixes to get compound suppression
Dirt material.
3. a kind of dust suppressant according to claim 2, which is characterized in that the mixing washing lotion in the step (1): in mass ratio
3:16 ~ 25 take HCl solution, ethanol solution mixing to get mixing washing lotion.
4. a kind of dust suppressant according to claim 2, which is characterized in that the reagent A in the step (2): in mass ratio 7 ~
12:2 takes Tris-HCl buffer, sodium citrate mixing to get reagent A.
5. a kind of dust suppressant according to claim 2, which is characterized in that reagent B: 5:2 by volume in the step (3)
~ 4 take dimethylformamide, acetonitrile mixing to get reagent B.
6. a kind of dust suppressant according to claim 1, which is characterized in that the preparation of the composite auxiliary material: in 30 ~ 45 DEG C, pressing
Mass ratio 1:1 ~ 3:12 ~ 18 take laureth sodium sulfovinate, dodecyldimethylammonium hydroxide inner salt, water to be mixed, and must mix
Material takes mixture 8 ~ 15:1:1 in mass ratio ~ 3:0.1 that sodium alginate, pretreatment chitosan liquid, dimethicone mixing is added,
Shearing dispersion is to get composite auxiliary material.
7. a kind of dust suppressant according to claim 6, which is characterized in that the pretreatment chitosan liquid: in 30 ~ 50 DEG C, press
Mass ratio 1:0.1:20 ~ 40 take chitosan, gelatin, water to be mixed, and heat preservation is stood, and obtain mixed liquid, take mixed liquid in mass ratio 6 ~ 10:
1 is added soybean lecithin mixing to get pretreatment chitosan liquid.
8. a kind of dust suppressant according to claim 1, which is characterized in that the dispersing agent: 1:3 ~ 6 take microlite in mass ratio
The double stearoylketene amine mixing of wax, vinyl are to get dispersing agent.
9. a kind of dust suppressant according to claim 1, which is characterized in that the preservative: 5:1 ~ 3 take benzoic acid in mass ratio
Sodium, potassium sorbate mixing are to get preservative.
10. a kind of dust suppressant according to claim 1, which is characterized in that the defoaming agent: polypropylene glycerol aether, polyoxy
Any one in propylene polyoxyethylene glycerol ether, dimethyl silicone polymer.
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Cited By (5)
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CN111607241A (en) * | 2020-05-22 | 2020-09-01 | 中国路桥工程有限责任公司 | Asphalt modifier and preparation process thereof |
CN112412523A (en) * | 2020-10-23 | 2021-02-26 | 山东科技大学 | Coal bed moistening method based on mussel bionic principle |
CN114058332A (en) * | 2021-12-01 | 2022-02-18 | 河北钢铁集团矿业有限公司 | Polyelectrolyte biological composite dust suppressant for mining engineering and preparation method thereof |
CN115029106A (en) * | 2022-06-22 | 2022-09-09 | 北京中润新能源有限公司 | Dust-proof agent with self-cleaning function and preparation method thereof |
CN115627174A (en) * | 2022-10-09 | 2023-01-20 | 山东大学 | Natural polymer mine soil surface covering material with plant growth promotion and surface dust control functions |
Citations (1)
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CN108192570A (en) * | 2018-01-22 | 2018-06-22 | 天津圣洁环保科技有限公司 | Dust suppressant and preparation method thereof, application method and application |
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2018
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108192570A (en) * | 2018-01-22 | 2018-06-22 | 天津圣洁环保科技有限公司 | Dust suppressant and preparation method thereof, application method and application |
Cited By (7)
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CN111607241A (en) * | 2020-05-22 | 2020-09-01 | 中国路桥工程有限责任公司 | Asphalt modifier and preparation process thereof |
CN111607241B (en) * | 2020-05-22 | 2022-03-01 | 中国路桥工程有限责任公司 | Asphalt modifier and preparation process thereof |
CN112412523A (en) * | 2020-10-23 | 2021-02-26 | 山东科技大学 | Coal bed moistening method based on mussel bionic principle |
CN114058332A (en) * | 2021-12-01 | 2022-02-18 | 河北钢铁集团矿业有限公司 | Polyelectrolyte biological composite dust suppressant for mining engineering and preparation method thereof |
CN115029106A (en) * | 2022-06-22 | 2022-09-09 | 北京中润新能源有限公司 | Dust-proof agent with self-cleaning function and preparation method thereof |
CN115029106B (en) * | 2022-06-22 | 2023-11-10 | 北京中润新能源有限公司 | Dustproof agent with self-cleaning function and preparation method thereof |
CN115627174A (en) * | 2022-10-09 | 2023-01-20 | 山东大学 | Natural polymer mine soil surface covering material with plant growth promotion and surface dust control functions |
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