CN108973292A - A kind of high-strength waterproof production method for furniture - Google Patents

A kind of high-strength waterproof production method for furniture Download PDF

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Publication number
CN108973292A
CN108973292A CN201810827088.2A CN201810827088A CN108973292A CN 108973292 A CN108973292 A CN 108973292A CN 201810827088 A CN201810827088 A CN 201810827088A CN 108973292 A CN108973292 A CN 108973292A
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CN
China
Prior art keywords
paper
waterproof
production method
strength waterproof
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810827088.2A
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Chinese (zh)
Inventor
黄庆中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Dongzheng Home Science And Technology Development Co Ltd
Original Assignee
Shenzhen Dongzheng Home Science And Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Dongzheng Home Science And Technology Development Co Ltd filed Critical Shenzhen Dongzheng Home Science And Technology Development Co Ltd
Priority to CN201810827088.2A priority Critical patent/CN108973292A/en
Publication of CN108973292A publication Critical patent/CN108973292A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B29/005Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/06Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments

Abstract

The invention discloses a kind of high-strength waterproof production methods for furniture, and described specific step is as follows: selecting chipboard to brush selected fine paper pulp as matrix and its surface, form the biggish fine pulp layer of one layer of density on the bilateral surface layer of chipboard;Amylan is brushed on its surface again, papers waterproof kraft paper;Using 140 DEG C of -160 DEG C of degree high temperature, pressing sizing;Specific step is as follows for the paper waterproof kraft paper: waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected on brown paper by force (forcing) pump;It is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C -120 DEG C;Brown paper after grey board and heating is carried out to mounting, while continuously adding amylan in machine drum and carrying out kiss-coating roller coating;Heating box of entering is conveyed, continuously exports and is cut into and open.Waterproof board folding strength made of the present invention is high, waterproof performance is good, and the amylan used achievees the purpose that environmental protection without containing harmful substances such as formaldehyde.

Description

A kind of high-strength waterproof production method for furniture
Technical field
The present invention relates to furniture part technical field more particularly to a kind of high-strength waterproof production sides for furniture Method.
Background technique
Furniture refers to that the mankind maintain normal life, are engaged in production practices and carry out the essential utensil facility of social activities Major class.Furniture also follows the step in epoch to continue to develop innovation, and of a great variety by now, materials are different, great variety of goods, and purposes is not One.It is the important foundation for establishing Working Life space.Furniture is made of material, structure, appearance forrns and function four factors, Wherein function is guide, is the power for pushing furniture development;Structure is trunk, is the basis for realizing function.These four factors are mutual It is associated, and conditions each other.Since furniture is to meet the certain material requisite of people and the design and fabrication using purpose , therefore the factor in terms of furniture also has material and appearance forrns.
Existing furniture uses wood as material mostly, and the baffle partition of antique traditional furniture is all made of straw board or artificial Plank, there are mutability damages, and poor waterproof properties, intensity is low, are not easy bending, not environmentally the disadvantages of.
Summary of the invention
The purpose of the present invention is to solve the problems of the prior art, and a kind of high intensity for furniture proposed is anti- Water production method.
To achieve the goals above, present invention employs following technical solutions:
A kind of high-strength waterproof production method for furniture, described specific step is as follows:
(1), chipboard is selected to brush selected fine paper pulp as matrix and its surface, in the bilateral surface layer shape of chipboard At the biggish fine pulp layer of one layer of density;
(2), amylan is brushed on its surface again, papers waterproof kraft paper;
(3), using 140 DEG C of -160 DEG C of degree high temperature, pressing sizing.
Preferably, specific step is as follows for paper waterproof kraft paper in the step (2):
(A), waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected in ox by force (forcing) pump On mulberry paper;
(B), it is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C -120 DEG C;
(C), the brown paper after grey board and heating is carried out to mounting, at the same continuously add in machine drum amylan into Row kiss-coating roller coating;
(D), heating box of entering is conveyed, continuously exports and is cut into and open.
Preferably, the waterproof kraft paper with a thickness of 1.3 millimeters -1.6 millimeters, and hung one layer on waterproof ox-hide facial tissue Paper pastes 100g-200g.
Preferably, graphene oxide is added in the general paper pulp that fine paper pulp is spent by 20 degree -30 of beating degree in the step (1) Solution 200ml-400ml, uniform stirring are made.
Preferably, the piece diameter for the graphene oxide of the graphene oxide solution used is -1000 mesh of 200 mesh.
Preferably, the density of the fine pulp layer in the step (1) is 340g/mL-420g/mL.
Preferably, it is 2-4 times that the number of selected fine paper pulp is brushed on the surface in the step (1).
Preferably, pressing sizing is carried out in pressing machine in the step (3), pressing machine model XSC-5000- 200。
Preferably, in the step (D) conveying enter heating box when, the internal temperature of heating box is 60 DEG C -90 DEG C.
Preferably, high-strength waterproof cardboard is formed after pressing sizing in the step (3), and high-strength waterproof cardboard is strong Degree >=890KPa.
Compared with prior art, the present invention provides a kind of high-strength waterproof production method for furniture, have Below the utility model has the advantages that
(1), the amylan that the present invention uses achievees the purpose that environmental protection without containing harmful substances such as formaldehyde.
(2), selected fine paper pulp and paper waterproof kraft paper are brushed in chipboard surface of the present invention, can be improved cardboard Waterproof performance, and joined graphene oxide in fine paper pulp, graphene oxide can be well dispersed in water, and surface is contained A large amount of oxygen-containing functional group, such as carboxyl hydroxyl, methoxyl group, ehter bond, these oxygen-containing functional groups, can on paper pulp fiber Great amount of hydroxy group combines, and forms hydrogen bond, increases pulp strength performance, to must further improve the intensity of waterproof board.
It is not directed to part in the device to be the same as those in the prior art or can be realized by using the prior art, structure of the invention Simply, easy to operate.
Detailed description of the invention
Fig. 1 is a kind of flow chart of the high-strength waterproof production method for furniture proposed by the present invention;
Fig. 2 is a kind of paper waterproof kraft paper of the high-strength waterproof production method for furniture proposed by the present invention Flow process chart.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
In the description of the present invention, it is to be understood that, term " on ", "lower", "front", "rear", "left", "right", "top", The orientation or positional relationship of the instructions such as "bottom", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, merely to just In description the present invention and simplify description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with Specific orientation construction and operation, therefore be not considered as limiting the invention.
A kind of high-strength waterproof production method for furniture, described specific step is as follows:
(1), chipboard is selected to brush selected fine paper pulp as matrix and its surface, in the bilateral surface layer shape of chipboard At the biggish fine pulp layer of one layer of density;
(2), amylan is brushed on its surface again, papers waterproof kraft paper;
(3), using 140 DEG C of -160 DEG C of degree high temperature, pressing sizing.
Specific step is as follows for paper waterproof kraft paper in the step (2):
(A), waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected in ox by force (forcing) pump On mulberry paper;
(B), it is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C -120 DEG C, and brown paper is allowed to generate heat;
(C), the brown paper after grey board and heating is carried out to mounting, at the same continuously add in machine drum amylan into Row kiss-coating roller coating;
(D), heating box of entering is conveyed, continuously exports and is cut into and open.
The waterproof kraft paper has hung one layer of paper paste with a thickness of 1.3 millimeters -1.6 millimeters, and on waterproof ox-hide facial tissue 100g-200g, waterproof ox-hide facial tissue have hung one layer of paper and have pasted 100 grams, and waterproof performance is exactly 100 seconds or more, if being suspended to 200 Gram be exactly 200 seconds or more.
Graphene oxide solution is added in the general paper pulp that fine paper pulp is spent by 20 degree -30 of beating degree in the step (1) 200ml-400ml, uniform stirring are made.
The piece diameter for the graphene oxide of the graphene oxide solution used is -1000 mesh of 200 mesh, graphene oxide energy It is well dispersed in water, a large amount of oxygen-containing functional group, such as carboxyl hydroxyl, methoxyl group, ehter bond, these polarity are contained in surface Group is well dispersed in graphene oxide in water, stands some months and coagulation phenomenon does not occur, therefore can use this spy Graphene oxide is dispersed in paper pulp dispersion liquid by property, makes it possible the compound of graphene and its oxide and paper pulp fiber, Secondly, these oxygen-containing functional groups, can form hydrogen bond in conjunction with the great amount of hydroxy group on paper pulp fiber, increase pulp strength performance Add, to must further improve the intensity of waterproof board.
The density of fine pulp layer in the step (1) is 340g/mL-420g/mL.
The number that selected fine paper pulp is brushed on surface in the step (1) is 2-4 times.
Pressing sizing is carried out in pressing machine in the step (3), pressing machine model XSC-5000-200.
In the step (D) conveying enter heating box when, the internal temperature of heating box is 60 DEG C -90 DEG C.
Formation high-strength waterproof cardboard after pressing sizing in the step (3), and the intensity of high-strength waterproof cardboard >= 890KPa。
Embodiment 1
As shown in Figs. 1-2, a kind of high-strength waterproof production method for furniture, described specific step is as follows:
(1), chipboard is selected to brush selected fine paper pulp as matrix and its surface, in the bilateral surface layer shape of chipboard At the biggish fine pulp layer of one layer of density;
(2), amylan is brushed on its surface again, papers waterproof kraft paper;
(3), using 150 DEG C of degree high temperature, pressing sizing.
Specific step is as follows for paper waterproof kraft paper in step (2):
(A), waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected in ox by force (forcing) pump On mulberry paper;
(B), it is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C, and brown paper is allowed to generate heat;
(C), the brown paper after grey board and heating is carried out to mounting, at the same continuously add in machine drum amylan into Row kiss-coating roller coating;
(D), heating box of entering is conveyed, continuously exports and is cut into and open.
The waterproof kraft paper has hung one layer of paper paste 100g with a thickness of 1.6 millimeters, and on waterproof ox-hide facial tissue.
Graphene oxide solution 200ml is added by 25 degree of beating degree of general paper pulp in fine paper pulp in the step (1), Even stirring is made.
The piece diameter for the graphene oxide of the graphene oxide solution used is 200 mesh.
The density of fine pulp layer in the step (1) is 340g/mL.
The number that selected fine paper pulp is brushed on surface in the step (1) is 3 times.
Pressing sizing is carried out in pressing machine in the step (3), pressing machine model XSC-5000-200.
In the step (D) conveying enter heating box when, the internal temperature of heating box is 90 DEG C.
Embodiment 2
As shown in Figs. 1-2, a kind of high-strength waterproof production method for furniture, a kind of high intensity for furniture Waterproof board production method, described specific step is as follows:
(1), chipboard is selected to brush selected fine paper pulp as matrix and its surface, in the bilateral surface layer shape of chipboard At the biggish fine pulp layer of one layer of density;
(2), amylan is brushed on its surface again, papers waterproof kraft paper;
(3), using 150 DEG C of degree high temperature, pressing sizing.
Specific step is as follows for paper waterproof kraft paper in step (2):
(A), waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected in ox by force (forcing) pump On mulberry paper;
(B), it is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C, and brown paper is allowed to generate heat;
(C), the brown paper after grey board and heating is carried out to mounting, at the same continuously add in machine drum amylan into Row kiss-coating roller coating;
(D), heating box of entering is conveyed, continuously exports and is cut into and open.
The waterproof kraft paper has hung one layer of paper paste 100g with a thickness of 1.6 millimeters, and on waterproof ox-hide facial tissue.
Graphene oxide solution 200ml is added by 25 degree of beating degree of general paper pulp in fine paper pulp in the step (1), Even stirring is made.
The piece diameter for the graphene oxide of the graphene oxide solution used is 300 mesh.
The density of fine pulp layer in the step (1) is 340g/mL.
The number that selected fine paper pulp is brushed on surface in the step (1) is 3 times.
Pressing sizing is carried out in pressing machine in the step (3), pressing machine model XSC-5000-200.
In the step (D) conveying enter heating box when, the internal temperature of heating box is 90 DEG C.
Embodiment 3
As shown in Figs. 1-2, a kind of high-strength waterproof production method for furniture, a kind of high intensity for furniture Waterproof board production method, described specific step is as follows:
(1), chipboard is selected to brush selected fine paper pulp as matrix and its surface, in the bilateral surface layer shape of chipboard At the biggish fine pulp layer of one layer of density;
(2), amylan is brushed on its surface again, papers waterproof kraft paper;
(3), using 150 DEG C of degree high temperature, pressing sizing.
Specific step is as follows for paper waterproof kraft paper in step (2):
(A), waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected in ox by force (forcing) pump On mulberry paper;
(B), it is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C, and brown paper is allowed to generate heat;
(C), the brown paper after grey board and heating is carried out to mounting, at the same continuously add in machine drum amylan into Row kiss-coating roller coating;
(D), heating box of entering is conveyed, continuously exports and is cut into and open.
The waterproof kraft paper has hung one layer of paper paste 100g with a thickness of 1.6 millimeters, and on waterproof ox-hide facial tissue.
Graphene oxide solution 200ml is added by 25 degree of beating degree of general paper pulp in fine paper pulp in the step (1), Even stirring is made.
The piece diameter for the graphene oxide of the graphene oxide solution used is 1000 mesh.
The density of fine pulp layer in the step (1) is 340g/mL.
The number that selected fine paper pulp is brushed on surface in the step (1) is 3 times.
Pressing sizing is carried out in pressing machine in the step (3), pressing machine model XSC-5000-200.
In the step (D) conveying enter heating box when, the internal temperature of heating box is 90 DEG C.
Embodiment 4
As shown in Figs. 1-2, a kind of high-strength waterproof production method for furniture, a kind of high intensity for furniture Waterproof board production method, described specific step is as follows:
(1), chipboard is selected to brush selected fine paper pulp as matrix and its surface, in the bilateral surface layer shape of chipboard At the biggish fine pulp layer of one layer of density;
(2), amylan is brushed on its surface again, papers waterproof kraft paper;
(3), using 150 DEG C of degree high temperature, pressing sizing.
Specific step is as follows for paper waterproof kraft paper in step (2):
(A), waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected in ox by force (forcing) pump On mulberry paper;
(B), it is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C, and brown paper is allowed to generate heat;
(C), the brown paper after grey board and heating is carried out to mounting, at the same continuously add in machine drum amylan into Row kiss-coating roller coating;
(D), heating box of entering is conveyed, continuously exports and is cut into and open.
The waterproof kraft paper has hung one layer of paper paste 100g with a thickness of 1.6 millimeters, and on waterproof ox-hide facial tissue.
The density of fine pulp layer in the step (1) is 340g/mL.
The number that selected fine paper pulp is brushed on surface in the step (1) is 3 times.
Pressing sizing is carried out in pressing machine in the step (3), pressing machine model XSC-5000-200.
In the step (D) conveying enter heating box when, the internal temperature of heating box is 90 DEG C.
Table 1 is the piece diameter of different graphene oxides to the tensile index of waterproof board and the influence of water-resistance:
Table 1
The paper mold folding strength of the invention from table 1 is high, and tensile index is most in 300 mesh for the piece diameter of graphene oxide Greatly, the piece diameter of graphene oxide is excessive too small all bad.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of high-strength waterproof production method for furniture, which is characterized in that described specific step is as follows:
(1), it selects chipboard to brush selected fine paper pulp as matrix and its surface, forms one on the bilateral surface layer of chipboard The layer biggish fine pulp layer of density;
(2), amylan is brushed on its surface again, papers waterproof kraft paper;
(3), using 140 DEG C of -160 DEG C of degree high temperature, pressing sizing.
2. a kind of high-strength waterproof production method for furniture according to claim 1, which is characterized in that described Specific step is as follows for paper waterproof kraft paper in step (2):
(A), waste paper paste is made into brown paper, and starch is cooked into paste paddle mist by steam boiler, is injected in brown paper by force (forcing) pump On;
(B), it is heated at the brown paper of roll, hot cylinder temperature is 90 DEG C -120 DEG C;
(C), the brown paper after grey board and heating is carried out to mounting, while continuously adds amylan in machine drum and is hung Rubber-surfaced roll applies;
(D), heating box of entering is conveyed, continuously exports and is cut into and open.
3. a kind of high-strength waterproof production method for furniture according to claim 2, which is characterized in that described Waterproof kraft paper has hung one layer of paper paste 100g-200g with a thickness of 1.3 millimeters -1.6 millimeters, and on waterproof ox-hide facial tissue.
4. a kind of high-strength waterproof production method for furniture according to claim 1, which is characterized in that described Graphene oxide solution 200ml-400ml is added in the general paper pulp that fine paper pulp is spent by 20 degree -30 of beating degree in step (1), Even stirring is made.
5. a kind of high-strength waterproof production method for furniture according to claim 4, which is characterized in that described The piece diameter for the graphene oxide of graphene oxide solution used is -1000 mesh of 200 mesh.
6. a kind of high-strength waterproof production method for furniture according to claim 1, which is characterized in that described The density of fine pulp layer in step (1) is 340g/mL-420g/mL.
7. a kind of high-strength waterproof production method for furniture according to claim 1, which is characterized in that described The number that selected fine paper pulp is brushed on surface in step (1) is 2-4 times.
8. a kind of high-strength waterproof production method for furniture according to claim 1, which is characterized in that described Pressing sizing is carried out in pressing machine in step (3), pressing machine model XSC-5000-200.
9. a kind of high-strength waterproof production method for furniture according to claim 2, which is characterized in that described In step (D) conveying enter heating box when, the internal temperature of heating box is 60 DEG C -90 DEG C.
10. a kind of high-strength waterproof production method for furniture according to claim 1, which is characterized in that institute It states and forms high-strength waterproof cardboard, and intensity >=890KPa of high-strength waterproof cardboard in step (3) after pressing sizing.
CN201810827088.2A 2018-07-25 2018-07-25 A kind of high-strength waterproof production method for furniture Pending CN108973292A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810827088.2A CN108973292A (en) 2018-07-25 2018-07-25 A kind of high-strength waterproof production method for furniture

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Application Number Priority Date Filing Date Title
CN201810827088.2A CN108973292A (en) 2018-07-25 2018-07-25 A kind of high-strength waterproof production method for furniture

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Publication Number Publication Date
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Application Number Title Priority Date Filing Date
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1316030A (en) * 1998-09-03 2001-10-03 斯托拉·科帕伯格斯·伯格斯拉格斯公司 Paper or paperboard laminate and method to produce such laminate
CN106320062A (en) * 2016-08-31 2017-01-11 北京碳世纪科技有限公司 Method of adding graphene to improve elastic modulus of paper
CN207359804U (en) * 2017-08-07 2018-05-15 无锡海特新材料研究院有限公司 A kind of waterproof board

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1316030A (en) * 1998-09-03 2001-10-03 斯托拉·科帕伯格斯·伯格斯拉格斯公司 Paper or paperboard laminate and method to produce such laminate
CN106320062A (en) * 2016-08-31 2017-01-11 北京碳世纪科技有限公司 Method of adding graphene to improve elastic modulus of paper
CN207359804U (en) * 2017-08-07 2018-05-15 无锡海特新材料研究院有限公司 A kind of waterproof board

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