CN108976648A - A kind of PVC cable material with excellent fire-retardancy - Google Patents

A kind of PVC cable material with excellent fire-retardancy Download PDF

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Publication number
CN108976648A
CN108976648A CN201810627665.3A CN201810627665A CN108976648A CN 108976648 A CN108976648 A CN 108976648A CN 201810627665 A CN201810627665 A CN 201810627665A CN 108976648 A CN108976648 A CN 108976648A
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CN
China
Prior art keywords
parts
retardancy
chlorinated paraffin
excellent fire
flame
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810627665.3A
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Chinese (zh)
Inventor
叶明江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI ZHUOYUE CABLE Co Ltd
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ANHUI ZHUOYUE CABLE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI ZHUOYUE CABLE Co Ltd filed Critical ANHUI ZHUOYUE CABLE Co Ltd
Priority to CN201810627665.3A priority Critical patent/CN108976648A/en
Publication of CN108976648A publication Critical patent/CN108976648A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of PVC cable materials with excellent fire-retardancy, it is characterized in that, by following parts by weight at being grouped as: 74 parts of Corvic, 37 parts of flame-proof polyethylene, 5-11 parts of ethylene propylene diene rubber, 2-5 parts of methyl hydroxyethylcellulose, 2-9 parts of diisononyl phthalate, 2-6 parts of magnesium hydroxide, 2-5 parts of aluminium hydroxide, 3-6 parts of dibasic lead phosphite, 3-6 parts of nano-titanium dioxide, 4-8 parts of calcium stearate, 3-9 parts of calcium carbonate, 4-11 parts of chlorinated paraffin, 8-14 parts of bamboo charcoal powder, 6-9 parts of talcum powder, 12-18 parts of calcinated argil, 5-9 parts of kaolin, 2-5 parts of magnetite, 1-4 parts of alum, 3-9 parts of soybean oil.The present invention is made of environment-friendly materials, and effect at low cost is good, uses polyvinyl chloride resin as major ingredient, other materials is added, have synergistic effect.Magnesium hydroxide is fire retardant, increases anti-flammability of the invention;Electrical insulating property can be improved in chlorinated paraffin.

Description

A kind of PVC cable material with excellent fire-retardancy
Technical field
The present invention relates to a kind of cable material technical field more particularly to a kind of PVC cables with excellent fire-retardancy Material.
Background technique
With the rapid development of imbedded power cable laying work, to the requirements at the higher level that cable protection proposes, cable protection Set is a kind of protection most common electric insulating tube of electric wire and cable.Because having, insulation performance is good, chemical stability is high, does not give birth to Rust, is suitable for harsh environment and is applied extensively not aging.Cable sheath material not only needs excellent physical Can, such as tensile strength, elongation at break, while also needing to possess good flame retardant property.
Summary of the invention
In order to overcome the defects of the prior art described above, the object of the present invention is to provide a kind of with excellent fire-retardancy PVC cable material.
The present invention takes following technical scheme to realize: a kind of PVC cable material with excellent fire-retardancy, under Column parts by weight at being grouped as: 74 parts of Corvic, 37 parts of flame-proof polyethylene, 5-11 parts of ethylene propylene diene rubber, methyl hydroxyl 2-5 parts of ethyl cellulose, 2-9 parts of diisononyl phthalate, 2-6 parts of magnesium hydroxide, 2-5 parts of aluminium hydroxide, two alkali formulas are sub- 3-6 parts of lead phosphate, 3-6 parts of nano-titanium dioxide, 4-8 parts of calcium stearate, 3-9 parts of calcium carbonate, 4-11 parts of chlorinated paraffin, bamboo charcoal powder 8-14 parts, 6-9 parts of talcum powder, 12-18 parts of calcinated argil, 5-9 parts of kaolin, 2-5 parts of magnetite, 1-4 parts of alum, soybean oil 3-9 Part.
Above-mentioned a kind of PVC cable material with excellent fire-retardancy, by following parts by weight at being grouped as: polyvinyl chloride 74 parts of resin, 37 parts of flame-proof polyethylene, 5-10 parts of ethylene propylene diene rubber, 2-4 parts of methyl hydroxyethylcellulose, phthalic acid two 2-8 parts of different nonyl ester, 2-5 parts of magnesium hydroxide, 2-4 parts of aluminium hydroxide, 3-5 parts of dibasic lead phosphite, nano-titanium dioxide 3-5 Part, 4-7 parts of calcium stearate, 3-8 parts of calcium carbonate, 4-10 parts of chlorinated paraffin, 8-12 parts of bamboo charcoal powder, 6-8 parts of talcum powder, calcinated argil 12-17 parts, 5-8 parts of kaolin, 2-4 parts of magnetite, 1-3 parts of alum, 3-7 parts of soybean oil.
Above-mentioned a kind of PVC cable material with excellent fire-retardancy, by following parts by weight at being grouped as: polyvinyl chloride 74 parts of resin, 37 parts of flame-proof polyethylene, 7 parts of ethylene propylene diene rubber, 3 parts of methyl hydroxyethylcellulose, the different nonyl of phthalic acid two 5 parts of ester, 4 parts of magnesium hydroxide, 3 parts of aluminium hydroxide, 4 parts of dibasic lead phosphite, 4 parts of nano-titanium dioxide, 6 parts of calcium stearate, It is 5 parts of calcium carbonate, 8 parts of chlorinated paraffin, 10 parts of bamboo charcoal powder, 7 parts of talcum powder, 15 parts of calcinated argil, 6 parts of kaolin, 3 parts of magnetite, bright 2 parts of alum, 5 parts of soybean oil.
In summary the invention has the following advantages:
The present invention is made of environment-friendly materials, and effect at low cost is good, uses polyvinyl chloride resin as major ingredient, other materials is added, has Synergistic effect.Magnesium hydroxide is fire retardant, increases anti-flammability of the invention;Electrical insulating property can be improved in chlorinated paraffin;Calcium stearate The resistance to low temperature for improving CABLE MATERIALS, hardness, tensile strength and in terms of performance be greatly improved.
Specific embodiment
Specific embodiment 1:
A kind of PVC cable material with excellent fire-retardancy, by following parts by weight at being grouped as: 74 parts of Corvic, 37 parts of flame-proof polyethylene, 10 parts of ethylene propylene diene rubber, 4 parts of methyl hydroxyethylcellulose, 8 parts of diisononyl phthalate, hydrogen 5 parts of magnesia, 4 parts of aluminium hydroxide, 5 parts of dibasic lead phosphite, 5 parts of nano-titanium dioxide, 7 parts of calcium stearate, calcium carbonate 8 Part, 10 parts of chlorinated paraffin, 12 parts of bamboo charcoal powder, 8 parts of talcum powder, 17 parts of calcinated argil, 8 parts of kaolin, 4 parts of magnetite, 3 parts of alum, 7 parts of soybean oil.
Specific embodiment 2:
A kind of PVC cable material with excellent fire-retardancy, by following parts by weight at being grouped as: 74 parts of Corvic, 37 parts of flame-proof polyethylene, 7 parts of ethylene propylene diene rubber, 3 parts of methyl hydroxyethylcellulose, 5 parts of diisononyl phthalate, hydrogen-oxygen Change 4 parts of magnesium, 3 parts of aluminium hydroxide, 4 parts of dibasic lead phosphite, 4 parts of nano-titanium dioxide, 6 parts of calcium stearate, 5 parts of calcium carbonate, 8 parts of chlorinated paraffin, 10 parts of bamboo charcoal powder, 7 parts of talcum powder, 15 parts of calcinated argil, 6 parts of kaolin, 3 parts of magnetite, 2 parts of alum, soybean 5 parts of oil.
Specific embodiment 3:
A kind of PVC cable material with excellent fire-retardancy, by following parts by weight at being grouped as: 74 parts of Corvic, 37 parts of flame-proof polyethylene, 5 parts of ethylene propylene diene rubber, 2 parts of methyl hydroxyethylcellulose, 2 parts of diisononyl phthalate, hydrogen-oxygen Change 3 parts of magnesium, 2 parts of aluminium hydroxide, 3 parts of dibasic lead phosphite, 3 parts of nano-titanium dioxide, 4 parts of calcium stearate, 5 parts of calcium carbonate, 4 parts of chlorinated paraffin, 8 parts of bamboo charcoal powder, 6 parts of talcum powder, 12 parts of calcinated argil, 5 parts of kaolin, 2 parts of magnetite, 1 part of alum, soybean oil 3 parts.
Embodiment provided above is better embodiment of the invention, only is used to facilitate to illustrate the present invention, not to this hair It is bright to make any form of restriction, any those of ordinary skill in the art, if not departing from the proposed skill of the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from technical feature content of the invention, in the range of still falling within the technology of the present invention feature.

Claims (3)

1. a kind of PVC cable material with excellent fire-retardancy, which is characterized in that by following parts by weight at being grouped as: polychlorostyrene 74 parts of vinyl, 37 parts of flame-proof polyethylene, 5-11 parts of ethylene propylene diene rubber, 2-5 parts of methyl hydroxyethylcellulose, O-phthalic Sour dinonyl 2-9 parts, 2-6 parts of magnesium hydroxide, 2-5 parts of aluminium hydroxide, 3-6 parts of dibasic lead phosphite, nano-titanium dioxide 3-6 parts, 4-8 parts of calcium stearate, 3-9 parts of calcium carbonate, 4-11 parts of chlorinated paraffin, 8-14 parts of bamboo charcoal powder, 6-9 parts of talcum powder, calcining 12-18 parts of clay, 5-9 parts of kaolin, 2-5 parts of magnetite, 1-4 parts of alum, 3-9 parts of soybean oil.
2. a kind of PVC cable material with excellent fire-retardancy according to claim 1, which is characterized in that by following heavy Amount part at being grouped as: 74 parts of Corvic, 37 parts of flame-proof polyethylene, 5-10 parts of ethylene propylene diene rubber, dimethyl hydroxyethyl 2-4 parts of cellulose, 2-8 parts of diisononyl phthalate, 2-5 parts of magnesium hydroxide, 2-4 parts of aluminium hydroxide, two alkali formula phosphorous acid 3-5 parts of lead, 3-5 parts of nano-titanium dioxide, 4-7 parts of calcium stearate, 3-8 parts of calcium carbonate, 4-10 parts of chlorinated paraffin, bamboo charcoal powder 8-12 Part, 6-8 parts of talcum powder, 12-17 parts of calcinated argil, 5-8 parts of kaolin, 2-4 parts of magnetite, 1-3 parts of alum, 3-7 parts of soybean oil.
3. a kind of PVC cable material with excellent fire-retardancy according to claim 1, which is characterized in that by following heavy Amount part at being grouped as: 74 parts of Corvic, 37 parts of flame-proof polyethylene, 7 parts of ethylene propylene diene rubber, methyl hydroxyethyl cellulose Plain 3 parts, 5 parts of diisononyl phthalate, 4 parts of magnesium hydroxide, 3 parts of aluminium hydroxide, 4 part, nanometer two of dibasic lead phosphite 4 parts of titanium oxide, 6 parts of calcium stearate, 5 parts of calcium carbonate, 8 parts of chlorinated paraffin, 10 parts of bamboo charcoal powder, 7 parts of talcum powder, calcinated argil 15 Part, 6 parts of kaolin, 3 parts of magnetite, 2 parts of alum, 5 parts of soybean oil.
CN201810627665.3A 2018-06-19 2018-06-19 A kind of PVC cable material with excellent fire-retardancy Withdrawn CN108976648A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810627665.3A CN108976648A (en) 2018-06-19 2018-06-19 A kind of PVC cable material with excellent fire-retardancy

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Application Number Priority Date Filing Date Title
CN201810627665.3A CN108976648A (en) 2018-06-19 2018-06-19 A kind of PVC cable material with excellent fire-retardancy

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112980068A (en) * 2021-03-08 2021-06-18 上海瀛宏汽车配件有限公司 Anti-aging rubber composition for automobile parts

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112980068A (en) * 2021-03-08 2021-06-18 上海瀛宏汽车配件有限公司 Anti-aging rubber composition for automobile parts

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Application publication date: 20181211