CN103613944A - Calcium, wood and plastic decorative plate - Google Patents
Calcium, wood and plastic decorative plate Download PDFInfo
- Publication number
- CN103613944A CN103613944A CN201310532619.2A CN201310532619A CN103613944A CN 103613944 A CN103613944 A CN 103613944A CN 201310532619 A CN201310532619 A CN 201310532619A CN 103613944 A CN103613944 A CN 103613944A
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- CN
- China
- Prior art keywords
- wood
- parts
- calcium
- plastic decorative
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004033 plastic Substances 0.000 title claims abstract description 23
- 229920003023 plastic Polymers 0.000 title claims abstract description 23
- 239000002023 wood Substances 0.000 title abstract description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title abstract 2
- 239000011575 calcium Substances 0.000 title abstract 2
- 229910052791 calcium Inorganic materials 0.000 title abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229920002522 Wood fibre Polymers 0.000 claims abstract description 8
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims abstract description 7
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 7
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 7
- 239000008116 calcium stearate Substances 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims abstract description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- 238000012986 modification Methods 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000004902 Softening Agent Substances 0.000 claims description 9
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 6
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 229940119170 jojoba wax Drugs 0.000 claims description 6
- 239000005543 nano-size silicon particle Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 230000000630 rising effect Effects 0.000 claims description 6
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 5
- 239000003063 flame retardant Substances 0.000 abstract description 3
- 239000004743 Polypropylene Substances 0.000 abstract description 2
- -1 polypropylene Polymers 0.000 abstract description 2
- 229920001155 polypropylene Polymers 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000002025 wood fiber Substances 0.000 abstract 1
- 229920001587 Wood-plastic composite Polymers 0.000 description 3
- 239000011155 wood-plastic composite Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229940089401 xylon Drugs 0.000 description 1
Abstract
The invention discloses a calcium, wood and plastic decorative plate, which is composed of the following raw materials in parts by weight: 60 to 70 parts of polypropylene resin particle, 70 to 75 parts of wood fiber, 4 to 6 parts of light calcium carbonate, 1 to 2 parts of anhydrous calcium chloride, 2 to 3 parts of calcium stearate, 2 to e parts of rosin, 1 to 2 parts of glycerin, 2 to 3 parts of sodium polyacrylate, 1 to 2 parts of aminopropyltriethoxysilane, 1 to 2 parts of chlorinated polyethylene, and 3 to 4 parts of modified plasticizer. The wood and plastic decorative plate provided by the invention has the advantages of greenness, energy saving, environment-friendliness, and good properties such as water resistance, acid and alkali resistance, and fire retardant property, and has a wood quality, wood feeling and wood grain similar to the natural wood material.
Description
Technical field
The present invention relates generally to a kind of composite material, relates in particular to a kind of calcium-wood-plastic decorative board.
Background technology
Wood plastic composite includes plastics and fiber, therefore, has the similar processing characteristics of same timber, can saw, can follow closely, can dig, and use carpenter's utensil to complete, and nail-holding ability is obviously better than other synthetic materialss.Mechanical property is better than wood materials.Nail-holding ability is generally 3 times of timber, is 5 times of shaving board.
Wood plastic composite includes plastics, thereby has good Young's modulus.In addition, due to including fiber and through fully mixing with plastics, thereby there is the resistance to compression suitable with hardwood, the physical and mechanical properties such as counter-bending, and its wearing quality is obviously better than normal wood material.Surface hardness is high, is generally 2 of timber---and 5 times.
Wood-plastic material and products thereof is compared with timber, can anti-strong acid-base, water-fast, corrosion-resistant, and do not breed bacterium, be difficult for being damaged by worms, long fungi.Long service life, can reach more than 50 years.
By auxiliary agent, the changes such as plastics polymerization, foaming can occur, solidify, modification, thus change the characteristics such as density, intensity of Wood-plastic material, can also reach anti-aging, anti-electrostatic, the particular requirement such as fire-retardant.
There is ultraviolet stability, tint permanence is good.Its great advantage turns waste into wealth exactly, and can 100% reclaiming produce.
Can decompose, can not cause " white pollution ", be real Green Product.
Raw material sources are extensive, and the plastic raw materials of producing wood plastic composite is mainly high density polyethylene(HDPE) or polypropylene, and wood fibre can be wood powder, cavings or xylon, also need in addition a small amount of additive and other processing aids.Can also as required, make arbitrary shape and size.
Summary of the invention
The object of the invention is just to provide a kind of calcium-wood-plastic decorative board.
The present invention is achieved by the following technical solutions:
A calcium-wood-plastic decorative board, it is comprised of the raw material of following weight parts:
Acrylic resin particle 60-70, wood fibre 70-75, light calcium carbonate 4-6, Calcium Chloride Powder Anhydrous 1-2, calcium stearate 2-3, rosin 2-3, glycerine 1-2, sodium polyacrylate 2-3, aminopropyltriethoxywerene werene 1-2, chlorinatedpolyethylene 1-2, modification softening agent 3-4;
Described modification softening agent is comprised of the raw material of following weight parts:
Sewer oil 30-40, phthalic ester 20-30, Viscotrol C 5-6, Jojoba oil 2-3, γ-aminopropyl triethoxysilane 1-2, nano silicon nitride aluminium powder 0.2-0.3, terpine resin 1-2, di-t-butyl peroxide 0.1-0.2, isocaprylic acid 0.1-0.2;
Above-mentioned terpine resin is heated to 80-100 ℃, insulation 10-15 minute, reduction temperature is 50-60 ℃, add γ-aminopropyl triethoxysilane, dispersed with stirring 3-5 minute, add successively phthalic ester, sewer oil, Viscotrol C, Jojoba oil, after interpolation, rising temperature is 90-100 ℃, fully stirs, add nano silicon nitride aluminium powder, isocaprylic acid, continuing rising temperature is 105-110 ℃, drips di-t-butyl peroxide, stirring reaction 1-2 hour, be cooled to normal temperature, obtain described modification softening agent.
A preparation method for calcium-wood-plastic decorative board, comprises the following steps:
It is 60-100 order that above-mentioned wood fibre oven dry is ground to form to fineness, water content is 2-3%, in temperature, is to heat 10-15 minute at 80-90 ℃, adds glycerine, calcium stearate, insulated and stirred 4-6 minute, reduction temperature is 50-60 ℃, adds aminopropyltriethoxywerene werene, after fully stirring, is cooled to normal temperature, add each raw material of residue, by twin screw extruder melt blending, extrude, moulding, obtains described calcium-wood-plastic decorative board.
Advantage of the present invention is:
Wood-plastic decorative board of the present invention is green, energy-saving and environmental protection, has wooden, wood sense and the wood grain of natural timber, and water tolerance, acid-alkali-corrosive-resisting, the performance such as fire-retardant are good.
Embodiment
Embodiment 1
A calcium-wood-plastic decorative board, it by following weight parts (kilogram) raw material form:
Acrylic resin particle 60, wood fibre 75, light calcium carbonate 6, Calcium Chloride Powder Anhydrous 1, calcium stearate 3, rosin 3, glycerine 1, sodium polyacrylate 3, aminopropyltriethoxywerene werene 1, chlorinatedpolyethylene 1, modification softening agent 3;
Described modification softening agent is comprised of the raw material of following weight parts:
Sewer oil 40, phthalic ester 30, Viscotrol C 5, Jojoba oil 3, γ-aminopropyl triethoxysilane 1, nano silicon nitride aluminium powder 0.3, terpine resin 1, di-t-butyl peroxide 0.2, isocaprylic acid 0.2;
Above-mentioned terpine resin is heated to 100 ℃, is incubated 15 minutes, reducing temperature is 60 ℃, add γ-aminopropyl triethoxysilane, dispersed with stirring 5 minutes, adds phthalic ester, sewer oil, Viscotrol C, Jojoba oil successively, after interpolation, rising temperature is 100 ℃, fully stirs, add nano silicon nitride aluminium powder, isocaprylic acid, continuing rising temperature is 110 ℃, drips di-t-butyl peroxide, stirring reaction 1-2 hour, be cooled to normal temperature, obtain described modification softening agent.
A preparation method for calcium-wood-plastic decorative board, comprises the following steps:
It is 60 orders that above-mentioned wood fibre oven dry is ground to form to fineness, water content is 3%, in temperature, is at 90 ℃, to heat 15 minutes, adds glycerine, calcium stearate, insulated and stirred 4 minutes, reducing temperature is 60 ℃, adds aminopropyltriethoxywerene werene, after fully stirring, is cooled to normal temperature, add each raw material of residue, by twin screw extruder melt blending, extrude, moulding, obtains described calcium-wood-plastic decorative board.
Performance test:
Flexural strength is 56.10MPa;
Modulus in flexure is 3.50GPa.
Claims (2)
1. a calcium-wood-plastic decorative board, is characterized in that what it was comprised of the raw material of following weight parts:
Acrylic resin particle 60-70, wood fibre 70-75, light calcium carbonate 4-6, Calcium Chloride Powder Anhydrous 1-2, calcium stearate 2-3, rosin 2-3, glycerine 1-2, sodium polyacrylate 2-3, aminopropyltriethoxywerene werene 1-2, chlorinatedpolyethylene 1-2, modification softening agent 3-4;
Described modification softening agent is comprised of the raw material of following weight parts:
Sewer oil 30-40, phthalic ester 20-30, Viscotrol C 5-6, Jojoba oil 2-3, γ-aminopropyl triethoxysilane 1-2, nano silicon nitride aluminium powder 0.2-0.3, terpine resin 1-2, di-t-butyl peroxide 0.1-0.2, isocaprylic acid 0.1-0.2;
Above-mentioned terpine resin is heated to 80-100 ℃, insulation 10-15 minute, reduction temperature is 50-60 ℃, add γ-aminopropyl triethoxysilane, dispersed with stirring 3-5 minute, add successively phthalic ester, sewer oil, Viscotrol C, Jojoba oil, after interpolation, rising temperature is 90-100 ℃, fully stirs, add nano silicon nitride aluminium powder, isocaprylic acid, continuing rising temperature is 105-110 ℃, drips di-t-butyl peroxide, stirring reaction 1-2 hour, be cooled to normal temperature, obtain described modification softening agent.
2. a preparation method for calcium-wood-plastic decorative board as claimed in claim 1, is characterized in that comprising the following steps:
It is 60-100 order that above-mentioned wood fibre oven dry is ground to form to fineness, water content is 2-3%, in temperature, is to heat 10-15 minute at 80-90 ℃, adds glycerine, calcium stearate, insulated and stirred 4-6 minute, reduction temperature is 50-60 ℃, adds aminopropyltriethoxywerene werene, after fully stirring, is cooled to normal temperature, add each raw material of residue, by twin screw extruder melt blending, extrude, moulding, obtains described calcium-wood-plastic decorative board.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532619.2A CN103613944B (en) | 2013-11-01 | 2013-11-01 | A kind of calcium-wood-plastic decorative board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532619.2A CN103613944B (en) | 2013-11-01 | 2013-11-01 | A kind of calcium-wood-plastic decorative board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103613944A true CN103613944A (en) | 2014-03-05 |
| CN103613944B CN103613944B (en) | 2016-04-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310532619.2A Active CN103613944B (en) | 2013-11-01 | 2013-11-01 | A kind of calcium-wood-plastic decorative board |
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| Country | Link |
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| CN (1) | CN103613944B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153722A (en) * | 2015-07-31 | 2015-12-16 | 濮阳市东宝科技发展有限公司 | Flame-retardant antibacterial wood plastic material and preparation method thereof |
| CN105348840A (en) * | 2015-12-14 | 2016-02-24 | 湖南工业大学 | Poplar powder based biomass composite material and preparation method thereof |
| CN105860365A (en) * | 2016-06-12 | 2016-08-17 | 南京旭华圣洛迪新型建材有限公司 | Fire-proof and damp-proof PVC compound stabilizer wood-plastic composite and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1621440A (en) * | 2004-10-21 | 2005-06-01 | 俞立群 | Plastic lignified board and its making method |
| CN101372539A (en) * | 2008-07-31 | 2009-02-25 | 浙江嘉澳化工有限公司 | Method for producing environment-friendly type plasticiser using waste oil and oil foot |
| CN101613503A (en) * | 2009-07-16 | 2009-12-30 | 浙江大学 | Water-resistant wood-plastic composite material and preparation method thereof |
| CN103102586A (en) * | 2011-11-15 | 2013-05-15 | 上海杰事杰新材料(集团)股份有限公司 | Fibrilia/polypropylene wear-resistant wood-plastic composite material and preparation method thereof |
-
2013
- 2013-11-01 CN CN201310532619.2A patent/CN103613944B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1621440A (en) * | 2004-10-21 | 2005-06-01 | 俞立群 | Plastic lignified board and its making method |
| CN101372539A (en) * | 2008-07-31 | 2009-02-25 | 浙江嘉澳化工有限公司 | Method for producing environment-friendly type plasticiser using waste oil and oil foot |
| CN101613503A (en) * | 2009-07-16 | 2009-12-30 | 浙江大学 | Water-resistant wood-plastic composite material and preparation method thereof |
| CN103102586A (en) * | 2011-11-15 | 2013-05-15 | 上海杰事杰新材料(集团)股份有限公司 | Fibrilia/polypropylene wear-resistant wood-plastic composite material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153722A (en) * | 2015-07-31 | 2015-12-16 | 濮阳市东宝科技发展有限公司 | Flame-retardant antibacterial wood plastic material and preparation method thereof |
| CN105348840A (en) * | 2015-12-14 | 2016-02-24 | 湖南工业大学 | Poplar powder based biomass composite material and preparation method thereof |
| CN105348840B (en) * | 2015-12-14 | 2018-05-18 | 湖南工业大学 | A kind of Poplar Powder based biomass composite material and preparation method thereof |
| CN105860365A (en) * | 2016-06-12 | 2016-08-17 | 南京旭华圣洛迪新型建材有限公司 | Fire-proof and damp-proof PVC compound stabilizer wood-plastic composite and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103613944B (en) | 2016-04-13 |
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Denomination of invention: Calcium, wood and plastic decorative plate Effective date of registration: 20171120 Granted publication date: 20160413 Pledgee: The development of small and medium-sized enterprises financing Company Limited by Guarantee Jieshou City Pledgor: Anhui Huanjia Tianyi Regeneration Resource Co.,Ltd. Registration number: 2017340000352 |
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Denomination of invention: Calcium, wood and plastic decorative plate Effective date of registration: 20181126 Granted publication date: 20160413 Pledgee: The development of small and medium-sized enterprises financing Company Limited by Guarantee Jieshou City Pledgor: Anhui Huanjia Tianyi Regeneration Resource Co.,Ltd. Registration number: 2018340000668 |
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Date of cancellation: 20191227 Granted publication date: 20160413 Pledgee: The development of small and medium-sized enterprises financing Company Limited by Guarantee Jieshou City Pledgor: Anhui Huanjia Tianyi Regeneration Resource Co.,Ltd. Registration number: 2018340000668 |