CN108951210A - A kind of composite reactive golden dye and its application - Google Patents
A kind of composite reactive golden dye and its application Download PDFInfo
- Publication number
- CN108951210A CN108951210A CN201810511800.8A CN201810511800A CN108951210A CN 108951210 A CN108951210 A CN 108951210A CN 201810511800 A CN201810511800 A CN 201810511800A CN 108951210 A CN108951210 A CN 108951210A
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- Prior art keywords
- composite reactive
- dye
- formula
- reactive golden
- golden dye
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/382—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8219—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
Abstract
The invention discloses a kind of composite reactive golden dye and its application, composite reactive golden dye includes two kinds of specific components, formula (I) and formula (II), and M independently is H, Na, K or Li in each component；And its application in the dyeing of polyamide fibre union and in nylon cotton interwoven textile article；Composite reactive golden dye of the invention can individually dye nylon cotton interwoven fabric, cooperate without other type dyes and dye, and bright and beautiful cotton can be carried out while be dyed in same bath, colouring synchronism is consistent, staining procedure has been simplified, and has reduced the dosage of dyeing salt, alkali.
Description
Technical field
The invention belongs to textile printing and dyeing fields, more particularly to the reactive dye of bright and beautiful cotton, and in particular to a kind of composite reactive
Golden dye and its application.
Background technique
With the improvement of living standards, consumer has further requirement to the comfort and functionality of garment material,
Wherein with its hygroscopicity, strong, good heat preservation performance, the advantages that heat resistance is excellent, comfort level is high, receive the favor of consumer to pure cotton fabric,
But pure cotton fabric there is also easy wrinkle, easily shrinks, flexible type, it is not acidproof the disadvantages of, apply it and have received certain limitation, at present
The exploitation of nylon cotton interwoven fabric is received by the market very much, advantage are as follows: gloss is gorgeous, feel is full, ventilating comfortable and easy to wear, bullet
Property it is good, it is crease-resistant wear-resisting, it is with a good drape effect, be the first choice of high-grade fabric, be based on this, open in the prior art for nylon cotton interwoven fabric
Send out specific dyestuff and matched dyeing, the colouring method generallyd use are as follows:
The first, two bath resisdye method dyeing exhaust foot water again that is, with neutral, acid dyes or dispersion dye polyamide fibre after having contaminated
With medium temperature Dyeing of Cotton Fabric with Reactive Dyes, the advantages of being dyed using the method is the color (coloured light, the depth) of polyamide fibre and cotton fiber in resisdye
It can mutually make up in the process, cloth cover color is easier to adjust and control, but time-consuming there is such as technique, processing for its disadvantage
Low output, energy consumption are big, sewage discharge is more, deficiency in economic performance etc.；
Second, neutral dye 85 DEG C of dyes brocade is cooled to 60 DEG C plus alkali fixation again, with Dyeing of Cotton Fabric with Reactive Dyes, then washing,
Washing, however the method is not achieved polyamide fibre highest and exhausts dye there are still when obvious disadvantage, specially 85 DEG C of dyeing of neutral dye
95 DEG C -98 DEG C of temperature, not exclusively, fastness is poor, and medium temperature reactive dye are at relatively high temperatures to polyamide fibre staining weight, coloured light for colouring
Poor reproducibility, toning are difficult.
Therefore, other types of dyestuff must be cooperated when contaminating nylon cotton interwoven fabric with current reactive dye, and need substep
Suddenly polyamide fibre and cotton are dyed respectively, causes processing step cumbersome and time-consuming, quantity of wastewater effluent is big, is unfavorable for energy-saving ring
It protects, reduce production cost；Those skilled in the art, which urgently seeks one kind, to carry out while dye to bright and beautiful cotton in same bath
Reactive dye.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide a kind of golden yellow dye of composite reactive
Material, can individually dye nylon cotton interwoven fabric, without the cooperation dyeing of other type dyes, and can be right in same bath
Bright and beautiful cotton carries out while dyeing, and colouring synchronism is consistent, has simplified staining procedure, and reduce the dosage of dyeing salt, alkali.
The present invention also provides composite reactive golden dyes to the application in nylon cotton interwoven textile dyeing.
The present invention additionally provides a kind of nylon cotton interwoven textile article simultaneously.
In order to solve the above technical problems, a kind of technical solution that the present invention takes is as follows:
A kind of composite reactive golden dye, the composite reactive golden dye include component A shown in formula (I) and formula (II)
Shown in component B,
Wherein, the M in formula (I) and formula (II) independently is H, Na, K or Li.
Some preferred aspects according to the present invention, in terms of mass percentage, it is golden yellow that the formula (I) accounts for the composite reactive
The mass percentage of dyestuff is 60-85%.
It is further preferred that the mass percentage that the formula (I) accounts for the composite reactive golden dye is 65-75%.
Some preferred aspects according to the present invention, in terms of mass percentage, the formula (II) accounts for the composite reactive gold
The mass percentage of yellow dye is 1-20%.
It is further preferred that the mass percentage that the formula (II) accounts for the composite reactive golden dye is 5-15%.
More according to the present invention specific and preferred aspect, in terms of mass percentage, the golden yellow dye of composite reactive
Material further includes accounting for the alkali metal sulfates that the mass percentage of the composite reactive golden dye is 10-30%.
Some specific aspects according to the present invention, the alkali metal sulfates are selected from sodium sulphate, potassium sulfate and lithium sulfate
One of or a variety of combinations.
More according to the present invention specific and preferred aspect, the component A are selected from one of such as flowering structure or more
The combination of kind:
More according to the present invention specific and preferred aspect, the component B are selected from one of such as flowering structure or more
The combination of kind:
Another technical solution provided by the invention: a kind of colouring method of nylon cotton interwoven fabric, the colouring method include
Following steps:
(1) composite reactive golden dye described above is configured to dye liquor at 30-50 DEG C；
(2) temperature of the dye liquor is risen to 90-100 DEG C, then nylon cotton interwoven fabric is dyed；
(3) step (2) is cooled to 75-85 DEG C through hyperchromatic nylon cotton interwoven fabric and dye liquor, the water after lye fixation
It washes, soaps.
Some preferred aspects according to the present invention in step (2), make the dye of the dyeing at 95-98 DEG C of temperature
It is carried out in liquid.
According to the present invention, lye used in step (3) is the aqueous slkali that soda ash is prepared.
According to the present invention, dyestuff used in the colouring method is only in composite reactive golden dye described above
One or more combinations.
Another technical solution provided by the invention: a kind of nylon cotton interwoven textile article, the nylon cotton interwoven textile article contain
There is composite reactive golden dye described above.
Due to the use of above technical scheme, the invention has the following advantages over the prior art:
Composite reactive golden dye provided by the invention can individually dye nylon cotton interwoven fabric, be not necessarily to other classes
Type dye cooperation dyeing, and bright and beautiful cotton can be carried out while be dyed in same bath, colouring synchronism is consistent, has simplified dyeing step
Suddenly, it is time-consuming to reduce dyeing, dyeing time-consuming shortens half or so when reaching identical dyeing effect than originally, while also reducing
Dyeing salt, alkali number and slurry amount, and then the discharge that can greatly reduce sewage, sludge etc., reduce the dirt of enterprise
Cost of water treatment and cost of material especially meet instantly to the high standards in terms of environmental protection.
Specific embodiment
Currently, in the prior art when being dyed especially golden yellow to polyamide fibre union, require substantially using
At least two type dyes respectively step by step in polyamide fibre union polyamide fibre and cotton individually dye, however multiple types
Dyestuff individually carries out independent dyeing to polyamide fibre and cotton, on the one hand, the difficulty for increasing polyamide fibre and cotton colouring consistency is not easy to grasp
Make, dyeing easily defect ware occurs, and on the other hand, multi-step dyes cause the complicated of dyeing respectively, and time-consuming, and needs
A large amount of dyeing salt, alkali number, cause a large amount of discharges of sewage, sludge etc., all unfavorable to enterprise and environment.
In practice, it has been found that when component B shown in component A shown in formula (I) and formula (II) is carried out compounded combination
In use, can be realized one-bath dyeing, can realizing homogencous dyes to polyamide fibre and cotton in polyamide fibre union while contaminating gold
Yellow, and colo(u)r specification is almost the same with coloured light on two kinds of fibers, has reached colouring synchronism, and considerably reduce dyeing salt,
Alkali number, and then the discharge that can greatly reduce sewage, sludge etc. shorten dyeing time-consuming, are conducive to industrialized big rule
Mould application.
Above scheme is described further below in conjunction with specific embodiment；It should be understood that these embodiments are for illustrating
The basic principles, principal features and advantages of the present invention, and the present invention is not by the scope limitation of following embodiment；It is used in embodiment
Implementation condition further adjustment can be done according to specific requirement, the implementation condition being not specified is usually the item in routine experiment
Part.
In following, non-specified otherwise, all raw materials are prepared both from commercially available or conventional method by this field
And it obtains.
Embodiment 1
The present embodiment provides a kind of composite reactive golden dyes, in terms of mass percentage, including following component: formula (I-
1) component B 10% and sodium sulphate 20% shown in component A 70%, formula shown in (II -1).
Preparation method: weighing each component by formula rate, then mix, and stirs evenly golden yellow to get the composite reactive
Dyestuff.
Embodiment 2
The present embodiment provides a kind of composite reactive golden dyes, in terms of mass percentage, including following component: formula (I-
1) component B 12% and sodium sulphate 23% shown in component A 65%, formula shown in (II -2).
The preparation method is the same as that of Example 1.
Embodiment 3
The present embodiment provides a kind of composite reactive golden dyes, in terms of mass percentage, including following component: formula (I-
2) component B 11% and sodium sulphate 21% shown in component A 68%, formula shown in (II -3).
The preparation method is the same as that of Example 1.
Embodiment 4
The present embodiment provides a kind of composite reactive golden dyes, in terms of mass percentage, including following component: formula (I-
3) component B 10% and sodium sulphate 17% shown in component A 73%, formula shown in (II -4).
The preparation method is the same as that of Example 1.
Comparative example 1
Commercially available active golden dye.Structural formula are as follows:
Since active golden yellow dyestuff common at present individually dyes the polyamide fibre being difficult to realize in nylon cotton interwoven fabric and cotton
Simultaneously dyeing simultaneously, therefore, to reach and ideal dyeing effect (colouring consistency, coloration, color fastness etc.), colouring method
Prior art is selected to carry out, specific as follows:
Processing step is successively as follows: first select commercially available active golden yellow dyes cotton (60 DEG C of dyeing temperature or so), alkali fixation,
Washing twice, peracid, wash, soap, wash select twice, again acid dyes dye polyamide fibre (98 DEG C of dyeing temperature or so), wash.
Application example
Composite reactive golden dye provided by embodiment 1-4 is used for the dyeing of nylon cotton interwoven fabric, due to the application
Composite reactive golden dye individually can individually dye polyamide fibre union, therefore select the specific colouring method of the present invention
It carries out, specific colouring method is as follows:
Processing step is successively as follows: selecting composite reactive golden dye (practical operation prepared by the embodiment of the present application 1-4
In be dissolved in water and be configured to dye liquor) independent (98 DEG C of dyeing temperature or so) dyed to nylon cotton interwoven fabric, are cooled to 80 DEG C of left sides
The right side plus alkali fixation, then wash, soap.
The dyestuff of embodiment 1-4 and comparative example 1 dye nylon cotton interwoven fabric below and reach essentially identical
Dyeing effect when, measurement under different dyeing concentrations used sodium sulphate dosage and soda ash dosage.Test result is as follows table
Shown in one:
Table one
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention, it is all according to the present invention
Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of composite reactive golden dye, which is characterized in that the composite reactive golden dye includes component shown in formula (I)
Component B shown in A and formula (II),
Wherein, the M in formula (I) and formula (II) independently is H, Na, K or Li.
2. composite reactive golden dye according to claim 1, which is characterized in that in terms of mass percentage,
The mass percentage that the formula (I) accounts for the composite reactive golden dye is 60-85%；And/or
The mass percentage that the formula (II) accounts for the composite reactive golden dye is 1-20%.
3. composite reactive golden dye according to claim 2, which is characterized in that the formula (I) accounts for the composite reactive
The mass percentage of golden dye is 65-75%；And/or
The mass percentage that the formula (II) accounts for the composite reactive golden dye is 5-15%.
4. composite reactive golden dye according to claim 1, which is characterized in that described multiple in terms of mass percentage
Closing active golden yellow dyestuff further includes accounting for the alkali metal sulphuric acid that the mass percentage of the composite reactive golden dye is 10-30%
Salt.
5. composite reactive golden dye according to claim 4, which is characterized in that the alkali metal sulfates are selected from sulphur
One of sour sodium, potassium sulfate and lithium sulfate or a variety of combinations.
6. composite reactive golden dye according to claim 1, which is characterized in that the component A is selected from such as flowering structure
One of or a variety of combinations:
7. composite reactive golden dye according to claim 1 or 6, which is characterized in that the component B is selected from following knot
One of structure or a variety of combinations:
8. a kind of colouring method of nylon cotton interwoven fabric, which is characterized in that the colouring method includes the following steps:
(1) composite reactive golden dye described in any one of claim 1-7 claim is configured to contaminate at 30-50 DEG C
Liquid；
(2) temperature of the dye liquor is risen to 90-100 DEG C, then nylon cotton interwoven fabric is dyed；
(3) step (2) is cooled to 75-85 DEG C through hyperchromatic nylon cotton interwoven fabric and dye liquor, is washed after lye fixation, soap
It washes.
9. the colouring method of nylon cotton interwoven fabric according to claim 8, which is characterized in that used in the colouring method
Dyestuff be only one of composite reactive golden dye described in any one of claim 1-7 claim or a variety of groups
It closes.
10. a kind of nylon cotton interwoven textile article, which is characterized in that the nylon cotton interwoven textile article contains in claim 1-7
Composite reactive golden dye described in any one claim.
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| CN201810511800.8A CN108951210A (en) | 2018-05-25 | 2018-05-25 | A kind of composite reactive golden dye and its application |
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| CN201810511800.8A CN108951210A (en) | 2018-05-25 | 2018-05-25 | A kind of composite reactive golden dye and its application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114561818A (en) * | 2022-04-06 | 2022-05-31 | 浙江亿得新材料股份有限公司 | Compounding method of reactive dye yellow suitable for dyeing composite cellulose fibers, and product and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440227A (en) * | 2007-11-22 | 2009-05-27 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN102161840A (en) * | 2011-02-16 | 2011-08-24 | 刘鹏 | Active black dye composition |
| CN102321986A (en) * | 2011-08-10 | 2012-01-18 | 无锡市联盛印染有限公司 | A kind of silk-cotton fabric co-bathing dyeing method |
| CN102558907A (en) * | 2011-12-30 | 2012-07-11 | 浙江科永化工有限公司 | Compound active black dye composition |
| CN103965653A (en) * | 2014-05-12 | 2014-08-06 | 浙江亿得化工有限公司 | Post-mercerized composite activated dye as well as dyeing method and use thereof |
| CN104513497A (en) * | 2013-09-27 | 2015-04-15 | 浙江科永化工有限公司 | Reactive black dye composition |
| CN107974103A (en) * | 2017-12-04 | 2018-05-01 | 湖北华丽染料工业有限公司 | A kind of composite reactive yellow dye |
-
2018
- 2018-05-25 CN CN201810511800.8A patent/CN108951210A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440227A (en) * | 2007-11-22 | 2009-05-27 | 上海雅运精细化工有限公司 | Yellow reactive dye composition and use thereof |
| CN102161840A (en) * | 2011-02-16 | 2011-08-24 | 刘鹏 | Active black dye composition |
| CN102321986A (en) * | 2011-08-10 | 2012-01-18 | 无锡市联盛印染有限公司 | A kind of silk-cotton fabric co-bathing dyeing method |
| CN102558907A (en) * | 2011-12-30 | 2012-07-11 | 浙江科永化工有限公司 | Compound active black dye composition |
| CN104513497A (en) * | 2013-09-27 | 2015-04-15 | 浙江科永化工有限公司 | Reactive black dye composition |
| CN103965653A (en) * | 2014-05-12 | 2014-08-06 | 浙江亿得化工有限公司 | Post-mercerized composite activated dye as well as dyeing method and use thereof |
| CN107974103A (en) * | 2017-12-04 | 2018-05-01 | 湖北华丽染料工业有限公司 | A kind of composite reactive yellow dye |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114561818A (en) * | 2022-04-06 | 2022-05-31 | 浙江亿得新材料股份有限公司 | Compounding method of reactive dye yellow suitable for dyeing composite cellulose fibers, and product and application thereof |
| CN114561818B (en) * | 2022-04-06 | 2024-02-13 | 浙江亿得新材料股份有限公司 | Compounding method of reactive dye yellow suitable for dyeing composite cellulose fiber, product and application thereof |
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Application publication date: 20181207 |