CN108976946A - A kind of ceramic coating resistant to high temperature - Google Patents
A kind of ceramic coating resistant to high temperature Download PDFInfo
- Publication number
- CN108976946A CN108976946A CN201810697978.6A CN201810697978A CN108976946A CN 108976946 A CN108976946 A CN 108976946A CN 201810697978 A CN201810697978 A CN 201810697978A CN 108976946 A CN108976946 A CN 108976946A
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- Prior art keywords
- parts
- high temperature
- agent
- ceramic coating
- coating resistant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/166—Magnesium halide, e.g. magnesium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of ceramic coating resistant to high temperature, ceramic industry technical field, it include: 55-75 parts of gas-phase silica by mass parts composition, 40-45 parts of magnesia, six 24-32 parts of carbonoxides, 16-19 parts of zinc oxide, 5-15 parts of magnesium chloride, 8-16 parts of ochre, 20-25 parts of talcum powder, 18-22 parts of quartz sand, 11-19 parts of glass fiber, 44-54 parts of epoxy curing agent, 25-30 parts of cesium hydroxide, 19-24 parts of silane coupling agent, 9-18 parts of surfactant, 10-18 parts of anti-aging agent, 26-30 parts of melamine, 16-22 parts of succinic anhydride, 21-29 parts of hydrazine hydrate, 30-39 parts of polyacrylic acid, 45-55 parts of deionized water.Usefulness of the present invention is to apply dye to arrive ceramic surface, and ceramics is made to have the function of certain high temperature resistant.
Description
Technical field
The present invention relates to ceramic industry technical field, especially a kind of ceramic coating resistant to high temperature.
Background technique
Coating Industry in Our Country is with a long history, and output and consumption figure are in rank first, and development prospect is wide, just
It is being increasingly becoming national economy new growth point.The early detection U.S., Japan, South Korea have some ceramic coatings in terms of research,
Report, but Related product is had not seen in its domestic market;With the development of society, ceramic coating occupy in many fields it is important
Status, and the approval by many consumers, ceramic use environment is sufficiently complex, this is greatly reduced using ceramics
Service life increases cost, so traditional ceramic material can no longer meet increasingly harsh job requirement and therefore develop one
The novel ceramic protective material of kind.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides a kind of ceramic coating resistant to high temperature, applies dye and arrives ceramic surface,
Ceramics are made to have the function of certain high temperature resistant.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of ceramic coating resistant to high temperature includes: 55-75 parts of gas-phase silica, magnesia 40-45 by mass parts composition
Part, 24-32 parts of six carbonoxide, 16-19 parts of zinc oxide, 5-15 parts of magnesium chloride, 8-16 parts of ochre, 20-25 parts of talcum powder, quartz sand
18-22 parts, 11-19 parts of glass fiber, 44-54 parts of epoxy curing agent, 25-30 parts of cesium hydroxide, silane coupling agent 19-24
Part, 9-18 parts of surfactant, 10-18 parts of anti-aging agent, 26-30 parts of melamine, 16-22 parts of succinic anhydride, hydrazine hydrate 21-29
Part, 30-39 parts of polyacrylic acid, 45-55 parts of deionized water.
It preferably, include: 65 parts of gas-phase silica, 43 parts of magnesia, 28 parts of six carbonoxide, zinc oxide by mass parts composition
18 parts, 10 parts of magnesium chloride, 14 parts of ochre, 23 parts of talcum powder, 20 parts of quartz sand, 16 parts of glass fiber, 50 parts of epoxy curing agent,
28 parts of cesium hydroxide, 22 parts of silane coupling agent, 15 parts of surfactant, 14 parts of anti-aging agent, 28 parts of melamine, succinic anhydride 20
Part, 25 parts of hydrazine hydrate, 35 parts of polyacrylic acid, 50 parts of deionized water.
Preferably, a kind of ceramic coating resistant to high temperature, production method include the following steps:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant,
Anti-aging agent is put into stirring ware, is first heated to 78-85 DEG C, then stirs 22-28min with the speed of 43-48r/min, then
Ochre, talcum powder, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride are poured into, used instead with 52-58r/min's
Speed stirs 42-45min, finally again pours into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, with 22-
The speed of 28r/min stirs 36-40min;
(2) step (1) coating is poured into grinder, in 50-56 DEG C of grinding 7-10h.
Preferably, the promotor is dibutyl tin dilaurate.
Preferably, the anti-aging agent is N- phenyl-α-aniline.
Compared with prior art, the beneficial effects of the present invention are:
By the way that magnesia, six carbonoxides, zinc oxide, magnesium chloride, ochre, talcum powder, quartz sand, glass are added in formula
This variety of material with high-temperature stability of silk apply dye and arrive ceramic surface, ceramics is made to have the function of certain high temperature resistant.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of ceramic coating resistant to high temperature includes: 55 parts of gas-phase silica, 40 parts of magnesia, six oxygen by mass parts composition
Change 24 parts of carbon, 16 parts of zinc oxide, 5 parts of magnesium chloride, 8 parts of ochre, 20 parts of talcum powder, 18 parts of quartz sand, 11 parts of glass fiber, asphalt mixtures modified by epoxy resin
44 parts of rouge curing agent, 25 parts of cesium hydroxide, 19 parts of silane coupling agent, 9 parts of surfactant, 10 parts of anti-aging agent, melamine 26
Part, 16 parts of succinic anhydride, 21 parts of hydrazine hydrate, 30 parts of polyacrylic acid, 45 parts of deionized water.
Preferably, a kind of ceramic coating resistant to high temperature, production method include the following steps:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant,
Anti-aging agent is put into stirring ware, is first heated to 78 DEG C, then 22min is stirred with the speed of 43r/min, then by ochre, cunning
Mountain flour, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride pour into, and use the speed stirring with 52r/min instead
42min finally again pours into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, is stirred with the speed of 22r/min
Mix 36min;
(2) step (1) coating is poured into grinder, in 50 DEG C of grinding 7h.
Preferably, the promotor is dibutyl tin dilaurate.
Preferably, the anti-aging agent is N- phenyl-α-aniline.
Embodiment 2
A kind of ceramic coating resistant to high temperature includes: 75 parts of gas-phase silica, 45 parts of magnesia, six oxygen by mass parts composition
Change 32 parts of carbon, 19 parts of zinc oxide, 15 parts of magnesium chloride, 16 parts of ochre, 25 parts of talcum powder, 22 parts of quartz sand, 19 parts of glass fiber, epoxy
54 parts of resin curing agent, 30 parts of cesium hydroxide, 24 parts of silane coupling agent, 18 parts of surfactant, 18 parts of anti-aging agent, melamine
30 parts, 22 parts of succinic anhydride, 29 parts of hydrazine hydrate, 39 parts of polyacrylic acid, 55 parts of deionized water.
Preferably, a kind of ceramic coating resistant to high temperature, production method include the following steps:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant,
Anti-aging agent is put into stirring ware, is first heated to 85 DEG C, then 28min is stirred with the speed of 48r/min, then by ochre, cunning
Mountain flour, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride pour into, and use the speed stirring with 58r/min instead
45min finally again pours into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, is stirred with the speed of 28r/min
Mix 40min;
(2) step (1) coating is poured into grinder, in 56 DEG C of grinding 10h.
Preferably, the promotor is dibutyl tin dilaurate.
Preferably, the anti-aging agent is N- phenyl-α-aniline.
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although
Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned
Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention
Within the scope of.
Claims (5)
1. a kind of ceramic coating resistant to high temperature, which is characterized in that forming by mass parts includes: 55-75 parts of gas-phase silica, oxidation
40-45 parts of magnesium, 24-32 parts of six carbonoxide, 16-19 parts of zinc oxide, 5-15 parts of magnesium chloride, 8-16 parts of ochre, talcum powder 20-25
It is part, 18-22 parts of quartz sand, 11-19 parts of glass fiber, 44-54 parts of epoxy curing agent, 25-30 parts of cesium hydroxide, silane coupled
19-24 parts of agent, 9-18 parts of surfactant, 10-18 parts of anti-aging agent, 26-30 parts of melamine, 16-22 parts of succinic anhydride, hydration
21-29 parts of hydrazine, 30-39 parts of polyacrylic acid, 45-55 parts of deionized water.
2. a kind of ceramic coating resistant to high temperature according to claim 1, which is characterized in that forming by mass parts includes: gas phase
65 parts of white carbon black, 43 parts of magnesia, 28 parts of six carbonoxide, 18 parts of zinc oxide, 10 parts of magnesium chloride, 14 parts of ochre, 23 parts of talcum powder,
20 parts of quartz sand, 16 parts of glass fiber, 50 parts of epoxy curing agent, 28 parts of cesium hydroxide, 22 parts of silane coupling agent, surface-active
15 parts of agent, 14 parts of anti-aging agent, 28 parts of melamine, 20 parts of succinic anhydride, 25 parts of hydrazine hydrate, 35 parts of polyacrylic acid, deionized water
50 parts.
3. a kind of ceramic coating resistant to high temperature according to claim 1 or claim 2, which is characterized in that production method includes following step
It is rapid:
(1) by six carbonoxides, zinc oxide, magnesium chloride, polyacrylic acid, deionized water, silane coupling agent, surfactant, anti-old
Agent is put into stirring ware, is first heated to 78-85 DEG C, then stirs 22-28min with the speed of 43-48r/min, then will be reddish brown
Stone, talcum powder, quartz sand, epoxy curing agent, cesium hydroxide, succinic anhydride pour into, and use the speed with 52-58r/min instead
42-45min is stirred, is finally again poured into gas-phase silica, magnesia, glass fiber, melamine, hydrazine hydrate, with 22-28r/
The speed of min stirs 36-40min;
(2) step (1) coating is poured into grinder, in 50-56 DEG C of grinding 7-10h.
4. a kind of ceramic coating resistant to high temperature according to claim 1, which is characterized in that the promotor is tin dilaurate two
Butyl tin.
5. a kind of ceramic coating resistant to high temperature according to claim 1, which is characterized in that the anti-aging agent is N- phenyl-α-
Aniline.
Priority Applications (1)
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CN201810697978.6A CN108976946A (en) | 2018-06-29 | 2018-06-29 | A kind of ceramic coating resistant to high temperature |
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CN201810697978.6A CN108976946A (en) | 2018-06-29 | 2018-06-29 | A kind of ceramic coating resistant to high temperature |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113860845A (en) * | 2021-10-21 | 2021-12-31 | 福建禄德辰新材料有限公司 | High-temperature-resistant special material for simulation ceramics of fireplace and bathroom cabinet |
Citations (2)
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CN104087121A (en) * | 2014-07-18 | 2014-10-08 | 关锦池 | High-temperature-resistant, wear-resistant and antioxidant ceramic coating |
CN106366890A (en) * | 2016-09-09 | 2017-02-01 | 朱燕华 | Environment-friendly ceramic coating material for nodular cast iron pipe |
-
2018
- 2018-06-29 CN CN201810697978.6A patent/CN108976946A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104087121A (en) * | 2014-07-18 | 2014-10-08 | 关锦池 | High-temperature-resistant, wear-resistant and antioxidant ceramic coating |
CN106366890A (en) * | 2016-09-09 | 2017-02-01 | 朱燕华 | Environment-friendly ceramic coating material for nodular cast iron pipe |
Non-Patent Citations (3)
Title |
---|
《军事医学》编辑委员会: "《中国医学百科全书 军事医学》", 30 November 1995, 上海科学技术出版社 * |
COREY S. JAMISON ET AL: ""First detection of the Cs symmetric isomer of carbon hexaoxide(CO6)at 10K"", 《CHEMICAL PHYSICS LETTERS》 * |
孙道兴等: "《涂料调制与配色技术》", 30 November 2008, 中国纺织出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113860845A (en) * | 2021-10-21 | 2021-12-31 | 福建禄德辰新材料有限公司 | High-temperature-resistant special material for simulation ceramics of fireplace and bathroom cabinet |
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