CN108976797A - A kind of edge band and its production method of bisphenol a polysulfone material - Google Patents
A kind of edge band and its production method of bisphenol a polysulfone material Download PDFInfo
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- CN108976797A CN108976797A CN201810671125.5A CN201810671125A CN108976797A CN 108976797 A CN108976797 A CN 108976797A CN 201810671125 A CN201810671125 A CN 201810671125A CN 108976797 A CN108976797 A CN 108976797A
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention relates to furniture edge banding technical fields, and in particular to a kind of edge band and its production method of bisphenol a polysulfone material.Edge band by bisphenol a polysulfone resin, composite strengthening resin, hydroxyl organosilicon, EVA lotion, cross-linking aid, filler auxiliary agent, ultraviolet absorbing agent, in-lubricant, antioxidant, silane coupling agent, wear-resistant auxiliary agent and antistatic agent by extra fine quality proportion mixing after through extrusion molding in the way of be made.Wherein bisphenol a polysulfone resin is main material, and the compounding resin, hydroxyl organosilicon, EVA lotion etc. for applying polycarbonate, ABS resin and polytetrafluoroethylene (PTFE), collaboration compound system is formed under cross-linking aid, filler auxiliary agent, antistatic agent, antioxidant, silane coupling agent, ultraviolet absorbing agent, the wear-resistant auxiliary agent the effects of, gained edge band has stronger chemical-resistance, heat-resisting, heatproof, dimensional stability, UV resistance etc., and production method is simple, has expanded demand selection space of the market to edge band type.
Description
Technical field
The present invention relates to furniture edge banding technical fields, and in particular to a kind of edge band of bisphenol a polysulfone material and its life
Production method.
Background technique
Edge band is used to carry out sealing to the section of Furniture panel, and reaching makes furniture section from environment and use process
Unfavorable factor such as moisture to the destruction of plate and the effect that prevents the formaldehyde inside plate from volatilizing, while reaching decorative beauty
The effect of sight can make furniture show the overall effect that wood grain is clear, riotous with colour.Existing frequently-used edge band mainly has: former
The wooden edge band, PVC edge band, ABS edge band and melamine edge band, wherein log edge band is original with the raw wooden skin of trees
Material, have the characteristics that naturally, without chemical contamination, but, higher cost larger to tree resources demand；PVC edge band is with polychlorostyrene second
Olefine resin is raw material, has a good wearability, but PVC material poor heat resistance, can decompose release in long-term use process and contain
Chloride material causes an influence to environment and health, and edge band intensity is inadequate, and service life is short；ABS edge band has resistance to
The advantages that mill, antiacid alkali and obdurability, but easily snap off, and higher cost, it is mainly used for top-grade furniture；Melamine envelope
Edge strip be it is a kind of by melamine-impregnated on paper manufactured paper edge band, melamine edge band flexibility it is poor, intensity is weak, easily
Chipping, glue tracks are obvious.In summary, existing furniture edge banding has the shortcomings that different, and type is fewer, may be selected
Leeway is small, it is therefore desirable to develop the edge band of New Type Material.
Bisphenol a polysulfone resin is a kind of thermoplastic engineering resin, and there is stronger toughness, dimensional stability, resistance to environment to answer
Power cracking ability, anti-flammability, colourability and electrical insulating property isosceles advantage, wherein the aryl in bisphenol a polysulfone has polymer
There are higher temperature resistant capability and a chemical resistance, sulfuryl makes polymer have stronger thermo-oxidative stability, is not easy compared with PVC point
Solution.
Summary of the invention
It is fewer for existing furniture edge banding type, the lesser problem in leeway may be selected, it is an object of the invention to mention
For a kind of edge band of bisphenol a polysulfone material, obdurability, dimensional stability and the chemically-resistant of bisphenol a polysulfone resin are made full use of
The properties such as property prepare the edge band of bisphenol a polysulfone material, meet the needs of market is to edge band type.
Another object of the present invention is to provide the preparation methods of the edge band of bisphenol a polysulfone material.
The present invention provides the following technical solution:
A kind of edge band of bisphenol a polysulfone material, the edge band are made of the components of following parts: bisphenol a polysulfone resin
80~100 parts, 40~60 parts of composite strengthening resin, 20~30 parts of hydroxyl organosilicon, 6~10 parts of EVA lotion, cross-linking aid 1
~3 parts, 5~10 parts of filler auxiliary agent, 2~3 parts of ultraviolet absorbing agent, 1~2 part of in-lubricant, 0.8~1 part of antioxidant, silane idol
0.6~1 part of agent of connection, 1~2 part of wear-resistant auxiliary agent and 0.6~0.8 part of antistatic agent.
As a preference of the present invention, the composite strengthening resin is that ABS resin, polycarbonate and polyflon are pressed
Mass ratio is the mixture that 2~3:1:0.6~1 is formed.
As a preference of the present invention, the hydroxyl organosilicon is terminal hydroxyl dimethyl-polysiloxane, terminal hydroxy group diethyl
Polysiloxanes, terminal hydroxy ethylene dimethyl polysiloxane, terminal hydroxy ethylene diethyl based polysiloxane and terminal hydroxy group hydrogeneous two
One of methyl polysiloxane is a variety of.
As a preference of the present invention, the cross-linking aid be respectively component A, component B and component C be in mass ratio 10~
The mixture that 12:1:5~6 is formed, wherein component A is alkoxy silane, acetoxylsilane, ethyl orthosilicate, poly- methyl-prop
One of olefin(e) acid ethyl ester and polybutyl methacrylate, component B are dibutyltin dilaurate, stannous octoate, dibutyl
One of tin dimaleate and dibutyltin diacetate, component C are one of acrylic acid, crotonic acid and cinnamic acid.
As a preference of the present invention, the filler auxiliary agent is nano silica, nano diatomite, nano mica powder or receives
One of rice talcum powder is a variety of.
As a preference of the present invention, wear-resistant auxiliary agent is be chopped one of wood fibre, tyre talc and calcium stearate or more
Kind.
As a preference of the present invention, ultraviolet absorbing agent is nano titanium dioxide powder, Zirconium dioxide powder and titanium dioxide
The mixture of at least one of tin powder and methyl acrylate, 5~6:1 of the two mass ratio.
As a preference of the present invention, the in-lubricant is one in stearic acid, myristic acid, lauric acid and microcrystalline wax
Kind.
Edge band of the invention utilizes bisphenol a polysulfone resin, composite strengthening resin and hydroxyl organosilicon, EVA lotion etc.
It is made.
Bisphenol a polysulfone resin is a kind of thermoplastic engineering resin, and there is stronger toughness, dimensional stability, resistance to environment to answer
Power cracking ability, anti-flammability, colourability and electrical insulating property isosceles advantage, wherein the aryl in bisphenol a polysulfone has polymer
There are higher temperature resistant capability and a chemical resistance, sulfuryl makes polymer have stronger thermo-oxidative stability, is not easy compared with PVC point
Solution.Composite strengthening resin used is polycarbonate, ABS resin and polyflon, and wherein polycarbonate has Gao Chong
Hit intensity, good stability of the dimension, fatigue durability and weatherability are strong, polyflon low, heatproof, resistance toization with coefficient of friction
Corrosion and the resistance to characteristics such as ultraviolet are learned, and the shrinkage ratio of polycarbonate and ABS resin is closer to, about 0.5%, compatibility is good,
Polycarbonate, ABS resin and polyflon compounding are added in bisphenol a polysulfone resin, enhanced by cooperative reinforcing
The performances such as the impact strength of edge band made of bisphenol a polysulfone resin, dimensional stability, resistant to chemical etching.Hydroxyl used has
Machine silicon can be terminal hydroxyl dimethyl-polysiloxane, terminal hydroxy group diethyl based polysiloxane, the poly- silicon oxygen of terminal hydroxy ethylene dimethyl
Alkane, terminal hydroxy ethylene diethyl based polysiloxane and the hydrogeneous dimethyl polysiloxane of terminal hydroxy group, that is, the end group of at least one end
For the dimethyl polysiloxane or diethyl based polysiloxane of hydroxyl, these end groups are dimethyl polysiloxane, the diethyl of hydroxyl
Polysiloxanes is liquid substantially, is easy to use；Contained terminal hydroxy group has good activity, can be with the A group in cross-linking aid
Part is as in alkoxy silane, acetoxylsilane, ethyl orthosilicate, polyethyl methacrylate or polybutyl methacrylate
Alkoxy is in B component such as dibutyltin dilaurate, stannous octoate, dibutyl tin dimaleate and dibutyltin diacetate
Catalysis under condensation reaction occurs, thus the webbed modified organic silicon of shape, there is good mobility, composite strengthening can be improved
The mobility and processing performance of resin and bisphenol a polysulfone polysulfone Blends, while having after modified netted organosilicon solidification
Higher heat resistance, electrical insulating property and waterproof, humidity resistance play the role of mutually enhancing with composite strengthening resin.And net
The film forming dispersion performance of the organosilicon of shape is good, facilitates filler auxiliary agent etc. and disperses film forming in reinforced resin, plays reinforcing enhancing
The effect of resin.The main component of EVA lotion is polyethylene vinyl acetate, and wherein the content of vinyl acetate is not less than 20wt%,
With flexibility, resistance to acid and alkali, compatibility, film forming and the mobility perfected, the performance of the edge band of preparation can be enhanced, together
When EVA lotion in unsaturated bond crosslink and react with the C component in cross-linking aid such as acrylic acid, crotonic acid, cinnamic acid, and
Catalytic intensification through B component forms elastomer in the edge band of organic silicon material so that EVA lotion be made further to solidify, into
Toughness, the performance of resistance to acid and alkali and ultraviolet aging resistance of one step enhancing edge band.Filler auxiliary agent such as nano silica, nano-silicon
Diatomaceous earth, nano mica powder or nano talc etc. are evenly dispersed under the action of modified organic silicon and EVA lotion, in potting resin
Micro-structure, play enhancing edge band mechanical strength, wear-resisting property the effects of.Fragrant adoption can be enhanced in ultraviolet absorbing agent
The resistance to UV aging of carbonic ester forms the effect for mutually cooperateing with and promoting with netted modified organic silicon structure, wherein will receive
Rice titania powder, nanometer titanium dioxide zirconium powder and/or nano tin dioxide powder and methyl acrylate are used in compounding, and are utilized
The film forming characteristics of methyl acrylate is evenly dispersed, and the service life of ultraviolet absorbing agent can be enhanced.Wear-resistant auxiliary agent is such as chopped wooden
Matter fiber, tyre talc, calcium stearate and polyflon etc. can improve the wear-resisting property of edge band, and be chopped wooden fibre
The diameter of dimension is 3~5 μm, and diameter is 400~500 μm.Interior powdered lubricant such as stearic acid, myristic acid, lauric acid and microcrystalline wax
Etc. the interior friction that can reduce the high-polymer molecule chain, mobility is improved；The compatibility of silane coupling agent and hydroxyl organosilicon is high,
And then enhanced in the effect of organosilicon reticular structure and the compatibility of reinforced resin, to be played well to filler auxiliary agent
" molecular bridge " effect, makes edge band obtain preferable surface quality and mechanical property, and preferred silane coupling agent is silane coupled
Agent KH550, KH560, KH470 and KH570 etc..Antioxidant can be uniform with reinforced resin under the action of organosilicon reticular structure
Dispersing contact improves the anti-aging property of reinforced resin, and extend edge band uses time, preferably antioxidant such as antioxidant
1076, antioxidant 164, antioxidant DNP, antioxidant TNP, antioxidant TPP, antioxidant CA and antioxidant BHT etc..Antistatic agent can
To enhance the antistatic property of edge band, preferably such as short carbon fiber, D-sorbite, glycollic amide and glycerol, wherein being chopped
Carbon fibe preferred length is 600~800 μm, and diameter is 1~3 μm.
Edge band of the invention applies polycarbonate, ABS resin and polytetrafluoro using bisphenol a polysulfone resin as main material
The compounding resin of ethylene, hydroxyl organosilicon, EVA lotion etc., in cross-linking aid, filler auxiliary agent, antistatic agent, antioxidant, silicon
Collaboration compound system is formed under the effects of alkane coupling agent, ultraviolet absorbing agent, wear-resistant auxiliary agent, gained edge band has stronger resistance to
Chemical property, heat-resisting, heatproof, dimensional stability, UV resistance etc..
The production method of the edge band of above-mentioned polysulfones material, comprising the following steps:
(1) EVA lotion and cross-linking aid room temperature premix are stood into 2~5h, filler auxiliary agent, wear-resistant auxiliary agent and silane coupling agent room temperature
Premix stand 90~120min, then with bisphenol a polysulfone resin, composite strengthening resin, hydroxyl organosilicon, ultraviolet radiation absorption
Agent, in-lubricant, antioxidant and antistatic agent are thoroughly mixed 30~40min at 110~130 DEG C, and then 230~240 DEG C
Extruding pelletization；
(2) gained particle is sent into double screw extruder and squeezes out, is cooled and shaped, obtain the edge sealing of bisphenol a polysulfone resin material
Item.
As the preferred of the method for the present invention, the L/D of double screw extruder is 20~25:1, revolving speed 8~12r/min, each section
Temperature are as follows: 270~290 DEG C of leading portion, 260~270 DEG C of middle section, 250~260 DEG C of back segment, 260~280 DEG C of head, mouth mold 240~
250℃。
The production method of edge band of the invention is succinct, is convenient for operation, during the preparation process by EVA lotion and cross-linking aid
It first adequately premixes, is crosslinked part EVA lotion, reduce the viscosity of EVA lotion, then mix, stirring with other compositions again
The dynamic crosslinking that EVA lotion and organosilicon are realized in mixing and granulation process, ensure that the good mobility of object material.
Beneficial effects of the present invention are as follows:
Edge band of the invention applies polycarbonate, ABS resin and polytetrafluoroethylene (PTFE) using bisphenol a polysulfone resin as main material
Compounding resin, hydroxyl organosilicon, EVA lotion etc., it is even in cross-linking aid, filler auxiliary agent, antistatic agent, antioxidant, silane
Collaboration compound system is formed under the effects of joining agent, ultraviolet absorbing agent, wear-resistant auxiliary agent, gained edge band has stronger chemically-resistant
Performance, heat-resisting, heatproof, dimensional stability, UV resistance etc., and production method is simple, it is high-efficient, market has been expanded to envelope
The demand of edge strip type selects space.
Specific embodiment
A specific embodiment of the invention is described further below.
Unless otherwise instructed, raw material employed in the present invention is commercially available or commonly used in the art, such as
Without special instruction, the method in following embodiments is the conventional method of this field.
Embodiment 1
A kind of edge band of bisphenol a polysulfone material, following component are made: bisphenol a polysulfone resin 80g, composite strengthening resin 40g,
It is terminal hydroxyl dimethyl-polysiloxane 20g, EVA lotion 6g, cross-linking aid 1g, nano silica 5g, ultraviolet absorbing agent 2g, hard
Resin acid 1g, antioxidant DNP 0.8g, Silane coupling agent KH550 0.6g, be chopped wood fibre 1g and short carbon fiber 0.6g,
In: composite strengthening resin is the mixing that ABS resin, polycarbonate and polyflon are 2:1:0.6 composition in mass ratio
Object；Cross-linking aid is respectively the mixture that component A, component B and component C are 10:1:5 composition in mass ratio, and wherein component A is alkane
Oxysilane, component B are dibutyltin dilaurate, and component C is acrylic acid；Ultraviolet absorbing agent is nanometer titanium dioxide titanium valve
The mixture at end and methyl acrylate, the two mass ratio 5:1.
The production method of the edge band of above-mentioned polysulfones material, comprising the following steps:
(1) EVA lotion and cross-linking aid room temperature are premixed stand 2h, nano silica, be chopped wood fibre with it is silane coupled
Agent KH550 room temperature premix stand, then with bisphenol a polysulfone resin, composite strengthening resin, terminal hydroxyl dimethyl-polysiloxane, purple
Ultraviolet absorbers, stearic acid, antioxidant DNP and short carbon fiber are thoroughly mixed 30min at 110 DEG C, then 230 DEG C of extrusions
It is granulated；
(2) gained particle is sent into double screw extruder and squeezes out, is cooled and shaped, the L/D of double screw extruder is 20:1, revolving speed
8r/min, temperature of each section are as follows: 270 DEG C of leading portion, 260 DEG C of middle section, 250 DEG C of back segment, 260 DEG C of head, 240 DEG C of mouth mold obtain bisphenol-A
The edge band of polysulfone resin material.
Embodiment 2
A kind of edge band of bisphenol a polysulfone material, following component are made: bisphenol a polysulfone resin 85g, composite strengthening resin 45g,
Terminal hydroxy group diethyl based polysiloxane 22.5g, EVA lotion 7g, cross-linking aid 1.5g, nano silica 7g, ultraviolet absorbing agent
2.25g, stearic acid 1.25g, antioxidant TNP 0.85g, Silane coupling agent KH550 0.7g, be chopped wood fibre 1.25g and short
Cut Carbon fibe 0.65g, in which: composite strengthening resin is that ABS resin, polycarbonate and polyflon are in mass ratio
The mixture of 2.25:1:0.7 composition；Cross-linking aid is respectively that component A, component B and component C are 10.5:1:5.25 in mass ratio
The mixture of composition, wherein component A is acetoxylsilane, and component B is dibutyltin dilaurate, and component C is acrylic acid；
Ultraviolet absorbing agent is the mixing of the mixture and methyl acrylate of nano titanium dioxide powder and nanometer titanium dioxide zirconium powder, is received
Rice titania powder and the mixture of nanometer titanium dioxide zirconium powder and the mass ratio 5.25:1 of methyl acrylate.
The production method of the edge band of above-mentioned polysulfones material, comprising the following steps:
(1) EVA lotion and cross-linking aid room temperature are premixed stand 2h, nano silica, be chopped wood fibre with it is silane coupled
Agent KH550 room temperature premix stands 90min, with bisphenol a polysulfone resin, composite strengthening resin, terminal hydroxy group diethyl based polysiloxane, purple
Ultraviolet absorbers, stearic acid, antioxidant TNP and short carbon fiber are thoroughly mixed 30min at 115 DEG C, then 230 DEG C of extrusions
It is granulated；
(2) gained particle is sent into double screw extruder and squeezes out, is cooled and shaped, the L/D of double screw extruder is 22:1, revolving speed
9r/min, temperature of each section are as follows: 275 DEG C of leading portion, 260 DEG C of middle section, 250 DEG C of back segment, 265 DEG C of head, 240 DEG C of mouth mold obtain bisphenol-A
The edge band of polysulfone resin material.
Embodiment 3
A kind of edge band of bisphenol a polysulfone material, following component are made: bisphenol a polysulfone resin 90g, composite strengthening resin 50g,
Terminal hydroxy ethylene dimethyl polysiloxane 25g, EVA lotion 8g, cross-linking aid 2g, nano diatomite 8g, ultraviolet absorbing agent
2.5, myristic acid 1.5g, antioxidant TPP 0.9g, silane coupling agent KH560 0.8g, tyre talc 1.5g and D-sorbite
0.7g, in which: composite strengthening resin is that ABS resin, polycarbonate and polyflon are 2.5:1:0.8 group in mass ratio
At mixture；Cross-linking aid is respectively the mixture that component A, component B and component C are 11:1:5.5 composition in mass ratio,
Middle component A is ethyl orthosilicate, and component B is stannous octoate, and component C is crotonic acid；Ultraviolet absorbing agent is nano zirconium dioxide
The mixture of powder and methyl acrylate, the two mass ratio 5.5:1.
The production method of the edge band of above-mentioned polysulfones material, comprising the following steps:
(1) EVA lotion and cross-linking aid room temperature premix are stood into 3h, nano diatomite, tyre talc and the room silane coupling agent KH560
Temperature premix stand 100min, then with bisphenol a polysulfone resin, composite strengthening resin, terminal hydroxy ethylene dimethyl polysiloxane,
Ultraviolet absorbing agent, myristic acid, antioxidant TPP and D-sorbite are thoroughly mixed 35min at 120 DEG C, then squeeze for 235 DEG C
It is granulated out；
(2) gained particle is sent into double screw extruder and squeezes out, is cooled and shaped, the L/D of double screw extruder is 23:1, revolving speed
9r/min, temperature of each section are as follows: 280 DEG C of leading portion, 265 DEG C of middle section, 255 DEG C of back segment, 270 DEG C of head, 2245 DEG C of mouth mold obtain bis-phenol
The edge band of A polysulfone resin material.
Embodiment 4
A kind of edge band of bisphenol a polysulfone material, following component are made: bisphenol a polysulfone resin 95g, composite strengthening resin 55g,
Terminal hydroxy ethylene diethyl based polysiloxane 27.5g, EVA lotion 9g, cross-linking aid 2.5g, nano mica powder 9g, ultraviolet light are inhaled
Receive agent 2.75g, lauric acid 1.75g, antioxidant CA 0.95g, silane coupling agent KH470 0.9g, calcium stearate 1.75g and ethyl alcohol
Amide 0.75g, in which: composite strengthening resin is that ABS resin, polycarbonate and polyflon are 2.75 in mass ratio:
1:0.9 the mixture of composition；Cross-linking aid is respectively that component A, component B and component C are what 11.5:1:5.75 was formed in mass ratio
Mixture, wherein component A is polyethyl methacrylate, and component B is dibutyl tin dimaleate, and component C is cinnamic acid；It is purple
Ultraviolet absorbers are the mixing of the mixture and methyl acrylate of nanometer titanium dioxide zirconium powder and nano tin dioxide powder, nanometer
The mass ratio 5.75:1 of the mixture and methyl acrylate of Zirconium dioxide powder and nano tin dioxide powder.
The production method of the edge band of above-mentioned polysulfones material, comprising the following steps:
(1) EVA lotion and cross-linking aid room temperature premix are stood into 4h, nano mica powder, calcium stearate and silane coupling agent KH470
Room temperature premix stand 110min, then with bisphenol a polysulfone resin, composite strengthening resin, the poly- silicon oxygen of terminal hydroxy ethylene diethyl
Alkane, ultraviolet absorbing agent, lauric acid, antioxidant CA and glycollic amide are thoroughly mixed 40min at 125 DEG C, then squeeze for 240 DEG C
It is granulated out；
(2) gained particle is sent into double screw extruder and squeezes out, is cooled and shaped, obtain the edge sealing of bisphenol a polysulfone resin material
Item, the L/D of double screw extruder are 24:1, revolving speed 11r/min, temperature of each section are as follows: 285 DEG C of leading portion, 270 DEG C of middle section, back segment 260
DEG C, 275 DEG C of head, 250 DEG C of mouth mold.
Embodiment 5
A kind of edge band of bisphenol a polysulfone material, following component are made: bisphenol a polysulfone resin 100g, composite strengthening resin 60g,
Hydrogeneous dimethyl polysiloxane 30g, EVA lotion 10g of terminal hydroxy group, cross-linking aid 3g, nano talc 10g, ultraviolet absorbing agent
3g, microcrystalline wax 2g, antioxidant BHT 1g, silane coupling agent KH570 1g, calcium stearate 2g and glycerol 0.8g, wherein: it is compound
Reinforced resin is the mixture that ABS resin, polycarbonate and polyflon are 3:1:1 composition in mass ratio；Crosslinking helps
Agent is respectively the mixture that component A, component B and component C are 12:1:6 composition in mass ratio, and wherein component A is polymethyl
Acid butyl ester, component B are dibutyltin diacetate, and component C is cinnamic acid；Ultraviolet absorbing agent is nano tin dioxide powder and third
The mixture of e pioic acid methyl ester, the two mass ratio 6:1.
The production method of the edge band of above-mentioned polysulfones material, comprising the following steps:
(1) EVA lotion and cross-linking aid room temperature premix are stood into 5h, nano talc, calcium stearate and silane coupling agent KH570
Room temperature premix stand 120min, then with bisphenol a polysulfone resin, composite strengthening resin, the hydrogeneous dimethyl polysiloxane of terminal hydroxy group, purple
Ultraviolet absorbers, microcrystalline wax, antioxidant BHT and glycerol are stirred 40min, then 240 DEG C of extruding pelletizations at 130 DEG C；
(2) gained particle is sent into double screw extruder and squeezes out, is cooled and shaped, obtain the edge sealing of bisphenol a polysulfone resin material
Item, the L/D of double screw extruder are 25:1, revolving speed 12r/min, temperature of each section are as follows: 290 DEG C of leading portion, 270 DEG C of middle section, back segment 260
DEG C, 280 DEG C of head, 250 DEG C of mouth mold.
Performance test
The size of sample and comparative example: long 100 × wide by 10 × thickness 3mm, according to standard QB/T4463-2013 " household edge band skill
Art requirement " physicochemical property of the edge band of Examples 1 to 5 and comparative example is tested, while also carrying out bending property test
And toughness test；
Bending property test: standard ISO178, rate of bending 2mm/min, span 64mm；
Toughness test: edge band is fixed on fixture, and applies the load-carrying of 1000g in the free end of edge band, then left and right
It is bent after swinging certain number, number of oscillations when record fractures.
Comparative example used is the ABS edge band of the identical size of Dongguan, Guangdong companies market, test result is as follows 1 institute of table
Show.
1 test result of table
It is resistance to ag(e)ing, resistance to from standard as can be seen that the edge band of organic silicon material of the invention is compared with commercially available ABS edge band
The good bending strength of cracking behavior, color fastness to light is slightly good, and meets the requirements of the standard, and overall performance is relatively better than commercially available ABS edge band.
Claims (10)
1. a kind of edge band of bisphenol a polysulfone material, which is characterized in that the edge band is made of the components of following parts:
80~100 parts of bisphenol a polysulfone resin, 40~60 parts of composite strengthening resin, 20~30 parts of hydroxyl organosilicon, EVA lotion 6~10
Part, 1~3 part of cross-linking aid, 5~10 parts of filler auxiliary agent, 2~3 parts of ultraviolet absorbing agent, 1~2 part of in-lubricant, antioxidant 0.8
~1 part, 0.6~1 part of silane coupling agent, 1~2 part of wear-resistant auxiliary agent and 0.6~0.8 part of antistatic agent.
2. edge band according to claim 1, which is characterized in that the composite strengthening resin is ABS resin, polycarbonate
It is in mass ratio the mixture that 2~3:1:0.6~1 is formed with polyflon.
3. edge band according to claim 1, which is characterized in that the hydroxyl organosilicon is the poly- silicon of terminal hydroxy group dimethyl
Oxygen alkane, terminal hydroxy group diethyl based polysiloxane, terminal hydroxy ethylene dimethyl polysiloxane, the poly- silicon oxygen of terminal hydroxy ethylene diethyl
One of alkane and the hydrogeneous dimethyl polysiloxane of terminal hydroxy group are a variety of.
4. edge band according to claim 1 or 3, which is characterized in that the cross-linking aid be respectively component A, component B and
Component C be in mass ratio 10~12:1:5~6 form mixture, wherein component A be alkoxy silane, acetoxylsilane,
One of ethyl orthosilicate, polyethyl methacrylate and polybutyl methacrylate, component B are dibutyltindilaurylmercaptide cinnamic acid
One of ester, stannous octoate, dibutyl tin dimaleate and dibutyltin diacetate, component C be acrylic acid, crotonic acid and
One of cinnamic acid.
5. edge band according to claim 1 or 2 or 3, which is characterized in that the filler auxiliary agent be nano silica,
One of nano diatomite, nano mica powder or nano talc are a variety of.
6. edge band according to claim 1 or 2 or 3, which is characterized in that the wear-resistant auxiliary agent be chopped wood fibre,
One of tyre talc and calcium stearate are a variety of.
7. edge band according to claim 1 or 2 or 3, which is characterized in that ultraviolet absorbing agent is nanometer titanium dioxide titanium valve
The mixture of at least one of end, Zirconium dioxide powder and stannic oxide powder with methyl acrylate, the two mass ratio 5~6:
1。
8. edge band according to claim 1 or 2 or 3, which is characterized in that the in-lubricant is stearic acid, nutmeg
One of acid, lauric acid and microcrystalline wax.
9. the production method of edge band as described in any of the claims 1 to 8, comprising the following steps:
(1) EVA lotion and cross-linking aid premix 2~5h, filler auxiliary agent, wear-resistant auxiliary agent and silane coupling agent premix is stood to stand
90~120min, then with bisphenol a polysulfone resin, composite strengthening resin, hydroxyl organosilicon, ultraviolet absorbing agent, interior lubrication
Agent, antioxidant and antistatic agent are thoroughly mixed 30~40min at 110~130 DEG C, then 230~240 DEG C of extruding pelletizations；
(2) gained particle is sent into double screw extruder and squeezes out, is cooled and shaped, obtain the edge sealing of bisphenol a polysulfone resin material
Item.
10. the production method of edge band according to claim 9, which is characterized in that the L/D of double screw extruder be 20~
25:1,8~12r/min of revolving speed, temperature of each section are as follows: 270~290 DEG C of leading portion, 260~270 DEG C of middle section, 250~260 DEG C of back segment,
260~280 DEG C of head, 240~250 DEG C of mouth mold.
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| CN201810671125.5A CN108976797B (en) | 2018-06-26 | 2018-06-26 | Edge banding made of bisphenol A polysulfone and production method thereof |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3345849A1 (en) * | 1983-12-19 | 1985-06-27 | Resopal Werk H. Römmler GmbH, 6800 Mannheim | Process for producing an edge band |
| EP0562166A1 (en) * | 1992-03-20 | 1993-09-29 | Alkor Gmbh Kunststoffe | Edge band made of polymers, its method of production and use |
| CN101475722A (en) * | 2008-07-22 | 2009-07-08 | 东莞市兄奕塑胶制品有限公司 | Formula of environment friendly edge banding strips |
| US20100004399A1 (en) * | 2008-07-01 | 2010-01-07 | Empting Jr Harry V | Edge Banding |
| DE102008046481A1 (en) * | 2008-09-09 | 2010-03-11 | Rehau Ag + Co. | Composite material, useful e.g. in outdoor area, preferably in form of fence, comprises natural fibers, thermoplastic or thermoplastic editable polymer, flame retardant e.g. halogen free compound and further additive, preferably lubricant |
| CN101798434A (en) * | 2010-03-20 | 2010-08-11 | 东莞市华立实业股份有限公司 | Furniture ABS resin sealing strip |
| CN105820433A (en) * | 2016-04-18 | 2016-08-03 | 东莞欧德雅装饰材料有限公司 | Polypropylene edge banding and preparation method |
| CN107674351A (en) * | 2017-09-22 | 2018-02-09 | 南京肯特复合材料股份有限公司 | Wear-resisting dust-free area sealing strip PTFE resin composite and preparation method thereof |
-
2018
- 2018-06-26 CN CN201810671125.5A patent/CN108976797B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3345849A1 (en) * | 1983-12-19 | 1985-06-27 | Resopal Werk H. Römmler GmbH, 6800 Mannheim | Process for producing an edge band |
| EP0562166A1 (en) * | 1992-03-20 | 1993-09-29 | Alkor Gmbh Kunststoffe | Edge band made of polymers, its method of production and use |
| US20100004399A1 (en) * | 2008-07-01 | 2010-01-07 | Empting Jr Harry V | Edge Banding |
| CN101475722A (en) * | 2008-07-22 | 2009-07-08 | 东莞市兄奕塑胶制品有限公司 | Formula of environment friendly edge banding strips |
| DE102008046481A1 (en) * | 2008-09-09 | 2010-03-11 | Rehau Ag + Co. | Composite material, useful e.g. in outdoor area, preferably in form of fence, comprises natural fibers, thermoplastic or thermoplastic editable polymer, flame retardant e.g. halogen free compound and further additive, preferably lubricant |
| CN101798434A (en) * | 2010-03-20 | 2010-08-11 | 东莞市华立实业股份有限公司 | Furniture ABS resin sealing strip |
| CN105820433A (en) * | 2016-04-18 | 2016-08-03 | 东莞欧德雅装饰材料有限公司 | Polypropylene edge banding and preparation method |
| CN107674351A (en) * | 2017-09-22 | 2018-02-09 | 南京肯特复合材料股份有限公司 | Wear-resisting dust-free area sealing strip PTFE resin composite and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 吴智慧等: "《家具用封边条技术要求》行业标准解读", 《家具》 * |
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