CN108976946A - A kind of ceramic coating resistant to high temperature - Google Patents

A kind of ceramic coating resistant to high temperature Download PDF

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Publication number
CN108976946A
CN108976946A CN201810697978.6A CN201810697978A CN108976946A CN 108976946 A CN108976946 A CN 108976946A CN 201810697978 A CN201810697978 A CN 201810697978A CN 108976946 A CN108976946 A CN 108976946A
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CN
China
Prior art keywords
parts
high temperature
agent
ceramic coating
coating resistant
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810697978.6A
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Chinese (zh)
Inventor
熊子义
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Foshan Gaoming District Productivity Promotion Center
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Foshan Gaoming District Productivity Promotion Center
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Priority to CN201810697978.6A priority Critical patent/CN108976946A/en
Publication of CN108976946A publication Critical patent/CN108976946A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/16Halogen-containing compounds
    • C08K2003/166Magnesium halide, e.g. magnesium chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of ceramic coating resistant to high temperature, ceramic industry technical field, it include: 55-75 parts of gas-phase silica by mass parts composition, 40-45 parts of magnesia, six 24-32 parts of carbonoxides, 16-19 parts of zinc oxide, 5-15 parts of magnesium chloride, 8-16 parts of ochre, 20-25 parts of talcum powder, 18-22 parts of quartz sand, 11-19 parts of glass fiber, 44-54 parts of epoxy curing agent, 25-30 parts of cesium hydroxide, 19-24 parts of silane coupling agent, 9-18 parts of surfactant, 10-18 parts of anti-aging agent, 26-30 parts of melamine, 16-22 parts of succinic anhydride, 21-29 parts of hydrazine hydrate, 30-39 parts of polyacrylic acid, 45-55 parts of deionized water.Usefulness of the present invention is to apply dye to arrive ceramic surface, and ceramics is made to have the function of certain high temperature resistant.

Description

A kind of ceramic coating resistant to high temperature
Technical field
The present invention relates to ceramic industry technical field, especially a kind of ceramic coating resistant to high temperature.
Background technique
Coating Industry in Our Country is with a long history, and output and consumption figure are in rank first, and development prospect is wide, just It is being increasingly becoming national economy new growth point.The early detection U.S., Japan, South Korea have some ceramic coatings in terms of research, Report, but Related product is had not seen in its domestic market;With the development of society, ceramic coating occupy in many fields it is important Status, and the approval by many consumers, ceramic use environment is sufficiently complex, this is greatly reduced using ceramics Service life increases cost, so traditional ceramic material can no longer meet increasingly harsh job requirement and therefore develop one The novel ceramic protective material of kind.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides a kind of ceramic coating resistant to high temperature, applies dye and arrives ceramic surface, Ceramics are made to have the function of certain high temperature resistant.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of ceramic coating resistant to high temperature includes: 55-75 parts of gas-phase silica, magnesia 40-45 by mass parts composition Part, 24-32 parts of six carbonoxide, 16-19 parts of zinc oxide, 5-15 parts of magnesium chloride, 8-16 parts of ochre, 20-25 parts of talcum powder, quartz sand 18-22 parts, 11-19 parts of glass fiber, 44-54 parts of epoxy curing agent, 25-30 parts of cesium hydroxide, silane coupling agent 19-24 Part, 9-18 parts of surfactant, 10-18 parts of anti-aging agent, 26-30 parts of melamine, 16-22 parts of succinic anhydride, hydrazine hydrate 21-29 Part, 30-39 parts of polyacrylic acid, 45-55 parts of deionized water.
It preferably, include: 65 parts of gas-phase silica, 43 parts of magnesia, 28 parts of six carbonoxide, zinc oxide by mass parts composition 18 parts, 10 parts of magnesium chloride, 14 parts of ochre, 23 parts of talcum powder, 20 parts of quartz sand, 16 parts of glass fiber, 50 parts of epoxy curing agent, 28 parts of cesium hydroxide, 22 parts of silane coupling agent, 15 parts of surfactant, 14 parts of anti-aging agent, 28 parts of melamine, succinic anhydride 20 Part, 25 parts of hydrazine hydrate, 35 parts of polyacrylic acid, 50 parts of deionized water.
Preferably, a kind of ceramic coating resistant to high temperature, production method include the following steps:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant, Anti-aging agent is put into stirring ware, is first heated to 78-85 DEG C, then stirs 22-28min with the speed of 43-48r/min, then Ochre, talcum powder, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride are poured into, used instead with 52-58r/min's Speed stirs 42-45min, finally again pours into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, with 22- The speed of 28r/min stirs 36-40min;
(2) step (1) coating is poured into grinder, in 50-56 DEG C of grinding 7-10h.
Preferably, the promotor is dibutyl tin dilaurate.
Preferably, the anti-aging agent is N- phenyl-α-aniline.
Compared with prior art, the beneficial effects of the present invention are:
By the way that magnesia, six carbonoxides, zinc oxide, magnesium chloride, ochre, talcum powder, quartz sand, glass are added in formula This variety of material with high-temperature stability of silk apply dye and arrive ceramic surface, ceramics is made to have the function of certain high temperature resistant.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of ceramic coating resistant to high temperature includes: 55 parts of gas-phase silica, 40 parts of magnesia, six oxygen by mass parts composition Change 24 parts of carbon, 16 parts of zinc oxide, 5 parts of magnesium chloride, 8 parts of ochre, 20 parts of talcum powder, 18 parts of quartz sand, 11 parts of glass fiber, asphalt mixtures modified by epoxy resin 44 parts of rouge curing agent, 25 parts of cesium hydroxide, 19 parts of silane coupling agent, 9 parts of surfactant, 10 parts of anti-aging agent, melamine 26 Part, 16 parts of succinic anhydride, 21 parts of hydrazine hydrate, 30 parts of polyacrylic acid, 45 parts of deionized water.
Preferably, a kind of ceramic coating resistant to high temperature, production method include the following steps:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant, Anti-aging agent is put into stirring ware, is first heated to 78 DEG C, then 22min is stirred with the speed of 43r/min, then by ochre, cunning Mountain flour, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride pour into, and use the speed stirring with 52r/min instead 42min finally again pours into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, is stirred with the speed of 22r/min Mix 36min;
(2) step (1) coating is poured into grinder, in 50 DEG C of grinding 7h.
Preferably, the promotor is dibutyl tin dilaurate.
Preferably, the anti-aging agent is N- phenyl-α-aniline.
Embodiment 2
A kind of ceramic coating resistant to high temperature includes: 75 parts of gas-phase silica, 45 parts of magnesia, six oxygen by mass parts composition Change 32 parts of carbon, 19 parts of zinc oxide, 15 parts of magnesium chloride, 16 parts of ochre, 25 parts of talcum powder, 22 parts of quartz sand, 19 parts of glass fiber, epoxy 54 parts of resin curing agent, 30 parts of cesium hydroxide, 24 parts of silane coupling agent, 18 parts of surfactant, 18 parts of anti-aging agent, melamine 30 parts, 22 parts of succinic anhydride, 29 parts of hydrazine hydrate, 39 parts of polyacrylic acid, 55 parts of deionized water.
Preferably, a kind of ceramic coating resistant to high temperature, production method include the following steps:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant, Anti-aging agent is put into stirring ware, is first heated to 85 DEG C, then 28min is stirred with the speed of 48r/min, then by ochre, cunning Mountain flour, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride pour into, and use the speed stirring with 58r/min instead 45min finally again pours into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, is stirred with the speed of 28r/min Mix 40min;
(2) step (1) coating is poured into grinder, in 56 DEG C of grinding 10h.
Preferably, the promotor is dibutyl tin dilaurate.
Preferably, the anti-aging agent is N- phenyl-α-aniline.
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention Within the scope of.

Claims (5)

1. a kind of ceramic coating resistant to high temperature, which is characterized in that forming by mass parts includes: 55-75 parts of gas-phase silica, oxidation 40-45 parts of magnesium, 24-32 parts of six carbonoxide, 16-19 parts of zinc oxide, 5-15 parts of magnesium chloride, 8-16 parts of ochre, talcum powder 20-25 It is part, 18-22 parts of quartz sand, 11-19 parts of glass fiber, 44-54 parts of epoxy curing agent, 25-30 parts of cesium hydroxide, silane coupled 19-24 parts of agent, 9-18 parts of surfactant, 10-18 parts of anti-aging agent, 26-30 parts of melamine, 16-22 parts of succinic anhydride, hydration 21-29 parts of hydrazine, 30-39 parts of polyacrylic acid, 45-55 parts of deionized water.
2. a kind of ceramic coating resistant to high temperature according to claim 1, which is characterized in that forming by mass parts includes: gas phase 65 parts of white carbon black, 43 parts of magnesia, 28 parts of six carbonoxide, 18 parts of zinc oxide, 10 parts of magnesium chloride, 14 parts of ochre, 23 parts of talcum powder, 20 parts of quartz sand, 16 parts of glass fiber, 50 parts of epoxy curing agent, 28 parts of cesium hydroxide, 22 parts of silane coupling agent, surface-active 15 parts of agent, 14 parts of anti-aging agent, 28 parts of melamine, 20 parts of succinic anhydride, 25 parts of hydrazine hydrate, 35 parts of polyacrylic acid, deionized water 50 parts.
3. a kind of ceramic coating resistant to high temperature according to claim 1 or claim 2, which is characterized in that production method includes following step It is rapid:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant, anti-old Agent is put into stirring ware, is first heated to 78-85 DEG C, then stirs 22-28min with the speed of 43-48r/min, then will be reddish brown Stone, talcum powder, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride pour into, and use the speed with 52-58r/min instead 42-45min is stirred, is finally again poured into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, with 22-28r/ The speed of min stirs 36-40min;
(2) step (1) coating is poured into grinder, in 50-56 DEG C of grinding 7-10h.
4. a kind of ceramic coating resistant to high temperature according to claim 1, which is characterized in that the promotor is tin dilaurate two Butyl tin.
5. a kind of ceramic coating resistant to high temperature according to claim 1, which is characterized in that the anti-aging agent is N- phenyl-α- Aniline.
CN201810697978.6A 2018-06-29 2018-06-29 A kind of ceramic coating resistant to high temperature Pending CN108976946A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113860845A (en) * 2021-10-21 2021-12-31 福建禄德辰新材料有限公司 High-temperature-resistant special material for simulation ceramics of fireplace and bathroom cabinet

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104087121A (en) * 2014-07-18 2014-10-08 关锦池 High-temperature-resistant, wear-resistant and antioxidant ceramic coating
CN106366890A (en) * 2016-09-09 2017-02-01 朱燕华 Environment-friendly ceramic coating material for nodular cast iron pipe

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104087121A (en) * 2014-07-18 2014-10-08 关锦池 High-temperature-resistant, wear-resistant and antioxidant ceramic coating
CN106366890A (en) * 2016-09-09 2017-02-01 朱燕华 Environment-friendly ceramic coating material for nodular cast iron pipe

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《军事医学》编辑委员会: "《中国医学百科全书 军事医学》", 30 November 1995, 上海科学技术出版社 *
COREY S. JAMISON ET AL: ""First detection of the Cs symmetric isomer of carbon hexaoxide(CO6)at 10K"", 《CHEMICAL PHYSICS LETTERS》 *
孙道兴等: "《涂料调制与配色技术》", 30 November 2008, 中国纺织出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113860845A (en) * 2021-10-21 2021-12-31 福建禄德辰新材料有限公司 High-temperature-resistant special material for simulation ceramics of fireplace and bathroom cabinet

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Application publication date: 20181211

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