CN108951299A - A kind of environmental protection wall paper of brownish black and preparation method thereof - Google Patents
A kind of environmental protection wall paper of brownish black and preparation method thereof Download PDFInfo
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- CN108951299A CN108951299A CN201810835137.7A CN201810835137A CN108951299A CN 108951299 A CN108951299 A CN 108951299A CN 201810835137 A CN201810835137 A CN 201810835137A CN 108951299 A CN108951299 A CN 108951299A
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- friendlywallpaper
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- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 230000007613 environmental effect Effects 0.000 title description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000002002 slurry Substances 0.000 claims abstract description 34
- 239000008103 glucose Substances 0.000 claims abstract description 27
- 229920002472 Starch Polymers 0.000 claims abstract description 22
- 239000008107 starch Substances 0.000 claims abstract description 22
- 235000019698 starch Nutrition 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 229920000728 polyester Polymers 0.000 claims abstract description 15
- 229920001131 Pulp (paper) Polymers 0.000 claims abstract description 14
- 229920002678 cellulose Polymers 0.000 claims abstract description 14
- 239000001913 cellulose Substances 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 11
- 239000011268 mixed slurry Substances 0.000 claims abstract description 9
- 238000010009 beating Methods 0.000 claims description 22
- 239000002994 raw material Substances 0.000 claims description 13
- 238000005360 mashing Methods 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims description 2
- 239000005871 repellent Substances 0.000 claims description 2
- GZCGUPFRVQAUEE-VANKVMQKSA-N aldehydo-L-glucose Chemical compound OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)C=O GZCGUPFRVQAUEE-VANKVMQKSA-N 0.000 claims 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 26
- 238000004043 dyeing Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- -1 beating time 1h Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910021389 graphene Inorganic materials 0.000 description 3
- 241000219094 Vitaceae Species 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 235000021021 grapes Nutrition 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241001212228 Sesbania drummondii Species 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
- D21D1/00—Methods of beating or refining; Beaters of the Hollander type
- D21D1/02—Methods of beating; Beaters of the Hollander type
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/02—Chemical or biochemical treatment
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paper (AREA)
Abstract
The present invention relates to a kind of brownish black Environment-friendlywallpaper wallpapers and preparation method thereof, which comprises the following steps: (1) prepares glucose/starch solution;(2) wood pulp cellulose, polyester fiber are added in glucose solution obtained in step (1), are beaten with beater, mixed slurry is made;(3) mixing slurry is made into hanging raw stock by copy paper, squeezing, drying, coiling process;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, carried out hydro-thermal reaction, obtain a kind of Environment-friendlywallpaper wallpaper of brownish black.The process flow of this method is simple, at low cost, and the wallpaper prepared has uniform color, is not necessarily to subsequent dyeing or printing technology.
Description
Technical field
The present invention relates to building decoration materials more particularly to a kind of Environment-friendlywallpaper wallpapers of brownish black.
Background technique
Wallpaper, i.e. wallpaper are a kind of materials for being widely used in interior decoration, original are made after being beaten by wood pulp cellulose
Paper is obtained by stamp and post-processing later, can also be directly using non-woven fabrics directly as wallpaper.Wallpaper is because its style is more
Become, rich in color, the factors such as easy for construction, it is therefore, deep popular.With the improvement of human lives' condition, people are to day
The requirement for the ornament materials being often used is also higher and higher, and people, which have not only required nothing more than wallpaper, has common decorative performance, right
The additional properties of the environmental protection of wallpaper, antibiotic property, some column such as anti-flammability have higher performance.
Chinese Patent Application No. is the patent of invention of CN105544306A, discloses a kind of antibacterial and mouldproof containing graphene oxide
Wallpaper and preparation method thereof, and specifically disclosing the invention is that the antibacterial mildew inhibitor of preparation is evenly distributed on base through spray processing
To get antibacterial and mouldproof enzyme wallpaper on paper.The synergistic effect of nano graphene oxide, rattlebush extract and nano-cerium oxide
Under, the effect that its antibacterial and mouldproof eliminates the unusual smell is improved significantly.This method is mainly to pass through the method for post-processing for antibacterial agent
Being attached on wallpaper makes wallpaper have antibacterial and mouldproof effect, but by simply spraying, the effect between antibacterial agent and wallpaper
Power is smaller, and the adhesion time of antibacterial agent can shorten, and then influence the anti-microbial property of wallpaper.Graphene is a kind of with face simultaneously
The substance of color, and subsequent attachment, can make the irregular colour one of wallpaper, this substance is easy to influence the integrated beauty of wallpaper
It sees.
It is all to adhere to wallpaper using postfinishing process that the research for preparing antibacterial wallpaper from the prior art, which can be seen that many,
Color, while as the techniques such as dyeing, stamp, complex process, and the dyestuff used is synthetic dyestuffs mostly, the pollution to environment
It is larger.
The present invention is in order to solve the problems, such as that wallpaper colours existing complex process, heavy-polluted in the prior art, proposes one
The method that kind assigns the color of wallpaper when preparing wallpaper, this method does not use traditional dyestuff or coating, using naturally without dirt
Substance is contaminated, the color of wallpaper is adjusted by process conditions such as control temperature.
Summary of the invention
The object of the invention is that providing a kind of Environment-friendlywallpaper wallpaper and preparation method thereof of brownish black, existing skill is particularly solved
Wallpaper has a single function in art, and product feel is poor, and family wear leads to the problem of formaldehyde and is not easy to remove, and the specific method is as follows:
A kind of Environment-friendlywallpaper wallpaper of brownish black, which is characterized in that the raw material of wallpaper includes 0-30 parts of wood pulp cellulose, polyester fiber
30-100 parts, 1-15 parts of glucose, 1-10 parts of starch, water is 20-100 times of other total mass of raw materiales;The glucose and shallow lake
Hydro-thermal reaction occurs under the high temperature conditions and obtains a nanometer carbosphere for powder.
Preferably, a kind of Environment-friendlywallpaper wallpaper of brownish black, which is characterized in that the raw material of wallpaper includes 5-30 parts of wood pulp cellulose,
30-100 parts of polyester fiber, 5-15 parts of glucose, 5-10 parts of starch, water is 20-100 times of other total mass of raw materiales;Glucose
Hydro-thermal reaction occurs under the high temperature conditions with starch and obtains a nanometer carbosphere.
The preparation-obtained wallpaper of the present invention, by the way that hydro-thermal reaction occurs under the high temperature conditions using grape sugar and starch,
Grape sugar and starch occurs fragrant chemical combination carbonization reaction and becomes brown or black so that the color of wallpaper changes.
The dosage of grape sugar and starch also influences whether the depth of color, can by controlling the dosage of grape sugar and starch
It is controlled with the depth to color.
Since the present invention undergoes high temperature during the preparation process, in the proportion to wallpaper raw material, select terylene fine
The dosage of dimension is greater than wood pulp cellulose, can reduce generate large effect to wallpaper mechanical performance due to hot conditions in this way.
130-190 DEG C of hydrothermal temperature, time 2-5 hour.
The temperature and time of hydro-thermal reaction influences whether the virtueization and degree of carbonization of carbon source, when the temperature is too low, carbon source master
What is carried out is fragrantization, and the wallpaper of brown can be obtained, and when temperature continues growing, charing accounts for main reflection, obtains carbosphere, so that
Black is presented in wallpaper.When reaction temperature is too low, and the reaction time is insufficient, virtueization or charing, wallpaper can not occur for carbon source
Color will not change.
The thickness of wallpaper is less than 1mm, and the wallpaper is brown or black.
The present invention also provides a kind of preparation methods of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepares grape
Sugar/starch solution;(2) wood pulp cellulose, polyester fiber are added in glucose solution obtained in step (1), use beater
It is beaten, mixed slurry is made;(3) mixing slurry is made into hanging raw stock by copy paper, squeezing, drying, coiling process;(4)
The hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, hydro-thermal reaction is carried out, obtains a kind of ring of brownish black
Protect wallpaper.
The present invention is first dispersed grape sugar and starch before mashing, is beaten later, and joined enough
The water of amount, so that grape sugar and starch is uniformly dispersed in the slurry, it, can be uniform since the concentration of glucose and starch solution is low
Point in the slurry, therefore, in hydro-thermal reaction, so that the color of wallpaper is more uniform, obtained wallpaper aesthetic measure is high.
The beating degree of step (2) beating time 0.5-1.5 hours, slurry is controlled in 50~60 ° of SR.
Because the performance of slurry influences whether the performance of final wallpaper, according to test of many times, beating time 0.5-1.5 is found
Hour, the beating degree of slurry controls under the conditions of 50~60 ° of SR, and the wallpaper feel prepared is good, and flexibility is good, and quality is high.
One of fire retardant, softening agent, water repellent or a variety of can also be added when being beaten in step (2) into slurry.
According to the demand of wallpaper performance, corresponding functional finish can also be added in the preparation step of slurry, this
A little functional finish in pulping process due to being added, and the fixation with wallpaper is preferably.
The reaction temperature of step (4) is 170-190 DEG C, reaction time 2-5 hour.
Technical problem to be solved by the present invention lies in for the coloring of wallpaper, mainly use selection coloured in the prior art
The modes such as fiber, dyeing, stamp colour wallpaper, however there are complex process for the method for these colorings, and energy consumption is high, and
The big problem of environmental pollution, the present invention is intended to provide a kind of Environment-friendlywallpaper wallpaper of brownish black, by be added in the feed glucose and
Starch makes grape sugar and starch that virtueization and charing occur by high-temperature heating, and then assigns wallpaper brownish black, and pass through control
The amount ratio of grape sugar and starch processed and the temperature and time of hydro-thermal reaction, the uniform brown wallpaper of available color.
Specific embodiment
Embodiment 1
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 5 portions of grapes
Sugar and 5 parts of starch are dissolved in 200 parts of water;(2) 20 parts of wood pulp cellulose, 80 parts of polyester fiber are added to obtained in step (1)
In glucose solution, water is added and is beaten so that the quality of water is 70 times of other raw materials with beater, mixing slurry is made
The beating degree of material, beating time 1h, slurry is controlled in 50~60 ° of SR;(3) by mixing slurry by copy paper, squeezing, dry, batch
Process makes hanging raw stock;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, it is anti-to carry out hydro-thermal
It answers, 180 DEG C of reaction temperature, reacts 3h, obtain a kind of Environment-friendlywallpaper wallpaper of brownish black.
The wallpaper prepared is soft, and color is uniform.
Embodiment 2
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 10 parts of Portugals
Grape sugar and 3 parts of starch are dissolved in 200 parts of water;(2) 20 parts of wood pulp cellulose, 80 parts of polyester fiber are added in step (1) and are obtained
Glucose solution in, be added water be beaten so that the quality of water is 60 times of other raw materials with beater, be made mixing
The beating degree of slurry, beating time 1h, slurry is controlled in 50~60 ° of SR;(3) mixing slurry is passed through into copy paper, squeezing, drying, volume
Process is taken to make hanging raw stock;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, it is anti-to carry out hydro-thermal
It answers, 180 DEG C of reaction temperature, reacts 3h, obtain a kind of Environment-friendlywallpaper wallpaper of brownish black.
The wallpaper prepared is soft, and color is uniform, the content 0.05mg/m of formaldehyde after 3 days3。
Embodiment 3
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 15 parts of Portugals
Grape sugar and 5 parts of starch are dissolved in 200 parts of water;(2) 20 parts of wood pulp cellulose, 80 parts of polyester fiber are added in step (1) and are obtained
Glucose solution in, be added water be beaten so that the quality of water is 60 times of other raw materials with beater, be made mixing
The beating degree of slurry, beating time 1h, slurry is controlled in 50~60 ° of SR;(3) mixing slurry is passed through into copy paper, squeezing, drying, volume
Process is taken to make hanging raw stock;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, it is anti-to carry out hydro-thermal
It answers, 120 DEG C of reaction temperature, reacts 5h, obtain a kind of Environment-friendlywallpaper wallpaper of brownish black.
The wallpaper prepared is soft, and color is uniform.
Embodiment 4
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 10 parts of Portugals
Grape sugar is dissolved in 200 parts of water;(2) that 20 parts of wood pulp cellulose, 80 parts of polyester fiber are added to glucose obtained in step (1) is molten
In liquid, water is added and is beaten so that the quality of water is 60 times of other raw materials with beater, mixed slurry is made, when mashing
Between 1h, the beating degree of slurry controls in 50~60 ° of SR;(3) mixing slurry is made into wall by copy paper, squeezing, drying, coiling process
Paper body paper;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, carry out hydro-thermal reaction, reaction temperature
130 DEG C, 5h is reacted, a kind of Environment-friendlywallpaper wallpaper of brownish black is obtained.
The wallpaper prepared is soft, and color is uniform.
Embodiment 5
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 10 parts of Portugals
Grape sugar is dissolved in 200 parts of water;(2) 100 parts of polyester fiber are added in glucose solution obtained in step (1), water are added,
So that the quality of water is 60 times of other raw materials, it is beaten with beater, obtained mixed slurry, beating time 1h, slurry
Beating degree is controlled in 50~60 ° of SR;(3) mixing slurry is made into hanging raw stock by copy paper, squeezing, drying, coiling process;(4)
The hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, hydro-thermal reaction is carried out, 160 DEG C of reaction temperature, reacts
2h obtains a kind of Environment-friendlywallpaper wallpaper of brownish black.
The wallpaper prepared is soft, and color is uniform, the content 0.05mg/m of formaldehyde after 3 days3。
Embodiment 6
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 10 parts of Portugals
Grape sugar and 5 parts of starch are dissolved in 200 parts of water;(2) glucose solution obtained in step (1) is added to by 100 parts of polyester fiber
In, water is added and is beaten so that the quality of water is 60 times of other raw materials with beater, mixed slurry, beating time is made
The beating degree of 1h, slurry are controlled in 50~60 ° of SR;(3) mixing slurry is made into wallpaper by copy paper, squeezing, drying, coiling process
Body paper;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, carry out hydro-thermal reaction, reaction temperature 190
DEG C, 2h is reacted, a kind of Environment-friendlywallpaper wallpaper of brownish black is obtained.
The wallpaper prepared is soft, and color is uniform.
Embodiment 7
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 10 parts of Portugals
Grape sugar and 5 parts of starch are dissolved in 200 parts of water;(2) glucose solution obtained in step (1) is added to by 100 parts of polyester fiber
In, 5 parts of fire retardants are added, 1 part of softening agent is added water and is beaten so that the quality of water is 60 times of other raw materials with beater
Slurry, is made mixed slurry, and the beating degree of beating time 1h, slurry are controlled in 50~60 ° of SR;(3) by mixing slurry by copy paper,
Squeezing, drying, coiling process make hanging raw stock;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, added
Water carries out hydro-thermal reaction, 190 DEG C of reaction temperature, reacts 2h, obtain a kind of Environment-friendlywallpaper wallpaper of brownish black.
The wallpaper prepared is soft, and color is uniform.
Comparative example 1
A kind of preparation method of Environment-friendlywallpaper wallpaper, comprising the following steps: (1) add 20 parts of wood pulp cellulose, 80 parts of polyester fiber
Enter water, so that the quality of water is 60 times of other raw materials, be beaten with beater, mixed slurry, beating time 1h, slurry is made
The beating degree of material is controlled in 50~60 ° of SR;(2) mixing slurry is made into hanging raw stock by copy paper, squeezing, drying, coiling process;
Obtain a kind of Environment-friendlywallpaper wallpaper.
The wallpaper prepared is soft, and color is uniform, the content 0.21mg/m of formaldehyde after 3 days3。
Comparative example 2
A kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black, comprising the following steps: (1) prepare glucose solution, 5 portions of grapes
Sugar is dissolved in 200 parts of water;(2) by 20 parts of wood pulp cellulose, 80 parts of polyester fiber, water is added, so that the quality of water is other raw materials
70 times, be beaten with beater, mixed slurry, beating time 1h be made, the beating degree of slurry is controlled in 50~60 ° of SR;
(3) mixing slurry is made into hanging raw stock by copy paper, squeezing, drying, coiling process;(4) glucose obtained step (1) is molten
Liquid sprays on hanging raw stock, and is sent to pyroreaction kettle, adds water, carries out hydro-thermal reaction, 180 DEG C of reaction temperature, reacts 3h,
Obtain a kind of Environment-friendlywallpaper wallpaper of brownish black.
The wallpaper prepared is soft, irregular colour one, the content 0.13mg/m of formaldehyde after 3 days3。
These are only the preferred embodiment of the present invention, is not intended to restrict the invention, although referring to embodiment to this
Invention is described in detail, for those skilled in the art, still can be to recorded in foregoing embodiments
Technical solution modify or equivalent replacement of some of the technical features, but it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of Environment-friendlywallpaper wallpaper of brownish black, which is characterized in that the raw material of wallpaper includes 5-30 parts of wood pulp cellulose, polyester fiber
30-100 parts, 1-15 parts of glucose, 1-10 parts of starch, water is 20-100 times of other total mass of raw materiales;The glucose and shallow lake
Hydro-thermal reaction occurs under the high temperature conditions and obtains a nanometer carbosphere for powder, and the Environment-friendlywallpaper wallpaper is brownish black.
2. a kind of Environment-friendlywallpaper wallpaper of brownish black as described in claim 1, which is characterized in that 170-190 DEG C of hydrothermal temperature.
3. a kind of Environment-friendlywallpaper wallpaper of brownish black as described in claim 1, which is characterized in that the hydro-thermal reaction time 2-5 hours.
4. a kind of Environment-friendlywallpaper wallpaper of brownish black as described in claim 1, which is characterized in that the thickness of wallpaper is less than 1mm, described
Wallpaper is brown or black.
5. a kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black according to any one of claims 1-4, which is characterized in that including
Following steps: (1) glucose/starch solution is prepared;(2) wood pulp cellulose, polyester fiber are added to Portugal obtained in step (1)
It in grape sugar juice, is beaten with beater, mixed slurry is made;(3) mixing slurry is passed through into copy paper, squeezing, drying, fourth hand
Sequence makes hanging raw stock;(4) hanging raw stock that step (3) obtains is sent to pyroreaction kettle, adds water, carry out hydro-thermal reaction,
Obtain a kind of Environment-friendlywallpaper wallpaper of brownish black.
6. a kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black as claimed in claim 5, which is characterized in that step (4) it is anti-
Answering temperature is 170-190 DEG C, reaction time 2-5 hour.
7. a kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black as claimed in claim 5, which is characterized in that step (2) mashing
The beating degree of time 0.5-1.5 hour, slurry are controlled in 50~60 ° of SR.
8. a kind of preparation method of the Environment-friendlywallpaper wallpaper of brownish black as claimed in claim 5, which is characterized in that step (2) mashing
When one of fire retardant, softening agent, water repellent or a variety of can also be added into slurry.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102268835A (en) * | 2010-06-03 | 2011-12-07 | 中国制浆造纸研究院 | Preparation method for tile stock |
WO2014208934A1 (en) * | 2013-06-24 | 2014-12-31 | Lg Hausys, Ltd. | Absorption and desorption wallpaper and method of manufacturing the same |
CN102978995B (en) * | 2012-11-01 | 2015-06-03 | 福建希源纸业有限公司 | Production method for base wallpaper |
CN107189494A (en) * | 2017-05-23 | 2017-09-22 | 景德镇陶瓷大学 | A kind of zirconium silicate wraps up the preparation method of nano carbon microsphere ceramic black material |
CN107366195A (en) * | 2017-09-20 | 2017-11-21 | 武汉菡美洛建筑材料有限公司 | A kind of light soft sound insulation high-adhesiveness wallpaper and its manufacture method |
CN107476137A (en) * | 2017-09-13 | 2017-12-15 | 武汉菡美洛建筑材料有限公司 | A kind of antibacterial environment protection wallpaper |
-
2018
- 2018-07-26 CN CN201810835137.7A patent/CN108951299B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102268835A (en) * | 2010-06-03 | 2011-12-07 | 中国制浆造纸研究院 | Preparation method for tile stock |
CN102978995B (en) * | 2012-11-01 | 2015-06-03 | 福建希源纸业有限公司 | Production method for base wallpaper |
WO2014208934A1 (en) * | 2013-06-24 | 2014-12-31 | Lg Hausys, Ltd. | Absorption and desorption wallpaper and method of manufacturing the same |
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CN107476137A (en) * | 2017-09-13 | 2017-12-15 | 武汉菡美洛建筑材料有限公司 | A kind of antibacterial environment protection wallpaper |
CN107366195A (en) * | 2017-09-20 | 2017-11-21 | 武汉菡美洛建筑材料有限公司 | A kind of light soft sound insulation high-adhesiveness wallpaper and its manufacture method |
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