CN108962747A - Diode manufacturing method with ladder-type structure - Google Patents

Diode manufacturing method with ladder-type structure Download PDF

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Publication number
CN108962747A
CN108962747A CN201710373920.1A CN201710373920A CN108962747A CN 108962747 A CN108962747 A CN 108962747A CN 201710373920 A CN201710373920 A CN 201710373920A CN 108962747 A CN108962747 A CN 108962747A
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CN
China
Prior art keywords
semiconductor layer
type semiconductor
processing procedure
chip body
ladder
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710373920.1A
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Chinese (zh)
Inventor
彭工及
萧上智
张靖奇
黄承扬
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Yea Shin Technology Co Ltd
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Yea Shin Technology Co Ltd
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Priority to CN201710373920.1A priority Critical patent/CN108962747A/en
Publication of CN108962747A publication Critical patent/CN108962747A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66083Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices
    • H01L29/6609Diodes

Abstract

A kind of diode manufacturing method with ladder-type structure, the diode grain structure mainly includes a n type semiconductor layer, it is one p type semiconductor layer of storehouse in the one side of the n type semiconductor layer, a N+ type semiconductor layer is attached on the another side of the n type semiconductor layer, it is that there is a groove in the periphery of the p type semiconductor layer, finally the top surface with an insulating protective layer and the insulating protective layer in the groove of the n type semiconductor layer periphery and p type semiconductor layer is not higher than the p type semiconductor layer top surface, the height of the insulating protective layer is reduced by the design of the p type semiconductor layer groove, ensure that the acceptance rate of subsequent encapsulation procedure gets a promotion, and improve the efficiency of diode entirety.

Description

Diode manufacturing method with ladder-type structure
Technical field
The invention relates to a kind of diodes, refer in particular to a kind of diode manufacturing method with ladder-type structure.
Background technique
Rectifier diode is a kind of separate type component in the industry, and rectifier diode is mainly used for as rectification and inhibits Abnormal signal two acts on greatly, and so-called rectification, which refers to have, to be converted alternating current to as direct current, and inhibit abnormal signal refer to by Input signal is removed beyond range part is limited, and to maintain the stabilization of input signal, to be used as protection circuit, rectifies two poles Pipe institute's use scope is indispensable one of electronic building brick on the fields such as semiconductor, communication and consumer electronics.
It is currently known the structure of diode crystal particle, as shown in the known grain structure schematic diagram of Fig. 1, it is known that diode crystal particle For a PN diode crystal particle 10, which includes a N+ type semiconductor layer 101, in the N+ type semiconductor layer 101 Upper one n type semiconductor layer 102 of storehouse, then in one p type semiconductor layer 103 of upper surface storehouse of n type semiconductor layer 102, and at this A protective layer 104 is equipped on 10 periphery of crystal grain again, which is an insulating glass.
In diode processing procedure, crystal grain can first pass through the size that etching process defines crystal grain before cutting, and in crystal grain The peripheral position etched is sintered processing procedure, i.e., is sintered in sintering furnace after the peripheral position is placed in glass powder, with The protective layer 104 is formed, then carries out the cooling encapsulation processing procedure of crystal grain after crystal grain cutting, is dissipated with forming crystal grain as shown in Figure 2 Seal assembling structure.
However, as shown in the PN diode crystal particle 10 of Fig. 1, as the protective layer of insulation protection in sintering process 104 after sintered, and for the insulating properties of the complete preservation crystal grain, p type semiconductor layer 103 can be higher than by being formed by structure; Therefore, in subsequent cooling encapsulation processing procedure, in order to cooperate 104 structure of protective layer of its 10 peripheral projection of PN diode crystal particle, The cooling fin 105 being located on p type semiconductor layer 103 must generate structure convex with complete smooth in p type semiconductor layer 103, as shown in Figure 2;Since the raised structure of protective layer 104 is different, which is packaged Shi Wufa is completely attached on p type semiconductor layer 103, the problem for causing heat dissipation uneven, and such structure is also be easy to cause The structure of ambetti excessive height causes acceptance rate to decline, influences diode crystal particle so that easily causing glass impaired when encapsulation Prouctiveness.
Summary of the invention
For above-mentioned missing, the main purpose of the present invention is to provide a kind of diode fabrications with ladder-type structure Method forms a stair-stepping groove structure, it is ensured that follow-up process institute shape by etch process for several times on diode crystal particle At protective layer decline, so as to subsequent encapsulation procedure, and promote the acceptance rate and efficiency of whole diode.
To reach above-mentioned purpose, the present invention provides a kind of diode manufacturing method with ladder-type structure, production The step of method includes: to provide a chip body;First time Cutting Road oxide etch processing procedure and Cutting Road are carried out to the chip body Etch process, to define the size of crystal grain;Pre-baked processing procedure is carried out to the chip body, and again in p-type after the chip body is cooling Photoresist is coated on the top surface surface of semiconductor layer and carries out soft roasting operation;To the p type semiconductor layer top surface surface of the chip body It is exposed processing procedure, development and fixing processing procedure and hard baking processing procedure, then the N+ type semiconductor layer bottom surface of the chip body is carried out Coat photoresist and hard baking processing procedure;Second of Cutting Road oxide etch processing procedure is carried out to the chip body and Cutting Road etching is made Journey;The photoresist on the chip body surface is removed, then is rinsed with water, that is, forms stairstepping groove structure.
As a further improvement of the present invention, wherein the chip body is partly led by a p type semiconductor layer, a N-type in a step Body layer and a N+ type semiconductor layer are formed.
As further improvement of the invention, wherein Cutting Road oxide etch processing procedure is to utilize titanium dioxide in b step Silicon etching liquid, i.e. hydrofluoric acid and ammonium fluoride are carried out with the ratio of 1:6, etching period between 15 ~ 20 minutes programs.
As further improvement of the invention, wherein in b step Cutting Road etch process be using nitric acid, hydrofluoric acid and Glacial acetic acid is carried out with the ratio of 3:1:1, and etching period adjusts its time between 5 ~ 10 minutes, according to the situation that its acid subsides.
As further improvement of the invention, wherein second of Cutting Road oxide etch processing procedure is to utilize in step e SiO 2 etch liquid, i.e. hydrofluoric acid and ammonium fluoride are carried out with the ratio of 1:6, etching period between 15 ~ 20 minutes programs.
As further improvement of the invention, wherein in step e Cutting Road etch process be using nitric acid, hydrofluoric acid and Glacial acetic acid is carried out with the ratio of 3:1:1, and etching period adjusts its time between 5 ~ 10 minutes, according to the situation that its acid subsides.
As a further improvement of the present invention, the photoresist on the chip body surface is wherein removed in step e using sulfuric acid.
To enable above and other objects, features and advantages of the invention to be clearer and more comprehensible, preferred embodiment is cited below particularly, And cooperate institute's accompanying drawings, it is described in detail below.
Detailed description of the invention
Fig. 1 is a schematic diagram of known grain structure.
Fig. 2 is another schematic diagram of known grain structure.
Fig. 3 is the first schematic diagram of production process structure of the invention.
Fig. 4 is the second schematic diagram of production process structure of the invention.
Fig. 5 is the third schematic diagram of production process structure of the invention.
Fig. 6 is the 4th schematic diagram of production process structure of the invention.
Fig. 7 is block flow diagram of the invention.
Symbol indicates in figure:
Symbol mark in known technology:
10 PN diode crystal particles;101 N+ type semiconductor layers;102 n type semiconductor layers;103 p type semiconductor layers;104 protections Layer;105 cooling fins;
Symbol mark in the present invention:
1 n type semiconductor layer;10 chip bodies;2 p type semiconductor layers;21 grooves;3 N+ type semiconductor layers;4 insulation protections Layer;S1 ~ S6 step.
Specific embodiment
It is production process structural schematic diagram of the invention refering to shown in Fig. 3 to Fig. 6.As shown in figure 3, two poles of the invention Pipe grain structure mainly includes a n type semiconductor layer 1, and the n type semiconductor layer 1 is N-type crystal (N-type in the present embodiment Wafer), one p type semiconductor layer 2 of storehouse in the one side of the n type semiconductor layer 1, is pasted on the another side of the n type semiconductor layer 1 Attached N+ type semiconductor layer 3, the p type semiconductor layer 2 and N+ type semiconductor layer 3 are to attach boron paper and phosphorus paper respectively in processing procedure In on 1 two sides of n type semiconductor layer, using burn off processing procedure, pre- long-pending processing procedure, separation process, wet oxidation processing procedure and diffusion are impregnated It is respectively formed the p type semiconductor layer 2 and N+ type semiconductor layer 3 after journey, forms it into a chip body 10.
Later, which enters back into etching and cutting processing procedure;Wherein, which first carries out etch process, Photoresist (Photo Resist) is coated on the top surface surface of the p type semiconductor layer 2 after cooling down Deng the chip body 10 and is carried out Soft roasting operation selects various sizes of light shield to be exposed processing procedure, at this after the exposure manufacture process according to product demand later The processing procedure that the 2 top surface surface of p type semiconductor layer of chip body 10 is developed and is fixed finally carries out the hard baking system of chip body 10 Journey;Photoresist (Photo is coated on 3 bottom surface of N+ type semiconductor layer of chip body 10 after chip body 10 is cooling later Resist), to form the protective effect for protecting 10 bottom surface of chip body, and hard baking processing procedure is then carried out again;The crystalline substance later Sheet body 10 carries out first time Cutting Road oxide etch processing procedure, and the Cutting Road oxide etch processing procedure is to utilize in the present embodiment SiO 2 etch liquid (BOE, Buffered Oxide Etch), i.e., hydrofluoric acid and ammonium fluoride are with the ratio of 1:6, etching period It is carried out between 15 ~ 20 minutes programs, finally carries out first time Cutting Road etch process again to define the size of the crystal grain, such as Shown in Fig. 4, the Cutting Road etch process is wet etching processing procedure in the present embodiment, which is to utilize nitric acid, hydrofluoric acid and ice Acetic acid is carried out with the ratio of 3:1:1, and etching period adjusts its time between 5 ~ 10 minutes, according to the situation that its acid subsides.
Refering to shown in Fig. 5.After terminating first time Cutting Road etch process, which is subjected to stairstepping groove Structure processing procedure;Wherein the chip body 10 repeats pre-baked processing procedure, and again in the p type semiconductor layer 2 after chip body 10 is cooling Top surface surface on coat photoresist (Photo Resist) and carry out soft roasting operation, repeat exposure manufacture process, development and fixed Shadow processing procedure and hard baking processing procedure, behind the top surface surface for completing p type semiconductor layer 2, then to 3 bottom surface of N+ type semiconductor layer of chip body 10 Surface carries out coating photoresist and hard baking processing procedure;Second of Cutting Road oxide etch processing procedure is carried out later, is equally to utilize two It aoxidizes silicon etching liquid (BOE, Buffered Oxide Etch), i.e., hydrofluoric acid and ammonium fluoride are with the ratio of 1:6, etching period 15 ~ 20 minutes programs carry out, and carry out second of Cutting Road etch process again later, process conditions be in the present embodiment with Nitric acid, hydrofluoric acid and glacial acetic acid are carried out with the ratio of 3:1:1, and etching period was between 5 ~ 10 minutes, according to the situation tune of its acid recession Its whole time;After the etching to be done, the photoresist on 10 surface of chip body is first removed using sulfuric acid, is rinsed after completion with water, Stairstepping groove structure is formed, as shown in figure 5, forming a groove 21 in 2 periphery of p type semiconductor layer.
Refering to shown in Fig. 6.After completing aforementioned secondary Cutting Road oxide etch processing procedure, then carry out glass protection burning Tie processing procedure;Wherein after the leading pre-baked processing procedure of the chip body 10, protective glue is added in 2 top surface of p type semiconductor layer, which is It is mixed by glass powder and photoresist, carries out soft roasting, exposure and development again later with after fixing processing procedure, finally entering sintering Processing procedure so that protective glue formed insulating protective layer 4, as shown in fig. 6, and the insulating protective layer 4 because 2 periphery of p type semiconductor layer ditch 21 space of slot and generate sinking, make its insulating protective layer 4 structural portion can be higher than the p type semiconductor layer 2 top surface, so as to subsequent Encapsulating structure combination.
It is to illustrate production process above-mentioned with block diagram as shown in fig.7, being block flow diagram of the invention.It provides One chip body 10 (S1), the chip body 10 are that have a n type semiconductor layer 1, form a p-type in the one side of the n type semiconductor layer 1 Semiconductor layer 2 forms a N+ type semiconductor layer 3 on the another side of the n type semiconductor layer 1;First is carried out to the chip body 10 Secondary Cutting Road oxide etch processing procedure and Cutting Road etch process, to define the size (S2) of crystal grain;Chip body 10 is carried out Pre-baked processing procedure, and photoresist (Photo is coated on the top surface surface of the p type semiconductor layer 2 again after chip body 10 is cooling Resist) and soft roasting operation (S3) is carried out;To the 2 top surface surface of p type semiconductor layer of chip body 10 be exposed processing procedure, development with It is fixed processing procedure and hard baking processing procedure, then 3 bottom surface of N+ type semiconductor layer of chip body 10 is carried out coating photoresist and hard baking system Journey (S4);Second of Cutting Road oxide etch processing procedure and Cutting Road etch process (S5) are carried out to chip body 10;Remove chip The photoresist on 10 surface of body is rinsed again with water, that is, forms stairstepping groove structure (S6).
Embodiments described above, only preferable embodiment, cannot be limit the scope of implementation of the present invention with this, If all should belong to patent of the invention according to equivalent change or modification made by scope of the present invention patent and description and contain Lid range.

Claims (7)

1. a kind of diode manufacturing method with ladder-type structure, which is characterized in that step includes:
A., one chip body is provided;
B. first time Cutting Road oxide etch processing procedure and Cutting Road etch process are carried out to the chip body, to define crystal grain Size;
C. pre-baked processing procedure is carried out to the chip body, and again on the top surface surface of p type semiconductor layer after the chip body is cooling On coat photoresist and carry out soft roasting operation;
D. processing procedure, development and fixing processing procedure and hard baking are exposed to the p type semiconductor layer top surface surface of the chip body Processing procedure, then the N+ type semiconductor layer bottom surface of the chip body is carried out coating photoresist and hard baking processing procedure;
E. second of Cutting Road oxide etch processing procedure and Cutting Road etch process are carried out to the chip body;
F. the photoresist for removing the chip body surface is rinsed again with water, forms stairstepping groove structure.
2. as described in claim 1 with the diode manufacturing method of ladder-type structure, which is characterized in that wherein in a step The chip body is made of a p type semiconductor layer, a n type semiconductor layer and a N+ type semiconductor layer.
3. as described in claim 1 with the diode manufacturing method of ladder-type structure, which is characterized in that wherein in b step The Cutting Road oxide etch processing procedure is using SiO 2 etch liquid, i.e., hydrofluoric acid and ammonium fluoride are with the ratio of 1:6, etching Time between 15 ~ 20 minutes program carry out.
4. as described in claim 1 with the diode manufacturing method of ladder-type structure, which is characterized in that wherein in b step The Cutting Road etch process is to be carried out using nitric acid, hydrofluoric acid and glacial acetic acid with the ratio of 3:1:1, and etching period is between 5 ~ 10 Minute.
5. as described in claim 1 with the diode manufacturing method of ladder-type structure, which is characterized in that wherein in step e Second of Cutting Road oxide etch processing procedure is using SiO 2 etch liquid, i.e., hydrofluoric acid and ammonium fluoride are with the ratio of 1:6 Example, etching period were carried out between 15 ~ 20 minutes programs.
6. as described in claim 1 with the diode manufacturing method of ladder-type structure, which is characterized in that wherein in step e The Cutting Road etch process is to be carried out using nitric acid, hydrofluoric acid and glacial acetic acid with the ratio of 3:1:1, and etching period is between 5 ~ 10 Minute.
7. as described in claim 1 with the diode manufacturing method of ladder-type structure, which is characterized in that wherein in step e The photoresist on the chip body surface is removed using sulfuric acid.
CN201710373920.1A 2017-05-24 2017-05-24 Diode manufacturing method with ladder-type structure Pending CN108962747A (en)

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Application Number Priority Date Filing Date Title
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5977605A (en) * 1995-08-30 1999-11-02 Asea Brown Boveri Ab SiC Semiconductor device comprising a pn Junction with a voltage absorbing edge
CN201383498Y (en) * 2009-03-03 2010-01-13 百圳君耀电子(深圳)有限公司 Semiconductor diode chip
CN101982872A (en) * 2010-10-30 2011-03-02 强茂电子(无锡)有限公司 Manufacturing method of grooved diode chip
CN102543722A (en) * 2011-12-26 2012-07-04 天津中环半导体股份有限公司 High-voltage transient voltage suppressor chip and production process
CN104008970A (en) * 2014-06-17 2014-08-27 安徽芯旭半导体有限公司 Glassivation diode chip and manufacturing method thereof
CN104201102A (en) * 2014-08-28 2014-12-10 苏州启澜功率电子有限公司 Fast recovery diode FRD chip and production process for same
CN104616978A (en) * 2014-12-31 2015-05-13 国家电网公司 Silicon-carbide power device terminal structure manufacturing method
CN104952909A (en) * 2014-09-03 2015-09-30 安徽省祁门县黄山电器有限责任公司 Junction terminal structure of diode chip

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5977605A (en) * 1995-08-30 1999-11-02 Asea Brown Boveri Ab SiC Semiconductor device comprising a pn Junction with a voltage absorbing edge
CN201383498Y (en) * 2009-03-03 2010-01-13 百圳君耀电子(深圳)有限公司 Semiconductor diode chip
CN101982872A (en) * 2010-10-30 2011-03-02 强茂电子(无锡)有限公司 Manufacturing method of grooved diode chip
CN102543722A (en) * 2011-12-26 2012-07-04 天津中环半导体股份有限公司 High-voltage transient voltage suppressor chip and production process
CN104008970A (en) * 2014-06-17 2014-08-27 安徽芯旭半导体有限公司 Glassivation diode chip and manufacturing method thereof
CN104201102A (en) * 2014-08-28 2014-12-10 苏州启澜功率电子有限公司 Fast recovery diode FRD chip and production process for same
CN104952909A (en) * 2014-09-03 2015-09-30 安徽省祁门县黄山电器有限责任公司 Junction terminal structure of diode chip
CN104616978A (en) * 2014-12-31 2015-05-13 国家电网公司 Silicon-carbide power device terminal structure manufacturing method

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Application publication date: 20181207