CN107174155B - A kind of toilet paper prepared using bleaching process - Google Patents
A kind of toilet paper prepared using bleaching process Download PDFInfo
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- CN107174155B CN107174155B CN201710448629.6A CN201710448629A CN107174155B CN 107174155 B CN107174155 B CN 107174155B CN 201710448629 A CN201710448629 A CN 201710448629A CN 107174155 B CN107174155 B CN 107174155B
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/001—Heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/003—Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
- B27K5/0065—Ultrasonic treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K9/00—Chemical or physical treatment of reed, straw, or similar material
- B27K9/002—Cane, bamboo
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/02—Pretreatment of the raw materials by chemical or physical means
- D21B1/021—Pretreatment of the raw materials by chemical or physical means by chemical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2200/00—Wooden materials to be treated
- B27K2200/15—Pretreated particles or fibres
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Forests & Forestry (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
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- Sanitary Thin Papers (AREA)
Abstract
The invention discloses a kind of toilet papers prepared using bleaching process, belong to pulp technology for making paper, the toilet paper is by secondary pretreatment, washing, screening, bleaching, defibrination, decontamination degassing, screening the pulp, squeezing, drying, press polish, batches, rewinding, cuts, made of packaging step.The brightness of toilet paper prepared by the present invention, tensile index, pliability are high；The toilet paper of production does not have any stimulation or adverse reaction to human skin.
Description
[technical field]
The invention belongs to pulp technology for making paper, and in particular to a kind of toilet paper prepared using bleaching process.
[background technique]
The production method of paper pulp mainly includes the productions stream such as chemical method, semichemical method, Mechanical Method and chemical mechanical pulping at present
Journey.Wherein chemical pulping is occupied an leading position among current numerous pulping process.Claim by paper pulp made from chemical method boiling
For true qualities paper pulp, true qualities paper pulp limits its application since whiteness is lower, and true qualities paper pulp will could generally give birth to after bleaching
Produce the paper kind of higher level.
Paper for daily use, particularly toilet paper are a kind of common daily consumption articles, still, in psychologically to whiteness
It needs and the demand to some physical indexs, generallys use the pulp manufacture based on bleached wood pulp.Even if being starched using herb
Prepare toilet paper, also all use bleached pulp, however gained paper pulp yield and whiteness are still lower, the brightness of toilet paper, tensile index,
Pliability is not also high.
With the continuous expansion of paper industry, constantly opening up for pulp applications is wide, originally the wood as main paper making raw material
Gradually supply falls short of demand for material, and forest is caused excessively to be cut down, and influences ecological environment, therefore, it is necessary to seek new raw material substituent.
Sinocalamus latiflorus (Dendrocalamus latiflorus Munro) is that south China cultivates most wide one of bamboo kind, is standing grain
Undergraduate course (Poaceae) Bambusoideae (Bambusoideae) Dendrocalamus (Dendrocalamus) large-scale sympodial bamboo kind, is distributed mainly on
The provinces and regions such as Fujian, TaiWan, China, Guangdong and Guangxi Provinces, Yunnan, Hainan, Sichuan, the Guizhou middle and south are protected for edible, material use, Ye Yong, water and soil
It holds, afforest the multipurposes bamboo kind such as ornamental, to produce bamboo shoot or do based on pulpwood.Sinocalamus latiflorus growth is fast, the bamboo shoot phase is long, yield is high, bamboo shoot are of fine quality
Good, sinocalamus latiflorus fast growing is widely used, and primary plant utilizes for many years, is that a kind of economic value is high, excellent calculation profitable on ecology
The dual-purpose bamboo kind of material, economic benefit, ecological benefits and social benefit Three benefits are significant.
Therefore be conducive to avoid result in forest and excessively cut down as wood raw material is replaced using artificial growth sinocalamus latiflorus, influence
Ecological environment.
[summary of the invention]
It is provided by the invention it is a kind of using bleaching process prepare toilet paper, with solve how to improve sinocalamus latiflorus paper pulp yield and
Whiteness improves the problem of producing toilet paper quality.
In order to solve the above technical problems, the present invention uses following technical matters:
A kind of toilet paper prepared using bleaching process, is by secondary pretreatment, washing, screening, bleaching, defibrination, gone
Dirty degassing, squeezing, drying, press polish, is batched, rewinding, is cut, made of packaging step at screening the pulp.
Further, the toilet paper prepared using bleaching process, preparation method, comprising the following steps:
S1: being cut into sinocalamus latiflorus piece for sinocalamus latiflorus and crush, and gained crushed material is delivered in primary pretreatment immersion liquid A, described
Primary pretreatment immersion liquid A, including following raw material: alkyl phenol polyoxyethylene ether, triethanolamine, stearic acid, oleic acid, lauric acid, water,
Immersion 26-40min is carried out under ultrasonic wave effect, is then filtered, leaching material A is obtained；
S2: leaching material A made from step S1 is delivered in secondary pretreatment immersion liquid B, the secondary pretreatment immersion liquid B includes
Following raw material: percarbamide, potassium hydroxide, amino carboxylic acid, vanadic anhydride, water are steamed at being 142-160 DEG C in temperature
It boils, then filters, obtain leaching material B；
S3: leaching material B made from step S2 is washed with 60-80 DEG C of hot water, then screens, bleach, health is made
Paper bleached pulp；
S4: carrying out defibrination again with bleached pulp for toilet paper made from step S3, and screened stock is made；
S5: screened stock made from step S4 is subjected to decontamination degassing, is then put into head box and is squeezed after screening the pulp, then connect
Drying, press polish, batch, finished product sinocalamus latiflorus body paper；
S6: finished product sinocalamus latiflorus body paper made from step S5 is subjected to rewinding, cuts, pack, finished product toilet paper.
Further, the size of sinocalamus latiflorus piece described in step S1 is 20-30mm × 2.8-3.7mm × 1.2-2.5mm.
Further, the ratio between sinocalamus latiflorus crushed material weight described in step S1 and primary pretreatment immersion liquid A volume are 1:1.5-
3.5。
Further, immersion liquid A is once pre-processed described in step S1 as unit of parts by weight, including following raw material: alkyl
4-8 parts of phenol polyethenoxy ether, 0.3-0.6 parts of triethanolamine, 0.5-1 parts of stearic acid, 0.4-1.2 parts of oleic acid, lauric acid 0.8-
1.5 parts, 42-90 parts of water.
Further, ultrasonic power described in step S1 is 30-50W, and temperature is 43-48 DEG C.
Further, the ratio between the A weight and secondary pretreatment immersion liquid B volume of leaching material described in step S2 are 1:5.6-12.3.
Further, immersion liquid B described in step S2 is as unit of parts by weight, including following raw material: percarbamide 10-20
Part, 4-6 parts of potassium hydroxide, 0.3-0.5 parts of amino carboxylic acid, 0.1-0.2 parts of vanadic anhydride, 35-150 parts of water.
Further, the time of boiling described in step S2 is 1.5-2h.
Further, washing described in step S3 to pH value is 6.8-7.2.
The invention has the following advantages:
(1) addition of percarbamide, amino carboxylic acid, vanadic anhydride plays synergistic effect, improves paper pulp yield
And whiteness；
(2) alkyl phenol polyoxyethylene ether, triethanolamine, stearic acid, oleic acid, lauric addition play synergistic effect,
Improve paper pulp yield and whiteness；
(3) paper pulp yield made from method of the invention and whiteness be significantly above paper pulp yield made from the prior art and
Whiteness；
(4) addition of percarbamide, amino carboxylic acid, vanadic anhydride plays synergistic effect, improves toilet paper
Brightness, tensile index, pliability；
(5) alkyl phenol polyoxyethylene ether, triethanolamine, stearic acid, oleic acid, lauric addition play synergistic effect,
Improve brightness, the tensile index, pliability of toilet paper；
(6) brightness of toilet paper prepared by the present invention, tensile index, pliability are significantly above made from the prior art and defend
The brightness of raw paper, tensile index, pliability；
(7) toilet paper produced does not have any stimulation or adverse reaction to human skin.
[specific embodiment]
It to facilitate a better understanding of the present invention, is illustrated by following embodiment, these embodiments belong to of the invention
Protection scope, but do not limit the scope of the invention.
In embodiment, the preparation method of the toilet paper of bleaching process preparation is utilized, comprising the following steps:
S1: being cut into sinocalamus latiflorus having a size of 20-30mm × 2.8-3.7mm × 1.2-2.5mm sinocalamus latiflorus piece and crush, institute
It obtains crushed material to be delivered in primary pretreatment immersion liquid A, the ratio between the sinocalamus latiflorus crushed material weight and primary pretreatment immersion liquid A volume are
1:1.5-3.5, the primary pretreatment immersion liquid A is as unit of parts by weight, including following raw material: alkyl phenol polyoxyethylene ether 4-8
Part, 0.3-0.6 parts of triethanolamine, 0.5-1 parts of stearic acid, 0.4-1.2 parts of oleic acid, 0.8-1.5 parts of lauric acid, 42-90 parts of water,
Ultrasonic power is 30-50W, and temperature is to carry out immersion 26-40min at 43-48 DEG C, is then filtered, and obtains leaching material A；
S2: leaching material A made from step S1 is delivered in secondary pretreatment immersion liquid B, the leaching material A weight and secondary pre- place
Managing the ratio between immersion liquid B volume is 1:5.6-12.3, and the secondary pretreatment immersion liquid B is as unit of parts by weight, including following raw material: mistake
10-20 parts of carbamide, 4-6 parts of potassium hydroxide, 0.3-0.5 parts of amino carboxylic acid, 0.1-0.2 parts of vanadic anhydride, water 35-150
Part, boiling 1.5-2h is carried out at being 142-160 DEG C in temperature, is then filtered, leaching material B is obtained；
S3: leaching material B made from step S2 is washed with 60-80 DEG C of hot water, then screens, bleach, health is made
Paper bleached pulp；
S4: carrying out defibrination again with bleached pulp for toilet paper made from step S3, and screened stock is made；
S5: screened stock made from step S4 is subjected to decontamination degassing, is then put into head box and is squeezed after screening the pulp, then connect
Drying, press polish, batch, finished product sinocalamus latiflorus body paper；
S6: finished product sinocalamus latiflorus body paper made from step S5 is subjected to rewinding, cuts, pack, finished product toilet paper.
Embodiment 1
A kind of preparation method of the toilet paper using bleaching process preparation, comprising the following steps:
S1: sinocalamus latiflorus is cut into having a size of 22mm × 3.2mm × 1.3mm sinocalamus latiflorus piece and is crushed, gained crushed material is defeated
It send into primary pretreatment immersion liquid A, the ratio between the sinocalamus latiflorus crushed material weight and primary pretreatment immersion liquid A volume are 1:1.6, institute
Primary pretreatment immersion liquid A is stated as unit of parts by weight, including following raw material: 4 parts of alkyl phenol polyoxyethylene ether, triethanolamine 0.3
Part, 0.5 part of stearic acid, 0.4 part of oleic acid, 0.8 part of lauric acid, 42 parts of water, ultrasonic power be 30W, temperature be 43 DEG C at into
Row impregnates 40min, then filters, and obtains leaching material A；
S2: leaching material A made from step S1 is delivered in secondary pretreatment immersion liquid B, the leaching material A weight and secondary pre- place
Managing the ratio between immersion liquid B volume is 1:5.6, and the secondary pretreatment immersion liquid B is as unit of parts by weight, including following raw material: crossing phosphinylidyne
10 parts of amine, 4 parts of potassium hydroxide, 0.3 part of amino carboxylic acid, 0.1 part of vanadic anhydride, 35 parts of water are steamed at being 142 DEG C in temperature
2h is boiled, is then filtered, leaching material B is obtained；
S3: leaching material B made from step S2 is washed with 70 DEG C of hot water, then screens, bleach, toilet paper is made and uses
Bleached pulp；
S4: carrying out defibrination again with bleached pulp for toilet paper made from step S3, and screened stock is made；
S5: screened stock made from step S4 is subjected to decontamination degassing, is then put into head box and is squeezed after screening the pulp, then connect
Drying, press polish, batch, finished product sinocalamus latiflorus body paper；
S6: finished product sinocalamus latiflorus body paper made from step S5 is subjected to rewinding, cuts, pack, finished product toilet paper.
Embodiment 2
A kind of preparation method of the toilet paper using bleaching process preparation, comprising the following steps:
S1: sinocalamus latiflorus is cut into having a size of 29mm × 3.6mm × 2.4mm sinocalamus latiflorus piece and is crushed, gained crushed material is defeated
It send into primary pretreatment immersion liquid A, the ratio between the sinocalamus latiflorus crushed material weight and primary pretreatment immersion liquid A volume are 1:3.4, institute
Primary pretreatment immersion liquid A is stated as unit of parts by weight, including following raw material: 8 parts of alkyl phenol polyoxyethylene ether, triethanolamine 0.6
Part, 1 part of stearic acid, -1.2 parts of oleic acid, 1.5 parts of lauric acid, 90 parts of water, ultrasonic power be 50W, temperature be 48 DEG C at into
Row impregnates 26min, then filters, and obtains leaching material A；
S2: leaching material A made from step S1 is delivered in secondary pretreatment immersion liquid B, the leaching material A weight and secondary pre- place
Managing the ratio between immersion liquid B volume is 1:12.3, and the secondary pretreatment immersion liquid B is as unit of parts by weight, including following raw material: crossing phosphinylidyne
20 parts of amine, 6 parts of potassium hydroxide, 0.5 part of amino carboxylic acid, 0.2 part of vanadic anhydride, 150 parts of water carry out at being 160 DEG C in temperature
Boiling 1.5h, is then filtered, and obtains leaching material B；
S3: leaching material B made from step S2 is washed with 60 DEG C of hot water, then screens, bleach, toilet paper is made and uses
Bleached pulp；
S4: carrying out defibrination again with bleached pulp for toilet paper made from step S3, and screened stock is made；
S5: screened stock made from step S4 is subjected to decontamination degassing, is then put into head box and is squeezed after screening the pulp, then connect
Drying, press polish, batch, finished product sinocalamus latiflorus body paper；
S6: finished product sinocalamus latiflorus body paper made from step S5 is subjected to rewinding, cuts, pack, finished product toilet paper.
Embodiment 3
A kind of preparation method of the toilet paper using bleaching process preparation, comprising the following steps:
S1: sinocalamus latiflorus is cut into having a size of 26mm × 6.2mm × 1.8mm sinocalamus latiflorus piece and is crushed, gained crushed material is defeated
It send into primary pretreatment immersion liquid A, the ratio between the sinocalamus latiflorus crushed material weight and primary pretreatment immersion liquid A volume are 1:2.5, institute
Primary pretreatment immersion liquid A is stated as unit of parts by weight, including following raw material: 6 parts of alkyl phenol polyoxyethylene ether, triethanolamine 0.5
Part, 0.7 part of stearic acid, 0.8 part of oleic acid, 1.2 parts of lauric acid, 67 parts of water, ultrasonic power be 40W, temperature be 46 DEG C at into
Row impregnates 33min, then filters, and obtains leaching material A；
S2: leaching material A made from step S1 is delivered in secondary pretreatment immersion liquid B, the leaching material A weight and secondary pre- place
Managing the ratio between immersion liquid B volume is 1:9.2, and the secondary pretreatment immersion liquid B is as unit of parts by weight, including following raw material: crossing phosphinylidyne
16 parts of amine, 5 parts of potassium hydroxide, 0.4 part of amino carboxylic acid, 0.1 part of vanadic anhydride, 92 parts of water are steamed at being 151 DEG C in temperature
1.8h is boiled, is then filtered, leaching material B is obtained；
S3: leaching material B made from step S2 is washed with 80 DEG C of hot water, then screens, bleach, toilet paper is made and uses
Bleached pulp；
S4: carrying out defibrination again with bleached pulp for toilet paper made from step S3, and screened stock is made；
S5: screened stock made from step S4 is subjected to decontamination degassing, is then put into head box and is squeezed after screening the pulp, then connect
Drying, press polish, batch, finished product sinocalamus latiflorus body paper；
S6: finished product sinocalamus latiflorus body paper made from step S5 is subjected to rewinding, cuts, pack, finished product toilet paper.
Comparative example 1
After sinocalamus latiflorus is cut into the crushing of sinocalamus latiflorus piece, impregnates, but be fed directly to secondary pre- without primary pretreatment immersion liquid A
It handles immersion liquid B to impregnate, other preparation processes are identical as the preparation process of embodiment 3.
Comparative example 2
The secondary pretreatment immersion liquid B is as unit of parts by weight, including following raw material: 5 parts of potassium hydroxide, amino carboxylic acid
0.4 part, 0.1 part of vanadic anhydride, 92 parts of water, other preparation processes are identical as the preparation process of comparative example 1.
Comparative example 3
The secondary pretreatment immersion liquid B is as unit of parts by weight, including following raw material: 16 parts of percarbamide, potassium hydroxide 5
Part, 0.1 part of vanadic anhydride, 92 parts of water, other preparation processes are identical as the preparation process of comparative example 1.
Comparative example 4
The secondary pretreatment immersion liquid B is as unit of parts by weight, including following raw material: 16 parts of percarbamide, potassium hydroxide 5
Part, 0.4 part of amino carboxylic acid, 92 parts of water, other preparation processes are identical as the preparation process of comparative example 1.
Comparative example 5
After sinocalamus latiflorus is cut into the crushing of sinocalamus latiflorus piece, only by primary pretreatment immersion liquid A immersion, and soaked without secondary pretreatment
Liquid B impregnates, the preparation process of other preparation processes and embodiment 3 are essentially identical.
Comparative example 6
The primary pretreatment immersion liquid A is as unit of parts by weight, including following raw material: 6 parts of alkyl phenol polyoxyethylene ether, three
0.5 part of ethanol amine, 67 parts of water, other preparation processes are identical as the preparation process of comparative example 5.
Comparative example 7
The primary pretreatment immersion liquid A is as unit of parts by weight, including following raw material: 0.7 part of stearic acid, 0.8 part of oleic acid,
1.2 parts of lauric acid, 67 parts of water, other preparation processes are identical as the preparation process of comparative example 5.
Bleached pulp is prepared using the preparation process of embodiment 1-3 and comparative example 1-7, detects paper pulp yield and whiteness respectively,
As a result as shown in the table.
Can by comparative example 1-4 it is found that percarbamide, amino carboxylic acid, vanadic anhydride is not added in secondary pretreatment immersion liquid B
Paper pulp yield and whiteness are reduced, this is because percarbamide, which will be slow, releases hydrogen peroxide, the hydrogen peroxide released and wood
Element reaction is conducive to improve paper pulp yield and whiteness；Amino carboxylic acid can play chelation；Vanadic anhydride plays the work of catalysis
With；Know that percarbamide, amino carboxylic acid, vanadic anhydride add by the paper pulp yield and whiteness of example 3 and comparative example 1-4 simultaneously
Add and play synergistic effect, improves paper pulp yield and whiteness.
By comparative example 5-7 it is found that alkyl phenol polyoxyethylene ether, triethanolamine, tristearin once is not added in pretreatment immersion liquid A
Acid, oleic acid, lauric acid can reduce paper pulp yield and whiteness, this is because alkyl phenol polyoxyethylene ether, triethanolamine are wet
Agent plays good humidification；Stearic acid, oleic acid, lauric acid play sinocalamus latiflorus crushed material surface-active action；Simultaneously by reality
Alkyl phenol polyoxyethylene ether, triethanolamine, stearic acid, oleic acid, laurel known to the paper pulp yield and whiteness of example 3 and comparative example 5-7
The addition of acid plays synergistic effect, improves paper pulp yield and whiteness.
Finished product toilet paper is prepared using the preparation process of embodiment 1-3 and comparative example 1-7, detects brightness respectively, anti-tensile refers to
Number, pliability, as a result as shown in the table.
Can by comparative example 1-4 it is found that percarbamide, amino carboxylic acid, vanadic anhydride is not added in secondary pretreatment immersion liquid B
Reduce the brightness of toilet paper, tensile index, pliability release this is because percarbamide, which will be slow, releases hydrogen peroxide
Hydrogen peroxide and lignin reaction；Amino carboxylic acid can play chelation；Vanadic anhydride plays the role of catalysis；Simultaneously by reality
The brightness of the life paper of example 3 and comparative example 1-4, tensile index, percarbamide known to pliability, amino carboxylic acid, vanadic anhydride
Addition plays synergistic effect, improves brightness, the tensile index, pliability of toilet paper.
By comparative example 5-7 it is found that alkyl phenol polyoxyethylene ether, triethanolamine, tristearin once is not added in pretreatment immersion liquid A
Acid, oleic acid, lauric acid can reduce the brightness of toilet paper, tensile index, pliability, this is because alkyl phenol polyoxyethylene ether,
Triethanolamine is wetting agent, plays good humidification；It is living that stearic acid, oleic acid, lauric acid play sinocalamus latiflorus crushed material surface
Property effect；The alkylphenol-polyethenoxy known to the brightness of example 3 and the toilet paper of comparative example 5-7, tensile index, pliability simultaneously
Ether, triethanolamine, stearic acid, oleic acid, lauric addition play synergistic effect, improve brightness, the anti-tensile of toilet paper
Index, pliability.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that
Specific implementation of the invention is only limited to these instructions, and for person of an ordinary skill in the technical field, is not being departed from
Under the premise of present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to the present invention by being submitted
Claims determine scope of patent protection.
Claims (9)
1. a kind of toilet paper prepared using bleaching process, it is characterised in that: be by secondary pretreatment, washing, screening, drift
White, defibrination, screening the pulp, squeezing, drying, press polish, is batched, rewinding, is cut, made of packaging step at decontamination degassing；
Preparation method, comprising the following steps:
S1: being cut into sinocalamus latiflorus piece for sinocalamus latiflorus and crush, and gained crushed material is delivered in primary pretreatment immersion liquid A, described primary
Immersion liquid A, including following raw material: alkyl phenol polyoxyethylene ether, triethanolamine, stearic acid, oleic acid, lauric acid, water are pre-processed, super
Immersion 26-40min is carried out under sound wave effect, is then filtered, and leaching material A is obtained；
S2: leaching material A made from step S1 is delivered in secondary pretreatment immersion liquid B, the secondary pretreatment immersion liquid B includes following
Raw material: percarbamide, potassium hydroxide, amino carboxylic acid, vanadic anhydride, water carry out boiling at being 142-160 DEG C in temperature, connect
Filtering, obtain leaching material B；
S3: leaching material B made from step S2 is washed with 60-80 DEG C of hot water, then screens, bleach, toilet paper is made and uses
Bleached pulp；
S4: carrying out defibrination again with bleached pulp for toilet paper made from step S3, and screened stock is made；
S5: screened stock made from step S4 is subjected to decontamination degassing, is then put into head box and is squeezed after screening the pulp, followed by dry
Dry, press polish is batched, finished product sinocalamus latiflorus body paper；
S6: finished product sinocalamus latiflorus body paper made from step S5 is subjected to rewinding, cuts, pack, finished product toilet paper.
2. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: sinocalamus latiflorus described in step S1
The size of piece is 20-30mm × 2.8-3.7mm × 1.2-2.5mm.
3. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: sinocalamus latiflorus described in step S1
The ratio between crushed material weight and primary pretreatment immersion liquid A volume are 1:1.5-3.5.
4. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: primary described in step S1
Immersion liquid A is pre-processed as unit of parts by weight, including following raw material: 4-8 parts of alkyl phenol polyoxyethylene ether, triethanolamine 0.3-0.6
Part, 0.5-1 parts of stearic acid, 0.4-1.2 parts of oleic acid, 0.8-1.5 parts of lauric acid, 42-90 parts of water.
5. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: ultrasound described in step S1
Wave power is 30-50W, and temperature is 43-48 DEG C.
6. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: soak material described in step S2
The ratio between A weight and secondary pretreatment immersion liquid B volume are 1:5.6-12.3.
7. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: immersion liquid described in step S2
B is as unit of parts by weight, including following raw material: 10-20 parts of percarbamide, 4-6 parts of potassium hydroxide, 0.3-0.5 parts of amino carboxylic acid,
0.1-0.2 parts of vanadic anhydride, 35-150 parts of water.
8. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: boiling described in step S2
Time be 1.5-2h.
9. the toilet paper according to claim 1 prepared using bleaching process, it is characterised in that: washed described in step S3
It is 6.8-7.2 to pH value.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107558288A (en) * | 2017-09-30 | 2018-01-09 | 广西金荣纸业有限公司 | One kind utilizes bleaching process production high-strength corrugated paper coagulation liquid and its application |
| CN107675547A (en) * | 2017-09-30 | 2018-02-09 | 广西金荣纸业有限公司 | Bleached pulp preparation technology is used in a kind of high-strength corrugated paper production |
| CN107604729A (en) * | 2017-09-30 | 2018-01-19 | 广西金荣纸业有限公司 | A kind of preprocess method for producing high-strength corrugated paper bleached pulp |
| CN107604760A (en) * | 2017-09-30 | 2018-01-19 | 广西金荣纸业有限公司 | A kind of high-strength corrugated paper produced using bleaching process |
| CN107675548A (en) * | 2017-09-30 | 2018-02-09 | 广西金荣纸业有限公司 | A kind of coagulation liquid and its preparing the application of high-strength corrugated paper |
| CN107858845A (en) * | 2017-09-30 | 2018-03-30 | 广西金荣纸业有限公司 | A kind of two stage treatment liquid and its application in production high-strength corrugated paper |
| CN107604728A (en) * | 2017-09-30 | 2018-01-19 | 广西金荣纸业有限公司 | A kind of preprocess method for producing high-strength corrugated paper |
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